JP4574721B2 - Soi基板及びその作製方法並びに半導体装置及びその作製方法 - Google Patents
Soi基板及びその作製方法並びに半導体装置及びその作製方法 Download PDFInfo
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- JP4574721B2 JP4574721B2 JP2009109681A JP2009109681A JP4574721B2 JP 4574721 B2 JP4574721 B2 JP 4574721B2 JP 2009109681 A JP2009109681 A JP 2009109681A JP 2009109681 A JP2009109681 A JP 2009109681A JP 4574721 B2 JP4574721 B2 JP 4574721B2
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- 239000000758 substrate Substances 0.000 title claims description 215
- 239000004065 semiconductor Substances 0.000 title claims description 63
- 238000004519 manufacturing process Methods 0.000 title claims description 29
- 229910021421 monocrystalline silicon Inorganic materials 0.000 claims description 129
- 239000010408 film Substances 0.000 claims description 121
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 99
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 92
- 238000000034 method Methods 0.000 claims description 56
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 55
- 229910052710 silicon Inorganic materials 0.000 claims description 43
- 229910052739 hydrogen Inorganic materials 0.000 claims description 42
- 239000010703 silicon Substances 0.000 claims description 42
- 239000001257 hydrogen Substances 0.000 claims description 41
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 37
- 239000013078 crystal Substances 0.000 claims description 34
- 238000010438 heat treatment Methods 0.000 claims description 26
- 238000007254 oxidation reaction Methods 0.000 claims description 15
- 230000003647 oxidation Effects 0.000 claims description 14
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 11
- 239000000919 ceramic Substances 0.000 claims description 8
- 239000010409 thin film Substances 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 6
- 239000010453 quartz Substances 0.000 claims description 6
- 238000000059 patterning Methods 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 146
- 229910021426 porous silicon Inorganic materials 0.000 description 19
- 239000001301 oxygen Substances 0.000 description 17
- 229910052760 oxygen Inorganic materials 0.000 description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 13
- 239000012535 impurity Substances 0.000 description 12
- 230000008569 process Effects 0.000 description 11
- 239000004973 liquid crystal related substance Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 125000004429 atom Chemical group 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 8
- 230000006870 function Effects 0.000 description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
- 238000007743 anodising Methods 0.000 description 7
- -1 hydrogen ions Chemical class 0.000 description 7
- 230000001603 reducing effect Effects 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- 229910052719 titanium Inorganic materials 0.000 description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 6
- 238000000137 annealing Methods 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 229910052581 Si3N4 Inorganic materials 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000005530 etching Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 229920005591 polysilicon Polymers 0.000 description 3
- 229910021332 silicide Inorganic materials 0.000 description 3
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- UMIVXZPTRXBADB-UHFFFAOYSA-N benzocyclobutene Chemical compound C1=CC=C2CCC2=C1 UMIVXZPTRXBADB-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005401 electroluminescence Methods 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000007517 polishing process Methods 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 229910001362 Ta alloys Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021417 amorphous silicon Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000002241 glass-ceramic Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002513 implantation Methods 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 238000005224 laser annealing Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical class [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
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- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1214—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
- H01L27/1259—Multistep manufacturing methods
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- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/76—Making of isolation regions between components
- H01L21/762—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers
- H01L21/7624—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using semiconductor on insulator [SOI] technology
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- H01L21/762—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers
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Description
において矢印で示す部分に3つのシリコン原子が存在するが、これらは図8(A)にて矢印で示した3つのシリコン原子と同一のものである。
の島状シリコン層108に相当する。
従って、公知のあらゆる構造のTFTに対して適用可能である。また、本実施例の工程条件は一例であり、本願発明の本質部分以外は実施者が適宜最適な条件を設定すれば良い。
形成方法としては、熱酸化、プラズマ酸化、レーザー酸化などを用いることが可能である。このとき、単結晶シリコン層305が残存する。(図3(B))
(図3(C))
用いるエッチャントはフッ酸水溶液と過酸化水素水溶液との混合溶液が良い。49%HFと30%H2O2を1:5で混合した溶液は、単結晶シリコン層と多孔質シリコン層との間で10万倍以上の選択比を持つことが報告されている。
となる様に調節すれば良い。
504は窒化シリコン膜/酸化シリコン膜/樹脂膜の積層膜でなる絶縁層、その上にはチタン配線505が設けられ、前述のCMOS回路とTFT502とが電気的に接続されている。チタン配線はさらに樹脂膜でなる絶縁層506で覆われている。二つの絶縁層504、506は平坦化膜としての機能も有している。
Claims (20)
- 支持基板と、
前記支持基板上の酸化シリコン膜と、
前記酸化シリコン膜上の主表面が{110}面である単結晶シリコン層とを有し、
前記単結晶シリコン層は、主表面が{110}面である単結晶シリコン基板上に前記酸化シリコン膜を形成し、前記酸化シリコン膜を介して前記単結晶シリコン基板に水素を添加して水素含有層を形成し、前記酸化シリコン膜を間に挟んで前記単結晶シリコン基板と前記支持基板とを接合し、前記酸化シリコン膜を間に挟んで前記単結晶シリコン層が前記支持基板上に残るように、熱処理により前記水素含有層に沿って前記単結晶シリコン基板を分断し、前記単結晶シリコン層の表面を平坦化して前記単結晶シリコン層の厚さを10〜200nmとして作製されたものであることを特徴とするSOI基板。 - 支持基板と、
前記支持基板上の第1の酸化シリコン膜と、
前記第1の酸化シリコン膜上の第2の酸化シリコン膜と、
前記第2の酸化シリコン膜上の主表面が{110}面である単結晶シリコン層とを有し、
前記単結晶シリコン層は、前記支持基板上に前記第1の酸化シリコン膜を形成し、主表面が{110}面である単結晶シリコン基板上に前記第2の酸化シリコン膜を形成し、前記第2の酸化シリコン膜を介して前記単結晶シリコン基板に水素を添加して水素含有層を形成し、前記第1の酸化シリコン膜及び前記第2の酸化シリコン膜を間に挟んで前記単結晶シリコン基板と前記支持基板とを接合し、前記第1の酸化シリコン膜及び前記第2の酸化シリコン膜を間に挟んで前記単結晶シリコン層が前記支持基板上に残るように、熱処理により前記水素含有層に沿って前記単結晶シリコン基板を分断し、前記単結晶シリコン層の表面を平坦化して前記単結晶シリコン層の厚さを10〜200nmとして作製されたものであることを特徴とするSOI基板。 - 請求項1において、前記酸化シリコン膜は、前記単結晶シリコン基板に熱酸化処理を行って形成された膜厚が20〜50nmである酸化シリコン膜であることを特徴とするSOI基板。
- 請求項2において、前記第2の酸化シリコン膜は、前記単結晶シリコン基板に熱酸化処理を行って形成された膜厚が20〜50nmである酸化シリコン膜であることを特徴とするSOI基板。
- 請求項1乃至請求項4のいずれか一において、
前記支持基板は、シリコン基板、多結晶シリコン基板、セラミックス基板、石英基板、又はガラス基板であることを特徴とするSOI基板。 - 主表面が{110}面である単結晶シリコン基板上に酸化シリコン膜を形成し、
前記酸化シリコン膜を介して前記単結晶シリコン基板に水素を添加して水素含有層を形成し、
前記酸化シリコン膜を間に挟んで、前記単結晶シリコン基板と、支持基板とを接合し、
前記酸化シリコン膜を間に挟んで単結晶シリコン層が前記支持基板上に残るように、熱処理により前記水素含有層に沿って前記単結晶シリコン基板を分断し、
前記単結晶シリコン層の表面を平坦化して前記単結晶シリコン層の厚さを10〜200nmとすることを特徴とするSOI基板の作製方法。 - 請求項6において、
前記支持基板は、シリコン基板、多結晶シリコン基板、セラミックス基板、石英基板、又はガラス基板であることを特徴とするSOI基板の作製方法。 - 請求項6または請求項7において、前記単結晶シリコン基板に熱酸化処理を行い、膜厚が20〜50nmである前記酸化シリコン膜を形成することを特徴とするSOI基板の作製方法。
- 請求項6乃至請求項8のいずれか一において、
前記単結晶シリコン層の表面をCMP法により平坦化することを特徴とするSOI基板の作製方法。 - 請求項6乃至請求項9のいずれか一において、
前記支持基板の表面に酸化シリコン膜を有し、
前記単結晶シリコン基板と前記支持基板の接合は、前記単結晶シリコン基板上に形成された酸化シリコン膜と、前記支持基板の表面の酸化シリコン膜の接合によって行われることを特徴とするSOI基板の作製方法。 - 支持基板と、
前記支持基板上の酸化シリコン膜と、
前記酸化シリコン膜上の主表面が{110}面である島状のシリコン層と、
前記島状のシリコン層上のゲート絶縁膜と、
前記ゲート絶縁膜上のゲート配線と、を有し、
前記島状のシリコン層は、主表面が{110}面である単結晶シリコン基板上に前記酸化シリコン膜を形成し、前記酸化シリコン膜を介して前記単結晶シリコン基板に水素を添加して水素含有層を形成し、前記酸化シリコン膜を間に挟んで前記単結晶シリコン基板と前記支持基板とを接合し、前記酸化シリコン膜を間に挟んで単結晶シリコン層が前記支持基板上に残るように、熱処理により前記水素含有層に沿って前記単結晶シリコン基板を分断し、前記単結晶シリコン層の表面を平坦化して、前記単結晶シリコン層の厚さを10〜200nmとし、前記単結晶シリコン層をパターニングして作製されたものであることを特徴とする半導体装置。 - 支持基板と、
前記支持基板上の第1の酸化シリコン膜と、
前記第1の酸化シリコン膜上の第2の酸化シリコン膜と、
前記第2の酸化シリコン膜上の主表面が{110}面である島状のシリコン層と、
前記島状のシリコン層上のゲート絶縁膜と、
前記ゲート絶縁膜上のゲート配線と、を有し、
前記島状のシリコン層は、前記支持基板上に前記第1の酸化シリコン膜を形成し、主表面が{110}面である単結晶シリコン基板上に前記第2の酸化シリコン膜を形成し、前記第2の酸化シリコン膜を介して前記単結晶シリコン基板に水素を添加して水素含有層を形成し、前記第1の酸化シリコン膜及び前記第2の酸化シリコン膜を間に挟んで前記単結晶シリコン基板と前記支持基板とを接合し、前記第1の酸化シリコン膜及び前記第2の酸化シリコン膜を間に挟んで単結晶シリコン層が前記支持基板上に残るように、熱処理により前記水素含有層に沿って前記単結晶シリコン基板を分断し、前記単結晶シリコン層の表面を平坦化して前記単結晶シリコン層の厚さを10〜200nmとし、前記単結晶シリコン層をパターニングして作製されたものであることを特徴とする半導体装置。 - 請求項11において、前記酸化シリコン膜は、前記単結晶シリコン基板に熱酸化処理を行って形成された膜厚が20〜50nmである酸化シリコン膜であることを特徴とする半導体装置。
- 請求項12において、前記第2の酸化シリコン膜は、前記単結晶シリコン基板に熱酸化処理を行って形成された膜厚が20〜50nmである酸化シリコン膜であることを特徴とする半導体装置。
- 請求項11乃至請求項14のいずれか一において、
前記支持基板は、シリコン基板、多結晶シリコン基板、セラミックス基板、石英基板、又はガラス基板であることを特徴とする半導体装置。 - 主表面が{110}面である単結晶シリコン基板上に酸化シリコン膜を形成し、
前記酸化シリコン膜を介して前記単結晶シリコン基板に水素を添加して水素含有層を形成し、
前記酸化シリコン膜を間に挟んで、前記単結晶シリコン基板と、支持基板とを接合し、
前記酸化シリコン膜を間に挟んで単結晶シリコン層が前記支持基板上に残るように、熱処理により前記水素含有層に沿って前記単結晶シリコン基板を分断し、
前記単結晶シリコン層を用いて、薄膜トランジスタの活性層となる島状シリコン層を形成し、
前記島状シリコン層上にゲート絶縁膜を形成し、
前記ゲート絶縁膜上にゲート配線を形成し、
前記島状シリコン層の厚さは10〜200nmであることを特徴とする半導体装置の作製方法。 - 請求項16において、
前記支持基板は、シリコン基板、多結晶シリコン基板、セラミックス基板、石英基板、又はガラス基板であることを特徴とする半導体装置の作製方法。 - 請求項16または請求項17において、前記単結晶シリコン基板に熱酸化処理を行い、膜厚が20〜50nmである前記酸化シリコン膜を形成することを特徴とする半導体装置の作製方法。
- 請求項16乃至請求項18のいずれか一において、
前記単結晶シリコン層の表面をCMP法により平坦化することを特徴とする半導体装置の作製方法。 - 請求項16乃至請求項19のいずれか一において、
前記支持基板の表面に酸化シリコン膜を有し、
前記単結晶シリコン基板と前記支持基板の接合は、前記単結晶シリコン基板上に形成された酸化シリコン膜と、前記支持基板の表面の酸化シリコン膜の接合によって行われることを特徴とする半導体装置の作製方法。
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US8405090B2 (en) | 2013-03-26 |
JP2000150905A (ja) | 2000-05-30 |
US7642598B2 (en) | 2010-01-05 |
JP5498990B2 (ja) | 2014-05-21 |
US20050009252A1 (en) | 2005-01-13 |
US20090236698A1 (en) | 2009-09-24 |
US20080070335A1 (en) | 2008-03-20 |
JP2011216895A (ja) | 2011-10-27 |
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USRE42241E1 (en) | 2011-03-22 |
US20020137265A1 (en) | 2002-09-26 |
US20080067596A1 (en) | 2008-03-20 |
US9070604B2 (en) | 2015-06-30 |
US20080054269A1 (en) | 2008-03-06 |
US7473971B2 (en) | 2009-01-06 |
US20070184632A1 (en) | 2007-08-09 |
US20080113487A1 (en) | 2008-05-15 |
US20080113488A1 (en) | 2008-05-15 |
JP2007165923A (ja) | 2007-06-28 |
US6803264B2 (en) | 2004-10-12 |
USRE42097E1 (en) | 2011-02-01 |
US7638805B2 (en) | 2009-12-29 |
JP6182555B2 (ja) | 2017-08-16 |
JP2010278454A (ja) | 2010-12-09 |
JP4801785B2 (ja) | 2011-10-26 |
JP4476390B2 (ja) | 2010-06-09 |
US6335231B1 (en) | 2002-01-01 |
JP2013236099A (ja) | 2013-11-21 |
USRE42139E1 (en) | 2011-02-15 |
JP2009177203A (ja) | 2009-08-06 |
JP2015099933A (ja) | 2015-05-28 |
US7476576B2 (en) | 2009-01-13 |
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