JP2019504048A - Composition for treatment of keratin substrate containing polycarbodiimide and amino compound - Google Patents

Abstract

Increasing the quality of keratin substrates comprising polycarbodiimide and its derivatives together with one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof and derivatives thereof Composition for. The present invention relates to cosmetic treatments and processes for the treatment of keratin materials, in particular hair care and hair styling, the composition comprising polycarbodiimide and alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines As well as one or more of the compounds selected from the mixture may be included in an amount sufficient to render it hydrophobic upon application to keratinous substrates, including hair fibres. It particularly comprises a hair treatment composition for one or more of durable non-permanent shaping and hair curling enhancement, improved dyeability, improved color retention and extended color durability and It is a process. [Selection figure] None

Description

(Cross-reference of related applications)
This patent application is filed on Dec. 30, 2016 and is entitled “COMPOSITIONS CONTAINING POLYCARBODIMIDES AND AMINO COMPOUNDS FOR TREATING KERATINUS SUBSTRATES”, US Non-Provisional Patent Application No. 15 / 395,453, 2016. US non-provisional patent application No. 15 / 395,484 on October 31, 2015 on the 31st of June, 2015 U.S. non-provisional patent application No. 14 / 986,283, entitled "IMIDES AND AMINO COMPOUNDS FOR TREATING KERTINOUS SUBSTRATS," filed on December 31, 2015 No. 14 / 986,114, the disclosure of which is hereby incorporated by reference as if fully rewritten herein.

(Field of Invention)
The present invention relates generally to compositions and methods for treating keratin substrates. More specifically, the present invention relates to polycarbodiimide compounds and, in certain embodiments, one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof. Wherein the combination is for durable non-permanent shaping of the at least one keratin fiber or durable retention of the non-permanent shape and protects against extrinsic damage of the keratin fiber or The present invention relates to a keratin treatment composition that provides keratin fiber repair.

  In some embodiments, the present invention further generally relates to compositions and methods for treating keratin substrates. More specifically, the present invention relates to a keratin treatment composition for enhancing style performance comprising at least one polycarbodiimide compound and an amino compound selected from polyamines and comprising at least one polyvinylamine compound.

  In some embodiments, the present invention further generally relates to compositions and methods for treating keratin substrates. More specifically, the present invention provides enhanced dyeability for shampoos, washing and other hair treatments comprising at least one polycarbodiimide compound, optionally a colorant or dye and an amino compound selected from polyamines and silicone amines. And a keratin treatment composition for any one or more of color retention enhancement and fading resistance enhancement.

  The appearance and / or condition of keratinous fibers such as keratinous substrates such as hair, skin, nails and lips is often affected by both external factors and internal factors such as aging. In particular, when a keratin substrate is exposed to environmental conditions such as high or low humidity or ultraviolet radiation from the sun, many of its desirable properties are lost and may be damaged in some cases. Keratin fibers, especially hair, are chemically damaged by severe external conditions, such as the sun, for example, surfactants, decolorization, relaxation, dyeing and permanent waving, for example heat by hair dryers or curlers and mechanical by, for example, brushing or dressing Always exposed to stress or mechanical wear. In addition, any type of hair may vary in amount and / or due to factors such as aging over time and / or natural oily stickiness, sweating, skin cell shedding from the scalp, contamination, dirt, and extreme humidity conditions. Quality may be reduced.

  The above factors can result in thinning and / or loss of hair appearance and feel, and can cause hair thinning and volume reduction. For example, under low and high humidity conditions, the hair may dry out and lose its shine or shrink and become unwieldy. Under low humidity conditions, the hair may dry, and the dried hair tends to be less shining and brittle. On the other hand, under high humidity conditions, the hair tends to lose its shape by absorbing moisture, making it difficult to handle and unattractive. In addition, physical stresses such as brushing and heating the hair can cause the hair to lose its desirable properties. The magnitude of the influence of these factors varies depending on, for example, the hair quality, length, style and environmental factors. Thus, these factors generally cause damage to the keratin fibers by affecting the hair surface protective substances (cuticles) or by changing the hair fiber interior (cortex).

  More specifically, the protective substance may be peeled off from the hair surface due to external conditions, and / or the organized structure called the α structure of the hair fiber may be destroyed, and the tensile strength may be lowered accordingly. Such damage to the hair by external factors becomes more pronounced as the hair fibers grow from the roots and the hair is exposed to such external factors for a longer period of time. In fact, hair has what can be called a “damage history” as it grows, that is, the farther away from the root, the lower the tensile strength and the greater the destruction of the α structure that has occurred so far. As a result, consumers continue to seek products such as hair care and hair cosmetic compositions that protect and enhance the appearance of hair and reduce the harmful effects of harmful environmental conditions, light damage and physical stress. Yes.

  Morphologically, hair fibers contain four structural units: cuticle, cortex, medura and intercellular cement. Robbins, C.I. R. Chemical and Physical Behavior of Human Hair, 3rd edition, Springer-Verlag (1994). The cuticle layer is located on the hair surface and consists of flat, overlapping cells (“scale”). This scale attaches to the root tip and faces the distal end (top end) of the fiber, forming a layer surrounding the hair cortex. Cortex is a major part of hair fibers. Cortex consists of spindle-shaped cells arranged along the fiber axis, that is, macrofibrils. Macrofibrils further consist of microfibrils (highly organized protein units) embedded in a matrix of amorphous protein structure. Medura is a porous region in the center of the fiber. Medura is a common part with wool fibers, but is only found in thick human hair fibers. Finally, intercellular cement is a material that binds cells together to form the main pathway for diffusion into the fiber.

  The mechanical properties of hair are determined by cortex. A two-phase model has been proposed for cortex organization. Milczarek et al., Colloid Polym. Sci. , 270, 1106-1115 (1992). In this model, impermeable microfilaments (“rods”) are oriented parallel to the fiber axis. Microfilaments are embedded in a water permeable matrix (“cement”). Within the microfilament, coiled protein molecules are arranged in a unique highly organized manner, indicating the crystallinity of the hair fibers.

  Similar to other crystal structures, hair fibers have a clear diffraction pattern when examined by wide-angle X-ray diffraction. In normal unstretched hair fibers, this pattern is called the “alpha pattern”. The alpha pattern or α structure of the hair is characterized by unique repeating intervals (9.8 Å, 5.1 Å and 1.5 Å). Any protein exhibiting this X-ray diffraction pattern is called α protein, and particularly includes human hair and nails, wool, and porcupine spines. When hair fibers are stretched in water, a new X-ray diffraction pattern called “beta pattern” with new spacing (9.8 Å, 4.65 Å and 3.3 Å) appears.

  Hair damage can occur with cuticles and / or cortex. When normal hair is damaged by heat, chemical treatment, UV irradiation and / or physical / mechanical means, numerous chemical and physical changes are induced in the hair. For example, these damaging processes can descale or damage the cuticle or break the thioester bond that retains the hydrophobic 18-methyleicosanoic acid (“18-MEA”) layer on the hair. It has been known. For this reason, it is often observed that undamaged hair exhibits significant hydrophobicity, whereas damaged hair exhibits significant hydrophilicity due to removal of surface lipids.

  For this reason, there is a need for cosmetics useful to protect the chemical and physical structure of keratin fibers from harsh external conditions and to restore the physical properties of the hair to the pre-damage state after damage due to external conditions. More specifically, there is a need for water-resistant and / or hydrophobic and / or protective substances, compositions or methods that can provide hair with a barrier that protects its cortex. Such a protective barrier should not be easily removed from the substrate over time by normal daily activities. Furthermore, the protective barrier should be shampoo resistant, wash resistant or water resistant so that it is not easily removed. Non-migrating, shampoo, wash-resistant or water-resistant cosmetic compositions, hair care compositions and skin care compositions that form deposits that do not even migrate partially to the substrate (eg clothing) that it contacts There is a need for compositions having the advantage of: It is also desirable to have a composition that does not easily “spill” or wash away from the skin and lips when exposed to water, rain, or tears. Thus, products that provide a protective barrier to the substrate and that are also shampoo-resistant, wash-resistant or water-resistant and non-migrating appear to be beneficial in the cosmetic field. For this reason, manufacturers of cosmetic products such as hair care products and skin care products continue to seek substances and ingredients that can provide such benefits.

  Furthermore, in today's market, many consumers prefer non-permanent hairstyles, ie the flexibility of the styles obtained by non-permanent hair shaping. Such non-permanent styles usually disappear when the hair gets wet, especially when the hair is washed with water and / or shampoo, or when the hair is exposed to high humidity conditions. Methods for non-permanently shaping keratin fibers include, for example, brushing, reverse hair raising, hair knitting, use of hair rollers and heated styling, optionally using commercially available styling products. Non-limiting examples of heat styling include blow drying using high temperatures, curling, curling and straightening (eg curling and heating hair setting, curling iron and / or hot / steam roller and / or flat Curling with iron, etc.).

  While such compositions and methods can result in non-permanent shaping of keratin fibers, many consumers are aware of most known materials (eg, film formers, resins, gums and / or adhesive polymers), There is also a desire for styling / molding that lasts or lasts longer than commercial products (eg, conventional hair sprays, mousses, gels and lotions) and methods using these materials and products. For example, many consumers desire compositions and methods that improve and retain non-permanent curl formation or hairstyle.

  In addition, many people want compositions and methods that retain keratin fibers such as certain non-permanent shapes or styles of hair. One commonly used method for maintaining a particular hairstyle is to use a hair spray that is usually applied after the hair is trimmed. Other methods of maintaining the shape of the hairstyle or keratin fibers include the use of mousses, gels and lotions. The materials in these compositions generally include film formers, resins, gums and / or adhesive polymers.

  This makes it more durable when trimmed / shaped / curled hair is exposed to harmful environmental and physical factors and / or wet, washed or shampooed, or There is a need for materials, compositions and methods that result in long-lasting shapes or styles.

  In order to obtain at least one of the above and other advantages, the present invention provides a polycarbodiimide compound and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof. And the combination is applied to the keratinous fiber in an amount effective to impart or improve the hydrophobicity of the keratinous fiber, thereby providing a keratinous substrate, more specifically hair, eyelashes and eyebrows. A method of protecting and / or repairing the aforementioned keratin fibers selected from: exogenous damage caused by heating, UV irradiation or chemical treatment is provided.

  In addition, the step of changing the color of the hair deposits an artificial color on the hair to give the hair a different shade or color, or lightens the hair color from a dark brown shade to a medium brown or light brown shade, for example. Sometimes. The color of the hair can be changed using permanent, semi-permanent or temporary hair coloring products.

  Many consumers want permanent color changes or long-lasting colors, and therefore use products containing permanent dyes. Conventional permanent hair dye products include dye compositions containing an oxidative dye precursor, also known as a primary intermediate or coupler. This oxidative dye precursor is a colorless or slightly colored compound that, when combined with an oxidation product, produces a colored complex by the process of oxidative condensation. Oxidized products conventionally use peroxides such as hydrogen peroxide as oxidants. Such permanent hair dye products also contain other alkalizing agents such as ammonia or monoethanolamine (MEA) to swell the hair shaft, so that small oxidative dyes can be obtained before the oxidative condensation process is completed. Molecules penetrate into cuticles and cortex. The large colored complex produced by the oxidation reaction is then trapped inside the hair fibers, thereby permanently changing the color of the hair.

  New and permanently colored hair usually exhibits a bright, brilliant and brilliant appearance. However, in just a few weeks or even shorter periods, it begins to fade due to cleaning or exposure to environmental conditions. For example, beautiful bright browns are dull and dull, beautiful shades of blondes are cheesy, bright reds are no longer so vivid and have a golden, orange or brownish that is undesirable to consumers It becomes the tone. As described herein, the inventors of the present disclosure provide compositions and methods that provide one or more benefits, including improved dyeability, improved color retention, and extended color duration. Developed.

  In an exemplary embodiment, a keratin treatment composition comprising a polycarbodiimide compound and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof. Things are disclosed. The composition comprises a polycarbodiimide compound and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, based on the total weight of the composition. A total amount of about 0.25 to about 10.0% by weight. The composition comprises a polycarbodiimide compound and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, respectively, after application to a keratin substrate. It is included in an amount sufficient to provide it with one or more of hydrophobicity or increased hydrophobicity and increased retention in the shape or profile of the keratin substrate.

  In another exemplary embodiment, a keratin substrate selected from hair, eyelashes and eyebrows is protected from exogenous damage caused by heating, UV irradiation or chemical treatment, or a keratin substrate selected from hair, eyelashes and eyebrows A method to repair after extrinsic damage caused by heating, UV irradiation or chemical treatment. The method protects a keratin substrate with a composition comprising polycarbodiimide and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof. Applying to the keratin substrate in an amount effective to repair; the polycarbodiimide compound is present at a concentration of about 0.1 to about 8% by weight, based on the total weight of the composition.

  Another embodiment of the present invention is a method of protecting a keratin substrate selected from hair, wherein the hair is chemically treated (eg, permanent dye composition, semi-permanent dyeing composition or semi-permanent). Dye the hair with a demi-permanent dyeing composition, decolorize / lighten hair with a chemical oxidant, or lighten, perm the hair with a chemical reducing agent / oxidant, Protect or repair the aforementioned keratin substrate before, during or after hair relaxation using a caustic solution composition and non-caustic solution composition, or hair straightening using a chemical hair straightener. A method comprising applying to the keratin fibers an effective amount of the composition of the present invention.

  In some embodiments, the keratin substrate in the above composition is heated and the composition is applied to the substrate before, during or after heating the substrate.

  In another exemplary embodiment, a method of durable non-permanent molding of at least one keratin substrate or durable retention of a non-permanent shape of at least one keratin substrate is disclosed. This method comprises a composition comprising a polycarbodiimide compound and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, at least as described above. Applying to one keratin substrate.

  In some embodiments, the method includes heating the keratin substrate before, during or after application of the composition.

  The present invention also relates to a method of cosmetic treatment of keratinous tissue, such as keratinous fibers, by applying the composition disclosed above to the surface of keratinous tissue, such as hair fiber cuticles.

  The present invention also relates to methods and kits for the cosmetic treatment of keratinous tissues such as keratin fibers by applying the composition disclosed above in a stepwise manner to the surface of keratinous tissues, such as hair fiber cuticles. Related. In some such embodiments, the kit includes one or more activities of the composition of the present invention prepared in one or more increased or non-increased aqueous and non-aqueous phases. One or a plurality of treatment agents selected from a packaged substance and one of the above selected from a colorant, a pigmentation agent, a permanent treatment agent, a relaxation treatment agent, a hair straightening treatment agent, and a highlight treatment agent And packaged items separately.

  In yet another exemplary embodiment, a keratin treatment composition is disclosed that includes a polycarbodiimide compound and an amino compound selected from polyvinylamine. The composition comprises a polycarbodiimide compound and an amino compound selected from polyvinylamine in a total amount of about 0.1% to about 40.0% by weight, based on the total weight of the composition. This composition is composed of a polycarbodiimide compound and an amino compound selected from polyvinylamine, respectively, with or without the use of heat after application, and maintains continuous style moisture resistance and increased styling without losing beauty. In an amount sufficient to provide one or more of the forces.

  In some embodiments, the composition comprises a polycarbodiimide compound and an amino compound selected from polyvinylamine, based on the total weight of the composition, a total amount of about 0.25 wt% to about 20 wt%, In embodiments, from about 1% to about 10% by weight, based on the total weight of the composition, and in some other embodiments, from about 1% to about 5% by weight, based on the total weight of the composition.

  In some embodiments, the composition comprises at least one polycarbodiimide compound and at least one polyvinylamine compound, wherein the ratio of polycarbodiimide to polyvinylamine in the composition is in the range of 10: 1 to 1:10. It is in.

  In some embodiments, the composition comprises a polyvinylamine compound, a polycarbodiimide compound, a cationic surfactant, a nonionic surfactant, an aminosilicone, a nonionic film former, a polyol, a propellant and water. At least one or more of each component included.

  In another exemplary embodiment, a keratin substrate selected from hair, eyelashes and eyebrows is protected from exogenous damage caused by heating, UV irradiation or chemical treatment, or a keratin substrate selected from hair, eyelashes and eyebrows A method to repair after extrinsic damage caused by heating, UV irradiation or chemical treatment. The method includes applying a composition comprising a polycarbodiimide and an amino compound selected from polyvinylamine to the keratin substrate in an amount effective to protect or repair the keratin substrate; the polycarbodiimide compound comprises the composition Present in a concentration of from about 0.01% to about 20% by weight, based on the total weight of

  In yet another exemplary embodiment, a keratin treatment composition is disclosed comprising a polycarbodiimide compound, optionally a colorant or dye, and an amino compound selected from polyamines and silicone amines. The composition includes a polycarbodiimide compound and an amino compound in a total amount of about 0.1 wt% to about 40.0 wt%, based on the total weight of the composition. The composition provides a polycarbodiimide compound and an amino compound selected from polyamine and silicone amine, respectively, in one or more of improved dyeability, improved color retention and extended color duration. Included in a sufficient amount.

  In some embodiments, the composition comprises a polycarbodiimide compound and an amino compound selected from polyamine and silicone amine, based on the total weight of the composition, a total amount of about 0.25 to about 20% by weight, In embodiments, from about 1% to about 10% by weight, based on the total weight of the composition, and in some embodiments, from about 1% to about 5% by weight, based on the total weight of the composition.

  In another exemplary embodiment, a method of treating a keratin substrate selected from hair, eyelashes and eyebrows comprises improving the dyeability of a composition comprising polycarbodiimide and an amino compound selected from polyamine and silicone amine, Applying to the keratin substrate in an amount effective to provide one or more of an improvement in color retention and an extension of color duration; the polycarbodiimide compound is based on the total weight of the composition; It is present at a concentration of 0.01 to about 20% by weight.

  In some specific embodiments, the composition comprises a polycarbodiimide compound and an amino compound selected from polyamines, along with a dye or colorant, from about 0.1% to about 40%, based on the total weight of the composition. %, In some embodiments, from about 0.25 to about 20%, based on the total weight of the composition, and in some embodiments, from about 1% to about 10%, based on the total weight of the composition. In some embodiments, from about 1% to about 5% by weight, based on the total weight of the composition. In such embodiments, the polyamine can be selected from polyvinylamine.

  In some specific embodiments, the composition comprises a polycarbodiimide compound and an amino compound selected from silicone amines in a total amount of about 0.1 wt% to about 40 wt%, based on the total weight of the composition, In some embodiments, from about 0.25 to about 20% by weight, based on the total weight of the composition, in some embodiments, from about 1% to about 10%, based on the total weight of the composition, some In embodiments, it comprises from about 1% to about 5% by weight, based on the total weight of the composition. In such embodiments, the silicone amine can be selected from side chain silicones. In certain embodiments, the silicone amine can be amodimethicone.

  The present invention is by applying a composition comprising a polycarbodiimide compound, optionally a colorant or dye, and an amino compound selected from polyamines and silicone amines to the surface of keratinous tissue, such as a cuticle of hair fibers. Also related to the method of cosmetic treatment of keratinous tissues such as keratin fibers.

  In some embodiments, the composition is applied with a coloring process. In some such embodiments, the composition comprises a colorant or dye and an amino compound selected from polyamines.

  In some embodiments, the composition is applied at a point after the coloring process. In some such embodiments, the composition comprises an amino compound selected from silicone amines.

  In some embodiments, the composition is applied at a point before the coloring process.

  In some embodiments, the keratin substrate in the composition is heated and the composition is applied to the substrate before, during or after heating the substrate.

  Other features and advantages of the present invention will become apparent from the following more detailed description of the preferred embodiment, which illustrates, by way of example, the principles of the invention.

(Detailed description of the invention)
Except where specifically stated in the examples or otherwise, any numerical value representing the amount of components and / or reaction conditions is meant to be within 10% of the numerical value indicated in each case (eg, “about 10%” 9% to 11%, "about 2%" means 1.8% to 2.2%) and should be interpreted as being modified by the term "about".

  As used herein, the articles “a” and “an” mean one or more when applied to any feature of an embodiment of the invention described in the specification and the claims. The use of “a” and “an” does not limit its meaning to a single feature, unless specifically stated to be limited. The article “the” preceding a singular or plural noun or noun phrase represents one or more specific features and may include one or more meanings depending on the context in which it is used. . The adjective “any” means indiscriminately one, some or all of any quantity.

  “Active substance” or “weight” as used herein with respect to the percentage amount of an ingredient or ingredient refers to 100% activity of the ingredient or ingredient. Unless stated otherwise, all percentages and ratios are calculated by weight. Unless stated otherwise, all percentages are calculated based on the entire composition. Unless otherwise specified herein, “weight” or “amount” as used herein with respect to a percentage amount of a component generally refers to the amount of raw material containing that component, where the raw material is 100% or less of the component. It can be described herein as comprising activity. Thus, the weight percentage of active substance in the composition is expressed as the amount of raw material containing that active substance used, which may or may not reflect the final percentage of active substance, The final percentage is determined by the weight percent of active material in the feedstock.

  As used herein, the term “changing color” or variations thereof may refer to dyeing or coloring hair, or pigmenting hair.

  As used herein, the terms “applying a composition to keratin fibers” and “applying a composition to hair” and variations of these phrases may be used in any manner with the fiber or hair. Of at least one composition.

  As used herein, “at least one” means one or more and thus encompasses individual components and mixtures / combinations.

  “Dyeability” refers to a keratin substrate by applying a composition containing a colorant or dye to the substrate, resulting in a permanent, ie “does not wash off” or “not trial” colored application or coloring composition. Refers to the visually distinguishable coloring effect that results.

  “Color retention” and “prolongation of color duration” are intended to maintain a visually distinguishable coloring effect on a keratin substrate by applying a composition comprising a colorant or dye to the substrate, in particular the present disclosure. The composition according to the invention is used together with a comparative composition that does not contain a combination of a polycarbodiimide of the present invention and one or more amino compounds selected from polyamines and silicone amines to increase the maintenance of the coloring effect. Point to.

  As used herein, the term “comprising” (and grammatical variations thereof) is used in the generic sense of “having” or “including”. , “Consisting only of” is not used exclusively.

  As used herein, “conditioning” means giving the hair at least one of combing, ease of handling, moisturizing, gloss, gloss, softness and strain.

  As used herein, “durable conditioning” refers to treatment of keratin fibers such as hair with a composition of the present disclosure, after which the treated hair is still subjected to shampoo / wash / rinse at least once. It means that the condition is better than untreated hair. The condition of conditioning is the ease of combing of treated and untreated hair as viewed from the combing operation (gm-in) and / or the fixability of the conditioning agent to the hair and / or the measured contact angle (water droplets on the hair surface). Can be evaluated by measuring and comparing the hydrophobicity of the hair, which can be evaluated by

  As used herein, “durable shape retention” refers to treatment of keratin fibers such as hair with a composition of the present disclosure followed by at least one exposure to shampoo / wash / rinse or high humidity conditions. Nevertheless, it is meant that the treated hair exhibits the ability to retain a particular or desired shape after styling as compared to the ability to retain the particular or desired shape after styling exhibited by untreated hair. “Durable shape retention” is also related to the hydrophobicity of the hair, which can be evaluated by contact angle measurements (spreading of water droplets on the hair surface).

  As used herein, “durable molding” refers to maintaining or maintaining the shape of keratin fibers until the keratin fibers are washed with water and / or shampoos or exposed to high humidity conditions. Point to. Shape retention can be evaluated by measuring and comparing the curl retention ability of treated and untreated hair under high relative humidity conditions from curl efficiency. “Durable shaping” is also related to imparting hydrophobicity to hair that can be evaluated by contact angle measurements (spreading of water droplets on the surface of the hair).

  “Heating” refers to the use of elevated temperatures (ie, temperatures above room temperature, such as 40 ° C. or higher). In one embodiment, the heating in the method of the present invention can be effected by direct contact of at least one keratin fiber with a heat source, for example by heating styling of at least one keratin fiber. Non-limiting examples of heat styling by direct contact with at least one keratin fiber include flat ironing and curling methods using high temperatures (eg curling and heating hair setting, curling irons and / or hot rollers). Curling to be used). In another embodiment, the heating in the method of the present invention can be effected by heating at least one keratin fiber with a heat source that cannot be in direct contact with the at least one keratin fiber. Non-limiting examples of heat sources that cannot be in direct contact with at least one keratin fiber include blow dryers, food dryers, heating caps and steamers.

  As used herein, a “heat activated” composition refers to a composition that shapes at least one keratin fiber better than, for example, the same composition that is not heated during or after application of the composition. Another example is a composition that retains the shape of at least one keratin fiber better than the same composition that is not heated during or after application.

  “High humidity” as defined herein refers to atmospheric humidity above 40%.

  “Homogeneous” means having an overall appearance that is substantially uniform, ie, visually looking like a single phase emulsion and / or dispersion.

  As used herein, “keratin substrate” includes but is not limited to skin, hair and nails. As used herein, “keratin substrate” also encompasses “keratin tissue” or “keratin fibers”, as defined herein, which can be human keratin fibers, such as human hair It may be selected from hair or body hair constituting hair or eyelashes.

  As used herein, the term “style” or “styling” refers to molding, straightening, curling or placing keratin fibers, such as hair, into a particular arrangement, form or shape; or keratin fibers or other Including changing the curvature of the substrate; or rearranging the keratin fibers or other substrate to a different arrangement, form or profile; or providing / maintaining retention force to the shape or profile of the keratin fibers. In some embodiments, the retention force for the outer shape of the fiber can be expressed as an improvement in bending force characteristics and can be evaluated using a general three-point bending test.

  As used herein, the term “styling of keratin fibers” and variations thereof are understood to refer to any means or method that modifies the appearance of the spatial arrangement, shape, curvature or form of keratin fibers or hair. Is done. When the keratin fibers include human hair, the terms “styling keratin fibers” or “styling hair” also refer to curling, waving or embossing the hair, smoothing or straightening the hair, It is understood to include sharpening or providing / maintaining retention force in the shape or contour of the keratin fibers.

  As used herein, the term “treating” (and grammatical variations thereof) refers to the application of the composition of the present invention to a keratin substrate such as keratin fibers, hair or skin.

  As used herein, the term “wash cycle” refers to the step or process of washing a keratin substrate, treating the substrate with a surfactant-based product (eg, shampoo, conditioner or body wash), and then It may include washing or rinsing the substrate with water. The term “wash cycle” can also include washing or rinsing the substrate with water.

  In this specification, trade names are quoted for materials including but not limited to polymers and optional ingredients. The inventors herein do not intend to be limited to materials described and cited by a particular trade name. In the methods described and claimed herein, equivalent substances (eg, those obtained by different names or catalogs (reference numbers) from different sources than those cited by trade names) are substituted. Also good.

  All percentages and ratios are calculated by weight unless otherwise indicated. All percentages are calculated based on the total weight of the composition unless otherwise specified. The level of any component or composition relates to the activity level of that component or composition and excludes impurities such as residual solvents or residual by-products that may be present in commercial sources.

  One of the objects of the present invention is to provide a protective barrier to keratin substrates such as hair, which imparts natural / undamaged physical properties to hair, particularly damaged hair, such as hydrophobicity, combability, etc. It is to provide materials, compositions and methods that provide treated hair with durable or long-lasting physical properties that mimic natural / undamaged hair. Substances, compositions that improve the keratin substrate's resistance to humidity and other environmental conditions so that a durable non-permanent shaped retention of at least one keratin fiber or a durable retention of non-permanent shape is maintained Providing products and methods is also an object of the present invention.

  The inventors have surprisingly and unexpectedly discovered that one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof; When a cosmetic composition containing a combination with polycarbodiimide is applied to a keratin substrate such as hair, the composition enhances various properties (hydrophobicity, adhesion, chemical resistance, water resistance, etc.) It has been found that it exhibits excellent performance for substrates. In embodiments of the present disclosure, the combination of a polycarbodiimide compound and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof is a hair This combination enhances properties and increases the conditioning effect (eg, hydrophobicity, gloss and smoothness), increases hair strength, increases hair firmness and moisture resistance, and improves damaged hair condition. Improve by improving the appearance and quality of the hair (eg, smoother feel, softer feel, reduced curl, less dryness, easier to bundle). Further, the compositions according to the present disclosure provide a significant reduction in combing force that indicates that the hair is easy to comb and / or that the hair is difficult to entangle.

  Compositions according to the present disclosure have resulted in increased percent curl retention on curled / shaped hair and have been shown to have higher hair resistance to high humidity and temperature compared to compositions containing either substance alone .

  The inventors have surprisingly and unexpectedly confirmed that curled / shaped hair treated with the composition according to the present disclosure maintains its shape after shampooing / washing the hair (ie, the degree of curl retention). It is also the same or nearly the same).

  Robust to give treated hair the natural / undamaged physical properties of keratin substrates such as hair, such as durable or long-lasting physical properties that mimic natural / undamaged hair It is also an object of the present invention to provide materials, compositions and methods that result in films. Improves keratin substrate resistance to humidity and other environmental conditions and cleansing / washing so that durable non-permanent shaping retention or non-permanent shape retention of at least one keratin fiber is maintained It is also an object of the present invention to provide materials, compositions and methods. In addition, one of the objects of the present invention is to provide a protective barrier or coating that enhances or imparts the hydrophobicity, combability, etc. of hair, particularly damaged hair, and provides retention to the shape or contour of the hair. It is to provide substances, compositions and methods that result in a substrate, such as hair.

  Surprisingly, the inventors have applied a composition comprising a combination of at least one polycarbodiimide compound and at least one amino compound selected from polyvinylamine to keratin substrates such as hair, whether or not heat is present. First, it was discovered that the composition improved sustained style moisture resistance and resulted in increased styling retention. This surprising result is that a polycarbodiimide is added to a cosmetic composition containing polyvinylamine and the ratio of the polycarbodiimide to polyvinylamine-containing composition in the combination is in the range of about 1: 1 to about 1: 2, and the conditioning Only in compositions where styling performance is increased without compromising surface benefits, long-lasting hairstyles are provided, and sustained moisture resistance and styling retention are significantly increased without compromising aesthetics. It is done.

  Accordingly, in some embodiments according to the present disclosure, hair that has been treated and curled / shaped with a combination of polycarbodiimide and a polyvinylamine compound has a shape as shown by the high humidity curl retention test and the three point bend test. Maintained (ie, the curl retention of the association was higher than that observed with either compound alone) and the styling performance of the composition compared to a composition containing only one or the other of polycarbodiimide and polyvinylamine And improved.

  The inventors have surprisingly and unexpectedly discovered that a composition comprising a combination of at least one polycarbodiimide compound and at least one amino compound selected from polyamines and silicone amines, particularly where the amino compound is a silicone. When a composition selected from amines is applied to a keratin substrate such as hair in combination with a colorant or dye, the composition, with or without heat, is conventional or used with a comparable or less amount of dye. It has also been found to deposit colors more efficiently than commercial hair dyes. The inventors have surprisingly and unexpectedly repeated washing and other post-coloring treatments when applying the described composition, in particular a composition wherein the amino compound is selected from polyamines, before dyeing. It has also been discovered that the treated hair is maintained for a long time after. Thus, the compositions and methods of the present invention can provide enhanced color visibility, range, color retention and durability.

  Without being bound by any theory, the inventors of the present disclosure, when applying the keratin treatment composition of the present invention to a keratin substrate such as hair or skin, the composition reacts with each other and with the keratin substrate. The polymer is considered to form a crosslinked network. Further, the crosslinked composition improves or restores the hydrophobicity of the keratin substrate by providing a protective barrier useful in cosmetic applications, particularly but not limited to hair care, and the observations reported herein. It is believed to result in reduced performance, significantly better cosmetic styling effect, feel and appearance and reduced damage to substrates such as hair and skin. Further, the crosslinked composition improves or restores the hydrophobicity of the keratin substrate by providing a protective barrier useful for cosmetic applications, particularly but not limited to hair cosmetics, and is reported herein. It is believed that one or more of the observed performance and significant dyeability improvements, improved color retention and extended color duration will result.

  In some embodiments, the composition according to the invention comprises polycarbodiimide and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof. A composition comprising The composition may contain other ingredients suitable for hair treatment or hair repair. For example, in addition to one or more compounds selected from polycarbodiimides and alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, known solvents and / or additives Can be used to provide additional benefits to the composition. A combination of polycarbodiimide and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, are used to form the compositions of the present invention. In some cases, this results in a significant increase in the hydrophobicity of the keratin fibers.

  In some other embodiments, the composition according to the invention is a composition comprising at least one or more compounds of amino compounds selected from polycarbodiimide compounds and polyvinylamines. The composition may contain other ingredients suitable for hair treatment or hair repair. For example, in addition to amino compounds selected from polycarbodiimide compounds and polyvinylamines, known benefits of solvents and / or additives can be used to provide additional benefits to the composition.

  In yet another embodiment, the composition according to the present invention comprises at least one or more compounds of each of a polycarbodiimide compound and an amino compound, and optionally one or more dyes or colorants. It is a thing. The composition may contain other ingredients suitable for hair treatment or hair repair. For example, in addition to an amino compound selected from polycarbodiimide compounds and polyamines and silicone amines, known solvents and / or additives may be used to provide additional benefits to the composition.

  In some embodiments, the range of weight concentrations of the composition where the association provides hydrophobicity and / or retention to the shape or shape of the keratin substrate includes polycarbodiimide compounds and alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, The total amount of one or more compounds selected from polyamines and silicone amines and mixtures thereof from about 0.01% to about 10%, such as from about 0.5% to about 8%, or such as from about 1% to about 5%. Compositions wherein association of polycarbodiimide with one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof provides hydrophobicity to keratin substrates such as hair The range of weight ratios in the product, including all ranges and subranges therebetween, is from about 20: 1 to about 20: 1 or such as from about 10: 1 to about 1:10 or such as from about 20: 1 to about 1: 1 and so on. In certain embodiments, among the compounds selected from polycarbodiimides in compositions of the present disclosure that impart hydrophobicity to keratin substrates and alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof The weight ratio of the one or more compounds is about 1: 1, about 1: 2, about 1: 3, about 1: 4, about 1: 5, about 1: 7, about 1: 7, about 1: 8. About 1: 9, about 1:10, about 10: 1, about 9: 1, about 8: 1, about 7: 1, about 8: 1, about 7: 1, about 6: 1, about 5: 1. About 4: 1, about 3: 1, or about 2: 1.

Compositions comprising one or more of each of a polycarbodiimide compound and a polyvinylamine compound In various embodiments, a combination of a polycarbodiimide compound and an amino compound selected from polyvinylamine is present in a composition according to the present disclosure. Present in an amount ranging from about 0.1% to about 40%, in some embodiments from about 0.25% to about 20%, and in some further embodiments, from about 1% to about 10%. In some exemplary embodiments, the combination of the polycarbodiimide compound and an amino compound selected from polyvinylamine is present from about 0.5% to about 10% and from about 0.5% to about 5%. In yet another embodiment, the combination of polycarbodiimide compound and an amino compound selected from polyvinylamine is present at least 0.5%. In yet another embodiment, the combination of polycarbodiimide compound and an amino compound selected from polyvinylamine is present from at least 0.5% up to about 40%. In some specific embodiments, the combination of polycarbodiimide compound and an amino compound selected from polyvinylamine is present at about 5%. In some other specific embodiments, the combination of polycarbodiimide compound and an amino compound selected from polyvinylamine is present at about 2.5%. In some other specific embodiments, the combination of polycarbodiimide compound and amino compound selected from polyvinylamine is present at about 0.75%.

  Thus, combinations of polycarbodiimide compounds and amino compounds selected from polyvinylamine include about 0.1 wt%, 0.2 wt%, 0.3 wt%,. 4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17% %, 18%, 19%, 20%, 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28%, 29%, 30%, 31%, 32%, 33%, 34%, 35%, 36% , 37 wt%, 38 wt%, may be present 39% to about 40 wt%.

  The range of the weight ratio of the amino compound selected from polycarbodiimide and polyvinylamine in the composition that provides hydrophobicity to the keratin substrate such as hair ranges from about 10: 1 to about including all ranges and subranges therebetween. 1:10.

  In various embodiments, the combination of the polycarbodiimide compound and the amino compound selected from polyvinylamine is present in the composition in the amount described above, and the ratio of the amino compound selected from the polycarbodiimide compound and polyvinylamine is about It is in the range of 10: 1 to about 1:10. In some exemplary embodiments, the ratio of the amino compound selected from the polycarbodiimide compound and polyvinylamine is about 2: 1 to 1: 2. In some exemplary embodiments, the ratio of the amino compound selected from the polycarbodiimide compound and polyvinylamine is about 1: 1. In some other exemplary embodiments, the ratio of the amino compound selected from the polycarbodiimide compound and polyvinylamine is about 1: 2.

  In some embodiments, the composition according to the present disclosure includes, in addition to the polycarbodiimide compound and the polyvinylamine compound, further optional compounds described more fully herein. In some specific embodiments, the composition is selected from polymer-based (eg, cellulosic) thickeners, amphoteric surfactants, nonionic anchoring polymers, cationic surfactants, polyols and propellants. At least one or more additional compounds.

Composition comprising a polycarbodiimide compound and one or more of each of amino compounds selected from polyamines and silicone amines In various embodiments, a polycarbodiimide compound and an amino compound selected from polyamines and silicone amines. The combination is about 0.1% to about 40% in a composition according to the present disclosure, about 0.01% to about 20% in some embodiments, about 1% to about 10% in some further embodiments. Present in amounts in the range. In some exemplary embodiments, the combination of the polycarbodiimide compound and an amino compound selected from polyamine and silicone amine is present from about 0.5% to about 10% and from about 0.5% to about 5%. . In yet another embodiment, the combination of polycarbodiimide compound and an amino compound selected from polyamine and silicone amine is present at least 0.5%. In yet another embodiment, the combination of polycarbodiimide compound and amino compound selected from polyamine and silicone amine is present from at least 0.5% up to about 40%. In some specific embodiments, the combination of the polycarbodiimide compound and the amino compound selected from polyamine and silicone amine is present at about 5%. In some other specific embodiments, the combination of a polycarbodiimide compound and an amino compound selected from polyamines and silicone amines is present at about 2.5%. In some other specific embodiments, the combination of the polycarbodiimide compound and the amino compound selected from polyamine and silicone amine is present at about 0.75%.

  Thus, the combination of a polycarbodiimide compound and an amino compound selected from polyamines and silicone amines, including intermediate and intermediate increments and ranges, is about 0.1 wt%, 0.2 wt%, 0.3 wt%, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 2%, 3%, 4% %, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17%, 18%, 19%, 20%, 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28%, 29% %, 30%, 31%, 32%, 33%, 34%, 35% The amount%, 36 wt%, 37 wt%, 38 wt%, may be present 39% to about 40 wt%.

  The range of weight ratios of polycarbodiimides to amino compounds selected from polyamines and silicone amines in compositions where associations render the keratin substrate such as hair hydrophobic is about 10: 1, including all ranges and subranges in between. To about 1:10.

  In various embodiments, a combination of a polycarbodiimide compound and an amino compound selected from polyamines and silicone amines is present in the composition in the amounts described above, and the amino compound selected from polycarbodiimide compounds and polyamines and silicone amines. The ratio is in the range of about 10: 1 to about 1:10. In some exemplary embodiments, the ratio of the polycarbodiimide compound to the amino compound selected from polyamine and silicone amine is about 2: 1 to 1: 2. In some exemplary embodiments, the ratio of polycarbodiimide compound to amino compound selected from polyamine and silicone amine is about 1: 1. In some other exemplary embodiments, the ratio of the polycarbodiimide compound to the amino compound selected from polyamine and silicone amine is about 1: 2.

  In some embodiments, a composition according to the present disclosure includes a polycarbodiimide compound and an amino compound selected from polyamines and silicone amines, as well as further optional compounds described more fully herein. In some specific embodiments, the composition is selected from polymer-based (eg, cellulosic) thickeners, amphoteric surfactants, nonionic anchoring polymers, cationic surfactants, polyols and propellants. At least one or more additional compounds.

Polycarbodiimide compounds Carbodiimide groups are generally represented by the formula (I):
*-(N = C = N)-*
(I)
Is a linear triatomic moiety represented by

  At least one nitrogen is bonded to or incorporated into the main chain or other bridging group, resulting in a molecule having at least two carbodiimide groups.

によって表すことができ、
式中、Ｘ_１およびＸ_２はそれぞれ独立して、Ｏ、ＳまたはＮＨを表す。Ｒ_１およびＲ_２は、１つもしくは複数のカテナリ型（ｃａｔｅｎａｒｙ）もしくは非カテナリ型（ｎｏｎ−ｃａｔｅｎａｒｙ）の窒素、硫黄および酸素などのヘテロ原子を含む炭化水素基およびイオン性もしくは非イオン性のセグメントであり得る直鎖状もしくは分岐鎖状および環状もしくは非環状の基または１つもしくは複数のカテナリ型（ｃａｔｅｎａｒｙ）もしくは非カテナリ型（ｎｏｎ−ｃａｔｅｎａｒｙ）ヘテロ原子を含み得る一部もしくは全部がフッ素化された炭化水素基から選択され；ｎおよびｚはそれぞれ独立して、０〜２０の整数であり；Ｌ_１（カルボジイミド基のリンカー）は、Ｃ_１〜Ｃ_１８二価脂肪族炭化水素基、Ｃ_３〜Ｃ_１３二価脂環式炭化水素基、Ｃ_６〜Ｃ_１４二価芳香族炭化水素基およびＣ_３〜Ｃ_１２二価複素環基から選択され；複数のＬ_１は互いに同一であっても異なっていてもよく、別の実施形態では、式（ＩＩ）のＬ_１は、Ｃ_１〜Ｃ_１８二価脂肪族炭化水素基、Ｃ_３〜Ｃ_１３二価脂環式炭化水素基、ｍ−テトラメチルキシリレンから選択されないＣ_６〜Ｃ_１４二価芳香族炭化水素基およびＣ_３〜Ｃ_１２二価複素環基から選択され；複数のＬ_１は互いに同一であっても異なっていてもよく；
Ｅは以下の式
Ｏ−Ｒ_３−Ｏ；Ｓ−Ｒ_４−Ｓ；および
Ｒ_５−Ｎ−Ｒ_４−Ｎ−Ｒ_５；
から選択されるラジカルであり、
式中、Ｒ_３およびＲ_４はそれぞれ独立して、ハロゲン原子または１つもしくは複数のカテナリ型（ｃａｔｅｎａｒｙ）（すなわち、鎖中で炭素のみと結合している）もしくは非カテナリ型（ｎｏｎ−ｃａｔｅｎａｒｙ）ヘテロ原子を含み得る、芳香族ラジカル、脂環式ラジカル、アリールラジカルおよびアルキルラジカル（直鎖状または分岐鎖状）を含めた炭化水素ラジカルであり、Ｒ_５は、水素あるいはハロゲン原子または１つもしくは複数のカテナリ型（ｃａｔｅｎａｒｙ）（すなわち、鎖中で炭素のみと結合している）もしくは非カテナリ型（ｎｏｎ−ｃａｔｅｎａｒｙ）ヘテロ原子を含み得る炭化水素ラジカルである。 Polycarbodiimide In one embodiment, a polycarbodiimide consisting of at least two carbodiimide units as described above is represented by the formula (II):

Can be represented by
In the formula, X ₁ and X ₂ each independently represent O, S or NH. R ₁ and R ₂ are one or more catenary-type or non-catenary-type hydrocarbon groups containing heteroatoms such as nitrogen, sulfur and oxygen, and ionic or non-ionic segments Some or all of which may contain linear or branched and cyclic or acyclic groups or one or more catenary or non-catenary heteroatoms, which may be N and z are each independently an integer of 0 to 20; L ₁ (a linker of a carbodiimide group) is a C _{1 to} C ₁₈ divalent aliphatic hydrocarbon group, C ₃ -C ₁₃ divalent alicyclic hydrocarbon _group, C 6 _{-C 14} divalent aromatic hydrocarbon group and _C 3 -C ₁ It is selected from ₂ divalent heterocyclic group; a plurality of L ₁ may be the being the same or different, in another embodiment, L ₁ of formula (II), C ₁ -C ₁₈ divalent aliphatic family hydrocarbon _group, C 3 _{-C 13} divalent alicyclic hydrocarbon group, m- tetramethyl not selected from xylylene _C 6 _{-C 14} divalent aromatic hydrocarbon group and _C 3 _{-C 12} divalent heterocyclic A plurality of L ₁ may be the same or different from each other;
E represents the following formulas O—R ₃ —O; S—R ₄ —S; and R ₅ —N—R ₄ —N—R ₅ ;
A radical selected from
Wherein R ₃ and R ₄ are each independently a halogen atom or one or more catenary forms (ie, bonded to carbon only in the chain) or non-catenary forms. Hydrocarbon radicals, including aromatic radicals, alicyclic radicals, aryl radicals and alkyl radicals (straight or branched), which may contain heteroatoms, R ₅ is hydrogen or a halogen atom or one or A hydrocarbon radical that may contain multiple catenary (ie, bonded to carbon only in the chain) or non-catenary heteroatoms.

Examples of R ₁ and R ₂ can be methyl glycolate, methyl lactate, polypropylene glycol, polyethylene glycol monomethyl ether, dialkylamino alcohol.

Examples of L ₁ are tolylene, hexamethylene, hydrogenated xylylene, xylylene, 2,2,4-trimethylhexamethylene, 1,12-dodecane, norbornane, 2,4-bis- (8-octyl) -1,3. -Dioctylcyclobutane, 4,4'-dicyclohexylmethane, tetramethylxylylene, isophorone, 1,5-naphthylene, 4, 4 'diphenylmethane, 4, 4' diphenyldimethylmethane, phenylene diradical.

で表され、式中、Ｒは、アルキル基、シクロアルキル基またはアリール基（いくつかの特定の実施形態では１〜２４個の炭素原子を有する）である。 Polycarbodiimides can include polymers in which a plurality of carbodiimide groups are added to the polymer backbone. For example, US Pat. No. 5,352,400 (the disclosure of which is incorporated herein by reference for all purposes as if fully described) was derived from alpha-methylstyryl-isocyanate. Polymers and copolymers are disclosed. Such polymers have the formula (III)

In which R is an alkyl group, a cycloalkyl group, or an aryl group (in some specific embodiments, having 1 to 24 carbon atoms).

  In another embodiment, the polycarbodiimide according to the present disclosure is a polycarbodiimide having a branched chain structure as shown in Formula (IV) and Technology for Waterborne Coatings, E.I. J. et al. Glass, Chapter 8 of ACS Symposium 663, 1997; The Application of Carbide Chemistry-Coating, by J. Am. W. Taylor and D.C. R. Included are polycarbodiimides having a branched structure described in Bassett, the disclosure of which is incorporated herein by reference for all purposes as if described in its entirety.

（式中、Ｒは、アルキル基、シクロアルキル基またはアリール基（いくつかの特定の実施形態では１〜２４個の炭素原子を有する）である。）

Wherein R is an alkyl group, a cycloalkyl group or an aryl group (in some specific embodiments having 1 to 24 carbon atoms).

In one embodiment, the compositions of the present disclosure are those that do not use a polycarbodiimide having a linker L ₁ which is selected from m- tetramethylxylylene.

  Suitable polycarbodiimide compounds include, but are not limited to, those sold by suppliers Nisshinbo, Picassian and 3M. Particularly suitable polycarbodiimide compounds include, but are not limited to, CARBODILITE series, V-02, V02-L2, SV-02, E-02, V-10, SW-12G and E-03A, which are commercially available from Nishishinbo. What is known by name is mentioned.

In some embodiments, a polycarbodiimide of the present disclosure is selected from a compound of formula (II) and L ₁ (a linker of a carbodiimide group) is a C ₁ -C ₁₈ divalent aliphatic hydrocarbon group, C _3- C _{13 represents} a divalent alicyclic hydrocarbon group, a C _{3 to} C ₁₂ divalent heterocyclic group or a C _{6 to} C ₁₄ divalent aromatic hydrocarbon group, and a plurality of L ₁ are different even if they are the same as each other May be.

In other embodiments, the polycarbodiimides of the present disclosure are selected from compounds of formula (II), wherein L ₁ is not selected from m-tetramethylxylylene.

In certain embodiments, the composition of the present disclosure does not include a polycarbodiimide having a linker L ₁ selected from m-tetramethylxylylene.

  The polycarbodiimide is typically in the composition of the present disclosure, including all ranges and subranges therebetween, from about 0.01 wt% or from about 0.15 wt% to about 8 wt%, based on the total weight of the composition, In certain embodiments, it is present in an amount from about 0.2 wt% to about 7 wt%, and in certain embodiments, from about 0.25 wt% to about 5 wt%.

  In various embodiments, the amount of polycarbodiimide in the composition of the present disclosure is about 0.01 wt%, 0.05 wt%, 0.25 wt%, 0.5 wt% based on the total weight of the composition. %, 0.55%, 0.9%, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4%, 5%, 5%, 5.5%, 6%, 6.5%, 7%, 7.5% and 8% by weight.

Compositions comprising one or more of each of a polycarbodiimide and a polyvinylamine compound In various embodiments, the polycarbodiimide compound is present in a composition according to the present disclosure from about 0.01% to about 20%, some Present in an amount ranging from about 0.1% to about 15%, and in some further embodiments from about 0.1% to about 10%. In some exemplary embodiments, the polycarbodiimide compound is present from about 0.1% to about 5% and from about 0.2% to about 3%. In yet another embodiment, the polycarbodiimide compound is present at least 0.2%. In yet another embodiment, the polycarbodiimide compound is present from at least 0.2% up to about 40%. In some specific embodiments, the polycarbodiimide compound is present at about 1.5%. In some specific embodiments, the polycarbodiimide compound is present at about 0.75%. In some other specific embodiments, the polycarbodiimide compound is present at about 0.25%.

  Thus, the polycarbodiimide compound includes about 0.01 wt%, 0.05 wt%, 0.1 wt%, 0.2 wt%, 0.3 wt%,. 4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17% %, 18%, 19% to about 20% by weight.

Composition comprising a polycarbodiimide compound and one or more of each of amino compounds selected from polyamines and silicone amines In various embodiments, the polycarbodiimide compound is about 0.01% in the composition according to the present disclosure. Present in an amount ranging from about 0.1% to about 20%, in some embodiments from about 0.1% to about 15%, and in some further embodiments, from about 0.1% to about 10%. In some exemplary embodiments, the polycarbodiimide compound is present from about 0.1% to about 5% and from about 0.2% to about 3%. In yet another embodiment, the polycarbodiimide compound is present at least 0.2%. In yet another embodiment, the polycarbodiimide compound is present from at least 0.2% up to about 40%. In some specific embodiments, the polycarbodiimide compound is present at about 1.5%. In some specific embodiments, the polycarbodiimide compound is present at about 0.75%. In some other specific embodiments, the polycarbodiimide compound is present at about 0.25%.

  Thus, the polycarbodiimide compound includes about 0.01 wt%, 0.05 wt%, 0.1 wt%, 0.2 wt%, 0.3 wt%,. 4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16%, 17% %, 18%, 19% to about 20% by weight.

Amino compounds Amine In some embodiments, a composition according to the present disclosure comprises one or more amino compounds. The term “amino compound” is intended to mean any compound containing at least one primary amine group, secondary amine group, tertiary amine group or quaternary ammonium group.

  The amino compounds of the present disclosure are selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and mixtures thereof. In certain embodiments, the amino compounds of the present disclosure contain no silicon atoms or silicone moieties. In other embodiments, the amino compounds of the present disclosure include a silicon atom or a silicone moiety.

Alkyl Monoamine The alkyl monoamine of the present disclosure is an amino compound having one amino group.

Non-limiting examples of preferred alkyl monoamines include aliphatic amine compounds corresponding to formula (IA):
RN (R ′) ₂
(IA)
And salts thereof, wherein
R is a hydrocarbon radical containing at least 6 carbon atoms. Further, R can be linear or branched, acyclic or cyclic, saturated or unsaturated, aliphatic or aromatic, substituted or unsubstituted. R is usually a linear or branched acyclic alkyl or alkenyl group or an alkylphenyl group;
The radicals R ′ may be the same or different and represent H or a hydrocarbon radical containing less than 6 carbon atoms. Furthermore, the radicals R ′ may be the same or different and are linear or branched, acyclic or cyclic, saturated or unsaturated, substituted or unsubstituted. In certain embodiments, the groups R ′ may be the same or different and are H or a methyl group.

  Preferred alkyl monoamines include, but are not limited to, the following examples: dimethyl lauramine, dimethyl behenamine, dimethyl cocamine, dimethyl myristamine, dimethyl palmitamine, dimethyl stearamine, dimethyl tallow amine, dimethyl soiamine , Stearamine, soyamine, cocamine, lauramine, palmitamine, oleamine, tallow amine and mixtures thereof.

Other non-limiting examples of preferred alkyl monoamines include amidoamine compounds corresponding to formula (IIA):
RCONHR'N (R ″) ₂
(IIA)
And salts thereof, wherein
R is a hydrocarbon radical containing at least 6 carbon atoms. Further, R can be linear or branched, acyclic or cyclic, saturated or unsaturated, aliphatic or aromatic, substituted or unsubstituted. R is usually a linear or branched acyclic alkyl or alkenyl group or an alkylphenyl group;
R ′ is a divalent hydrocarbon radical containing less than 6 carbon atoms, and in certain embodiments 2 or 3 carbon atoms, and R ″ contains H or less than 6 carbon atoms. It is a hydrocarbon radical. Furthermore, R ″ is linear or branched, acyclic or cyclic, saturated or unsaturated, substituted or unsubstituted. R ″ is usually a linear or branched acyclic alkyl group or alkenyl group. In certain embodiments, R ″ is H or a methyl group.

  Preferred amidoamines include, but are not limited to, the following examples: oleamidopropyldimethylamine, stearamidepropyldimethylamine, isostearamidepropyldimethylamine, stearamideethyldimethylamine, lauramidopropyldimethylamine, myristamide Propyldimethylamine, behenamidopropyldimethylamine, dilinolamidopropyldimethylamine, palmitamidopropyldimethylamine, ricinolamidopropyldimethylamine, soyamidopropyldimethylamine, wheat germ amidopropyldimethylamine, sunflower seed amidopropyldimethylamine , Almondamidopropyldimethylamine, avocadoamidopropyldimethylamine, babasamidopropyldimethylamine, Midopropyl dimethylamine, mincamide propyl dimethylamine, emacamide propyl dimethylamine, sesame amide propyl dimethylamine, tallamido propyl dimethylamine, canola amide propyl dimethylamine, olive amide propyl dimethylamine, palmitamide propyl dimethylamine, stearamide Ethyl diethylamine and mixtures thereof.

Alkoxylated Polyamine The alkoxylated polyamine of the present disclosure is selected from amine compounds having at least two amino groups and at least one degree of alkoxylation. Alkoxylation is effected by an alkylene oxide group, which in certain embodiments is selected from ethylene oxide and propylene oxide.

Non-limiting preferred examples of suitable alkoxylated polyamines include compounds corresponding to formula (IB):
NH ₂ R (R′CHCH ₂ O) _x (R′CHCH ₂ O) _y (R′CHCH ₂ O) _z RNH ₂
(IB)
In the formula,
R is a —CH ₂ — group, —CH ₂ CH ₂ — group, —CHCH ₃ — group or —C (CH ₃ ) ₂ group or a linear or branched chain, acyclic structure containing at least 3 carbon atoms. Or represents a hydrocarbon radical that is cyclic, saturated or unsaturated, aliphatic or aromatic, substituted or unsubstituted;
x, y and z represent each independently a number from 0 to about 100;
R ′ represents hydrogen or an alkyl group, and in certain embodiments, a methyl group;
The sum of x + y + z is at least 1.

  In formula (IB), R is, in certain embodiments, a linear or branched acyclic alkyl or alkenyl group or an alkylphenyl group; x, y and z are independently of each other Certain embodiments represent numbers in the range of 2-100.

  Examples of alkoxylated polyamines corresponding to formula (IB) and used in the present disclosure include, for example, tetradecyloxypropyl-1,3-diaminopropane; C12-14 alkyloxypropyl-1,3-diaminopropane; C12 -15 alkyloxypropylamine and other similar materials commercially available from Tomah under the trade name TOMAH DA-17.

  Other examples of alkoxylated polyamines of formula (IB) include diamine compounds belonging to the JEFFAMINE series, such as the JEFFAMINE D series and JEFFAMINE ED series available from Huntsman, Salt Lake City, Utah. Examples of these Jeffamine compounds are JEFFAMINE D230, JEFFAMINE D400, JEFFAMINE D2000, JEFFAMINE D4000, JEFFAMINE HK-511, JEFFAMINE ED600, JEFFAMINE ED900 and JEFFAMINE ED2003. The JEFFAMINE D series compound is an amine-terminated PPG (polypropylene glycol), and the JEFFAMINE ED series compound is a polyether diamine based mainly on a PEG (polyethylene glycol) main chain.

Other non-limiting preferred examples of suitable alkoxylated polyamines in the diamine form include compounds corresponding to formula (IIB):
NH ₂ (CH ₂ ) _x OCH ₂ CH ₂ O (CH ₂ ) _x NH ₂
(IIB)
In which x is 2 or 3.

  Examples of alkoxylated polyamines of formula (IIB) include diamine compounds belonging to the JEFFAMINE series, such as JEFFAMINE EDR148 and JEFFAMINE EDR176, available from Huntsman, Salt Lake City, Utah.

に対応する化合物が挙げられ、式中、
Ｒは、水素、−ＣＨ_２または−Ｃ_２Ｈ_５であり、
ｎ＝０または１であり、
ｘ、ｙおよびｚは互いに独立して、０〜１００の数を表し、ｘ＋ｙ＋ｚの合計は少なくとも１である。 Further non-limiting preferred examples of alkoxylated polyamines in the triamine form include formula (IIIB):

And a compound corresponding to
R is hydrogen, —CH ₂ or —C ₂ H ₅ ;
n = 0 or 1;
x, y and z each independently represent a number from 0 to 100, and the sum of x + y + z is at least 1.

  Examples of alkoxylated polyamines corresponding to formula (IIIB) and used in the present disclosure include triamine compounds belonging to the JEFFAMINE series, such as the JEFFAMINE T series available from Huntsman Corporation of Salt Lake City, Utah. Examples of JEFFAMINE T series compounds include JEFFAMINE T403, JEFFAMINE T3000, and JEFFAMINE T5000. The JEFFAMINE T series compounds are triamines made by reacting PO with a triol initiator and then aminating the terminal hydroxyl group.

が挙げられ、
式（ＩＶＢ）中のＲは獣脂由来のアルキル基を表し、式（ＶＢ）中のＲはヤシ油由来のアルキル基を表し；
式（ＩＶＢ）および（ＶＢ）の両式中のｎは、合計値が１０〜２０の範囲内にあり；
式（ＩＶＢ）および（ＶＢ）の両式中のｍは、２〜６の範囲内の値を有し；
式（ＩＶＢ）および（ＶＢ）の両式中のｘは、２〜４の範囲内の値を有する。 Another type of preferred alkoxylated polyamine includes compounds of the following formulas (IVB) and (VB):

Are mentioned,
R in Formula (IVB) represents an alkyl group derived from tallow; R in Formula (VB) represents an alkyl group derived from coconut oil;
N in both formulas (IVB) and (VB) has a total value in the range of 10-20;
M in both formulas (IVB) and (VB) has a value in the range of 2-6;
X in both formulas (IVB) and (VB) has a value in the range of 2-4.

のＪＥＦＦＡＭＩＮＥ Ｔ−５００ポリエーテルアミンがある。 One specific triamine alkylated polyamine compound has the formula:

JEFFAMINE T-500 polyetheramine.

  Other preferred types of alkoxylated polyamines include aminosilicones having at least one degree of alkoxylation.

  Preferred examples of alkoxylated polyamines used in this disclosure include compounds of formula (IVB), (VB) and (VIB) above, such as PEG-15 tallow polyamine, PEG-15 cocopolyamine and JEFFAMINE T- 500 polyetheramine and the like.

Alkoxylated monoamine The alkoxylated monoamine of the present disclosure is selected from amine compounds having one amino group and at least one degree of alkoxylation. Alkoxylation is effected by an alkylene oxide group, which in certain embodiments is selected from ethylene oxide and propylene oxide.

Non-limiting preferred examples of suitable alkoxylated monoamines include compounds corresponding to formula (IC):
RN [(R′CHCH ₂ O) _x H] [(R′CHCH ₂ O) _y H]
(IC)
In which R is a hydrocarbon radical containing at least 6 carbon atoms. R may be linear or branched, acyclic or cyclic, saturated or unsaturated, aliphatic or aromatic, substituted or unsubstituted;
x and y independently of each other represent a number from 0 to 100, provided that the sum of x + y is greater than 0;
The groups R ′ may be the same or different and represent hydrogen or an alkyl group such as a methyl group.

  Usually, R is a linear or branched acyclic alkyl or alkenyl group or an alkylphenyl group; x and y are each independently a number of 0 to 30, independently of each other. Usually, one R 'group is hydrogen and the other R' group is methyl.

  Examples of preferred alkoxylated monoamines corresponding to formula (IC) and used in the present disclosure include PEG-2 cocamine, PEG-3 cocamine, PEG-5 cocamine, PEG-10 cocamine, PEG-15 cocamine, PEG-20 Cocamine, PEG-2 lauramine, PEG-12 palmitamin, PEG-2 rapeseed amine, PEG-2 oleamine, PEG-5 oleamine, PEG-6 oleamine, PEG-10 oleamine, PEG-15 oleamine, PEG-20 oleamine, PEG- There are 25 oleamine and PEG-30 oleamine. Other examples include alkoxylated derivatives of soiamine, stearamine and tallow amine.

Other non-limiting examples of suitable alkoxylated monoamines include compounds corresponding to formula (IIC):
RNR ″ [(R′CHCH ₂ O) _x H]
(IIC)
In which R is a hydrocarbon radical containing at least 6 carbon atoms. R may be linear or branched, acyclic or cyclic, saturated or unsaturated, aliphatic or aromatic, substituted or unsubstituted;
x represents a number from 1 to 100;
R ′ represents hydrogen or an alkyl group such as in particular a methyl group;
R ″ is hydrogen or a hydrocarbon radical.

  R is usually a linear or branched acyclic alkyl or alkenyl group or alkylphenyl group; x is usually a number from 1 to 30.

When R ″ in formula (IIC) is a hydrocarbon radical group, this group can be linear or branched, saturated or unsaturated, substituted or unsubstituted. The hydrocarbon radical represented by R ″ may also contain alkoxylated moieties (defined by [(R′CHCH 2 O) _y H]) and / or heteroatoms such as nitrogen. When R ″ contains at least one alkoxylation moiety, the total number of alkoxylations in the formula can be in the range 1-120.

  Examples of alkoxylated monoamines corresponding to formula (IIC) and used in the present disclosure include PEG-3 tallow aminopropylamine, PEG-10 tallow aminopropylamine, PEG-15 tallow aminopropylamine and PEG-105 behenyl propylene. There is a diamine.

Further non-limiting examples of alkoxylated monoamines include compounds corresponding to formula (IIIC):
R (R′CHCH ₂ O) _x (R′CHCH ₂ O) _y NH ₂
(IIIC)
In which R is a hydrocarbon radical containing at least 6 carbon atoms. R may be linear or branched, acyclic or cyclic, saturated or unsaturated, aliphatic or aromatic, substituted or unsubstituted;
x and y independently of each other represent a number from 0 to 100, provided that the sum of x + y is greater than 0;
The groups R ′ may be the same or different and represent hydrogen or an alkyl group such as in particular a methyl group.

  Usually, R is a linear or branched acyclic alkyl or alkenyl group or an alkylphenyl group; x and y are each independently a number of 0 to 30, independently of each other.

  Examples of alkoxylated monoamines corresponding to formula (IIIC) and used in the present disclosure include polyetheramines containing monoamine groups. These polyetheramines are commercially available from Hunstman under the trade names JEFFAMINE (M series such as M-600, M-1000, M-2005 and M-2070) and SURFONAMINE series (B-60, B-100, B-200, L-100, L-200, L-207, L-300).

Polyamines Polyamines are specifically polyvinylamines, aminated polysaccharides, amine-substituted polyalkylene glycols, amine-substituted polyacrylic acid crosspolymers, amine-substituted polyacrylic acids, amine-substituted polymethacrylic acids, proteins, protein derivatives, amine-substituted polyesters, polyamino acids, It can be selected from polyalkylamines, diethylenetriamine, triethylenetetramine, spermidine, spermine and mixtures thereof. The polyamine used in the present disclosure may also be selected from aminosilicones having at least two amino groups.

Amino compounds of the present disclosure selected from polyamines are particularly in the range of 500 to 1,000,000, in certain embodiments in the range of 500 to 500,000, preferentially in the range of 500 to 100,000. May be selected from amine-containing polymers having a weight average molecular weight of As polymers containing amines, polyamines such as poly ((C2-C5) alkylenimines, especially polyethyleneimine and polypropyleneimine, especially poly (ethyleneimine); poly (allylamine); copolymers thereof with polyvinylamine and especially vinylamide; Polyamino acids having NH ₂ groups; aminodextran; amino polyvinyl alcohol; acrylamidopropylamine-based copolymers; as well as chitosan can be used.

  The polyamines of the present disclosure are also selected, in certain embodiments, from polyvinylamines that are commonly sold by BASF under the trade names LUPAMINE or LUVIQUAT. One preferred example of such a polyamine is a polyvinylamine sold by BASF in the LUVIQUAT series, such as the vinylamine / vinylformamide copolymer (INCI name) sold as LUVIQUAT9030.

  The polyamines of the present disclosure may also be selected from vinylamine / vinyl alcohol copolymers (INCI name).

  Other preferred polyamines of the present disclosure include amine-substituted polyalkylene glycols such as PEG-15 cocopolyamine and PEG-15 tallow polyamine and amine-substituted polyacrylic acid crosspolymers such as CARBOPOL AQUAC CC polymer from Lubrizol Advanced Materials. There are products on sale.

  The polyamine compounds of the present disclosure can also be selected from proteins and protein derivatives such as wheat protein, soy protein, oat protein, collagen and keratin protein.

  In one embodiment of the present disclosure, the polyamine compound is selected from a polyamino acid compound comprising lysine, a compound comprising arginine, a compound comprising histidine and a compound comprising hydroxylysine. Non-limiting examples include chitosan and polyamino acids such as polyarginine, polyhistidine, polylysine and mixtures thereof.

  In one preferred embodiment of the present disclosure, the amino compound of the present disclosure comprises a polyvinylamine, such as the vinylamine / vinylformamide copolymer (INCI name) sold by BASF as LUVIQUAT9030; the alkoxylated polyamine corresponding to formula (IIIB) For example JEFFAMINE T403, JEFFAMINE T3000 and JEFFAMINE T5000 (especially corresponding to formula (VIB)); alkoxylated monoamines corresponding to formula (IIIC), such as JEFFAMINE M-600; and alkyls selected from aliphatic amines and amidoamines Selected from amines; and mixtures thereof.

  The alkylamine selected from aliphatic amines, in certain embodiments, is dimethyllauramine, dimethylbehenamine, dimethylcocamine, dimethylmyristamine, dimethylpalmitamine, dimethyl stearamine, dimethyl tallow amine, dimethyl soiamine. , Stearamine, soyamine, cocamine, lauramine, palmitamine, oleamine, tallow amine and mixtures thereof.

  The alkylamine selected from amidoamines, in certain embodiments, is stearamidopropyldimethylamine, isostearamidopropyldimethylamine, stearamideethyldimethylamine, lauramidopropyldimethylamine, behenamidopropyldimethylamine, dilinol. Selected from amidopropyldimethylamine, babasamidopropyldimethylamine, cocamidopropyldimethylamine, stearamide ethyldiethylamine and mixtures thereof.

  Amino compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and mixtures thereof are usually based on the total weight of the composition, including any ranges and subranges therebetween, in the compositions of the present disclosure, In an amount from about 0.15% to about 8%, in certain embodiments from about 0.2% to about 7%, and in certain embodiments, from about 0.25% to about 5%. Exists.

  In various embodiments, the amount of amino compound in the composition of the present disclosure is about 0.25%, 0.5%, 0.55%, 0.9% based on the total weight of the composition. %, 1%, 1.5%, 2%, 2.5%, 3%, 3.5%, 4%, 4.5%, 5%, 5.5% %, 6%, 6.5%, 7%, 7.5% and 8% by weight.

Aminosilicone compounds The composition according to the invention comprises one or more aminosilicone compounds. The term “aminosilicone compound” and alternative “silicone amine” means any silicone containing at least one primary amine group, secondary amine group, tertiary amine group or quaternary ammonium group. It shall be.

（式中、ｘ’およびｙ’は、重量平均分子量（Ｍｗ）が約５０００〜５００，０００に収まる整数である）；
ｂ）式（Ｂ）に対応するアミノシリコーン化合物：
Ｒ’_ａＧ３−ａ−Ｓｉ（ＯＳｉＧ２）_ｎ−（ＯＳｉＧｂＲ’２−ｂ）_ｍ−Ｏ−ＳｉＧ３−ａ−Ｒ’_ａ （Ｂ）
（式中、
Ｇは、同一であっても異なっていてもよく、水素原子またはフェニル基、ＯＨ基もしくはＣ１〜Ｃ８アルキル基、例えばメチルまたはＣ１〜Ｃ８アルコキシ、例えばメトキシを表し、
ａは、同一であっても異なっていてもよく、０または１〜３の整数、特に０を表し；
ｂは、０または１、特に１を表し；
ｍおよびｎは、合計（ｎ＋ｍ）が１〜２０００、特に５０〜１５０の範囲内に収まる数であり、ｎが０〜１９９９、特に４９〜１４９の数を表し、ｍが１〜２０００、特に１〜１０の数を表すことが可能である；
Ｒ’は、同一であっても異なっていてもよく、式−ＣｑＨ２ｑＬを有する一価ラジカルを表し、式中、ｑは２〜８の範囲内の数であり、Ｌは以下の基：
−ＮＲ’’−Ｑ−Ｎ（Ｒ’’）_２
−Ｎ（Ｒ’’）_２
−Ｎ＋（Ｒ’’）_３Ａ−
−Ｎ＋Ｈ（Ｒ’’）_２Ａ−
−Ｎ＋Ｈ_２（Ｒ’’）Ａ−
−Ｎ（Ｒ’’）−Ｑ−Ｎ＋Ｒ’’Ｈ_２Ａ−
−ＮＲ’’−Ｑ−Ｎ＋（Ｒ’’）_２ＨＡ−
−ＮＲ’’−Ｑ−Ｎ＋（Ｒ’’）_３Ａ−
（式中、Ｒ’’は、同一であっても異なっていてもよく、水素、フェニル、ベンジルまたは飽和一価炭化水素系ラジカル、例えばＣ１〜Ｃ２０アルキルラジカルを表し；Ｑは直鎖状または分岐鎖状ＣｒＨ２ｒ基を表し、ｒは２〜６、ある特定の実施形態では２〜４の範囲内の整数であり；Ａ−は、化粧品に許容されるイオン、特にハロゲン化物、例えばフッ化物、塩化物、臭化物またはヨウ化物などを表す）
から選択される、任意選択で四級化されたアミノ基である。 Aminosilicone compounds that can be used within the scope of the present invention include:
Polysiloxane corresponding to formula (A):

(Wherein x ′ and y ′ are integers having a weight average molecular weight (Mw) of about 5000 to 500,000);
b) Aminosilicone compound corresponding to formula (B):
_{R 'a G3-a-Si} (OSiG2) n - (OSiGbR'2-b) m -O-SiG3-a-R' a (B)
(Where
G may be the same or different and represents a hydrogen atom or a phenyl group, an OH group or a C1-C8 alkyl group, such as methyl or C1-C8 alkoxy, such as methoxy,
a may be the same or different and represents 0 or an integer of 1 to 3, especially 0;
b represents 0 or 1, in particular 1;
m and n are numbers in which the total (n + m) falls within the range of 1 to 2000, particularly 50 to 150, n represents a number of 0 to 1999, particularly 49 to 149, and m is 1 to 2000, particularly 1 A number from 10 to 10 can be represented;
R ′ may be the same or different and represents a monovalent radical having the formula —CqH2qL, where q is a number in the range of 2-8, and L is the following group:
-NR "-QN (R") ₂
-N (R ″) ₂
−N + (R ″) ₃ A−
−N + H (R ″) ₂ A−
−N + H ₂ (R ″) A−
-N (R '') - Q -N + R''H 2 A-
-NR '' - Q-N + (R '') 2 HA-
-NR "-Q-N + (R") ₃ A-
Wherein R ″ may be the same or different and represents hydrogen, phenyl, benzyl or a saturated monovalent hydrocarbon radical such as a C1-C20 alkyl radical; Q is linear or branched Represents a chain CrH2r group, where r is an integer in the range of 2-6, and in certain embodiments in the range of 2-4; A- is a cosmetically acceptable ion, particularly a halide, such as fluoride, chloride, etc. Product, bromide or iodide)
An optionally quaternized amino group selected from

を有し「トリメチルシリルアモジメチコン」と呼ばれるシリコーンによって表され、式中、ｎおよびｍは式Ｂで上に記載した意味を有する。 A group of aminosilicone compounds corresponding to this definition (B) has the formula (C):

Represented by “trimethylsilylamodimethicone”, where n and m have the meanings described above in Formula B.

を有するシリコーンによって表され、
式中、
ｍおよびｎは、合計（ｎ＋ｍ）が１〜１０００、特に５０〜２５０、より具体的には１００〜２００の範囲内に収まり得る数であり、ｎが０〜９９９、特に４９〜２４９、より具体的には１２５〜１７５の数を表し、ｍが１〜１０００、特に１〜１０、より具体的には１〜５の数を表すことが可能であり；
Ｒ１、Ｒ２、Ｒ３は、同一であっても異なっていてもよく、ヒドロキシまたはＣ１〜Ｃ４アルコキシラジカルを表し、この場合、ラジカルＲ１〜Ｒ３のうち少なくとも１つはアルコキシラジカルを表す。 Another group of aminosilicone compounds corresponding to this definition is the following formula (D) or (E):

Represented by silicone having
Where
m and n are numbers whose total (n + m) can be within the range of 1 to 1000, particularly 50 to 250, more specifically 100 to 200, and n is 0 to 999, particularly 49 to 249, more specifically. Specifically represents a number from 125 to 175, m can represent a number from 1 to 1000, in particular from 1 to 10, more specifically from 1 to 5;
R1, R2, and R3, which may be the same or different, represent a hydroxy or a C1-C4 alkoxy radical, and in this case, at least one of the radicals R1-R3 represents an alkoxy radical.

  The alkoxy radical is a methoxy radical in certain embodiments.

  The molar ratio of hydroxy / alkoxy is in the range of 0.2: 1 to 0.4: 1 in certain embodiments, in the range of 0.25: 1 to 0.35: 1 in certain embodiments, and more Specifically, it is equal to 0.3: 1.

  The weight average molecular weight (Mw) of the silicone is in the range of 2000-1000000, more specifically 3500-200000 in certain embodiments.

式中、
ｐおよびｑは、合計（ｐ＋ｑ）が１〜１０００、具体的には５０〜３５０、より具体的には１５０〜２５０の範囲内に収まる数であり；ｐが０〜９９９、特に４９〜３４９、より具体的には１５９〜２３９の数を表し、ｑが１〜１０００、特に１〜１０、より具体的には１〜５の数を表すことが可能であり；
Ｒ１、Ｒ２は異なるものであり、ヒドロキシまたはＣ１〜Ｃ４アルコキシラジカルを表し、この場合、ラジカルＲ１またはＲ２のうち少なくとも一方はアルコキシラジカルを表す。

Where
p and q are numbers whose total (p + q) falls within the range of 1-1000, specifically 50-350, more specifically 150-250; p is 0-999, especially 49-349, More specifically represents a number from 159 to 239, q can represent a number from 1 to 1000, in particular from 1 to 10, more specifically from 1 to 5;
R1 and R2 are different and represent a hydroxy or C1-C4 alkoxy radical, and in this case, at least one of the radicals R1 or R2 represents an alkoxy radical.

  The alkoxy radical is a methoxyci radical in certain embodiments.

  The molar ratio of hydroxy / alkoxy is generally in the range of 1: 0.8 to 1: 1.1, in certain embodiments 1: 0.9 to 1: 1, more specifically 1: Equal to 0.95.

  The weight average molecular weight (Mw) of the silicone is in the range of 2000-200000, even more specifically 5000-100000, more specifically 10000-50000 in certain embodiments.

  Commercial products corresponding to the above silicones having structure (D) or (E) may contain one or more other aminosilicone compounds in the composition that differ from formula (D) or (E).

  A product containing an aminosilicone compound having the structure (D) is sold by Wacker under the name BELSIL ADM652.

  A product containing an aminosilicone compound having the structure (E) is sold under the name FLUID WR1300® by Wacker.

  When using these aminosilicone compounds, one particularly advantageous embodiment consists in using it in the form of an oil-in-water emulsion. The oil-in-water emulsion may contain one or more surfactants. The surfactant may be of any nature, but in certain embodiments is cationic and / or nonionic. The number average size of the silicone particles in the emulsion is generally in the range of 3 nm to 500 nm. In certain embodiments, particularly for aminosilicone compounds having formula (E), the particle size ranges from 5 nm to 60 nm (including boundary values), and in certain embodiments, from 10 nm to 50 nm (including boundary values). Use the microemulsion inside. Therefore, in the present invention, a microemulsion of an aminosilicone compound having the formula (E) sold as FINISH CT96E (registered trademark) or SLM28020 (registered trademark) by Wacker can be used.

によって表され、式中、
ｍおよびｎは、合計（ｎ＋ｍ）が１〜２０００、特に５０〜１５０の範囲内に収まる数であり、ｎが０〜１９９９、特に４９〜１４９の数を表し、ｍが１〜２０００、特に１〜１０を表すことが可能であり；
Ａは、４〜８個の炭素原子、ある特定の実施形態では４個の炭素原子を含む直鎖状または分岐鎖状アルキレンラジカルを表す。このラジカルは、ある特定の実施形態では直鎖状である。 Another group of aminosilicone compounds corresponding to this definition includes the following formula (F):

Represented by:
m and n are numbers in which the total (n + m) falls within the range of 1 to 2000, particularly 50 to 150, n represents a number of 0 to 1999, particularly 49 to 149, and m is 1 to 2000, particularly 1 Can represent -10;
A represents a linear or branched alkylene radical containing 4 to 8 carbon atoms, and in certain embodiments 4 carbon atoms. This radical is linear in certain embodiments.

  The weight average molecular weight (Mw) of these aminosilicone compounds is in the range of 2000 to 1000000, even more specifically 3500 to 200000 in certain embodiments.

  A preferred silicone of formula (F) is Amodimethicone (INCI name) sold by Dow Corning under the trade name XIAMETER® MEM-8299 Cation Emulsion.

によって表され、式中、
ｍおよびｎは、合計（ｎ＋ｍ）が１〜２０００、特に５０〜１５０の範囲内に収まる数であり、ｎが０〜１９９９、特に４９〜１４９の数を表し、ｍが１〜２０００、特に１〜１０の数を表すことが可能であり；
Ａは、４〜８個の炭素原子、ある特定の実施形態では４個の炭素原子を含む直鎖状または分岐鎖状アルキレンラジカルを表す。このラジカルは、ある特定の実施形態では分岐鎖状である。 Another group of aminosilicone compounds corresponding to this definition is the following formula (G):

Represented by:
m and n are numbers in which the total (n + m) falls within the range of 1 to 2000, particularly 50 to 150, n represents a number of 0 to 1999, particularly 49 to 149, and m is 1 to 2000, particularly 1 A number from 10 to 10 can be represented;
A represents a linear or branched alkylene radical containing 4 to 8 carbon atoms, and in certain embodiments 4 carbon atoms. This radical is branched in certain embodiments.

  The weight average molecular weight (Mw) of these aminosilicone compounds is in the range of 500 to 1000000, even more specifically 1000 to 200000 in certain embodiments.

  Silicones having this formula include, for example, DC2-8566 Amino Fluid from Dow Corning.

式中、
Ｒ５は、１〜１８個の炭素原子を含む一価炭化水素系ラジカル、特にＣ１〜Ｃ１８アルキルまたはＣ２〜Ｃ１８アルケニルラジカル、例えばメチルを表し；
Ｒ６は、ＳｉＣ結合を介してＳｉと結合している二価炭化水素系ラジカル、特にＣ１〜Ｃ１８アルキレンラジカルまたは二価のＣ１〜Ｃ１８アルキレンオキシラジカル、例えばＣ１〜Ｃ８アルキレンオキシラジカルを表し；
Ｑ−は、ハロゲン化物イオン、特に塩化物などの陰イオンまたは有機酸塩（例えば、酢酸塩）であり；
ｒは、２〜２０、特に２〜８の平均統計値を表し；
ｓは、２０〜２００、特に２０〜５０の平均統計値を表す。 c) Aminosilicone compound corresponding to formula (H):

Where
R5 represents a monovalent hydrocarbon radical containing 1 to 18 carbon atoms, in particular a C1 to C18 alkyl or C2 to C18 alkenyl radical, for example methyl;
R6 represents a divalent hydrocarbon radical bonded to Si via a SiC bond, in particular a C1-C18 alkylene radical or a divalent C1-C18 alkyleneoxy radical, such as a C1-C8 alkyleneoxy radical;
Q − is a halide ion, in particular an anion such as chloride or an organic acid salt (eg acetate);
r represents an average statistic of 2-20, in particular 2-8;
s represents an average statistic value of 20 to 200, particularly 20 to 50.

  U.S. Pat. No. 4,185,087 describes more specifically such aminosilicone compounds.

式中、
Ｒ７は、同一であっても異なっていてもよく、１〜１８個の炭素原子を含む一価炭化水素系ラジカル、特にＣ１〜Ｃ１８アルキルラジカル、Ｃ２〜Ｃ１８アルケニルラジカルまたは５〜６個の炭素原子を含む環、例えばメチルを表し；
Ｒ６は、ＳｉＣ結合を介してＳｉと結合している二価炭化水素系ラジカル、特にＣ１〜Ｃ１８アルキレンラジカルまたは二価のＣ１〜Ｃ１８アルキレンオキシラジカル、例えばＣ１〜Ｃ８アルキレンオキシラジカルを表し；
Ｒ８は、同一であっても異なっていてもよく、水素原子、１〜１８個の炭素原子を含む一価炭化水素系ラジカル、特にＣ１〜Ｃ１８アルキルラジカル、Ｃ２〜Ｃ１８アルケニルラジカルまたは−Ｒ６−ＮＨＣＯＲ７ラジカルを表し；
Ｘ−は、ハロゲン化物イオン、特に塩化物などの陰イオンまたは有機酸塩（例えば、酢酸塩）であり；
ｒは、２〜２００、特に５〜１００の平均統計値を表す； d) Quaternary ammonium silicones having the formula (I):

Where
R7 may be the same or different and is a monovalent hydrocarbon radical containing 1 to 18 carbon atoms, in particular a C1 to C18 alkyl radical, a C2 to C18 alkenyl radical or 5 to 6 carbon atoms. Represents a ring containing, for example methyl;
R6 represents a divalent hydrocarbon radical bonded to Si via a SiC bond, in particular a C1-C18 alkylene radical or a divalent C1-C18 alkyleneoxy radical, such as a C1-C8 alkyleneoxy radical;
R8 may be the same or different and is a hydrogen atom, a monovalent hydrocarbon radical containing 1 to 18 carbon atoms, in particular a C1 to C18 alkyl radical, a C2 to C18 alkenyl radical, or -R6-NHCOR7. Represents a radical;
X- is a halide ion, in particular an anion such as chloride or an organic acid salt (eg acetate);
r represents an average statistic of 2 to 200, in particular 5 to 100;

  These silicones are described, for example, in patent application EP-A 0 530 974.

式中、
Ｒ１、Ｒ２、Ｒ３およびＲ４は、同一であっても異なっていてもよく、Ｃ１〜Ｃ４アルキルラジカルまたはフェニル基を表し；
Ｒ５は、Ｃ１〜Ｃ４アルキルラジカルまたはヒドロキシル基を表し；
ｎは、１〜５の範囲内の整数であり；
ｍは、１〜５の範囲内の整数であり；
ｘは、アミン数が０．０１〜１ｍｅｑ／ｇになるよう選択される； e) Aminosilicone compound having formula (J):

Where
R1, R2, R3 and R4 may be the same or different and represent a C1-C4 alkyl radical or a phenyl group;
R5 represents a C1-C4 alkyl radical or a hydroxyl group;
n is an integer in the range of 1-5;
m is an integer in the range of 1-5;
x is selected such that the amine number is 0.01-1 meq / g;

  f) (AB) n-type multi-block polyoxyalkylenated aminosilicone compound, wherein A is a polysiloxane block and B is a polyoxyalkylenated block containing at least one amine group.

The silicone described above, in certain embodiments, has a repeating unit having the general formula:
_{[- (SiMe 2 O) x} SiMe 2 -R-N (R '') - R'-O (C 2 H 4 O) a (C 3 H 6 O) b -R'-N (H) -R -] or _{[- (SiMe 2 O) x} SiMe 2 -R-N (R '') - R'-O (C 2 H 4 O) a (C 3 H 6 O) b -]
Is composed of:
a is an integer greater than or equal to 1, in certain embodiments in the range of 5 to 200, more specifically in the range of 10 to 100;
b is an integer comprised between 0 and 200, in certain embodiments an integer in the range of 4 to 100, more specifically an integer of 5 to 30;
x is an integer in the range of 1 to 10000, more specifically 10 to 5000;
R ″ is a hydrogen atom or methyl;
R may be the same or different and represents a divalent linear or branched C2-C12 hydrocarbon-based radical optionally containing one or more heteroatoms such as oxygen; In certain embodiments, R represents an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, or a —CH ₂ CH ₂ CH ₂ OCH (OH) CH ₂ — radical. Preferentially, R represents a —CH ₂ CH ₂ CH ₂ OCH (OH) CH ₂ — radical;
R ′ may be the same or different and represents a divalent linear or branched C2-C12 hydrocarbon radical optionally containing one or more heteroatoms such as oxygen; In certain embodiments, R ′ represents an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, or a —CH ₂ CH ₂ CH ₂ OCH (OH) CH ₂ — radical. Representation; preferentially, R ′ represents —CH (CH ₃ ) —CH ₂ —.

  The siloxane block comprises 50-95 mol%, more specifically 70-85 mol% of the total weight of the silicone in certain embodiments.

  The amine content is, in certain embodiments, 0.02-0.5 meq / g of the copolymer in a 30% dipropylene glycol solution, more specifically 0.05-0.2.

  The weight average molecular weight (Mw) of the silicone is in the range of 5000 to 1000000, more specifically 10,000 to 200000 in certain embodiments.

  Mention may be made, in particular, of silicones sold under the name SILSOFT A-843 or SILSOFT A + from Momentive.

式中、Ｒ、Ｒ’およびＲ’’は、同一であっても異なっていてもよく、それぞれＣ１〜Ｃ４アルキル基またはヒドロキシル基を表し、ＡはＣ３アルキレン基を表し、ｍおよびｎは、化合物の重量平均分子質量が約５０００〜５００，０００になるものである；

式中、
ｘおよびｙは１〜５０００の範囲内の数であり；ある特定の実施形態では、ｘは１０〜２０００、特に１００〜１０００の範囲内にあり；ある特定の実施形態では、ｙは１〜１００の範囲内にあり；
Ｒ１およびＲ２は、同一であっても異なっていてもよく、ある特定の実施形態では同一であり、６〜３０個の炭素原子、ある特定の実施形態では８〜２４個の炭素原子、特に１２〜２０個の炭素原子を含む、直鎖状または分岐鎖状の飽和または不飽和アルキルラジカルであり；
Ａは、２〜８個の炭素原子を含む直鎖状または分岐鎖状アルキレンラジカルを表す。 g) Alkylaminosilicone compounds corresponding to the following formulas (K ′ and K):

Wherein R, R ′ and R ″ may be the same or different and each represents a C1-C4 alkyl group or a hydroxyl group, A represents a C3 alkylene group, and m and n are compounds. The weight average molecular mass of which is about 5000 to 500,000;

Where
x and y are numbers in the range of 1 to 5000; in certain embodiments, x is in the range of 10-2000, especially 100-1000; in certain embodiments, y is 1-100. In the range of;
R1 and R2 may be the same or different and are the same in certain embodiments and are 6 to 30 carbon atoms, in certain embodiments 8 to 24 carbon atoms, especially 12 A linear or branched, saturated or unsaturated alkyl radical containing -20 carbon atoms;
A represents a linear or branched alkylene radical containing 2 to 8 carbon atoms.

In certain embodiments, A contains 3-6 carbon atoms, especially 4 carbon atoms; in certain embodiments, A is branched. In particular, the following divalent radicals: —CH ₂ CH ₂ CH ₂ and —CH ₂ CH (CH ₃ ) CH ₂ — may be mentioned.

  In certain embodiments, R 1 and R 2 may be the same or different and are 6-30 carbon atoms, in certain embodiments 8-24 carbon atoms, especially 12-20. Saturated linear alkyl radicals containing the following carbon atoms; especially dodecyl radicals, tetradecyl radicals, pentadecyl radicals, hexadecyl radicals, heptadecyl radicals, octadecyl radicals, nonadecyl radicals and eicosyl radicals; R1 and R2 may be the same or different and are selected from hexadecyl (cetyl) and octadecyl (stearyl) radicals.

Preferentially, the silicone is of the formula (K) as follows:
x is in the range 10 to 2000, in particular 100 to 1000;
y is in the range of 1-100;
A contains 3 to 6 carbon atoms, especially 4 carbon atoms; in certain embodiments, A is branched; more specifically, A is the following divalent radical: CH 2 CH 2 CH 2 and — Selected from CH2CH (CH3) CH2-;
R1 and R2 may be the same or different and are straight chain containing 6 to 30 carbon atoms, in certain embodiments 8 to 24 carbon atoms, especially 12 to 20 carbon atoms. Saturated alkyl radicals; particularly selected from dodecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl radical and eicosyl radical; preferentially, R1 and R2 are the same or different And is selected from hexadecyl (cetyl) and octadecyl (stearyl) radicals.

  A preferred silicone of formula (K) is bis-cetearyl amodimethicone (INCI name).

  In particular, mention may be made of silicone sold under the name SILSOFT AX from Momentive.

のポリジメチルシロキサンからも選択され得る。 The aminosilicone compounds of the present disclosure include polydimethylsiloxanes containing primary amine groups on the chain ends and side chains, such as aminopropyl ends or side groups, such as formula (A), (B) or (C):

The polydimethylsiloxane may also be selected.

  In formula (A), the value of n is such that the weight average molecular weight of the silicone is 500-55000. Examples of aminosilicones (A) include those sold by Gelest under the names DMS-A11, DMS-A12, DMS-A15, DMS-A21, DMS-A31, DMS-A32 and DMS-A35. .

  In formula (B), the values of n and m are such that the weight average molecular weight of silicone is 1000 to 55000. Examples of silicone (B) include those sold by Gelest under the names AMS-132, AMS-152, AMS-162, AMS-163, AMS-191 and AMS-1203.

  In the formula (C), the value of n is such that the weight average molecular weight of the silicone is 500 to 3000. Examples of silicone (C) include those sold by Gelest under the names MCR-A11 and MCR-A12.

  In certain embodiments, the aminosilicone compounds according to the present invention are amodimethicone (INCI name), for example AMMO sold under the trade name KF8020 from the supplier Shin Etsu or under the trade name SILSOFT 253 from the supplier MOMENTIVE PERFORMANCE MATERIALALS. Dimethicone etc. Another preferred aminosilicone compound is amodimethicone of formula (F) sold under the trade name XIAMETER® MEM-8299 Cationic Emulsion by Dow Corning.

  In another embodiment, the aminosilicone according to the invention is selected from bis-cetearyl amodimethicone (sold under the name SILSOFT AX from Momentive).

  The aminosilicone compound is typically in the composition of the present disclosure, including all ranges and subranges therebetween, from about 0.01 wt% or from about 0.15 wt% to about 8 wt%, based on the total weight of the composition. In certain embodiments from about 0.2% to about 7% by weight, and in certain embodiments from about 0.25% to about 5% by weight.

  In various embodiments, the amount of aminosilicone compound in the composition of the present disclosure is about 0.01%, 0.00.2%, 0.03% by weight, based on the total weight of the composition. 0.04 wt%, 0.05 wt%, 0.06 wt%, 0.07 wt%, 0.08 wt%, 0.09 wt%, 0.1 wt%, 0.15 wt%,. 2%, 0.25%, 0.5%, 0.55%, 0.9%, 1%, 1.5%, 2%, 2.5%, 3% %, 3.5%, 4%, 4.5%, 5%, 5.5%, 6%, 6.5%, 7%, 7.5% and 8% %.

Hair Treatment Compositions Each Containing One or More of Polycarbodiimide and Amino Compound Containing Polyvinylamine In some embodiments, the amino compound of the present disclosure is selected from polyvinylamine (vinylformamide / vinylamine copolymer).

  In certain embodiments, the amino compounds of the present disclosure contain no silicon atoms or silicone moieties. In other embodiments, the amino compounds of the present disclosure include a silicon atom or a silicone moiety.

  In various embodiments, an amino compound selected from polyvinylamine is present in a composition according to the present disclosure from about 0.01% to about 40%, in some embodiments from about 0.1% to about 20%, In such further embodiments, it is present in an amount ranging from about 0.1% to about 15%. In some exemplary embodiments, the amino compound selected from polyvinylamine is present from about 0.25% to about 10% and from about 0.5% to about 5%. In yet another embodiment, the amino compound selected from polyvinylamine is present at least 0.5%. In yet another embodiment, the amino compound selected from polyvinylamine is present from at least 0.5% up to about 40%. In some specific embodiments, the amino compound selected from polyvinylamine is present at about 1.5%. In some other specific embodiments, the amino compound selected from polyvinylamine is present at about 0.75%. In some other specific embodiments, the amino compound selected from the polyvinylamine compounds is present at about 0.25%.

  Thus, an amino compound selected from polyvinylamine includes about 0.01 wt%, 0.05 wt%, 0.1 wt%, 0.2 wt%, 0.3 wt%, including intermediate and intermediate increments and ranges. Wt%, 0.4 wt%, 0.5 wt%, 0.6 wt%, 0.7 wt%, 0.8 wt%, 0.9 wt%, 1 wt%, 2 wt%, 3 wt% 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16% Wt%, 17 wt%, 18 wt%, 19 wt%, 20 wt%, 21 wt%, 22 wt%, 23 wt%, 24 wt%, 25 wt%, 26 wt%, 27 wt%, 28 wt% 29%, 30%, 31%, 32%, 33%, 34%, 35%, 36%, 7 wt%, 38 wt%, may be present 39% to about 40 wt%.

Hair dye compositions comprising a polycarbodiimide and one or more amino compounds each selected from polyamines and aminosilicones In various embodiments, an amino compound selected from polyamines is about 0 in the composition according to the present disclosure. 0.01% to about 40%, in some embodiments from about 0.1% to about 20%, and in some further embodiments, from about 0.1% to about 15%. In some exemplary embodiments, the amino compound selected from the polyamine is present from about 0.25% to about 10% and from about 0.5% to about 5%. In yet another embodiment, the amino compound selected from the polyamine is present at least 0.5%. In yet another embodiment, the amino compound selected from the polyamine is present from at least 0.5% up to about 40%. In some specific embodiments, the amino compound selected from the polyamine is present at about 1.5%. In some other specific embodiments, the amino compound selected from the polyamine is present at about 0.75%. In some other specific embodiments, the amino compound selected from the polyamine compounds is present at about 0.25%.

  Thus, amino compounds selected from polyamines include about 0.01 wt%, 0.05 wt%, 0.1 wt%, 0.2 wt%, 0.3 wt% including increments and ranges in and between %, 0.4%, 0.5%, 0.6%, 0.7%, 0.8%, 0.9%, 1%, 2%, 3%, 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16% %, 17%, 18%, 19%, 20%, 21%, 22%, 23%, 24%, 25%, 26%, 27%, 28%, 29%, 30%, 31%, 32%, 33%, 34%, 35%, 36%, 37% %, 38 wt%, may be present 39% to about 40 wt%.

  In some specific embodiments, the polyamine is selected from polyvinylamine.

  Further, in various embodiments, an amino compound selected from silicone amines is about 0.01% to about 40%, and in some embodiments about 0.1% to about 20% in the compositions of the present disclosure. In some further embodiments, it is present in an amount ranging from about 0.1% to about 15%. In some exemplary embodiments, the amino compound selected from silicone amine is present from about 0.25% to about 10% and from about 0.5% to about 5%. In yet another embodiment, the amino compound selected from silicone amine is present at least 0.5%. In yet another embodiment, the amino compound selected from silicone amine is present from at least 0.5% up to about 40%. In some specific embodiments, the amino compound selected from silicone amine is present at about 1.5%. In some other specific embodiments, the amino compound selected from silicone amine is present at about 0.75%. In some other specific embodiments, the amino compound selected from silicone amine compounds is present at about 0.25%.

  Thus, amino compounds selected from silicone amines include about 0.01 wt%, 0.05 wt%, 0.1 wt%, 0.2 wt%, 0.3 wt%, including increments and ranges in and between Wt%, 0.4 wt%, 0.5 wt%, 0.6 wt%, 0.7 wt%, 0.8 wt%, 0.9 wt%, 1 wt%, 2 wt%, 3 wt% 4%, 5%, 6%, 7%, 8%, 9%, 10%, 11%, 12%, 13%, 14%, 15%, 16% Wt%, 17 wt%, 18 wt%, 19 wt%, 20 wt%, 21 wt%, 22 wt%, 23 wt%, 24 wt%, 25 wt%, 26 wt%, 27 wt%, 28 wt% 29%, 30%, 31%, 32%, 33%, 34%, 35%, 36%, 7 wt%, 38 wt%, may be present 39% to about 40 wt%.

  In some specific embodiments, the silicone amine is selected from side chain aminosilicones. In some examples, the silicone amine is selected from amodimethicone.

Optional colorants Colorants It is a known practice to dye hair with dye compositions containing an oxidative dye precursor, commonly known as an oxidizable base. These oxidized bases are colorless or slightly colored compounds that, when combined with the oxidation products, give colored compounds by the process of oxidative condensation. It is also known that the shading obtained with these oxidized bases can be changed by combining it with couplers or color modifiers. A wide variety of colors can be obtained by changing the molecule used as the oxidizing base and coupler. A dye composition containing an oxidation dye precursor is usually combined with an oxidation composition containing an oxidizing agent, and the oxidation composition is sometimes referred to as a “coloring composition”.

  It is also known to dye hair by direct dyeing. The process conventionally used for direct dyeing is to apply a colored molecule that has an affinity for hair and a dye to be colored directly to the hair, let it stay on the hair, and then rinse the fibers is there.

  The resulting coloration is particularly colored, but the nature of the interaction that directly binds the dye to the keratin fiber and its desorption from the surface and / or center of the fiber is its weakness of dyeing power and its It is only temporary or semi-permanent because it causes poor fixing properties.

  For certain hair coloring operations, the dye composition includes both an oxidative dye precursor and a direct dye so that other shades are obtained and the fixability of the dye / colorant to the hair is improved. Such a dye composition may be combined with an oxidizing composition.

  The oxidizing composition comprises at least one oxidizing agent, which can be selected, for example, from peroxides, persulfates, perborates, percarbonates, alkali metal bromates, ferricyanides, peroxides or mixtures thereof. . Other oxidizing agents that may be used include at least one oxidoreductase, such as two-electron oxidoreductases such as laccase, peroxidase and uricase, optionally in the presence of the respective donor or cofactor. Oxygen in the air can also be used as an oxidant.

  In one embodiment, the oxidizing agent is hydrogen peroxide present in an aqueous solution where the titer can fall within a range of 1-40 volumes, such as 5-40 volumes, or such as 5-20 volumes.

  In another embodiment, the oxidizing agent is a persulfate and / or monopersulfate, such as potassium persulfate, sodium persulfate, ammonium persulfate and mixtures thereof. In one embodiment, the oxidant is selected from hydrogen peroxide, potassium persulfate, sodium persulfate and mixtures thereof.

  The oxidizing agent is generally about 0.05 to about 50%, such as about 0.1% to about 30%, such as about 0.1% to about 20%, based on the total weight of the oxidizing composition. Or in an amount such as, for example, from about 1% to about 10% by weight.

  The oxidizing composition may contain at least one solvent selected from water, organic solvents and mixtures thereof.

  Organic solvents suitable for use in the oxidizing composition include ethanol, isopropyl alcohol, propanol, benzyl alcohol, phenylethyl alcohol, glycols and glycol ethers such as propylene glycol, hexylene glycol, ethylene glycol monomethyl, monoethyl or monobutyl ether. Propylene glycol and its ethers such as propylene glycol monomethyl ether, butylene glycol, dipropylene glycol, diethylene glycol alkyl ethers such as diethylene glycol monoethyl ether and diethylene glycol monobutyl ether, ethylene glycol, propylene glycol, butylene glycol, hexylene glycol, Propanediol Glycerol, hydrocarbons, such as straight chain hydrocarbons, mineral oil, polybutene, hydrogenated polyisobutene, hydrogenated polydecene, polydecene, squalane, petrolatum, and isoparaffins, and mixtures thereof.

  The oxidizing composition can be in the form of a powder, gel, liquid, foam, lotion, cream, mousse and emulsion.

  The dye composition containing the oxidative dye precursor is usually from about 1: 0.01 to about 1:10, such as from about 1: 0.01 to about 1: 0.05, about 1: 0.05, with the oxidative composition. To about 1: 0.1, about 1: 0.1 to about 1: 0.5, about 1: 0.5 to about 1: 1, about 1: 1 to about 1: 2, about 1: 2 to about 1: 3, about 1: 3 to about 1: 4, about 1: 4 to about 1: 5, about 1: 5 to about 1:10, and the like. In various embodiments, the dye composition containing the oxidative dye precursor includes the oxidative composition and includes from 1 to about 0.01, including increments and ranges between and between about 1: 0.01 and about 1:10. 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.2, 03, 0.4, 0.5 , 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9 and 10 in a weight ratio, Or they can be combined.

Solvent The composition according to the present disclosure further comprises a solvent suitable for the treatment of keratin fibers. Examples of suitable solvents include polycarbodiimide and as carrier and solvent for one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof. Water, in some embodiments distilled or deionized water, or organic solvents and optional colorants or dyes and mixtures thereof are included.

  Suitable organic solvents can be selected from volatile organic solvents and non-volatile organic solvents.

  Suitable organic solvents are usually C1-C4 lower alcohols, glycols, polyols, polyol ethers, hydrocarbons and oils. Examples of organic solvents include, but are not limited to, ethanol, isopropyl alcohol, benzyl alcohol, phenylethyl alcohol, isododecane, propylene glycol, pentylene glycol, hexylene glycol, glycerol and mixtures thereof.

  Other suitable organic solvents include glycol ethers such as ethylene glycol and its ethers such as ethylene glycol monomethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, propylene glycol and its ethers such as propylene glycol monomethyl ether, propylene Examples include glycol monopropyl ether, propylene glycol monobutyl ether, dipropylene glycol alkyl ether and diethylene glycol alkyl ether such as diethylene glycol monoethyl ether, diethylene glycol monobutyl ether and dipropylene glycol n-butyl ether. Glycol ethers are commercially available as Dow E series and DOW P series from Dow Chemical Company. An exemplary glycol ether used in the present invention is dipropylene glycol n-butyl ether known by the trade name DOWANOL DPnB.

  Suitable organic solvents also include synthetic oils and hydrocarbon oils, including mineral oils, petrolatum and C10-C40 hydrocarbons, which are aliphatic oils (straight, branched or cyclic), aromatic oils, aryl Aliphatic oils such as paraffins, iso-paraffins, isododecanes, aromatic hydrocarbons, polybutenes, hydrogenated polyisobutenes, hydrogenated polydecenes, polydecenes, squalene, petrolatum and isoparaffins can be silicone oils, fluorinated oils and mixtures thereof.

  The term “hydrocarbon-based oil” or “hydrocarbon oil” refers to an oil mainly containing hydrogen and carbon atoms and possibly oxygen, nitrogen, sulfur and / or phosphorus atoms. Representative examples of hydrocarbon-based oils include oils containing 8 to 16 carbon atoms, especially branched C8 C16 alkanes (also known as isoparaffins) such as isododecane (2,2,4,4,6 pentane). (Also known as methyl heptane), isodecane and isohexadecane.

Examples of silicone oils that may be useful in the present invention include non-volatile silicone oils such as polydimethylsiloxane (PDMS), pendant and / or at the end of the silicone chain, each containing 2 to 24 carbon atoms Such as polydimethylsiloxanes containing alkyl or alkoxy groups, such as phenyl silicones such as phenyltrimethicone, phenyldimethicone, phenyltrimethylsiloxydiphenylsiloxane, diphenyldimethicone, diphenylmethyldiphenyltrisiloxane and 2-phenylethyltrimethylsiloxysilicate Examples thereof include dimethicone or phenyltrimethicone of 100 cSt (100 mm ² / sec) or less.

Other representative examples of silicone oils that may be useful in the present invention include volatile silicone oils, such as linear or cyclic silicone oils, especially 2-10 silicon atoms, especially 2-7 silicon atoms. These silicones include alkyl or alkoxy groups that optionally contain 1 to 10 carbon atoms. Specific examples include dimethicone having a viscosity of 5 cSt (5 mm ² / sec) and 6 cSt (6 mm ² / sec), octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethylhexyltrisiloxane, hepta. Mention may be made of methyloctyltrisiloxane, hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane and dodecamethylpentasiloxane and mixtures thereof.

  Representative examples of fluorinated oils that may be suitable for use in the present invention include volatile fluorinated oils such as nanofluoromethoxybutane and perfluoromethylcyclopentane.

  Particularly suitable solvents for the compositions of the present disclosure include water, isododecane, ethanol and combinations thereof. The solvent is usually in a total amount within the range of about 60% to 98% by weight, and in some embodiments 80% to 96% by weight, based on the total weight of the composition, including all ranges and subranges therebetween. Exists. Thus, the solvent is about 98 wt%, 97 wt%, 96 wt%, 95 wt%, based on the total weight of the composition, including increments and ranges between and between about 40 wt% and about 98 wt%, 94 wt%, 93 wt%, 92 wt%, 91 wt%, 90 wt%, 85 wt%, 80 wt%, 75 wt%, 70 wt%, 65 wt%, 60 wt% and about 55 wt%, 50 It can be present in amounts of 48%, 46%, 45%, 44%, 42%, 40% by weight.

  In some other embodiments, the solvent of the present disclosure does not include water and / or organic solvent added to the present invention as a separate component in the present invention, and thus in the composition of the present invention. Water and / or organic solvents are present in the compositions of the present invention when accompanied by one or more ingredients of the ingredients added to the.

  When the composition of the present disclosure contains water in various embodiments, the water, including in and between increments and ranges, is about 98 wt% or less, such as about 96 wt%, based on the total weight of the composition, 95%, 90%, 85%, 80%, 75%, 70%, 65%, 60%, 55%, 50%, 48%, 46%, 45% %, 44%, 42%, 40%, 35%, 30%, 20%, 10% or 5% by weight or less.

  When the composition of the present disclosure contains the organic solvent (s) in various embodiments, the organic solvent (s) is included in the total weight of the composition, including in and between increments and ranges. Based on about 98 wt% or less, such as about 96 wt%, 95 wt%, 90 wt%, 85 wt%, 80 wt%, 75 wt%, 70 wt%, 65 wt%, 60 wt%, 55 wt%, 50 wt%, 48 wt%, 46 wt%, 45 wt%, 44 wt%, 42 wt%, 40 wt%, 35 wt%, 30 wt%, 20 wt%, 10 wt% or less, etc. May be present in total amount.

Additives The composition according to the present disclosure further comprises additives suitable for the treatment of keratin fibers.

  The composition according to the present disclosure comprises an amine compound or an amino compound (other than the amino compound of the present invention), a surfactant (anionic, nonionic, cationic and amphoteric / zwitterionic) and the polycarbodiimide of the present invention. Other additives such as anionic polymers, nonionic polymers, amphoteric polymers, polymer rheology modifiers, thickeners and / or viscosity modifiers, associative or non-associative polymeric thickeners, etc. May be included. Other suitable additives include non-polymeric thickeners, pearlescent agents, opacifiers, dyes or pigments, fragrances, mineral oils, vegetable or synthetic oils, waxes including ceramides, vitamins, UV screens, It may be selected from free radical scavengers, antidandruff agents, hair loss inhibitors, hair restorers, preservatives, pH stabilizers and solvents and mixtures thereof.

  Certain embodiments of the composition may include a stabilizer, such as sodium chloride, magnesium dichloride, or magnesium sulfate.

  The amine compound or amino compound that can be used in the composition of the present disclosure is not selected from the aminosilicones of the present invention. The term “amino” shall refer to a primary amine group, a secondary amine group, a tertiary amine group or a quaternary ammonium group.

  The amine or amino compounds that can be used in the compositions of the present disclosure can also be selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines and polyamines, particularly those that do not contain silicon atoms or silicone moieties. In some embodiments, the aminosilicones that can be used in the compositions of the present disclosure are polysiloxanes having at least one primary amine group, secondary amine group, or tertiary amine group, such as trimethylsilylamodimethicone, Quaternary ammonium silicones, (AB) n-type multiblock polyoxyalkylenated aminosilicones, alkylaminosilicones and mixtures thereof wherein A is a polysiloxane block and B is a polyoxyalkylenated block containing at least one amine group Can be selected.

  Suitable examples of amine or aminosilicone compounds include amodimethicone (for example, sold under the name KF8020 by Shin Etsu or sold under the name XIAMETER® MEM-8299 Cationic Emulsion from Dow Corning). And bis-cetearyl amodimethicone (sold under the name SILSOFT AX by Momentive).

  Suitable examples of alkyl monoamines include, but are not limited to, the following examples: dimethyl lauramine, dimethyl behenamine, dimethyl cocamine, dimethyl myristamine, dimethyl palmitamine, dimethyl stearamine, dimethyl tallow amine, Dimethyl soiamine, stearamine, soiamine, cocamine, lauramine, palmitamine, oleamine, tallow amine and mixtures thereof.

  The alkyl monoamine is not particularly limited, but may also be selected from amidoamines including the following examples: oleamidopropyldimethylamine, stearamidepropyldimethylamine, isostearamidepropyldimethylamine, stearamideethyldimethylamine, lauramidopropyl Dimethylamine, palmitamidopropyldimethylamine, stearamide ethyl diethylamine and mixtures thereof.

  The alkoxylated polyamines that can be used in the compositions of the present disclosure have at least two amino groups and in certain embodiments at least one degree of alkoxylation provided by alkylene oxide groups selected from ethylene oxide and propylene oxide. Selected from amino compounds.

  Suitable examples of alkoxylated polyamines include, but are not limited to, diamine compounds and triamine compounds belonging to the JEFFAMINE series available from Huntsman, such as the JEFFAMINE D series, JEFFAMINE ED series, JEFFAMINE EDR series, and JEFFAMINE T series. It is done.

  The alkoxylated monoamines that can be used in the compositions of the present disclosure have an amino group having an amino group and, in certain embodiments, at least one degree of alkoxylation provided by an alkylene oxide group selected from ethylene oxide and propylene oxide. Selected from compounds.

  Suitable examples include cocamine, lauramine, palmitamine, rapeseed amine, oleamine, soiamine, stearamine, tallow amine, tallow aminopropylamine, alkoxylated derivatives of behenylpropylenediamine and those of the Huntsman JEFFAMINE M series.

  Polyamines that can be used in the compositions of the present disclosure include aminosilicones, polyvinylamines, aminated polysaccharides, amine-substituted polyalkylene glycols, amine-substituted polyacrylic acid crosspolymers, amine-substituted polyacrylic acid, amine-substituted polymethacrylic acid, proteins, It may also be selected from protein derivatives, amine-substituted polyesters, polyamino acids, polyalkylamines, diethylenetriamine, triethylenetetramine, spermidine, spermine and mixtures thereof.

  Among the compounds selected from rheology modifiers and thickeners / viscosity modifiers that may be used in the compositions of the present disclosure are polycarbodiimides, alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof. One or more compounds as well as any water soluble or water dispersible compound compatible with the composition of the present disclosure, such as acrylic polymers (especially acrylic acid / C10-30 alkyl acrylic acid crosspolymers, carbomers, acrylic acid Copolymer, acrylic acid cross-polymer), non-acrylic polymer, starch, saccharide-based polymer (eg guar, guar gum), cellulosic polymer (especially hydroxyethyl cellulose, cellulose gum, alkylhydroxyethyl) Cellulose, carboxylic acid-containing cellulose / carbohydrates), non-polymeric gelling agents and polymer gelling agents, silica particles, clay, hyaluronic acid, alginate and mixtures thereof.

Other Additives Polycarboxylic Acid Polymer Compound The compound of the present disclosure, polycarboxylic acid, can be selected from anionic polymers, nonionic polymers and amphoteric polymers.

  Anionic polymers can be used in the form of solid dispersions or liquid particles (latex or pseudolatex) of the polymer because they can be soluble in a cosmetically acceptable medium or insoluble in the same medium.

を有するものなどによってもたらされ、式中、ｎは０〜１０の整数であり、Ａ_１は、任意選択で酸素または硫黄などのヘテロ原子を介して不飽和基の炭素原子またはｎが１より大きい場合は近隣するメチレン基と結合したメチレン基を表し、Ｒ_７は水素原子またはフェニル基もしくはベンジル基を表し、Ｒ_８は水素原子または低級アルキル基もしくはカルボキシル基を表し、Ｒ_９は、水素原子、低級アルキル基、ＣＨ_２−ＣＯＯＨ基、フェニル基またはベンジル基を表す。 The anionic polymer is selected from polymers containing groups derived from carboxylic acids and can have a number average molecular weight of about 500 to 5,000,000. Carboxylic acid groups are unsaturated monoacid or diacid carboxylic acid monomers such as, for example, the formula:

Wherein n is an integer from 0 to 10 and A ₁ is optionally a carbon atom of an unsaturated group or n is greater than 1 through a heteroatom such as oxygen or sulfur. When large, it represents a methylene group bonded to an adjacent methylene group, R ₇ represents a hydrogen atom, a phenyl group or a benzyl group, R ₈ represents a hydrogen atom, a lower alkyl group or a carboxyl group, and R ₉ represents a hydrogen atom. represents a lower alkyl _group, CH 2 -COOH, phenyl or benzyl group.

  In the above formula, lower alkyl groups represent groups containing 1 to 4 carbon atoms, in particular methyl and ethyl groups, in certain embodiments.

  Polycarboxylic acid compounds include acrylic acid or methacrylic acid copolymers or salts thereof, particularly acrylic acid and acrylamide copolymers sold in the form of sodium salts.

  Polycarboxylic acid compounds include acrylic acid or methacrylic acid and optionally monoethylene monomers grafted onto polyalkylene glycols such as polyethylene glycol and optionally crosslinked, such as ethylene, styrene, vinyl esters and acrylic esters Or a copolymer with a methacrylic acid ester etc. is mentioned. Examples of the polycarboxylic acid compound include methacrylic acid / acrylic acid / ethyl acrylic acid / methyl methacrylate copolymer in an aqueous dispersion.

  Polycarboxylic acid compounds include crotonic acid copolymers, such as long carbonizations such as vinyl acetate units or vinyl propionate units in the chain, and optionally allyl or methallyl esters, hydrocarbon-based chains containing at least 5 carbon atoms. And those containing other monomers such as vinyl ethers or vinyl esters of linear or branched saturated carboxylic acids having a hydrogen chain, and these polymers are optionally grafted or crosslinked, Alternatively, it may be a vinyl ester monomer, allyl ester monomer or methallyl ester monomer of another [alpha] cyclic carboxylic acid or [beta] cyclic carboxylic acid.

  Polycarboxylic acid compounds include (i) one or more maleic acid, fumaric acid, itaconic acid, allyloxyacetic acid, methallyloxyacetic acid, 3-allyloxypropionic acid, allylthioacetic acid, allylaminoacetic acid, vinylacetic acid, vinyloxyacetic acid, crotyloxy Acetic acid, 3-butenoic acid, 4-pentenoic acid, 10-undecenoic acid, allylmalonic acid, maleamic acid, itaconamic acid, N-monohydroxyalkyl-maleamic acid or N-dihydroxy-alkyl-maleamic acid and (ii) vinyl ester A copolymer of C4 to C8 monosaturated carboxylic acid selected from copolymers comprising at least one monomer selected from vinyl ether, vinyl halide, phenyl vinyl derivatives, acrylic acid and esters thereof, Anhydride functional groups are monoesterified or monoamidated optionally. Polycarboxylic acid compounds include (i) one or more maleic anhydride units, citraconic anhydride units or itaconic anhydride units, and (ii) optionally one or more acrylamides in the chain, And copolymers comprising one or more monomers selected from methacrylamide, [alpha] -olefins, acrylic or methacrylic esters, acrylic acid or methacrylic acid or allyl esters or methallyl esters containing vinylpyrrolidone groups, The anhydrous functional group is optionally monoesterified or monoamidated. Examples of the polycarboxylic acid compound include polyacrylamide containing a carboxylate group.

  Examples of the polycarboxylic acid of the present disclosure include an anionic polymer commercially available as a FIXATE series from Lubrizol, such as a branched block anionic polymer and a branched anionic acrylic acid copolymer sold as FIXATE G-100. Polyacrylic acid-2 cross polymer (FIXATE SUPERHOLD polymer), acrylic acid cross polymer-3 (FIXATE FREESTYLE polymer), polyacrylic acid-14 (FIXATE PLUS polymer), and the like, which are commercially available as CARBOPOL series from Lubrizol, for example Acrylic acid cross polymer-4 (CARBOPOL AQUA SF-2), Acrylic acid cross polymer-4 (CARBOPOL AQUA CC), etc. and I Mention may also be made of what is commercially available from nterpolymer as the SYNTRAN series, for example acrylic acid copolymer (SYNTRAN 5190), styrene / acrylate / ammonium methacrylate copolymer (SYNTRAN 5760) and ammonium acrylate copolymer (SYNTRAN KL-219C).

  Polycarboxylic acid compounds of the present disclosure also include anionic latex polymers such as acrylic copolymers and (meth) acrylate copolymer dispersions.

  Polycarboxylic acid compounds include acrylic acid or copolymers of acrylic esters, such as acrylate / t-butylacrylamide copolymers sold as ULTRAHOLD 8, especially acrylic acid / ethyl acrylate / sold as ULTRAHOLD STRONG from BASF. N-tert-butylacrylamide terpolymer, vinyl acetate / tert-butyl vinyl benzoate / crotonic acid terpolymer and in particular the crotonic acid / vinyl acetate / vinyl neododecanoate terpolymer sold by Azko Nobel as RESYN 28-29-30 Copolymers derived from crotonic acid, such as vinyl esters, vinyl ethers, vinyl halides, phenyl vinyl derivatives and acrylic acid and its Polymers derived from esters and maleic acid, fumaric acid or itaconic acid or anhydride, such as methyl vinyl ether / monoesterified maleic anhydride copolymer sold by ISP as GANTREZ AN or ES, EUDRAGIT L from Rohm Pharma Copolymers of methacrylic acid and methyl methacrylate sold as LUVIMER MAEX or MAE from BASF, vinyl acetate / crotonic acid sold as LUVISET CA66 from BASF A copolymer, a vinyl acetate / crotonic acid copolymer grafted with polyethylene glycol sold by BASF as ARITOFLEX A, and Such polymers from oveon sold by the company as Fixate G-100 and the like.

Polycarboxylic acid compounds include amphoteric polymers that can be selected from the following polymers:
Derived from copolymers having acidic vinyl units and basic vinyl units, for example carboxylic acid groups, more specifically vinyl compounds having carboxylic acid groups such as acrylic acid, methacrylic acid, maleic acid, alpha-chloroacrylic acid. Copolymers obtained by copolymerization of monomers with basic monomers derived from substituted vinyl compounds containing at least one basic atom, such as more specifically dialkylaminoalkyl methacrylates and acrylates, dialkylaminoalkyls. Such as methallylamide and acrylamide. Such compounds are described in US Pat. No. 3,836,537.

As a polycarboxylic acid compound,
At least one monomer selected from acrylic and methacrylamide in which the nitrogen atom is substituted with an alkyl group;
More specifically, one selected from acrylic acid, methacrylic acid, crotonic acid, itaconic acid, maleic acid and fumaric acid and alkyl monoesters of maleic acid or fumaric acid having 1 to 4 carbon atoms or anhydride. Or at least one acidic comonomer containing a plurality of reactive carboxylic acid groups and at least one basic comonomer such as acrylic acid and methacrylic acid and a first quaternization product of dimethylaminoethyl methacrylate with dimethyl or diethyl sulfate. And polymers containing units derived from esters having secondary, secondary, tertiary or quaternary amine substituents. Particularly preferred N-substituted acrylamide or N-substituted methacrylamide in the present invention is a compound in which an alkyl group contains 2 to 12 carbon atoms, and more specifically, N-ethylacrylamide, N-tert-butylacrylamide, N -Tert-octylacrylamide, N-octylacrylamide, N-decylacrylamide, N-dodecylacrylamide and the corresponding methacrylamide. Preferred basic comonomers include aminoethyl methacrylate, butylaminoethyl methacrylate, N, N′-dimethylaminoethyl methacrylate and N-tert-butylaminoethyl methacrylate.

  A copolymer whose CTFA (4th edition, 1991) name is an octylacrylamide / acrylate / butylaminoethyl methacrylate copolymer, for example a product sold as AMPHOMER LV71 by National Starch, acrylate sold as 28-4961 or LOVOCRYL47 / Octylacrylamide copolymers and the like are particularly used.

  Polycarboxylic acid compounds include cross-linked and acylated polyaminoamides.

  Polycarboxylic acid compounds include ethylene double bonds such as acids having 6 to 10 carbon atoms, such as adipic acid, 2,2,4-trimethyladipic acid, 2,4,4-trimethyladipic acid, terephthalic acid, etc. Examples of the acid include carboxylic acid selected from acrylic acid, methacrylic acid, itaconic acid and the like.

（ＩＩ’）
の双性イオン単位を含むポリマーが挙げられ、式中、Ｒ１１は、アクリラート基、メタクリラート基、アクリルアミド基またはメタクリルアミド基などの重合可能な不飽和基を表し、ｙおよびｚは１〜３の整数を表し、Ｒ１２およびＲ１３は、水素原子、メチル基、エチル基またはプロピル基を表し、Ｒ１４およびＲ１５は、水素原子またはＲ１４およびＲ１５の炭素原子の合計が１０を超えないようなアルキル基を表す。 As polycarboxylic acid compounds, the formula:

(II ')
In which R11 represents a polymerizable unsaturated group such as an acrylate group, a methacrylate group, an acrylamide group or a methacrylamide group, and y and z are 1 to 3 Represents an integer, R12 and R13 represent a hydrogen atom, a methyl group, an ethyl group or a propyl group; R14 and R15 represent a hydrogen atom or an alkyl group in which the total of carbon atoms of R14 and R15 does not exceed 10. .

に対応するモノマー単位を含むキトサンから誘導されるが挙げられ、
単位（Ｄ）は０〜３０パーセントの割合で存在し、単位（Ｅ）は５パーセント〜５０パーセントの割合で存在し、単位（Ｆ）は３０パーセント〜９０パーセントの割合で存在し、この単位（Ｆ）のＲ１６は式：

の基を表すことが理解され、式中、
ｑ＝０である場合、Ｒ１７、Ｒ１８およびＲ１９は、同一であっても異なっていてもよく、それぞれ水素原子、メチル残基、ヒドロキシル残基、アセトキシ残基もしくはアミノ残基、任意選択で１つもしくは複数の窒素原子が散在し、かつ／または任意選択で１つもしくは複数のアミン基、ヒドロキシル基、カルボキシル基、アルキルチオ基もしくはスルホン基で置換されたモノアルキルアミン残基またはジアルキルアミン残基、アルキル基がアミノ残基を有するアルキルチオ残基を表し、この場合、基Ｒ１７、Ｒ１８およびＲ１９のうち少なくとも１つが水素原子であるか；あるいは
ｑ＝１である場合、Ｒ１７、Ｒ１８およびＲ１９はそれぞれ、水素原子およびこれらの化合物と塩基または酸によって形成された塩も表す。 Polymers containing such units are units derived from non-zwitterionic monomers such as dimethylaminoethyl or diethylaminoethyl acrylate or methacrylate or alkyl acrylate or methacrylate, acrylamide or methacrylamide or vinyl acetate such as , Methyl methacrylate / methyldimethylcarboxymethylammonioethyl methacrylate copolymers such as those sold by Sandoz as DIAFORMER Z301 may also be included. As the polycarboxylic acid compound, the following formula:

Derived from chitosan containing monomer units corresponding to
Unit (D) is present at a rate of 0 to 30 percent, Unit (E) is present at a rate of 5 percent to 50 percent, Unit (F) is present at a rate of 30 percent to 90 percent, and this unit ( R16 of F) is the formula:

It is understood that it represents a group of
When q = 0, R17, R18 and R19 may be the same or different and each is a hydrogen atom, a methyl residue, a hydroxyl residue, an acetoxy residue or an amino residue, optionally one Or a monoalkylamine residue or dialkylamine residue, alkyl interspersed with a plurality of nitrogen atoms and / or optionally substituted with one or more amine groups, hydroxyl groups, carboxyl groups, alkylthio groups or sulfone groups The group represents an alkylthio residue having an amino residue, in which case at least one of the groups R17, R18 and R19 is a hydrogen atom; or when q = 1, R17, R18 and R19 are each hydrogen Also represented are atoms and salts formed with these compounds and bases or acids.

に対応する単位を有するポリマーが挙げられ、式中、Ｒ２０は、水素原子、ＣＨ３Ｏ基、ＣＨ３ＣＨ２Ｏ基またはフェニル基を表し、Ｒ２１は、水素原子またはメチルもしくはエチルなどの低級アルキル基を表し、Ｒ２２は、水素原子またはメチルもしくはエチルなどのＣ１〜Ｃ６低級アルキル基を表し、Ｒ２３は、メチルもしくはエチルなどのＣ１〜Ｃ６低級アルキル基または式：−Ｒ２４−Ｎ（Ｒ２２）２に対応する基を表し、Ｒ２４は基−ＣＨ２−ＣＨ２−、−ＣＨ２−ＣＨ２−ＣＨ２−または−ＣＨ２−ＣＨ（ＣＨ３）−を表し、Ｒ２２は上記の意味を有する。 As the polycarboxylic acid compound, for example, the following general formula described in French Patent No. 1400366:

In which R20 represents a hydrogen atom, a CH3O group, a CH3CH2O group or a phenyl group, R21 represents a hydrogen atom or a lower alkyl group such as methyl or ethyl, and R22 represents , A hydrogen atom or a C1-C6 lower alkyl group such as methyl or ethyl, R23 represents a C1-C6 lower alkyl group such as methyl or ethyl or a group corresponding to the formula: -R24-N (R22) 2. R24 represents the group -CH2-CH2-, -CH2-CH2-CH2- or -CH2-CH (CH3)-, wherein R22 has the above-mentioned meaning.

  Polycarboxylic acid compounds include polymers derived from N-carboxyalkylation of chitosan, such as N-carboxymethyl chitosan or N-carboxybutyl chitosan.

  Polycarboxylic acid compounds include -DXD-X type amphoteric polymers selected from:

基を表し、Ｘは記号ＥまたはＥ’を表し；ＥまたはＥ’は同一であっても異なっていてもよく、主鎖中に最大７個の炭素原子を含み、ヒドロキシル基により置換されていないか、または置換されており、酸素原子、窒素原子および硫黄原子に加えて１〜３個の芳香族環および／または複素環を含み得る、直鎖または分岐鎖を有するアルキレン基である二価の基を表し；酸素原子、窒素原子および硫黄原子はエーテル基、チオエーテル基、スルホキシド基、スルホン基、スルホニウム基、アルキルアミン基またはアルケニルアミン基、ヒドロキシル基、ベンジルアミン基、アミンオキシド基、第四級アンモニウム基、アミド基、イミド基、アルコール基、エステル基および／またはウレタン基の形態で存在する）
の単位を少なくとも１つ含む化合物に対するクロロ酢酸またはクロロ酢酸ナトリウムの作用によって得られるポリマー。 a) Formula:
-D-X-D-X-D- (V ')
(Where D is

X represents the symbol E or E ′; E or E ′ may be the same or different and contains up to 7 carbon atoms in the main chain and is not substituted by a hydroxyl group Or a divalent alkylene group having a straight chain or a branched chain, which may be substituted and may contain 1 to 3 aromatic rings and / or heterocyclic rings in addition to oxygen, nitrogen and sulfur atoms Represents oxygen group, nitrogen atom and sulfur atom are ether group, thioether group, sulfoxide group, sulfone group, sulfonium group, alkylamine group or alkenylamine group, hydroxyl group, benzylamine group, amine oxide group, quaternary (Ammonium group, amide group, imide group, alcohol group, ester group and / or urethane group)
A polymer obtained by the action of chloroacetic acid or sodium chloroacetate on a compound containing at least one unit of

基を表し、Ｘは記号ＥまたはＥ’、少なくとも１回はＥ’を表し；Ｅは上記の意味を有し、Ｅ’は、主鎖中に最大７個の炭素原子を有し、１つまたは複数のヒドロキシル基で置換されていないか、または置換されており、１つまたは複数の窒素原子を含む、直鎖または分岐鎖を有するアルキレン基である二価の基であり、窒素原子は、任意選択で酸素原子が散在し、必ず１つもしくは複数のカルボキシル官能基または１つもしくは複数のヒドロキシル官能基を含み、クロロ酢酸またはクロロ酢酸ナトリウムとの反応によりベタイン化されたアルキル鎖で置換されている）
を有するポリマー。 b) Formula:
-D-X-D-X- (VI ')
(Where D is

X represents the symbol E or E ′, at least once represents E ′; E has the meaning given above, E ′ has a maximum of 7 carbon atoms in the main chain and is one Or a divalent group that is a linear or branched alkylene group that is unsubstituted or substituted with a plurality of hydroxyl groups and contains one or more nitrogen atoms, Optionally interspersed with alkyl chains interspersed with oxygen atoms, necessarily containing one or more carboxyl functions or one or more hydroxyl functions and betaened by reaction with chloroacetic acid or sodium chloroacetate Yes)
A polymer having

  The polycarboxylic acid compound was partially modified by semiamidation with N, N-dialkylaminoalkylamine such as N, N-dimethylaminopropylamine or by semiamidation with N, N-dialkylaminoalkanol (C1 to C1). C5) alkyl vinyl ether / maleic anhydride copolymers. These copolymers can also contain other vinyl comonomers such as vinylcaprolactam.

  The most preferred of the amphoteric polymers described above are octylacrylamide / acrylate / butylaminoethyl methacrylate copolymers, such as those sold by National Star as AMPHOMER, AMPHOMER LV71 or LOVOCRYL47, and sold by, for example, Sandoz as DIAFORMER Z301. A copolymer of methyl methacrylate / methyldimethylcarboxy-methylammonioethyl methacrylate.

  The polycarboxylic acids of the present disclosure may be selected from compounds known to be used as rheology modifiers or thickeners in cosmetic compositions. Such polymers include anionic and amphoteric polymers such as crosslinked homopolymers of acrylic acid, associative polymers, non-associative thickening polymers and water-soluble thickening polymers. Such polymers can also be selected from nonionic, anionic, cationic and amphoteric polymers. Examples of the rheology modifier or thickener that can be used include the above-mentioned polycarboxylic acid compounds.

  The amphiphilic polymer is optionally saturated or unsaturated, aromatic or non-aromatic, linear or branched, optionally comprising one or more oxyalkylene (oxyethylene and / or oxypropylene) units. It may contain a hydrophobic chain that is a C6-C30 hydrocarbon-based chain.

Representative examples of such amphiphilic polymers include:
Nonionic amphiphilic polymers containing hydrophobic chains such as:
A copolymer of C1-C6 alkyl (meth) acrylic acid and a copolymer of amphiphilic monomers containing a hydrophobic chain;
A copolymer of a hydrophilic (meth) acrylic acid and a copolymer of a hydrophobic monomer containing at least one hydrophobic chain, such as a polyethylene glycol methacrylate / lauryl methacrylate copolymer; at least one that is cross-linked or non-cross-linked Anionic amphiphilic polymers containing two hydrophobic chains are free or derived from one or more ethylenically unsaturated monomers having carboxylic acid functional groups that are partially or fully neutralized From at least one hydrophilic unit, at least one hydrophobic unit derived from one or more ethylenically unsaturated monomers having a hydrophobic side chain, and optionally from one or more polyunsaturated monomers At least one cross-linked unit derived.

  Examples of anionic amphiphilic polymers include CARBOPOL ETD-2020 (acrylic acid / C10-C30 alkyl methacrylate cross-linked copolymer sold by Noveon); CARBOPOL 1382, PEMULEN TR1 and PEMULEN TR2 (sold by Noveon). Acrylic acid / C10-C30 alkyl acrylate cross-linked copolymer), methacrylic acid / ethyl acrylate / oxyethylenated stearyl methacrylate copolymer (55/35/10); (meth) acrylic acid / ethyl acrylate / 25EO oxyethylene Behenyl methacrylate copolymer (ACULYN28 sold by Rohm and Haas) and methacrylic acid / ethyl acrylate / steareth- 10 allyl ether crosslinked copolymers.

  Other examples include cross-linked acrylic polymers such as those commercially available as the CARBOPOL SF series, such as ethyl acrylate / acrylic copolymers sold under the name CARBOPOL SF1® by LUBRIZOL and the INCI name being an acrylate copolymer A methacrylic acid copolymer etc. are mentioned.

  As another example, anions also known as carbomers, acrylate copolymers and anionic thickening polymers selected from crosslinked terpolymers of methacrylic acid, ethyl acrylate and polyethylene glycol (10EO stearyl alcohol ether (Steareth 10)) An aqueous emulsion containing 30 percent of a crosslinked terpolymer of polymers such as methacrylic acid, ethyl acrylate and steareth-10-allyl ether (40/50/10) and sold under the names SALCARE SC80 and SALCARE SC90 from ALLIED COLLOIDS Products that have been released.

Anionic thickening polymers are:
Terpolymers formed from maleic anhydride / C30-C38 alpha-olefin / alkyl maleate, such as the product sold under the name PERFORMA 1608 from NEWPHASE TECHNOLOGIES (maleic anhydride / C30-C38 alpha-olefin / isopropyl maleate) Copolymer) and the like;
(A) 20 weight percent to 70 weight percent of a carboxylic acid having alpha, beta-monoethylenic unsaturation; (b) a non-surfactant monomer 20 having alpha, beta-monoethylenic unsaturation different from (a). And (c) formed from 0.5 weight percent to 60 weight percent of a nonionic monourethane that is the reaction product of a monohydroxyl surfactant and a monoisocyanate having monoethylenic unsaturation. (3) a carboxylic acid formed from at least two monomers, at least one of the two monomers having an alpha, beta-monoethylenic unsaturation, a carboxylic acid having an alpha, beta-monoethylenic unsaturation Acid esters and oxyalkylenated fatty alcohols And (4) formed from at least three monomers, at least one of the three monomers is selected from carboxylic acids having alpha, beta-monoethylenic unsaturation, and It can be selected from copolymers where one is selected from esters of carboxylic acids having alpha beta-monoethylenic unsaturation and at least one of the three monomers is selected from oxyalkylenated fatty alcohols.

  In addition, these compounds may also contain, as monomers, carboxylic esters containing alpha, beta-monoethylenic unsaturation and C1-C4 alcohols. An example of this type of compound is ACULYN2, which is an oxyalkylenated stearyl methacrylate / ethyl acrylate / methacrylic acid terpolymer and is sold by the company ROHM and HAAS.

  Polycarboxylic acid compounds include associative polyurethanes, associative unsaturated polyacids and associative polymers or copolymers comprising at least one monomer containing ethylenic unsaturation.

  Representative examples of associative polyurethanes include a 25 percent aqueous dispersion of methacrylic acid / methyl acrylate / ethoxylated (40 EO) behenyl alcohol dimethyl (meta-isopropenyl) benzylisocyanate known under the trade name VISCOPHOBE DB1000 and commercially available from Amerchol. There is a natterpolymer.

  In some embodiments of the invention, the polycarboxylic acid compound is an acrylic acid-based, (meth) acrylic acid-based, acrylate-based or (meth) acrylate-based having an anionic functional group and / or a cationic functional group. At least one monomer. Suitable compounds include, but are not limited to, polymers containing polyacrylic acid, such as those identified by International Cosmetic Ingredient Dictionary and Handbook (9th edition, 2002), such as polyacrylic acid-1, polyacrylic acid- 2, polyacrylic acid-3, polyacrylic acid-4, polyacrylic acid-16, polyacrylic acid-17, polyacrylic acid-18, polyacrylic acid-19, polyacrylic acid-21, and mixtures thereof. . Such (co) polymers or similar (co) polymers can be combined individually or form a suitable bimodal drug having both cationic and anionic functional groups. It may be combined with other (co) polymers. In certain embodiments, the bimodal drug is polyacrylic acid-21 and an acrylate / dimethylaminoethyl methacrylate copolymer (commercially available from Interpolymer under the name SYNTRAN PC5100), polyacrylic acid-16 (from Interpolymer). Selected from the group consisting of polymers consisting of polyacrylic acid-18 and polyacrylic acid-19 (commercially available from Interpolymer under the name SYNTRAN PC5107 or SYNTRAN PC5117).

（式中、Ｒ_１およびＲ_３は独立して、２〜２０個の炭素原子を含む直鎖状または分岐鎖状アルキレンラジカルを表し、Ｒ_２は、ヒドロキシル基を含み得る１〜５０個の炭素原子を含む直鎖状または分岐鎖状アルキレンラジカルを表し、ａは０または１を表し、ｂは０〜２００の範囲内の数であり、Ｍは、水素、アルカリ金属もしくはアルカリ土類金属、ＮＨ４または第四級アンモニウム基、例えばモノ−、ジ−、トリ−もしくはテトラ（Ｃ１〜Ｃ４アルキルアンモニウム）基などを表し、Ｒ_１およびＲ_３は例えばエチレン、プロピレンまたはブチレを表し得る）を有する化合物または
（Ｂ）以下の式：

（式中、Ｒはメチルまたはフェニルから選択され；Ｒ８は水素またはメチルであり、ｍは１〜１０００の整数である）を有するピロリドンカルボン酸単位を少なくとも１つ含む基または
（Ｃ）ジビニル−ＰＤＭＳ、クロトン酸、酢酸ビニルおよびビニルイソアルキルエステルの重合から生じるポリビニル酸／エステル単位（C）を少なくとも１つ含む基
ならびに（Ａ）、（Ｂ）および（Ｃ）の組合せ
を含む、オルガノポリシロキサンであり得る。 Silicone polymer having at least one carboxylic acid group (carboxysilicone polymer).
A silicone polymer having at least one carboxylic acid group according to the present disclosure, referred to herein as a carboxysilicone polymer,
(A) The following formula:

Wherein R ₁ and R ₃ independently represent a linear or branched alkylene radical containing 2 to 20 carbon atoms, and R ₂ is 1 to 50 carbons that may contain a hydroxyl group. Represents a linear or branched alkylene radical containing an atom, a represents 0 or 1, b is a number in the range of 0 to 200, M is hydrogen, alkali metal or alkaline earth metal, NH 4 Or a compound having a quaternary ammonium group, such as a mono-, di-, tri- or tetra (C1-C4 alkylammonium) group, where R ₁ and R ₃ can represent, for example, ethylene, propylene or butylene) or (B) The following formula:

A group comprising at least one pyrrolidone carboxylic acid unit having (wherein R is selected from methyl or phenyl; R8 is hydrogen or methyl and m is an integer from 1 to 1000) or (C) divinyl-PDMS An organopolysiloxane comprising a group comprising at least one polyvinyl acid / ester unit (C) resulting from the polymerization of crotonic acid, vinyl acetate and vinyl isoalkyl ester, and a combination of (A), (B) and (C) possible.

のオルガノポリシロキサンから選択される、少なくとも１つのカルボン酸基を含むシリコーンポリマーが挙げられ、式中、
ラジカルＲ４、Ｒ４’は、互いに同一であっても異なっていてもよく、直鎖状または分岐鎖状Ｃ１〜Ｃ２２アルキルラジカル、Ｃ１〜Ｃ２２アルコキシラジカルおよびフェニルラジカルから選択され、ラジカルＲ５、Ｒ５’、Ｒ５’’、Ｒ６、Ｒ６’、Ｒ６’’、Ｒ７およびＲ７’は、互いに同一であっても異なっていてもよく、直鎖状または分岐鎖状Ｃ１〜Ｃ２２アルキルラジカル、Ｃ１〜Ｃ２２アルコキシラジカル、フェニルラジカル、ラジカル−（Ｒ１O）ａ−Ｒ２−（ＯＲ３）ｂ−ＣＯＯＭ、ピロリドンカルボン酸を含むラジカル、ポリビニル酸／エステルのラジカルから選択され；
ラジカルＲ５、Ｒ６およびＲ７のうち少なくとも１つは、ラジカル−（Ｒ１O）ａ−Ｒ２−（ＯＲ３）ｂ−ＣＯＯＭ、ピロリドンカルボン酸を含むラジカル、ポリビニル酸／エステルのラジカルから選択されるラジカルであり；
Ｒ１、Ｒ２、Ｒ３、ａ、ｂおよびＭは、上の単位（Ａ）に記載したものと同じ意味を有し；
ｃおよびｄは０〜１０００の整数であり、ｃ＋ｄの合計は、いくつかの特定の実施形態では１〜１０００または２〜１０００の範囲内にある。 Suitable carboxy silicone polymers include, for example, the formula:

Silicone polymers containing at least one carboxylic acid group selected from the organopolysiloxanes of the formula:
The radicals R4, R4 ′ may be the same or different from each other and are selected from linear or branched C1-C22 alkyl radicals, C1-C22 alkoxy radicals and phenyl radicals, and radicals R5, R5 ′, R5 ″, R6, R6 ′, R6 ″, R7 and R7 ′ may be the same as or different from each other, and may be a linear or branched C1-C22 alkyl radical, a C1-C22 alkoxy radical, Selected from phenyl radicals, radicals-(R1O) a-R2- (OR3) b-COOM, radicals including pyrrolidone carboxylic acid, polyvinyl acid / ester radicals;
At least one of the radicals R5, R6 and R7 is a radical selected from the radicals-(R1O) a-R2- (OR3) b-COOM, radicals comprising pyrrolidone carboxylic acid, polyvinyl acid / ester radicals;
R1, R2, R3, a, b and M have the same meaning as described in unit (A) above;
c and d are integers from 0 to 1000, and the sum of c + d is in the range of 1-1000 or 2-1000 in some specific embodiments.

の化合物があり、式中、Ｒ２およびＭは、上の単位（Ａ）に記載したものと同じ意味を有し、ｎは１〜１０００の整数である。例として、Ｓｈｉｎ Ｅｔｓｕ社の両末端型カルボキシシリコーンＸ−２２−１６２ＣおよびＭｏｍｅｎｔｉｖｅ社のＳｉｌｆｏｒｍ ＩＮＸ（ＩＮＣＩ名：ビス−カルボキシデシルジメチコン）がある。 The carboxysilicone polymer of formula (III ″) comprising at least one unit (I ″), in some specific embodiments, has the following formula:

Wherein R2 and M have the same meaning as described in unit (A) above, and n is an integer from 1 to 1000. Examples include Shin Etsu's double-ended carboxysilicone X-22-162C and Momentive's Silform INX (INCI name: bis-carboxydecyl dimethicone).

のものがあり、式中、
Ｒ_２、Ｒ_４、ｎおよびＭは、上の単位（Ａ）に記載したものと同じ意味を有する。１つの例には、一例として、Ｓｈｉｎ Ｅｔｓｕ社の片末端型カルボキシシリコーンＸ−２２−３７１０がある。 Other exemplary embodiments of the organopolysiloxane of formula (III ″) include the formula:

In the formula,
R ₂ , R ₄ , n and M have the same meaning as described for unit (A) above. One example is Shin Endu's single-ended carboxysilicone X-22-3710, by way of example.

のものがあり、式中、Ｘはラジカル−（Ｒ１O）ａ−Ｒ２−（ＯＲ３）ｂ−ＣＯＯＭであり、Ｒ１、Ｒ２、Ｒ３、ａ、ｂおよびＭは、上の単位（Ａ）に記載したものと同じ意味を有する。 Other exemplary embodiments of the organopolysiloxane of formula (III ″) include the formula:

Wherein X is a radical — (R1O) a-R2- (OR3) b-COOM, and R1, R2, R3, a, b and M are described in the unit (A) above. Has the same meaning as.

  Even more specifically, a formula wherein a and b are equal to 0 and R2 is a linear or branched C2-C12 alkylene group such as (CH2) 9, (CH2) 10 or -CH (CH3)-. The compound of (VI ′) is an exemplary embodiment. An example is Shin Etsu's side chain carboxysilicone X-22-3701E.

が挙げられ、式中、Ｒ８、ｍは上の単位（Ｂ）で定義した通りであり、ｎは１〜１０００の整数である。一例として、Ｇｒａｎｔ Ｉｎｄｕｓｔｒｉｅｓ社のＧｒａｎｄｓｉｌ ＳｉＷ−ＰＣＡ−１０（ＩＮＣＩ名：ジメチコン（および）ＰＣＡジメチコン（および）ブチレングリコール（および）デシルグルコシド）などのＧｒａｎｄｓｉｌ ＰＣＡがある。 Of the organopolysiloxanes of formula (III ″) containing units (B), exemplary embodiments include compounds of the following formula:

In the formula, R8 and m are as defined in the unit (B) above, and n is an integer of 1 to 1000. An example is Grandsil PCA, such as Grant Industries's Grandsil SiW-PCA-10 (INCI name: dimethicone (and) PCA dimethicone (and) butylene glycol (and) decyl glucoside).

  Of the organopolysiloxanes of formula (III ″) comprising polyvinyl acid / ester units (C), exemplary embodiments include cross-linked anionic copolymers consisting of an organic polymer block and silicone to produce a multi-block polymer structure . In particular, the silicone-organic polymer compounds of the present invention can be selected from crosslinked anionic copolymers comprising at least one crosslinked polysiloxane structural unit. As an example of such a branched multi-block carboxysilicone polymer, Wasil Chemie's Belsil® P1101 (also known as the trade name Belsil® P1101) (INCI name: crotonic acid / vinyl) C8-12 isoalkyl ester / VA / bis-vinyl dimethicone crosspolymer, also known as crotonic acid / vinyl C8-12 isoalkyl ester / VA / divinyl dimethicone crosspolymer).

  Other suitable carboxysilicone polymers are described, for example, in patent applications, WO 95/23579 and European Patent Application No. 0,219,830 (A), which are incorporated herein by reference in their entirety. Yes.

The compound corresponding to the above formula (VI ″) is, for example, the name of HUILE M642 from Wacker, the names of SLM23000 / 1 and SLM23000 / 2 from Wacker, the name of 176-12057 from General Electric, It is sold under the name FZ3703 and BY16880 from Toray Silicone.
Other non-limiting examples of carboxysilicone polymers include silicone carboxylate-containing polymers (silicone carboxylates).

  Suitable silicone carboxylates include water-soluble silicone compounds containing at least one carboxylic acid group, oil-soluble silicone compounds containing at least one carboxylic acid group, water-dispersible silicones containing at least one carboxylic acid group, and at least one carboxylic acid group. It may be selected from silicones that contain acid groups and are soluble in organic solvents. In one embodiment, the silicone carboxylate further comprises at least one alkoxylated chain, wherein the at least one alkoxy group is selected from a terminal alkoxy group, a pendant alkoxy group, and an alkoxy group incorporated within the at least one silicone backbone. obtain. Non-limiting examples of at least one alkoxy group include ethylene oxide groups and propylene oxide groups.

  The at least one carboxylic acid group can be selected from a terminal carboxylic acid group and a pendant carboxylic acid group. Further, the at least one carboxylic acid may be selected from a free acid form of a carboxylic acid group, i.e. -COOH, and a salt form of a carboxylic acid group, i.e. -COOM, wherein M is an inorganic cation. May be selected from, for example, potassium and sodium cations and organic cations.

の化合物であり、式中、ａは１〜１００の範囲内の整数であり；ｂは０〜５００の範囲内の整数であり；Ｒは、同一であっても異なっていてもよく、それぞれ、１〜９個の炭素原子を含む任意選択で置換された炭化水素基、任意選択で置換されたフェニル基および以下の式の基：
−（ＣＨ_２）_３−Ｏ−（ＥＯ）_ｃ−（ＰＯ）_ｄ−（ＥＯ）_ｅ−Ｃ（Ｏ）−Ｒ’−Ｃ（Ｏ）−ＯＨ
（ＩＸ’’）
から選択され、式中、ｃ、ｄおよびｅは、同一であっても異なっていてもよく、それぞれ０〜２０の範囲内の整数であり；ＥＯはエチレンオキシド基であり；ＰＯはプロピレンオキシド基であり；Ｒ’は、任意選択で置換された二価炭化水素、例えば２〜２２個の炭素原子を含むアルキレン基およびアルケニレン基などならびに任意選択で置換された二価芳香族基、例えば以下の式（Ｘ’’）：

の基および以下の式（ＸＩ’’）：

の基などから選択され、ただし、Ｒ基のうち少なくとも１つは式（ＶＩＩＩ’’）の基から選択され、さらには、Ｒ基のうち１つのみが式（ＶＩＩ’’）の基から選択される場合、それ以外のＲ基は全部がメチル基であるというわけではない。 In one embodiment, the silicone carboxylate has the formula:

Wherein a is an integer in the range of 1 to 100; b is an integer in the range of 0 to 500; and R may be the same or different, An optionally substituted hydrocarbon group containing 1 to 9 carbon atoms, an optionally substituted phenyl group and a group of the following formula:
_{- (CH 2) 3 -O- (} EO) c - (PO) d - (EO) e -C (O) -R'-C (O) -OH
(IX '')
In which c, d and e may be the same or different and each is an integer in the range of 0-20; EO is an ethylene oxide group; PO is a propylene oxide group Yes; R ′ is an optionally substituted divalent hydrocarbon, such as alkylene and alkenylene groups containing 2 to 22 carbon atoms, and an optionally substituted divalent aromatic group such as (X ″):

And the following formula (XI ″):

Wherein at least one of the R groups is selected from the group of formula (VIII ″), and furthermore only one of the R groups is selected from the group of formula (VII ″) When done, the other R groups are not all methyl groups.

およびその塩から選択され、式中、ａは１〜１００の範囲内の整数であり、ｂは０〜５００の範囲内の整数であり、ＡＯは以下の式（ＸＩＩＩ’’）：
−（ＥＯ）ｃ−（ＰＯ）ｄ−（ＥＯ）ｅ−
（ＸＩＩＩ’’）
の基（式中、ｃ、ｄおよびｅは、同一であっても異なっていてもよく、それぞれ０〜２０の範囲内の整数であり；ＥＯはエチレンオキシド基であり；ＰＯはプロピレンオキシド基である）から選択され；ｘは０〜６０の範囲内の整数であり；Ｒ’は、任意選択で置換された二価炭化水素、例えば２〜２２個の炭素原子を含むアルキレン基およびアルケニレン基などならびに任意選択で置換された二価芳香族基、例えば以下の式（ＸＩＶ’’）：

の基および式（ＸＶ’’）：

の基などから選択される。 Non-limiting examples of silicone carboxylates include the names Ultrasil® CA-1 Silicone (dimethicone PEG-7 phthalate) and Ultrasil® CA-2 Silicone (dimethicone PEG-7 succinate) from Noveon. Which correspond to any of the following formulas (XII ″). Thus, in one embodiment, the at least one silicone carboxylate is a compound of the formula:

And a salt thereof, wherein a is an integer in the range of 1 to 100, b is an integer in the range of 0 to 500, and AO is the following formula (XIII ″):
-(EO) c- (PO) d- (EO) e-
(XIII '')
Wherein c, d and e may be the same or different and each is an integer in the range of 0-20; EO is an ethylene oxide group; PO is a propylene oxide group X is an integer in the range of 0-60; R ′ is an optionally substituted divalent hydrocarbon, such as alkylene and alkenylene groups containing 2 to 22 carbon atoms, and the like, and An optionally substituted divalent aromatic group, for example the following formula (XIV ″):

And the formula (XV ″):

Selected from the group of

  Non-limiting examples of silicone carboxylates include those described in US Pat. Nos. 5,248,783 and 5,739,371, the disclosures of which are incorporated herein by reference, These are silicone compounds of the formula (VIII ″).

A cationic polymer comprising at least one carboxyl group.
Cationic polymers can have a negative charge but are generally in a cationic state, can be amphoteric polymers that can have a cationic charge based on pH, or are amphoteric at any pH It can be a betaine polymer.

  The cationic polymer comprises (i) at least one nonionic monomer, such as (alkyl) (meth) acrylamide, (alkyl) (meth) acrylic acid ester, vinyl pyrrolidone, vinyl imidazole, etc .; (ii) at least one cation Monomers such as ethyltrimonium (alkyl) (meth) acrylamide, ethyltrimonium (alkyl) (meth) acrylic ester, vinylimidazoline, dimethylaminopropyl (alkyl) (meth) acrylamide, methacrylamide propyltriethylammonium chloride (MAPTAC) ), Diallyldimethylammonium chloride (DADMAC), etc .; (iii) at least one (alkyl) acrylic acid; (iv) at least one amphoteric monomer such as carboxybeta It is a polymer resulting from homopolymerization or copolymerization of ethylenically unsaturated monomers selected from such zwitterionic monomer.

  Suitable examples of such cationic polymers include diary dimethyl ammonium diacrylic diacrylic diacrylic diacrylic acid, sold under the name MERQUAT280 POLYMER, MERQUAT280 NPPOLYMER, MERQUAT281 POLYMER or MERQUAT295 POLYMER. (INCI name: Polyquaternium-22); a copolymer of methacrylamidopropyltrimonium chloride, acrylic acid and / or methyl acrylate sold under the name MERQUAT2001 POLYMER or MERQUAT2001 POLYMER by Nalco (Lubrizol) (IN I name: polyquaternium-47); MERQUAT3330DRY POLYMER, MERQUAT3330PR POLYMER, MERQUAT3 POLY33, MERQUAL MER31, MERQUAL MER31, MERQUAL MER31 and MERQUAL PLUS31. Polymer (INCI name: Polyquaternium-39); methacrylamidepropyltrimethylammonium chloride (MAPTAC), acrylamide, and acrylamide sold under the name MERQUAT2003PR POLYMER by the company Nalco (Lublizol) Amphoteric terpolymers (INCI name: polyquaternium-53) consisting of crylic acid; polyquaternium-30, polyquaternium-35, polyquaternium-45, polyquaternium-50, polyquaternium-54; polyquaternium-57; polyquaternium-63; polyquaternium-74; polyquaternium-74 Polyquaternium-86; polyquaternium-89; polyquaternium-95; polyquaternium-98, polyquaternium-104; polyquaternium-111; polyquaternium-112 and mixtures thereof.

Latex Polymers In various exemplary embodiments, the composition of the present invention comprises a carboxyl functional acrylate latex polymer, a carboxyl functional polyurethane latex polymer, a carboxyl functional silicone latex polymer, a carboxyl functional non-acrylate latex polymer and mixtures thereof. May further include one or more latex polymers (also referred to herein as “latex polymers”).

  In various embodiments, the latex polymer of the present invention can be a film-forming latex polymer or a non-film-forming latex polymer.

  In at least certain embodiments of the present disclosure, the latex polymer is prepared in the form of an aqueous dispersion prior to preparing the composition of the present disclosure. In various embodiments, the aqueous dispersion can be obtained by emulsion polymerization of monomers, and the resulting latex polymer has a particle size of less than about 1 micron. In at least one exemplary embodiment, a dispersion prepared by polymerizing one or more monomers having a polymerizable double bond in water may be selected. In another exemplary embodiment, the aqueous dispersion obtained by emulsion polymerization may be spray dried.

  In other embodiments, the latex polymer is made by a condensation reaction between monomers and then dispersed in an aqueous medium.

  Thus, the latex polymer may exist as polymer particles dispersed in a dispersion medium, such as an aqueous dispersion medium, in various exemplary embodiments. The latex polymers, in various embodiments, may each be dispersed in separate dispersion media or may be dispersed together in the same dispersion media.

  The dispersion medium includes at least one solvent selected from water. The dispersion medium may further comprise at least one solvent selected from cosmetically acceptable organic solvents, such as the organic solvents described above.

  In embodiments according to the present disclosure, the latex polymer particles are not soluble in the solvent of the dispersion medium, i.e. not water soluble and / or not soluble in at least one cosmetically acceptable organic solvent. Thus, the latex polymer retains its particle morphology in the selected solvent or solvents.

  In at least certain exemplary embodiments, latex polymer particles according to the present disclosure may have an average diameter of up to about 1000 nm, such as in the range of about 50 nm to about 800 nm or about 100 nm to about 500 nm. Such particle size can be measured with a laser granulometer (eg, Brookhaven BI90).

  In various embodiments, the latex polymer can independently be neutralized, partially neutralized, or non-neutralized. In exemplary embodiments where the latex polymer is neutralized or partially neutralized, the particle size can be, for example, greater than about 800 nm. In at least certain embodiments, the particle form of the latex polymer is retained in the dispersion medium.

  In further embodiments, the latex polymer may be selected from uncharged latex polymers and charged latex polymers. Thus, the latex polymer may be selected from nonionic latex polymers, cationic latex polymers, anionic latex polymers and amphoteric latex polymers in various exemplary embodiments.

  As merely a non-limiting example, latex polymers are carboxyl functional acrylate latex polymers such as vinyl monomers, (meth) acrylic acid monomers, (meth) acrylamide monomers, monocarboxyl unsaturated acids and dicarboxyl unsaturated acids, It can be selected from those obtained by homopolymerization or copolymerization of ethylenically unsaturated monomers selected from esters of (meth) acrylic monomers and amides of (meth) acrylic monomers. As used herein, the term “(meth) acryl” and variations thereof refer to acrylic or methacrylic.

  The (meth) acrylic monomer can be selected from, for example, acrylic acid, methacrylic acid, citraconic acid, itaconic acid, maleic acid, fumaric acid, crotonic acid and maleic anhydride. Esters of (meth) acrylic monomers include, as non-limiting examples, C1-C8 alkyl (meth) acrylates such as methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, isopropyl (meth) acrylate, Butyl (meth) acrylate, tert-butyl (meth) acrylate, pentyl (meth) acrylate, isopentyl (meth) acrylate, neopentyl (meth) acrylate, hexyl (meth) acrylate, isohexyl (meth) acrylate, 2-ethylhexyl (meth) Acrylate, cyclohexyl (meth) acrylate, isohexyl (meth) acrylate, heptyl (meth) acrylate, isoheptyl (meth) acrylate, octyl (meth) acrylate, isooctyl (Meth) acrylate, allyl (meth) may be acrylates and combinations thereof. Amides of (meth) acrylic monomers are, for example, (meth) acrylamide, in particular N-alkyl (meth) acrylamide, in particular N- (C1-C12) alkyl (meth) acrylic acid, for example N-ethyl (meth) acrylamide, N It may be made of -t-butyl (meth) acrylamide, Nt-octyl (meth) acrylamide, N-methylol (meth) acrylamide, N-diacetone (meth) acrylamide and the like and any combination thereof.

  Vinyl monomers include, but are not limited to, vinyl cyanide compounds such as acrylonitrile and methacrylonitrile; vinyl esters such as vinyl formate, vinyl acetate, vinyl propionate, vinyl neodecanoate, vinyl pivalate, vinyl benzoate and t -Vinyl butyl benzoate, triallyl cyanurate and the like; vinyl halides such as vinyl chloride and vinylidene chloride; aromatic monovinyl or divinyl compounds such as styrene, α-methylstyrene, chlorostyrene, alkylstyrene, divinylbenzene and diallyl phthalate And para-styrene sulfonic acid, vinyl sulfonic acid, 2- (meth) acryloyloxyethyl sulfonic acid, 2- (meth) acrylamide-2-methylpropyl sulfonic acid and Mixtures thereof.

  The list of monomers described is not limiting and any monomer known to those skilled in the art can be used including acrylic monomers and / or vinyl monomers (including monomers modified with silicone chains) Should be understood.

  In at least certain non-limiting exemplary embodiments, the carboxyl functional acrylate latex polymer is a methacrylic acid / ethyl acrylate copolymer (INCI: acrylate copolymer, such as BASF's Luviflex® SOFT), PEG / PPG-23 / 6 dimethicone citraconic acid / C10-30 alkyl PEG-25 methacrylate / acrylic acid / methacrylic acid / ethyl acrylate / trimethylolpropane PEG-15 triacrylate copolymer (INCI: polyacrylate-2 crosspolymer) For example, Fixate Superhold (registered trademark) manufactured by Lubrizol), styrene / acrylic copolymer (such as Accudine Shine manufactured by Dow Chemical), ethyl acrylate, etc. Hexyl / methyl methacrylate / butyl acrylate / acrylic acid / methacrylic acid copolymer (INCI: acrylate / ethyl hexyl acrylate copolymer, such as Daitosol 5000SJ from Daito Kasei Kogyo), acrylic / acrylate copolymer (INCI name: acrylate copolymer, For example, Daitosol 5000AD manufactured by Daito Kasei Kogyo), acrylate copolymers such as Dermacryl AQF (Akzo Nobel), LUVIMER (registered trademark) MAE (BASF), or BLANCE CR (AKZO NOBEL). Product name ACUDYNE180 POLYMWE (Dow Chemical Company) Acrylate / hydroxyester acrylate copolymer known as styrene / acrylate copolymer known under the trade name Accudine Bold from Dow Chemical, styrene / acrylate / ammonium methacrylate copolymer known as Interpolymer PC SYN620 PC5620 CG and mixtures thereof Can be selected from aqueous dispersions of

の構造を有し得るものであり、式中、Ｒ１はジヒドロキシル官能性化合物の二価ラジカルから選択され、Ｒ２は脂肪族ポリイソシアナートまたは脂環式ポリイソシアナートの炭化水素ラジカルから選択され、Ｒ３は、任意選択でイオン性または潜在的にイオン性の基で置換された低分子量ジオールのラジカルから選択され、ｎは約０〜約５の範囲内にあり、ｍは約１より大きい。 In a further exemplary non-limiting embodiment, the latex polymer may be selected from carboxyl functional polyurethane latex polymers such as aqueous polyurethane dispersions. These polyurethanes are formed by reacting the prepolymer (i) and the co-reactant (ii) in a conventional manner to produce a carboxyl-terminated or pendant polyurethane polymer. The prepolymer (i) has the formula (I ′ ″):

Wherein R1 is selected from a divalent radical of a dihydroxyl functional compound, R2 is selected from a hydrocarbon radical of an aliphatic polyisocyanate or an alicyclic polyisocyanate; R3 is selected from a radical of a low molecular weight diol optionally substituted with an ionic or potentially ionic group, n is in the range of about 0 to about 5, and m is greater than about 1.

  Dihydroxyl compounds suitable for providing the divalent radical R1 include those having at least two hydroxy groups and having a number average molecular weight such as from about 700 to about 16,000, such as from about 750 to about 5000. . Non-limiting examples of high molecular weight compounds include polyester polyols, polyether polyols, polyhydroxy polycarbonates, polyhydroxy polyacetals, polyhydroxy polyacrylates, polyhydroxy polyester amides, polyhydroxy polyalkadienes and polyhydroxy polythioethers. Is mentioned. In various embodiments, polyester polyols, polyether polyols, and polyhydroxy polycarbonates can be selected. Mixtures of such compounds are also within the scope of this disclosure.

  Optional polyisocyanates for providing the hydrocarbon radical R2 include, for example, organic diisocyanates having a molecular weight in the range of about 100 to about 1500, such as about 112 to about 1000 or about 140 to about 400. Is mentioned.

  The optional diisocyanate is selected from the general formula R2 (NCO) 2, wherein R2 is a divalent aliphatic hydrocarbon group containing about 4-18 carbon atoms, about 5-15 carbon atoms. Represents a divalent alicyclic hydrocarbon group containing, a divalent aromatic hydrocarbon group containing about 7 to 15 carbon atoms, or a divalent aromatic hydrocarbon group containing about 6 to 15 carbon atoms.

  The use of a diol, such as R3, which is a low molecular weight diol, in at least certain embodiments, cures the polymer chain. The expression “low molecular weight diol” means a diol having a molecular weight in the range of about 50 to about 800, such as about 60 to 700 or about 62 to 200. These may include aliphatic groups, alicyclic groups or aromatic groups in various embodiments. In certain exemplary embodiments, the compound comprises only aliphatic groups. The diol that can be selected is optionally one having up to about 20 carbon atoms, such as ethylene glycol, diethylene glycol, propane-1,2-diol, propane-1,3-diol, butane-1 , 4-diol, 1,3-butylene glycol, neopentyl glycol, butylethylpropanediol, cyclohexanediol, 1,4-cyclohexanedimethanol, hexane-1,6-diol, bisphenol A (2,2-bis (4 -Hydroxyphenyl) propane), hydrogenated bisphenol A (2,2-bis (4-hydroxycyclohexyl) propane) and mixtures thereof. For example, R3 can be derived from neopentyl glycol.

  Optionally, the low molecular weight diol may contain ionic or potentially ionic groups. Suitable low molecular weight diols containing ionic or potentially ionic groups can be selected from those disclosed in US Pat. No. 3,412,054. In various embodiments, the compound may be selected from dimethylol-butanoic acid (DMBA), dimethylolpropionic acid (DMPA) and carboxyl-containing caprolactone polyester diol. If low molecular weight diols containing ionic or potentially ionic groups are selected, they can be used, for example, in polyurethane dispersions in amounts where less than about 0.30 meq of -COOH is present per gram of polyurethane. . In at least certain exemplary non-limiting embodiments, low molecular weight diols containing ionic or potentially ionic groups are not used.

The co-reactant (ii) comprises a primary amine in certain embodiments, such as a functional group, such as a hydroxy group or an amine group adapted to react preferentially with an isocyanate group over a carboxyl group, Formula (II ′ ″):
X-R4-X X = OH, NH2
(II ''')
Wherein R ₄ is a divalent aliphatic hydrocarbon group, alicyclic hydrocarbon group or aromatic hydrocarbon optionally substituted with an ionic group or a potentially ionic group. Represents a group. In various embodiments, the compound may optionally be selected from alkylene diamines such as hydrazine, ethylene diamine, propylene diamine, 1,4-butylene diamine and piperazine. In various embodiments, the compound may optionally be selected from alkylene diols such as ethylene glycol, 1,4-butanediol (1,4-BDO or BDO), 1,6-hexanediol, and the like.

  As used herein, ionic or potentially ionic groups include groups containing ternary or quaternary ammonium groups, groups convertible to such groups, carboxyl groups, carboxylate groups, sulfones. Examples include acid groups and sulfonate groups. At least partial conversion of the groups convertible to the above types of salt groups can occur before or during mixing with water. Special compounds may be selected from carboxy-functional polyesters containing dimethylolbutanoic acid (DMBA), dimethylolpropionic acid (DMPA) or excess equivalents of dicarboxylic acids that react with a small equivalent of glycol or carboxyl-containing caprolactone polyester diol.

  R1, R2, R3, R4 may independently have at least one carboxyl group.

  As a non-limiting example, such a latex is not particularly limited, but includes isophthalic acid / adipic acid / hexylene glycol / neopentyl glycol / dimethylolpropanoic acid / isophorone diisocyanate copolymer (INCI name: polyurethane-1) For example, BASF's Luviset® PUR), hexylene glycol monomer, neopentyl glycol monomer, adipic acid monomer, saturated methylene diphenyl diisocyanate monomer and dimethylol propanoic acid monomer (INCI name) : Polyurethane 2), copolymer of PPG-17 monomer, PPG-34 monomer, isophorone diisocyanate monomer and dimethylolpropanoic acid monomer (INCI name: polyurethane 4), iso Copolymers of taric acid monomer, adipic acid monomer, hexylene glycol monomer, neopentyl glycol monomer, dimethylolpropanoic acid monomer, isophorone diisocyanate monomer and bis-ethylaminoisobutyl-dimethicone monomer (INCI name: polyurethane 6), isophorone di Isocyanate, cyclohexanedimethanol, dimethylolbutanoic acid, polyalkylene glycol and N-methyldiethanolamine copolymer (INCI name: polyurethane 10), trimethylolpropane, neopentyl glycol, dimethylolpropionic acid, polytetramethylene ether glycol and isocyanate Methyl ethylbenzene copolymer (INCI name: Polyurethane 12), propylene oxide, ethylene Isophorone diisocyanate, dimethylolpropionic acid and 4,4′-isopropylidenediphenol (INCI name: Polyurethane 14), isophorone diisocyanate, adipic acid, tris reacted with xoxide and PEG / PPG-17 / 3 copolymer Ethylene glycol and dimethylol propionic acid copolymer (INCI name: polyurethane 15), 2-methyl-2,4-pentanediol, 2,2-dimethyl-1,3-propanediol, hexanedioic acid, methylenedicyclohexane diisocyanate And 2,2-di (hydroxymethyl) propanoic acid polymer, hydrolyzed tris (2-hydroxyethyl) amine salt, reaction product with 1,2-ethanediamine (INCI name: polyurethane 17) in aqueous polyurethane dispersion Liquid Polyurethane-27 is a composite polymer formed by reacting polyperfluoroethoxymethoxydifluorohydroxyethyl ether and isophorone diisocyanate (IPDI) to form a prepolymer. The prepolymer is a composite polymer formed by further reacting a polyester composed of dimethylolpropionic acid and adipic acid, hexylene glycol, neopentyl glycol and methylenedicyclohexyl diisocyanate (SMDI) to form a prepolymer. It is reacted with a triethylamine salt of 3-hydroxy-2- (hydroxymethyl) -2-methyl-1-propionic acid (INCI name: polyurethane 27). The prepolymer is neutralized with triethylamine and then the chain is extended with hydrazine (INCI name: polyurethane 33).

Carboxylic acid compounds selected from fatty acids, salts thereof and mixtures thereof.
Carboxylic acid compounds generally have a carbon chain comprising 6 to 30 carbon atoms, in certain embodiments 9 to 30 carbon atoms, and in certain embodiments 9 to 22 carbon atoms, The chain may optionally be selected from saturated or unsaturated carboxylic acids, for example substituted with one or more (especially 1 to 4) hydroxyl groups. When the fatty acids of the present disclosure are unsaturated, these compounds may contain 1 to 3 conjugated or nonconjugated carbon-carbon double bonds.

  Suitable examples of carboxylic acid compounds of the present disclosure include oleic acid, linoleic acid, linolenic acid, isostearic acid, caproic acid, capric acid, caprylic acid, oleic acid, linoleic acid, linolenic acid, behenic acid, lauric acid, myristic There are acids, stearic acid, palmitic acid and mixtures thereof.

  The carboxylic acid compounds of the present disclosure may also be selected from fatty acid salts, particularly fatty acid alkali metal salts (metal soaps) and fatty acid organic base salts.

  Examples of the metal of the alkali metal salt of the fatty acid include sodium, potassium, lithium, and a mixture thereof. The organic base salt of a fatty acid can be obtained by neutralizing a fatty acid with an organic base such as ammonia, monoethanolamine or triethanolamine. Suitable examples include sodium stearate, zinc laurate, magnesium stearate, magnesium myristate, zinc stearate, palm fatty acid potassium ammonium stearate, ammonium oleate, ammonium nonanoate and mixtures thereof.

  When present in the composition, the above additives generally include up to about 95% by weight based on the total weight of the composition, including all ranges and subranges therebetween, for example, up to about maximum based on the total weight of the composition. 50 wt%, up to about 40 wt%, up to about 30 wt%, up to about 20 wt%, up to about 15 wt%, up to about 10 wt%, up to about 5 wt%, etc., for example from about 0.001 wt% to about 50 wt%, about 0.001 wt% to about 40 wt%, about 0.001 wt% to about 30 wt%, about 0.001 wt% to about 20 wt%, or about 0.001 wt% to about 10 wt% Present in an amount within a range such as%.

  One skilled in the art will recognize this or any optional additional compounds and / or amounts thereof so that the advantageous properties of the composition according to the invention are not adversely affected or substantially unaffected by the envisaged addition. Needless to say, choose carefully.

Methods of Preparation and Use In some embodiments, a polycarbodiimide and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, and a solvent Are combined to prepare the composition of the present disclosure.

  In other embodiments, polycarbodiimide, one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, and water, organic solvents and mixtures thereof A composition of the present disclosure is prepared by combining with a solvent selected from:

  In yet another embodiment, polycarbodiimide, one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, and water and an organic solvent. A composition of the present disclosure is prepared by combining with a containing solvent.

Methods: Preparation and Use with Colorants / Dyes In some embodiments, by combining polycarbodiimide, an optional colorant or dye, an amino compound selected from polyamines and silicone amines, and a solvent, A composition of the present disclosure is prepared.

  In other embodiments, the polycarbodiimide, an optional colorant or dye, an amino compound selected from polyamines and silicone amines, and a solvent selected from water, organic solvents, and mixtures thereof are combined to provide The disclosed composition is prepared.

  In yet another embodiment, the composition of the present disclosure by combining a polycarbodiimide, an optional colorant or dye, an amino compound selected from polyamines and silicone amines, and a solvent comprising water and an organic solvent. Prepare the product.

One-Step Application Process In one embodiment, the composition of the present disclosure is applied to a keratin substrate such as hair in a one-step application process. A composition for use in a one-step application is prepared by combining ingredients including polycarbodiimide, aminosilicone and a solvent, and then a composition for application to a keratin substrate is obtained.

  In one embodiment, when the composition for the one-step coating process includes a solvent comprising water and an organic solvent, a combination of polycarbodiimide and water is formed on the aqueous phase to form an aminosilicone and an organic solvent. To form a non-aqueous phase. The phases are then combined and stirred to form an emulsion. The formed emulsion is then applied to a keratin substrate such as hair and processed.

  In another embodiment, polycarbodiimide and aminosilicone and water are combined to form an aqueous composition, which is applied to a keratin substrate such as hair and processed.

Two-stage application process In another embodiment, the composition of the present disclosure is applied to a keratin substrate such as hair in a two-stage application process. In the two-step application process, the individual components (polycarbodiimide combined with solvent and aminosilicone combined with solvent) are applied to the keratin substrate stepwise in any order to treat the substrate.

  Application of the composition to a keratin substrate such as hair according to the present disclosure may be performed at room temperature.

  In other embodiments, application of the composition according to the present disclosure may be performed at elevated temperatures (or higher than room temperature) by applying heat to the hair or exposing the hair to elevated temperatures. Although not particularly limited, the heating is performed by, for example, a commonly used heating means such as a helmet-type dryer or blow dryer (40 ° C. or higher) or a hot iron or flat iron (120 ° C. to 250 ° C.) or a steam / hot roller. Can be implemented.

  Compositions and treatments according to the present disclosure provide keratin fibers with advantageous properties. In one embodiment, applying the composition and treatment according to the present disclosure to hydrophilic or damaged keratin fibers, such as damaged (platinum bleached) hair, etc., imparts or renders it hydrophobic . In certain embodiments, hydrophobicity is provided at room temperature, that is, without heating the hair or applying heat to the hair. In other embodiments, hydrophobicity is provided when heat is used on the hair (before or after applying the composition to the hair or when applying the composition to the hair). In one embodiment, the hydrophobicity provided to the less hydrophobic or hydrophilic keratin fibers comprises a contact angle greater than 80 °, greater than 90 °, greater than 100 ° or greater than 110 °. In yet another embodiment, hydrophobicity is provided when heat is used on the hair (before or after applying the composition to the hair or when applying the composition to the hair). In one embodiment, the hydrophobicity provided to the less hydrophobic or hydrophilic keratin fibers is greater than 70 °, greater than 80 °, greater than 90 °, greater than 100 °, greater than 110 °, greater than 120 °, or greater than about 70 °. A contact angle in the range of from about 120 °, such as from about 90 ° to about 120 °, or such as from about 100 ° to about 120 °.

  For example, when the hair treated with the composition of the present invention was heated at 50 ° C. for 30 minutes and then allowed to cool at room temperature for a certain period of time, an increase in percent curl retention was seen, compared to hair treated with either substance alone. High resistance to high humidity and high temperature was shown. Even with the use of heat (drying in the oven), the percent curl retained with the composition of the present invention was higher than that obtained when no heat was applied or used to the hair. . Thus, the compositions according to the present disclosure are particularly suitable for commonly used heating means such as blow dryers (60 ° C.) or hot or flat irons (120 ° C. to 250 ° C.) or heating lamps, heating rods or other similar devices. When used when exposed to keratin fibers, it provides curling benefits.

  The method or process of using the composition of the present invention will depend on the type of hair intended, and thus the specific ingredients contained in the composition used to shape, shape or maintain the hair shape.

  One embodiment of the invention is a method of shaping, shaping or maintaining the shape of the hair.

  Another embodiment of the present invention is a method of imparting a durable or long lasting style or shape to the hair, comprising applying to the hair any one composition of the present disclosure. is there.

  In at least one embodiment, such a method comprises applying an effective amount of any one composition of the present disclosure to the hair.

  The compositions of the present disclosure may be used in an amount effective to sufficiently cover the surface of the hair fibers and to obtain the desired or effective hair style or shape and the desired amount of retention. Thus, the exact amount of composition applied to the hair depends on the degree of treatment / styling / forming / holding power desired.

  An effective amount of the composition is commonly used, from about 0.1 grams to about 50 grams, for some hair treatment applications, an amount of about 20-60 grams, in a further embodiment for rich hair, about 20 ˜about 80 grams or more. Thus, the amount applied depends on the amount or volume of the keratinous material to be treated, e.g. hair etc., and thus the greater range for the higher amount or portion of the hair from the lower range for the lesser amount or portion of the hair. It will be understood that it can fall within the range and beyond. In the case of hair treatment, a typical application is for the entire head. It will be appreciated that application to the hair typically includes penetrating the composition into the hair.

  Further disclosed herein is the use of the composition of the present disclosure for shaping or styling hair and / or retaining hairstyles. Also disclosed is the use of the composition of the present disclosure for hair care such as hair repair treatment by imparting hydrophobicity to the hair, reducing damage to the hair, or improving the feel of the hair.

  The composition may be applied to wet or dry hair before or after shaping. The composition may be used in a method that does not perform rinsing. In some other embodiments, the composition may be rinsed from the hair.

  Hair contacted with the composition of the present invention may be air dried and / or further trimmed or shaped by applying heat to the hair and / or passing a comb, brush or finger through the hair. Other shaping means may be selected from combs and brushes.

  In certain embodiments, the composition is, for example, from about 1 to about 60 minutes, or such as from about 5 to about 45 minutes, or such as from about 5 to about 30 minutes, or such as from about 10 to about 20 minutes, or For example, it is held on the keratin fibers for about 20 minutes or for example about 10 minutes (standing time).

  The smoothing operation may be performed by the use of a suitable device for brushing or smoothing the hair, including a hair brush, comb or flat iron. The smoothing operation on the hair can also include passing a finger through the hair.

  A suitable application device is an application brush. A brush is an example of an applicator that is particularly suitable for hair, including but not limited to spray bottles, squeeze bottles, 1 and 2 chamber pumps, tubes, combs and other applicators known in the art. It will be appreciated that other applicators may be used.

  While performing a smoothing operation on the hair, heat can be applied to the hair (at a temperature of at least 40 ° C.). The heat source may be selected from a blow dryer, flat iron, hair dryer, heating lamp, heating rod or other similar device.

  Further, regardless of the use of the embodiment, the composition present on the fiber or hair is removed for a period of time, generally from about 1 to about 60 minutes, such as from about 5 to about 45 minutes, or such as from about 5 to about 20 minutes. Or, for example, for about 10 to about 20 minutes, or for example about 20 minutes, or for example about 10 minutes. In another embodiment, the processing time is even longer, in some embodiments it can be considerably longer and the application can be allowed to stand for up to 24 hours to about 48 hours.

  The compositions of the present disclosure spread easily on the hair.

  Surprisingly and unexpectedly, it has been discovered that application of the composition to the hair preserves the hair shape, style or curl or making the hair moisture resistant. Surprisingly and unexpectedly, it has also been discovered that application of the composition to the hair results in improved hair quality, such as improved hair feel and appearance.

  Surprisingly and unexpectedly, application of the composition to the hair preserves a good cosmetic appearance and properties while at the same time keeping the hair shape, style or curl or hair moisture resistant. I also discovered that.

  Also, the shape / styling management, curl retention, moisture resistance and hair care benefits obtained using the compositions and methods of the present invention are durable or long lasting, i.e. resistant to washing or shampooing. Can be a thing.

  As used herein, “long-lasting” or “durable” means that the benefit imparted to the hair by the composition of the present invention over a period of time and / or under high humidity conditions, and And / or is understood to mean persisting after one or more wash cycles (water, shampoo / water, shampoo / water / conditioner / water or conditioner / water). Multiple washing cycles shall mean two or more washing cycles, for example 2, 3, 4, 5, 6, 7, 8, 9 or 10 washing cycles, etc. Understood.

  Another embodiment of the present invention is a method of imparting durable or long lasting style / shape and / or curl and / or care to hair comprising (a) a composition of the present invention And (b) providing instructions for applying the composition to the hair.

  Instructions for applying the composition of the present invention to a keratin substrate such as hair or eyelashes may include instructions regarding the use of the composition to be followed by the end user. The end user can be a consumer, a beauty professional or a hairdresser at a beauty salon. The instructions may include instructing the end user to take a certain amount of the composition in an amount sufficient to sufficiently cover the hair fiber and give the hair fiber the desired shape, style or retention. . The instructions further explain to the end user to shape or style the hair using devices such as combs, brushes (eg, hair brush or brush bar), flat iron plate, blow dryer or fingers, or to separate the hair fibers. Can be. The instructions may further explain to the end user to apply heat to the hair, such as by drying the hair with a dryer or using a heating device on the hair.

  Instructions for applying the composition of the present invention to keratin fibers such as hair include a container (can, bottle, jar, etc.) containing the composition of the present invention or a box containing the composition, a cardboard box Or it may be displayed on other packaging.

  Another embodiment of the present invention is a method of protecting keratin fibers selected from hair, wherein the hair is chemically treated (e.g., permanent dyeing composition, semi-permanent dyeing composition or semi-permanent). Dyeing the hair with a demi-permanent dyeing composition, decolorizing / lightening or lightening the hair with a chemical oxidant, perming the hair with a chemical reduction / oxidant, Protect or repair the keratin fibers before, during, or after (relaxing hair with caustic and non-caustic solution compositions, straightening hair with chemical hair straighteners) A method comprising applying to the keratin fibers an effective amount of the composition of the present invention.

  The above composition is useful for application to keratin substrates such as human hair.

  Thus, the composition of the present invention can be made into various cosmetic products such as hair care products, hair styling products and makeup products.

  Representative types of hair care compositions, including hair cosmetic compositions and hair styling compositions of the present invention, include hair shaping, hair shape maintenance, styling products (eg, gels, creams, emulsions, pastes, waxes) , Ointment, serum, foam, hair lotion, mousse, pump spray, non-aerosol spray and aerosol spray), conditioning or protection from thermal damage, leave-in hair treatment, rinse-off hair treatment composition, shampoo / styling combination composition Products and hair volume up compositions.

  The compositions of the present invention may be in the form of an aqueous composition or emulsion, such as a lotion or cream, and in some embodiments may be applied in another form, such as a serum such as anhydrous serum.

  In one embodiment, the composition of the present invention is in the form of a non-aerosol spray, which in some embodiments contains a volatile organic solvent / compound.

  In one embodiment, the composition of the present invention is in the form of a cream. In another embodiment, the composition of the present invention is in the form of an aqueous lotion (non-emulsion).

  The composition may be packaged in various forms, particularly tubes, jars or bottles, pump bottles, squeeze bottles or aerosol containers that apply the composition in vaporized or mousse form. The composition may be soaked in applicators, particularly gloves or wipes.

  The composition may be applied manually using an insoluble substrate impregnated with a container or composition with an application nozzle or actuator pump, pump, applicator and application comb.

  As used herein, the processes and compositions disclosed herein can be used on hair that has not been artificially dyed, colored, or permed.

  As used herein, the processes and compositions disclosed herein are also used for hair that has been artificially dyed, colored or permed, relaxed, curly straightened, or other chemical process. obtain.

  Compositions according to the present disclosure can be prepared by techniques well known to those skilled in the art.

  Although reference is made above to various exemplary embodiments, it will be understood that the present disclosure is not so limited. Those skilled in the art will appreciate that various modifications may be made to the embodiments of the present disclosure, and such modifications are intended to be included within the scope of the present disclosure. Where embodiments are used in this disclosure that illustrate particular structures and / or configurations, the present disclosure may be implemented with any other compatible structure and / or configuration that is functionally equivalent, provided that It is understood that such substitutions are not specifically prohibited or known to be impossible to those skilled in the art.

  The following examples are intended to further illustrate the present invention. They are in no way intended to limit the invention. Unless otherwise indicated, all percentages are by weight.

  In some embodiments, the present invention is a cosmetic composition applied to a keratin substrate, comprising at least one polycarbodiimide compound; and at least one amino compound selected from the group consisting of polyamines and silicone amines; At least one polycarbodiimide compound and at least one amino compound are present in a weight ratio of polycarbodiimide to amino compound in the range of about 10: 1 to about 1:10; the composition of the polycarbodiimide compound and amino compound Polycarbodiimide compound and amino compound in an amount sufficient to provide one or more of improved dyeability, improved color retention and extended color duration compared to a composition comprising only one of them A cosmetic composition is provided.

  In some embodiments, the composition comprises the polycarbodiimide and the amino compound together in an amount from about 0.1% to about 40.0% of the composition by active weight.

  In some embodiments, the amino compound is selected from polyamines and includes a colorant, and the composition provides keratin substrate with improved staining and retention.

  In some embodiments, the polycarbodiimide is present in an amount from about 0.01% to about 20% by weight, based on the weight of the composition, and the amino compound selected from the polyamine is based on the weight of the composition. The amino compound selected from silicone amine is present in an amount of from about 0.01% to about 40% by weight, based on the weight of the composition. To do. In some embodiments, the amino compound is a polyamine selected from vinylamine / vinylformamide copolymers.

  In some embodiments, the amino compound is a silicone amine selected from amodimethicone.

  In some embodiments, the present invention is a method of treating a keratin substrate that is effective to provide one or more of improved dyeability, improved color retention and increased color duration A method is provided comprising applying a quantity of the composition of claim 1 to a keratin substrate.

In some embodiments, the application to the keratin substrate is
A one-step process comprising preparing a composition comprising a polycarbodiimide and an amino compound as a premix, preparing by combining the polycarbodiimide, the amino compound and at least one solvent, and applying the mixed composition to a keratin substrate ;
The composition is prepared as a separate premix, each premix separately containing a polycarbodiimide, an amino compound and an optional colorant or dye, and the premix is a separate combination of polycarbodiimide and at least water. Prepared on a phase, separately combining an amino compound and at least one organic solvent to form a non-aqueous phase, and separately combining an optional colorant or dye and a suitable solvent. Yes, a one-step process where the premix is combined and stirred at the time of use to form an emulsion, which is applied to a keratin substrate;
The composition is prepared in the form of a separate premix, the premix is separately formed on the aqueous phase by combining polycarbodiimide and water, and the amino compound and organic solvent are combined separately to form a non-aqueous phase. Prepared separately by combining an optional colorant or dye and a suitable solvent, and when used, a premix containing a polycarbodiimide and a premix containing an amino compound are combined to form a mixture. A two-step process wherein the mixture and the premix containing the optional colorant or dye are each separately applied to the keratin substrate in any order; and the composition is prepared in the form of a separate premix The premix is separately formed on the aqueous phase by combining polycarbodiimide and water, and separately from the non-aqueous phase by combining the amino compound and the organic solvent. A multi-step process in which the premix is separately applied to the keratin substrate in any order, each in the order of use, prepared by separately combining an optional colorant or dye and a suitable solvent. A process of at least one stage selected from:

  In some embodiments, the present invention is a method of treating a keratin substrate, comprising an amino compound selected from polyamines and a colorant, the combination of which improves dyeability, improves color retention. And applying a composition according to claim 1 to a keratin substrate in an amount effective to provide one or more of color extension and color duration.

  In some embodiments, the present invention is a method of treating a keratin substrate that is effective to provide one or more of improved dyeability, improved color retention and increased color duration A method is provided comprising applying the composition of claim 1 to a keratin group, wherein the composition is an amino compound selected from any amount of silicone amine.

  In some embodiments, the present invention includes a kit comprising separately packaged forms, wherein the kit combines a polycarbodiimide, an optional colorant or dye, and an amino compound, and at least one The composition of claim 1 comprising two solvents; and polycarbodiimide, an optional colorant or dye, and an amino compound are provided in two or more separate packages, and in use, the contents of the package A product comprising at least one of the compositions of claim 1, wherein one or a combination of is stirred to form an emulsion and applied to a keratin substrate.

  In some embodiments, the present invention is a cosmetic composition applied to a keratin substrate, comprising at least one polycarbodiimide compound; and at least one amino compound comprising at least one polyvinylamine; a polycarbodiimide compound and An amino compound comprising polyvinylamine is present in a weight ratio of polycarbodiimide to polyvinylamine in the range of about 10: 1 to about 1:10; compared to a composition comprising only one of polycarbodiimide and polyvinylamine compound Thus, cosmetic compositions are provided that each include a sufficient amount of the polycarbodiimide compound and polyvinylamine to provide one or more of sustained style moisture resistance and increased styling retention.

  In some embodiments, the composition includes the polycarbodiimide and the polyvinylamine compound in an amount from about 0.1% to about 40.0% of the composition by active weight.

  In some embodiments, the composition comprises the polycarbodiimide and the polyvinylamine compound together in an amount from about 0.25% to about 20.0% by weight of the composition.

  In some embodiments, the composition comprises the polycarbodiimide and the polyvinylamine compound together in an amount from about 1% to about 10.0% by weight of the composition.

  In some embodiments, the retention force imparted to the keratin substrate provides the substrate with improved bending force properties.

  In some embodiments, the at least one additive comprising one or more rheology modifiers and thickener / viscosity modifiers that are water soluble or water dispersible compounds is an acrylic polymer, a non-acrylic polymer, starch Saccharide-based polymers (eg guar, guar gum), cellulosic polymers (particularly hydroxyethylcellulose, cellulose gum, alkylhydroxyethylcellulose, cellulose / carbohydrate containing carboxylic acids), non-polymeric and polymeric gelling agents, silica Selected from particles, clay, hyaluronic acid, alginic acid and mixtures thereof.

  In some embodiments, at least one or more selected from polymer-based (eg, cellulosic) thickeners, amphoteric surfactants, nonionic anchoring polymers, cationic surfactants, polyols and propellants. The composition further comprising:

  In some embodiments, the polyvinylamine is a vinylamine / vinylformamide copolymer.

  In some embodiments, the composition is at least selected from polymer-based (eg, cellulosic) thickeners, amphoteric surfactants, nonionic anchoring polymers, cationic surfactants, polyols and propellants. It further comprises one or more additional compounds.

  In some embodiments, the polycarbodiimide is present in an amount of about 0.01% to about 20% by weight, based on the weight of the composition, and the polyvinylamine is about 0.1% by weight, based on the weight of the composition. Present in an amount of ˜about 40% by weight.

  In some embodiments, the present invention is a method of applying to a keratin substrate selected from hair, eyelashes and eyebrows to enhance its styling, comprising of sustained style moisture resistance and increased styling retention A method is provided comprising applying to a keratin substrate an amount of the composition of claim 1 effective to provide one or more.

  In some embodiments, the method includes applying heat to the keratin substrate, and applying heat before, during or after applying the composition to the keratin substrate.

  In some embodiments, the present invention provides a method for durable non-permanent molding of at least one keratin substrate or a method for durable retention of a non-permanent form of at least one keratin substrate. Applying the composition of claim 1 to at least one keratin substrate; optionally heating at least one keratin substrate; if heating is used; A method of applying is provided.

Method of preparing a hair treatment composition (for hair repair or hair styling) Stirring a selected amount or weight percentage of active RM (raw material) in each solvent (either water, isododecane (IDD) or ethanol) A stock solution for each phase was prepared. Immediately before application, the desired ratio (usually active substance 1: 1) was weighed into a vial and shaken vigorously by hand for about 10 seconds per gram to produce a milky white emulsion. Usually 1 g of product was applied to 1 g of hair. In the case of a two-stage treatment, the stock solution was applied directly to the hair without premixing.

(Example)
A: Examples using silicone amines The following examples are intended to illustrate the invention and are non-limiting.

A. Test method 1) Method of determining durability using high humidity curl retention (HHCR) test Hair treatment Normal bleached hair sample (IHIP, length 13.5 cm, weight approx. 0.5 g) active substance in test solution Treated with 4 wt% solution (0.5 g solution / g hair). A comb was passed through the hair until the solution was evenly distributed on the surface of the hair swatch. The treated hair is then wrapped around a spiral rod (diameter 0.5)
Dry overnight at room temperature or in an oven at 50 ° C. for 30 minutes and then dry overnight at room temperature.

2) Measurement of curl retention The coiled hair was removed from the rod and placed in a humidified chamber at 90% RH, 40 ° C. for 5 hours. The following formula:
% Curl retention = (Lo-Lt) / (Lo-Li) × 100
In the formula: Lo = original hair length (length of fully elongated hair)
Li = initial hair length (length of hair before exposure to humidity)
% Curl retention was calculated using Lt = hair length after 5 hours exposure to moisture.

2) Method of hydrophobicity test using contact angle Hair treatment A piece or sample of hair that has been decolored twice (IHIP, width 0.5 cm, approx. 0.75 g) with the test composition (1 g treatment / g hair) Processed and placed in a 50 ° C. oven for 30 minutes, then allowed to dry overnight. The next morning, the hair was washed with a conventional sulfate ester shampoo (DOP shampoo), rinsed and dried with a helmet-type dryer, and the remaining hydrophobicity was measured.

Hydrophobicity Measurement The hydrophobicity of each sample was measured by contact angle measurement using Biolin Scientific's Contact Angle Tensiometer, Model C204A. A bundle of 30 to 50 fibers was finally sandwiched between them so that the surface was flat. A 3 uL drop of DI H2O was placed on the fiber surface and the contact angle was measured for 10 seconds. The numerical value reported below is the average of three measurements using the contact angle after 10 seconds.

  Fully porous or hydrophilic hair does not fully support the drop for 10 seconds. In such a case, the time taken for the drop to be fully absorbed / spread instead is reported instead.

I. High humidity curl retention of hair treated with aminosilicone compound 1 and polycarbodiimide 1 Hair samples were treated with the following 4% active solution (0.5 g / g hair):
4% isododecane solution of aminosilicone compound 1 2% (isododecane) solution of aminosilicone compound 1 + 2% aqueous solution of polycarbodiimide 1 4% aqueous solution of polycarbodiimide 1

  The hair was then wrapped around a spiral curling rod and allowed to dry overnight. The results of high humidity curl retention (HHCR) are shown below.

  The results show that the percent curl retained is increased in hair treated with the composition of the present invention at room temperature and is resistant to higher humidity and temperature than hair treated with either substance alone. Is high. Hair treated with the composition of the present invention is treated with any of the substances alone and retains curl more than a hair swatch that exhibits a low curl retention value indicating low styling / curl retention over time and at high humidity. As is apparent from the high value, the styling / curl retention strength was large over time and under high humidity conditions. Thus, the incorporation of polycarbodiimide results in increased moisture resistance along with hair coating due to cross-linking interaction with amine silicone and hair.

II. High humidity curl retention of hair treated with aminosilicone compound 1 and polycarbodiimide 1 and heat 3 hair samples were treated with a 4% active treatment solution prepared as described in Example I above (0.5 g product / g hair).

  The hair was then dried in an oven at 50 ° C. for 30 minutes and then further dried at room temperature overnight on a spiral curling rod. HHCR results are shown below.

  The results show an increase in the percent curl retained in hair treated with the composition of the present invention, heat dried (50 ° C. for 30 minutes), and then dried at room temperature, It can be seen that the hair treated with either substance alone is more resistant to high humidity and high temperature. Furthermore, the percent curl retention of hair treated with the composition of the present invention was greater when using heat than that obtained without heat (see Table 1). It can be expected that other types of heating means such as blow dryers, flat irons, hot irons, steam / hot rollers, etc. can be used to achieve the same or nearly the same results as obtained by the present invention.

III. High-humidity curl retention of hair treated with aminosilicone compound 2 and polycarbodiimide 1 A hair sample is a 4% active solution of the following composition (0.5 g / g hair):
4% isododecane solution of aminosilicone compound 2 (isododecane) 2% solution of aminosilicone compound 2 + 2% polycarbodiimide 1
4% polycarbodiimide 1
Was processed.

  The hair was then wrapped around a spiral curling rod and allowed to dry overnight. The results of high humidity curl retention (HHCR) are shown below.

  The results show an increase in the percent curl retained in treated hair with the composition of the present invention at room temperature, which is more resistant to high humidity and temperature than hair treated with either substance alone. I understand that it is expensive. Hair treated with the composition of the present invention is treated with any of the substances alone and retains curl more than a hair swatch that exhibits a low curl retention value indicating low styling / curl retention over time and at high humidity. As is apparent from the high value, the styling / curl retention strength was large over time and under high humidity conditions. Thus, the incorporation of polycarbodiimide results in increased moisture resistance along with hair coating due to cross-linking interaction with amine silicone and hair.

IV. High humidity curl retention of hair treated with aminosilicone compound 2 and polycarbodiimide 1 and heat 3 hair samples with 4% active treatment solution (0.5 g product / g hair) prepared as described in Example I above Processed.

The hair was then dried in an oven at 50 ° C. for 30 minutes and then further dried at room temperature overnight on a spiral curling rod. The results of high humidity curl retention are shown below.

  The results show an increase in the percent curl retained in hair treated with the composition of the present invention, heat dried (50 ° C. for 30 minutes), and then dried at room temperature, It can be seen that the hair treated with either substance alone is more resistant to high humidity and high temperature. Furthermore, the percent curl retention of hair treated with the composition of the present invention was greater when using heat than that obtained without using heat (see Table 3). It can be expected that other types of heating means such as blow dryers, flat irons, hot irons, steam / hot rollers, etc. can be used to achieve the same or nearly the same results as obtained by the present invention.

  The above examples show that the cross-linking interaction between aminosilicone compounds and polycarbodiimide and hair results in better style and shape memory as evidence from hairstyle / curl resilience to high humidity. ing.

V. Hydrophobicity of hair treated with aminosilicone compound 1 and polycarbodiimide 1 Three hair swatches with the following composition:
2% isododecane solution of aminosilicone compound 1 Isododecane 2% solution of aminosilicone compound 1 + 2% aqueous solution of polycarbodiimide 1 Treated with a 2% aqueous solution of polycarbodiimide 1 (1 g product / g hair).

The hair was then placed in a 50 ° C. oven for 30 minutes and then allowed to dry overnight at room temperature. After the next day's shampoo, the sample showed these contact angles:

  The above contact angle measurements resulted in an increase in the hydrophobicity imparted to the hair even after shampooing the hair by combining polycarbodiimide and an aminosilicone compound, ie imparted to the hair It indicates that the hydrophobicity was shampoo resistance. In contrast, the results show that the aminosilicone compound did not impart hydrophobicity to the hair, as indicated by the zero contact angle, and that the polycarbodiimide imparted low hydrophobicity to the hair.

VI. High humidity curl retention (HHCR) test and shampoo resistance Hair treatment Wash hair sample obtained in Test Method 1 (Apply product (dry with or without heat, 40 ° C, humidity 90) High humidity curl retention is performed at%) Remove the swatch from the humidification chamber and place at ambient room temperature.

Washing treatment The hair is washed with 0.4 g of a commercially available shampoo per gram of hair. Moisten hair with shampoo for 10 seconds and rinse with water for 20 seconds. Pass the comb twice through the hair to loosen it. Wrap the hair swatch around the curling rod. Dry overnight at room temperature.

Measurement of curl retention The coiled hair was removed from the rod and placed in a humidified chamber at 90% RH, 40 ° C. for 5 hours. % Curl retention was calculated as described above.

  The sample was first dried in an oven at 50 ° C. for 30 minutes and then dried at room temperature after one shampooing. After washing the sample, it was not dried further using heat.

  The results show that the percent curl retained is increased in hair treated with the composition of the present invention at room temperature and is more resistant to shampoo, high humidity and high temperature than hair treated with either substance alone. I understand that it is expensive. As can be seen from the higher curl retention value of the composition of the present invention, high styling / curl retention force was exhibited even when subjected to shampooing over time under high humidity conditions. In contrast, hair treated with either substance alone showed low curl retention values and low styling retention when subjected to high humidity over time and shampooing. Thus, the incorporation of polycarbodiimide provides increased moisture resistance along with hair coating due to cross-linking interaction with amine silicone and hair, with or without a heating step.

B: Example using amine / polyamine

A. Test method 1) Method for determining durability using high humidity curl retention (HHCR) test Hair treatment Ordinary bleaching hair sample (IHIP, length 13.5 cm, weight approx. 0.5 g) Treated with a solution of 4% by weight of active substance (0.5 g solution / g hair). A comb was passed through the hair until the solution was evenly distributed on the surface of the hair swatch. The treated hair is then wrapped around a spiral rod (diameter 0.5)
Dry overnight at room temperature or in an oven at 50 ° C. for 30 minutes and then dry overnight at room temperature.

Measurement of curl retention The coiled hair was removed from the rod and placed in a humidified chamber at 90% RH, 40 ° C. for 5 hours. The following formula:
% Curl retention = (Lo-Lt) / (Lo-Li) × 100
In the formula: Lo = original hair length (length of fully elongated hair)
Li = initial hair length (length of hair before exposure to humidity)
% Curl retention was calculated using Lt = hair length after 5 hours exposure to moisture.

2) Method for obtaining mechanical properties of treated hair using three-point bending Hair treatment A piece of normal hair (IHIP, 1 cm wide, 15 cm long, about 2.0 to 2.5 g hair) with the test solution Treated (0.5 g aqueous solution / g hair). A comb was passed through the hair until the solution was evenly distributed on the surface of the lock. The straight shaped treated hair was then dried overnight at room temperature.

Three-point bending measurement Cosmet. Sci. , 53, 345-362 (November / December 2002), using a texture analyzer (Model TA-XPlus, Texture Technologies) with accessories for hair mounting did. The cantilever bending experiment consisted of the following series of steps: the hair strand was placed on two points of 6 cm in width, the third probe was lowered to the center of the hair strand, and the hair strand was strained 10 mm. For 10 cycles. The test protocol was as follows:
Test mode = Compression Speed before test = 2 mm / sec Test speed = 2 mm / sec Speed after test = 2 mm / sec Target mode = Distance Distance = 10 mm
Count = 10
Trigger type = Automatic (force)
Trigger force = 1g

  After 10 cycles of bending, a force plot was made as a function of 10 strain distances. The maximum force of the first strain was obtained from the plot.

  A large maximum force indicates that the hair is hard and has a strong holding force, and a small maximum force indicates that the hair is soft and has a weak holding force.

  Each experiment is performed in triplicate and results are reported from the average of three experiments.

3) Method of hydrophobicity test using contact angle Hair treatment A piece or sample of hair that has been decolored twice (IHIP, width 0.5 cm, approx. 0.75 g) is treated with the composition of the invention (1 g treatment) / G hair), placed in a 50 ° C. oven for 30 minutes and then dried overnight. The next morning, the hair was washed with a conventional sulfate ester shampoo (DOP shampoo), rinsed and dried with a helmet-type dryer, and the remaining hydrophobicity was measured.

Hydrophobicity Measurement The hydrophobicity of each sample was measured by contact angle measurement using Biolin Scientific's Contact Angle Tensiometer, Model C204A. A bundle of 30 to 50 fibers was finally sandwiched between them so that the surface was flat. A 3 uL drop of DI H ₂ O was placed on the fiber surface and the contact angle was measured for 10 seconds. The numerical value reported below is the average of three measurements using the contact angle after 10 seconds.

B. Example I. A hair sample treated with polyvinylamine and polycarbodiimide 1 is treated with a 4% active solution:
4% aqueous solution of polyvinylamine 2% polyvinylamine + 2% aqueous solution of polycarbodiimide 1 Treated with a 4% aqueous solution of polycarbodiimide 1 (0.5 g / g hair).

  The hair was then dried overnight under ambient environmental conditions wrapped around a curling rod. The hair was removed from the curling rod and placed in a humid chamber at 90% humidity and 40 ° C. for 5 hours. The results of high humidity curl retention are shown below.

  The results in the table above show an increase in the percent curl retained with hair treated with the composition of the present invention at room temperature and higher humidity than with hair treated with either substance alone. It can also be seen that the resistance to high temperatures is high. Hair treated with the composition of the present invention is treated with any of the substances alone and retains curl more than a hair swatch that exhibits a low curl retention value indicating low styling / curl retention over time and at high humidity. As is apparent from the high value, the styling / curl retention strength was large over time and under high humidity conditions. Thus, the combination of polycarbodiimide and amino compound resulted in a coating on the hair, thereby imparting the hair with increased moisture resistance resulting from the interaction of the polycarbodiimide with the amino compound and the hair.

II. High humidity curl retention of polyvinlyamine and polycarbodiimide 1 and heat treated hair 3 hair swatches in 4% active solution:
4% aqueous solution of polyvinylamine 2% polyvinylamine + 2% aqueous solution of polycarbodiimide 1 Treated with a 4% aqueous solution of polycarbodiimide 1 (0.5 g / product g).

  The hair was then dried on a spiral curling rod in an oven at 50 ° C. for 30 minutes and then further dried overnight at room temperature. The hair was then removed from the curling rod and placed in a humidification chamber at 90% humidity and 40 ° C. for 5 hours. The results of high humidity curl retention are shown below.

  The results in the table above show an increase in the percent curl retained in hair treated with the composition of the present invention, heat dried (50 ° C. for 30 minutes), and then dried at room temperature. It can be seen that the hair treated with the substance alone has higher resistance to high humidity and high temperature. Furthermore, the percent curl retention of hair treated with the composition of the present invention was greater when using heat than that obtained without heat (see Table 1). Other types of heating means, such as helmet-type dryers (in stores), blow dryers, heating lamps and curling irons or any other means deemed appropriate, are also obtainable by the present invention. It can be expected that the same or nearly the same results will be obtained.

III. High-humidity curl retention of hair treated with alkoxylated polyamine and polycarbodiimide 1 A hair swatch is a 4% active solution of the following composition:
4% ethanol solution of alkoxylated polyamine 2% ethanol solution of alkoxylated polyamine + 2% aqueous solution of polycarbodiimide 1 Treated with a 4% aqueous solution of polycarbodiimide 1 (0.5 g / g hair).

  The hair was then dried overnight with the curling rod wrapped around. The hair was then removed from the curling rod and placed in a humidification chamber at 90% humidity and 40 ° C. for 5 hours. The results of high humidity curl retention are shown below.

  The results in the table above show an increase in the percent curl retained with hair treated with the composition of the present invention at room temperature and higher humidity than with hair treated with either substance alone. It can also be seen that the resistance to high temperatures is high. Hair treated with the composition of the present invention is treated with any of the substances alone and retains curl more than a hair swatch that exhibits a low curl retention value indicating low styling / curl retention over time and at high humidity. As is apparent from the high value, the styling / curl retention strength was large over time and under high humidity conditions. Thus, the combination of polycarbodiimide and amino compound resulted in a coating on the hair, thereby imparting the hair with increased moisture resistance resulting from the interaction of the polycarbodiimide with the amino compound and the hair.

IV. High humidity curl retention of hair treated with alkoxylated polyamine and polycarbodiimide 1 and heat An active solution was prepared as described in Example IV above.

Three hair swatches with 4% active solution:
4% ethanol solution of alkoxylated polyamine 2% ethanol solution of alkoxylated polyamine + 2% aqueous solution of polycarbodiimide 1 Treated with a 4% aqueous solution of polycarbodiimide 1 (0.5 g / g product).

  The hair was then dried on a spiral curling rod in an oven at 50 ° C. for 30 minutes and then further dried overnight at room temperature. The hair was then removed from the curling rod and placed in a humidification chamber at 90% humidity and 40 ° C. for 5 hours. The results of high humidity curl retention are shown below.

  The results in the table above show that there was an increase in the percent curl retained in hair treated with the composition of the invention, heat dried (50 ° C. for 30 minutes) and then dried at room temperature. It can be seen that the hair treated with either substance alone is more resistant to high humidity and high temperature. Furthermore, the percent curl retention of hair treated with the composition of the present invention was greater when using heat than that obtained without using heat (see Table 3). Other types of heating means, such as helmet-type dryers (in stores), blow dryers, heating lamps, curling irons or any other means deemed appropriate, are also obtainable by the present invention. It can be expected that the same or nearly the same results will be obtained.

V. Mechanical properties of hair treated with polyvinylamine and polycarbodiimide 1 A virgin (non-chemically treated) hair sample (approximately 2.0-2.5 g) was treated with the following aqueous solution prepared as in Example I above. (0.5 g product / g hair):
2% aqueous solution of polyvinylamine 2% aqueous solution of polyvinylamine + 2% polycarbodiimide 1 2% aqueous solution of polycarbodiimide 1.

  The treated hair swatch was dried overnight at room temperature. A three-point bend test was performed on these hair samples (three replicates) to determine the maximum force (FMax) required to bend the hair down 10 cm.

  The results show that the hair treated with the composition of the present invention is significantly increased in hardness compared to hair treated with either PVA or polycarbodiimide alone, at least twice and up to 138 times stiffer. Yes. Also, the maximum force obtained using the composition of the present invention was significantly greater than the combined maximum force obtained using each substance alone. The greatly increased hardness of the hair treated with the composition of the present invention also indicates a strong retention on the hair. By incorporating polycarbodiimide into the coating, the hardness increases due to the interaction of the polycarbodiimide with the amino compound and the hair. This increase in hardness is interpreted as an improvement in the styling / molding performance of the coating or film.

  The above example shows that the interaction between amino compounds, polycarbodiimides and hair is better, as evidenced by the higher stiffness / stiffness / retentiveness as well as the resilience of hairstyle / curls to high humidity It brings about memory of style and shape.

VI. Hydrophobic and shampoo resistance of damaged hair treated with polyvinylamine and polycarbodiimide 1 A hair sample (width 0.5 cm, 0.75 g) decolorized twice is used as an aqueous solution as follows:
2% polyvinylamine 2% polyvinylamine 2% polycarbodiimide 1
2% polycarbodiimide 1
(1 g product / g hair).

The treated hair swatch was placed in a 50 ° C. oven for 30 minutes and then allowed to dry overnight at room temperature. The sample was shampooed 10 times using a conventional sulfate ester shampoo (10 shampoo / wash cycles). The following contact angles were measured:

  The contact angle measurements in the table above show that the combination of polycarbodiimide and an amino compound resulted in an increase in the hydrophobicity imparted to the hair even after 10 shampoos on the hair, i.e. It shows that the imparted hydrophobicity was shampoo resistance. In contrast, polycarbodiimide does not impart hydrophobicity to the hair, as indicated by the zero contact angle, and the hydrophobicity imparted to the hair by the amino compound is low.

VII. High Humidity Curl Retention (HHCR) Test and Shampoo Resistance Method Hair Treatment Hair samples treated according to Examples I and II above (Tables 1 and 2) were washed as described below.

Washing treatment The hair was treated with 0.4 g of a commercially available shampoo per gram of hair. The hair was rubbed with shampoo for 10 seconds and rinsed with water for 20 seconds. The comb was passed through the hair twice to loosen it. A hair swatch was wrapped around a curling rod and allowed to dry overnight at room temperature.

Measurement of curl retention The coiled hair was removed from the rod and placed in a humidified chamber at 90% RH, 40 ° C. for 5 hours. % Curl retention was calculated as described above.

1) Results of shampoo resistance test for hair treated according to Example I (Table 1) (HHCR value)
The hair sample treated with the active solution was shampooed and dried overnight while wrapped around a curling rod.

  The results in the table above show that the percent curl retained is increased in hair treated with the composition of the present invention at room temperature and is higher in shampoo, higher than hair treated with either substance alone. It can be seen that it is highly resistant to humidity and high temperature conditions. As can be seen from the higher curl retention value of the composition of the present invention, high styling / curl retention power was exhibited even when shampooing was performed over time under high humidity conditions. In contrast, hair treated with either substance alone showed low curl retention values and low styling retention when subjected to high humidity over time and shampooing. Thus, the hair treated with the composition of the present invention exhibited significantly better wash / shampoo properties than the hair treated with each substance alone.

2) Shampoo resistance test results (HHCR value) for hair treated according to Example II (Table 2) (heated)
These specimens were first dried in an oven at 50 ° C. for 30 minutes and then dried at room temperature after one shampooing. After washing the sample, it was not dried further using heat.

  The results show that the percent curl retained is increased in hair treated with the composition of the present invention at room temperature and is more sensitive to shampoo, high humidity and high temperature than hair treated with either substance alone. It turns out that tolerance is high. As can be seen from the higher curl retention value of the composition of the present invention, high styling / curl retention power was exhibited even when shampooing was performed over time under high humidity conditions. In contrast, hair treated with either substance alone showed low curl retention values and low styling retention when subjected to high humidity over time and shampooing. Thus, hair treated with the composition of the present invention and exposed to heat exhibited significantly better anti-wash / shampoo properties than hair treated with each substance alone.

  Furthermore, the percent curl retention of hair treated with the composition of the present invention was greater when using heat than that obtained without using heat (see Table 7). Other types of heating means, such as helmet-type dryers (in stores), blow dryers, heating lamps, curling irons or any other means deemed appropriate, are also obtainable by the present invention. It can be expected that the same or nearly the same results will be obtained.

  It should be understood that the foregoing describes preferred embodiments of the present disclosure and modifications may be made thereto without departing from the spirit and scope of the present disclosure as set forth in the claims.

C: Examples using polyvinylamine Method for preparing hair treatment composition (for hair repair or hair styling) Selected amount or weight percentage of active RM (raw material) selected solvent (water, water and isododecane (IDD) ) Or a mixture with an organic solvent such as ethanol or an organic solvent) to prepare a stock solution for each phase. Immediately prior to application, the desired ratio (usually 2: 1 active substance) was weighed into a vial and mixed into a hair treatment solution. When the two phases included an aqueous phase and a non-aqueous phase, the two phases in the vial were stirred or shaken into an emulsion. Usually, 0.25-1 g of product was applied to 0.5-2 g of hair. In the case of a two-stage treatment, the stock solution is applied directly to the hair without premixing.

Test method 1) Method of determining durability using high humidity curl retention (HHCR) test Hair treatment Normal bleached hair sample (IHIP, length 13.5 cm, weight approx. 0.5 g) active substance in test solution (0.5 g solution / g hair). A comb was passed through the hair until the solution was evenly distributed on the surface of the hair swatch. The treated hair is then wrapped around a spiral rod (diameter 0.5)
Dry overnight at room temperature or in an oven at 60 ° C. for 30 minutes and then dry overnight at room temperature.

Measurement of curl retention The coiled hair was removed from the rod and placed in a humidified chamber at 80% RH, 25 ° C. for 5 hours. The following formula:
% Curl retention = (Lo-Lt) / (Lo-Li) × 100
In the formula: Lo = original hair length (length of fully elongated hair)
Li = initial hair length (length of hair before exposure to humidity)
% Curl retention was calculated using Lt = hair length after 5 hours exposure to moisture.

2) Method for obtaining mechanical properties of treated hair using three-point bending Hair treatment A piece of normal hair (IHIP, 1 cm wide, 15 cm long, about 2.0 to 2.5 g hair) with the test solution Treated (0.5 g aqueous solution / g hair). A comb was passed through the hair until the solution was evenly distributed on the surface of the lock. The straight shaped treated hair was then dried overnight at room temperature.

Three-point bending measurement Cosmet. Sci. , 53, 345-362 (November / December 2002), using a texture analyzer (Model TA-XPlus, Texture Technologies) with accessories for hair mounting did. The cantilever bending experiment consisted of the following series of steps: the hair strand was placed on 2 points of 6 cm width, the third probe was lowered to the center of the hair, and a 10 mm strain was applied to the hair strand. Cycled.

  The test protocol included the following parameters: test mode = compression; pre-test speed = 2 mm / sec; test speed = 2 mm / sec; post-test speed = 2 mm / sec; target mode = distance; distance = 10 mm; count = 10; trigger type = automatic (force); trigger force = 1 g.

  After 10 cycles of bending, a force plot was made as a function of 10 strain distances. The maximum force of the first strain was obtained from the plot. A large maximum force indicates that the hair is hard and has a strong holding force, and a small maximum force indicates that the hair is soft and has a weak holding force.

  Each experiment is performed in triplicate and results are reported from the average of three experiments.

Examples Raw materials used in Examples A: Names and names of ingredients:
Polyvinylamine or PVA (INCI name is vinylamine / vinylformamide copolymer; commercially available as LUVIQUAT9030 from the supplier BASF)
Polycarbodiimide 1 (commercially available as V-02-L2 from supplier Nishishinbo)

B. Exemplary Composition In one exemplary embodiment, a composition according to the present invention includes a component comprising polyvinlyamine, as listed in Table 1A, and the polyvinlyamine is represented in Table 1B. In combination with the polycarbodiimide in an amount of about 1: 1 to about 1: 2 of the polycarbodiimide to polyvinylamine-containing composition.

I. High-humidity curl retention of hair treated with polyvinylamine and polycarbodiimide 1 A hair sample with a composition comprising polycarbodiimide and polyvinylamine in the following ratio at room temperature (25 ° C.) and with heat (60 C.) treated (0.5 g product / g hair). The hair was then dried overnight under ambient conditions with the curling rod wrapped around. The hair was removed from the curling rod and placed in a humidification chamber at 80% humidity and 25 ° C. for 5 hours.

  The results in the table above show that the percent curl retained was increased for hair treated with the composition of the present invention at room temperature compared to hair treated with Formulation 1 containing polyvinylamine alone. A significant increase is observed in the composition treated with heat, indicating that it is more resistant to high humidity and temperature than hair treated with either substance alone.

  Hair treated with the composition of the present invention has a low curl when the curl retention value when treated at a high temperature indicates that the styling / curl retention is small even when treated with any of the substances alone and over time and at high humidity. As is apparent from the fact that it was higher than the hair sample that showed a retention value, it showed a large styling / curl retention force over time and under high humidity conditions. Thus, the combination of polycarbodiimide and an amino compound resulted in a film coating on the hair, thereby imparting the hair with increased moisture resistance resulting from the interaction of the polycarbodiimide with the amino compound and the hair. .

II. Mechanical properties of hair treated with polyvinylamine and polycarbodiimide 1 Virgin (non-chemically treated) hair swatches (about 2.0-2.5 g) were treated with the solution prepared as in Example I above ( 0.5 g product / g hair). The treated hair swatch was dried overnight at room temperature. A three-point bend test was performed on these hair samples (three replicates) to determine the maximum force (FMax) required to bend the hair down 10 cm.

  The results show that the hair treated with the composition of the present invention showed a significant increase in hardness whether treated at room temperature or at elevated temperatures, with the most pronounced increase observed for hair treated at room temperature. Is shown. Formulation 1 of the present invention containing polycarbodiimide showed more than twice the hardness of hair treated with Formulation 1 of the present invention alone, and more than 6 times the hardness of hair treated with polycarbodiimide alone. . Also, the maximum force obtained using the composition of the present invention was significantly greater than the combined maximum force obtained using each substance alone. The greatly increased hardness of the hair treated with the composition of the present invention also indicates a strong retention on the hair.

  The above example shows that the interaction between amino compounds, polycarbodiimides and hair is better, as evidenced by the higher stiffness / stiffness / retentiveness as well as the resilience of hairstyle / curls to high humidity It brings about memory of style and shape.

D: Examples using silicone amines and polyamines for hair dyeing Steps to discolor hair In some embodiments, the present invention has made hair color lighter or lighter and / or deposited artificial colors on the hair Including discoloring the hair, which can be achieved in some cases.

  Artificial colors can be due to oxidative coloring using oxidative dye precursors, direct coloring using direct dyes or temporary coloring using temporary colorants such as pigments and natural dyes.

  When it is desired to lighten the color of the hair, it is possible to mix the hair treatment composition of the present invention with an oxidizing composition containing at least an oxidizing agent.

  When performing oxidative coloring on the hair, the hair treatment composition of the present invention further contains a colorant selected from oxidative dye precursors and mixes such a composition with an oxidative composition containing at least an oxidant. Is possible.

  As used herein, the term “mixing” and any variation of this term refers to bringing the hair treatment composition into contact with, combing, reconstituting, dissolving, dispersing, formulating, Or to penetrate. It may also mean introducing the hair treatment composition into the oxidizing composition. It may also mean that the hair treatment composition is placed in the same vessel or container as the oxidizing composition.

  Therefore, the step of discoloring hair with the oxidizing composition according to the present invention comprises applying to the hair a composition for discoloring hair comprising the hair treatment composition of the present invention and the oxidizing composition. The aforementioned composition applied to the hair is formed by mixing the hair treatment composition and the oxidizing composition.

  The hair treatment composition may be about 1: 0.01 to about 1:10, such as about 1: 0.01 to about 1: 0.05, about 1: 0.05 to about 1: 0.1 with the oxidizing composition. About 1: 0.1 to about 1: 0.5, about 1: 0.5 to about 1: 1, about 1: 1 to about 1: 2, about 1: 2 to about 1: 3, about 1: 3 to about 1: 4, about 1: 4 to about 1: 5, about 1: 5 to about 1:10, and the like can be mixed or combined. Accordingly, in various embodiments, the compositions of the present invention according to the present disclosure include from 1 to about 0.01, including increments and ranges between and between about 1: 0.01 and about 1:10 with the oxidizing composition. 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.2, 03, 0.4, 0.5, Mix or combine in weight ratios up to one of 0.6, 0.7, 0.8, 0.9, 1, 2, 3, 4, 5, 6, 7, 8, 9 and 10 be able to.

  When applying a composition for discoloring hair comprising a hair treatment composition and an oxidizing composition, from about 1 to about 60 minutes, such as from about 5 to about 45 minutes, or such as from about 5 to about 20 minutes, etc. Or after a resting time (standing time) in the range of for example about 10 to about 20 minutes, or for example about 20 minutes, optionally rinsing the hair, optionally shampooing and rinsing again, optionally a hair conditioning composition Wash with material, rinse again and then dry. The shampoo and hair conditioning composition can be any conventional hair shampoo product and hair conditioner product.

  In other embodiments, the composition does not include a color changing composition and is applied to the keratin substrate either before, simultaneously with, or after application of the color changing composition. In some embodiments, the application before or after is immediately before or after, and in other embodiments, the time frame between application of the combination of the present invention and application of the color changing composition is minutes, hours or It can be a day.

  Further, regardless of whether the composition of the present invention is applied together with the discoloring composition, the mixture or composition present on the fiber or hair (immediate mixing of the hair treatment and oxidizing composition, hair treatment and oxidizing composition) Continuous application or application of a composition without any colorant or dye) for a period of time, generally from about 1 to about 60 minutes, such as from about 5 to about 45 minutes, or such as from about 5 to about 30 minutes, etc. Or, for example, for about 5 to about 20 minutes, or for example about 10 to about 20 minutes, or for example about 20 minutes, or for example about 10 minutes.

  The temperature in the step of discoloring the hair is from room temperature to 80 ° C, and in certain embodiments from room temperature to 60 ° C.

  An effective amount of the composition is typically about 0.1 grams to about 50 grams, an amount of about 20-60 grams for some hair treatment applications, and about 20 to about about 20 to about additional embodiments for rich hair. An amount of 80 grams or more. Thus, the amount applied depends on the amount or volume of the keratin substrate to be treated, e.g. hair, and thus the greater range for the higher amount or portion of hair from the lower range for the lower amount or portion of hair. It will be understood that it can fall within the range and beyond. In the case of hair treatment, a typical application is for the entire head. It will be appreciated that application to the hair typically includes penetrating the composition into the hair.

Test Method Colorimetric Measurement After treatment of the hair, to measure the degree of change in the color of the hair (for example, lightening / lightening the color or degree of dyeing), the Minolta CM2600d in the CIEL ^* a ^* b ^* system The color of each sample is measured using a spectrocolorimeter (with reflector component, angle 10 degrees, light source D65).

The L ^* a ^* b ^* color system is a color system that assigns each color to a position in a spherical color space. In this color space, lightness is represented by a position in the vertical axis (z-axis) direction, hue is represented by a circumferential position, and saturation is represented by a distance from the central axis. Position on the vertical axis representing lightness (z-axis) is referred to as L ^*, L ^* value is changed from 0 corresponding to black and 100 corresponding to white. The positive x-axis direction corresponds to the red direction, the positive y-axis direction corresponds to the yellow direction, the negative x-axis direction corresponds to the green direction, and the negative y-axis direction corresponds to the blue direction. The position on x is referred to as a ^* and its value varies from −60 to +60, the position on y is referred to as b ^* and its value varies from −60 to +60. Hue and saturation are represented by a ^* and b ^* values, respectively.

Two parameters, L and ΔE (Delta E) can be measured. L ^* represents the color intensity, a ^* represents the green / red axis, and b ^* represents the blue / yellow axis. The determination of the value of ΔE is based on L ^* , a ^* and b ^* .

  In this system, the larger the value of L, the lighter the color or the lower the intensity. Conversely, the smaller the value of L, the darker the color or the greater the intensity (when the composition contains a colorant, this also indicates higher dyeability).

  ΔL, ie, the difference between the L value of the treated hair and the L value of the control hair sample represents a change in the L value. Specifically, the more negative the ΔL value, the darker the color deposited on the hair: ΔL = Lt ( Treated hair) -Lc (control hair).

  Delta E (ΔE) represents a change in color. When ΔE is less than 1.0, there is almost no color difference visible to the human eye. If ΔE is greater than 1.0, there is a visible color difference.

Example 1: Hair dye protection using polycarbodiimide and polyamine Objective To use polycarbodiimide and polyamine as a color treatment to improve dyeability and color retention of colored hair against shampoos.

Materials Polycarbodiimide (Carbolite V-10 from Nishibo)
Vinylamine / vinylformamide copolymer (Lupamine 9080 from BASF)

Protocol A normal depigmented hair sample (approximately 5 g) was dyed with L'Oreal Excellence 6RR color cream (Intense Auburn) for 30 minutes according to the following protocol:

The following ratios were used for the coloring process:
1 (g number of hair): 2 (g number of color cream / dye): 3 (g number of 20 Vol color former): 0.5 (g number of water or test substance):

  After coloring, the hair was rinsed with water for 30 seconds, dried with a dryer, and shampooed 10 times.

  L, a, and b values were determined before and after shampooing. Subsequently, the change dE (delta E) of the whole color was calculated.

  The results show that samples treated with color cream containing both polycarbodiimide and polyamine are more red in color (highest value of a) and retain most color after shampooing compared to untreated and other controls (DE is the smallest).

  Specifically, when polycarbodiimide alone is added to the colored composition, no improvement in color protection is seen, as can be seen from the comparable dE values. Polyamine alone reduces color protection, as can be seen from the higher dE value than protocol 1. Only when the polyamine and polycarbodiimide work together, color protection is provided, as can be seen from the lower dE value than protocol 1.

  The color protection provided by this collaboration is visible because it is true to the original color compared to any control.

Example 2: Post-coloring treatment for hair color protection using polycarbodiimide and silicone amine Purpose Use of polycarbodiimide and silicone amine as post-coloring treatment to promote color retention for colored hair shampoo.
Materials Polycarbodiimide (Carbodilite V-02-L2 from Nishibo)
Amodimethicone / Siliconeamine (Shin Etsu KF8020)

Protocol Normal depigmented hair swatches (about 1 g each) were colored with L'Oreal Excellence 6RR color cream (Intense Auburn) for 30 minutes, rinsed and air dried. The following ratios were used for the coloring process:
1 (g number of hair): 1.5 (g number of color cream): 3 (g number of 20 Vol color former).

After coloring, 2 g of the following treatment agent was applied to the colored hair, left on the hair for 15 minutes, and then the hair was dried with a dryer:

  After the treatment, the hair was shampooed 10 times.

  L, a, and b values were determined before and after shampooing. Subsequently, the change dE (delta E) of the whole color was calculated.

  The results show that samples treated with both polycarbodiimide and silicone amine retain the most color after shampooing (smallest dE) compared to untreated and other controls. Specifically, when carbodilite alone is used, there is a reduction in color protection, as can be seen from the large dE value. Silicone amine alone does provide some color protection on its own, as can be seen from the low dE value. However, when silicone amines and polycarbodiimides work together, the best color protection is provided, as can be seen from the lowest dE values.

  The color protection provided by this collaboration is visible because it is true to the original color compared to any control.

  It should be understood that the foregoing describes preferred embodiments of the present disclosure and modifications may be made thereto without departing from the spirit and scope of the present disclosure as set forth in the claims.

Claims (21)

A composition for the treatment of keratin substrates,
A polycarbodiimide compound;
One or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof;
The polycarbodiimide compound in a total amount of about 0.01 to about 10.0% by weight of the composition and one of the compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof Or a plurality of compounds,
Increased hydrophobicity after applying the polycarbodiimide compound and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof to the keratin substrate, respectively. In an amount sufficient to provide one or more of increased retention and force to the shape or profile of the keratin substrate,
Composition. The polycarbodiimide compound includes a carbodiimide polymer or a carbodiimide copolymer, and has the following formula:

Wherein X ₁ and X ₂ each independently represent O, S or NH; R ₁ and R ₂ each independently represent one or more catenary or non-catenary forms (non -Catenarly) a hydrocarbon group containing a heteroatom and containing a linear or branched and cyclic or acyclic group that is an ionic or nonionic segment, or one or more catenary or non-catenary A partially or wholly fluorinated hydrocarbon group containing a catenary heteroatom; n and z are each independently an integer of 0 to 20; L ₁ is C ₁ to C ₁₈ divalent aliphatic hydrocarbon _groups, C 3 _{-C 13} divalent alicyclic hydrocarbon _groups, C 6 _{-C 14} divalent aromatic hydrocarbon groups, C Represents -C ₁₂ divalent heterocyclic group or m- tetramethylxylylene C ₆ -C ₁₄ divalent aromatic that are not selected from alkylene hydrocarbon group, the plurality of L ₁ groups may be the being the same or different E is
O—R ₃ —O; S—R ₄ —S; and R ₅ —N—R ₄ —N—R ₅ ;
A radical selected from the group consisting of:
Wherein R ₃ and R ₄ are each independently an aromatic radical, alicyclic radical, which may contain a halogen atom or one or more catenary or non-catenary heteroatoms , Aryl radicals and hydrocarbon radicals including linear or branched alkyl radicals, R ₅ is hydrogen or a hydrocarbon radical, and when present, said hydrocarbon radical is a halogen atom or one or Including multiple catenary or non-catenary heteroatoms)
The composition of claim 1 having The polycarbodiimide compound has the following formula:

(Wherein R is an alkyl, cycloalkyl or aryl group having 1 to 24 carbon atoms)
The composition of claim 2 which is a copolymer derived from alpha-methylstyryl-isocyanate having: The polycarbodiimide compound has the following structure:

(In the formula, R is an alkyl group, a cycloalkyl group or an aryl group)
The composition of Claim 2 which is a compound which has this.   5. R is selected from the group consisting of alkyl groups having 1 to 24 carbon atoms, cycloalkyl groups having 1 to 24 carbon atoms, and aryl groups having 1 to 24 carbon atoms. A composition according to 1.   The composition of claim 1, wherein the polycarbodiimide compound is present at a concentration of about 0.1 wt% to about 8 wt%.   The composition of claim 2, wherein the polycarbodiimide compound is present in a concentration of about 0.25 wt% to about 5 wt%.   The compound selected from one or more of alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof is present at a concentration of about 0.01 wt% to about 8 wt%. The composition of claim 1.   The compound selected from one or more of alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof is present at a concentration of about 0.25 wt% to about 5 wt%. The composition according to claim 2.   The compound selected from one or more of alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof is trimethylsilylamodimethicone, quaternary ammonium silicone, A is a polysiloxane block And wherein B is a polyoxyalkylenated block containing at least one amine group (AB) is an aminosilicone compound selected from n-type multiblock polyoxyalkylenated aminosilicones, alkylaminosilicones and mixtures thereof. 2. The composition according to 2.   The compound selected from one or more of alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof is selected from aminosilicone compounds selected from amodimethicone and polyvinylamines The composition according to claim 2, which is one of amino compounds.   The durability imparted by the hydrophobicity imparted to the keratin substrate is characterized by a contact angle of greater than 70 ° to the substrate, a contact angle of 80 ° to about 120 ° after one or more wash cycles, The composition of claim 1, wherein the composition provides one or more of high humidity curl retention, improved bending force properties within a range of about 40% to about 90% after exposure.   The compound selected from one or more of alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof is present in a proportion equal to or greater than the polycarbodiimide compound; The composition of claim 1. Polycarbodiimide solvent selected from distilled or deionized water,
Of compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof selected from C1-C4 lower alcohols, glycols, polyols, polyol ethers, hydrocarbons, oils and mixtures thereof A solvent of one or more compounds,
Surfactants (anionic, nonionic, cationic, amphoteric / zwitterionic), polymers other than the polycarbodiimides of the present invention and alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and their Colorants and / or additives selected from amino compounds other than the compounds of the invention selected from one or more of the mixtures, such as anionic polymers, nonionic polymers, amphoteric polymers, polymer rheology modifiers, Thickeners and / or viscosity modifiers, associative or non-associative polymeric thickeners, non-polymeric thickeners, pearlescent agents, opacifiers, dyes or pigments, fragrances, mineral oils, vegetable oils or synthetic oils , Wax including ceramide, vitamins, UV screen, Comprising chromatography radical scavengers, antidandruff agents, hair loss agents, hair growth agents, preservatives, one such as pH stabilizers and solvents, and mixtures thereof or the ones,
Additives including one or more rheology modifiers and thickener / viscosity modifiers that are water soluble or water dispersible compounds include acrylic polymers, non-acrylic polymers, starches, saccharide based polymers (eg, guar , Guar gum), cellulosic polymers (particularly hydroxyethyl cellulose, cellulose gum, alkyl hydroxyethyl cellulose, carboxylic acid-containing cellulose / carbohydrate), non-polymeric gelling agents and polymeric gelling agents, silica particles, clay, hyaluronic acid, alginic acid As well as mixtures thereof,
The composition of claim 1. Keratin substrates selected from hair, eyelashes and eyebrows are heated, protected from extrinsic damage caused by UV irradiation, chemical treatment or mechanical stress, or keratin fibers selected from hair, eyelashes and eyebrows are heated, UV irradiation A method of repairing after exogenous damage caused by chemical treatment or mechanical stress,
Applying the composition of claim 1 to the keratin substrate in an amount effective to protect or repair the keratin fibers;
The polycarbodiimide compound is present at a concentration of about 0.01 to about 8.0 weight percent based on the total weight of the composition;
Optionally applying heat to the keratin substrate, wherein the heat is applied before, during or after applying the composition to the keratin substrate;
Method. Keratin substrates selected from hair, eyelashes and eyebrows are heated, protected from extrinsic damage caused by UV irradiation, chemical treatment or mechanical stress, or keratin substrates selected from hair, eyelashes and eyebrows are heated, UV irradiation A method of repairing after exogenous damage caused by chemical treatment or mechanical stress,
The polycarbodiimide of the composition of claim 1 and at least one compound selected from one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, respectively. Providing in the form of a premix comprising one solvent and applying the premix to the keratin substrate according to a process selected from a one-step process and a two-step process;
Method. A method for treating a keratin substrate, comprising:
Applying the composition of claim 1 to the keratin substrate in an amount effective to provide one or more of improved dyeability, improved color retention and extended color duration. ,
Method. The step
Preparing as a premix a composition comprising said polycarbodiimide and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, and said polycarbodiimide Prepared by combining one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof with at least one solvent, and mixed in advance Applying a composition to the keratin substrate, a one step process;
The composition in the form of a separate premix comprising each of the polycarbodiimide and one or more compounds selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof. The pre-mixture is formed on the aqueous phase by combining the polycarbodiimide and at least water, and is separately selected from alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof. Prepared by combining one or more compounds and at least one suitable solvent, and combining the premixes at the time of use to form an emulsion, A one-step process for applying to a keratin substrate, as well as preparing the composition in the form of a separate premix, the premix is formed on the aqueous phase by combining the polycarbodiimide and water and separately alkylating Prepared by combining one or more compounds selected from monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof with a suitable solvent, said pre-mixture when used 19. A method according to any one of claims 16, 17 or 18 wherein each is a step of at least one stage selected from a two-step process wherein each is separately applied to the keratin substrate in any order. The step
Applying heat to the keratin substrate, applying the heat before, during or after applying any one or more premixed compositions to the keratin substrate; and coloring, pigmentation, perm, Including in any order one or more additional process steps selected from treating the keratin substrate by any one or more processes selected from relaxation, straightening and highlighting;
Optionally, in any combination of two or more stages, one or more of the pre-mix compositions is a colorant (colorant), a pigmentation agent, a permanent treatment, a relaxation treatment, a hair straightening treatment. And for application together with any one of the highlight treatments,
The method of claim 19.   At least one premix comprising said polycarbodiimide and one or both of said compounds selected from one or more of alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof; 21. The method of claim 20, further comprising one of a colorant, a pigmentation agent, a permanent treatment, a relaxation treatment, a hair straightening treatment, and a highlight treatment. A kit comprising separately packaged forms, the kit comprising:
The polycarbodiimide is combined with the compound selected from one or more of alkyl monoamines, alkoxylated polyamines, alkoxylated monoamines, polyamines and silicone amines and mixtures thereof, and the premix is at least 1 2. The composition of claim 1 comprising one solvent, and selected from one or more of the polycarbodiimide and an alkyl monoamine, alkoxylated polyamine, alkoxylated monoamine, polyamine and silicone amine and mixtures thereof The compound is provided in a separately packaged form, and includes a packaged premix comprising polycarbodiimide and at least one solvent comprising water, comprising an alkyl monoamine, an alkoxylated polyamine, an alkoxy Also included is a packaged premix containing said compound selected from one or more of silylated monoamines, polyamines and silicone amines and mixtures thereof together with at least one suitable solvent, wherein the premixes are combined in use. A product comprising at least one of the compositions of claim 1 that is stirred to form an emulsion.