JPS54107994A - Preparation of styrene resin - Google Patents
Preparation of styrene resinInfo
- Publication number
- JPS54107994A JPS54107994A JP1562378A JP1562378A JPS54107994A JP S54107994 A JPS54107994 A JP S54107994A JP 1562378 A JP1562378 A JP 1562378A JP 1562378 A JP1562378 A JP 1562378A JP S54107994 A JPS54107994 A JP S54107994A
- Authority
- JP
- Japan
- Prior art keywords
- styrene
- butylperoxy
- styrene resin
- bis
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
Abstract
PURPOSE: To prepare a styrene resin having a high molecular weight and excellent mechanical strength, by carrying out the suspension polymerization of styrene, etc. in the presence of a specific organic perioxide catalyst.
CONSTITUTION: 80W100wt.% of styrene or its mixture with copolymerizable monomers, e.g. acrylonitrile, etc., is mixed with 0W20wt.% of a rubbery polymer, e.g. polybutadiene, etc., and polymerized at 80W140°C in the presence of 1,1-bis(t- butylperoxy)cyclohexane I or 1,1-bis(t-butylperoxy)-3,3,5-trimethylcyclohexane II (0.01W0.5wt.% on the basis of the styrene monomer) to give the desired resin.
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1562378A JPS54107994A (en) | 1978-02-14 | 1978-02-14 | Preparation of styrene resin |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1562378A JPS54107994A (en) | 1978-02-14 | 1978-02-14 | Preparation of styrene resin |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS54107994A true JPS54107994A (en) | 1979-08-24 |
Family
ID=11893828
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1562378A Pending JPS54107994A (en) | 1978-02-14 | 1978-02-14 | Preparation of styrene resin |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS54107994A (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5631600A (en) * | 1979-08-22 | 1981-03-30 | Osaka Gas Co Ltd | Method of sealing pipe joint |
JPS5631599A (en) * | 1979-08-22 | 1981-03-30 | Osaka Gas Co Ltd | Method of sealing pipe joint |
JPS6047037A (en) * | 1983-08-24 | 1985-03-14 | Hitachi Chem Co Ltd | Production of expandable styrene resin particle |
EP0307238A2 (en) * | 1987-09-11 | 1989-03-15 | Dainippon Ink And Chemicals, Inc. | Production of styrene resins by continuous bulk polymerization |
JPH01188505A (en) * | 1988-01-22 | 1989-07-27 | Toshiba Chem Corp | Heat-resistant resin composition |
JPH01229020A (en) * | 1988-03-10 | 1989-09-12 | Nippon Oil & Fats Co Ltd | Radical reaction initiator composed of cyclic monoperoxy ketal |
US5185405A (en) * | 1989-05-24 | 1993-02-09 | Sanyo Chemical Industries, Ltd. | Resin compostions for electrophotographic toner |
US5292914A (en) * | 1992-07-28 | 1994-03-08 | Nof Corporation | Organic peroxide and use thereof |
US5665833A (en) * | 1995-07-18 | 1997-09-09 | Sumitomo Chemical Company, Limited | Method for controlling a polymerization rate of styrene resins |
WO2002053608A1 (en) * | 2001-01-08 | 2002-07-11 | Lg Chem, Ltd. | Method for preparing thermoplastic resin |
WO2012177225A1 (en) * | 2011-06-20 | 2012-12-27 | Thai Abs Company Limited | Styrene - acrylonitrile resin with enhanced transparency properties and manufacturing method therefor |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50161587A (en) * | 1974-06-21 | 1975-12-27 | ||
JPS5153592A (en) * | 1974-11-06 | 1976-05-12 | Nippon Steel Chemical Co | SUCHIRENKEITAISHOGEKISEIJUSHINO SEIZOHOHO |
-
1978
- 1978-02-14 JP JP1562378A patent/JPS54107994A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50161587A (en) * | 1974-06-21 | 1975-12-27 | ||
JPS5153592A (en) * | 1974-11-06 | 1976-05-12 | Nippon Steel Chemical Co | SUCHIRENKEITAISHOGEKISEIJUSHINO SEIZOHOHO |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5631600A (en) * | 1979-08-22 | 1981-03-30 | Osaka Gas Co Ltd | Method of sealing pipe joint |
JPS5631599A (en) * | 1979-08-22 | 1981-03-30 | Osaka Gas Co Ltd | Method of sealing pipe joint |
JPS6047037A (en) * | 1983-08-24 | 1985-03-14 | Hitachi Chem Co Ltd | Production of expandable styrene resin particle |
JPS6338063B2 (en) * | 1983-08-24 | 1988-07-28 | Hitachi Chemical Co Ltd | |
EP0307238A2 (en) * | 1987-09-11 | 1989-03-15 | Dainippon Ink And Chemicals, Inc. | Production of styrene resins by continuous bulk polymerization |
JPH01188505A (en) * | 1988-01-22 | 1989-07-27 | Toshiba Chem Corp | Heat-resistant resin composition |
JPH01229020A (en) * | 1988-03-10 | 1989-09-12 | Nippon Oil & Fats Co Ltd | Radical reaction initiator composed of cyclic monoperoxy ketal |
US5185405A (en) * | 1989-05-24 | 1993-02-09 | Sanyo Chemical Industries, Ltd. | Resin compostions for electrophotographic toner |
US5292914A (en) * | 1992-07-28 | 1994-03-08 | Nof Corporation | Organic peroxide and use thereof |
US5665833A (en) * | 1995-07-18 | 1997-09-09 | Sumitomo Chemical Company, Limited | Method for controlling a polymerization rate of styrene resins |
WO2002053608A1 (en) * | 2001-01-08 | 2002-07-11 | Lg Chem, Ltd. | Method for preparing thermoplastic resin |
US6593424B2 (en) | 2001-01-08 | 2003-07-15 | Lg Chem, Ltd. | Method for preparing thermoplastic resin |
WO2012177225A1 (en) * | 2011-06-20 | 2012-12-27 | Thai Abs Company Limited | Styrene - acrylonitrile resin with enhanced transparency properties and manufacturing method therefor |
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