JPH04294132A - Manufacture of hollow product of fiber reinforced thermoplastic plastic - Google Patents
Manufacture of hollow product of fiber reinforced thermoplastic plasticInfo
- Publication number
- JPH04294132A JPH04294132A JP3083352A JP8335291A JPH04294132A JP H04294132 A JPH04294132 A JP H04294132A JP 3083352 A JP3083352 A JP 3083352A JP 8335291 A JP8335291 A JP 8335291A JP H04294132 A JPH04294132 A JP H04294132A
- Authority
- JP
- Japan
- Prior art keywords
- surface material
- core surface
- reinforced thermoplastic
- heat
- hollow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000000835 fiber Substances 0.000 title abstract description 3
- 239000000463 material Substances 0.000 claims abstract description 36
- 239000010419 fine particle Substances 0.000 claims abstract description 13
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 11
- 239000000057 synthetic resin Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 7
- 239000004416 thermosoftening plastic Substances 0.000 claims description 8
- 239000012783 reinforcing fiber Substances 0.000 claims description 6
- 229920005992 thermoplastic resin Polymers 0.000 claims description 5
- 238000000071 blow moulding Methods 0.000 claims description 4
- 238000007664 blowing Methods 0.000 abstract 1
- 238000005266 casting Methods 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- 239000011162 core material Substances 0.000 description 25
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 238000000465 moulding Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- -1 polyethylene Polymers 0.000 description 4
- 239000000956 alloy Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 239000006249 magnetic particle Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
Landscapes
- Moulds For Moulding Plastics Or The Like (AREA)
- Moulding By Coating Moulds (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は、例えば、ゴルフクラブ
のカーボンヘッドなどの中空の繊維強化熱可塑性プラス
チック成形品の製法に関し、合成樹脂で中空の芯表面材
を作り、この芯表面材に耐熱性微粒子を充填してその内
部を減圧状態とし、この状態のものを成形用の中型とす
ることによって成形品内部からの中型の撤去を容易に行
えるようにしたものである。[Industrial Application Field] The present invention relates to a method for manufacturing hollow fiber-reinforced thermoplastic molded products, such as carbon heads of golf clubs. The inside of the mold is filled with magnetic particles to create a reduced pressure state, and this state is used as a mold for molding, so that the mold can be easily removed from the inside of the molded product.
【0002】0002
【従来の技術】例えば、カーボン繊維強化合成樹脂ヘッ
ドゴルフクラブのカーボン繊維強化合成樹脂ヘッドなど
の繊維強化熱可塑性プラスチック中空の成形品の製法と
して、塩、低融点合金などを用いてヘッドの形状に類似
の形状の中型を作り、この中型に強化繊維と熱可塑性樹
脂からなる加熱軟化状態のプリプレグを巻き付け、この
ものを金属製の外型のキャビティ内に収容し、加熱加圧
して成形し、ついで冷却後中型をなす塩や低融点合金を
溶解して取り除き、繊維強化熱可塑性プラスチック製の
中空の成形品を得る方法が提案されている。[Prior Art] For example, as a manufacturing method for a fiber-reinforced thermoplastic hollow molded product such as a carbon fiber-reinforced synthetic resin head for a golf club with a carbon fiber-reinforced synthetic resin head, salt, a low-melting point alloy, etc. are used to shape the head. A medium mold with a similar shape is made, a heat-softened prepreg made of reinforcing fibers and thermoplastic resin is wrapped around this medium mold, this material is housed in the cavity of a metal outer mold, and is molded by heating and pressurizing. A method has been proposed in which a medium-sized salt or low-melting point alloy is melted and removed after cooling to obtain a hollow molded product made of fiber-reinforced thermoplastic plastic.
【0003】しかしながら、この製法では、成形品の内
部に存在し、中型を構成する塩や低融点合金を成形後に
溶解させるには、長時間を要し、中空の成形品を容易に
得られず、さらにこの溶解後の廃液が多量に生じ、処理
が困難になるという欠点があった。However, with this manufacturing method, it takes a long time to melt the salt and low melting point alloy that are present inside the molded product and make up the middle mold after molding, and it is not easy to obtain a hollow molded product. Furthermore, there is a drawback that a large amount of waste liquid is generated after dissolution, making treatment difficult.
【0004】0004
【発明が解決しようとする課題】よって、この発明にお
ける課題は、成形後に成形品の内部の中型の撤去が簡単
に行なえ、繊維強化熱可塑性プラスチック中空の成形品
を容易に得られる製法を提供することにある。[Problems to be Solved by the Invention] Therefore, an object of the present invention is to provide a manufacturing method that allows easy removal of the middle mold inside the molded product after molding and easily obtains a fiber-reinforced thermoplastic hollow molded product. There is a particular thing.
【0005】[0005]
【課題を解決するための手段】かかる課題は、合成樹脂
を吹込み成形して中空の芯表面材を作り、この芯表面材
中に耐熱性微粒子を充填し、芯表面材内を減圧として中
型となし、ついで強化繊維と熱可塑性樹脂からなり加熱
軟化したプリプレグをこの中型の芯表面材に巻き付け、
これを外型のキャビティ内に挿入して加熱加圧し、この
状態で冷却してプリプレグを外型の成形面に沿った形状
となし、ついで上記芯表面材内を大気圧に開放したのち
上記耐熱性微粒子を排出する方法で解決される。[Means for solving the problem] This problem was solved by blow molding a synthetic resin to create a hollow core surface material, filling this core surface material with heat-resistant fine particles, and reducing the pressure inside the core surface material to create a medium-sized core surface material. Next, heat-softened prepreg made of reinforcing fibers and thermoplastic resin is wrapped around this medium-sized core surface material.
This is inserted into the cavity of the outer mold, heated and pressurized, and cooled in this state to form the prepreg into a shape that follows the molding surface of the outer mold.Then, the interior of the core surface material is opened to atmospheric pressure, and then the heat resistant The problem can be solved by removing the harmful particles.
【0006】以下、この発明の一例を図面に基づき詳し
く説明する。この例は、繊維強化熱可塑性プラスチック
中空の成形品の具体例としてゴルフクラブのカーボン繊
維強化合成樹脂ヘッドを得るものである。まず、図1に
示すようなポリエチレン、ポリプロピレン、ポリ塩化ビ
ニル、メタクリル樹脂、ポリカーボネートなどの合成樹
脂を用いて吹込み形成により中空の芯表面材1を作る。
この芯表面材1は、製造しようとする中空の成形品の内
部の形状とほぼ類似する形状のもので、この例ではカー
ボン繊維強化合成樹脂ヘッドのヘッドの形状に類似の形
状となっている。芯表面材1の厚みは、0.1〜1.0
mm程度が好ましい。An example of the present invention will be explained in detail below with reference to the drawings. In this example, a carbon fiber-reinforced synthetic resin head of a golf club is obtained as a specific example of a fiber-reinforced thermoplastic hollow molded product. First, a hollow core surface material 1 is made by blow molding using a synthetic resin such as polyethylene, polypropylene, polyvinyl chloride, methacrylic resin, or polycarbonate as shown in FIG. This core surface material 1 has a shape almost similar to the internal shape of the hollow molded product to be manufactured, and in this example, it has a shape similar to the shape of the head of a carbon fiber reinforced synthetic resin head. The thickness of the core surface material 1 is 0.1 to 1.0
Approximately mm is preferable.
【0007】ついで、この芯表面材1の内部に砂、鉄粉
、ガラス粉、パーライト粉などの耐熱性微粒子2を充填
する。こののち、芯表面材1の内部を約10〜100ト
ール程度の減圧とする。ここでは芯表面材1のネックと
なる部分を通常の真空排気装置に接続し、布などの通気
性材料を介して芯表面材1内部を排気する方法などが採
用される。この減圧状態で、耐熱性微粒子2は大気圧に
よって加圧されて固化した状態となって、全体が硬い固
化状態となっている。本発明ではこの減圧状態にあるも
のが成形用の中型3となる。この中型3においては、し
たがって少なくとも加圧開始まで望ましくは成形が終了
するまで、この減圧状態を維持しておく必要がある。[0007] Next, the inside of this core surface material 1 is filled with heat-resistant fine particles 2 such as sand, iron powder, glass powder, perlite powder, or the like. Thereafter, the pressure inside the core surface material 1 is reduced to about 10 to 100 torr. Here, a method is adopted in which the neck portion of the core surface material 1 is connected to a normal vacuum evacuation device and the inside of the core surface material 1 is evacuated through an air permeable material such as cloth. In this reduced pressure state, the heat-resistant fine particles 2 are pressurized by atmospheric pressure and solidified, and the whole is in a hard solidified state. In the present invention, the mold in this reduced pressure state becomes the medium mold 3 for molding. Therefore, in this medium mold 3, it is necessary to maintain this reduced pressure state at least until the start of pressurization, preferably until the end of molding.
【0008】次に、図2に示すようなカーボン繊維、ア
ラミド繊維、ガラス繊維などの強化繊維とナイロン6、
ナイロン66、ナイロン11等のポリアミド、ポリブチ
レンテレフタレート、ポリオキシメチレン、ポリカーボ
ネイト、変性ポリフェニレンオキサイド、ポリフェニレ
ンスルファイドなどの熱可塑性樹脂からなり加熱軟化状
態のプリプリグ4を中型3に巻き付ける。このプリプレ
グ4は、中型3に巻き付けが容易であるようにテープ状
のものである。プリプレグの層数は、通常複数層とされ
、各回の巻き付け層毎に繊維方向を変えることもできる
。Next, as shown in FIG. 2, reinforcing fibers such as carbon fibers, aramid fibers, and glass fibers and nylon 6,
A prepreg 4 made of a thermoplastic resin such as polyamide such as nylon 66 or nylon 11, polybutylene terephthalate, polyoxymethylene, polycarbonate, modified polyphenylene oxide, or polyphenylene sulfide and softened by heating is wound around the middle mold 3. This prepreg 4 is tape-shaped so that it can be easily wrapped around the medium size 3. The number of layers of prepreg is usually multiple, and the fiber direction can be changed for each layer wrapped.
【0009】ついで、このプリプレグ4を巻き付けた中
型3を図3に示すような外型5のキャビティ6内にセッ
トする。この外型5は、二つ割り構造となっており、そ
の内部のキャビティ6の形状が最終成形品の外形の形状
、ここではゴルフクラブのヘッドの形状と一致したもの
である。そして、この外型5全体を加熱加圧し、さらに
この状態で冷却する。この加熱加圧によってプリプレグ
は外型のキャビティ6の形状にそったゴルフクラブのヘ
ッドの形状になる。この加熱加圧の条件は、温度50〜
150℃、圧力0.5〜5MPa、時間1〜10分程度
とされるが、この範囲に限られるものではなく、使用す
る熱可塑性樹脂の種類やゴルフクラブのヘッドの寸法、
強化繊維量などに応じて適宜変更することができる。[0009] Next, the middle mold 3 wrapped with the prepreg 4 is set in the cavity 6 of the outer mold 5 as shown in FIG. This outer mold 5 has a two-piece structure, and the shape of the cavity 6 inside thereof matches the outer shape of the final molded product, here the shape of the head of a golf club. Then, the entire outer mold 5 is heated and pressurized, and further cooled in this state. By this heating and pressurization, the prepreg takes the shape of a golf club head that follows the shape of the cavity 6 of the outer mold. The conditions for this heating and pressurization are as follows:
The temperature is 150°C, the pressure is 0.5 to 5 MPa, and the time is about 1 to 10 minutes, but the temperature is not limited to this range.
It can be changed as appropriate depending on the amount of reinforcing fibers, etc.
【0010】次に、外型5から成形品と中型3とが一体
となったものを取り外し、中型3をなす芯表面材1内を
大気圧に開放し、ついで耐熱性微粒子2をネックとなる
部分から排出する。これの排出は、充填物が微粒子であ
ることから、比較的容易に芯材の破壊作業を要せずに行
なえ、排出後の耐熱性微粒子2は回収して再使用が可能
であり、無駄となることがない。これによって図4に示
すような中空の目的とする繊維強化熱可塑性プラスチッ
ク製のカーボン繊維強化合成樹脂ヘッド7が得られる。Next, the molded product and the middle mold 3 are removed from the outer mold 5, the inside of the core surface material 1 forming the middle mold 3 is exposed to atmospheric pressure, and then the heat-resistant fine particles 2 are removed as a neck. Drain from the part. Because the filler is fine particles, this can be discharged relatively easily without the need to destroy the core material, and the heat-resistant fine particles 2 after discharge can be recovered and reused, eliminating waste. It never becomes. As a result, a hollow carbon fiber-reinforced synthetic resin head 7 made of fiber-reinforced thermoplastic plastic as shown in FIG. 4 is obtained.
【0011】この方法では中空の繊維強化可塑性プラス
チック製カーボンヘッド7の内部に芯表面材1が残留し
たままになっているが、必ずしも取り除く必要はない。
取り除く場合には、芯表面材1を有機溶剤で溶解する方
法や常温または軽く加熱して芯表面材1を軟化状態とし
て引っ張り出す方法などがある。In this method, the core surface material 1 remains inside the hollow fiber-reinforced plastic carbon head 7, but it is not necessarily necessary to remove it. When removing the core surface material 1, there are methods such as dissolving the core surface material 1 with an organic solvent, or heating it at room temperature or slightly to soften the core surface material 1 and pulling it out.
【0012】また、必要に応じて繊維強化熱可塑性プラ
スチック製カーボンヘッド7の内部に発泡ポリウレタン
樹脂などの液状未硬化発泡性樹脂を注入し、その内部を
発泡樹脂で満たすこともできる。また、上述の例は、成
形品としてゴルフクラブのカーボン繊維強化合成樹脂ヘ
ッドについて説明したが本発明の製法は勿論これに限ら
れるものではなく、他の中空成形品に適用できることは
言うまでもない。Furthermore, if necessary, a liquid uncured foamable resin such as a foamed polyurethane resin can be injected into the inside of the fiber-reinforced thermoplastic carbon head 7 to fill the inside with the foamed resin. Further, in the above example, a carbon fiber-reinforced synthetic resin head of a golf club was explained as a molded product, but the manufacturing method of the present invention is of course not limited to this, and it goes without saying that it can be applied to other hollow molded products.
【0013】[0013]
【発明の効果】以上説明したように、この発明の繊維強
化熱可塑性プスチック中空成形品の製法は、合成樹脂を
吹込み成形して中空の芯表面材を作り、この芯表面材中
に耐熱性微粒子を充填し、芯表面材内を減圧として中型
となし、ついで強化繊維と熱可塑性樹脂からなり、加熱
軟化したプリプレグをこの中型の芯表面材に巻き付け、
これを外型のキャビティ内にセットして加熱加圧成形し
、ついで冷却後上記芯表面材内を大気圧に開放したのち
、上記耐熱性微粒子を排出するものであるので、成形後
の中空の繊維強化熱可塑性プラスチック成形品から、中
型を取り出す作業が単純化されて迅速に行うことができ
、しかも廃液等の不要物を発生することもない。[Effects of the Invention] As explained above, the method for producing fiber-reinforced thermoplastic plastic hollow molded products of the present invention involves blow molding a synthetic resin to create a hollow core surface material, and adding heat-resistant material to the core surface material. Filled with fine particles, the inside of the core surface material is reduced to a medium size, and then heated and softened prepreg made of reinforcing fibers and thermoplastic resin is wrapped around this medium size core surface material.
This is set in the cavity of the outer mold and molded under heat and pressure.Then, after cooling, the inside of the core surface material is released to atmospheric pressure, and the heat-resistant fine particles are discharged. The work of removing a medium mold from a fiber-reinforced thermoplastic molded product is simplified and can be done quickly, and moreover, no unnecessary materials such as waste liquid are generated.
【0014】[0014]
【図1】 この発明の製法の一例で中空の芯表面材に
耐熱性微粒子を充填した状態を示す概略断面図である。FIG. 1 is a schematic cross-sectional view showing a state in which a hollow core surface material is filled with heat-resistant fine particles in an example of the manufacturing method of the present invention.
【図2】 この発明の製法の一例でプリプレグを中型
に巻き付けた状態を示す概略断面図である。FIG. 2 is a schematic cross-sectional view showing a prepreg wrapped around a medium mold according to an example of the manufacturing method of the present invention.
【図3】 この発明の製法の一例で中型を外型のキャ
ビティ内に挿入した状態を示す概略断面図である。FIG. 3 is a schematic cross-sectional view showing a state in which the middle mold is inserted into the cavity of the outer mold in an example of the manufacturing method of the present invention.
【図4】 この発明の製法の一例で繊維強化熱可塑性
プラスチック中空成形品を示す概略断面図である。FIG. 4 is a schematic cross-sectional view showing a fiber-reinforced thermoplastic hollow molded product according to an example of the manufacturing method of the present invention.
Claims (1)
面材を作り、この芯表面材中に耐熱性微粒子を充填し、
芯表面材内を減圧して中型となし、ついで強化繊維と熱
可塑性樹脂からなるプリプレグをこの中型の芯表面材に
巻き付け、これを外型のキャビティ内に挿入して加熱加
圧し、ついで上記芯表面材内の耐熱性微粒子を排出する
ことを特徴とする繊維強化熱可塑性プラスチック中空成
形品の製法。[Claim 1] A hollow core surface material is made by blow molding a synthetic resin, and heat-resistant fine particles are filled in this core surface material,
The inside of the core surface material is depressurized to form a medium-sized core, then prepreg made of reinforcing fibers and thermoplastic resin is wrapped around this medium-sized core surface material, and this is inserted into the cavity of the outer mold and heated and pressurized. A method for manufacturing fiber-reinforced thermoplastic hollow molded products, which is characterized by ejecting heat-resistant fine particles from the surface material.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3083352A JPH04294132A (en) | 1991-03-22 | 1991-03-22 | Manufacture of hollow product of fiber reinforced thermoplastic plastic |
US07/853,978 US5262118A (en) | 1991-03-22 | 1992-03-20 | Method for producing a hollow FRP article |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP3083352A JPH04294132A (en) | 1991-03-22 | 1991-03-22 | Manufacture of hollow product of fiber reinforced thermoplastic plastic |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH04294132A true JPH04294132A (en) | 1992-10-19 |
Family
ID=13800047
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP3083352A Withdrawn JPH04294132A (en) | 1991-03-22 | 1991-03-22 | Manufacture of hollow product of fiber reinforced thermoplastic plastic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH04294132A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005074950A (en) * | 2003-09-03 | 2005-03-24 | Araco Corp | Manufacturing process of shaped body |
JP2011224939A (en) * | 2010-04-23 | 2011-11-10 | Torai Engineering Kk | Fiber-reinforced resin molded article and manufacturing method therefor |
JP2012187730A (en) * | 2011-03-09 | 2012-10-04 | Mitsubishi Rayon Co Ltd | Method for molding fiber-reinforced plastic |
WO2013187418A1 (en) * | 2012-06-12 | 2013-12-19 | 三菱レイヨン株式会社 | Molding method for fiber-reinforced plastic structure, and vehicle wheel |
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1991
- 1991-03-22 JP JP3083352A patent/JPH04294132A/en not_active Withdrawn
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