JP6410120B2 - Method for producing organic slow-release fertilizer - Google Patents
Method for producing organic slow-release fertilizer Download PDFInfo
- Publication number
- JP6410120B2 JP6410120B2 JP2017533330A JP2017533330A JP6410120B2 JP 6410120 B2 JP6410120 B2 JP 6410120B2 JP 2017533330 A JP2017533330 A JP 2017533330A JP 2017533330 A JP2017533330 A JP 2017533330A JP 6410120 B2 JP6410120 B2 JP 6410120B2
- Authority
- JP
- Japan
- Prior art keywords
- liquid phase
- oil
- elements
- meal
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003337 fertilizer Substances 0.000 title claims description 70
- 238000004519 manufacturing process Methods 0.000 title claims description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 52
- 239000007791 liquid phase Substances 0.000 claims description 51
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 42
- 229910052700 potassium Inorganic materials 0.000 claims description 37
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 33
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 33
- 239000011591 potassium Substances 0.000 claims description 33
- 239000000843 powder Substances 0.000 claims description 33
- 229910052757 nitrogen Inorganic materials 0.000 claims description 30
- 239000011575 calcium Substances 0.000 claims description 28
- 229910052791 calcium Inorganic materials 0.000 claims description 28
- 239000003921 oil Substances 0.000 claims description 28
- 235000019198 oils Nutrition 0.000 claims description 28
- 241000251468 Actinopterygii Species 0.000 claims description 26
- 235000019688 fish Nutrition 0.000 claims description 26
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 25
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 25
- 235000010755 mineral Nutrition 0.000 claims description 25
- 239000011707 mineral Substances 0.000 claims description 25
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
- 239000011248 coating agent Substances 0.000 claims description 23
- 238000000576 coating method Methods 0.000 claims description 23
- 239000008280 blood Substances 0.000 claims description 22
- 210000004369 blood Anatomy 0.000 claims description 22
- 238000006460 hydrolysis reaction Methods 0.000 claims description 22
- 229910052717 sulfur Inorganic materials 0.000 claims description 22
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 21
- 235000013339 cereals Nutrition 0.000 claims description 19
- 230000007062 hydrolysis Effects 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 18
- 239000002374 bone meal Substances 0.000 claims description 18
- 229940036811 bone meal Drugs 0.000 claims description 18
- 239000012535 impurity Substances 0.000 claims description 18
- 239000011593 sulfur Substances 0.000 claims description 18
- 239000011573 trace mineral Substances 0.000 claims description 18
- 235000013619 trace mineral Nutrition 0.000 claims description 18
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 17
- 239000010459 dolomite Substances 0.000 claims description 17
- 229910000514 dolomite Inorganic materials 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 17
- 238000000354 decomposition reaction Methods 0.000 claims description 16
- 239000008187 granular material Substances 0.000 claims description 16
- 239000011777 magnesium Substances 0.000 claims description 16
- 229910052749 magnesium Inorganic materials 0.000 claims description 16
- 235000012054 meals Nutrition 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 15
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 15
- 235000018927 edible plant Nutrition 0.000 claims description 14
- 239000005996 Blood meal Substances 0.000 claims description 13
- 210000003278 egg shell Anatomy 0.000 claims description 13
- 239000010440 gypsum Substances 0.000 claims description 12
- 229910052602 gypsum Inorganic materials 0.000 claims description 12
- 238000005470 impregnation Methods 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 12
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 12
- 239000008158 vegetable oil Substances 0.000 claims description 12
- 239000004927 clay Substances 0.000 claims description 11
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 235000015170 shellfish Nutrition 0.000 claims description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- 235000020774 essential nutrients Nutrition 0.000 claims description 9
- 239000004467 fishmeal Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000005909 Kieselgur Substances 0.000 claims description 8
- 235000015165 citric acid Nutrition 0.000 claims description 8
- 239000001103 potassium chloride Substances 0.000 claims description 8
- 235000011164 potassium chloride Nutrition 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 8
- 102000002322 Egg Proteins Human genes 0.000 claims description 7
- 108010000912 Egg Proteins Proteins 0.000 claims description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000011574 phosphorus Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 239000003549 soybean oil Substances 0.000 claims description 7
- 235000012424 soybean oil Nutrition 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 235000019483 Peanut oil Nutrition 0.000 claims description 5
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 5
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 5
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 5
- 235000019774 Rice Bran oil Nutrition 0.000 claims description 5
- 235000011054 acetic acid Nutrition 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 235000012343 cottonseed oil Nutrition 0.000 claims description 5
- 239000002385 cottonseed oil Substances 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 235000013379 molasses Nutrition 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 5
- 239000000312 peanut oil Substances 0.000 claims description 5
- 239000008165 rice bran oil Substances 0.000 claims description 5
- 239000008159 sesame oil Substances 0.000 claims description 5
- 235000011803 sesame oil Nutrition 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 239000000454 talc Substances 0.000 claims description 5
- 229910052623 talc Inorganic materials 0.000 claims description 5
- 239000002383 tung oil Substances 0.000 claims description 5
- 244000147058 Derris elliptica Species 0.000 claims description 4
- 241000233855 Orchidaceae Species 0.000 claims description 4
- 240000002834 Paulownia tomentosa Species 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- 230000000813 microbial effect Effects 0.000 claims description 4
- 230000001376 precipitating effect Effects 0.000 claims description 4
- 239000004575 stone Substances 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 3
- 241000972773 Aulopiformes Species 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 235000019764 Soybean Meal Nutrition 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- 235000021329 brown rice Nutrition 0.000 claims description 3
- 150000001735 carboxylic acids Chemical class 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 3
- 230000002255 enzymatic effect Effects 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 235000019253 formic acid Nutrition 0.000 claims description 3
- 239000003864 humus Substances 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- 150000002894 organic compounds Chemical class 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 229910001562 pearlite Inorganic materials 0.000 claims description 3
- 239000011435 rock Substances 0.000 claims description 3
- 239000004455 soybean meal Substances 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 235000013618 yogurt Nutrition 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 239000012071 phase Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- 235000019733 Fish meal Nutrition 0.000 claims 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 2
- 239000011733 molybdenum Substances 0.000 claims 2
- 239000011236 particulate material Substances 0.000 claims 2
- 238000001179 sorption measurement Methods 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- 235000013601 eggs Nutrition 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- 239000006166 lysate Substances 0.000 claims 1
- 239000011259 mixed solution Substances 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 238000007789 sealing Methods 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 description 10
- 235000015097 nutrients Nutrition 0.000 description 9
- 241000237502 Ostreidae Species 0.000 description 8
- 210000000988 bone and bone Anatomy 0.000 description 8
- 235000020636 oyster Nutrition 0.000 description 8
- 239000006227 byproduct Substances 0.000 description 7
- 241001465754 Metazoa Species 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 239000000944 linseed oil Substances 0.000 description 4
- 235000021388 linseed oil Nutrition 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000011505 plaster Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 241000252233 Cyprinus carpio Species 0.000 description 3
- 210000003608 fece Anatomy 0.000 description 3
- 244000144972 livestock Species 0.000 description 3
- 239000010871 livestock manure Substances 0.000 description 3
- 244000052769 pathogen Species 0.000 description 3
- 150000003109 potassium Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 241001519451 Abramis brama Species 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 241001397173 Kali <angiosperm> Species 0.000 description 2
- YBCVMFKXIKNREZ-UHFFFAOYSA-N acoh acetic acid Chemical compound CC(O)=O.CC(O)=O YBCVMFKXIKNREZ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000002361 compost Substances 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 240000001866 Vernicia fordii Species 0.000 description 1
- FPWJLQXCGHQXLL-UHFFFAOYSA-N [P].OP(O)(O)=O Chemical compound [P].OP(O)(O)=O FPWJLQXCGHQXLL-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000009264 composting Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002498 deadly effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000007515 enzymatic degradation Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000001459 mortal effect Effects 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- ZDHURYWHEBEGHO-UHFFFAOYSA-N potassiopotassium Chemical compound [K].[K] ZDHURYWHEBEGHO-UHFFFAOYSA-N 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F5/00—Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
- C05F5/002—Solid waste from mechanical processing of material, e.g. seed coats, olive pits, almond shells, fruit residue, rice hulls
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F1/00—Fertilisers made from animal corpses, or parts thereof
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D1/00—Fertilisers containing potassium
- C05D1/02—Manufacture from potassium chloride or sulfate or double or mixed salts thereof
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F1/00—Fertilisers made from animal corpses, or parts thereof
- C05F1/002—Fertilisers made from animal corpses, or parts thereof from fish or from fish-wastes
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F5/00—Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/90—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/10—Solid or semi-solid fertilisers, e.g. powders
- C05G5/12—Granules or flakes
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Soil Sciences (AREA)
- Botany (AREA)
- Mechanical Engineering (AREA)
- Fertilizers (AREA)
Description
本発明は、有機緩効性肥料の製造方法に関するもので、より詳細には、天然の材料を利用して、植物生育に必要な必須栄養元素の12種類、即ち、N、P、K、Ca、Mg、S、Fe、Mn、Cu、B、Mo、Znのうちの多量元素及び中量元素とミネラル肥料を有機的に製造する有機緩効性肥料の製造方法に関するものである。 The present invention relates to a method for producing an organic slow-release fertilizer, and more specifically, using natural materials, 12 kinds of essential nutrient elements necessary for plant growth, that is, N, P, K, Ca , Mg, S, Fe, Mn, Cu, B, Mo, and Zn. The present invention relates to a method for producing an organic slow-release fertilizer that organically produces a large amount element and a medium amount element and mineral fertilizer.
一般的に、肥料は食用植物及び観賞用植物に栄養分を供給するためのもので、水や水分によって溶解された養液で前記植物に栄養分を供給する。 Generally, a fertilizer is for supplying a nutrient to an edible plant and an ornamental plant, and the nutrient is supplied to the plant with a nutrient solution dissolved by water or moisture.
このような肥料は緩効性肥料と化学肥料または有機肥料で区別することができ、化学肥料及び緩効性肥料は、化学肥料のような化学性物質で組成されているため、食用植物に栄養分として提供されると、土壌を酸性化させ、地力を落とし、環境汚染など様々な副作用を引き起こす問題点がある。 Such fertilizers can be distinguished from slow-release fertilizers, chemical fertilizers or organic fertilizers, and chemical fertilizers and slow-release fertilizers are composed of chemical substances such as chemical fertilizers, so that nutrients can be added to edible plants. When it is provided, there are problems that acidify the soil, reduce the strength of the soil, and cause various side effects such as environmental pollution.
また、これは前記土壌汚染に応じて生成された食用植物を人が摂取すると、汚染成分が人体に吸収されて、様々な病気を誘発させるなど、人体の不調和現象が発生する問題点がある。 In addition, when a person ingests an edible plant generated in response to the soil contamination, the contaminated component is absorbed into the human body, causing various diseases, such as causing various diseases. .
また、これらの問題点を解決するために、有機肥料である堆肥、即ち、畜糞、鶏糞、魚及びおがくずのような植物繊維を混合して、土壌に混ぜると、環境汚染を予防することができる。 In addition, in order to solve these problems, composting that is an organic fertilizer, that is, mixing plant fibers such as animal manure, chicken manure, fish and sawdust, and mixing with soil can prevent environmental pollution. .
しかし、植物ごとに、または畜糞と鶏糞、魚副産物及びおがくずは時期と家畜の状態及び環境に応じて、飼料の栄養成分と堆肥の生産環境が異なるため、それぞれ異なる栄養成分を含み、食用植物別に要求される栄養分と異なる場合、良質の食用植物を生産することができないことおよび、栽培者及び栽培地域によって相互に異なる品質の食用植物を生産する必要があるとの問題点がある。 However, each animal or animal manure, fish by-product, and sawdust contain different nutritional components depending on the time, the state of the livestock, and the environment. When it is different from the required nutrients, there are problems that it is impossible to produce a good quality edible plant and that it is necessary to produce edible plants having different qualities depending on the grower and the cultivation area.
また、堆肥に病原菌が含まれる場合、食用植物に致命的な有害環境を提供するとの問題点がある。 In addition, when pathogens are included in compost, there is a problem of providing a deadly harmful environment to edible plants.
また、栽培時期ごとに相互に異なる品質の食用植物を生産するため、消費者に安全で、高品質の食用植物を均等に供給することができないので、消費者に信頼性を確保することができなくなる問題点がある。 In addition, edible plants with different qualities are produced at different cultivation periods, so it is not possible to supply high-quality edible plants that are safe to consumers and can be reliably supplied to consumers. There is a problem that disappears.
また、このような従来の堆肥は、常に悪臭が多く発生して、栽培環境が劣悪になり、長期保管と移動が困難で、取り扱いが難しい問題点がある。 In addition, such conventional compost has a problem that a lot of bad odors are always generated, the cultivation environment is deteriorated, long-term storage and movement are difficult, and handling is difficult.
本発明は、前記のような問題点を解決するために創案されたもので、油粕(植物油を採取して残った残渣を通称することで、大豆粕、パーム粕などを含む)、血粉(家畜の血、即ち、鮮血)、斃死魚または魚の骨を含む副産物、骨粉、死海鉱物(死海で採取される鉱物で、「塩化加里」と呼ばれる)、卵の殻、貝殻、カキ殻、天然石膏、ドロマイト、千枚岩、天然塩を所定の抽出過程で食用植物の必須栄養元素の12種類(N、P、K、Ca、Mg、S、Fe、Mn、Cu、B、Mo、Zn)のうちの、多量元素または中量元素別に抽出して、粒の形態で有機肥料を製造し、これを植物別に相応しい比率の元素肥料を提供することができるようにした有機緩効性肥料の製造方法を提供することに、その目的がある。 The present invention was devised to solve the above-mentioned problems, and includes oil lees (including soybean oil, palm lees, etc., by referring to residues remaining after collecting vegetable oil), blood meal (livestock Blood (ie, fresh blood), dead products or by-products including fish bones, bone meal, Dead Sea minerals (minerals collected in the Dead Sea, called “Kori Chloride”), egg shells, shells, oyster shells, natural plaster, Among twelve kinds of essential nutrient elements of edible plants (N, P, K, Ca, Mg, S, Fe, Mn, Cu, B, Mo, Zn) in a predetermined extraction process of dolomite, shale, natural salt A method for producing an organic slow-release fertilizer that can produce organic fertilizers in the form of grains by extracting them in large quantities or medium elements, and providing an appropriate proportion of elemental fertilizers for each plant. The purpose is to provide.
また、本発明は、多量、中量元素、ミネラル別に肥料粒形態で固形処理して、植物に長い時間の間、漸進的で、継続的な栄養分供給を提供するようにした有機緩効性肥料の製造方法を提供することに、その目的がある。 In addition, the present invention provides an organic slow-release fertilizer that is solid-processed in the form of fertilizer grains according to a large amount, medium amount element, and mineral to provide a gradual and continuous nutrient supply to a plant for a long time. The purpose is to provide a manufacturing method.
また、本発明は、必要な栄養成分を多量に、重量別にそれぞれ多孔質体の粒に含浸させ、有機固形肥料を生産して、長時間保管及び移動を容易にした有機緩効性肥料の製造方法を提供することに、その目的がある。 In addition, the present invention is a method for producing an organic slow-release fertilizer that is impregnated in a large amount of necessary nutrients by weight into each porous body grain to produce an organic solid fertilizer that can be stored and moved for a long time. The purpose is to provide a method.
また、本発明は、多量、中量元素別に必須栄養成分を個別的に生成することができるため、有機に含まれる病原体から比較的に安全に生育管理することができるようにした有機緩効性肥料の製造方法を提供することに、その目的がある。 In addition, the present invention is capable of individually producing essential nutrients for each of a large amount and a medium amount element, so that the organic slow-release property can be managed relatively safely from pathogens contained in the organic matter. The purpose is to provide a method for producing fertilizer.
また、本発明は、多量、中量元素別に必須栄養成分を個別的に生成することができるため、植物別に様々に要求される相応しいカスタム栄養成分を供給するようにした有機緩効性肥料の製造方法を提供することに、その目的がある。 In addition, since the present invention is capable of individually producing essential nutrients for each of the large and medium elements, it is possible to produce an organic slow-release fertilizer that can supply appropriate custom nutrients that are variously required for each plant. The purpose is to provide a method.
本発明は、前記の目的に応じて、有機緩効性肥料の製造方法において、植物油を抽出した後の残渣に該当する油粕及び魚を乾燥した魚粕を含む斃死魚または血粉(または乾血)と、骨粉と、塩化加里と、天然石膏、ドロマイトを一定の時間の間乾燥させ、表面積を最大化するために、これを個別的に破砕機でパウダーに破砕させる破砕段階と、前記天然石膏とドロマイト、塩化加里を除いて破砕されたそれぞれの前記パウダーと、クエン酸または酢酸及び苛性ソーダのような加水分解溶媒を多数の個別の混合容器に収容して密閉した後、常温で一定の時間の間に加水分解の反応を誘導して、窒素、リン、カリウム(「加里」とも呼ばれる)に該当する多量の元素の混合液相で液化させる加水分解段階と、前記加水分解段階で液化された多量の元素の混合液相を一定期間の間、不純物と水分解残留物を沈殿させて、これを除去した後、混合液のみを分離させる沈殿分離段階と、前記の多量元素の混合液相に、人工用土であるハイドロボール、ゼオライト、パーライト、蘭石のうちのいずれか一つの多孔質体の粒を加熱容器で一定時間の間加熱して、多孔質体の吸着力によって、前記粒の微細空隙内に向かって前記多量元素の混合物と中量元素混合物のうちのいずれか一つ以上を含浸させながら、充填及び乾燥させる含浸段階と、前記破砕段階でカルシウム、マグネシウム、硫黄を有する中量元素に該当する前記天然石膏とドロマイトと塩化加里パウダーに、糖蜜と澱粉のうちのいずれか一つ以上の液相粘結材を混合して、粒形態の粒状を製造する粒状形成段階と、前記粘結材によって形成された粒状と前記含浸された多孔質体の粒のうちのいずれか一つの外面に、亜麻仁油と大豆油(豆油)、桐油(桐油木の油)を含む植物油と、粘土と滑石と珪藻土と吸着シリカのパウダーのうちから選択されるいずれか一つ以上の結合体を混合したコーティング部材をコーティングさせるコーティング段階を含むことを特徴とする有機緩効性肥料の製造方法によって達成される。 According to the present invention, in the method for producing an organic slow-release fertilizer, dying fish or blood meal (or dry blood) containing an oil cake corresponding to a residue after extracting vegetable oil and a fish cake obtained by drying the fish in the method for producing an organic slow-release fertilizer A crushing step in which bone powder, potassium chloride, natural gypsum and dolomite are dried for a certain period of time, and individually crushed into powder with a crusher to maximize the surface area, and the natural gypsum Each powder, except for dolomite and potassium chloride, and a hydrolyzing solvent such as citric acid or acetic acid and caustic soda are placed in a number of individual mixing containers and sealed, and then at room temperature for a certain period of time. A hydrolysis step in which a hydrolysis reaction is induced to liquefy in a mixed liquid phase of a large amount of elements corresponding to nitrogen, phosphorus and potassium (also called “Kari”), and a large amount of liquefied in the hydrolysis step The mixed liquid phase of the element is precipitated for a certain period of time by precipitating impurities and water splitting residue, removing this, and then separating only the mixed liquid. The particles of any one of hydroball, zeolite, pearlite, and orchid stone, which is a soil, are heated in a heating container for a certain period of time, and the pores adsorb in the fine voids of the particles. Corresponds to the impregnation step of filling and drying while impregnating any one or more of the mixture of the large elements and the medium element toward the medium, and the medium elements having calcium, magnesium and sulfur in the crushing step A granule forming step for producing granules in the form of granules by mixing one or more liquid phase binders of molasses and starch into the natural gypsum, dolomite and chlorinated potassium powder, and the binder By Vegetable oil containing linseed oil, soybean oil (bean oil), tung oil (paulownia oil tree oil), clay, talc and diatomaceous earth on the outer surface of any one of the formed granules and the impregnated porous body grains And a method for producing an organic slow-release fertilizer, comprising a coating step of coating a coating member mixed with at least one binder selected from powders of adsorbed silica.
ここで、前記加水分解段階は、植物油を抽出した後の残渣に該当する油粕及び魚を乾燥した魚粕を含む斃死魚、または血粉(または乾血)と、骨粉と、卵の殻、貝殻、カキ殻、貝化石を所定の水と一緒に分解容器に収容して、その分解容器に玄米雑穀と腐葉土を添加して、酵素分解と土着微生物分解のうちのいずれかの一つで分解して、前記多量元素及び中量元素のうちのいずれかの一つの混合液相で液化させる生物学的分解段階に代替されることが好ましい。 Here, the hydrolysis step includes an oil pod corresponding to a residue after extracting the vegetable oil and a moribund fish including a fish pod dried from the fish, or blood meal (or dry blood), bone meal, egg shell, shell, Oyster shells and shell fossils are placed in a decomposition container together with the prescribed water, brown rice grains and humus are added to the decomposition container, and decomposed by either enzymatic decomposition or indigenous microbial decomposition. Preferably, it is replaced with a biological decomposition step in which the mixed liquid phase of any one of the large element and the medium element is liquefied.
また、前記コーティング段階は、含浸された前記多孔質体肥料粒が乾燥される前に、その露出面に粘土、白土、珪藻土のうちのいずれかの一つ以上のパウダー形状の硬化剤が一緒に被覆されるように混合する段階を含み、前記油粕はパーム粕、大豆粕、菜種油粕、綿実油粕、ヒマシ油粕、米ぬか油粕、ゴマ油粕、落花生油粕のうちのいずれかの一つから構成されており、前記油粕の多量元素の混合液相は、窒素(N)3〜15重量%、リン酸(P2O5)2〜9重量%、カリウムまたは加里(K2O)1〜3重量%で肥料成分を含み、その他の成分は、水分や不純物及び微量元素を含み、前記魚粕の多量と中量元素に該当する液相は、窒素(N)4〜8重量%、リン酸(P2O5)6〜9重量%、カルシウム(CaO)7〜11重量%で肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含み、前記血粉と乾血の多量元素の混合液相は、窒素(N)8〜12重量%、リン酸(P2O5)0.11重量%、カリウムまたは加里(K2O)0.11重量%で肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含み、前記骨粉の多量及び中量元素の混合液相は、窒素(N)2〜4重量%、リン酸(P2O5)18〜21重量%、カルシウム(CaO)27〜30重量%で肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含み、前記塩化加里の中量元素の混合液相は、カルシウム(CaO)60〜62重量%で肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含み、前記ドロマイトの中量元素の混合液相は、カルシウム(CaO)27〜30重量%、マグネシウム(MgO)17〜21重量%で肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含み、前記天然石膏の中量元素の混合液相は、カルシウム(CaO)29〜33重量%、硫黄15 〜19重量%で肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含むことが好ましい。 In addition, the coating step may be performed before the impregnated porous body fertilizer grains are dried, with one or more powdery curing agents selected from clay, white clay, and diatomaceous earth on the exposed surface. The oil cake is composed of any one of palm cake, soybean cake, rapeseed oil cake, cottonseed oil cake, castor oil cake, rice bran oil cake, sesame oil cake, peanut oil cake The mixed liquid phase of the large elements of the oil cake is 3 to 15% by weight of nitrogen (N), 2 to 9% by weight of phosphoric acid (P 2 O 5 ), 1 to 3% by weight of potassium or potassium (K 2 O). Including the fertilizer component, the other components include moisture, impurities and trace elements, and the liquid phase corresponding to the large amount and medium amount element of the fish salmon is 4 to 8% by weight of nitrogen (N), phosphoric acid (P 2 O 5) 6 to 9% by weight, calcium (CaO) 7 to 11 wt% And the other components contain moisture, impurities and trace elements, and the mixed liquid phase of blood powder and dry blood contains a large amount of nitrogen (N) 8-12 wt%, phosphoric acid (P 2 O 5 ) 0.11% by weight, potassium or potassium (K 2 O) 0.11% by weight, including fertilizer components, other components include moisture, impurities and trace elements, The mixed liquid phase contains 2 to 4% by weight of nitrogen (N), 18 to 21% by weight of phosphoric acid (P 2 O 5 ), 27 to 30% by weight of calcium (CaO), and contains fertilizer components. The mixed liquid phase of the medium element of chlorinated potassium contains fertilizer components at 60 to 62% by weight of calcium (CaO), and other components include moisture, impurities and trace elements, The mixed liquid phase of medium elements of the dolomite is calcium ( aO) 27-30% by weight, magnesium (MgO) 17-21% by weight, including fertilizer components, other components include moisture, impurities and trace elements, It is preferable that fertilizer components are contained in calcium (CaO) 29 to 33% by weight and sulfur 15 to 19% by weight, and other components include moisture, impurities and trace elements.
そして、ミネラル成分で構成された天然塩及び千枚岩またはそのパウダーの場合、これを水に一定時間の間、強制的交絡(混合)で溶解させる溶解段階と、前記溶解液を沈殿させ、ミネラル液相に分離させる沈殿段階と、そのミネラル液相に粘結材を混合し、加熱容器から一定の温度に加熱して、前記多孔質体の粒の空隙にミネラル成分を含浸させながら、乾燥させる含浸段階と、前記パウダーに粘結材を混合して前記糖蜜と澱粉のうちのいずれかの一つ以上の粘結材液相を混合して、粒形態の粒状を製造する粒状形成段階とのうちのいずれかの一つで実行する段階をさらに含み、前記ミネラル成分が含浸された多孔質体と前記粒状のうちのいずれかの一つが前記コーティング段階で同様に行われることが好ましい。 And, in the case of natural salt and shale or powder thereof composed of mineral components, a dissolution stage in which this is dissolved in water by forced entanglement (mixing) for a certain period of time, and the solution is precipitated, A precipitation stage for separation into a liquid phase, and a binder is mixed with the mineral liquid phase, heated to a certain temperature from a heating vessel, and dried while impregnating the mineral components in the pores of the porous body grains. An impregnation step, and a granule formation step in which a caking agent is mixed with the powder, and one or more caustic agent liquid phases of the molasses and starch are mixed to produce granules in the form of granules. Preferably, the method further includes a step of performing any one of them, and one of the porous material impregnated with the mineral component and the granular material is similarly performed in the coating step.
また、前記加水分解溶媒は硫黄、苛性ソーダ(水酸化ナトリウム)、水を所定の構成比で混合された混合物のみならず、酸性を有する有機化合物を通称する有機酸に該当するクエンさん、酢酸(アセト酸)、カルボン酸、乳酸(ヨーグルト)、ギ酸、シトリック酸、シュウ酸、琥珀酸、酒石酸、リンゴ酸のうちのいずれかの一つのものを含むことが好ましい。 In addition, the hydrolysis solvent is not only a mixture in which sulfur, caustic soda (sodium hydroxide) and water are mixed in a predetermined composition ratio, but also a citrate, acetic acid (acetate) corresponding to an organic acid commonly referred to as an acidic organic compound. Acid), carboxylic acid, lactic acid (yogurt), formic acid, citric acid, oxalic acid, succinic acid, tartaric acid, and malic acid.
本発明は、油粕(植物油を採取して残った残渣を通称することで、大豆粕、パーム粕などを含む)、血粉(家畜の血、即ち、鮮血)、斃死魚または魚の骨を含む副産物、骨粉、死海鉱物(死海で採取される鉱物で、「塩化加里」と呼ばれる)、卵の殻、貝殻、カキ殻、天然石膏、ドロマイト、千枚岩、天然塩を所定の抽出過程で食用植物の必須栄養元素の12種類(N、P、K、Ca、Mg、S、Fe、Mn、Cu、B、Mo、Zn)のうちの、多量元素または中量元素別に抽出して、粒の形態で有機肥料を製造し、これを植物別に相応しい比率の元素肥料を提供することができるため、生産者に関係ないだけではなく、どこでも均等な品質の食用植物を生産することができ、消費者の信頼性を確保することができる効果がある。 The present invention relates to oil candy (referring to the residue left after collecting vegetable oil, including soybean meal, palm cocoon, etc.), blood meal (livestock blood, ie, fresh blood), dead products or by-products containing fish bones, Bone meal, Dead Sea minerals (minerals collected from the Dead Sea, called “Kori Chloride”), egg shells, shells, oyster shells, natural plaster, dolomite, shale, natural salt Of the 12 types of essential nutrient elements (N, P, K, Ca, Mg, S, Fe, Mn, Cu, B, Mo, Zn) It is possible to produce organic fertilizers and provide them with appropriate proportions of elemental fertilizers for each plant, so that not only the producers can be produced, but also edible plants of equal quality can be produced everywhere. There is an effect that can secure the sex.
また、本発明は、元素別に肥料粒形態で固形処理して、植物に長い時間の間、漸進的で、継続的な標的栄養分の供給を提供するため、食用植物の旺盛な生育活用により、有機食用植物を安全に多量生産を可能にする効果がある。 In addition, the present invention solid-processes in the form of fertilizer grains by element, and provides a gradual and continuous supply of target nutrients for a long time to the plant. It has the effect of enabling safe mass production of edible plants.
また、本発明は、元素別に必須栄養成分のそれぞれを多孔質体の粒に含浸させ、有機固形肥料を生産するため、長時間の保管及び移動を容易にする効果があり、植物別に肥料の容量を正確に提供することができるので、標的管理を可能にする効果がある。 In addition, the present invention impregnates each of the essential nutrients for each element into the porous body grains to produce organic solid fertilizer, which has the effect of facilitating long-term storage and movement, and the fertilizer capacity for each plant. Can be provided accurately, which has the effect of enabling target management.
また、本発明は、元素別に必須栄養成分を個別的に生成することができるため、有機に含まれる病原体から比較的安全に生育管理することができる効果がある。 Moreover, since this invention can produce | generate an essential nutrient component according to an element separately, there exists an effect which can carry out growth management comparatively safely from the pathogen contained in organic.
以下、添付された図面を参照して、本発明に係る有機緩効性肥料の製造方法を詳細に説明すると、次の通りである。 Hereinafter, a method for producing an organic slow-release fertilizer according to the present invention will be described in detail with reference to the accompanying drawings.
本発明に係る必須栄養成分の12元素は、N、P、K、Ca、Mg、S、Fe、Mn、Cu、B、Mo、Znで構成されており、これらのうちの多量元素は、窒素、リン、カリウム( 「加里」とも呼ばれる)であり、中量元素は、カルシウム、マグネシウム、硫黄であり、微量元素は、残りの元素である。これらを生成するために、油粕(植物油を抽出して残った残渣を通称することで、パーム粕、大豆粕、菜種油粕、綿実油粕、ヒマシ油粕、米ぬか油粕、ゴマ油粕、落花生油粕などを含む)、血粉(家畜の血、即ち、鮮血)、斃死魚または魚の骨を含む副産物及び魚粕、骨粉、塩化加里(採取される鉱物)、卵の殻、貝殻、カキ殻、天然石膏、ドロマイト、千枚岩、天然塩を用意する。ここで、骨粉は動物の骨であり、塩化加里は採取される鉱物として、硫酸加里を含み、貝殻とカキ殻は貝類に該当する貝類全体を対象とする。 The 12 essential nutrient components according to the present invention are composed of N, P, K, Ca, Mg, S, Fe, Mn, Cu, B, Mo, and Zn. , Phosphorus and potassium (also called “Kari”), medium elements are calcium, magnesium and sulfur, and trace elements are the remaining elements. In order to produce these, oil lees (including the residue remaining after extracting vegetable oil, including palm lees, soybean lees, rapeseed oil lees, cottonseed oil lees, castor oil lees, rice bran oil lees, sesame oil lees, peanut oil lees, etc.) , Blood meal (domestic blood, ie, fresh blood), by-products including fish dying or fish bones and fish carp, bone meal, chlorinated salt (minerals collected), egg shells, shells, oyster shells, natural plaster, dolomite, thousand Prepare single rock and natural salt. Here, bone meal is animal bones, potassium chloride contains potassium sulfate as a mineral to be collected, and shells and oyster shells cover the entire shellfish corresponding to shellfish.
前記多量元素に対応する天然肥料、即ち、窒素、リン酸(「リン」に該当する)、カリウム(加里)は、これらの多量元素を多く含有している物質で、油粕、血粉、斃死魚から抽出可能であり、前記中量元素に対応する天然肥料、即ち、カルシウム、マグネシウム、硫黄を含有しており、これを多量に含有している塩化加里、天然石膏、ドロマイト、卵の殻、貝殻、カキ殻から抽出可能である。ミネラルは千枚岩と、天然塩から抽出可能である。 Natural fertilizers corresponding to the above-mentioned multi-elements, that is, nitrogen, phosphoric acid (corresponding to “phosphorus”), potassium (Kari) are substances containing a large amount of these multi-elements, from oil cake, blood meal, moribund fish Natural fertilizers that can be extracted and correspond to the above-mentioned intermediate elements, i.e., calcium, magnesium, sulfur, and contain a large amount of this, potassium chloride, natural gypsum, dolomite, egg shells, shells, Extractable from oyster shells. Minerals can be extracted from phyllite and natural salt.
本有機緩効性肥料の製造方法は、図1に示した通りである。 The method for producing the organic slow-release fertilizer is as shown in FIG.
まず、多量元素の抽出について説明すると、パーム粕、大豆粕、菜種油粕、綿実油粕、ヒマシ油粕、米ぬか油粕、ゴマ油粕、落花生油粕のうちのいずれかの一つに該当する油粕を用意し、または斃死魚及び魚の骨を含む副産物(魚を乾燥した「魚粕」を含む)と血粉(動物の血を凝固させた鮮血)、骨粉のうちのいずれかの一つを用意する。 First, the extraction of a large amount of element will be described. Prepare an oil cake corresponding to any one of palm meal, soybean meal, rapeseed oil meal, cottonseed oil meal, castor oil meal, rice bran oil meal, sesame oil meal, peanut oil meal, or Prepare one of mortal fish and by-products containing fish bones (including “fish carp” that dried the fish), blood meal (fresh blood that coagulates animal blood), and bone meal.
油粕、斃死魚、魚の骨を含む副産物、血粉、骨粉を一定時間の間、完全に乾燥させ、表面積を最大化させるために、これを破砕機でパウダーの形態になれるように破砕させる。(破砕段階)このとき、前記骨粉と血粉はパウダーで形成されている場合、破砕させない。 Oil culms, moribund fish, by-products including fish bones, blood meal, and bone meal are completely dried for a certain period of time and crushed into powder form with a crusher to maximize surface area. (Crushing step) At this time, when the bone meal and blood meal are formed of powder, they are not crushed.
ここで、前記油粕は油を抽出して残った残渣を通称するものであり、このような前記破砕物以外の多量元素及び中量元素が多く含有した動植物に該当する他の天然物質を使用することもできる。 Here, the oil lees generally refers to the residue left after extracting the oil, and other natural substances corresponding to animals and plants containing a large amount of large elements and medium elements other than the crushed material are used. You can also
このように破砕されたパウダーのうち、油粕、斃死魚、魚の骨の副産物及び血粉のパウダーを混合容器に収容し、その混合容器にクエンさん及び酢酸のような加水分解溶媒のうちのいずれか一つを所定の比率で収容して、密閉させた後、25℃前、後の室温で一定の期間、または時間の間に加水分解反応を誘導すると、多量元素である窒素、リン(リン酸)、加里(カリウム)を一定の比率で混合した多量元素混合液相に液化される。(加水分解段階) Among the powders crushed in this way, oil cake, moribund fish, fish bone by-product and blood powder powder are stored in a mixing container, and either one of a hydrolysis solvent such as Quen and acetic acid is stored in the mixing container. When a hydrolysis reaction is induced for a certain period of time or at a room temperature before and after 25 ° C. after being stored in a predetermined ratio and sealed, nitrogen, phosphorus (phosphoric acid), which are large elements, are introduced. Then, it is liquefied into a multi-element mixed liquid phase in which potassium (potassium) is mixed at a constant ratio. (Hydrolysis stage)
ここで、前記加水分解溶媒は、前記クエン酸及び酢酸などを含む有機酸または有機酸複合体に該当する有機材料を使用するだけでなく、苛性ソーダと硫黄の複合体も含む。特に、前記苛性ソーダ(水酸化ナトリウム:NaOH)の場合は、前記加水分解溶媒は、硫黄と水を混合して、前記パウダーを加水分解可能にする。即ち、硫黄25重量%、苛性ソーダ20重量%、水55重量%に該当する構成比で構成されており、加水分解の効率的な状況を誘導するために、前記混合構成比に水32重量%をさらに混合、及び中和させて使用することもできる。 Here, the hydrolysis solvent includes not only an organic acid containing the citric acid and acetic acid, or an organic material corresponding to the organic acid complex, but also a complex of caustic soda and sulfur. In particular, in the case of caustic soda (sodium hydroxide: NaOH), the hydrolysis solvent mixes sulfur and water to make the powder hydrolyzable. That is, it is composed of a composition ratio corresponding to 25% by weight of sulfur, 20% by weight of caustic soda, and 55% by weight of water. Further, it can be used after mixing and neutralization.
そして、前記有機酸の種類は、酸性を有する有機化合物を通称するもので、前記クエン酸、酢酸(アセト酸)のみならず、カルボン酸、乳酸(ヨーグルト)、ギ酸、シトリック酸、シュウ酸、琥珀酸、酒石酸、リンゴ酸のうちのいずれか一つを含む。 The kind of the organic acid is a general term for an organic compound having acidity, and includes not only the citric acid and acetic acid (acetic acid), but also carboxylic acid, lactic acid (yogurt), formic acid, citric acid, oxalic acid, 琥珀Including any one of acid, tartaric acid and malic acid.
前記多量元素の混合液相は、菜種油粕である場合、窒素(N)5.8重量%、リン酸(P2O5)3.1重量%、カリウムまたは加里(K2O)1.5重量%で肥料成分を構成し、大豆油粕である場合、窒素(N)7.17重量%、リン酸(P2O5)2重量%、カリウムまたは加里(K2O)2.37重量%で肥料成分を構成し、綿実油粕である場合、窒素(N)6.6重量%、リン酸(P2O5)2.9重量%、カリウムまたは加里(K2O)1.7重量%で肥料成分を構成し、ヒマシ油粕である場合、窒素(N)5.7重量%、リン酸(P2O5)2.2重量%、カリウムまたは加里(K2O)1.3重量%で肥料成分を構成し、米ぬか油粕である場合、窒素(N)3.2重量%、リン酸(P2O5)8.2重量%、カリウムまたは加里(K2O)2.54重量%で肥料成分を構成し、ゴマ油粕である場合、窒素(N)7.26重量%、リン酸(P2O5)2.55重量%、カリウムまたは加里(K2O)1.17重量%で肥料成分を構成して、ピーナッツ油粕である場合、窒素(N)7.27重量%、リン酸(P2O5)3 2重量%、カリウムまたは加里(K2O)1.3重量%で肥料成分を構成し、パーム粕である場合、窒素(N)3.3重量%、リン酸(P2O5)1.5重量%、カリウムまたは加里(K2O)1重量%で肥料成分を構成している。 In the case of rapeseed oil cake, the mixed liquid phase of the large elements is 5.8% by weight of nitrogen (N), 3.1% by weight of phosphoric acid (P 2 O 5 ), 1.5% of potassium or potassium (K 2 O). In the case of soybean oil lees, the fertilizer component is composed of wt%, nitrogen (N) 7.17 wt%, phosphoric acid (P 2 O 5 ) 2 wt%, potassium or potassium (K 2 O) 2.37 wt% If the fertilizer component is composed of cottonseed oil cake, nitrogen (N) 6.6% by weight, phosphoric acid (P 2 O 5 ) 2.9% by weight, potassium or potassium (K 2 O) 1.7% by weight In the case of castor oil cake, the fertilizer component is composed of 5.7% by weight of nitrogen (N), 2.2% by weight of phosphoric acid (P2O5), 1.3% by weight of potassium or potassium (K 2 O). When the rice bran oil cake is made up, nitrogen (N) 3.2 wt%, phosphoric acid (P 2 O 5 ) 8.2 wt%, potassium or potassium (K 2 O) The fertilizer component is composed of 2.54% by weight, and in the case of sesame oil cake, nitrogen (N) 7.26% by weight, phosphoric acid (P 2 O 5 ) 2.55% by weight, potassium or potassium (K 2 O) 1.17% by weight of the fertilizer component, in the case of peanut oil cake, nitrogen (N) 7.27% by weight, phosphoric acid (P 2 O 5 ) 3 2% by weight, potassium or potassium (K 2 O) The fertilizer component is composed of 1.3% by weight, and in the case of palm koji, nitrogen (N) 3.3% by weight, phosphoric acid (P 2 O 5 ) 1.5% by weight, potassium or potassium The fertilizer component is composed of 1% by weight of (K 2 O).
また、前記魚粕の多量及び中量元素に該当する液相は,窒素(N)4〜8重量%、リン酸(P2O5)6〜9重量%、カルシウム(CaO)7〜11重量%で肥料成分を構成し、前記血粉と乾血の多量元素の混合液相は、窒素(N)8〜12重量%、リン酸(P2O5)0.11重量%、カリウムまたは加里(K2O)0.11重量%で肥料成分を構成している。ここで、他の成分は、水分と不純物及び微量元素で構成されている。 In addition, the liquid phase corresponding to the large and medium elements of the fish salmon is nitrogen (N) 4-8 wt%, phosphoric acid (P 2 O 5 ) 6-9 wt%, calcium (CaO) 7-11 wt%. %, And the mixed liquid phase of the blood powder and dry blood multi-elements is 8 to 12% by weight of nitrogen (N), 0.11% by weight of phosphoric acid (P 2 O 5 ), potassium or potassium ( K 2 O) 0.11% by weight constitutes the fertilizer component. Here, the other components are composed of moisture, impurities, and trace elements.
前記加水分解段階で液化された多量元素の混合液相を、一定期間の間に前記混合容器で維持しながら、加水分解反応後の残渣不純物と加水分解残留物を沈殿させ、これを除去した後、多量元素の混合液相のみを分離させる。(沈殿分離段階) After maintaining the mixed liquid phase of the multi-elements liquefied in the hydrolysis step in the mixing vessel for a certain period of time, the residual impurities and hydrolysis residues after the hydrolysis reaction are precipitated and removed. Only the mixed liquid phase of a large amount of elements is separated. (Precipitation separation stage)
前記沈殿分離段階で分離及び抽出した前記多量元素の混合液相を、含浸用個別容器に混合可能に収容し、同時にゼオライト、パーライト、蘭石のような比較的に空隙率が高い多孔質体の粒を一緒に収容して、一定の時間の間に漸進的に高温加熱すると、前記多孔質体の空隙に高濃度の多量元素の混合液相が流入され、固形状態で含浸される。(含浸段階) The mixed liquid phase of the large elements separated and extracted in the precipitation separation step is stored in a separate container for impregnation, and at the same time, a porous body having a relatively high porosity such as zeolite, pearlite, orchid stone. When the grains are accommodated together and gradually heated to a high temperature for a certain period of time, a mixed liquid phase of a high concentration of a large amount of elements flows into the voids of the porous body, and is impregnated in a solid state. (Impregnation stage)
このように、前記多量元素の混合液相が固形状態で含浸された多孔質体の粒、即ち、有機多量元素の混合含浸粒は、その外径面に亜麻仁油と大豆油(豆油)、桐油(桐油木の油)を含む植物油と、粘土と滑石と珪藻土と吸着シリカのパウダーのうちから選択されるいずれか一つ以上の結合体を混合したコーティング部材をコーティングさせ、一定の時間の間に乾燥させる。(コーティング段階) Thus, the porous body particles impregnated with the mixed liquid phase of the multi-elements in a solid state, that is, the mixed impregnated grains of the organic multi-elements are linseed oil, soybean oil (bean oil), tung oil on the outer diameter surface thereof. (Coating oil of paulownia oil tree) and a coating member mixed with any one or more selected from powders of clay, talc, diatomaceous earth, and adsorbed silica, and coated for a certain period of time dry. (Coating stage)
そうすると、このようにコーティングされた有機多量元素の混合含浸粒は、水に浸かっても前記コーティング部材によって多量元素である窒素、リン、加里の混合肥料を漸進的で、継続的に食用植物に供給することになる。 Then, even if the mixed impregnated grains of organic multi-elements coated in this way are soaked in water, mixed fertilizers of nitrogen, phosphorus and potassium, which are multi-elements, are gradually supplied to the edible plant continuously by the coating member. Will do.
ここで、前記破砕段階で植物油を抽出した後の残渣に該当する油粕及び魚を乾燥した魚粕を含む斃死魚または血粉(または乾血)と、骨粉と、卵の殻、貝殻、カキ殻、貝化石を破砕機でパウダーに破砕したり、パウダー化したものを用意する。そして、前記加水分解段階に代わって、植物油を抽出した後の残渣に該当する油粕及び魚を乾燥した魚粕を含む斃死魚または血粉(または乾血)と、骨粉と、卵の殻、貝殻、カキ殻、貝化石を所定の水と一緒に分解容器に収容し、その分解容器に常温以上で玄米雑穀と腐葉土を添加して、酵素分解と土着微生物分解のうちのいずれか一つにより分解させ、前記多量元素及び中量元素のうちのいずれか一つの混合液相に液化させる。(生物学的分解段階)その後は、前記沈殿分離段階、含浸段階、コーティング段階を順次的に実行すると、多量元素、中量元素のうちのいずれか一つの肥料成分の緩効性肥料を製造することができる。ここで、前記微生物分解のための相応しい温度は30度以上であり、前記酵素分解のための相応しい温度は40度以上が好ましい。 Here, dying fish or blood meal (or dry blood) including oil bream corresponding to residues after extraction of vegetable oil in the crushing stage and dried fish bream, bone meal, egg shell, sea shell, oyster shell, Shell fossil is crushed into powder with a crusher or prepared in powder form. And instead of the hydrolysis step, dying fish or blood meal (or dry blood) containing oil meal corresponding to the residue after extracting the vegetable oil and dried fish carp (or dry blood), bone meal, egg shell, shell, Oyster shells and shell fossils are stored in a decomposition container together with the prescribed water, brown rice grains and humus are added to the decomposition container at room temperature or higher, and decomposed by either enzymatic decomposition or indigenous microbial decomposition. And liquefying into a mixed liquid phase of any one of the large element and the medium element. (Biological decomposition step) Thereafter, when the precipitation separation step, the impregnation step, and the coating step are sequentially performed, a slow release fertilizer of any one of a large amount element and a medium amount element is produced. be able to. Here, a suitable temperature for the microbial degradation is 30 degrees or more, and a suitable temperature for the enzymatic degradation is preferably 40 degrees or more.
前述したような有機緩効性肥料の製造方法でカルシウム、マグネシウム、硫黄に該当する中量元素を、多孔質体粒に含浸させてコーティングしたものを、製造することができる。 It is possible to produce a product obtained by impregnating a porous particle with a medium amount element corresponding to calcium, magnesium, or sulfur by the method for producing an organic slow-release fertilizer as described above.
即ち、骨粉と、塩化加里と、卵の殻及び天然石膏、または、貝殻、カキ殻と、ドロマイト、貝化石を一定時間の間に乾燥させ、表面積を最大化するために、これを個別に破砕機でパウダーに破砕させる。(破砕段階)ただし、塩化加里や、ドロマイト、天然石膏、貝化石などはパウダーの形態で流通することができるため、別途にパウダー化しなくてもよい。 That is, bone meal, potassium chloride, egg shells and natural plaster, or shells, oyster shells, dolomite, and shell fossils are dried separately over a period of time and then crushed individually to maximize surface area. Break into powder with a machine. (Crushing stage) However, Kali chloride, dolomite, natural gypsum, shell fossil, etc. can be distributed in the form of powder, and thus do not need to be powdered separately.
ここで、前記骨粉の多量及び中量元素の混合液相は、窒素(N)2〜4重量%、リン酸(P2O5)18〜21重量%、カルシウム(CaO)27〜30重量%で肥料成分を構成し、純度95%以上の前記塩化加里(塩化カルシウムとも呼ばれる)の中量元素の混合液相は、カルシウム(CaO)60〜62重量%で肥料成分を構成し、純度95%以上の前記ドロマイトの中量元素の混合液相は、カルシウム(CaO)27〜30重量%、マグネシウム(MgO)17〜21重量%で肥料成分を構成し、純度95%以上の前記天然石膏の中量元素の混合液相は、カルシウム(CaO)29〜33重量%、硫黄15〜19重量%で肥料成分を構成し、他の成分は、水分と不純物及び微量元素で構成されている。 Here, the mixed liquid phase of a large amount and a medium amount element of the bone meal is nitrogen (N) 2 to 4% by weight, phosphoric acid (P 2 O 5 ) 18 to 21% by weight, calcium (CaO) 27 to 30% by weight. The mixed liquid phase of the above-mentioned Kali chloride (also called calcium chloride) having a purity of 95% or more is composed of 60 to 62% by weight of calcium (CaO), and the purity is 95%. The mixed liquid phase of the above-mentioned dolomite medium elements comprises fertilizer components with calcium (CaO) 27-30 wt% and magnesium (MgO) 17-21 wt%, and the natural gypsum with a purity of 95% or more The mixed liquid phase of quantitative elements constitutes a fertilizer component with 29 to 33% by weight of calcium (CaO) and 15 to 19% by weight of sulfur, and the other components are composed of moisture, impurities and trace elements.
前記カルシウム、マグネシウム、硫黄を有する中量元素に該当する前記骨粉、卵の殻、貝類殻、塩化加里、天然石膏とドロマイトパウダーに、糖蜜と澱粉のうちのいずれかのうちの一つ以上の液相粘結材を混合して、一定時間の乾燥過程を経て、粒形態の粒状に製造する。(粒状形成段階) One or more liquids selected from the above-mentioned bone meal, egg shell, shellfish shell, chlorinated potassium, natural gypsum and dolomite powder, molasses and starch corresponding to the medium amount element having calcium, magnesium and sulfur A phase binder is mixed, and after a drying process for a certain time, it is produced into a granular form. (Granular formation stage)
このように、前記中量元素の混合粒状、即ち、粒状化された有機中量元素の粒は、その外径面に、亜麻仁油と大豆油(豆油)、桐油(桐油木の油)を含む植物油と、粘土と滑石と珪藻土と吸着シリカのパウダーのうちから選択されるいずれか一つ以上の結合体を混合したコーティング部材をコーティングして、一定の時間の間に乾燥させる。(コーティング段階) In this way, the mixed granular form of the medium element, that is, the granulated organic medium element grains include linseed oil, soybean oil (bean oil), and tung oil (oil of tung oil tree) on the outer diameter surface thereof. A coating member mixed with any one or more of a combination selected from vegetable oil, clay, talc, diatomaceous earth, and adsorbed silica powder is coated and dried for a predetermined time. (Coating stage)
一方、前述したように、粒状化していない場合、前記加水分解段階とは異なり、水に溶解させる技法を利用して、中量元素の混合液相に沈殿分離させた後、その多量元素の混合液相を含浸用個別容器に混合可能に収容し、同時にゼオライト、パーライト、蘭石のような比較的に空隙率が高い多孔質体の粒と一緒に収容して、一定の時間に高温加熱すると、前記多孔質体の空隙に高濃度の元素液相が流入され、固形状態で含浸される。(含浸段階) On the other hand, as described above, when not granulated, unlike the hydrolysis step, using a technique of dissolving in water, the precipitate is separated into a mixed liquid phase of medium elements, and then mixed with the large elements. When the liquid phase is contained in a separate container for impregnation in a mixable manner and at the same time together with relatively porous particles such as zeolite, perlite, orchid stone, and heated at a high temperature for a certain time , A high-concentration elemental liquid phase flows into the voids of the porous body and is impregnated in a solid state. (Impregnation stage)
このように、多量元素の混合液相が固形状態で含浸された多孔質体の粒、即ち、有機多量元素含浸粒は、その外径面に亜麻仁油と大豆油(豆油)、桐油(桐油木の油)を含む植物油と、粘土と滑石と珪藻土と吸着シリカのパウダーのうちから選択されるいずれか一つ以上の結合体を混合したコーティング部材をコーティングして、一定の時間の間に乾燥させる。(コーティング段階) As described above, the porous body particles impregnated with a mixed liquid phase of a large amount of elements in a solid state, that is, organic large amount element impregnated particles, are linseed oil, soybean oil (bean oil), tung oil (paulownia oil tree) on the outer diameter surface thereof. And a coating member in which any one or more of a combination selected from a powder of clay, talc, diatomaceous earth, and adsorbed silica are coated and dried for a certain period of time. . (Coating stage)
そうすると、このようにコーティングされた肥料元素粒は、水に浸かっても、前記のコーティング部材によってカルシウム、マグネシウム、硫黄の中量元素の混合肥料を漸進的で、継続的に食用植物に供給することになる。 Then, even if the fertilizer element grains coated in this way are soaked in water, a mixed fertilizer of medium elements of calcium, magnesium, and sulfur is gradually supplied to the edible plant continuously by the coating member. become.
また、窒素、リン、カリウム、カルシウム、マグネシウム、硫黄を除いた残りの微量元素は、前記ミネラル成分で構成された千枚岩と天然塩またはその粉パウダーの場合、これを水に一定時間の間、強制的交絡(混合)で溶解させる溶解段階と、前記溶解液を沈殿させ、ミネラル液相に分離させる沈殿工程と、そのミネラル液相に前記粘結材を混合し、加熱容器で一定の温度に加熱して、前記多孔質体の粒の空隙にミネラル成分を含浸させながら、乾燥させる含浸段階を経て、前記ミネラル成分が含浸された多孔質体が、前記コーティング段階で同様にコーティングされると、ミネラル緩効性肥料を完成することができる。 In addition, the remaining trace elements excluding nitrogen, phosphorus, potassium, calcium, magnesium, and sulfur are shale and natural salt or powdered powder composed of the mineral components, which are then added to water for a certain period of time. , A dissolution step for dissolving by forced entanglement (mixing), a precipitation step for precipitating the solution and separating it into a mineral liquid phase, and mixing the caking agent into the mineral liquid phase, and heating the mixture at a constant temperature. When the porous body impregnated with the mineral component is similarly coated in the coating step after the impregnation step of drying while impregnating the pores of the porous body with the mineral component, Mineral slow-release fertilizer can be completed.
ここで、前記すべてのコーティング段階は、含浸された前記多孔質体肥料粒が乾燥される前に、その露出面に澱粉と粘土、白土、珪藻土のうちのいずれか一つ以上のパウダー形状の硬化剤が一緒に被覆されるように混合することもできる。 Here, all of the coating steps may be performed by hardening any one or more powders of starch, clay, white clay, and diatomaceous earth on the exposed surface before the impregnated porous body fertilizer grains are dried. It can also be mixed so that the agents are coated together.
Claims (5)
植物油を抽出した後の残渣に該当する油粕及び魚を乾燥した魚粕を含む斃死魚もしくは血粉または乾血と、骨粉と、卵の殻と、貝類殻と、貝化石と、塩化加里と、天然石膏と、ドロマイトとを一定の時間の間に乾燥させ、表面積を最大化するために、これを個別に破砕機でパウダーに破砕させる破砕段階と、
前記卵の殻と、貝類殻と、貝化石と、天然石膏と、ドロマイトと、塩化加里を除いた物質について、破砕されたそれぞれの前記パウダーと、クエン酸または酢酸及び苛性ソーダを含む加水分解溶媒を多数の個別混合容器に収容して密閉した後、常温で一定の時間の間に加水分解の反応を誘導して、窒素、リン、カリウム(「加里」とも呼ばれる)に該当する多量元素の混合液相物質として液化させる加水分解段階と、
前記加水分解段階で液化された多量元素の混合液相物質から、一定期間の間、不純物と水分解残留物を沈殿させて、これらを除去した後、混合液のみ個別に分離させる沈殿分離段階と、
前記多量元素の混合液相物質に、人工用土であるハイドロボール、ゼオライト、パーライト、蘭石のうちいずれか一つの多孔質体の粒を加熱容器で一定時間の間加熱して、多孔質体の吸着力によって、前記多孔質体の粒の微細空隙内に向かって前記多量元素の混合物と中量元素の混合物のいずれか一つ以上を含浸させながら、個別に充填乾燥させる含浸段階と、
前記破砕段階で、カルシウム、マグネシウム、硫黄を有する中量元素に該当する前記骨粉と、卵の殻と、貝類殻と、貝化石と、天然石膏と、ドロマイトと、塩化加里のパウダーに糖蜜と澱粉のうちいずれか一つ以上の液相粘結材を混合して、個別に粒形態の粒状物質を製造する第1の粒状物質形成段階と、
前記液相粘結材によって形成された粒状物質と前記含浸された多孔質体の粒のうちのいずれか一つの外面に、亜麻仁油と大豆油(豆油)、桐油(桐油木の油)を含む植物油と、粘土と滑石と珪藻土と吸着シリカのパウダーのうちから選択されるいずれか一つ以上の結合体を混合したコーティング部材を個別にコーティングさせるコーティング段階を含み、
前記破砕段階と前記コーティング段階の間の、前記加水分解段階・沈殿分離段階及び前記第1の粒状物質形成段階と並行して製造する工程として、前記骨粉と、卵の殻と、貝類殻と、貝化石と、天然石膏と、ドロマイトと、塩化加里のパウダーから中量元素と多量元素の混合液相を個別に分離する溶解段階と、
中量元素の混合液相を前記液相粘結材と混合して個別に粒状物質に製造する第2の粒状物質形成段階とを含み、
多量元素の混合液相を含浸用個別容器に収容し、前記含浸段階において前記多孔質体に個別に充填乾燥する
ことを特徴とする有機緩効性肥料の製造方法。 In the method for producing organic slow-release fertilizer,
Dead fish or blood meal or dry blood containing fish meal that corresponds to residues after extraction of vegetable oil and dried fish meal, fish meal, bone meal, egg shell, shellfish shell, fossil shellfish, potassium chloride, natural A crushing stage in which the gypsum and dolomite are dried for a certain period of time and are individually crushed into powder with a crusher to maximize the surface area;
For each of the eggs shell, shellfish shell, shell fossil, natural gypsum , dolomite , and chlorinated substances, the crushed powder and a hydrolysis solvent containing citric acid or acetic acid and caustic soda are added. After containing and sealing in a number of individual mixing containers, a mixture of large elements corresponding to nitrogen, phosphorus and potassium (also called “Kari”) is induced by hydrolysis during a certain period of time at room temperature. A hydrolysis step to liquefy as a phase material;
A precipitation separation step of precipitating impurities and water decomposition residue for a certain period from the mixed liquid phase material liquefied in the hydrolysis step, removing these, and then separating only the mixed solution separately; ,
In the mixed liquid phase material of the above-mentioned multi-elements, the porous body particles of any one of hydroball, zeolite, pearlite, and orchid stone, which are artificial soils, are heated in a heating container for a certain time, An impregnation step of individually filling and drying while impregnating any one or more of the mixture of the multi-elements and the mixture of the medium elements into the fine voids of the particles of the porous body by adsorption force;
In the crushing step, calcium, magnesium, and the bone meal corresponding to medium heavy element having a sulfur, and egg shells, and shellfish shells, and fossil shells, and natural gypsum, dolomite and, molasses and starch powder chloride Potassium A first granular material forming step of mixing any one or more liquid phase binders to individually produce granular granular materials;
Lining oil, soybean oil (bean oil), and tung oil (paulownia oil tree oil) are included on the outer surface of any one of the particulate material formed by the liquid phase binder and the impregnated porous body grains. look-containing vegetable oil, coating step of coating individual coating member obtained by mixing one or more of the conjugates selected from among powder clay and talc and diatomaceous earth and adsorption silica,
As a process of manufacturing in parallel with the hydrolysis stage / precipitation separation stage and the first granular material forming stage between the crushing stage and the coating stage, the bone meal, egg shell, shellfish shell, A fossil shell, natural gypsum, dolomite, and a dissolution stage for individually separating a mixed liquid phase of medium and large elements from powder of potassium chloride;
A second granular material forming step of mixing a mixed liquid phase of medium amount elements with the liquid phase binder and individually producing a granular material;
A method for producing an organic slow-acting fertilizer , comprising storing a mixed liquid phase of a large amount of elements in an individual container for impregnation, and individually filling and drying the porous body in the impregnation step .
前記油粕が、パーム粕、大豆粕、菜種油粕、綿実油粕、ヒマシ油粕、米ぬか油粕、ゴマ油粕、落花生油粕のうちのいずれか一つから構成されており、前記油粕の多量元素の混合液相物質は、窒素(N)3〜15重量%、リン酸(P2O5)2〜9重量%、カリウムまたは加里(K2O)1〜3重量%の肥料成分を含み、その他の成分は、水分や不純物及び前記微量元素を含み、
前記魚粕の多量と中量元素に該当する液相物質は、窒素(N)4〜8重量%、リン酸(P2O5)6〜9重量%、カルシウム(CaO)7〜11重量%の肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含み、
前記血粉と乾血の多量元素の混合液相物質は、窒素(N)8〜12重量%、リン酸(P2O5)0.11重量%、カリウムまたは加里(K2O)0.11重量%の肥料成分を含み、その他の成分は、水分と不純物及び前記微量元素を含み、前記骨粉の多量及び中量元素の混合珪藻物質は、窒素(N)2〜4重量%、リン酸(P2O5)18〜21重量%、カルシウム(CaO)27〜30重量%の肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含み、
前記塩化加里の中量元素の混合液相物質は、カルシウム(CaO)60〜62重量%で肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含み、
前記ドロマイトの中量元素の混合液相物質は、カルシウム(CaO)27〜30重量%、マグネシウム(MgO)17〜21重量%の肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含み、前記天然石膏の中量元素の混合液相物質は、カルシウム(CaO)29〜33重量%、硫黄15〜19重量%の肥料成分を含み、その他の成分は、水分と不純物及び微量元素を含むことを特徴とする請求項1に記載の有機緩効性肥料の製造方法。 In the coating step, before the impregnated porous body fertilizer grains are dried, the exposed surface is coated with one or more powdery curing agents of clay, white clay, and diatomaceous earth. Mixing step so that
The oil cake is composed of any one of palm meal, soybean meal, rapeseed oil meal, cottonseed oil meal, castor oil meal, rice bran oil meal, sesame oil meal, peanut oil meal, and a mixed liquid phase material of a large amount of elements of the oil meal Contains 3 to 15% by weight of nitrogen (N), 2 to 9% by weight of phosphoric acid (P 2 O 5 ), 1 to 3% by weight of potassium or potassium (K 2 O), and other ingredients include It includes a moisture and impurities and the trace elements,
The liquid phase substances corresponding to large amounts and medium elements of the fish salmon are 4 to 8% by weight of nitrogen (N), 6 to 9% by weight of phosphoric acid (P 2 O 5 ), 7 to 11% by weight of calcium (CaO). The other fertilizer components contain moisture, impurities and trace elements,
The mixed liquid phase substance of blood powder and dry blood multi-elements is 8-12 wt% nitrogen (N), 0.11 wt% phosphoric acid (P 2 O 5 ), potassium or potassium (K 2 O) 0.11. The other components include moisture, impurities, and the trace elements, and the mixed diatom material of the large amount and medium amount elements of the bone meal is composed of 2 to 4% by weight of nitrogen (N), phosphoric acid ( P 2 O 5 ) 18-21% by weight, calcium (CaO) 27-30% by weight fertilizer components, other components include moisture, impurities and trace elements,
The mixed liquid phase substance of the medium element of potassium chloride contains 60 to 62% by weight of calcium (CaO) and a fertilizer component, and other components include moisture, impurities and trace elements,
The mixed liquid phase substance of the dolomite medium element contains a fertilizer component of 27 to 30% by weight of calcium (CaO) and 17 to 21% by weight of magnesium (MgO), and other components include moisture, impurities and trace elements. The mixed liquid phase substance of the medium amount element of natural gypsum includes a fertilizer component of 29 to 33% by weight of calcium (CaO) and 15 to 19% by weight of sulfur, and other components include moisture, impurities and trace elements. The manufacturing method of the organic slow release fertilizer of Claim 1 characterized by the above-mentioned.
前記溶解液を沈殿させ、ミネラル液相物質に個別に分離させる沈殿段階と、
前記ミネラル液相物質に粘結材を混合し、加熱容器から一定の温度に加熱して、前記多孔質体の粒の空隙にミネラル成分を含浸させながら、個別に乾燥させる含浸段階と、前記パウダーに前記糖蜜と澱粉のうちのいずれか一つ以上の液相粘結材を混合して、個別に粒形態の粒状物質を製造する第1の粒状物質形成段階とのうちのいずれか一つで実行する段階をさらに含み、
前記ミネラル成分が含浸された多孔質体と前記粒状物質のうちのいずれか一つが前記コーティング段階で同様に個別にコーティングされ、
前記ミネラル成分は、食用植物の必須栄養元素の12種類の窒素、リン、加里、カルシウム、マグネシウム、硫黄、鉄、マンガン、銅、ホウ素、モリブデン、亜鉛のうち、前記多量元素の窒素、リン、加里と前記中量元素のカルシウム、マグネシウム、硫黄を除いた残りの微量元素の鉄、マンガン、銅、ホウ素、モリブデン、亜鉛であることを特徴とする請求項1に記載の有機緩効性肥料の製造方法。 In the case of natural salt and shale rock composed of mineral components, or the natural salt and shale rock powder, this is mixed in water for a certain period of time and dissolved individually ,
A precipitation step of precipitating the lysate and separating it separately into mineral liquid phase materials;
An impregnation step in which a binder is mixed with the mineral liquid phase substance, heated to a certain temperature from a heating container, and impregnated with mineral components in the voids of the particles of the porous body, and individually dried; and the powder In any one of the first granular material forming steps of mixing any one or more liquid phase binders of molasses and starch and individually producing granular materials in the form of granules Further comprising performing,
Any one of the porous body impregnated with the mineral component and the particulate material are similarly coated individually in the coating step,
The mineral component includes 12 kinds of essential nutrient elements of edible plants such as nitrogen, phosphorus, potassium, calcium, magnesium, sulfur, iron, manganese, copper, boron, molybdenum, and zinc. And the remaining trace elements of iron, manganese, copper, boron, molybdenum, and zinc, excluding calcium, magnesium, and sulfur as medium elements, are produced. Method.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2014-0188706 | 2014-12-24 | ||
KR1020140188706A KR101575549B1 (en) | 2014-12-24 | 2014-12-24 | Organic fertilizer manufacturing methods |
PCT/KR2015/014241 WO2016105149A1 (en) | 2014-12-24 | 2015-12-24 | Organic-farming slow-release-fertilizer production method |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2018503590A JP2018503590A (en) | 2018-02-08 |
JP6410120B2 true JP6410120B2 (en) | 2018-10-24 |
Family
ID=54872595
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017533330A Expired - Fee Related JP6410120B2 (en) | 2014-12-24 | 2015-12-24 | Method for producing organic slow-release fertilizer |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP6410120B2 (en) |
KR (1) | KR101575549B1 (en) |
CN (1) | CN107001168A (en) |
WO (1) | WO2016105149A1 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101575549B1 (en) * | 2014-12-24 | 2015-12-07 | 영 성 왕 | Organic fertilizer manufacturing methods |
CN105601454B (en) * | 2015-12-29 | 2019-08-16 | 山西师范大学 | The preparation method of granular chemical fertilizer |
KR101839679B1 (en) * | 2016-05-17 | 2018-03-19 | 영 성 왕 | pack filling balance fertilizer having continuative supply function on growth period |
KR101857502B1 (en) * | 2016-10-20 | 2018-06-19 | 한국수자원공사 | The manufacturing method of the organic fertilizer with the fish |
KR101992526B1 (en) * | 2017-03-14 | 2019-10-01 | 영 성 왕 | Organic fertilizer manufacturing methods |
KR102067078B1 (en) * | 2019-04-09 | 2020-01-16 | 장현택 | Slow release fertilizer using dolomite and manufacturing method thereof |
KR102099253B1 (en) | 2019-04-09 | 2020-04-09 | 이중근 | manufacturing method of liquid fertilizer using natural pozzolan |
KR102144829B1 (en) * | 2019-08-27 | 2020-08-14 | 이희수 | Soil Conditioner For Wild Simulated Ginseng And Fertilization Method Thereof |
CN112028711A (en) * | 2020-09-10 | 2020-12-04 | 荆州市保平环保科技有限公司 | Organic fertilizer and preparation method thereof |
CN113237875A (en) * | 2021-04-27 | 2021-08-10 | 安徽省产品质量监督检验研究院(国家排灌及节水设备产品质量监督检验中心) | Detection method for rapidly detecting beta-stimulant and paper-based immunosensor |
KR102402745B1 (en) * | 2021-05-18 | 2022-05-30 | 농업회사법인 주식회사 친환경유기농사관학교 | Organic Fertilizer Manufacturing Method Added With Photosynthetic Bacteria And Its Medium, And Organic Fertilizer Produced By The Manufacturing Method |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5551786A (en) * | 1978-10-11 | 1980-04-15 | Ueda Setsukai Seizou Kk | Granular magnesia fertilizer and its manufacture |
JPS6136187A (en) * | 1984-07-26 | 1986-02-20 | 昭和電工株式会社 | Perlite composite body |
JPS62114696A (en) * | 1985-11-12 | 1987-05-26 | Kenya Otomo | Preparation of mineral active water |
JPH02188484A (en) * | 1989-01-13 | 1990-07-24 | Taki Chem Co Ltd | Production of liquid fertilizer |
JPH05874A (en) * | 1991-02-01 | 1993-01-08 | Nippon Hiryo Kk | Plant growth promoter its production and manure containing the same |
JPH06240254A (en) * | 1993-02-12 | 1994-08-30 | Obara Yasunori | Production of soil activator from plant resources |
KR970069954A (en) * | 1996-04-22 | 1997-11-07 | 송미영 | Matrix-type solid form fertilizer and method for producing the same |
CN1176953A (en) * | 1996-06-26 | 1998-03-25 | 辛益群 | Magnet activated bacleria, full element, and multi-effect fertilizer series, and method for producing same |
CN1196341A (en) * | 1996-12-24 | 1998-10-21 | 匡永成 | Complete compound fertilizer series products and complete producing technology |
CN1207380A (en) * | 1997-08-04 | 1999-02-10 | 汤洁 | Method for preparing functional compound liquid fertilizer using marine living things |
US6039781A (en) * | 1998-06-09 | 2000-03-21 | Oms Investments, Inc. | Precoated controlled release fertilizers and processes for their preparation |
JP2001192286A (en) * | 2000-01-05 | 2001-07-17 | Hidemichi Hirata | Method for manufacturing organic fertilizer |
KR100406171B1 (en) * | 2000-11-24 | 2003-11-17 | (주)바이오넬 | Preparation methods of amino acids from dry blood powder |
KR20060094297A (en) * | 2005-02-24 | 2006-08-29 | 양한춘 | Calcium composite fertilizer |
JP2010057363A (en) * | 2006-12-25 | 2010-03-18 | Saihatsu Ko | Microorganism-containing composition for saccharifying biomass |
JP2010202482A (en) * | 2009-03-06 | 2010-09-16 | Central Glass Co Ltd | Coated granular fertilizer and method of manufacturing the same |
KR101132712B1 (en) * | 2009-09-25 | 2012-04-06 | 윤채혁 | Environment-friendly organic agricultural products for soil insect pest control |
CN101696132B (en) * | 2009-10-27 | 2012-05-23 | 黄玉霖 | Multi-mineral organic nutrient fertilizer and preparation method thereof |
CN102603388B (en) * | 2012-03-20 | 2014-09-03 | 昆明理工大学 | Method for preparing slow-release compound fertilizer |
KR101374264B1 (en) | 2013-11-14 | 2014-03-25 | 김기면 | Composition for conditioning soil or promoting plant growth comprising inorganic sludge and method for producing thefeof |
KR101575549B1 (en) * | 2014-12-24 | 2015-12-07 | 영 성 왕 | Organic fertilizer manufacturing methods |
-
2014
- 2014-12-24 KR KR1020140188706A patent/KR101575549B1/en active IP Right Grant
-
2015
- 2015-12-24 CN CN201580065933.1A patent/CN107001168A/en active Pending
- 2015-12-24 WO PCT/KR2015/014241 patent/WO2016105149A1/en active Application Filing
- 2015-12-24 JP JP2017533330A patent/JP6410120B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2018503590A (en) | 2018-02-08 |
WO2016105149A1 (en) | 2016-06-30 |
CN107001168A (en) | 2017-08-01 |
KR101575549B1 (en) | 2015-12-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6410120B2 (en) | Method for producing organic slow-release fertilizer | |
KR101682768B1 (en) | Organic slow release fertilizer manufacturing methods | |
Loh et al. | Enhancement of palm oil refinery waste–Spent bleaching earth (SBE) into bio organic fertilizer and their effects on crop biomass growth | |
CN104671435B (en) | A kind of environmentally friendly breeding water body slow release oxygenation agent | |
CN106278769A (en) | A kind of aquaculture nutrition slow-release agent and preparation method thereof | |
RU2745119C2 (en) | Organic slow release fertilizer based on plantain seed coats and method of manufacture thereof | |
CA3013588A1 (en) | Biochar aggregate particles | |
CN102320874A (en) | A kind of preparation method of organic fertilizer | |
WO2012070955A1 (en) | Fertiliser | |
KR101839679B1 (en) | pack filling balance fertilizer having continuative supply function on growth period | |
RU2351576C1 (en) | Organomineral fertiliser (versions) | |
RU2535147C1 (en) | Method of obtaining organo-mineral fertilizings | |
CN105110916A (en) | Moisture-preserving and fertilizer-retaining nutritional soil for mechanized rice seedling transplanting and preparation method therefor | |
CN104447135A (en) | Method for preparing biological carbon-based controlled release fertilizer by macadamia nut shells/macadamia nut shells | |
KR100864218B1 (en) | a manufacturing technique method of vermiculite | |
CN110958997A (en) | A method for preparing bioactive soil and horticultural medium rich in nutrients and having predetermined characteristics | |
CA3013049A1 (en) | Biochars for use with animals | |
RU2505512C1 (en) | Method of production of humus-containing component of organo-mineral fertilisers and soil substrates | |
KR20240015249A (en) | Organic fertilizer manufacturing methods | |
JP2011037663A (en) | Fertilizer containing poultry manure and production method for the same | |
JP2012066957A (en) | Method of producing fertilizer using earthworm casting soil | |
PL210311B1 (en) | Method of obtaining the fertilizers from the sediments produced in biological sewage treatment plants | |
WO2020055345A1 (en) | Ecological life system regulator | |
CN103626607A (en) | High-concentration fertilizer and preparation method thereof | |
KR102677987B1 (en) | A method of manufacturing a functional fertilizer using blood from slaughtered animals and a functional fertilizer manufactured therethrough |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180426 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180515 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180730 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20180814 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20180912 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6410120 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |