JP5776293B2 - Harmful arthropod control composition and harmful arthropod control method - Google Patents
Harmful arthropod control composition and harmful arthropod control method Download PDFInfo
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- WXDDNHNGYQMETB-UHFFFAOYSA-N Cc1cc(C(N(C)NC(c2cccc(OC)c2C)=O)=O)cc(C)c1 Chemical compound Cc1cc(C(N(C)NC(c2cccc(OC)c2C)=O)=O)cc(C)c1 WXDDNHNGYQMETB-UHFFFAOYSA-N 0.000 description 1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-nitrogen bonds, e.g. azides, diazo-amino compounds, diazonium compounds, hydrazine derivatives
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
- A01N37/24—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides containing at least one oxygen or sulfur atom being directly attached to the same aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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Description
本発明は、有害節足動物防除組成物及び有害節足動物の防除方法に関するものである。 The present invention relates to a harmful arthropod control composition and a method for controlling harmful arthropods.
従来、有害節足動物防除組成物の有効成分として、多くの化合物が知られている（例えば、非特許文献１参照）。
メトキシフェノジド、
は、いずれもＮ−（１，１−ジメチルエチル）−Ｎ’−アリールカルボニル−３，５−ジメチルベンゾヒドラジド構造を有し、かつエクダイソン受容体アゴニスト作用により昆虫の変態や脱皮を促進して殺虫活性を示す昆虫成長制御化合物として知られている。
Conventionally, many compounds are known as an active ingredient of the harmful arthropod control composition (for example, refer nonpatent literature 1).
Methoxyphenozide,
All have an N- (1,1-dimethylethyl) -N′-arylcarbonyl-3,5-dimethylbenzohydrazide structure and promote insect transformation and molting by ecdysone receptor agonistic action to kill insects It is known as an insect growth control compound that exhibits activity.
本発明は、有害節足動物に対する優れた防除効力を有する有害節足動物防除組成物を提供することを課題とする。 An object of the present invention is to provide a harmful arthropod control composition having an excellent control effect on harmful arthropods.
本発明者等は、有害節足動物に対する優れた防除効力を有する有害節足動物防除組成物を見出すべく検討した結果、下記式（１）で示されるシアナミド化合物と、下記群（Ａ）より選ばれる１種以上の昆虫成長制御化合物と、下記群（Ｂ）より選ばれる１種以上の紋枯病防除化合物とを含有する組成物が、有害節足動物に対する優れた防除効力を有することを見出し、本発明に到った。
すなわち、本発明とは以下の［１］〜［６］のものである。
［１］ 式（１）
群（Ａ）：メトキシフェノジド、クロマフェノジド及びテブフェノジドからなる群。
群（Ｂ）：フルトラニル、ペンシクロン、Ｎ−［２−（１，３−ジメチルブチル）フェニル］−５−フルオロ−１，３−ジメチル−１Ｈ−ピラゾール−４−カルボキサミド、フラメトピル及びバリダマイシンＡからなる群。
［２］ シアナミド化合物と、昆虫成長制御化合物との重量比が、５０：１〜１：５０である［１］記載の有害節足動物防除組成物。
［３］ シアナミド化合物と、紋枯病防除化合物との重量比が、５０：１〜１：１００である［２］記載の有害節足動物防除組成物。
［４］ 紋枯病防除化合物が、フルトラニル、ペンシクロン又はＮ−［２−（１，３−ジメチルブチル）フェニル］−５−フルオロ−１，３−ジメチル−１Ｈ−ピラゾール−４−カルボキサミドである［１］〜［３］いずれか一項記載の有害節足動物防除組成物。
［５］ ［１］〜［４］いずれか一項記載の有害節足動物防除組成物の有効量を、植物又は植物の栽培地に施用する工程を含む有害節足動物の防除方法。
［６］ 植物又は植物の栽培地が、イネ又はイネの栽培地である［５］記載の有害節足動物の防除方法。
As a result of studies to find a harmful arthropod control composition having an excellent control effect on harmful arthropods, the present inventors have selected a cyanamide compound represented by the following formula (1) and the following group (A): And a composition containing one or more insect growth control compounds selected from the following group (B) and having an excellent control effect against harmful arthropods. The present invention has been reached.
That is, the present invention includes the following [1] to [6].
[1] Formula (1)
Group (A): A group consisting of methoxyphenozide, chromafenozide and tebufenozide.
Group (B): Group consisting of flutolanil, pencyclone, N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, flametopyr and validamycin A .
[2] The harmful arthropod control composition according to [1], wherein the weight ratio of the cyanamide compound and the insect growth control compound is 50: 1 to 1:50.
[3] The harmful arthropod control composition according to [2], wherein the weight ratio of the cyanamide compound and the blight control compound is 50: 1 to 1: 100.
[4] The blight control compound is flutolanil, pencyclon, or N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide. [1] The harmful arthropod control composition according to any one of [1] to [3].
[5] A method for controlling harmful arthropods, comprising a step of applying an effective amount of the harmful arthropod control composition according to any one of [1] to [4] to a plant or a planting site of the plant.
[6] The method for controlling harmful arthropods according to [5], wherein the plant or planting place is rice or rice growing place.
本発明により、有害節足動物を防除することができる。 According to the present invention, harmful arthropods can be controlled.
本発明の有害節足動物防除組成物とは、下記式（１）で示されるシアナミド化合物（以下、本シアナミド化合物と記す場合がある。）と、下記群（Ａ）より選ばれる１種以上の昆虫成長制御化合物（以下、本昆虫成長制御化合物と記す場合がある。）と、下記群（Ｂ）より選ばれる１種以上の紋枯病防除化合物（以下、本紋枯病防除化合物と記す場合がある。）とを含有するものである。
群（Ｂ）：フルトラニル、ペンシクロン、Ｎ−［２−（１，３−ジメチルブチル）フェニル］−５−フルオロ−１，３−ジメチル−１Ｈ−ピラゾール−４−カルボキサミド、フラメトピル及びバリダマイシンＡからなる群。
The harmful arthropod control composition of the present invention is a cyanamide compound represented by the following formula (1) (hereinafter sometimes referred to as the present cyanamide compound) and one or more selected from the following group (A). Insect growth control compound (hereinafter may be referred to as the present insect growth control compound) and one or more blight control compounds selected from the following group (B) (hereinafter referred to as the present blight control compound) Is included).
Group (B): Group consisting of flutolanil, pencyclone, N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, flametopyr and validamycin A .
本発明に用いられるシアナミド化合物は公知の化合物であり、たとえば国際公開第２００７／０９５２２９号パンフレットに記載された方法で製造することができる。 The cyanamide compound used for this invention is a well-known compound, for example, can be manufactured by the method described in the international publication 2007/095229 pamphlet.
また、本発明に用いられるメトキシフェノジド、クロマフェノジド、テブフェノジド、フルトラニル、ペンシクロン、フラメトピル及びバリダマイシンＡはいずれも公知の化合物であり、例えば「 Ｔｈｅ Ｐｅｓｔｉｃｉｄｅ Ｍａｎｕａｌ−１５ｔｈ ｅｄｉｔｉｏｎ（ＢＣＰＣ刊）；ＩＳＢＮ ９７８−１−９０１３９６−１８−８ 」の７６４、２１１、１０７４、５５９、８７１、５８０及び１１８７ページ等に記載されている。これらの化合物は市販の製剤から得るか、公知の方法で製造することにより得られる。
本発明に用いられるＮ−［２−（１，３−ジメチルブチル）フェニル］−５−フルオロ−１，３−ジメチル−１Ｈ−ピラゾール−４−カルボキサミド（以下、本活性化合物（Ｉ）と記す。）は公知の化合物であり、例えば国際公開第２００３／０１０１４９号パンフレットに記載された方法で製造することができる。
Further, methoxyphenozide, chromafenozide, tebufenozide, flutolanil, pencyclon, furametopyl, and validamycin A used in the present invention are all known compounds, such as “The Pesticide Manual-15th edition (published by BCPC); ISBN 978-1-901396; 18-8 ", pages 764, 211, 1074, 559, 871, 580 and 1187. These compounds are obtained from commercially available preparations or can be obtained by producing them by known methods.
N- [2- (1,3-dimethylbutyl) phenyl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide (hereinafter referred to as the active compound (I)) used in the present invention. ) Is a known compound and can be produced, for example, by the method described in International Publication No. 2003/010149.
本発明の有害節足動物防除組成物における、本シアナミド化合物と本昆虫成長制御化合物と本紋枯病防除化合物との含有割合は、特に限定されるものではないが、本シアナミド化合物１００重量部に対して、本昆虫成長制御化合物が、通常０．２〜５００００重量部、好ましくは２〜５０００重量部であり、本紋枯病防除化合物が、通常０．２〜１０００００重量部、好ましくは２〜１００００重量部である。 In the harmful arthropod control composition of the present invention, the content ratio of the present cyanamide compound, the present insect growth control compound, and the main blight control compound is not particularly limited, but is 100 parts by weight of the present cyanamide compound. On the other hand, the present insect growth control compound is usually 0.2 to 50000 parts by weight, preferably 2 to 5000 parts by weight, and the main blight control compound is usually 0.2 to 100000 parts by weight, preferably 2 to 10,000 parts by weight.
本発明の有害節足動物防除組成物は、本シアナミド化合物と本昆虫成長制御化合物と本紋枯病防除化合物とを単に混合したものでもよいが、通常は、本シアナミド化合物、本昆虫成長制御化合物及び本紋枯病防除化合物と不活性担体とを混合し、必要に応じて界面活性剤やその他の製剤用補助剤を添加して、油剤、乳剤、フロアブル剤、水和剤、顆粒水和剤、粉剤、粒剤等に製剤化されたものが用いられる。
また、前記の製剤化された有害節足動物防除組成物は、そのまま又はその他の不活性成分を添加して有害節足動物防除剤として使用することができる。
本発明の有害節足動物防除組成物における、本シアナミド化合物、本昆虫成長制御化合物及び本紋枯病防除化合物の合計量は、通常０．０１〜９９重量％、好ましくは０．１〜９０重量％の範囲、さらに好ましくは０．５〜７０重量％の範囲である。
The harmful arthropod control composition of the present invention may be a mixture of the present cyanamide compound, the present insect growth control compound, and the present blight control compound, but usually the present cyanamide compound and the present insect growth control compound. In addition, a compound for controlling blight of this coat and an inert carrier is added, and if necessary, surfactants and other formulation adjuvants are added to obtain oils, emulsions, flowables, wettable powders, and granular wettable powders. , Powders, granules and the like are used.
Moreover, the above-mentioned formulated harmful arthropod control composition can be used as a harmful arthropod control agent as it is or by adding other inactive ingredients.
In the harmful arthropod control composition of the present invention, the total amount of the present cyanamide compound, the present insect growth control compound and the main blight control compound is usually 0.01 to 99% by weight, preferably 0.1 to 90% by weight. %, More preferably 0.5 to 70% by weight.
製剤化の際に用いられる固体担体としては、例えばカオリンクレー、アッタパルジャイトクレー、ベントナイト、モンモリロナイト、酸性白土、パイロフィライト、タルク、珪藻土、方解石等の鉱物、トウモロコシ穂軸粉、クルミ殻粉等の天然有機物、尿素等の合成有機物、炭酸カルシウム、硫酸アンモニウム等の塩類、合成含水酸化珪素等の合成無機物等からなる微粉末あるいは粒状物等が挙げられ、液体担体としては、例えばキシレン、アルキルベンゼン、メチルナフタレン等の芳香族炭化水素類、２−プロパノール、エチレングリコール、プロピレングリコール、エチレングリコールモノエチルエーテル等のアルコール類、アセトン、シクロヘキサノン、イソホロン等のケトン類、ダイズ油、綿実油等の植物油、石油系脂肪族炭化水素類、エステル類、ジメチルスルホキシド、アセトニトリル及び水が挙げられる。
界面活性剤としては、例えばアルキル硫酸エステル塩、アルキルアリールスルホン酸塩、ジアルキルスルホコハク酸塩、ポリオキシエチレンアルキルアリールエーテルリン酸エステル塩、リグニンスルホン酸塩、ナフタレンスルホネートホルムアルデヒド重縮合物等の陰イオン界面活性剤及びポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンアルキルポリオキシプロピレンブロックコポリマー、ソルビタン脂肪酸エステル等の非イオン界面活性剤、及びアルキルトリメチルアンモニウム塩等の陽イオン界面活性剤が挙げられる。
その他の製剤用補助剤としては、例えばポリビニルアルコール、ポリビニルピロリドン等の水溶性高分子、アラビアガム、アルギン酸及びその塩、ＣＭＣ（カルボキシメチルセルロ−ス）、ザンサンガム等の多糖類、アルミニウムマグネシウムシリケート、アルミナゾル等の無機物、防腐剤、着色剤及びＰＡＰ（酸性リン酸イソプロピル）、ＢＨＴ等の安定化剤が挙げられる。
Examples of solid carriers used in formulation include kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite, talc, diatomaceous earth, calcite, corn cob flour, walnut shell powder, etc. Natural organic materials, synthetic organic materials such as urea, salts such as calcium carbonate and ammonium sulfate, fine powders or granular materials made of synthetic inorganic materials such as synthetic silicon hydroxide, etc., and liquid carriers include, for example, xylene, alkylbenzene, methyl Aromatic hydrocarbons such as naphthalene, alcohols such as 2-propanol, ethylene glycol, propylene glycol and ethylene glycol monoethyl ether, ketones such as acetone, cyclohexanone and isophorone, vegetable oils such as soybean oil and cottonseed oil, petroleum fats Group hydrocarbon , Esters, dimethyl sulfoxide, acetonitrile and water.
Examples of surfactants include anionic interfaces such as alkyl sulfate esters, alkylaryl sulfonates, dialkyl sulfosuccinates, polyoxyethylene alkylaryl ether phosphate esters, lignin sulfonates, naphthalene sulfonate formaldehyde polycondensates, and the like. Nonionic surfactants such as activators and polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl polyoxypropylene block copolymers, sorbitan fatty acid esters, and cationic surfactants such as alkyltrimethylammonium salts.
Examples of other adjuvants for preparation include water-soluble polymers such as polyvinyl alcohol and polyvinyl pyrrolidone, gum arabic, alginic acid and salts thereof, polysaccharides such as CMC (carboxymethyl cellulose) and xanthan gum, aluminum magnesium silicate, alumina sol Inorganic substances such as preservatives, colorants and stabilizers such as PAP (isopropyl acid phosphate) and BHT.
本発明の有害節足動物防除組成物は、植物に対して摂食、吸汁等の加害を行う有害節足動物による加害から植物を保護するために用いることができる。 The harmful arthropod control composition of the present invention can be used to protect a plant from harm by a harmful arthropod that causes feeding, sucking or the like to the plant.
本発明の有害節足動物防除組成物が防除効力を有する有害節足動物としては、例えば次のものが挙げられる。 Examples of the harmful arthropods having the controlling effect of the harmful arthropod control composition of the present invention include the following.
半翅目害虫：ヒメトビウンカ（Ｌａｏｄｅｌｐｈａｘ ｓｔｒｉａｔｅｌｌｕｓ）、トビイロウンカ（Ｎｉｌａｐａｒｖａｔａ ｌｕｇｅｎｓ）、セジロウンカ（Ｓｏｇａｔｅｌｌａ ｆｕｒｃｉｆｅｒａ）等のウンカ類、ツマグロヨコバイ（Ｎｅｐｈｏｔｅｔｔｉｘ ｃｉｎｃｔｉｃｅｐｓ）、タイワンツマグロヨコバイ（Ｎｅｐｈｏｔｅｔｔｉｘ ｖｉｒｅｓｃｅｎｓ）、イナズマヨコバイ（Ｒｅｃｉｌｉａ ｄｏｒｓａｌｉｓ）、チャノミドリヒメヨコバイ（Ｅｍｐｏａｓｃａ ｏｎｕｋｉｉ）等のヨコバイ類、ワタアブラムシ（Ａｐｈｉｓ ｇｏｓｓｙｐｉｉ）、モモアカアブラムシ（Ｍｙｚｕｓ ｐｅｒｓｉｃａｅ）、ダイコンアブラムシ（Ｂｒｅｖｉｃｏｒｙｎｅ ｂｒａｓｓｉｃａｅ）、ユキヤナギアブラムシ（Ａｐｈｉｓ ｓｐｉｒａｅｃｏｌａ）、チューリップヒゲナガアブラムシ（Ｍａｃｒｏｓｉｐｈｕｍ ｅｕｐｈｏｒｂｉａｅ）、ジャガイモヒゲナガアブラムシ（Ａｕｌａｃｏｒｔｈｕｍ ｓｏｌａｎｉ）、ムギクビレアブラムシ（Ｒｈｏｐａｌｏｓｉｐｈｕｍ ｐａｄｉ）、ミカンクロアブラムシ（Ｔｏｘｏｐｔｅｒａ ｃｉｔｒｉｃｉｄｕｓ）、モモコフキアブラムシ（Ｈｙａｌｏｐｔｅｒｕｓ ｐｒｕｎｉ）、リンゴワタムシ（Ｅｒｉｏｓｏｍａ ｌａｎｉｇｅｒｕｍ）等のアブラムシ類、アオクサカメムシ（Ｎｅｚａｒａ ａｎｔｅｎｎａｔａ）、アカヒゲホソミドリカスミカメ（Ｔｒｉｇｏｎｏｔｙｌｕｓ ｃａｅｌｅｓｔｉａｌｉｕｍ）、アカスジカメムシ（Ｇｒａｐｈｏｓｏｍａ ｒｕｂｒｏｌｉｎｅａｔｕｍ）、オオトゲシラホシカメムシ（Ｅｙｓａｒｃｏｒｉｓ ｌｅｗｉｓｉ）、ホソハリカメムシ（Ｒｉｐｔｏｒｔｕｓ ｃｌａｖｅｔｕｓ）、クモヘリカメムシ（Ｌｅｐｔｏｃｏｒｉｓａ ｃｈｉｎｅｎｓｉｓ）、トゲシラホシカメムシ（Ｅｙｓａｒｃｏｒｉｓ ｐａｒｖｕｓ）、クサギカメムシ（Ｈａｌｙｏｍｏｒｐｈａ ｍｉｓｔａ）、ミナミアオカメムシ（Ｎｅｚａｒａ ｖｉｒｉｄｕｌａ）、ターニシュトプラントバグ（Lｙｇuｓ ｌｉｎｅｏｌａｒｉｓ）等のカメムシ類、オンシツコナジラミ（Ｔｒｉａｌｅｕｒｏｄｅｓ ｖａｐｏｒａｒｉｏｒｕｍ）、タバココナジラミ（Ｂｅｍｉｓｉａ ｔａｂａｃｉ）、ミカンコナジラミ（Ｄｉａｌｅｕｒｏｄｅｓ ｃｉｔｒｉ）、ミカントゲコナジラミ（Ａｌｅｕｒｏｃａｎｔｈｕｓ ｓｐｉｎｉｆｅｒｕｓ）等のコナジラミ類、アカマルカイガラムシ（Ａｏｎｉｄｉｅｌｌａ ａｕｒａｎｔｉｉ）、サンホーゼカイガラムシ（Ｃｏｍｓｔｏｃｋａｓｐｉｓ ｐｅｒｎｉｃｉｏｓａ）、シトラススノースケール（Ｕｎａｓｐｉｓ ｃｉｔｒｉ）、ルビーロウムシ（Ｃｅｒｏｐｌａｓｔｅｓ ｒｕｂｅｎｓ）、イセリヤカイガラムシ（Ｉｃｅｒｙａ ｐｕｒｃｈａｓｉ）、フジコナカイガラムシ（Ｐｌａｎｏｃｏｃｃｕｓ ｋｒａｕｎｈｉａｅ）、クワコナカイガラムシ（Ｐｓｅｕｄｏｃｏｃｃｕｓ ｌｏｎｇｉｓｐｉｎｉｓ）、クワシロカイガラムシ（Ｐｓｅｕｄａｕｌａｃａｓｐｉｓ ｐｅｎｔａｇｏｎａ）等のカイガラムシ類、グンバイムシ類、トコジラミ（Ｃｉｍｅｘ ｌｅｃｔｕｌａｒｉｕｓ）等のトコジラミ類、ペアシラ（Ｃａｃｏｐｓｙｌｌａ ｐｙｒｉｃｏｌａ）等のキジラミ類等。
鱗翅目害虫：ニカメイガ（Ｃｈｉｌｏ ｓｕｐｐｒｅｓｓａｌｉｓ）、サンカメイガ（Ｔｒｙｐｏｒｙｚａ ｉｎｃｅｒｔｕｌａｓ）、コブノメイガ（Ｃｎａｐｈａｌｏｃｒｏｃｉｓ ｍｅｄｉｎａｌｉｓ）、ワタノメイガ（Ｎｏｔａｒｃｈａ ｄｅｒｏｇａｔａ）、ノシメマダラメイガ（Ｐｌｏｄｉａ ｉｎｔｅｒｐｕｎｃｔｅｌｌａ）、アワノメイガ（Ｏｓｔｒｉｎｉａ ｆｕｒｎａｃａｌｉｓ）、ハイマダラノメイガ（Ｈｅｌｌｕｌａ ｕｎｄａｌｉｓ）、シバツトガ（Ｐｅｄｉａｓｉａ ｔｅｔｅｒｒｅｌｌｕｓ）等のメイガ類、ハスモンヨトウ（Ｓｐｏｄｏｐｔｅｒａ ｌｉｔｕｒａ）、シロイチモジヨトウ（Ｓｐｏｄｏｐｔｅｒａ ｅｘｉｇｕａ）、アワヨトウ（Ｐｓｅｕｄａｌｅｔｉａ ｓｅｐａｒａｔａ）、イネヨトウ（Ｓｅｓａｍｉａ ｉｎｆｅｒｅｎｓ）、ヨトウガ（Ｍａｍｅｓｔｒａ ｂｒａｓｓｉｃａｅ）、タマナヤガ（Ａｇｒｏｔｉｓ ｉｐｓｉｌｏｎ），タマナギンウワバ（Ｐｌｕｓｉａ ｎｉｇｒｉｓｉｇｎａ）、イラクサギンウワバ（Ｔｒｉｃｈｏｐｌｕｓｉａ ｎi）、トリコプルシア属、ヘリオティス属、ヘリコベルパ属等のヤガ類、モンシロチョウ（Ｐｉｅｒｉｓ ｒａｐａｅ）等のシロチョウ類、アドキソフィエス属、ナシヒメシンクイ（Ｇｒａｐｈｏｌｉｔａ ｍｏｌｅｓｔａ）、マメシンクイガ（Ｌｅｇｕｍｉｎｉｖｏｒａ ｇｌｙｃｉｎｉｖｏｒｅｌｌａ），アズキサヤムシガ（Ｍａｔｓｕｍｕｒａｅｓｅｓ ａｚｕｋｉｖｏｒａ）、リンゴコカクモンハマキ（Ａｄｏｘｏｐｈｙｅｓ ｏｒａｎａ ｆａｓｃｉａｔａ）、チャノコカクモンハマキ（Ａｄｏｘｏｐｈｙｅｓ ｈｏｎｍａｉ）、チャハマキ（Ｈｏｍｏｎａ ｍａｇｎａｎｉｍａ）、ミダレカクモンハマキ（Ａｒｃｈｉｐｓ ｆｕｓｃｏｃｕｐｒｅａｎｕｓ）、コドリンガ（Ｃｙｄｉａ ｐｏｍｏｎｅｌｌａ）等のハマキガ類、チャノホソガ（Ｃａｌｏｐｔｉｌｉａ ｔｈｅｉｖｏｒａ）、キンモンホソガ（Ｐｈｙｌｌｏｎｏｒｙｃｔｅｒ ｒｉｎｇｏｎｅｅｌｌａ）のホソガ類、モモシンクイガ（Ｃａｒｐｏｓｉｎａ ｎｉｐｏｎｅｎｓｉｓ）等のシンクイガ類、リオネティア属等のハモグリガ類、リマントリア属、ユープロクティス属等のドクガ類、コナガ（Ｐｌｕｔｅｌｌａ ｘｙｌｏｓｔｅｌｌａ）等のスガ類、ワタアカミムシ（Ｐｅｃｔｉｎｏｐｈｏｒａ ｇｏｓｓｙｐｉｅｌｌａ）ジャガイモガ（Ｐｈｔｈｏｒｉｍａｅａ ｏｐｅｒｃｕｌｅｌｌａ）等のキバガ類、アメリカシロヒトリ（Ｈｙｐｈａｎｔｒｉａ ｃｕｎｅａ）等のヒトリガ類、イガ（Ｔｉｎｅａ ｔｒａｎｓｌｕｃｅｎｓ）、コイガ（Ｔｉｎｅｏｌａ ｂｉｓｓｅｌｌｉｅｌｌａ）等のヒロズコガ類、トゥタアブソリュータ（Ｔｕｔａ ａｂｓｏｌｕｔａ）等。
アザミウマ目害虫：ミカンキイロアザミウマ（Ｆｒａｎｋｌｉｎｉｅｌｌａ ｏｃｃｉｄｅｎｔａｌｉｓ）、ミナミキイロアザミウマ（Ｔｈｒｉｐｓ ｐａｒｍｉ）、チャノキイロアザミウマ（Ｓｃｉｒｔｏｔｈｒｉｐｓ ｄｏｒｓａｌｉｓ）、ネギアザミウマ（Ｔｈｒｉｐｓ ｔａｂａｃｉ）、ヒラズハナアザミウマ（Ｆｒａｎｋｌｉｎｉｅｌｌａ ｉｎｔｏｎｓａ）、タバコアザミウマ（Ｆｒａｎｋｌｉｎｉｅｌｌａ ｆｕｓｃａ）、オニオンスリップス（Ｔｈｒｉｐｓ ｔａｂａｃｉ）、イネアザミウマ（Ｓｔｅｎｃｈａｅｔｏｔｈｒｉｐｓ ｂｉｆｏｒｍｉｓ）、イネクダアザミウマ（Ｈａｐｌｏｔｈｒｉｐｓ ａｃｕｌｅａｔｕｓ）等のアザミウマ類等；
双翅目害虫：タマネギバエ（Ｈｙｌｅｍｙａ ａｎｔｉｑｕａ）、タネバエ（Ｈｙｌｅｍｙａ ｐｌａｔｕｒａ）、イネハモグリバエ（Ａｇｒｏｍｙｚａ ｏｒｙｚａｅ）、イネヒメハモグリバエ（Ｈｙｄｒｅｌｌｉａ ｇｒｉｓｅｏｌａ）、イネキモグリバエ（Ｃｈｌｏｒｏｐｓ ｏｒｙｚａｅ）、マメハモグリバエ（Ｌｉｒｉｏｍｙｚａ ｔｒｉｆｏｌｉｉ）等のハモグリバエ類、ウリミバエ（Ｄａｃｕｓ ｃｕｃｕｒｂｉｔａｅ）、チチュウカイミバエ（Ｃｅｒａｔｉｔｉｓ ｃａｐｉｔａｔａ）等；
甲虫目害虫：ニジュウヤホシテントウ（Ｅｐｉｌａｃｈｎａ ｖｉｇｉｎｔｉｏｃｔｏｐｕｎｃｔａｔａ）、ウリハムシ（Ａｕｌａｃｏｐｈｏｒａ ｆｅｍｏｒａｌｉｓ）、キスジノミハムシ（Ｐｈｙｌｌｏｔｒｅｔａ ｓｔｒｉｏｌａｔａ）、イネドロオイムシ（Ｏｕｌｅｍａ ｏｒｙｚａｅ）、イネゾウムシ（Ｅｃｈｉｎｏｃｎｅｍｕｓ ｓｑｕａｍｅｕｓ）、イネミズゾウムシ（Ｌｉｓｓｏｒｈｏｐｔｒｕｓ ｏｒｙｚｏｐｈｉｌｕｓ）、ワタミゾウムシ（Ａｎｔｈｏｎｏｍｕｓ ｇｒａｎｄｉｓ）、アズキゾウムシ（Ｃａｌｌｏｓｏｂｒｕｃｈｕｓ ｃｈｉｎｅｎｓｉｓ）、シバオサゾウムシ（Ｓｐｈｅｎｏｐｈｏｒｕｓ ｖｅｎａｔｕｓ）、マメコガネ（Ｐｏｐｉｌｌｉａ ｊａｐｏｎｉｃａ）、ドウガネブイブイ（Ａｎｏｍａｌａ ｃｕｐｒｅａ）、コーンルートワームの仲間（Ｄｉａｂｒｏｔｉｃａ ｓｐｐ.）、コロラドハムシ（Ｌｅｐｔｉｎｏｔａｒｓａ ｄｅｃｅｍｌｉｎｅａｔａ）、コメツキムシの仲間（Ａｇｒｉｏｔｅｓ ｓｐｐ.）、タバコシバンムシ（Ｌａｓｉｏｄｅｒｍａ ｓｅｒｒｉｃｏｒｎｅ）等；
直翅目害虫：ケラ（Ｇｒｙｌｌｏｔａｌｐａ ａｆｒｉｃａｎａ）、コバネイナゴ（Ｏｘｙａ ｙｅｚｏｅｎｓｉｓ）、ハネナガイナゴ（Ｏｘｙａ ｊａｐｏｎｉｃａ）等。
Hemiptera: small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), planthopper such Sejirounka (Sogatella furcifera), green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens), Inazuma leafhopper (Recilia dorsalis), Chanomidorihime Leafhoppers such as leafhopper (Empoasca onukii), cotton aphid (Aphis gossypi), peach aphid (Myzus persicae), radish aphid (Brevicorine brassicae), snowy spruce (Aphasianis spruce) la), tulip beetle aphids (Macrosiphum euporbiae), potato beetle aphids (Aulacorthum solai), wheat beetle aphids (Rhopalosiphum papili), citrus aphids papida (Toxoptera crum) Aphids, Nezara antenna, Trichotylus caelestialium, Grafosoma rubrolineatum, Ethiopium sorghum wisi), horned beetle (Riptortus clavetus), spider helicopter (Leptocorisa renen), nymphalid (Lystocoris uren) Stink bugs such as Trichouredos vaporiarum, Tobacco white lice (Bemisia tabaci), citrus whitefly (Dialeurodes citrus), Aleopinus aphidula ella aurantii), San Jose scale insects (Comstockcaspis perniciosa), Citrus snow scale (Unaspis citri), ruby beetle (Ceroplastes rubens), iceria scale insect (Icerya purchasi), cocci Scale insects such as Pseudouracapsis pentagona, Bombycidae, bedbugs such as Chime lectularius, killer whales such as peasilla (Campsylla pyricola) and the like.
Lepidoptera: rice stem borer (Chilo suppressalis), Sankameiga (Tryporyza incertulas), leaf roller (Cnaphalocrocis medinalis), Watanomeiga (Notarcha derogata), Indian meal moth (Plodia interpunctella), the European corn borer (Ostrinia furnacalis), high Madara Roh moth (Hellula undalis), Common moths such as Pediasia teterrellus, Spodoptera litura, Spodoptera exigua, Pseudoteria septata, Seiyoto ferens), mushroom brassicae, agrotis ipsilon, tamanagiwawa (plusia nigrisigna), cerium genus, trichoplusia ni, trichoplusia ni White butterflies, Adoxofies spp., Grapholivita molesta, Leguminivola glycinivolorella, Azusayamashia, Atsukiyashia physica es honmai), Chahamaki (Homona magnanima), Mi someone summer fruit moth (Archips fuscocupreanus), Tortricidae such as codling moth (Cydia pomonella), Chanohosoga (Caloptilia theivora), subfraction such apple leaf miner (Phyllonorycter ringoneella), peach fruit moth (Carposina niponensis), etc. Of the genus Thymus, Rioteria spp., Limantria spp., Euploctis spp. ), Higatria cunea, etc., Iga (Tinea translucens), Chiro (Tineola bisselliella), etc., Tuta absoluta, etc.
Thysanoptera: western flower thrips (Frankliniella occidentalis), Minami thrips (Thrips parmi), yellow tea thrips (Scirtothrips dorsalis), green onion thrips (Thrips tabaci), Hirazuhanaazamiuma (Frankliniella intonsa), tobacco thrips (Frankliniella fusca), onion thrips Thrips such as (Thrips tabaci), rice thrips (Stenchaethotrips biformis), and rice thrips (Haplotrips acculeatus), etc .;
Diptera: onion maggot (Hylemya antiqua), seedcorn maggot (Hylemya platura), rice leafminer (Agromyza oryzae), rice Hime leafminer (Hydrellia griseola), Inekimoguribae (Chlorops oryzae), leafminer such as beans leafminer (Liriomyza trifolii), melon fly (Dacus cucurbitae), fruit fly (Ceratitis capitata) and the like;
Coleoptera: beetle, Epilachna vigintioctopunctata (Epilachna vigintioctopunctata), cucurbit leaf beetle (Aulacophora femoralis), Kisujinomihamushi (Phyllotreta striolata), Inedorooimushi (Oulema oryzae), rice weevil (Echinocnemus squameus), rice water weevil (Lissorhoptrus oryzophilus), boll weevil (Anthonomus grandis), Azuki beetle (Callosobruchus chinensis), Shibahorusu weevil (Sphenophorus venatus), Japanese beetle (Popilia japonica), Douganebububu (Anomala cupre) ..), Corn rootworm fellow (Diabrotica spp), Colorado potato beetle (Leptinotarsa decemlineata), fellow of click beetles (Agriotes spp), cigarette beetle (Lasioderma serricorne) and the like;
Pterodoptera: Kelly (Grylotalpa africana), Oxya yezoensis, Oxya japonica, etc.
前記有害節足動物の中でも、好ましい例として、ウンカ類、ヨコバイ類、アブラムシ類、カメムシ類、イネミズゾウムシ、イネドロオイムシ、メイガ類、ヤガ類等を挙げることができる。 Among the harmful arthropods, preferred examples include planthoppers, leafhoppers, aphids, stink bugs, rice weevil, rice beetles, moths, and moths.
本発明の有害節足動物防除組成物は植物病害を防除する目的で使用してもよく、例えばイネの紋枯病（Ｒｈｉｚｏｃｔｏｎｉａ ｓｏｌａｎｉ）等の病害を防除することができる。 The harmful arthropod control composition of the present invention may be used for the purpose of controlling plant diseases. For example, diseases such as rice blight (Rhizotonia solani) can be controlled.
本発明の有害節足動物防除組成物は、畑、水田、乾田、芝生、果樹園等の農耕地又は非農耕地用にて用いることができる。また、本発明の有害節足動物防除組成物は、「植物」等を栽培する農耕地等において、当該農耕地の有害生物を防除するために使用することができる。 The harmful arthropod control composition of the present invention can be used in agricultural fields such as fields, paddy fields, dry fields, lawns, orchards, or non-cultivated areas. Moreover, the harmful arthropod control composition of the present invention can be used for controlling pests in the farmland in farmlands where "plants" and the like are cultivated.
本発明の有害節足動物防除組成物を用いることができる植物としては、例えば次のものが挙げられる。 Examples of plants to which the harmful arthropod control composition of the present invention can be used include the following.
農作物：トウモロコシ、イネ、コムギ、オオムギ、ライムギ、エンバク、ソルガム、ワタ、ダイズ、ピーナッツ、ソバ、テンサイ、ナタネ、ヒマワリ、サトウキビ、タバコ等。
野菜；ナス科野菜（ナス、トマト、ピーマン、トウガラシ、ジャガイモ等）、ウリ科野菜（キュウリ、カボチャ、ズッキーニ、スイカ、メロン等）、アブラナ科野菜（ダイコン、カブ、セイヨウワサビ、コールラビ、ハクサイ、キャベツ、カラシナ、ブロッコリー、カリフラワー、アブラナ等）、キク科野菜（ゴボウ、シュンギク、アーティチョーク、レタス等）、ユリ科野菜（ネギ、タマネギ、ニンニク、アスパラガス等）、セリ科野菜（ニンジン、パセリ、セロリ、アメリカボウフウ等）、アカザ科野菜（ホウレンソウ、フダンソウ等）、シソ科野菜（シソ、ミント、バジル等）、イチゴ、サツマイモ、ヤマノイモ、サトイモ等。
果樹：仁果類（リンゴ、セイヨウナシ、ニホンナシ、カリン、マルメロ等）、核果類（モモ、スモモ、ネクタリン、ウメ、オウトウ、アンズ、プルーン等）、カンキツ類（ウンシュウミカン、オレンジ、レモン、ライム、グレープフルーツ等）、堅果類（クリ、クルミ、ハシバミ、アーモンド、ピスタチオ、カシューナッツ、マカダミアナッツ等）、液果類（ブルーベリー、クランベリー、ブラックベリー、ラズベリー等）、ブドウ、カキ、オリーブ、ビワ、バナナ、コーヒー、ナツメヤシ、ココヤシ、アブラヤシ等。
果樹以外の樹木：チャ、クワ、花木類（サツキ、ツバキ、アジサイ、サザンカ、シキミ、サクラ、ユリノキ、サルスベリ、キンモクセイ等）、街路樹（トネリコ、カバノキ、ハナミズキ、ユーカリ、イチョウ、ライラック、カエデ、カシ、ポプラ、ハナズオウ、フウ、プラタナス、ケヤキ、クロベ、モミノキ、ツガ、ネズ、マツ、トウヒ、イチイ、ニレ、トチノキ等）、サンゴジュ、イヌマキ、スギ、ヒノキ、クロトン、マサキ、カナメモチ、等。
芝生：シバ類（ノシバ、コウライシバ等）、バミューダグラス類（ギョウギシバ等）、ベントグラス類（コヌカグサ、ハイコヌカグサ、イトコヌカグサ等）、ブルーグラス類（ナガハグサ、オオスズメノカタビラ等）、フェスク類（オニウシノケグサ、イトウシノケグサ、ハイウシノケグサ等）、ライグラス類（ネズミムギ、ホソムギ等）、カモガヤ、オオアワガエリ等。
その他：花卉類（バラ、カーネーション、キク、トルコギキョウ、カスミソウ、ガーベラ、マリーゴールド、サルビア、ペチュニア、バーベナ、チューリップ、アスター、リンドウ、ユリ、パンジー、シクラメン、ラン、スズラン、ラベンダー、ストック、ハボタン、プリムラ、ポインセチア、グラジオラス、カトレア、デージー、シンビジューム、ベゴニア等）、バイオ燃料植物（ヤトロファ、ベニバナ、アマナズナ類、スイッチグラス、ミスカンサス、クサヨシ、ダンチク、ケナフ、キャッサバ、ヤナギ等）、観葉植物等。
Agricultural crops: corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, peanut, buckwheat, sugar beet, rapeseed, sunflower, sugarcane, tobacco, etc.
Vegetables: Solanum vegetables (eggplants, tomatoes, peppers, peppers, potatoes, etc.), Cucurbitaceae vegetables (cucumbers, pumpkins, zucchini, watermelons, melons, etc.), Brassicaceae vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage) , Mustard, broccoli, cauliflower, rape, etc.), asteraceae vegetables (burdock, shungiku, artichoke, lettuce, etc.), liliaceae vegetables (eg, leek, onion, garlic, asparagus), celery family vegetables (carrot, parsley, celery, American Bow Fu etc.), Rubiaceae vegetables (spinach, chard, etc.), Lamiaceae vegetables (shiso, mint, basil etc.), strawberry, sweet potato, yam, taro etc.
Fruit trees: berries (apples, pears, Japanese pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, ume, sweet cherry, apricots, prunes, etc.), citrus (satsuma mandarin, orange, lemon, lime, grapefruit) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, oil palm etc.
Trees other than fruit trees: tea, mulberry, flowering trees (Satsuki, camellia, hydrangea, sasanqua, shikimi, sakura, yurinoki, crape myrtle, snapdragon, etc.), roadside trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak) , Poplar, redwood, fu, sycamore, zelkova, blackfish, Japanese amberjack, moths, pine, pine, spruce, yew, elm, Japanese cypress, etc.), coral jug, dogwood, cedar, cypress, croton, masaki, kanamochi, etc.
Lawn: Shiba (Nasis, Pleurotus, etc.), Bermudagrass (Neurodonidae, etc.), Bentgrass (Oleoptera, Hykonukagusa, Odonoptera, etc.), Bluegrass (Nagahagusa, Oosuzunokatabira, etc.), Fescue (Oonishi nokegusa, Drosophila, etc.) , Grass, etc.), ryegrass (rat, wheat, etc.), anemonefish, blue whale, etc.
Other: Flowers (Rose, Carnation, Chrysanthemum, Eustoma, Gypsophila, Gerbera, Marigold, Salvia, Petunia, Verbena, Tulip, Aster, Gentian, Lily, Pansy, Cyclamen, Orchid, Lily of the valley, Lavender, Stock, Habutton, Primula, Poinsettia, gladiolus, cattleya, daisy, symbidium, begonia, etc.), biofuel plants (Jatropha, safflower, Amanas, switchgrass, miscanthus, kusayoshi, dangiku, kenaf, cassava, willow, etc.), houseplants, etc.
前記植物の中でも、好ましい例として、トウモロコシ、コムギ、イネ等を挙げることができる。その中でも、特にイネが好ましい。 Among the plants, corn, wheat, rice and the like can be mentioned as preferable examples. Of these, rice is particularly preferable.
上記「植物」は、遺伝子組換え技術や交配による育種法により耐性を付与された植物であってもよい。 The “plant” may be a plant imparted with resistance by a genetic recombination technique or a breeding method by crossing.
本発明の有害節足動物防除組成物は、植物又は植物の栽培地に施用することにより、有害節足動物を防除するために用いられる。ここで植物としては、植物の茎葉、植物の花、植物の実、植物の種子等が挙げられる。 The harmful arthropod control composition of the present invention is used to control harmful arthropods by being applied to plants or plant cultivation areas. Examples of plants include plant foliage, plant flowers, plant nuts, plant seeds, and the like.
本発明の有害節足動物の防除方法は、本発明の有害節足動物防除組成物を処理することにより行われるが、具体的には、例えば、茎葉散布などの植物の茎葉への処理、植物の種子への処理、土壌処理、水面施用などの植物の栽培地への処理等が挙げられる。 The method for controlling harmful arthropods of the present invention is carried out by treating the composition for controlling harmful arthropods of the present invention. Specifically, for example, treatment of plant foliage such as foliage spraying, Treatment of seeds, soil treatment, water surface application, etc. to plant cultivation areas.
本発明における茎葉散布などの植物の茎葉への処理としては、具体的には、例えば、人力噴霧機、動力噴霧機、ブームスプレーヤ若しくはパンクルスプレーヤを用いて行う地上散布や、航空防除若しくは無人ヘリコプターを用いて行う空中散布等により、栽培されている植物の表面に処理する方法が挙げられる。 Specifically, the treatment of the foliage of plants such as foliage spraying in the present invention is, for example, ground spraying using a human sprayer, power sprayer, boom sprayer or punk rsprayer, aviation control or unmanned helicopter A method of treating the surface of a plant being cultivated, for example, by aerial spraying performed using
本発明における植物の種子への処理としては、具体的には、例えば、浸漬処理、吹きつけ処理、塗沫処理、フィルムコート処理及びペレットコート処理等が挙げられる。 Specific examples of the treatment for plant seeds in the present invention include immersion treatment, spraying treatment, smearing treatment, film coating treatment, and pellet coating treatment.
本発明における土壌処理や水面施用などの植物の栽培地への処理としては、具体的には、例えば、植穴処理、株元処理、植溝処理、作条処理、全面処理、側条処理、育苗箱処理、苗床処理、培土混和、床土混和、ペースト肥料混和、水面処理、湛水散布等が挙げられる。 As the treatment to the planting area of the plant such as soil treatment and water surface application in the present invention, specifically, for example, planting hole treatment, stock source treatment, grooving treatment, rowing treatment, full surface treatment, side stripe treatment, Examples include seedling box treatment, nursery treatment, soil mixing, bed soil mixing, paste fertilizer mixing, water surface treatment, and water spraying.
本発明の有害節足動物組成物を、植物又は植物の栽培地に処理する場合、その処理量は、処理する植物の種類、防除対象である有害節足動物の種類や発生程度、製剤形態、処理時期、気象条件等によって変化させ得るが、本シアナミド化合物と本昆虫成長制御化合物と本紋枯病防除化合物との合計量として、当該植物を栽培する場所１０００ｍ2あたり通常０．５〜３０００ｇ、好ましくは５〜３００ｇである。
本発明の有害節足動物組成物は、乳剤、水和剤、フロアブル剤等は通常水で希釈して散布することにより処理する。この場合、本シアナミド化合物と本昆虫成長制御化合物と本紋枯病防除化合物との合計での濃度は、。通常０．００００１〜１０重量％、好ましくは０．０００１〜５重量％の範囲である。粉剤、粒剤等は通常希釈することなくそのまま処理する。
When the harmful arthropod composition of the present invention is treated in a plant or a plant cultivation area, the amount of treatment is the type of plant to be treated, the type and occurrence of harmful arthropods to be controlled, the formulation form, The total amount of the cyanamide compound, the insect growth control compound, and the main blight control compound is usually 0.5 to 3000 g per 1000 m 2 where the plant is cultivated. Preferably it is 5-300g.
The harmful arthropod composition of the present invention is treated by spraying emulsions, wettable powders, flowables and the like usually diluted with water. In this case, the total concentration of the present cyanamide compound, the present insect growth control compound and the present blight control compound is: Usually, it is 0.00001-10 weight%, Preferably it is the range of 0.0001-5 weight%. Powders, granules, etc. are usually processed without dilution.
以下、本発明を製剤例及び試験例にてさらに詳しく説明するが、本発明は以下の例のみに限定されるものではない。なお、以下の例において、部は特にことわりの無い限り重量部を表す。 Hereinafter, the present invention will be described in more detail with reference to formulation examples and test examples, but the present invention is not limited to the following examples. In the following examples, parts represent parts by weight unless otherwise specified.
まず、製剤例を示す。 First, formulation examples are shown.
製剤例１
本シアナミド化合物５部、メトキシフェノジド２０部及びフルトラニル２部を、ラウリル硫酸ナトリウム４部、リグニンスルホン酸カルシウム２部、合成含水酸化珪素微粉末２０部及び珪藻土残部を混合した中に加え、よく攪拌混合して水和剤１００部を得る。
Formulation Example 1
Add 5 parts of this cyanamide compound, 20 parts of methoxyphenozide and 2 parts of flutolanil to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic silicon hydroxide fine powder and the remainder of diatomaceous earth and mix well. To obtain 100 parts of wettable powder.
製剤例２〜５
フルトラニル２部に代えて、［表１］記載のそれぞれの化合物及び使用量を適用した以外は製剤例１と同様の操作を行い、それぞれの水和剤１００部を得る。
Formulation Examples 2-5
It replaces with 2 parts of flutolanil, and except having applied each compound and usage-amount of the [Table 1] description, operation similar to the formulation example 1 is performed, and 100 parts of each wettable powder is obtained.
製剤例６
本シアナミド化合物５部、クロマフェノジド２０部及びフルトラニル２部を、ラウリル硫酸ナトリウム４部、リグニンスルホン酸カルシウム２部、合成含水酸化珪素微粉末２０部及び珪藻土残部を混合した中に加え、よく攪拌混合して水和剤１００部を得る。
Formulation Example 6
Add 5 parts of this cyanamide compound, 20 parts of chromafenozide and 2 parts of flutolanil to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic silicon hydroxide fine powder and the remainder of diatomaceous earth and mix well. To obtain 100 parts of wettable powder.
製剤例７〜１０
フルトラニル２部に代えて、［表２］記載のそれぞれの化合物及び使用量を適用した以外は製剤例６と同様の操作を行い、それぞれの水和剤１００部を得る。
Formulation Examples 7-10
It replaces with 2 parts of flutolanil, and except having applied each compound and usage-amount of the [Table 2] description, operation similar to the formulation example 6 is performed, and 100 parts of each wettable powder is obtained.
製剤例１１
本シアナミド化合物５部、テブフェノジド４０部及びフルトラニル２部を、ラウリル硫酸ナトリウム４部、リグニンスルホン酸カルシウム２部、合成含水酸化珪素微粉末２０部及び珪藻土残部を混合した中に加え、よく攪拌混合して水和剤１００部を得る。
Formulation Example 11
Add 5 parts of the present cyanamide compound, 40 parts of tebufenozide and 2 parts of flutolanil to a mixture of 4 parts of sodium lauryl sulfate, 2 parts of calcium lignin sulfonate, 20 parts of synthetic silicon hydroxide-containing fine powder and the remainder of diatomaceous earth and mix well. To obtain 100 parts of wettable powder.
製剤例１２〜１５
フルトラニル２部に代えて、［表３］記載のそれぞれの化合物及び使用量を適用した以外は製剤例１１と同様の操作を行い、それぞれの水和剤１００部を得る。
Formulation Examples 12-15
It replaces with 2 parts of flutolanil, and except having applied each compound and usage-amount of the [Table 3] description, operation similar to the formulation example 11 is performed, and 100 parts of each wettable powder is obtained.
製剤例１６
本シアナミド化合物０．３５部、メトキシフェノジド０．５部、フルトラニル２部、タルク１０部及びカオリンクレー残部をよく粉砕混合することにより粉剤１００部を得る。
Formulation Example 16
By thoroughly pulverizing and mixing 0.35 part of the present cyanamide compound, 0.5 part of methoxyphenozide, 2 parts of flutolanil, 10 parts of talc and the remainder of kaolin clay, 100 parts of a powder is obtained.
製剤例１７〜２０
フルトラニル２部に代えて、［表４］記載のそれぞれの化合物及び使用量を適用した以外は製剤例１６と同様の操作を行い、それぞれの粉剤１００部を得る。
Formulation Examples 17-20
It replaces with 2 parts of flutolanil, and except having applied each compound and usage-amount of the [Table 4] description, operation similar to the formulation example 16 is performed, and 100 parts of each powder agent is obtained.
製剤例２１
本シアナミド化合物０．３５部、クロマフェノジド０．５部、フルトラニル２部、タルク１０部及びカオリンクレー残部をよく粉砕混合することにより粉剤１００部を得る。
Formulation Example 21
By thoroughly pulverizing and mixing 0.35 part of the present cyanamide compound, 0.5 part of chromafenozide, 2 parts of flutolanil, 10 parts of talc and the remainder of kaolin clay, 100 parts of a powder is obtained.
製剤例２２〜２５
フルトラニル２部に代えて、［表５］記載のそれぞれの化合物及び使用量を適用した以外は製剤例２１と同様の操作を行い、それぞれの粉剤１００部を得る。
Formulation Examples 22-25
It replaces with 2 parts of flutolanil, and except having applied each compound and usage-amount of [Table 5], operation similar to the formulation example 21 is performed, and 100 parts of each powder agent is obtained.
製剤例２６
本シアナミド化合物０．３５部、テブフェノジド０．７５部、フルトラニル２部、タルク１０部及びカオリンクレー残部をよく粉砕混合することにより粉剤１００部を得る。
Formulation Example 26
By thoroughly pulverizing and mixing 0.35 parts of the present cyanamide compound, 0.75 parts of tebufenozide, 2 parts of flutolanil, 10 parts of talc and the remainder of kaolin clay, 100 parts of a powder is obtained.
製剤例２７〜３０
フルトラニル２部に代えて、［表６］記載のそれぞれの化合物及び使用量を適用した以外は製剤例２６と同様の操作を行い、それぞれの粉剤１００部を得る。
Formulation Examples 27-30
It replaces with 2 parts of flutolanil, and except having applied each compound and usage-amount of the [Table 6] description, operation similar to the formulation example 26 is performed, and 100 parts of each powder agent is obtained.
製剤例３１
本シアナミド化合物２部、メトキシフェノジド４部、フルトラニル１６部、ポリオキシエチレンアルキルエーテルサルフェートアンモニウム塩５０部を含むホワイトカーボン３０部及び水残部を混合した混合物１００部を湿式粉砕法で微粉砕することにより、フロアブル剤を得る。
Formulation Example 31
By finely pulverizing 100 parts of a mixture of 2 parts of the present cyanamide compound, 4 parts of methoxyphenozide, 16 parts of flutolanil, 30 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder of the water by a wet grinding method, Obtain a flowable agent.
製剤例３２〜３５
フルトラニル１６部に代えて、［表７］記載のそれぞれの化合物及び使用量を適用した以外は製剤例３１と同様の操作を行い、それぞれのフロアブル剤１００部を得る。
Formulation Examples 32-35
It replaces with 16 parts of flutolanil, and except having applied each compound and usage-amount of the [Table 7] description, operation similar to the formulation example 31 is performed, and 100 parts of each flowable agent is obtained.
製剤例３６
本シアナミド化合物２部、クロマフェノジド４部、フルトラニル１６部、ポリオキシエチレンアルキルエーテルサルフェートアンモニウム塩５０部を含むホワイトカーボン３０部及び水残部を混合した混合物１００部を湿式粉砕法で微粉砕することにより、フロアブル剤を得る。
Formulation Example 36
By finely pulverizing 100 parts of a mixture obtained by mixing 2 parts of the present cyanamide compound, 4 parts of chromafenozide, 16 parts of flutolanil, 30 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder of water by a wet pulverization method, Obtain a flowable agent.
製剤例３７〜４０
フルトラニル１６部に代えて、［表８］記載のそれぞれの化合物及び使用量を適用した以外は製剤例３６と同様の操作を行い、それぞれのフロアブル剤１００部を得る。
Formulation Examples 37-40
It replaces with 16 parts of flutolanil, and except having applied each compound and usage-amount of the [Table 8] description, operation similar to the formulation example 36 is performed, and 100 parts of each flowable agent is obtained.
製剤例４１
本シアナミド化合物２部、テブフェノジド８部、フルトラニル１６部、ポリオキシエチレンアルキルエーテルサルフェートアンモニウム塩５０部を含むホワイトカーボン３０部及び水残部を混合した混合物１００部を湿式粉砕法で微粉砕することにより、フロアブル剤を得る。
Formulation Example 41
By finely pulverizing 100 parts of a mixture of 2 parts of the present cyanamide compound, 8 parts of tebufenozide, 16 parts of flutolanil, 30 parts of white carbon containing 50 parts of polyoxyethylene alkyl ether sulfate ammonium salt and the remainder of the water by a wet grinding method, Obtain a flowable agent.
製剤例４２〜４５
フルトラニル１６部に代えて、［表９］記載のそれぞれの化合物及び使用量を適用した以外は製剤例４１と同様の操作を行い、それぞれのフロアブル剤１００部を得る。
Formulation Examples 42-45
It replaces with 16 parts of flutolanil, and except having applied each compound and usage-amount of [Table 9], operation similar to the formulation example 41 is performed, and 100 parts of each flowable agent is obtained.
次に、本発明の効果を試験例にて示す。 Next, the effect of the present invention will be shown by test examples.
試験例１
本シアナミド化合物６ｍｇを、それぞれソルゲンＴＷ−２０（第一工業製薬製）を含むアセトン（和光純薬工業製）０．２ｍｌに溶解した後、所定濃度になるように展着剤（商品名：ダイン（登録商標）、住化タケダ園芸製）０．０２容量％を含有する水で希釈した。メトキシフェノジド、クロマフェノジド、テブフェノジド、フルトラニル、ペンシクロン及び本活性化合物（Ｉ）３ｍｇを、それぞれソルゲンＴＷ−２０（第一工業製薬製）を含むアセトン（和光純薬工業製）０．２ｍｌに溶解した後、所定濃度になるように展着剤（商品名：ダイン（登録商標）、住化タケダ園芸製）０．０２容量％を含有する水で希釈した。
本シアナミド化合物の水希釈液と、メトキシフェノジド、クロマフェノジド又はテブフェノジドの水希釈液と、フルトラニル、ペンシクロン又は本活性化合物（Ｉ）の水希釈液とを混合し、試験用薬液を調製した。
２．５葉期のペーパーポット植えイネ（Ｏｒｙｚａ ｓａｔｉｖａ、品種：ほしのゆめ）稚苗に、前記試験用薬液を株あたり１０ｍｌ散布した。このイネ稚苗を風乾後、水を４．８ｍｌ入れたガラス製試験管（直径３０ｍｍ、高さ２００ｍｍ）に入れた。その試験管の中にトビイロウンカの３齢幼虫を１０頭ずつ放飼し、室内（２５℃、湿度５５％）に置いた。５日後に供試した幼虫の生死を観察した。その観察結果から、式１）によって死虫率、式２）によって補正死虫率を算出した。なお、試験は２反復で行った。その平均値を表１０に示す。
Test example 1
After dissolving 6 mg of this cyanamide compound in 0.2 ml of acetone (manufactured by Wako Pure Chemical Industries, Ltd.) each containing Sorgen TW-20 (manufactured by Daiichi Kogyo Seiyaku), a spreading agent (trade name: Dyne) (Registered trademark, manufactured by Sumika Takeda Horticulture) was diluted with water containing 0.02% by volume. After dissolving 3 mg of methoxyphenozide, chromafenozide, tebufenozide, flutolanil, pencyclon and this active compound (I) in 0.2 ml of acetone (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.) each containing Sorgen TW-20 (manufactured by Daiichi Kogyo Seiyaku) The solution was diluted with water containing 0.02% by volume of a spreading agent (trade name: Dyne (registered trademark), manufactured by Sumika Takeda Horticulture) to a concentration.
A water diluted solution of the present cyanamide compound, an aqueous diluted solution of methoxyphenozide, chromafenozide or tebufenozide, and an aqueous diluted solution of flutolanil, pencyclon or the active compound (I) were mixed to prepare a test drug solution.
2.5 ml of paper pot planted rice (Oryza sativa, variety: Hoshino Yume) seedlings were sprayed with 10 ml of the test chemical per strain. The rice seedlings were air-dried and placed in a glass test tube (diameter 30 mm, height 200 mm) containing 4.8 ml of water. Ten third-instar larvae of the green planthopper were released into the test tube and placed indoors (25 ° C., humidity 55%). The life and death of the larvae tested after 5 days were observed. From the observation results, the mortality rate was calculated by Equation 1) and the corrected mortality rate was calculated by Equation 2). The test was repeated twice. The average value is shown in Table 10.
式１）；死虫率（％）＝（供試虫数−生存虫数）／供試虫数×１００ Formula 1); death rate (%) = (number of test insects−number of surviving insects) / number of test insects × 100
式２）；補正死虫率（％）＝｛（処理区死虫率−無処理区死虫率）／（１００−無処理区死虫率）｝×１００ Formula 2); corrected mortality rate (%) = {(treatment area mortality rate−untreated area mortality ratio) / (100−untreated area mortality ratio)} × 100
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