JPH08135962A - Combustion device equipped with co detecting sensor and treatment method for heat up of the co detecting sensor - Google Patents

Abstract

PURPOSE: To conduct proper burning operation and safety operation of CO of a combustion device for a long period of time by effecting the heat cleaning of a CO detecting sensor surely. CONSTITUTION: In a combustion device equipped with a CO sensor 20 detecting the concentration of CO in exhaust gas by the reaction of contact of a CO detecting sensor with CO gas, a combustion stopping detecting means 24, detecting the stopping signal of burning operation, is provided to detect the stopping signal. When the stopping signal is detected, the amount of current, carried by the CO detecting element of the CO sensor 20 and the like, is increased by a sensor current-carrying amount limiting means 25 to increase the temperature of the CO detecting element or the like to the temperature of heat cleaning and the heat cleaning of the CO detecting element and the like is effected immediately after the finishing of the burning operation of the combustion device.

Description

Detailed Description of the Invention

[0001]

The present invention relates to carbon monoxide gas (CO
The present invention relates to a combustion device with a CO detection sensor in which a CO detection sensor for detecting the concentration of (gas) is installed, and a heat-up processing method for the CO detection sensor.

[0002]

2. Description of the Related Art FIG. 3 shows a system configuration of a general water heater as a combustion device. In the figure, a water supply pipe 3 is connected to the inlet side of the heat exchanger 2, and the water supply pipe 3 has a water inflow thermistor 10 for detecting the water inflow temperature and a flow rate sensor 9 for detecting a water inflow rate. And are provided. The hot water supply pipe 4 is connected to the outlet side of the heat exchanger 2,
A hot water supply tap 1 is provided on the outlet side of the hot water supply pipe 4.
Further, the hot water supply pipe 4 is provided with a water amount control valve 16 as a flow rate control means whose valve opening amount is controlled by a gear motor, and a hot water thermistor 11 for detecting the hot water temperature.

Below the heat exchanger 2, a burner 7 as a combustion heating means, an igniter electrode 18 for igniting the burner 7,
A flame rod electrode 19 for detecting ignition and a combustion fan 5 for supplying / exhausting air are arranged, a gas nozzle 6 is arranged opposite to a gas inlet of the burner 7, and a gas pipe 8 leading to the gas nozzle 6 is provided with a gas. Gas proportional valve 13 that controls the supply amount by the valve opening amount, and gas solenoid valve 12 that opens and closes the pipeline.
And are installed.

This type of water heater is provided with a control device 14, and a remote controller 15 is connected to the control device 14. The remote controller 15 has buttons for instructing hot water supply operation and buttons for setting hot water temperature. A display unit or the like for the hot water supply set temperature is provided. Also, on the wall surface on the exhaust top side, C in the exhaust gas
A CO sensor (carbon monoxide gas sensor) 20 as a CO detection sensor for detecting the O concentration (carbon monoxide gas concentration) is provided, and the CO detection signal of this CO sensor 20 is applied to the control device 14.

The control device 14 is provided with a circuit for controlling the hot water supply combustion operation and a circuit for performing a CO safety operation. The control circuit for the hot water supply combustion operation controls the hot water supply operation of the water heater as follows. When the hot water tap 1 is opened, the flow rate sensor 9 detects the amount of water entering, and when the amount of water entering exceeds a certain level (more than the minimum operating flow rate), a signal from the flow rate sensor 9 is received,
The control device 14 rotates the combustion fan 5. Then, when the rotation of the combustion fan 5 enters a predetermined rotation region, the gas solenoid valve 12 and the gas proportional valve 13 are opened to supply the gas to the burner 7, and the ignition operation by the igniter electrode 18 is performed. When the flame rod electrode 19 detects the ignition of the gas, the control device 14 performs the feedforward control so that the hot water outlet temperature becomes the set temperature, the opening amount of the gas proportional valve 13 is changed, and the hot water temperature coming out of the heat exchanger 2 is changed. The combustion control is performed so that the temperature becomes a set temperature, and after the hot water temperature is stabilized, the combustion control is performed by the combined control of the feedforward control and the feedback control.

In this combustion control, the control device 14 controls the CO
Control is performed based on the detection signal of the sensor 20, and when the CO detection value (CO detection concentration) obtained from the CO sensor 20 falls below a predetermined reference value, in order to raise the incoming water temperature to the set temperature The gas supply amount is controlled by the valve opening control of the gas proportional valve 13 according to the required heat amount required, and in accordance with this, the rotation control of the combustion fan 5 is performed so that the air amount corresponding to the gas amount is obtained. On the other hand, CO sensor
When the CO detection value detected at 20 exceeds the reference value, in order to improve the combustion in the incomplete combustion state in the complete combustion direction, the rotation speed of the combustion fan 5 is increased by a predetermined amount to increase the combustion air amount. Combustion control is performed so as to reduce the CO gas concentration in the exhaust gas. Instead of increasing the rotation speed of the combustion fan 5, the opening amount of the gas proportional valve 13 may be reduced to reduce the gas supply amount to the burner 7 to reduce the CO generation concentration.

The circuit for CO safe operation of the control unit 14 is
When the detected CO concentration detected by the CO sensor 20 reaches a predetermined dangerous concentration, combustion is stopped, or the CO sensor 20 detects the CO at a predetermined sampling time.
The detection signal is sampled, and C is sampled at each sampling time.
The CO safety operation is performed in various signal processing modes such that combustion is stopped when the O detection value is accumulated and the accumulated value reaches a preset danger judgment set value.

By the way, as an example of the CO sensor 20 provided in the above combustion apparatus, there is a contact reaction type sensor, and FIGS. 4 and 5 show examples of the contact reaction type CO sensor. ing. In these figures, three pairs of terminal pins 32 are projected on the upper surface of the base 31, and a CO wire is provided between each pair of terminal pins through a thin platinum wire having a diameter of, for example, 10 μm.
Comparison element 34 that is insensitive to gas and C that is sensitive to CO gas
An O detection element 35 and a temperature detection element 42 are provided, and a comparison element
34 and the CO detection element 35 are separated by a partition plate 36.

The circumference of the comparison element 34 and the CO detection element 35 is covered with a cylindrical glass wool 37 whose upper and lower ends are open, and the outer side thereof is covered with a metal cover 29. A blade-shaped plate 30 is formed on the inner surface of the peripheral wall of the metal cover 29.
Is formed by cutting and raising, and the raising and lowering opening 41
The exhaust gas is formed so as to enter the inside.

In this type of CO sensor 20, the comparison element 34 and the CO detection element 35 are heated to about 200 ° C. by energization, and when CO gas comes into contact with the CO detection element 35 in this state, the CO detection element 35 A contact reaction (contact combustion reaction) between CO and CO gas occurs, the temperature of the CO detection element 35 rises due to this reaction, and the electric resistance increases. Due to this resistance change, a change in the current drawn from the CO sensor 20 occurs,
The CO gas concentration is detected based on the change. In addition,
At this time, temperature compensation of the CO sensor output is performed based on the temperature information detected by the temperature detection element 42.

By the way, the CO sensor 20 of this type is designed to detect the CO gas concentration based on the catalytic combustion reaction by the CO gas contacting the CO detection element 35 as described above.
The surfaces of the O detection element 35 and the comparison element 34 need to be kept clean at all times. However, since the exhaust gas exhausted during the combustion operation of the combustion apparatus contains substances such as carbon dioxide, hydrocarbon, and carboxylic acid in addition to CO gas, these substances are used as the CO detection element.
35 and the surface of the comparison element 34, and then,
The element surface cannot be kept clean and CO
The detection operation will not be performed accurately.

Therefore, conventionally, as shown in FIG. 6 (b), at the start of the combustion operation, the energization amount to the CO detection element 35 and the comparison element 34 is made larger than the energization quantity V _S during the combustion operation. , The heat-up energization amount V _UP, and as shown in (c) of the figure, the element is heated to a high temperature such as 500 ° C. to heat-clean the element, and the hydrocarbon adhered to the element surface. The adhered substances such as are thermally decomposed and peeled off to remove hydrocarbons and the like.

During the heat cleaning, C
Since the CO gas concentration is not detected by the O sensor 20, the heat-up processing time T for heat cleaning is preset to a short time such as 20 seconds. The heat-up process is quickly performed in the interior, and the CO gas concentration is immediately detected by the CO sensor 20 after the heat-up process is completed.
It is designed so that safe operation can be performed without any problems.

[0014]

However, at the start of the combustion operation, the elements such as the CO detection element 35 of the CO sensor 20 are cooled to about room temperature, and the glass wool 37 and the like around them are also cooled. Even if the CO detection element 35 and the comparison element 34 are energized, it is difficult to make the temperature of the CO detection element 35 and the like rapidly reach a high temperature of 500 ° C. Therefore, it takes a short time such as 20 seconds at the start of combustion. a heat-up processing time, as indicated, the time element temperature is kept from reaching 500 ° C. to a temperature of 500 ℃ (T _R) was very short (c) in FIG. 6.

Moreover, since a certain amount of time has passed from the stop of the combustion operation of the combustion apparatus to the start of the combustion operation again, the adhered substances such as the hydrocarbons may be accumulated in the CO detection element 35 or the like. Some of them adhere strongly to the surface of the device and some of them react with each other, and it was difficult to thermally decompose and remove the adhered substances that adhered in such a manner.

Further, since the conventional heat cleaning is performed at the start of combustion operation and is performed while the equipment is burning, the exhaust gas discharged from the equipment is CO sensor 20.
However, the heat cleaning efficiency was poor and the adhering substances were not sufficiently removed because there was a large amount of substances such as hydrocarbons in the atmosphere around the CO sensor 20.

As described above, in the conventional combustion apparatus, since the CO detection element 35 of the CO sensor 20 could not be properly heat-cleaned in practice,
While using the combustion device, the CO gas detection sensitivity of the CO sensor 20 is lowered, which causes a problem that the combustion operation operation and the CO safety operation performed based on the detection signal of the CO sensor 20 are disturbed. It was

The present invention has been made in order to solve the above-mentioned conventional problems, and an object thereof is to enable efficient and reliable heat cleaning of a CO detection sensor, thereby enabling combustion operation. An object of the present invention is to provide a combustion device with a CO detection sensor and a heat-up processing method for the CO detection sensor, which can perform an operation and a CO safety operation accurately over a long period of time.

[0019]

In order to achieve the above object, the present invention is constructed as follows. That is, the combustion apparatus with a CO detection sensor of the present invention has a CO detection element, and during combustion operation, the CO detection element is energized to cause a contact reaction between the CO detection element and the CO gas to determine the CO concentration in the exhaust gas. In a combustion apparatus with a CO detection sensor equipped with a contact reaction type CO detection sensor for detecting, a combustion stop detection means for detecting a stop signal of the combustion operation operation, and a stop signal for the combustion operation operation are detected by the combustion stop detection means. Sometimes C
A sensor energization amount control means for increasing the amount of electricity supplied to the O detection element to raise the temperature of the CO detection element to the temperature of heat cleaning to perform heat cleaning is provided.

Further, the heat-up treatment method for the CO detection sensor of the combustion apparatus with a CO detection sensor of the present invention has a CO detection element, and the CO detection element is energized during combustion operation to generate C
In a combustion apparatus with a CO detection sensor, which comprises a contact reaction type CO detection sensor for contacting an O detection element and CO gas to detect a CO concentration in exhaust gas, a combustion operation stop signal is detected, When a stop signal is detected,
The CO detection element is heat-cleaned immediately after the end of the combustion operation by increasing the amount of electricity supplied to the CO detection element to raise the temperature of the CO detection element to the temperature of heat cleaning.

[0021]

In the present invention having the above-mentioned structure, the combustion stop detecting means detects the stop signal of the combustion operation of the combustion apparatus, and when this stop signal is detected, the sensor energization amount control means sends the signal to the CO detecting element. The temperature of the CO detection element is raised to the temperature of heat cleaning by increasing the energization amount, so that the CO
Heat cleaning of the detection element is performed.

[0022]

Embodiments of the present invention will be described below with reference to the drawings. In the description of the present embodiment, the same reference numerals will be given to the same names as those in the conventional example, and the duplicated description will be omitted.
The combustion apparatus with a CO detection sensor of the present embodiment is intended for the water heater shown in FIG. 3 as in the conventional example, and the CO sensor for detecting the CO concentration in the exhaust gas is provided on the exhaust top side of the water heater.
20 is provided, and the control device 14 is provided with a circuit for performing a CO safe operation and, as shown in FIG. 1, a combustion operation control unit 21 as a circuit for controlling combustion operation. . A feature of this embodiment is that a combustion stop detection means 24 and a sensor energization amount control means 25 are provided as means for efficiently performing heat cleaning of the CO sensor 20, as shown in FIG. .

The combustion stop detection means 24 includes a combustion operation control unit.
The signal from 21 is added, and the combustion stop detecting means 24 detects the stop signal of the combustion operation when the combustion operation of the water heater ends (stops). When the operation stop signal is detected, the combustion stop detection signal is added to the sensor energization amount control means 25.

The sensor energization amount control means 25 controls the CO detection element 35 of the CO sensor 20 before the combustion operation of the water heater is started.
When the combustion operation is performed, the energization amount to the CO detection element 35 and the like is set to a predetermined energization quantity V _S when the combustion amount is being supplied to the CO detection element 35 and the comparison element 34. Keep the temperature at 200 ° C.

Further, the sensor energization amount control means 25 increases the energization amount to the CO detection element 35 and the comparison element 34 when the combustion stop detection signal is added from the combustion stop detection means 24 to increase the CO detection element. The temperature of 35 etc. is raised to the temperature of heat cleaning to perform heat cleaning.
When the combustion stop detection signal is applied from the combustion stop detecting means 24 is the amount of current supplied to the comparison device 34 with CO detection element 35 and more than a normal energization amount V _S during combustion operation, heat-up power supply amount V and _uP, the temperature of the comparison element 34 with the CO sensing element 35, for example, increased to a temperature of heat cleaning, such 500 ° C.. Then, the amount of electricity supplied to the CO detection element 35 is
The heat-up energization amount V _UP is set only during the heat-up treatment time T given in advance, and C is set immediately after the end of the combustion operation of the water heater.
The O detection element 35 and the comparison element 34 are heat-cleaned.

The present embodiment is configured as described above,
Next, the operation will be described. Also in this embodiment, as in the case of the conventional water heater, the control device 14 is operated according to the instruction from the remote controller 15.
Thereby, the hot water supply combustion operation and the CO safety operation are performed, but in the present embodiment, the combustion operation is started and the combustion start signal is sent from the combustion operation control unit 21 to the sensor energization amount control as shown in (a) of FIG. When added to the means 25, the sensor energization amount control means
25 is the CO of the CO sensor 20, as shown in FIG.
The amount of electricity supplied to the detection element 35 and the comparison element 34 is increased to V _S.
Then, the temperatures of the CO detection element 35 and the comparison element 34 are raised to 200 ° C. as shown in FIG. Further, during the combustion operation, the amount of electricity supplied to the CO detection element 35 and the like is kept at V _S , and the element temperature of the CO detection element 35 and the like is also kept at 200 ° C.

When the hot water supply combustion operation is completed, the combustion stop detection means 24 detects the stop signal of the combustion operation operation of the water heater, and the combustion stop detection means 24 sends the combustion stop detection signal to the sensor energization amount control means 25. Added. Then, the sensor energization amount control means 25 receives the combustion stop detection signal and increases the energization amount to the CO detection element 35 and the comparison element 34 as shown in FIG. _UP
The temperature of the CO detection element 35 and the comparison element 34 is raised to the temperature of heat cleaning (500 ° C.) as shown in FIG. 2 (c). Then, the amount of electricity supplied to the CO detection element 35 and the like is maintained at the amount of heat-up electricity supply V _UP for the heat-up processing time T given in advance,
Thereby, as shown in (c) of FIG.
The temperatures of 35 and the comparison element 34 are kept for about 500 ° C. for a certain time, and the CO detection element 35 and the comparison element 34 are heat-cleaned.

According to this embodiment, when the combustion operation of the water heater is stopped by the above operation, the CO detection element 35 and the comparison element 34 are heated up, so that the CO detection element 35 is heated to 200 ° C. It is only necessary to heat up from the state of to 500 ℃, and the glass wool 37 etc. around the CO detection element 35 etc. is also warmed during the combustion operation of the water heater while it is warmed up during the combustion operation of the water heater. CO detection element
Since the temperature of 35 etc. is heated up, the temperature of the element is reduced to 20
Even if the heat-up processing time T is the same as the conventional heat-up processing time T, the element temperature of the CO detection element 35 and the like is 500 ℃ even if the heat-up processing time T is the same as the conventional heat-up processing time T. It becomes possible to maintain a long time (T _R ′ in the figure) as it is (heat cleaning temperature).

Further, according to this embodiment, as described above,
Since the heat cleaning of the CO detection element 35 is performed immediately when the combustion operation is stopped, the adhered substances such as the above-mentioned hydrocarbons are not firmly adhered to the element surface of the CO detection element 35, and the adhered substances are removed. It can be easily removed in a short time, and the heat cleaning is performed in a clean atmosphere after the combustion operation is completed.
Since it is carried out in the atmosphere of 20 where there is almost no substance such as hydrocarbon, heat cleaning can be carried out very efficiently.

Further, in this embodiment, since the CO detection sensor 35 and the like are heat cleaned after the combustion operation of the water heater, unlike the conventional case where the heat cleaning is performed at the start of the combustion operation, the heat cleaning is performed. Since it is not necessary to immediately detect the CO gas concentration by the CO sensor 20 after the end, it is possible to set the heat-up processing time T longer than before, so that the heat-up processing time is lengthened and the heat-up processing time is increased. It becomes possible to sufficiently thermally decompose the attached substance, and by doing so, the heat cleaning of the CO detection element 35 and the like can be performed more reliably.

As described above, the heat cleaning is efficiently and sufficiently performed, and the state of the element such as the CO detection element 35 is kept very clean until the next combustion operation is started. In order to maintain and start the next hot water supply combustion operation, hot water supply combustion operation and CO safety operation,
It becomes possible to carry out accurately based on the detection signal of the CO sensor 20.

Further, in the prior art, the CO gas concentration was not detected by the CO sensor 20 during the heat cleaning of the CO sensor 20 performed at the start of combustion operation, but in the present embodiment, immediately after the start of hot water supply combustion. Since the CO gas concentration detection operation is performed by the CO sensor 20, even if the CO gas concentration becomes abnormally high immediately after the start of hot water combustion, the CO gas concentration detection signal by the CO sensor 20 is used as the state. Based on the above, it is possible to immediately detect, and it is possible to promptly deal with such an abnormal state.

It should be noted that the present invention is not limited to the above-mentioned embodiments, and various embodiments can be adopted. For example, in the above embodiment, the combustion stop detection means 24 and the sensor energization amount control means 25 are provided in the control device 14, but the combustion stop detection means 24
The sensor energization amount control means 25 may be provided on the remote controller 15 side.

Further, in the above embodiment, when heat cleaning the CO detection element 35 and the like, the element temperature is set to 500 ° C.
However, the element temperature during heat cleaning is 500
The temperature is not necessarily set to 0 ° C., and is appropriately set, and the heat-up treatment time is also appropriately set.

Further, in the above embodiment, the amount of electricity supplied to the CO detection element 35 and the comparison element 34 of the CO sensor 20 is controlled every time the hot water heater is burned to complete the heat cleaning of the CO detection element 35 and the like. However, for example, the heat cleaning may be performed once every two combustion operations.

Further, in the above embodiment, the hot water supply device was described as an example of the combustion device, but the combustion device with a CO detection sensor of the present invention is a bath heater, an air conditioner, a heater, an air conditioner, an air conditioner, a fan heater. Etc. are applied to various other combustion devices that use gas or oil as fuel.

[0037]

According to the present invention, the combustion stop detecting means detects the stop signal of the combustion operation of the combustion apparatus, and when the stop signal is detected, the sensor energization amount control means sends the CO detecting element. In order to perform heat cleaning of the CO detection element immediately after the combustion operation ends by increasing the amount of electricity supplied to the CO detection element to the heat cleaning temperature, as in the conventional case, the CO detection element is started at the start of the combustion operation. The temperature of the CO detection element can be raised to the temperature of heat cleaning in a shorter time than the temperature of heat cleaning. Even if the heat-up treatment time for heat cleaning is the same as the conventional one, The temperature of the CO detection element can be maintained at the heat cleaning temperature for a long time.

Therefore, according to the present invention, it becomes possible to sufficiently perform the thermal decomposition of the adhered substance such as hydrocarbon which becomes a problem to adhere to the CO detecting element, and
Since the heat cleaning is performed immediately after the combustion operation is completed, the adherent such as hydrocarbon is not firmly adhered to the CO detection element, and the adherent can be easily removed by thermal decomposition. Becomes In addition, the heat cleaning is performed in a clean atmosphere after the combustion operation is completed and is performed in a state in which a substance such as hydrocarbon is scarcely present in the atmosphere around the CO detection element, so that the heat cleaning is very efficiently performed. It is possible to carry out, and it is possible to surely remove the attached substances.

Further, according to the present invention, since the substances adhering to the CO detection element are completely removed and kept until the next combustion operation is started, the next combustion operation is immediately started. , The CO gas concentration is accurately detected by the CO sensor, and there is no loss time such that the CO gas concentration detection operation is not performed due to heat cleaning at the start of the combustion operation as in the conventional case, and the CO detection sensor is accurate. Based on the CO gas concentration detection operation, the combustion operation operation and CO safety operation of the combustion device are accurately performed.

By using the combustion device while performing the heat-up process of the CO detection sensor as described above, the combustion device with the CO detection sensor of the present invention performs the combustion performed based on the detection signal of the CO detection sensor. Driving operation and C
O It is possible to provide a combustion device that can perform a safe operation accurately over a long period of time.

[Brief description of drawings]

FIG. 1 is a block diagram of a main part configuration showing an embodiment of a combustion device with a CO detection sensor according to the present invention.

FIG. 2 is an explanatory diagram of a heat-up processing operation of the CO detection sensor according to the above embodiment.

FIG. 3 is a system diagram of a general water heater as a combustion device.

FIG. 4 is an explanatory diagram showing an example of a CO sensor.

5 is an exploded view of the CO sensor shown in FIG.

FIG. 6 is an explanatory diagram of a heat-up processing operation of a conventional CO detection sensor.

[Explanation of symbols]

 14 Control device 20 CO sensor 24 Combustion stop detection means 25 Sensor energization amount control means 35 CO detection element

Claims (2)

[Claims] 1. A CO detection element is provided, and the C
In a combustion device with a CO detection sensor, which is equipped with a contact reaction type CO detection sensor that detects the CO concentration in the exhaust gas by energizing the O detection element to cause a CO reaction between the CO detection element and CO gas, Combustion stop detection means for detecting a stop signal, and when the combustion stop operation means detects a stop signal for combustion operation, the amount of electricity to the CO detection element is increased to bring the temperature of the CO detection element to the temperature for heat cleaning. A combustion device with a CO detection sensor, characterized in that it is provided with a sensor energization amount control means for enhancing heat cleaning. 2. A CO detection element is provided, and the C
In a combustion device with a CO detection sensor, which is equipped with a contact reaction type CO detection sensor that detects the CO concentration in the exhaust gas by energizing the O detection element to cause a CO reaction between the CO detection element and CO gas, When the stop signal is detected, and when the stop signal is detected, the amount of electricity supplied to the CO detection element is increased to raise the temperature of the CO detection element to the temperature of heat cleaning, so that the CO detection element of the CO detection element immediately after the end of the combustion operation. A heat-up treatment method for a CO detection sensor of a combustion device with a CO detection sensor, characterized by performing heat cleaning.