JP5010547B2 - Highly active catalyst and method for producing the same - Google Patents

Description

  The present invention relates to a noble metal catalyst supported and immobilized on an inorganic oxide carrier having high catalytic activity and a method for producing the same.

  Catalysts are used in a wide range of fields, such as oxidation or reduction reactions of organic substances, esterification, polymerization, other chemical reactions, purification of automobile exhaust gases, and fuel cells. In general, a noble metal is often used as such a catalyst material. Precious metals are expensive and have been devised to increase the exposed surface area as nanoparticles in order to maximize their performance. Specifically, metal oxides such as silica, alumina, and titania with high specific surface area and high thermal and chemical stability, or carbon materials such as activated carbon and carbon black are used as a support, and noble metal is nano-sized on the surface. It is used in a dispersed and fixed state as particles.

  Among noble metals, gold has been conventionally considered to have very poor catalytic activity, although it is cheaper than other noble metals. On the other hand, the present inventor has developed high catalytic activity by dispersing and fixing gold on various metal oxide supports, preferably as ultrafine particles (nanoparticles) having a diameter of 10 nm or less. Nanoparticle catalysts are suitable for many reactions such as low temperature CO oxidation, HCHO oxidation, gas phase one-step epoxidation of propylene, low temperature water gas shift reaction, direct hydrogen peroxide synthesis from oxygen and hydrogen, and partial oxidation of hydrocarbons. It has been found that it exhibits catalytic activity superior to other noble metals (see, for example, Patent Document 1 and Non-Patent Document 1). In addition, gold nanoparticles have been reported to have catalytic activities such as hydrogenation of unsaturated compounds, oxidation of alcohols, reduction of NOx, and carbonylation of epoxides and amines. Furthermore, the present inventor has also found that when the gold particle diameter is 2 nm or less and the number of atoms is within 300 clusters, the catalyst characteristics may be further drastically changed.

  When a noble metal or the like is used as a catalyst, it is usually necessary to fix a metal that functions as a catalyst on a support. Various carriers such as inorganic oxides, carbon materials, and organic polymers have been proposed. Among these, the inorganic oxide support is widely used at present because of easy production, use at high temperature, and high specific surface area. As a method for immobilizing a metal catalyst on an inorganic oxide carrier, conventionally, impregnation method, coprecipitation method, sol-gel method, precipitation precipitation method, vapor deposition method, solid phase mixing method, CVD method, sputtering method, etc. Various methods are known.

  However, when an inorganic oxide is used as the support, the activity of the obtained catalyst is usually greatly different depending on the selection of the material constituting the precious metal used as the catalyst and the inorganic oxide. Further, as a method for improving the conversion rate and selectivity of oxidation, reduction, or other chemical reaction, a metal that functions as a catalyst and a support material that supports the metal have been selected by trial and error based on past experience. For this reason, enormous time and energy are required to find a catalyst with improved characteristics. Therefore, there has been a strong demand for a method that can easily find a catalyst having further improved activity without using conventional trial and error.

On the other hand, in recent years, due to the problem of global warming and the rising price of oil, there is an interest in using biomass as an automobile fuel or a raw material for chemical products. As one of them, chemical synthesis using bioethanol is expected. Acetic acid is an important compound as a synthetic intermediate for various chemical substances. For example, acetic acid is used as a raw material for vinyl acetate monomer, and the world annual production is estimated to be 7.8 million tons or more. The synthesis uses carbonylation with carbon monoxide or synthesis gas of methanol, and various other methods such as gas phase oxidation of ethane, synthesis from ethylene and oxygen and water, and isomerization of methyl formate. Proposed and implemented, methanol, ethane, ethylene, etc. used as synthetic raw materials are all obtained from petroleum or coal. Although an acetic acid synthesis process using bioethanol as a raw material is desired, there is no selective oxidation catalyst, and a catalyst search for achieving this reaction with low energy is being conducted. Under such circumstances, recently, a gold catalyst using MgAl ₂ O ₃ as a support has been reported to show a high acetic acid selectivity (for example, see Non-Patent Documents 2 and 3). The reaction conditions in the reported method are a temperature of 180 ° C. and an oxygen pressure of 3 Mpa, and there is a demand for a catalyst that is milder and has improved selectivity.

  Furthermore, there is a demand for higher activation in oxidation catalysts such as oxidation of carbon monoxide. A gold nanoparticle catalyst using a base metal oxide as a carrier is known as a catalyst that can completely oxidize carbon monoxide at room temperature (see, for example, Non-Patent Document 4). It is rare.

Japanese Patent Publication No. 5-49338 Haruta M.M. , Chem. Record, 2003, 3 (2), 75-87. C. H. Christensen et al. , Angew. Chem. Int. Ed. 45 (2006) 4648. C. H. Christensen et al. , J .; Catal. 251 (2007) 332. M.M. Haruta, et al. , Chem. Lett. 2 (1987) 405.

  The present invention has been made in view of such circumstances, and an object of the present invention is to provide a highly active catalyst in which a noble metal is supported on an inorganic oxide support and a method for producing the catalyst.

  Moreover, this invention is used for the synthesis | combination of acetic acid from ethanol, and is providing the catalyst with a high conversion rate and a high selectivity on mild reaction conditions.

As a result of intensive research, the present inventor doped metal ions capable of controlling the valence electrons of the metal oxide as the inorganic oxide carrier or capable of being dissolved in the metal oxide. By using the metal oxide carrier, it is possible to increase the activity of the inorganic oxide catalyst supporting the noble metal fine particles. At this time, in the catalyst supporting the gold fine particles on the inorganic oxide carrier, the specific metal is used as the inorganic oxide carrier. by using the metal oxide support doped with ions, in acetic acid synthesis from ethanol, under mild reaction conditions and it found that catalyst is obtained with a high conversion and selectivity. The present invention has been made based on these findings.

The present invention relates to the catalyst described in the following (1) to ( 3 ) and a production method thereof.

(1) In a catalyst in which noble metal fine particles made of ruthenium, rhodium, palladium, iridium, platinum, silver or gold are supported on an inorganic oxide support, the inorganic oxide support has copper ions added to nickel oxide which mainly constitutes the support. inorganic oxide doped Tona is, the doping amount of the copper ions and a molar ratio relative to nickel, Ni: Cu = 99: 1~85 : production of acetic acid by oxidation of ethanol characterized by 15 der Rukoto use catalyst.

( 2 ) A water-soluble nickel salt for forming a metal oxide mainly constituting a support , a water-soluble copper salt having a molar ratio of copper to nickel and Ni: Cu = 99: 1 to 85:15 , and ruthenium, A water-soluble noble metal compound comprising rhodium, palladium, iridium, platinum, silver or gold is dissolved in water to produce an aqueous solution, the aqueous solution is poured into an excess amount of an alkaline aqueous solution, and the deposited precipitate is filtered. A method for producing a catalyst for producing acetic acid by oxidation of ethanol , characterized by calcining.

( 3 ) The method for producing a catalyst for acetic acid production by oxidation of ethanol as described in ( 2 ) above, wherein calcination is performed after hydrogen reduction treatment or calcination is performed in a hydrogen reduction atmosphere.

  The inorganic oxide carrier for supporting the noble metal fine particles by controlling the metal valence electrons of the metal oxide as the inorganic oxide carrier of the present invention or using a carrier doped with metal ions that can be dissolved in the metal oxide. A highly active catalyst can be easily produced as an oxide catalyst.

  Further, in the inorganic oxide-supported gold catalyst, by using a nickel oxide support doped with copper ions as the inorganic oxide support, a catalyst having a high conversion rate and selectivity in the synthesis of acetic acid from ethanol can be obtained.

Hereinafter, the present invention will be described in more detail.
The catalyst of the present invention is a catalyst in which noble metal fine particles are supported on an inorganic oxide support, and the metal oxide constituting the support is doped with metal ions to form valence electrons or form a solid solution, thereby supporting a noble metal with high catalytic activity. It is characterized by forming a catalyst. Further, the present invention, for a specific reaction, by selecting the kind of noble metal fine particles supported on the inorganic oxide carrier, the metal oxide mainly constituting the inorganic oxide carrier and the metal doped therein, It is also characterized by obtaining a catalyst having a high catalytic activity including conversion and selectivity.

First, the inorganic oxide support used as the support for the noble metal-supported catalyst of the present invention will be described. The inorganic oxide carrier mainly comprises a metal oxide constituting the carrier and a metal ion doped therein. The metal oxide constituting the mainly carriers include nickel oxide (NiO) is.

Doping amount, relative to the metal of the normal metal oxides, is about 0.01 to 15 mol%.

  The carrier shape may be any shape depending on the intended use, and is not particularly limited, but is usually a powder. The form of the carrier may be any form such as a dense body or a porous body. The size of the carrier is usually preferably about 5 nm to 1 mm.

  Examples of the noble metal constituting the noble metal fine particles supported on the inorganic oxide carrier include platinum group elements such as ruthenium, rhodium, palladium, osmium, iridium, platinum, gold, and silver. When gold fine particles are used as the noble metal fine particles, the average particle diameter is preferably 20 nm or less, more preferably 10 nm or less.

  The catalyst in which the noble metal fine particles are supported on the inorganic oxide carrier doped with the metal ions can be produced by a coprecipitation method, a sol-gel method, other solid phase mixing method, CVD method, sputtering method or the like. In the coprecipitation method, a water-soluble metal salt capable of forming a metal oxide constituting an inorganic oxide carrier, a water-soluble salt of a doped metal ion, and a water-soluble noble metal compound forming a catalytic metal are dissolved in water. This is poured into an excess amount of an aqueous alkaline solution, and the deposited precipitate can be filtered and fired. At this time, after performing a hydrogen reduction process, baking may be performed and processes, such as a carbon monoxide reduction process, may be performed. Moreover, baking may be performed in a reducing atmosphere.

  In the case of the sol-gel method, it is produced by mixing the metal alkoxide constituting the carrier and the metal alkoxide having the metal to be doped, and baking the gel obtained by hydrolysis and polymerization in an appropriate organic solvent. Is done.

  By the above method, an inorganic carrier made of a metal oxide doped with a metal is produced as a carrier. In complex oxides, multiple metals form a single crystal system as an oxide. In metal oxides doped with metal ions, the metal oxide crystal system of the metal oxide that mainly constitutes the carrier is retained. is doing.

  The catalyst will be described in more detail below by taking as an example a catalyst using gold fine particles as noble metal fine particles. As described above, gold is dispersed / fixed on various metal oxide supports, preferably as ultrafine particles having a diameter of 10 nm or less, so that low temperature CO oxidation, propylene gas phase one-step epoxidation, low temperature water gas shift reaction, oxygen For many reactions such as direct hydrogen peroxide synthesis from hydrogen and hydrogen, partial oxidation of hydrocarbons, hydrogenation of unsaturated compounds, oxidation of alcohol, removal of NOx, epoxy compounds, carbonylation of aliphatic amines, etc. Expresses catalytic activity superior to other noble metals. Among these catalytic activities of gold fine particles, the use of alcohol as an oxidation catalyst will be described first.

  In the catalyst for the oxidation of ethanol using a gold fine particle supported catalyst, utilization of various metal oxide supports as a support has been announced, and catalytic activity data of gold catalysts supported on various supports are also known (C H. Christensen, et al., Angew. Chem. Int. Ed, 45 (2006) 4648). Table 1 below shows ethanol oxidation characteristics of gold catalysts using metal oxides of cobalt, barium, manganese, iron, copper, cerium, yttrium, zirconium, tin, titanium, and nickel as carriers as metal oxides. The oxidation conditions were an ethanol concentration of 5% by weight, a solution amount of 10 ml, an oxygen pressure of 0.5 MPa, a reaction temperature of 120 ° C., a catalyst amount of ethanol / Au (molar ratio) = 1400, and a stirring speed of 1000 rpm.

  From Table 1, the catalytic activity of the gold catalyst using a single metal oxide support is relatively high in acetic acid selectivity, but the conversion is low except for nickel oxide. For this reason, a gold catalyst having a high conversion rate and high selectivity is desired. If the selectivity of the gold oxide-supported gold catalyst having a high conversion rate among the gold catalysts is further improved, the above-described requirement can be met.

Therefore, hereinafter, a method for forming the catalyst of the present invention using a carrier mainly composed of nickel oxide as a gold catalyst carrier and doped with other metal ions will be described . Preferred doped metal against nickel is copper. Also, the doping amount is nickel: copper (molar ratio) of 99: 1 to 85: preferably about 15, more preferably 99: 3 to 90: a 10, more preferably 96: 4-93: 7 is there. The catalyst is usually used as a powder having an average particle size of about 5 nm to 1 mm, and preferably the average particle size is about 50 nm to 0.1 mm.

The nickel oxide-supported gold catalyst doped with copper can be easily produced, for example, by the following method (coprecipitation method). First, a salt containing nickel constituting a metal oxide of a carrier, a salt containing copper used as a dopant, and a gold compound are dissolved in water. Any salt containing nickel may be used as long as it is water-soluble. Examples of the salt containing nickel include nickel nitrate, nickel chloride, nickel acetate and hydrates thereof. Examples of the salt containing copper include copper nitrate, copper chloride, copper acetate, and hydrates thereof. Furthermore, examples of the gold compound include tetrachloroauric acid (HAuCl ₄ ), alkali metal tetrachloroauric acid, gold trichloride (AuCl ₃ ), gold cyanide (AuCN), gold cyanide potassium {K [Au (CN) ₂ ]}, diethylamine trichloride gold acid [(C ₂ H ₅ ) ₂ NH · AuCl ₃ ], ethylenediamine gold complex (for example, chloride complex (Au [C ₂ H ₄ (NH ₂ ) ₂ ] Cl ₃ )), Dimethylgold β-diketone derivative gold complex (for example, dimethylgold acetylacetonate ((CH ₃ ) ₂ Au [CH ₃ COCHCOCH ₃ ]), (CH ₃ ) ₂ Au (CF ₃ COCHCOCH ₃ ), (CH ₃ ) ₂ Au (CF ₃ COCHCOCF ₃ ), (C ₂ H ₅ ) ₂ Au (CH ₃ COCHCOCH ₃ ), (CH ₃ ) ₂ Au (C ₆ H ₅ OOCHCOCF ₃ )).

  The concentration of the water-soluble nickel salt, water-soluble copper salt, and water-soluble gold compound in the aqueous solution is any concentration as long as each salt and compound used constitute a uniform aqueous solution. Also good. Since the amount of the copper salt and gold compound used as the dope metal is smaller than that of the nickel salt, it is the amount of the water-soluble nickel salt that is mainly problematic. However, the solubility of the water-soluble nickel salt is 25 to 30 g. About / L is preferable. The amount of copper salt used as the dope metal and the amount of gold compound used as the catalyst are determined by the dope amount or the catalyst amount. Usually, since the ratio (molar ratio) of nickel: copper is about 99: 1 to 85:15, the copper salt is used with respect to the weight of the water-soluble nickel salt so as to be such an amount. Further, since the gold fine particles are preferably supported by 10 to 15 parts by weight per 100 parts by weight of the catalyst, the gold compound is used in such an amount that the final catalyst has such a supported amount. If the amount of gold supported in the catalyst particles is 10% by weight or less, there is a problem that the amount of gold existing on the surface is reduced, and if the amount is 15% by weight or more, further improvement in the activity of the catalyst cannot be expected. Is not preferable because it is wasted. Therefore, the gold compound is added to the aqueous solution in such an amount that the supported amount becomes the above amount. Moreover, when dissolving the said salt in water, in order to promote solubility, it is preferable to perform dissolution at a temperature of about 70 ° C., for example, in a state where water is heated.

  The aqueous solution containing the water-soluble nickel salt, the water-soluble copper salt, and the water-soluble gold compound thus prepared is added to an alkali aqueous solution prepared separately. The alkali is preferably sodium carbonate, potassium carbonate, lithium carbonate, sodium hydroxide or the like, but is not particularly limited thereto. The amount of alkali used may be at least the amount by which the water-soluble nickel salt, water-soluble copper salt, and water-soluble gold compound are precipitated, and is usually an amount containing alkali at an amount equal to or greater than the equivalents of the salt and gold compound. . An aqueous solution containing a water-soluble nickel salt, a water-soluble copper salt, and a water-soluble gold compound may be added to the alkaline aqueous solution, or conversely, the alkaline aqueous solution may contain the water-soluble nickel salt, the water-soluble copper salt, and the water-soluble gold compound. Although it may be added to the aqueous solution containing, the former is preferable. The addition rate of the aqueous salt solution may be arbitrary, but if it is added slowly, there arises a problem that non-uniform dispersion of gold occurs. Therefore, it is preferable that the total amount is added usually at a stroke or within about 1 minute under stirring.

  It is preferable to continue stirring until the reaction is further completed after adding a total amount of an aqueous solution containing a water-soluble nickel salt, a water-soluble copper salt, and a water-soluble gold compound to the precipitant aqueous solution. Although the stirring time after addition may be arbitrary, it is usually sufficient to stir for about 1 hour. This precipitation is also preferably performed in a heated state, for example, about 70 ° C., from the viewpoint of promoting the reaction and preventing precipitation of the used water-soluble nickel salt, water-soluble copper salt, water-soluble gold compound and the like. .

  After stirring, the mixture is cooled, the precipitate is filtered, and the filtered precipitate is washed with distilled water until the pH is stabilized. After washing, suction filtration is performed, and the resulting cake is dried. At this time, in order to accelerate drying and completely remove moisture, it is preferable to heat dry at a temperature of about 100 ° C. The dried precipitation product is preferably calcined at a temperature of about 250 to 350 ° C, more preferably at a temperature of about 300 ° C. Firing may be performed in air or in an inert gas atmosphere. The firing time may be a time sufficient to completely modify nickel and copper in the precipitate into nickel and copper oxides. The firing time is not particularly limited because it varies depending on the firing temperature or firing atmosphere. However, firing in air at 300 ° C. may be performed for about 4 hours. If necessary, reduction treatment may be performed before firing, or firing may be performed in a hydrogen reduction atmosphere. Thereby, a catalyst with improved characteristics may be obtained. After calcination, it is pulverized to obtain the gold catalyst of the present invention. The particle size after pulverization may be arbitrary.

The copper- doped nickel oxide support-supported gold catalyst thus obtained exhibits very good characteristics as an ethanol oxidation catalyst.

  A method for performing ethanol oxidation using the copper-doped nickel oxide carrier-supported gold catalyst of the present invention will be described.

First, ethanol is put in a 20% aqueous solution in an autoclave as a reaction vessel, and a gold catalyst is added thereto. The amount of the gold catalyst is not particularly limited, but it may be added usually about 1/1400 (1/400) moles of gold per mole of ethanol. The inside of the reaction vessel is replaced with oxygen, and the reaction is carried out by raising the temperature under pressure. Although reaction time changes with pressurization conditions, reaction temperature, etc., it is not specifically limited, What is necessary is just to carry out normally for about 1 to 5 hours. The higher the oxygen pressure and temperature, the higher the ethanol conversion. As described above, a gold catalyst using MgAl ₂ O ₃ as a support has been reported to show high conversion and acetic acid selectivity. In this experiment, the reaction conditions were a temperature of 180 ° C., oxygen The pressure is 3 Mpa. When the gold catalyst of the present invention is used, a high selectivity can be achieved even at temperatures of 0.5 MPa and 120 ° C. as compared with the gold catalyst using MgAl ₂ O ₃ . Moreover, if the reaction temperature and reaction pressure are increased, the conversion of ethanol increases.

  The reason why ethanol is used as an aqueous solution is that it has a future application to bioethanol. When this is premised, the ethanol concentration is preferably about 5 to 60%. The conversion rate to ethanol and the selectivity of acetic acid may be determined by quantifying the amount of ethanol remaining and the amount of acetic acid formed by an appropriate method such as gas chromatography. The method shown in the above specific example is only a specific example of ethanol oxidation, and the ethanol oxidation method and oxidation mode using the catalyst of the present invention are limited to the above method. is not.

  The nickel oxide-supported gold catalyst doped with copper ions has an ethanol conversion comparable to that of the nickel oxide-supported gold catalyst not doped with copper ions, and the selectivity to acetic acid is remarkably increased. That is, as shown in the examples, by using a gold catalyst supported on a nickel oxide support doped with copper ions of the present invention, an ethanol pressure of 0.5 MPa, a reaction temperature of 120 ° C., and a low temperature and low pressure. Regarding the conversion rate, it was confirmed that the conversion rate was 42%, which was almost the same as that before the doping, and the acetic acid selectivity was greatly improved to 85%.

  EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated concretely, this invention is not limited at all by this.

Example 1
[Preparation of Au / Cu-NiO catalyst]
Nickel nitrate hexahydrate (Ni (NO ₃ ) ₂ .6H ₂ O) 0.0184 mol (5.35 g), copper nitrate trihydrate (Cu (NO ₃ ) ₂ .3H ₂ O) 0.00057 mol (0.138 g), 0.001 mol (0.412 g) of tetrachloroauric (III) acid tetrahydrate (HAuCl ₄ .4H ₂ O) was dissolved in 200 ml of distilled water at 70 ° C. to prepare an aqueous solution 1 did. Separately from this, 0.025 mol (2.66 g) of sodium carbonate (Na ₂ CO ₃ ) was dissolved in 250 ml of distilled water at 70 ° C. to prepare an aqueous solution 2. The aqueous solution 1 was added to the aqueous solution 2 within 3 minutes, stirred for 1 hour while maintaining 70 ° C., and then allowed to cool to room temperature. The produced precipitate was washed with distilled water until the pH became stable. The product was filtered off with suction and dried at 100 ° C. in air overnight. Firing was performed in air at 300 ° C. for 4 hours. By pulverizing after firing, a gold catalyst (Au / NiO—CuO; Ni: Cu = 97: 3 (molar ratio)) supported on a nickel oxide carrier doped with copper ions was obtained.

[Catalyst activity evaluation 1]
Catalytic reaction was performed using an autoclave (Tokyo Rika Kikai Co., Ltd. organic synthesis apparatus PPV-CPRL type), and analysis was performed by gas chromatography (SHIMAZDU GC-2014) equipped with a flame ionization detector. The procedure was as follows: a 20 wt% aqueous ethanol solution and a catalyst were charged into an autoclave (ethanol / Au = 1400 mol / mol), the inside of the container was replaced with oxygen, the oxygen pressure was 0.5 MPa, the temperature was raised to 120 ° C. The reaction was started for 2 hours. After the reaction, the mixture was cooled on ice, ethylene glycol as an internal standard was added to the reaction solution, filtered, and the product was quantitatively analyzed by gas chromatography. The ethanol conversion was 39% and the acetic acid selectivity was 61%. STY (Space Time Yield; unit time yield) was 0.38 (mol / L · h). Note that STY is calculated by the following equation.
STY (mol / L · h) = {[(2 × ethanol conversion) × acetic acid selectivity] × (1 / 66.06)} ÷ (2 × 0.01)

Example 2
A gold catalyst (Au / NiO—CuO; Ni: supported on a nickel oxide carrier doped with copper ions was used in the same manner as in Example 1 except that the amount of copper nitrate was 0.00099 mol (0.24 g). Cu = 95: 5 (molar ratio)) was produced. Catalytic activity was evaluated in the same manner as in Example 1. The ethanol conversion was 40%, the acetic acid conversion was 85%, and the STY was 0.49 (mol / L · h).

Example 3
A gold catalyst (Au / NiO—CuO; Ni: supported on a nickel oxide support doped with copper ions was used in the same manner as in Example 1 except that the amount of copper nitrate was 0.00204 mol (0.49 g). Cu = 90: 10 (molar ratio)) was produced. Catalytic activity was evaluated in the same manner as in Example 1. The ethanol conversion was 39%, the acetic acid conversion was 62%, and the STY was 0.38 (mol / L · h).

Comparative Example 1
A gold catalyst (Au / NiO) supported on a nickel oxide support was produced in the same manner as in Example 1 except that copper nitrate was not used. The catalyst activity was evaluated in the same manner as in Example 1 except that the reaction time in the catalyst activity evaluation method was 4 hours and the ethanol concentration was 5% by weight. The ethanol conversion was 47%, the acetic acid conversion was 55%, and the STY was 0.07 (mol / L · h).

The results of Examples 1 to 3 and Comparative Example 1 are summarized in the table as follows.

  From Table 2, the nickel oxide-supported gold catalyst doped with copper ions is somewhat inferior to the nickel oxide-supported gold catalyst not doped with copper ions, but the acetic acid selectivity is 85% at 5 mol% doping. It turns out that it becomes a phenomenal value of%. In the above examples, the oxygen pressure was set to 0.5 MPa and the reaction temperature was set to 120 ° C. However, the conversion rate is further increased by increasing the oxygen pressure and the reaction temperature.

Example 4
The catalyst activity was evaluated in the same manner as in Example 1 except that the catalyst produced in Example 2 was used and the reaction time in the catalyst activity evaluation method was 4 hours. The ethanol conversion was 42% and the acetic acid conversion was 85%.

Claims (3)

In a catalyst in which noble metal fine particles made of ruthenium, rhodium, palladium, iridium, platinum, silver or gold are supported on an inorganic oxide carrier, the inorganic oxide carrier is doped with copper ions in nickel oxide which mainly constitutes the carrier. Ri Do metal oxides, the doping amount of the copper ions is in a molar ratio relative to nickel, Ni: Cu = 99: 1~85 : 15 der acetate production catalyst according Rukoto oxidation of ethanol characterized by.
A water-soluble nickel salt for forming a metal oxide mainly constituting a support , a water-soluble copper salt in which the molar ratio of copper to nickel is Ni: Cu = 99: 1 to 85:15 , and ruthenium, rhodium, palladium A water-soluble noble metal compound comprising iridium, platinum, silver or gold is dissolved in water to produce an aqueous solution, the aqueous solution is poured into an excess amount of an alkaline aqueous solution, and the deposited precipitate is filtered and fired. A process for producing a catalyst for producing acetic acid by oxidation of ethanol . The method for producing a catalyst for acetic acid production by oxidation of ethanol according to claim 2 , wherein calcination is performed after hydrogen reduction treatment or calcination is performed in a hydrogen reduction atmosphere.