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KR100448241B1 - Pearl composition and cosmetic composition having pearl-like feeling comprising them thereof - Google Patents

Pearl composition and cosmetic composition having pearl-like feeling comprising them thereof Download PDF

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Publication number
KR100448241B1
KR100448241B1 KR10-2001-0080562A KR20010080562A KR100448241B1 KR 100448241 B1 KR100448241 B1 KR 100448241B1 KR 20010080562 A KR20010080562 A KR 20010080562A KR 100448241 B1 KR100448241 B1 KR 100448241B1
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pearl
composition
weight
examples
feeling
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KR10-2001-0080562A
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Korean (ko)
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KR20030050165A (en
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민두식
박현석
유인기
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주식회사 엘지생활건강
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/342Alcohols having more than seven atoms in an unbroken chain
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Emergency Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

본 발명은 음이온계면활성제, 비이온계면활성제, 펄화제 및 C14내지 C22의 직쇄 알킬기를 갖는 고급알코올을 포함하여 펄감 및 제품의 안정성을 향상시킨 펄 조성물 및 이를 포함하는 펄감을 갖는 화장료 조성물에 관한 것으로서, 상기 펄 조성물은 활성분 28%인 음이온계면활성제 30 내지 70중량%, 비이온계면활성제 2 내지 8중량%, 펄화제 5 내지 15중량%, C14내지 C22의 직쇄 알킬기를 갖는 고급알코올 1 내지 14중량% 및 잔량으로서 물을 포함하여 이루어짐을 특징으로 한다.The present invention is an anionic surfactant, a nonionic surfactant, a pulping agent and a pearl composition including a higher alcohol having a C 14 to C 22 straight chain alkyl group to improve the stability of the pearl and product and a cosmetic composition having a pearl Regarding, the pearl composition is a high-quality having 30 to 70% by weight of an anionic surfactant of 28% active ingredient, 2 to 8% by weight of nonionic surfactant, 5 to 15% by weight of a pearling agent, C 14 to C 22 It is characterized by consisting of 1 to 14% by weight of alcohol and water as a balance.

Description

펄 조성물 및 이를 포함하는 펄감을 갖는 화장료 조성물{Pearl composition and cosmetic composition having pearl-like feeling comprising them thereof}Pearl composition and cosmetic composition having a pearl-like feeling comprising the same

본 발명은 음이온계면활성제, 비이온계면활성제, 펄화제 및 고급알코올을 포함하여 펄감 및 제품의 안정성을 향상시킨 펄 조성물 및 이를 포함하는 펄감을 갖는 화장료 조성물에 관한 것이다.The present invention relates to a pearl composition including anionic surfactants, nonionic surfactants, pearling agents and higher alcohols to improve the stability of pearls and products, and to a cosmetic composition having the pearls including the same.

일반적으로, 펄감(Pearl-like feeling)을 가져 화려한 외관을 갖는 세정제 또는 화장료 조성물은 통상의 세정제 또는 화장료 조성물에 에틸렌글리콜모노에스테르, 에틸렌글리콜디에스테르, 프로필렌글리콜, 올리고머알킬렌글리콜 등의 펄화제를 투입한 다음, 70℃ 이상의 온도로 가열한 후 펄화제를 용융시킨 다음 냉각시킴으로써 제조되어 왔다. 그러나, 이러한 세정제 또는 화장료 조성물은 우수한 펄감을 얻기 위한 최적화된 조성 및 냉각조건을 얻는데 한계가 있으므로 화려한 펄감을 얻지 못하는 단점이 있었다.In general, a detergent or cosmetic composition having a pearl-like feeling and having a colorful appearance may include a pearlizing agent such as ethylene glycol monoester, ethylene glycol diester, propylene glycol, oligomeric alkylene glycol, etc. in a conventional detergent or cosmetic composition. It has been prepared by injecting, heating to a temperature of 70 ° C. or more, and then melting and cooling the pulping agent. However, such a cleaner or cosmetic composition has a disadvantage in that it is difficult to obtain a gorgeous pearly feeling because there is a limit in obtaining an optimized composition and cooling conditions for obtaining a good pearly feeling.

이러한 단점을 극복하기 위한 방안으로서, 미국특허출원 제5,925,604호에 펄화제만을 사용한 종래의 방법 대신에 펄화제에 여러 성분들을 혼합함으로써 "콜드펄(Cold Pearl)" 또는 "액상펄(Liquid Pearl)"이라 불리는 펄 조성물을 제조하고,이를 세정제 또는 화장료 조성물에 투입함으로써 제조되는 펄감을 갖는 세정제 또는 화장료 조성물에 관하여 출원된 바 있다. 이 경우, 펄감을 얻는 시간이 절감되는 효과가 있으나, 경제적인 면에서는 크게 향상되지 못 하였다.As a way to overcome this disadvantage, US Patent Application No. 5,925,604, "Cold Pearl" or "Liquid Pearl" by mixing several components in the pulping agent instead of the conventional method using only the pulping agent. It has been filed with respect to a detergent or a cosmetic composition having a pearly feeling prepared by preparing a pearl composition called this and injecting the same into a detergent or a cosmetic composition. In this case, there is an effect of reducing the time to obtain a pearl, but in terms of economics was not greatly improved.

상기한 미국특허출원 외에, 펄화제, 분산제, 펄보조제를 포함하는 통상의 조성과 일반적인 냉각방식을 이용하여 제조되어, 별도로 제품에 혼합되는 펄 조성물이 다수 제조되어 왔으나, 이들 조성물의 경우 펄입자 크기가 크고 불균일하여 화려하지 못하고 제품의 사용감이 떨어지는 단점이 있었다.In addition to the above-described US patent application, many pearl compositions have been prepared using conventional compositions and general cooling methods including pulping agents, dispersing agents, and pearl adjuvant, and mixed in a separate product. It was large and uneven, so it wasn't glamorous and the product had a downside.

그 외, 미국특허출원 제5,998,354호에는 펄감을 향상시킬 뿐만 아니라 미세한 펄입자를 분산시킴으로써 제품의 안정성을 증가시키기 위하여 베헨산(behenic acid)을 사용한 펄 조성물에 관하여 출원된 바 있으나, 제품의 안정성 증가 효과가 미미한 단점이 있었다.In addition, U.S. Patent Application No. 5,998,354 has been filed with a pearl composition using behenic acid to increase the stability of the product by not only improving the pearly feeling but also dispersing fine pearl particles, but increasing the stability of the product. There was a minor disadvantage.

이에, 본 출원인은 펄 결정의 모양 및 크기가 펄의 외관과 이를 사용한 제품의 안정성에 큰 영향을 끼치게 되는 점을 이용하여 소량 사용하더라도 우수한 펄감 및 제품 안정성을 나타낼 수 있는 본 발명의 펄 조성물을 완성하게 되었다.Accordingly, the present applicant completes the pearl composition of the present invention that can exhibit excellent pearl feeling and product stability even when used in a small amount by using the shape and size of the pearl crystals have a great influence on the appearance of the pearl and the stability of the product using the same. Was done.

본 발명은 앞서 설명한 바와 같은 종래 기술의 문제점을 더욱 효율적으로 해결하기 위하여 제공된 것으로서, 그 목적은 음이온계면활성제, 비이온계면활성제, 펄화제를 포함하는 통상의 펄 조성물에 고급알코올을 혼합하여 사용함으로써 펄감 및 제품의 안정성을 향상시키는 펄 조성물 및 이를 포함하는 펄감을 갖는 화장료 조성물을 제공하고자 하는 것이다.The present invention has been provided to more efficiently solve the problems of the prior art as described above, the object of which is to use a mixture of higher alcohol in a conventional pearl composition comprising anionic surfactant, nonionic surfactant, pulping agent An object of the present invention is to provide a pearl composition for improving the stability of a pearly product and a cosmetic composition having a pearly feeling thereof.

상기한 목적을 달성하기 위하여 본 발명에 따른 펄 조성물은, 활성분 28%인 음이온계면활성제 30 내지 70중량%, 비이온계면활성제 2 내지 8중량%, 펄화제 5 내지 15중량%, C14내지 C22의 직쇄 알킬기를 갖는 고급알코올 1 내지 14중량% 및 잔량으로서 물을 포함하여 이루어짐을 특징으로 한다.In order to achieve the above object, the pearl composition according to the present invention includes an active ingredient of 28%, an anionic surfactant 30 to 70% by weight, nonionic surfactant 2 to 8% by weight, a pulping agent 5 to 15% by weight, C 14 to It is characterized by comprising 1 to 14% by weight of higher alcohol having a straight chain alkyl group of C 22 and water as a balance.

또한, 본 발명에 따른 펄감을 갖는 화장료 조성물은, 공지의 두발 또는 피부 세정용 화장료 조성물에 제 1항의 펄 조성물을 5 내지 40중량%의 양으로 포함시켜 두발 또는 피부 세정용 화장료 조성물로 제형화함을 특징으로 한다.In addition, the cosmetic composition having a pearly feeling according to the present invention is formulated into a cosmetic composition for hair or skin cleansing by containing the pearl composition of claim 1 in a known hair or cosmetic composition for skin cleansing in an amount of 5 to 40% by weight. It features.

이하, 본 발명에 대하여 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.

펄화제 등을 투입함으로써 제조된 세정제 또는 화장료 조성물 중에서 펄입자는 고온의 용융상태에서 냉각과정을 통해 결정화함으로써 형성되는데, 이렇게 하여 형성된 결정의 모양 및 크기가 펄의 외관과 이를 사용한 제품의 안정성에 영향을 미치게 된다. 펄입자는 결정화 과정에서 주로 판상과 침상의 모양을 가짐으로써 빛의 일부는 반사하고 일부는 투과시켜, 투과된 빛이 다시 다른 펄입자에 반사와 투과를 반복하여 간섭현상을 일으킴으로써 펄감이 얻어진다. 따라서, 펄의 결정입자가 너무 큰 경우 빛의 반사를 주로 일으킴으로써 외관상 금속성이 많기는 하나 입자감이 느껴지는 조잡한 펄이 되기 쉽고, 제품의 안정성에 기여하는 정도가 적은 경향이 있다. 한편, 펄의 결정입자가 너무 얇고 작은 경우 제품의 안정성은 증가하지만 펄감이 급격히 감소하여 백탁이 되는 경향이 있다(「Cosmetics &Toiletries」, 96, 65-78, 1981).In the detergent or cosmetic composition prepared by adding a pulping agent, the pearl particles are formed by crystallization through a cooling process in a molten state at a high temperature. The shape and size of the crystals thus formed affect the appearance of the pearl and the stability of the product using the same. Get mad. In the crystallization process, the pearl particles have a plate-like shape and a needle-like shape, reflecting part of the light and transmitting part of it, and the permeated light is repeatedly reflected and transmitted to other pearl particles, causing a pearly feeling. . Therefore, when the crystal grains of pearls are too large, they mainly reflect light, but they tend to be coarse pearls, which are metallic in appearance but have a grainy feeling, and contribute to the stability of the product. On the other hand, when the crystal grains of pearl are too thin and small, the stability of the product is increased, but the pearly feeling is rapidly decreased, which tends to become cloudy ("Cosmetics & Toiletries", 96, 65-78, 1981).

펄입자의 이러한 성향을 이용하여 우수한 펄감 및 안정성을 갖는 펄 조성물을 제조하기 위하여, 본 발명 중 펄 조성물의 성분으로서 음이온계면활성제, 비이온계면활성제 및 펄화제 외에 고급알코올을 더 포함하도록 구성된다.In order to prepare a pearl composition having excellent pearl feeling and stability using this propensity of pearl particles, the components of the pearl composition of the present invention are configured to further include higher alcohols in addition to anionic surfactants, nonionic surfactants and pearling agents.

본 발명 중 음이온계면활성제로서는 라우릴황산나트륨, 라우릴황산암모늄, 폴리옥시에틸렌라우릴황산나트륨, 폴리옥시에틸렌라우릴황산암모늄 등이 사용될 수 있다.In the present invention, as the anionic surfactant, sodium lauryl sulfate, ammonium lauryl sulfate, sodium polyoxyethylene lauryl sulfate, polyoxyethylene lauryl sulfate, and the like can be used.

비이온계면활성제로서는 라우릴산디에탄올아미드, 야자유지방산디에탄올아미드, 야자유지방산모노에탄올아미드 등이 사용될 수 있다.As the nonionic surfactant, lauryl acid diethanolamide, palm oil fatty acid diethanolamide, palm oil fatty acid monoethanolamide, and the like can be used.

펄화제로서는 에틸렌글리콜모노에스테르, 에틸렌글리콜디에스테르, 프로필렌글리콜, 올리고머알킬렌글리콜 등이 사용될 수 있다.Ethylene glycol monoester, ethylene glycol diester, propylene glycol, oligomeric alkylene glycol, etc. can be used as a pearling agent.

고급알코올로서는 C14내지 C22의 직쇄 알킬기를 갖는 고급알코올이 사용되며, 예를 들어, 미리스틸알코올, 세틸알코올, 스테아릴알코올, 베헤닐알코올 등이 사용될 수 있다.As the higher alcohol, higher alcohol having a C 14 to C 22 linear alkyl group is used. For example, myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, or the like can be used.

이하에는 이러한 구성에 따른 본 발명의 펄 조성물의 작용 효과를 상세히 설명한다.Hereinafter, the effect of the pearl composition of the present invention according to such a configuration will be described in detail.

본 발명의 고급알코올로서 C14미만의 알킬기를 갖는 알코올을 사용하는 경우 안정화 효능 및 펄감이 저하되며, C22초과의 알킬기를 갖는 알코올을 사용하는 경우 백탁상태로 펄감이 없어지는 문제점이 있을 수 있다. 따라서, 본 발명의 고급알코올은 C14내지 C22의 직쇄 알킬기를 사용하는 것이 바람직하다. 또한, 상기 고급알코올은 조성물 총 중량에 대하여 1중량% 미만의 양으로 사용되는 경우 안정성 개선 효과가 미미하며, 14중량% 초과의 양으로 사용되는 경우 백탁화가 발생하고 점도가 너무 높아 펄 조성물의 사용이 어렵게 되는 문제점이 있다. 따라서, 본 발명의 고급알코올은 조성물 총 중량에 대하여 1 내지 14중량%의 양으로 포함되는 것이 바람직하다.When using an alcohol having an alkyl group of less than C 14 as the higher alcohol of the present invention, the stabilization efficacy and the pearl is reduced, and when using an alcohol having an alkyl group of more than C 22 may have a problem that the pearl is lost in a cloudy state. . Thus, the higher alcohol of the present invention, it is preferable to use a straight-chain alkyl group of C 14 to C 22. In addition, the higher alcohol has a slight stability improvement effect when used in an amount of less than 1% by weight based on the total weight of the composition, when used in an amount of more than 14% by weight, turbidity occurs and the viscosity is too high to use the pearl composition There is a problem that becomes difficult. Therefore, the higher alcohol of the present invention is preferably included in an amount of 1 to 14% by weight based on the total weight of the composition.

본 발명의 고급알코올의 펄감 및 제품 안정성 상승작용은 펄화제의 함량에 의해 결정된다. 펄화제가 5중량% 미만의 양으로 사용될 경우 상대적으로 고급알코올의 함량비가 너무 높아 백탁상태가 되어 펄감이 없어지는 문제점이 있을 수 있으며, 15중량% 초과의 양으로 사용될 경우 상대적으로 고급알코올의 함량비가 너무 낮아 펄감 및 제품 안정성 상승효과가 없어지는 문제점이 있을 수 있다. 따라서, 본 발명의 펄화제는 조성물 총 중량에 대하여 5 내지 15중량%의 양으로 포함되는 것이 바람직하다.The pearly and product stability synergy of the higher alcohols of the present invention is determined by the content of the pulping agent. When the pulping agent is used in an amount of less than 5% by weight, the content ratio of higher alcohol is relatively high, so there may be a problem that the pearly disappears due to a turbidity, and when used in an amount of more than 15% by weight, the content of higher alcohol There may be a problem that the ratio is too low to increase the pearly and product stability. Therefore, the pulping agent of the present invention is preferably included in an amount of 5 to 15% by weight based on the total weight of the composition.

본 발명의 음이온계면활성제는 주로 펄화제, 비이온계면활성제 및 고급알코올의 분산제로 이용되는 것으로, 활성분 28%인 음이온계면활성제가 30중량% 미만의 양으로 사용될 경우 분산이 제대로 되지 않아 펄이 형성되지 않으며, 70중량% 초과의 양으로 사용될 경우 펄은 형성되나 펄감이 약하고 급속냉각의 조건 설정이 어려워 냉각시간이 장시간 소요되는 문제점이 있을 수 있다. 따라서, 본 발명의 활성분 28%인 음이온계면활성제는 조성물 총 중량에 대하여 30 내지 70중량%의 양으로포함되는 것이 바람직하다.The anionic surfactant of the present invention is mainly used as a dispersing agent of a pulping agent, a nonionic surfactant and a higher alcohol, and when an anionic surfactant having an active content of 28% is used in an amount of less than 30% by weight, pearl is not properly dispersed. If it is not formed, when used in an amount of more than 70% by weight, the pearl is formed, but there is a problem that takes a long time to cool because the pearl is weak and difficult to set the conditions of rapid cooling. Therefore, the anionic surfactant of 28% of the active ingredient of the present invention is preferably included in an amount of 30 to 70% by weight based on the total weight of the composition.

한편, 본 발명의 펄 조성물은 두발 또는 피부 세정용 화장료 조성물 등을 포함한 다양한 형태로 제형화할 수 있다.On the other hand, the pearl composition of the present invention can be formulated in various forms, including hair or skin cleansing cosmetic composition.

이하 펄 조성물을 실시예 및 비교예를 들어 보다 구체적으로 설명하지만 본 발명이 이들예로만 한정되는 것은 아니다.Hereinafter, the pearl composition will be described in more detail with reference to Examples and Comparative Examples, but the present invention is not limited only to these examples.

[실시예 1∼8 및 비교예 1∼2 ][Examples 1-8 and Comparative Examples 1-2]

실시예1Example 1 실시예2Example 2 실시예3Example 3 실시예4Example 4 실시예5Example 5 실시예6Example 6 실시예7Example 7 실시예8Example 8 비교예1Comparative Example 1 비교예2Comparative Example 2 28% 라우릴황산암모늄28% Ammonium Lauryl Sulfate 50.050.0 50.050.0 50.050.0 50.050.0 50.050.0 50.050.0 50.050.0 50.050.0 50.050.0 50.050.0 야자유지방산모노에탄올아미드Palm oil fatty acid monoethanolamide 5.05.0 5.05.0 5.05.0 5.05.0 5.05.0 5.05.0 5.05.0 5.05.0 5.05.0 5.05.0 에틸렌글리콜모노스테아레이트Ethylene Glycol Monostearate 10.010.0 10.010.0 -- -- -- -- -- -- 10.010.0 -- 에틸렌글리콜디스테아레이트Ethylene Glycol Distearate -- -- 10.010.0 10.010.0 10.010.0 10.010.0 10.010.0 10.010.0 -- 10.010.0 미리스틸알코올Myristyl Alcohol -- -- -- -- 55 -- -- -- -- -- 세틸알코올Cetyl alcohol 55 1010 55 1010 -- 55 -- -- -- -- 베헤닐알코올Behenyl Alcohol -- -- -- -- -- -- 55 -- -- -- 스테아릴알코올Stearyl alcohol -- -- -- -- -- -- 55 -- -- 증류수Distilled water 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount

음이온계면활성제로서 활성분 28%인 라우릴황산암모늄, 비이온계면활성제로서 야자유지방산모노에탄올아미드, 펄화제로서 에틸렌글리콜모노스테아레이트 또는 에틸렌글리콜디스테아레이트, 고급알코올로서 미리스틸알코올, 세틸알코올, 베헤닐알코올 또는 스테아릴알코올 및 증류수를 상기 표 1에 기재된 각 성분비로 혼합한 후, 75℃ 온도까지 가온하여 5분동안 교반하여 균일하게 용해한 다음, 2.0℃/min의 속도로 45℃ 온도까지 급냉하여 실시예 1 내지 8 및 비교예 1 내지 2의 펄 조성물을 제조하였다.Ammonium lauryl sulfate as active ingredient 28% as anionic surfactant, palm oil fatty acid monoethanolamide as nonionic surfactant, ethylene glycol monostearate or ethylene glycol distearate as pearling agent, myristyl alcohol as higher alcohol, cetyl alcohol, Behenyl alcohol or stearyl alcohol and distilled water were mixed at the respective component ratios shown in Table 1 above, and then heated to 75 ° C., stirred for 5 minutes, and dissolved uniformly. The pearl compositions of Examples 1 to 8 and Comparative Examples 1 to 2 were prepared.

[시험예 1][Test Example 1]

상기 실시예 1 내지 실시예 7 및 비교예 1, 2의 펄 조성물 각각을 유브이셀(UV Cell)에 넣은 다음, 윤기측정기(Micro-gross meter, 85。)를 이용하여 윤기를 각 3회씩 반복하여 측정하여 이를 평균한 값을 하기 표 2에 나타내었다.Each of the pearl compositions of Examples 1 to 7 and Comparative Examples 1 and 2 were placed in a UV cell, and then repeated three times for each shine using a micro-gross meter (85 °). The measured and averaged values are shown in Table 2 below.

윤기측정기는 측정 대상체에 조사한 광원이 반사되어 나오는 광량을 측정하는 것으로, 윤기가 적은 대상일수록 반사각이 크다. 펄감이 약한 경우는 불투명한 백색을 띠고 펄감이 좋은 경우는 윤기있는 백색을 띠므로, 펄감이 좋은 경우 반사광량의 세기가 세어지게 된다. 하기의 윤기(%)는 이러한 방법에 의해 측정된 윤기정도를 입사광량 대비 반사광량의 비율을 백분율로 나타낸 것이다.The gloss meter measures the amount of light reflected by the light source irradiated to the measurement object. The smaller the gloss, the greater the reflection angle. When the pearl is weak, the color is opaque white, and when the pearl is good, the color is shiny. When the pearl is good, the intensity of the reflected light is increased. The following glossiness (%) represents the degree of shine measured by this method as a ratio of the amount of reflected light to the amount of incident light.

실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 실시예 5Example 5 실시예 6Example 6 실시예 7Example 7 비교예 1Comparative Example 1 비교예 2Comparative Example 2 윤기(%)burnish(%) 79.279.2 78.078.0 83.183.1 80.580.5 82.182.1 84.284.2 80.880.8 74.374.3 76.576.5

상기 표 2에서 알 수 있는 바와 같이, 실시예 1 내지 7은 고급알코올을 포함하지 않은 비교예 1 내지 2에 비하여 윤기(%)가 크므로 펄감이 우수하다. 또한, 펄화제만을 달리하여 제조된 실시예 1과 3, 실시예 2와 4를 비교하여 볼 때, 펄화제로서 에틸렌글리콜디스테아레이트를 사용한 조성물(실시예 3, 4)의 펄감이 에틸렌글리콜모노스테아레이트를 사용한 조성물(실시예 1, 2)의 펄감보다 우수한 것으로 나타났다.As can be seen in Table 2, Examples 1 to 7 are excellent in the sense of pearl because the gloss (%) is larger than Comparative Examples 1 to 2 containing no higher alcohol. In addition, when comparing the Examples 1 and 3, Examples 2 and 4 prepared by changing only the pulping agent, the pearl of the composition (Examples 3 and 4) using ethylene glycol distearate as the pulping agent is ethylene glycol mono It was shown to be superior to the pearly feeling of the compositions using stearates (Examples 1 and 2).

[시험예 2][Test Example 2]

두께 0.5㎝, 가로 30㎝, 세로 30㎝의 흑색 무광으로서 아노다이징 처리한 알루미늄판에 상기 실시예 1 내지 실시예 7 및 비교예 1, 2의 각 펄 조성물을 3g씩 따른 다음, 일반인 남녀 각 25명에게 이들 각각에 대한 펄감을 평가하게 하고, 그 결과를 평균하여 하기 표 3에 나타내었다.Each pearl composition of Examples 1 to 7 and Comparative Examples 1 and 2 was followed by 3 g of anodized aluminum plate having a thickness of 0.5 cm, 30 cm and 30 cm in length, and then 25 men and women of the general public. Was given to evaluate the pearl for each of them, and the results are averaged in Table 3 below.

실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 실시예 4Example 4 실시예 5Example 5 실시예 6Example 6 실시예 7Example 7 비교예 1Comparative Example 1 비교예 2Comparative Example 2 펄감선호도Pearl Preference 4.04.0 3.93.9 4.44.4 4.24.2 4.04.0 4.24.2 4.04.0 3.83.8 3.93.9

*펄감평가기준** Pearl Evaluation Criteria *

5 : 펄감이 우수하고 금속성이 있음5: excellent pearly and metallic

4 : 펄감은 우수하나 금속성은 떨어짐4: excellent pearly but poor metallicity

3 : 보통3: normal

2 : 펄감이 있으나 부족함2: pearly but not enough

1 : 펄감이 전혀 없음1: no pearl

상기 표 3에서 알 수 있는 바와 같이, 실시예 1 내지 7은 고급알코올을 포함하지 않은 비교예 1 내지 2에 비하여 펄감 선호도가 우수한 것으로 나타났다. 또한, 상기 시험예 1에서와 같이 펄화제로서 에틸렌글리콜디스테아레이트를 사용한 조성물(실시예 3, 4)의 펄감이 에틸렌글리콜모노스테아레이트를 사용한 조성물(실시예 1, 2)의 펄감보다 우수한 것으로 나타났다.As can be seen in Table 3, Examples 1 to 7 was found to be excellent in pearly preference compared to Comparative Examples 1 to 2 that do not contain higher alcohol. In addition, the pearly feeling of the composition (Examples 3 and 4) using ethylene glycol distearate as the pulverizing agent as in Example 1 was superior to that of the composition (Examples 1 and 2) using ethylene glycol monostearate. appear.

이하 제조예 및 비교제조예를 들어 본 발명을 보다 구체적으로 설명하지만본 발명이 이들예로만 한정되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Preparation Examples and Comparative Preparation Examples, but the present invention is not limited only to these Examples.

[제조예 1,2 및 비교제조예 1,2][Production Examples 1,2 and Comparative Production Examples 1,2]

제조예 1Preparation Example 1 제조예 2Preparation Example 2 비교제조예 1Comparative Production Example 1 비교제조예 2Comparative Production Example 2 28% 라우릴황산나트륨28% Sodium Lauryl Sulfate 10.010.0 10.010.0 10.010.0 20.020.0 28% 폴리옥시에틸렌라우릴황산나트륨28% Sodium Polyoxyethylene Lauryl Sulfate 30.030.0 30.030.0 30.030.0 30.030.0 야자유지방산디에탄올아미드Palm oil fatty acid diethanolamide 1.01.0 1.01.0 1.01.0 1.01.0 폴리쿼터늄-10Polyquaternium-10 1.01.0 1.01.0 1.01.0 1.01.0 디메치콘Dimethicone 2.02.0 2.02.0 2.02.0 2.02.0 실시예 6Example 6 2020 -- -- -- 실시예 8Example 8 -- 2020 -- -- 비교예 2Comparative Example 2 -- -- 2020 -- 청색 1호Blue 1 적량Quantity 적량Quantity 적량Quantity 적량Quantity 파라옥시안식향산에스테르Paraoxybenzoic Acid Ester 0.20.2 0.20.2 0.20.2 0.20.2 SEL-14178SEL-14178 0.40.4 0.40.4 0.40.4 0.40.4 염화나트륨Sodium chloride 적량Quantity 적량Quantity 적량Quantity 적량Quantity 구연산Citric acid 적량Quantity 적량Quantity 적량Quantity 적량Quantity 증류수Distilled water 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount 잔량Remaining amount

물에 대하여 상기 표 4의 조성을 갖도록 활성분 28%인 라우릴황산나트륨, 활성분 28%인 폴리옥시에틸렌라우릴황산나트륨, 야자유지방산디에탄올아미드, 폴리쿼터늄-10(Union Carbide; Polymer JR 400)을 분산용해시킨 후 45℃ 온도까지 가온한 다음, 디메치콘(Dow Corning; DC-200F)을 가하여 이 온도를 유지하며 30분간 교반시킨 다음 40℃ 온도까지 교반 냉각시켰다. 이어, 미리 만들어진 실시예 6, 실시예 8, 비교예 2의 펄 조성물 각각에 대하여 색소로서 청색 1호(보락향료(주) 제품), 파라옥시안식향산에스테르, 향료로서 SEL-14178(일본국 하세가와(Hasegawa)사 제품), 염화나트륨, 구연산 및 증류수를 가한 뒤 30분간 교반시켜 샴푸를 제조하였다.Sodium lauryl sulfate having an active ingredient of 28%, sodium polyoxyethylene lauryl sulfate having an active ingredient of 28%, palm oil fatty acid diethanolamide and polyquaternium-10 (Union Carbide; Polymer JR 400) After dissolution and warming, the mixture was warmed to a temperature of 45 ° C., and then dimethicone (Dow Corning; DC-200F) was added thereto. Subsequently, about the pearl composition of Example 6, Example 8, and Comparative Example 2 which were prepared previously, it is SEL-14178 (Hasegawa, Japan) as blue No. 1 (product of Boraku fragrance Co., Ltd.), paraoxybenzoic acid ester, a fragrance as a pigment | dye. Hasegawa)), sodium chloride, citric acid and distilled water were added and stirred for 30 minutes to prepare a shampoo.

[시험예 3][Test Example 3]

상기 제조예 1, 2 및 비교제조예 1, 2의 각 샴푸를 50℃ 항온기에 넣어서 안정성을 관찰하고, 그 결과를 하기 표 5에 나타내었다.The shampoos of Preparation Examples 1 and 2 and Comparative Preparation Examples 1 and 2 were placed in a 50 ° C. thermostat and observed for stability, and the results are shown in Table 5 below.

안정성 평가기준은 하단부에 분리된 투명층이 육안으로 보이기 시작하는 시점을 안정성 일수로 하여 평가하였다.Stability evaluation criteria were evaluated as the number of stability days when the transparent layer separated on the lower end starts to be visible to the naked eye.

제조예 1Preparation Example 1 제조예 2Preparation Example 2 비교제조예 1Comparative Production Example 1 비교제조예 2Comparative Production Example 2 안정성 일수Stability days 65일65 days 59일59 days 22일22 days 2일2 days

상기 표 5에서 알 수 있는 바와 같이, 고급알코올을 함유하는 실시예 6, 8의 펄 조성물을 함유시킨 제조예 1, 2의 안정성이 고급알코올을 함유하지 않은 비교예 2의 펄 조성물을 함유시킨 비교제조예 1과 펄 조성물을 전혀 함유하지 않은 비교제조예 2보다 크게 우수한 것으로 나타났다.As can be seen in Table 5, the comparison of the pearl compositions of Comparative Examples 2 and 2 containing the high-alcohol-containing pearl compositions of Examples 6 and 8 contained the high-alcohol comparative example 2 It was found to be significantly superior to Preparation Example 1 and Comparative Preparation Example 2 containing no pearl composition.

이상에서 알 수 있는 바와 같이, 본 발명의 펄 조성물은 향상된 펄감과 뛰어난 안정성 개선효과를 가짐으로 인하여 종래의 펄 조성물에 비하여 동량 사용시 우수한 펄감과 안정성 개선 효과를 부여할 수 있어 제품의 안정성 증대 및 펄감량을 통한 경제적인 효과를 제공할 수 있다.As can be seen from the above, the pearl composition of the present invention can provide excellent pearl feeling and stability improvement effect when used in the same amount compared to the conventional pearl composition due to the improved pearl permeability and excellent stability improving effect, thereby increasing the stability of the product and pearl Reduction can provide an economic effect.

Claims (2)

활성분 28%인 음이온계면활성제 30 내지 70중량%, 비이온계면활성제 2 내지 8중량%, 펄화제 5 내지 15중량%, C14내지 C22의 직쇄 알킬기를 갖는 고급알코올 1 내지 14중량% 및 잔량으로서 물을 포함하여 이루어짐을 특징으로 하는 펄 조성물.30% to 70% by weight of anionic surfactant having 28% of active ingredient, 2 to 8% by weight of nonionic surfactant, 5 to 15% by weight of pulping agent, 1 to 14% by weight of higher alcohol having C 14 to C 22 linear alkyl group, and Pearl composition comprising water as a residual amount. 공지의 두발 또는 피부 세정용 화장료 조성물에 제 1항의 펄 조성물을 5 내지 40중량%의 양으로 포함시켜 두발 또는 피부 세정용 화장료 조성물로 제형화함을 특징으로 하는 펄감을 갖는 화장료 조성물.A cosmetic composition having a pearly feeling, characterized in that the pearl composition of claim 1 is contained in a known hair or skin cleansing cosmetic composition in an amount of 5 to 40% by weight.
KR10-2001-0080562A 2001-12-18 2001-12-18 Pearl composition and cosmetic composition having pearl-like feeling comprising them thereof KR100448241B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101091513B1 (en) 2009-07-30 2011-12-08 서훈원 Solid detergent using the microorganism

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EP0407042A2 (en) * 1989-06-21 1991-01-09 Colgate-Palmolive Company Hair conditioning shampoo containing long chain alcohol component
JPH0633099A (en) * 1992-07-17 1994-02-08 Kao Corp Liquid cleaning agent composition
JPH07258699A (en) * 1994-03-22 1995-10-09 Sunstar Inc Pearl-like fluid detergent composition
JPH08217632A (en) * 1995-02-15 1996-08-27 Mikimoto Pharmaceut Co Ltd Beauty lotion having pearl-like luster
KR20000069738A (en) * 1997-10-27 2000-11-25 카렌 에이. 로우니 Method for Manufacture of Pigment-Containing Cosmetic Compositions
JP2001131014A (en) * 1999-11-02 2001-05-15 Kao Corp Rearlescent composition

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0407042A2 (en) * 1989-06-21 1991-01-09 Colgate-Palmolive Company Hair conditioning shampoo containing long chain alcohol component
JPH0633099A (en) * 1992-07-17 1994-02-08 Kao Corp Liquid cleaning agent composition
JPH07258699A (en) * 1994-03-22 1995-10-09 Sunstar Inc Pearl-like fluid detergent composition
JPH08217632A (en) * 1995-02-15 1996-08-27 Mikimoto Pharmaceut Co Ltd Beauty lotion having pearl-like luster
KR20000069738A (en) * 1997-10-27 2000-11-25 카렌 에이. 로우니 Method for Manufacture of Pigment-Containing Cosmetic Compositions
JP2001131014A (en) * 1999-11-02 2001-05-15 Kao Corp Rearlescent composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101091513B1 (en) 2009-07-30 2011-12-08 서훈원 Solid detergent using the microorganism

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