JPH05331047A - Aqueous composition - Google Patents
Aqueous compositionInfo
- Publication number
- JPH05331047A JPH05331047A JP4134633A JP13463392A JPH05331047A JP H05331047 A JPH05331047 A JP H05331047A JP 4134633 A JP4134633 A JP 4134633A JP 13463392 A JP13463392 A JP 13463392A JP H05331047 A JPH05331047 A JP H05331047A
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- composition
- fragrance
- aqueous composition
- weight
- water
- Prior art date
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- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、入浴剤等の水性組成物
に関し、詳しくは、５０重量倍以上の水に溶解して用い
ても、香調が劣化しない入浴剤等の水性組成物に関す
る。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an aqueous composition such as a bathing agent, and more particularly to an aqueous composition such as a bathing agent which does not deteriorate in aroma even when dissolved in 50 times by weight or more of water. ..
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】入浴
剤、水洗トイレ用芳香剤及び洗浄剤等は、多量の水に溶
解して用いられる水性組成物であり、このような水性組
成物は、使用時において、長時間経過後もその芳香を持
続することが要求される。BACKGROUND OF THE INVENTION Bath agents, fragrances for flush toilets, detergents and the like are aqueous compositions used by dissolving in a large amount of water. When used, it is required to maintain its aroma even after a long time has passed.
【０００３】しかし、上述の従来の入浴剤等の水性組成
物は、上記要求を充分に満たすものではなかった。However, the above-mentioned conventional aqueous compositions such as bath salts have not sufficiently satisfied the above requirements.
【０００４】そこで、上記入浴剤等の製品の香りの強
さ、持続性等を向上させるため、種々の試み、例えば、
次の〜のような試みが行われている。 高沸点（低揮発性）香料の大量使用。 香料組成物の製品への配合量アップ。 保留剤の配合。 包接剤の利用。Therefore, various attempts have been made to improve the fragrance intensity, durability, etc. of products such as the above-mentioned bath agents, for example,
The following attempts have been made. Large amount of high boiling (low volatility) fragrances used. Increasing the amount of fragrance composition added to products Retention agent formulation. Use of clathrates.
【０００５】しかし、上記を適用した製品は、香調が
限定されるという欠点があり、特に、テルペンとその誘
導体を用いたフレッシュな香料の作成が困難である。上
記を適用した製品は、液状製品系への溶解又は粉状製
品系もしくはこれを成形した製品系への配合の面での制
約が大きくなる。また、粉状製品系では、その生産性が
著しく低下する。さらに、製品使用中に時間とともに香
りの質が変化するという問題もあり、このような問題
は、上記を適用した製品についても生じる。また、上
記を適用した製品は、保留剤が液状の場合には、上記
を適用した製品と同様の問題を有する。さらに、上記
を適用した製品は、包接剤と香料成分との親和性の存
在により、使用可能な香料成分が限定され、さらに、包
接剤の使用によって価格が上昇するという欠点がある。However, the products to which the above is applied have a drawback that the fragrance tone is limited, and in particular, it is difficult to prepare a fresh fragrance using terpene and its derivative. The product to which the above is applied is greatly restricted in terms of dissolution in a liquid product system or blending in a powdery product system or a product system formed by molding the same. In addition, the productivity of powdered products is significantly reduced. Further, there is also a problem that the quality of the fragrance changes with time during use of the product, and such a problem also occurs in products to which the above is applied. In addition, the product to which the above is applied has the same problem as the product to which the above is applied when the holding agent is liquid. Further, the product to which the above is applied has the drawback that the usable flavoring component is limited due to the affinity between the clathrate and the flavoring component, and the use of the clathrate increases the price.
【０００６】従って、本発明の目的は、多量の水に溶解
した際の香りの強さが充分で且つ持続性に優れ、香調が
含有させる香料組成物の香調と大きく変わらず、しかも
該香料組成物の配合の面での制約が少ない、水性組成物
を提供することにある。Therefore, the object of the present invention is that the strength of the scent when dissolved in a large amount of water is sufficient and has excellent sustainability, and the scent does not significantly change from the scent of the fragrance composition to be contained, and An object of the present invention is to provide an aqueous composition which has few restrictions in terms of the composition of the fragrance composition.
【０００７】[0007]
【課題を解決するための手段】本発明者等は、鋭意研究
した結果、従来は悪臭物質とされていたジアルキルスル
フィドと特定の香料とを含有させた水性組成物が、上記
目的を達成することを知見した。本発明は、上記知見に
基づいてなされたもので、（Ａ）ジアルキルスルフィド
を含有し且つ（Ｂ）２５℃における蒸気圧が２０μＨｇ
以上のエステルを５０％以上含有する香料組成物を含有
し、使用時に５０重量倍以上の水に溶解することを特徴
とする水性組成物（以下、第一発明という場合には、本
発明をいう）を提供するものである。また、本発明は、
（Ａ）ジアルキルスルフィドを含有し且つ（Ｃ）テルペ
ン系香料及びその誘導体を４０％以上含有する香料組成
物を含有し、使用時に５０重量倍以上の水に溶解するこ
とを特徴とする水性組成物（以下、第二発明という場合
には、本発明をいう）を併せて提供するものである。Means for Solving the Problems As a result of intensive studies, the present inventors have found that an aqueous composition containing a dialkyl sulfide and a specific fragrance, which were conventionally regarded as malodorous substances, can achieve the above object. I found out. The present invention was made based on the above findings, and contains (A) dialkyl sulfide and (B) has a vapor pressure of 20 μHg at 25 ° C.
An aqueous composition containing a fragrance composition containing 50% or more of the above ester and being dissolved in 50 times by weight or more of water at the time of use (hereinafter, the first invention refers to the present invention. ) Is provided. Further, the present invention is
An aqueous composition containing (A) a dialkyl sulfide and (C) a fragrance composition containing 40% or more of a terpene-based fragrance and a derivative thereof, which is dissolved in 50 times by weight or more of water when used. (Hereinafter, the second invention will be referred to as the second invention).
【０００８】以下、まず、第一発明の水性組成物につい
て詳述する。第一発明における香料組成物の（Ａ）成分
であるジアルキルスルフィドとしては、下記〔化１〕の
一般式（Ｉ）で表される化合物が挙げられる。First, the aqueous composition of the first invention will be described in detail below. Examples of the dialkyl sulfide which is the component (A) of the fragrance composition in the first invention include compounds represented by the following general formula (I).
【０００９】[0009]
【化１】Ｒ−（Ｓ）n −Ｒ （Ｉ） （ｎ＝１，２，３、Ｒは炭素数１〜４のアルキル基を示
す。）Embedded image R- (S) n -R (I) (n = 1, 2, 3, R represents an alkyl group having 1 to 4 carbon atoms)
【００１０】上記一般式（Ｉ）で表されるジアルキルス
ルフィドとしては、ジメチルジスルフィド、ジメチルト
リスルフィド、ジエチルジスルフィド、ジエチルトリス
ルフィド、ジプロピルジスルフィド、ジブチルジスルフ
ィド等が挙げられる。上記一般式（Ｉ）で表されるジア
ルキルスルフィドは、通常、オニオン、ポテト、キャロ
ット様香気を有し種々のフレーバー等として用いられて
おり、一般的に臭化アルキルと硫酸ナトリウムとの反応
により製造される。Examples of the dialkyl sulfide represented by the above general formula (I) include dimethyl disulfide, dimethyl trisulfide, diethyl disulfide, diethyl trisulfide, dipropyl disulfide, dibutyl disulfide and the like. The dialkyl sulfide represented by the above general formula (I) usually has an onion, potato, carrot-like aroma and is used as various flavors and the like, and is generally produced by reacting an alkyl bromide with sodium sulfate. To be done.
【００１１】上記（Ａ）成分の配合量は、用途により異
なるが、通常、第一発明における香料組成物中、０．１
〜１００００ｐｐｍ（重量基準、以下同じ）が好まし
く、１０〜３０００ｐｐｍが更に好ましい。The blending amount of the above-mentioned component (A) varies depending on the use, but is usually 0.1 in the fragrance composition of the first invention.
It is preferably 10000 ppm (weight basis, the same applies hereinafter), and more preferably 10 3000 ppm.
【００１２】また、第一発明における香料組成物の
（Ｂ）成分である２５℃における蒸気圧が２０μＨｇ以
上のエステルとしては、例えば、イソアミルアセテー
ト、イソアミルプロピオネート、イソブチルｎ−ブチレ
ート、ｎ−アミルプロピオネート、エチルアセトアセテ
ート、ヘプチルアセテート、メチルベンゾエート、ベン
ジルフォルメート、ボルニルフォルメート、エチルベン
ゾエート、スチライルアセテート、ジエチルサクシネー
ト、メチルフェニルアセテート、ベンジルアセテート、
メチルサリチレート、メチルヘプチンカーボネート、ｐ
−クレジルアセテート、リナリルアセテート、イソプレ
ゴールアセテート、ボルニルアセテート、イソボルニル
アセテート、メンチルアセテート、エチルフェニルアセ
テート、ベンジルプロピオネート、テルペニルアセテー
ト、フェニルエチルアセテート、リナリルプロピオネー
ト、エチルサリチレート、ゲラニルフォルメート、シト
ロネリルアセテート、ボルニルイソブチレート、ｐ−ｔ
−ブチルシクロヘキシルアセテート、フェニルエチルプ
ロピオネート、ジメチルベンジルカルビノールアセテー
ト、ゲラニルアセテート、フェニルエチルイソブチレー
ト、ジエチルマレート、フェニルプロピルアセテート、
ジメチルアントラニレート、シトロネリルフォルメー
ト、ネリルアセテート、ヘキシルアセテート等が挙げら
れる。Further, the ester having a vapor pressure of 20 μHg or more at 25 ° C., which is the component (B) of the fragrance composition in the first invention, is, for example, isoamyl acetate, isoamyl propionate, isobutyl n-butyrate or n-amyl. Propionate, ethyl acetoacetate, heptyl acetate, methyl benzoate, benzyl formate, bornyl formate, ethyl benzoate, styryl acetate, diethyl succinate, methyl phenyl acetate, benzyl acetate,
Methyl salicylate, methyl heptine carbonate, p
-Cresyl acetate, linalyl acetate, isopulegol acetate, bornyl acetate, isobornyl acetate, menthyl acetate, ethyl phenyl acetate, benzyl propionate, terpenyl acetate, phenyl ethyl acetate, linalyl propionate, ethyl sali Tylate, geranyl formate, citronellyl acetate, bornyl isobutyrate, pt
-Butyl cyclohexyl acetate, phenyl ethyl propionate, dimethyl benzyl carbinol acetate, geranyl acetate, phenyl ethyl isobutyrate, diethyl maleate, phenyl propyl acetate,
Examples thereof include dimethyl anthranilate, citronellyl formate, neryl acetate, and hexyl acetate.
【００１３】尚、上記エステルの蒸気圧の測定は、「香
料の化学」（赤星著、大日本図書〔Ｓ６３．３．１０発
行〕）によった。上記蒸気圧が２０μＨｇ未満である
と、充分な香りの強度が得られない。The vapor pressure of the above ester was measured by "Kagaku no Kagaku" (Akahoshi, Dainippon Tosho [S63.3.10]). If the vapor pressure is less than 20 μHg, sufficient scent intensity cannot be obtained.
【００１４】上記（Ｂ）成分の配合量は、用途により異
なるが、通常、本発明における香料組成物中、５０重量
％以上であり、好ましくは５０〜９０重量％、更に好ま
しくは５０〜７０重量％である。（Ｂ）成分の配合量が
５０重量％未満であると、香りの持続性が充分でない。The blending amount of the above-mentioned component (B) varies depending on the use, but is usually 50% by weight or more, preferably 50 to 90% by weight, more preferably 50 to 70% by weight in the perfume composition of the present invention. %. If the blending amount of the component (B) is less than 50% by weight, the scent persistence is insufficient.
【００１５】第一発明における香料組成物の各成分の比
率（重量基準）は、（Ａ）成分／（Ｂ）成分＝１０-11
／５０〜１／５０が好ましく、１０-9／５０〜１／５０
が更に好ましい。The ratio (weight basis) of each component of the fragrance composition in the first invention is (A) component / (B) component = 10 −11
/ 50 to 1/50 is preferable, and 10 -9 / 50 to 1/50
Is more preferable.
【００１６】第一発明における香料組成物は、上記
（Ａ）成分及び（Ｂ）成分を含有するもので、必要に応
じて配合される他の香料成分及び添加剤を混合すること
により調製される。上記必要に応じて配合される他の香
料成分は、特に制限されるものではなく、用途に応じて
適宜用いられる。また、上記香料組成物に、必要に応じ
て配合される添加剤としては、香料保持剤、酸化防止剤
等が挙げられる。The fragrance composition in the first invention contains the above-mentioned components (A) and (B), and is prepared by mixing other fragrance components and additives to be blended as necessary. .. The other perfume ingredients that are blended as necessary are not particularly limited and may be appropriately used depending on the application. In addition, examples of additives to be added to the above fragrance composition as needed include fragrance-holding agents and antioxidants.
【００１７】第一発明の水性組成物は、入浴剤、水洗ト
イレ用芳香剤、水洗トイレ用洗浄剤等の通常の水性組成
物に、上記香料組成物を通常の手段により含有させて調
製される。本発明の水性組成物の形態は特に制限され
ず、例えば、液状製品系、粉末状製品系及びこれを成形
した製品系等として用いることができる。The aqueous composition of the first invention is prepared by adding the above-mentioned perfume composition to an ordinary aqueous composition such as a bath agent, an aromatic agent for flush toilets and a detergent for flush toilets by an ordinary means. .. The form of the aqueous composition of the present invention is not particularly limited, and it can be used, for example, as a liquid product system, a powder product system and a product system obtained by molding the same.
【００１８】第一発明の水性組成物における上記香料組
成物の含有量は、該水性組成物の種類により異なるが、
通常、上述のような通常の水性組成物１００重量部に対
し、好ましくは０．０５〜１５重量部、更に好ましくは
０．１〜１０重量部である。The content of the fragrance composition in the aqueous composition of the first invention varies depending on the type of the aqueous composition,
Usually, it is preferably 0.05 to 15 parts by weight, more preferably 0.1 to 10 parts by weight, based on 100 parts by weight of the above-mentioned ordinary aqueous composition.
【００１９】第一発明の水性組成物は、使用時に５０重
量倍以上、好ましくは１００〜５００００重量倍の水に
溶解されて用いられる。The aqueous composition of the first invention is used by dissolving it in 50 times by weight or more, preferably 100 to 50000 times by weight of water before use.
【００２０】次に、第二発明の水性組成物について説明
する。第二発明における香料組成物の（Ａ）成分である
ジアルキルスルフィドは、上記第一発明における香料組
成物の（Ａ）成分と同じであり、その配合量は、用途に
より異なるが、通常、第二発明における香料組成物中、
０．１〜１００００ｐｐｍが好ましく、１０〜３０００
ｐｐｍが更に好ましい。Next, the aqueous composition of the second invention will be described. The dialkyl sulfide, which is the component (A) of the fragrance composition in the second invention, is the same as the component (A) of the fragrance composition in the first invention, and the compounding amount thereof is usually the In the fragrance composition of the invention,
0.1-10,000 ppm is preferable, 10-3000
ppm is more preferred.
【００２１】第二発明における香料組成物の（Ｃ）成分
であるテルペン系香料及びその誘導体としては、テルペ
ン（炭素数１０）及びセスキテルペン（炭素数１５）及
びそれらの誘導体が挙げられる。上記テルペン及びその
誘導体としては、例えば、α−ピネン、リモネン、ター
ピノレン、ミルセン、リナロール、ゲラニオール、シト
ロネロール、ｌ−メントール、シトラール、トロネラー
ル、樟脳、メントンが挙げられる。また、上記セスキテ
ルペン及びその誘導体としては、例えば、β−カリオフ
ィレン、サンタロール、ネロリドール、セドロール、ベ
チベロール、パチュリアルコールが挙げられる。Examples of the terpene-based fragrance and its derivative which are the component (C) of the fragrance composition in the second invention include terpenes (having 10 carbon atoms), sesquiterpenes (having 15 carbon atoms) and their derivatives. Examples of the terpene and derivatives thereof include α-pinene, limonene, terpinolene, myrcene, linalool, geraniol, citronellol, 1-menthol, citral, tronellal, camphor, and menthone. Examples of the sesquiterpene and its derivatives include β-caryophyllene, santalol, nerolidol, cedrol, vetiverol and patchouli alcohol.
【００２２】上記（Ｃ）成分の配合量は、用途により異
なるが、通常、本発明における香料組成物中、４０重量
％以上であり、好ましくは４０〜９０重量％、更に好ま
しくは４０〜８０重量％である。（Ｃ）成分の配合量が
４０重量％未満であると、香りの強さ、持続性が不充分
となり、さらに（Ａ）成分の匂いが強くなり、香調が悪
化するため好ましくない。The blending amount of the above-mentioned component (C) varies depending on the use, but is usually 40% by weight or more, preferably 40 to 90% by weight, more preferably 40 to 80% by weight in the perfume composition of the present invention. %. When the content of the component (C) is less than 40% by weight, the strength and sustainability of the fragrance become insufficient, and the odor of the component (A) becomes stronger, which deteriorates the fragrance tone, which is not preferable.
【００２３】第二発明における香料組成物の各成分の比
率（重量基準）は、（Ａ）成分／（Ｃ）成分＝１０-11
／４０〜１／４０が好ましく、１０-9／４０〜１／４０
が更に好ましい。The ratio (weight basis) of each component of the fragrance composition in the second invention is (A) component / (C) component = 10 −11
/ 40 to 1/40 is preferable, and 10 -9 / 40 to 1/40
Is more preferable.
【００２４】第二発明における上記香料組成物の含有量
は、該水性組成物の種類により異なるが、通常、上述の
ような通常の水性組成物１００重量部に対し、好ましく
は０．０５〜１５重量部、更に好ましくは０．１〜１０
重量部である。The content of the fragrance composition in the second invention varies depending on the kind of the aqueous composition, but is usually preferably 0.05 to 15 with respect to 100 parts by weight of the conventional aqueous composition as described above. Parts by weight, more preferably 0.1-10
Parts by weight.
【００２５】第二発明の水性組成物は、第一発明と同じ
く、使用時に５０重量倍以上、好ましくは１００〜５０
０００重量倍の水に溶解されて用いられる。The aqueous composition of the second invention is, like the first invention, 50 times by weight or more, preferably 100 to 50 times when used.
It is used after being dissolved in 000 times the weight of water.
【００２６】尚、上述した以外の点で、第一発明の水性
組成物で説明した内容は、そのまま第二発明の水性組成
物に適用される。In addition to the points described above, the contents described in the aqueous composition of the first invention are directly applied to the aqueous composition of the second invention.
【００２７】[0027]
【実施例】以下に、実施例を挙げ、本発明の水性組成物
を具体的に説明するが、本発明はこれらの実施例に制限
されるものではない。EXAMPLES Hereinafter, the aqueous composition of the present invention will be specifically described with reference to examples, but the present invention is not limited to these examples.
【００２８】（実施例１，２及び比較例１）下記〔表
１〕に示す香料処方による香料組成物を調製した。(Examples 1 and 2 and Comparative Example 1) A fragrance composition was prepared according to the fragrance formulation shown in [Table 1] below.
【００２９】[0029]
【表１】 [Table 1]
【００３０】上記〔表１〕に示す香料組成物を用いて下
記組成の発泡系弱酸性入浴剤を得た。得られた入浴剤に
ついて、それらの効果を下記〔試験例１〕により評価し
た。Using the fragrance composition shown in [Table 1] above, a foaming weakly acidic bathing agent having the following composition was obtained. The effects of the obtained bath salts were evaluated by the following [Test Example 1].
【００３１】（発泡系弱酸性入浴剤） 成 分 重量部 ・無水芒硝 ３０ ・炭酸水素ナトリウム ５５ ・コハク酸 １５ ・香料組成物（〔表１〕参照） １ ・色 素 微量(Effervescent weakly acidic bathing agent) Component weight parts: anhydrous sodium sulfate 30 sodium bicarbonate 55 succinic acid 15 fragrance composition (see [Table 1]) 1 minute amount of dye
【００３２】〔試験例１〕上記入浴剤５０グラムを、４
０℃の温水１５０リットルに投入し、専門パネラー５名
により、香調及び持続性（経時変化）を下記（評価基
準）により評価した。その結果を下記〔表２〕に示す。[Test Example 1] 50 g of the above bathing agent was added to 4
The mixture was poured into 150 liters of warm water at 0 ° C., and five expert panelists evaluated the fragrance and persistence (change with time) according to the following (evaluation criteria). The results are shown in [Table 2] below.
【００３３】（評価基準） ◎：香調は、配合した香料組成物自体の香調と同様。 ○：香調は、配合した香料組成物自体の香調とほぼ同
様。 △：香調は、配合した香料組成物自体の香調と同様でや
や弱い。 ×：香調は、配合した香料組成物自体の香調から変化し
ており、香りも弱い。(Evaluation Criteria) A: The scent is the same as the scent of the blended fragrance composition itself. ◯: The scent tone is almost the same as the scent tone of the blended fragrance composition itself. Δ: The fragrance tone is similar to the fragrance tone of the blended fragrance composition itself and is slightly weak. X: The scent is changed from the scent of the blended fragrance composition itself, and the scent is weak.
【００３４】[0034]
【表２】 [Table 2]
【００３５】上記〔表２〕に示す結果から明らかなよう
に、本発明の水性組成物は、多量の水に溶解しても、そ
の香調が、配合した香料組成物自体の香調と比べてほと
んど変化せず、その持続性に優れたものである。As is clear from the results shown in the above [Table 2], even if the aqueous composition of the present invention is dissolved in a large amount of water, its fragrance tone is higher than that of the blended fragrance composition itself. It has almost no change and is highly durable.
【００３６】（実施例３，４及び比較例２）上記〔表
１〕に示す香料組成物を用いて下記組成の水洗オートク
リーナーを常法により調製し、２０ｇを固型化した。得
られた水洗オートクリーナーについて、それらの効果を
下記〔試験例２〕により評価した。(Examples 3, 4 and Comparative Example 2) Using the perfume composition shown in [Table 1] above, a water-washed auto cleaner having the following composition was prepared by a conventional method, and 20 g of it was solidified. The effects of the obtained water-washed auto cleaner were evaluated by the following [Test Example 2].
【００３７】 （水洗オートクリーナー） 重量部 ・ポリエチレングリコール ６５ ・クエン酸ナトリウム １５ ・硫酸マグネシウム ７ ・香料組成物（〔表１〕参照） １０ ・色素 ２(Washing Auto Cleaner) Parts by Weight Polyethylene glycol 65 Sodium Citrate 15 Magnesium Sulfate 7 Perfume Composition (See [Table 1]) 10 Pigment 2
【００３８】[0038]
【００３９】〔試験例２〕固形化した上記水洗オートク
リーナー２０ｇをトイレにセットした。４人家族の一ヵ
月間使用を想定し、その目安として５００回のフラッシ
ュテストを行い、香調の変化及び香りの強さを〔試験例
１〕と同様に評価した。その結果を下記〔表３〕に示
す。Test Example 2 20 g of the solidified water-washed auto cleaner was set in a toilet. Assuming that the family of four was used for one month, a flash test was conducted 500 times as a guide, and changes in aroma and aroma intensity were evaluated in the same manner as in [Test Example 1]. The results are shown in [Table 3] below.
【００４０】[0040]
【表３】 [Table 3]
【００４１】実施例５，６及び比較例３ 下記〔表４〕に示す香料処方による香料組成物を調製し
た。Examples 5, 6 and Comparative Example 3 A fragrance composition was prepared according to the fragrance formulation shown in Table 4 below.
【００４２】[0042]
【表４】 [Table 4]
【００４３】調製した香料組成物を用いて下記組成の発
泡系弱酸性入浴剤を得た。得られた入浴剤について、そ
れらの効果を下記〔試験例３〕により評価した。Using the prepared fragrance composition, a foaming weakly acidic bathing agent having the following composition was obtained. The effects of the obtained bath salts were evaluated by the following [Test Example 3].
【００４４】（発泡系弱酸系入浴剤） 成 分 重量部 ・無水芒硝 ３０ ・炭酸水素ナトリウム ５５ ・コハク酸 １５ ・香料組成物（〔表４〕参照） １ ・色素 微量(Effervescent weak acid type bathing agent) Component weight parts: anhydrous sodium sulfate 30 sodium bicarbonate 55 succinic acid 15 fragrance composition (see [Table 4]) 1 small amount of dye
【００４５】〔試験例３〕上記入浴剤５０ｇを、４０℃
の温水１５０リットルに投入し、専門パネラー５名によ
り、香調及び持続性（経時変化）を〔試験例１〕と同様
にして評価した。その結果を下記〔表５〕に示す。[Test Example 3] 50 g of the above bathing agent was added at 40 ° C.
Was poured into 150 liters of warm water, and 5 expert panelists evaluated the aroma and persistence (change with time) in the same manner as in [Test Example 1]. The results are shown in [Table 5] below.
【００４６】[0046]
【表５】 [Table 5]
【００４７】[0047]
【発明の効果】本発明の水性組成物は、多量の水に溶解
した際の香りの強さが充分で且つ持続性に優れ、香調が
含有させる香料組成物の香調と大きく変わらず、しかも
該香料組成物の配合の面での制約が少ないものである。EFFECT OF THE INVENTION The aqueous composition of the present invention has sufficient fragrance intensity when dissolved in a large amount of water and is excellent in sustainability, and does not significantly change from the scent of the fragrance composition contained in the scent. Moreover, there are few restrictions in terms of blending the fragrance composition.
フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ａ６１Ｋ 7/46 ３４１ 9051−4Ｃ ３４５ Ｂ 9051−4Ｃ ３５５ Ｋ 9051−4Ｃ ３８５ Ａ 9051−4Ｃ Ｇ 9051−4Ｃ Ｌ 9051−4Ｃ Ｐ 9051−4Ｃ Ｃ１１Ｂ 9/00 Ｚ 2115−4Ｈ Ｓ 2115−4Ｈ // Ａ６１Ｌ 9/04 8718−4Ｃ Continuation of the front page (51) Int.Cl. 5 Identification code Office reference number FI Technical indication location A61K 7/46 341 9051-4C 345 B 9051-4C 355 K 9051-4C 385 A 9051-4C G 9051-4C L 9051-4C P 9051-4C C11B 9/00 Z 2115-4H S 2115-4H // A61L 9/04 8718-4C
Claims (2)
つ（Ｂ）２５℃における蒸気圧が２０μＨｇ以上のエス
テルを５０重量％以上含有する香料組成物を含有し、使
用時に５０重量倍以上の水に溶解することを特徴とする
水性組成物。1. A perfume composition containing (A) a dialkyl sulfide and (B) 50% by weight or more of an ester having a vapor pressure at 25 ° C. of 20 μHg or more, and 50% by weight or more of water when used. An aqueous composition characterized by being dissolved.
つ（Ｃ）テルペン系香料及びその誘導体を４０重量％以
上含有する香料組成物を含有し、使用時に５０重量倍以
上の水に溶解することを特徴とする水性組成物。2. A fragrance composition containing (A) a dialkyl sulfide and (C) a terpene-based fragrance and a derivative thereof in an amount of 40% by weight or more, which is dissolved in 50 times by weight or more of water when used. A featured aqueous composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP04134633A JP3138059B2 (en) | 1992-05-27 | 1992-05-27 | Aqueous composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP04134633A JP3138059B2 (en) | 1992-05-27 | 1992-05-27 | Aqueous composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05331047A true JPH05331047A (en) | 1993-12-14 |
| JP3138059B2 JP3138059B2 (en) | 2001-02-26 |
Family
ID=15132938
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP04134633A Expired - Fee Related JP3138059B2 (en) | 1992-05-27 | 1992-05-27 | Aqueous composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3138059B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000015190A1 (en) * | 1998-09-17 | 2000-03-23 | Exxon Chemical Patents Inc. | Cosmetic compositions containing higher alkyl acetates as emollients |
| US6495171B2 (en) | 1999-02-22 | 2002-12-17 | Kao Corporation | Interleukin-4 production inhibitors |
| SG93838A1 (en) * | 1998-07-31 | 2003-01-21 | Atochem Elf Sa | Compositions based on dimethyl disulphide with a masked smell |
| JP2005060477A (en) * | 2003-08-08 | 2005-03-10 | Kao Corp | Perfume composition |
| JP2005206726A (en) * | 2004-01-23 | 2005-08-04 | T Hasegawa Co Ltd | Perfume composition for aromatic detergent for flush toilet and aromatic detergent for flush toilet containing the same |
| JP2006249135A (en) * | 2005-03-08 | 2006-09-21 | T Hasegawa Co Ltd | Perfume composition |
| FR2910348A1 (en) * | 2006-12-22 | 2008-06-27 | Arkema France | Reagent for sulfurizing hydrotreating catalysts comprising an active metal on a metal or metalloid oxide support comprises diethyl, dipropyl or dibutyl disulfide |
| JP2017066101A (en) * | 2015-09-30 | 2017-04-06 | アース製薬株式会社 | Effervescent bath agent of compression-molding type |
-
1992
- 1992-05-27 JP JP04134633A patent/JP3138059B2/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SG93838A1 (en) * | 1998-07-31 | 2003-01-21 | Atochem Elf Sa | Compositions based on dimethyl disulphide with a masked smell |
| WO2000015190A1 (en) * | 1998-09-17 | 2000-03-23 | Exxon Chemical Patents Inc. | Cosmetic compositions containing higher alkyl acetates as emollients |
| US6495171B2 (en) | 1999-02-22 | 2002-12-17 | Kao Corporation | Interleukin-4 production inhibitors |
| US6960359B2 (en) | 1999-02-22 | 2005-11-01 | Kao Corporation | Interleukin-4 production inhibitors |
| US6974596B2 (en) | 1999-02-22 | 2005-12-13 | Kao Corporation | Interleukin-4 production inhibitors |
| JP2005060477A (en) * | 2003-08-08 | 2005-03-10 | Kao Corp | Perfume composition |
| JP2005206726A (en) * | 2004-01-23 | 2005-08-04 | T Hasegawa Co Ltd | Perfume composition for aromatic detergent for flush toilet and aromatic detergent for flush toilet containing the same |
| JP2006249135A (en) * | 2005-03-08 | 2006-09-21 | T Hasegawa Co Ltd | Perfume composition |
| FR2910348A1 (en) * | 2006-12-22 | 2008-06-27 | Arkema France | Reagent for sulfurizing hydrotreating catalysts comprising an active metal on a metal or metalloid oxide support comprises diethyl, dipropyl or dibutyl disulfide |
| WO2008087330A2 (en) * | 2006-12-22 | 2008-07-24 | Arkema France | Sulphidation agent for hydroprocessing catalyst and use thereof for in-situ and ex-situ presulphidation |
| WO2008087330A3 (en) * | 2006-12-22 | 2008-09-12 | Arkema France | Sulphidation agent for hydroprocessing catalyst and use thereof for in-situ and ex-situ presulphidation |
| JP2017066101A (en) * | 2015-09-30 | 2017-04-06 | アース製薬株式会社 | Effervescent bath agent of compression-molding type |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3138059B2 (en) | 2001-02-26 |
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