KR20200140899A - 합성 피혁 - Google Patents
합성 피혁 Download PDFInfo
- Publication number
- KR20200140899A KR20200140899A KR1020207032706A KR20207032706A KR20200140899A KR 20200140899 A KR20200140899 A KR 20200140899A KR 1020207032706 A KR1020207032706 A KR 1020207032706A KR 20207032706 A KR20207032706 A KR 20207032706A KR 20200140899 A KR20200140899 A KR 20200140899A
- Authority
- KR
- South Korea
- Prior art keywords
- mass
- urethane resin
- parts
- preferable
- synthetic leather
- Prior art date
Links
- 239000002649 leather substitute Substances 0.000 title claims abstract description 36
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract description 136
- 125000000129 anionic group Chemical group 0.000 claims abstract description 55
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 51
- 239000010410 layer Substances 0.000 claims abstract description 44
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 37
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 37
- 239000012790 adhesive layer Substances 0.000 claims abstract description 35
- 239000002994 raw material Substances 0.000 claims abstract description 28
- 125000003118 aryl group Chemical group 0.000 claims abstract description 27
- 239000011342 resin composition Substances 0.000 claims abstract description 27
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 9
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 alkyl sulfosuccinate Chemical compound 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 32
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 51
- 150000003077 polyols Chemical class 0.000 description 43
- 229920005862 polyol Polymers 0.000 description 42
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 38
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 35
- 210000003491 skin Anatomy 0.000 description 32
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 27
- 239000004970 Chain extender Substances 0.000 description 26
- 230000015572 biosynthetic process Effects 0.000 description 24
- 239000000203 mixture Substances 0.000 description 23
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 21
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 19
- 229910052757 nitrogen Inorganic materials 0.000 description 19
- 239000000243 solution Substances 0.000 description 19
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 16
- 239000004793 Polystyrene Substances 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 16
- 229920002223 polystyrene Polymers 0.000 description 16
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 15
- 230000007062 hydrolysis Effects 0.000 description 14
- 238000006460 hydrolysis reaction Methods 0.000 description 14
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 14
- 230000003472 neutralizing effect Effects 0.000 description 14
- 238000003786 synthesis reaction Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 125000003277 amino group Chemical group 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 229920001451 polypropylene glycol Polymers 0.000 description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 10
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 238000010992 reflux Methods 0.000 description 10
- 239000005058 Isophorone diisocyanate Substances 0.000 description 9
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 9
- 239000003960 organic solvent Substances 0.000 description 9
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- 229920000515 polycarbonate Polymers 0.000 description 9
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 8
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- 238000001035 drying Methods 0.000 description 7
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- 238000004519 manufacturing process Methods 0.000 description 7
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 6
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 6
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 6
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- 239000000126 substance Substances 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 5
- 238000004440 column chromatography Methods 0.000 description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 5
- 229920000570 polyether Polymers 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 4
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 4
- VATRWWPJWVCZTA-UHFFFAOYSA-N 3-oxo-n-[2-(trifluoromethyl)phenyl]butanamide Chemical compound CC(=O)CC(=O)NC1=CC=CC=C1C(F)(F)F VATRWWPJWVCZTA-UHFFFAOYSA-N 0.000 description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 4
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 4
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000002723 alicyclic group Chemical group 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 239000012975 dibutyltin dilaurate Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 210000002615 epidermis Anatomy 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
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- CKFGINPQOCXMAZ-UHFFFAOYSA-N methanediol Chemical compound OCO CKFGINPQOCXMAZ-UHFFFAOYSA-N 0.000 description 4
- 239000004745 nonwoven fabric Substances 0.000 description 4
- 230000002940 repellent Effects 0.000 description 4
- 239000005871 repellent Substances 0.000 description 4
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical group NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 3
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- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical group NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 3
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- KXBFLNPZHXDQLV-UHFFFAOYSA-N [cyclohexyl(diisocyanato)methyl]cyclohexane Chemical compound C1CCCCC1C(N=C=O)(N=C=O)C1CCCCC1 KXBFLNPZHXDQLV-UHFFFAOYSA-N 0.000 description 3
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- 125000002091 cationic group Chemical group 0.000 description 3
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- 235000014113 dietary fatty acids Nutrition 0.000 description 3
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- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
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- NNOZGCICXAYKLW-UHFFFAOYSA-N 1,2-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC=C1C(C)(C)N=C=O NNOZGCICXAYKLW-UHFFFAOYSA-N 0.000 description 2
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- JVYDLYGCSIHCMR-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butanoic acid Chemical compound CCC(CO)(CO)C(O)=O JVYDLYGCSIHCMR-UHFFFAOYSA-N 0.000 description 2
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- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
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- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
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Classifications
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- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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Abstract
Description
Claims (5)
- 적어도, 기재(基材)(ⅰ), 접착층(ⅱ), 및 표피층(ⅲ)을 갖는 합성 피혁으로서,
상기 접착층(ⅱ)이, 방향족 폴리이소시아네이트(a1)를 원료로 하는 우레탄 수지(A), 및 물(B)을 함유하는 우레탄 수지 조성물에 의해 형성된 것이며, 또한,
상기 표피층(ⅲ)이, 음이온성기의 농도가 0.25m㏖/g 이하인 음이온성 우레탄 수지(X), 물(Y), 및 음이온성 계면활성제(Z)를 함유하는 우레탄 수지 조성물에 의해 형성된 것임을 특징으로 하는 합성 피혁. - 제1항에 있어서,
상기 방향족 폴리이소시아네이트(a1)가, 톨루엔디이소시아네이트를 포함하는 것인 합성 피혁. - 제1항 또는 제2항에 있어서,
상기 우레탄 수지(A) 중의 방향환의 농도가, 0.1∼2.5㏖/㎏의 범위인 합성 피혁. - 제1항 내지 제3항 중 어느 한 항에 있어서,
상기 우레탄 수지(A)의 중량 평균 분자량이, 2,000∼150,000의 범위인 합성 피혁. - 제1항 내지 제4항 중 어느 한 항에 있어서,
상기 음이온성 계면활성제(Z)가, 알킬설포숙신산염인 합성 피혁.
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CN113882166A (zh) * | 2021-10-12 | 2022-01-04 | 世联汽车内饰(苏州)有限公司 | 一种导电pu合成革及其制备方法 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003335836A (ja) * | 2002-05-17 | 2003-11-28 | Dainippon Ink & Chem Inc | ポリウレタン樹脂の水性分散体及び水性接着剤 |
JP2004051778A (ja) * | 2002-07-19 | 2004-02-19 | Dainippon Ink & Chem Inc | ポリウレタン樹脂水性分散体及び水性接着剤 |
JP2007119749A (ja) | 2005-09-27 | 2007-05-17 | Dai Ichi Kogyo Seiyaku Co Ltd | 繊維積層体表皮層用ポリウレタン樹脂水分散体組成物、繊維積層体の製造方法及び合成皮革 |
CN102618202A (zh) * | 2012-04-01 | 2012-08-01 | 江阴市诺科科技有限公司 | 一种制革用水性聚氨酯复合胶及其制备方法、应用 |
WO2013027489A1 (ja) * | 2011-08-22 | 2013-02-28 | Dic株式会社 | 皮革様シート及びその製造方法 |
KR101298892B1 (ko) * | 2005-09-30 | 2013-08-21 | 가부시키가이샤 구라레 | 피혁형 시트 및 그 제조 방법 |
WO2016140025A1 (ja) * | 2015-03-03 | 2016-09-09 | Dic株式会社 | 皮革様シートの製造方法 |
WO2017169244A1 (ja) * | 2016-04-01 | 2017-10-05 | Dic株式会社 | 一液型水性樹脂組成物、及び、繊維積層体 |
WO2018110105A1 (ja) * | 2016-12-12 | 2018-06-21 | Dic株式会社 | 水性ウレタン樹脂組成物、及び、合成皮革 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100389934B1 (ko) * | 2000-07-05 | 2003-07-04 | 다이니뽄 잉끼 가가꾸 고오교오 가부시끼가이샤 | 합성피혁용 수성 건식 적층 접착제 조성물 및 그것을사용하여 되는 합성피혁의 제조 방법 |
JP2003165950A (ja) * | 2001-11-29 | 2003-06-10 | Mitsui Chemicals Inc | 耐溶剤性に優れる水性塗工材 |
JP6179697B1 (ja) * | 2016-04-14 | 2017-08-16 | Dic株式会社 | 水性ウレタン樹脂組成物、及び、合成皮革 |
WO2019235121A1 (ja) * | 2018-06-07 | 2019-12-12 | Dic株式会社 | 合成皮革 |
US11466402B2 (en) * | 2018-06-07 | 2022-10-11 | Dic Corporation | Synthetic leather |
-
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Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2003335836A (ja) * | 2002-05-17 | 2003-11-28 | Dainippon Ink & Chem Inc | ポリウレタン樹脂の水性分散体及び水性接着剤 |
JP2004051778A (ja) * | 2002-07-19 | 2004-02-19 | Dainippon Ink & Chem Inc | ポリウレタン樹脂水性分散体及び水性接着剤 |
JP2007119749A (ja) | 2005-09-27 | 2007-05-17 | Dai Ichi Kogyo Seiyaku Co Ltd | 繊維積層体表皮層用ポリウレタン樹脂水分散体組成物、繊維積層体の製造方法及び合成皮革 |
KR101298892B1 (ko) * | 2005-09-30 | 2013-08-21 | 가부시키가이샤 구라레 | 피혁형 시트 및 그 제조 방법 |
WO2013027489A1 (ja) * | 2011-08-22 | 2013-02-28 | Dic株式会社 | 皮革様シート及びその製造方法 |
JP5196088B1 (ja) * | 2011-08-22 | 2013-05-15 | Dic株式会社 | 皮革様シート及びその製造方法 |
CN102618202A (zh) * | 2012-04-01 | 2012-08-01 | 江阴市诺科科技有限公司 | 一种制革用水性聚氨酯复合胶及其制备方法、应用 |
WO2016140025A1 (ja) * | 2015-03-03 | 2016-09-09 | Dic株式会社 | 皮革様シートの製造方法 |
WO2017169244A1 (ja) * | 2016-04-01 | 2017-10-05 | Dic株式会社 | 一液型水性樹脂組成物、及び、繊維積層体 |
WO2018110105A1 (ja) * | 2016-12-12 | 2018-06-21 | Dic株式会社 | 水性ウレタン樹脂組成物、及び、合成皮革 |
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