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JPH0561052A - Produciton of liquid crystal display element - Google Patents

Produciton of liquid crystal display element

Info

Publication number
JPH0561052A
JPH0561052A JP24403791A JP24403791A JPH0561052A JP H0561052 A JPH0561052 A JP H0561052A JP 24403791 A JP24403791 A JP 24403791A JP 24403791 A JP24403791 A JP 24403791A JP H0561052 A JPH0561052 A JP H0561052A
Authority
JP
Japan
Prior art keywords
spacers
electrode
liquid crystal
crystal display
transparent substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP24403791A
Other languages
Japanese (ja)
Inventor
Hiroyuki Sano
寛幸 佐野
Shinichi Imashiro
慎一 今城
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Stanley Electric Co Ltd
Original Assignee
Stanley Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stanley Electric Co Ltd filed Critical Stanley Electric Co Ltd
Priority to JP24403791A priority Critical patent/JPH0561052A/en
Publication of JPH0561052A publication Critical patent/JPH0561052A/en
Pending legal-status Critical Current

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  • Liquid Crystal (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)

Abstract

PURPOSE:To improve a display grade and the yield of production by dry spraying spacers to a transparent electrode substrate in a negatively electrified state and impressing a positive potential to the wiring electrodes of the transparent electrode substrate. CONSTITUTION:The spacers 4 are housed in a tank 10 and are injected toward the transparent electrode substrate 2 imposed on a base 11 from a nozzle 10b by applying the pressure of gaseous nitrogen, etc., thereto from a piping 10a. A discharge electrode 12 is provided in proximity to the nozzle 10b to negatively electrify the spacers 4 injected from the nozzle 10b. A control grid 13 is simultaneously provided between the nozzle 10b and the transparent electrode substrate 2 and the electrification quantity of the spacers 4 passing the control grid 13 is controlled. The positive potential is impressed to a wiring electrode 2a on the side of the transparent electrode substrate 2 when the spraying of the spacers 4 is executed. The spacers 4 are selectively stuck to the substrate by Coulomb force without being stuck to the picture element electrodes. Then, the degradation in the on-off ratio in the picture element electrode parts is prevented.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は液晶表示素子に関するも
のであり、詳細にはマトリックス表示方式と称され、一
面の表示面中に多数の画素が例えば縦横列に整列して配
置され、夫々の画素の点滅を制御することで任意の文
字、図形などを表示可能とした液晶表示素子に適する製
造方法の提供を目的とするものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a liquid crystal display device, more specifically referred to as a matrix display system, in which a large number of pixels are arranged in, for example, columns and rows on one display surface. An object of the present invention is to provide a manufacturing method suitable for a liquid crystal display device capable of displaying arbitrary characters, figures, etc. by controlling blinking of pixels.

【0002】[0002]

【従来の技術】従来のこの種マトリックス方式の液晶表
示素子90の例を示すものが図4であり、この種の液晶
表示素子90には直交する二方向に交差して格子状に配
設される配線電極91a(図4では一方のみが示してあ
る)と、この配線電極91aの格子間に配設される略矩
形状の画素電極91bとが敷設された電極透明基板91
と、略全面に渡り対向電極92aが敷設された対向透明
基板92とが、例えば樹脂で所定の径のビーズ状に形成
されたスペーサ93を挟持させることで、所定の間隔を
有するように対峙させられているものである。
2. Description of the Related Art FIG. 4 shows an example of a conventional liquid crystal display element 90 of this type of matrix system. The liquid crystal display element 90 of this type is arranged in a lattice form so as to intersect in two directions orthogonal to each other. An electrode transparent substrate 91 on which a wiring electrode 91a (only one of which is shown in FIG. 4) and a substantially rectangular pixel electrode 91b arranged between the grids of the wiring electrode 91a are laid.
And a counter transparent substrate 92 on which a counter electrode 92a is laid over substantially the entire surface, for example, by sandwiching a spacer 93 formed in a bead shape having a predetermined diameter with a resin so as to face each other with a predetermined interval. It is what has been.

【0003】このときに、前記スペーサ93は、電極透
明基板91または対向透明基板92の何れか一方に直接
噴射或いはフロン溶剤などに混和した状態で噴霧し、前
記透明基板91(或いは透明基板92)の表面にほぼ均
一に散布されるものとされている。
At this time, the spacer 93 is directly sprayed onto either the electrode transparent substrate 91 or the counter transparent substrate 92 or sprayed in a state of being mixed with a chlorofluorocarbon solvent or the like, and the transparent substrate 91 (or the transparent substrate 92) is sprayed. It is supposed to be distributed almost uniformly on the surface of.

【0004】尚、実際の液晶表示素子90においては、
前記した両透明基板91、92間に封入される液晶9
4、この液晶94に所定の配向方向を与える配向膜9
5、前記配線電極91aに印加される電位による液晶9
4の表示目的以外の応動を見えなくする目的で配線電極
91aを覆うように配設される遮光膜96、或いはカラ
ー表示とするためのカラーフィルタ97などが設けら
れ、更には図示は省略するが前記配線電極91aと画素
電極91bとを電気的に接続する薄膜トランジスタ或い
はダイオードなども設けられるものとされるが、本願発
明の要旨とは直接に関与しないので、これらに対するこ
こでの詳細な説明は省略する。
In the actual liquid crystal display element 90,
The liquid crystal 9 enclosed between the transparent substrates 91 and 92 described above.
4. Alignment film 9 that gives the liquid crystal 94 a predetermined alignment direction
5. Liquid crystal 9 according to the potential applied to the wiring electrode 91a
4 is provided with a light-shielding film 96 arranged to cover the wiring electrode 91a for the purpose of making the response other than the display purpose invisible, or a color filter 97 for color display, and the illustration thereof is omitted. A thin film transistor, a diode, or the like for electrically connecting the wiring electrode 91a and the pixel electrode 91b is also provided, but since they are not directly related to the gist of the present invention, detailed description thereof will be omitted here. To do.

【0005】[0005]

【発明が解決しようとする課題】しかしながら、前記し
た従来のスペーサ93の散布方法による液晶表示素子9
0の製造方法において、特に前記液晶表示素子90が前
述したようにマトリックス方式である場合には、図5に
示すように具体的には50〜100μm角である画素電
極91b中に5〜10μm径のスペーサ93の複数が散
布されるものとなり、このスペーサ93により光が散乱
するなどして表示品位を著しく損なったり、或いは特定
の画素電極91b中に多数のスペーサ93が集中して、
その画素電極91bを実質的に動作させないものとして
エレメント不良を生じ、液晶表示素子90全体を不良品
とするなどの問題点を生じ、この点の解決が課題とされ
るものと成っていた。
However, the liquid crystal display element 9 according to the above-mentioned conventional method of spraying the spacers 93 is used.
In the manufacturing method of No. 0, particularly when the liquid crystal display element 90 is of the matrix type as described above, as shown in FIG. 5, the pixel electrode 91b having a size of 50 to 100 μm square has a diameter of 5 to 10 μm. A plurality of spacers 93 are scattered, and light is scattered by the spacers 93, which significantly impairs display quality, or a large number of spacers 93 are concentrated in a specific pixel electrode 91b.
There has been a problem in that the pixel electrode 91b is not substantially operated to cause an element failure and the liquid crystal display element 90 as a whole is a defective product, and a solution to this point has been a problem.

【0006】[0006]

【課題を解決するための手段】本発明は前記した従来の
課題を解決するための具体的な手段として、画素電極と
配線電極とがマトリックス方式で敷設された電極透明基
板と対向電極が敷設された対向透明基板とにスペーサを
挟持させて適宜間隔で対峙させる液晶表示素子の製造方
法において、前記スペーサは前記電極透明基板に乾式で
且つ負に帯電させた状態で散布されるものとされ、この
スペーサの散布時には前記電極透明基板の前記配線電極
には正の電圧が印加されているものとされていることを
特徴とする液晶表示素子の製造方法を提供することで、
表示品位を向上させると共に生産歩留まりも向上させて
前記従来の課題を解決するものである。
According to the present invention, as a concrete means for solving the above-mentioned conventional problems, an electrode transparent substrate in which pixel electrodes and wiring electrodes are laid in a matrix system and a counter electrode are laid. In a method of manufacturing a liquid crystal display device in which spacers are sandwiched between opposed transparent substrates and face each other at appropriate intervals, the spacers are sprayed on the electrode transparent substrate in a dry and negatively charged state. By providing a method for manufacturing a liquid crystal display element, wherein a positive voltage is applied to the wiring electrode of the electrode transparent substrate at the time of spraying the spacers,
The conventional problems are solved by improving the display quality and the production yield.

【0007】[0007]

【実施例】つぎに、本発明を図に示す一実施例に基づい
て詳細に説明する。図1に符号1で示すものはマトリッ
クス方式の液晶表示素子であり、この液晶表示素子1は
例えば縦横方向に直交する配線電極2a(図では一方の
みが示してある)と、この配線電極2aの格子間に配設
される略矩形状の画素電極2bとが敷設された電極透明
基板2と、略全面に渡り対向電極3aが敷設された対向
透明基板3とが、スペーサ4を挟持させることで、所定
の間隔を有するように対峙させられているものである点
は従来例のものと同様である。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, the present invention will be described in detail based on an embodiment shown in the drawings. Reference numeral 1 in FIG. 1 denotes a matrix type liquid crystal display element. The liquid crystal display element 1 includes, for example, a wiring electrode 2a (only one of which is shown in the figure) orthogonal to the vertical and horizontal directions and a wiring electrode 2a. The spacer 4 is sandwiched between the electrode transparent substrate 2 on which the substantially rectangular pixel electrodes 2b arranged between the grids are laid, and the counter transparent substrate 3 on which the counter electrodes 3a are laid over substantially the entire surface. The point that they are opposed to each other with a predetermined interval is similar to that of the conventional example.

【0008】しかしながら、本発明により前記スペーサ
4を散布するときの方法は、前記電極透明基板2に対し
て溶剤などを用いることなく乾式の状態で且つ負電位に
帯電させて行われるものとされ、このとき同時に前記電
極透明基板2の配線電極2aには正の電圧が印加されて
いるものとされ、よって、得られる液晶表示素子1は前
記配線電極2aの部分のみにスペーサ4が散布され、画
素電極2bの部分には実質的に散布されないものとされ
ている。
However, according to the present invention, the method for spraying the spacers 4 is to be carried out in a dry state without using a solvent or the like on the transparent electrode substrate 2 and by charging it to a negative potential. At this time, at the same time, it is assumed that a positive voltage is applied to the wiring electrode 2a of the electrode transparent substrate 2, so that in the obtained liquid crystal display element 1, the spacers 4 are scattered only on the portion of the wiring electrode 2a, and the pixel It is assumed that the electrode 2b is not substantially dispersed.

【0009】上記を図2により更に具体的に説明を行え
ば、先ず前記スペーサ4はタンク10に納められ、この
タンク10に設けられたパイプ配管10aから窒素ガス
などにより圧力を加えることでノズル10bからベース
11上に載置された電極透明基板2に向けて噴射するも
のとされ、このときに、前記ノズル10bには近接して
放電電極12が設けられ、このノズル10bから噴射さ
れてくるスペーサ4を負に帯電させるものとされてい
る。
To explain the above in more detail with reference to FIG. 2, first, the spacer 4 is housed in a tank 10 and a nozzle 10b is provided by applying a pressure from a pipe pipe 10a provided in the tank 10 with nitrogen gas or the like. Is ejected toward the electrode transparent substrate 2 placed on the base 11. At this time, the discharge electrode 12 is provided in the vicinity of the nozzle 10b, and the spacer ejected from the nozzle 10b. 4 is charged negatively.

【0010】同時に前記ノズル10bの噴射方向の前
方、即ち、ノズル10bと電極透明基板2との中間には
金属線で金網状などに形成された制御格子13が設けら
れ、この制御格子13に印加される負電位を例えば0〜
300Vの範囲で調整することで、この制御格子13を
通過する前記スペーサ4の帯電量が制御される。
At the same time, a control grid 13 formed of metal wire in a wire mesh shape is provided in front of the jet direction of the nozzle 10b, that is, in the middle of the nozzle 10b and the electrode transparent substrate 2, and applied to the control grid 13. The negative potential to be
By adjusting in the range of 300V, the charge amount of the spacer 4 passing through the control grid 13 is controlled.

【0012】これに対して、前記したスペーサ4の散布
が行われる際に、前記電極透明基板2の側においては前
記配線電極2aに例えば30〜100Vの正電位が印加
されるものとされている.尚、前記電極透明基板2の構
成によっては、縦横方向とされた配線電極2aの双方に
正電位を印加するときには画素電極2bも同じ正電位と
なる構成、例えば配線電極2aと画素電極2bとがダイ
オードにより接続された単純マトリックスのものなども
存在するので、この場合には前記画素電極2bに影響を
及ぼさない側の配線電極2aのみに正電位を印加すれば
良い。
On the other hand, when the spacers 4 are sprayed, a positive potential of, for example, 30 to 100 V is applied to the wiring electrodes 2a on the electrode transparent substrate 2 side. . Depending on the configuration of the electrode transparent substrate 2, when a positive potential is applied to both the vertical and horizontal wiring electrodes 2a, the pixel electrode 2b also has the same positive potential, for example, the wiring electrode 2a and the pixel electrode 2b are There are some simple matrices connected by diodes, and in this case, a positive potential may be applied only to the wiring electrode 2a on the side that does not affect the pixel electrode 2b.

【0013】次いで、上記の方法としたことによる本発
明の作用、効果について説明を行えば、スペーサ4を負
に帯電させた状態で散布し、散布される側である電極透
明基板2の配線電極2aには正電位を印加しておくこと
で、図3に示すように前記スぺーサ4はクーロン力によ
り非常に高い確率で配線電極2aに吸着されるものと成
り、前記画素電極2bへの付着を実質的に生じないもの
とする。
Next, the operation and effect of the present invention by the above method will be described. The spacers 4 are sprayed in a state of being negatively charged, and the wiring electrodes of the electrode transparent substrate 2 on the side to be sprayed. By applying a positive potential to 2a, the spacer 4 is attracted to the wiring electrode 2a with a very high probability due to the Coulomb force, as shown in FIG. Adhesion shall not occur substantially.

【0014】このことは、本発明の方法により形成され
た電極透明基板2を採用した液晶表示素子1において
は、画素電極2bの部分にスペーサ4が実質的に存在し
ないものとなるので、前記画素電極2bに対応する部分
の表示は前記スペーサ4による屈折など生ずることがな
くオン―オフの動作を明快なものとし、また同時に、特
定の画素電極2bにスペーサ4が集中しエレメント不良
となる要因が排除されるものと成る。
This means that in the liquid crystal display element 1 employing the electrode transparent substrate 2 formed by the method of the present invention, the spacer 4 is substantially absent in the pixel electrode 2b portion, so that the pixel The display of the portion corresponding to the electrode 2b makes the on-off operation clear without causing the refraction by the spacer 4, and at the same time, there is a factor that the spacer 4 concentrates on a specific pixel electrode 2b and causes an element failure. Will be eliminated.

【0015】尚、この実施例の液晶表示素子1において
も、上記に説明した以外の構成部品として液晶5、配向
膜6、遮光膜7、カラーフィルタ8などが用いられるも
のとなっているが、従来例でも説明したように本発明の
要旨とは直接に関与しないので、ここでの詳細な説明は
省略し図示のみに止める、また、同様な理由で前記配線
電極2aと画素電極2b間に配置される薄膜トランジス
タ或いはダイオードに関しての説明と図示は省略する。
In the liquid crystal display element 1 of this embodiment, the liquid crystal 5, the alignment film 6, the light shielding film 7, the color filter 8 and the like are used as the components other than those described above. As described in the conventional example, since it does not directly relate to the gist of the present invention, detailed description thereof will be omitted and only illustrated, and for the same reason, it is arranged between the wiring electrode 2a and the pixel electrode 2b. The description and illustration of the thin film transistor or the diode to be performed are omitted.

【0016】[0016]

【発明の効果】以上に説明したように本発明により、画
素電極と配線電極とが敷設された電極透明基板におい
て、スペーサは前記電極透明基板に乾式で且つ負に帯電
させた状態で散布され、このスペーサの散布時には電極
透明基板の配線電極には正の電圧が印加されている液晶
表示素子の製造方法としたことで、クーロン力により配
線電極に選択的にスペーサを付着させ、表示が行われる
画素電極にはスペーサが付着しないものとして、前記画
素電極部分にスペーサが存在することで生ずるオン―オ
フ比の低下などを防止して表示品位の向上に極めて優れ
た効果を奏するものである。
As described above, according to the present invention, in the electrode transparent substrate on which the pixel electrode and the wiring electrode are laid, the spacer is sprayed on the electrode transparent substrate in a dry and negatively charged state, A positive voltage is applied to the wiring electrodes of the transparent electrode substrate when the spacers are scattered. The manufacturing method of the liquid crystal display element is that the spacers are selectively attached to the wiring electrodes by the Coulomb force and display is performed. Since the spacers are not attached to the pixel electrodes, it is possible to prevent the deterioration of the on-off ratio caused by the presence of the spacers in the pixel electrode portions and to achieve an extremely excellent effect of improving the display quality.

【0017】また同時に、前記画素電極部分にスペーサ
が散布されないものとしたことで、従来例のものの如く
に特定の画素電極に集中してスペーサが散布されエレメ
ント不良を生じて液晶表示素子全体が不良となることを
防止して、液晶表示素子の生産工程における歩留まり向
上にも併せて優れた効果を奏するものとなる。
At the same time, since the spacers are not scattered on the pixel electrode portion, the spacers are scattered on a specific pixel electrode as in the conventional example, and the element defects are generated, so that the entire liquid crystal display device is defective. It is possible to prevent the above-mentioned problems and improve the yield in the production process of the liquid crystal display element, and also to exert an excellent effect.

【図面の簡単な説明】[Brief description of drawings]

【図1】 本発明に係る液晶表示素子の製造方法で形成
された液晶表示素子を示す断面図である。
FIG. 1 is a cross-sectional view showing a liquid crystal display element formed by a method for manufacturing a liquid crystal display element according to the present invention.

【図2】 本発明に係る液晶表示素子の製造方法の一実
施例を製造工程で示す説明図である。
FIG. 2 is an explanatory view showing an example of a method of manufacturing a liquid crystal display element according to the present invention in a manufacturing process.

【図3】 本発明に係る製造方法の実施により得られる
スペーサの散布状態を示す説明図である。
FIG. 3 is an explanatory view showing a sprayed state of spacers obtained by carrying out the manufacturing method according to the present invention.

【図4】 従来の製造方法で形成された液晶表示素子を
示す断面図である。
FIG. 4 is a cross-sectional view showing a liquid crystal display element formed by a conventional manufacturing method.

【図5】 従来の製造方法により得られるスペーサの散
布状態を示す説明図である。
FIG. 5 is an explanatory view showing a sprayed state of spacers obtained by a conventional manufacturing method.

【符号の説明】[Explanation of symbols]

1……液晶表示素子 2……電極透明基板 2a……配線電極、2b……画素電極 3……対向透明基板 3a……対向電極 4……スペーサ 5……液晶 6……配向膜 7……遮光膜 8……カラーフィルタ 10……タンク 10a……パイプ配管、10b……ノズル 11……ベース 12……放電電極 13……制御格子 1 ... Liquid crystal display element 2 ... Electrode transparent substrate 2a ... Wiring electrode, 2b ... Pixel electrode 3 ... Counter transparent substrate 3a ... Counter electrode 4 ... Spacer 5 ... Liquid crystal 6 ... Alignment film 7 ... Light-shielding film 8 ... Color filter 10 ... Tank 10a ... Pipe piping, 10b ... Nozzle 11 ... Base 12 ... Discharge electrode 13 ... Control grid

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 画素電極と配線電極とがマトリックス方
式で敷設された電極透明基板と対向電極が敷設された対
向透明基板とにスペーサを挟持させて適宜間隔で対峙さ
せる液晶表示素子の製造方法において、前記スペーサは
前記電極透明基板に乾式で且つ負に帯電させた状態で散
布されるものとされ、このスペーサの散布時には前記電
極透明基板の前記配線電極には正の電圧が印加されてい
るものとされていることを特徴とする液晶表示素子の製
造方法。
1. A method of manufacturing a liquid crystal display device, wherein a spacer is sandwiched between an electrode transparent substrate in which pixel electrodes and wiring electrodes are laid in a matrix method and a counter transparent substrate in which a counter electrode is laid so as to face each other at appropriate intervals. The spacers are applied to the electrode transparent substrate in a dry and negatively charged state, and a positive voltage is applied to the wiring electrodes of the electrode transparent substrate when the spacers are applied. And a method for manufacturing a liquid crystal display device.
JP24403791A 1991-08-30 1991-08-30 Produciton of liquid crystal display element Pending JPH0561052A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24403791A JPH0561052A (en) 1991-08-30 1991-08-30 Produciton of liquid crystal display element

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24403791A JPH0561052A (en) 1991-08-30 1991-08-30 Produciton of liquid crystal display element

Publications (1)

Publication Number Publication Date
JPH0561052A true JPH0561052A (en) 1993-03-12

Family

ID=17112777

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24403791A Pending JPH0561052A (en) 1991-08-30 1991-08-30 Produciton of liquid crystal display element

Country Status (1)

Country Link
JP (1) JPH0561052A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
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DE19649406A1 (en) * 1995-11-30 1997-06-05 Sharp Kk LCD spacer on substrate spreading method
WO1997036205A1 (en) * 1996-03-22 1997-10-02 Hitachi, Ltd. Color liquid crystal display device and its manufacture
WO1998057225A1 (en) * 1997-06-13 1998-12-17 Sekisui Chemical. Co., Ltd. Liquid crystal display and method of manufacturing the same
WO1998057224A1 (en) * 1997-06-13 1998-12-17 Sekisui Chemical. Co., Ltd. Method of arranging particulates liquid crystal display, and anisotropic conductive film
WO1999022269A1 (en) 1997-10-27 1999-05-06 Sekisui Chemical Co., Ltd. Apparatus for spraying microparticles and spraying method using the apparatus, and method for manufacturing liquid crystal display
WO1999045429A1 (en) * 1998-03-03 1999-09-10 Sharp Kabushiki Kaisha Method of scattering fine particles, method of manufacturing liquid crystal display, apparatus for scattering fine particles, and liquid crystal display
KR20030031258A (en) * 2001-10-12 2003-04-21 엘지.필립스 엘시디 주식회사 Apparatus for Forming Spacer and Method of Manufacturing Liquid Crystal Display devices using the same
JP2007090251A (en) * 2005-09-29 2007-04-12 Toppan Printing Co Ltd Method and apparatus for forming thin film
US7223817B2 (en) 1998-09-02 2007-05-29 Kaneka Corporation Polymer, processes for producing polymer and composition
EP1898253A2 (en) * 2006-09-08 2008-03-12 Samsung Electronics Co., Ltd. Spacer spraying method and liquid crystal display manufactured by the same
US7370788B1 (en) 1998-12-28 2008-05-13 Kao Corporation Formed body

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JPS63285517A (en) * 1987-05-18 1988-11-22 Toshiba Corp Manufacture of liquid crystal display device
JPH02308223A (en) * 1989-05-24 1990-12-21 Seiko Epson Corp Manufacture of liquid crystal electrooptical element
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19649406A1 (en) * 1995-11-30 1997-06-05 Sharp Kk LCD spacer on substrate spreading method
WO1997036205A1 (en) * 1996-03-22 1997-10-02 Hitachi, Ltd. Color liquid crystal display device and its manufacture
US6577373B1 (en) 1997-06-13 2003-06-10 Sekisui Chemical Co., Ltd. Liquid crystal display and method of manufacturing the same
WO1998057225A1 (en) * 1997-06-13 1998-12-17 Sekisui Chemical. Co., Ltd. Liquid crystal display and method of manufacturing the same
WO1998057224A1 (en) * 1997-06-13 1998-12-17 Sekisui Chemical. Co., Ltd. Method of arranging particulates liquid crystal display, and anisotropic conductive film
WO1999022269A1 (en) 1997-10-27 1999-05-06 Sekisui Chemical Co., Ltd. Apparatus for spraying microparticles and spraying method using the apparatus, and method for manufacturing liquid crystal display
WO1999045429A1 (en) * 1998-03-03 1999-09-10 Sharp Kabushiki Kaisha Method of scattering fine particles, method of manufacturing liquid crystal display, apparatus for scattering fine particles, and liquid crystal display
US7223817B2 (en) 1998-09-02 2007-05-29 Kaneka Corporation Polymer, processes for producing polymer and composition
US7370788B1 (en) 1998-12-28 2008-05-13 Kao Corporation Formed body
KR20030031258A (en) * 2001-10-12 2003-04-21 엘지.필립스 엘시디 주식회사 Apparatus for Forming Spacer and Method of Manufacturing Liquid Crystal Display devices using the same
JP2007090251A (en) * 2005-09-29 2007-04-12 Toppan Printing Co Ltd Method and apparatus for forming thin film
EP1898253A2 (en) * 2006-09-08 2008-03-12 Samsung Electronics Co., Ltd. Spacer spraying method and liquid crystal display manufactured by the same
EP1898253A3 (en) * 2006-09-08 2008-05-14 Samsung Electronics Co., Ltd. Spacer spraying method and liquid crystal display manufactured by the same

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