JP2012223569A - Multi-piece solid golf ball - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a multi-piece solid golf ball that includes a multilayer-structured core, achieves both of low spin and an initial speed of an actual hit especially at a high-HS area, and increases carry on a full-shot with a driver (W#1).SOLUTION: In the multi-piece solid golf ball, a cover having one or at least two layers covers a solid core, the solid core includes a first spherical layer, a second layer for covering the first layer, and a third layer for covering the second layer, a diameter of the first layer is 3 to 24 mm, and the third layer is formed from a rubber composition with polybutadiene rubber as a main member. In the multi-piece solid golf ball, specified is a relationship between cross-sectional hardness at the center of a core on a cross section when the solid core is cut in half, and each hardness of the first layer inside a boundary between the first layer and the second layer by 1 mm, the second layer outside the boundary by 1 mm, the second layer inside a boundary between the second layer and the third layer by 1 mm, the third layer outside the boundary by 1 mm, and a surface of the third layer. By the present invention, a decrease in spin and an initial speed of an actual shot are achieved at a high-head-speed area, thus increasing carry, and obtaining a satisfactory feel on impact.

Description

  The present invention relates to a solid core having a multilayer structure having a spherical first layer, a second layer covering the first layer, a third layer covering the second layer, and one or two layers covering the core More particularly, the present invention relates to a multi-piece solid golf ball having excellent flight performance and feel.

  Conventionally, in order to increase the flight distance and to improve the hit feeling, the ball structure has been devised to have a multilayer structure. After that, low spin, high initial speed, head speed (HS) Various multilayer golf balls having not only a cover but also a core structure of two or more layers have been proposed for the purpose of further improving dependency and feel.

  For example, US Pat. No. 6,290,612 (Patent Document 1), US Pat. No. 7086969 (Patent Document 2), US Pat. No. 7,160,208 (Patent Document 3), US Pat. No. 7,175,542 (Patent Document). Document 4) and US Pat. No. 7,367,901 (Patent Document 5) propose golf balls having a solid core having a two-layer structure and a cover. Also, US Pat. No. 7,510,487 (Patent Document 6), US Pat. No. 6,569,036 (Patent Document 7), US Pat. No. 6,626,770 (Patent Document 8), US Pat. No. 5,743,816 (Patent Document). Document 9) and US Pat. No. 7,708,656 (Patent Document 10) propose golf balls having a solid core having a three-layer structure. However, in either case, the initial speed at the time of hitting the driver (W # 1) may not be sufficient, or the hit feeling may not be good, and further improvement is desired.

US Pat. No. 6,290,612 US Patent No. 7086969 U.S. Pat. No. 7,160,208 U.S. Pat. No. 7,175,542 US Pat. No. 7,367,901 US Pat. No. 7,510,487 US Pat. No. 6,569,036 US Pat. No. 6,626,770 US Pat. No. 5,743,816 US Pat. No. 7,708,656

  The present invention has been made in view of the above circumstances, and has a multi-layered core. In particular, in the high HS region, the low spin rate and the initial hitting speed are compatible, and the flight at the time of a full shot with a driver (W # 1) is achieved. An object of the present invention is to provide a multi-piece solid golf ball capable of increasing the distance.

  In order to achieve the above-mentioned object, the present inventors have conducted intensive studies. As a result, the solid core is covered with a cover, and the solid core is covered with a spherical first layer, and the second layer covers the first layer. And a golf ball having a multi-layer structure having a third layer covering the second layer, the cross-sectional hardness of the second layer is set lower than that of the first layer and the third layer, and the hardness relationship of each layer of the core By optimizing the speed, it is possible to achieve both low spin and actual hitting speed, especially in the high head speed range, improve the flight performance during a driver (W # 1) shot, and obtain even better feel. As a result, the present invention has been made.

Accordingly, the present invention provides the following multi-piece solid golf ball.
[1] The solid core is covered with one or more covers, and the solid core has a spherical first layer, a second layer that covers the first layer, and a second layer that covers the second layer. In the multi-piece solid golf ball having three layers, the diameter of the first layer is 3 to 24 mm, the third layer is formed of a rubber composition mainly composed of polybutadiene rubber, and the solid core The cross-sectional hardness in the JIS-C hardness of the core center in the cross section when cut in half is (a),
(B) the cross-sectional hardness in JIS-C hardness of the first layer 1 mm inside from the boundary surface between the first layer and the second layer,
(C) the cross-sectional hardness in JIS-C hardness of the second layer 1 mm outside the boundary surface,
(D) the cross-sectional hardness in JIS-C hardness of the second layer 1 mm inside from the boundary surface between the second layer and the third layer,
The cross-sectional hardness in JIS-C hardness of the third layer 1 mm outside from the boundary surface is (e),
When the surface hardness in the JIS-C hardness of the third layer is (f),
The value of (b)-(c) is 0-40,
The value of (e)-(d) is 0-40,
A multi-piece solid golf ball having a value of (a) + (b) + (c) + (d) + (e) + (f) in a range of 380 to 460.
[2] The multi-piece solid golf ball according to [1], wherein the value of (f)-(a) is in the range of -10 to 20 in the solid core.
[3] The multi-piece solid golf ball according to [1] or [2], wherein the first layer is formed of a rubber composition mainly composed of polybutadiene rubber.
[4] The multi-piece solid golf ball according to any one of [1] to [3], wherein the solid core has a cross-sectional hardness (a) in a JIS-C hardness of 60 to 95.
[5] The multi-piece solid golf ball according to any one of [1] to [4], wherein the second layer is formed of a rubber composition mainly composed of polybutadiene rubber.
[6] The multi-piece solid golf ball according to any one of [1] to [5], wherein a sphere in which the second layer is coated on the first layer (second layer-coated sphere) has a diameter of 20 to 33 mm.
[7] The diameter ratio (first layer / second layer coated sphere) of the sphere (second layer coated sphere) in which the second layer is coated on the first layer and the first layer is 0.20 to 0.50 [ The multi-piece solid golf ball according to any one of 1] to [6].
[8] The multi-piece solid golf ball according to any one of [1] to [7], wherein the volume ratio of the second layer and the solid core (second layer / solid core) is 0.10 to 0.50.
[9] From a state in which an initial load of 98 N (10 kgf) is applied to a sphere in which the second layer is coated on the first layer (second layer-covered sphere), from when a final load of 1,275 N (130 kgf) is applied The ratio of the amount of deflection and the amount of deflection (the second layer covered sphere / solid core) from when the initial load 98N (10 kgf) is applied to when the final load 1,275N (130 kgf) is applied to the solid core. The multi-piece solid golf ball according to any one of [1] to [8], which is 1.50 to 1.80.
[10] The amount of deflection from when the initial load of 98 N (10 kgf) is applied to the solid core until the final load of 1,275 N (130 kgf) is applied, and the initial load of 98 N (10 kgf) is applied to the ball. Any one of [1] to [9], wherein a ratio of a deflection amount (solid core / ball) from when it is loaded to when a final load of 1,275 N (130 kgf) is loaded is 1.20 to 1.40. The described multi-piece solid golf ball.
[11] The amount of deflection from when the initial load 98N (10 kgf) is applied to the ball to when the final load 5,880 N (600 kgf) is applied, and from the state where the initial load 98N (10 kgf) is applied to the ball. The multi-piece solid golf ball according to any one of [1] to [10], wherein a ratio of deflection amount (600 kgf / 130 kgf) when loaded with 1,275 N (130 kgf) is 3.50 to 3.80. .

  According to the present invention, by optimizing the hardness relationship of each layer of the multilayer structure core, a golf ball that achieves both low spin and actual hitting speed at a high head speed region and can be expected to increase the flight distance is obtained. Can do. In addition, the golf ball of the present invention can provide a good feel at impact.

It is a top view showing the dimple pattern used with the ball of this example.

Hereinafter, the present invention will be described in more detail.
The multi-piece solid golf ball of the present invention, although not particularly shown, has a multilayer structure having a spherical first layer, a second layer covering the first layer, and a third layer covering the second layer. The core is covered with one or more layers.

  The first layer is the innermost layer in the golf ball of the present invention and is spherical. The material capable of forming the first layer is not particularly limited, but may be formed using a rubber composition containing polybutadiene as a base rubber or a resin composition containing a thermoplastic resin as a main material. it can.

First, the case where the said 1st layer is formed using a rubber composition is demonstrated.
In this invention, when forming the said 1st layer using a rubber composition, the rubber composition which uses polybutadiene as a base rubber can be employ | adopted suitably.

  Here, the polybutadiene is not particularly limited, but has a cis-1,4-bond of 60% or more, preferably 80% or more, more preferably 90% or more, and most preferably 95% or more. It is recommended that

The polybutadiene is not particularly limited, but its Mooney viscosity (ML _{1 + 4} (100 ° C.)) is 30 or more, preferably 35 or more, more preferably 40 or more, still more preferably 50 or more. Most preferably it is recommended to be 52 or more. The upper limit is not particularly limited, and is 100 or less, preferably 80 or less, more preferably 70 or less, and still more preferably 60 or less.

The Mooney viscosity referred to in the present invention is an industrial viscosity index (JIS K 6300) measured with a Mooney viscometer, which is a kind of rotational plasticity meter, and has ML _{1 + 4} as a unit symbol. (100 ° C.) is used. M represents Mooney viscosity, L represents a large rotor (L-type), 1 + 4 represents a preheating time of 1 minute, and a rotor rotation time of 4 minutes, and the measurement was performed at 100 ° C.

  Further, the molecular weight distribution Mw / Mn (Mw: weight average molecular weight, Mn: number average molecular weight) of the polybutadiene is not particularly limited, but is 2.0 or more, preferably 2.2 or more, more preferably 2 .4 or more, more preferably 2.6 or more. The upper limit is not particularly limited, but is 6.0 or less, preferably 5.0 or less, more preferably 4.0 or less, and still more preferably 3.4 or less. When Mw / Mn is too small, workability may be reduced, and when Mw / Mn is too large, resilience may be reduced.

  The polybutadiene can be synthesized using a Ni catalyst, a Co catalyst, a Group VIII metal catalyst, and a rare earth element-based catalyst. In the present invention, those synthesized using a Ni catalyst and a rare earth element-based catalyst are particularly suitable. Can be used. Moreover, it is also optional to use these catalysts in combination with organoaluminum compounds, alumoxanes, halogen-containing compounds, Lewis bases, and the like as necessary. In the present invention, as the various compounds exemplified above, those described in JP-A No. 11-35633 can be preferably used.

  Among the rare earth element-based catalysts, use of a neodymium-based catalyst using a neodymium compound which is a lanthanum series rare earth element compound is particularly recommended. In this case, a high content of cis-1,4-bonds and 1,2-vinyl bonds However, a low content polybutadiene rubber can be obtained with excellent polymerization activity.

  When butadiene is polymerized in the presence of a rare earth element-based catalyst, a solvent may be used, bulk polymerization or gas phase polymerization may be performed without using a solvent, and the polymerization temperature is usually −30 to 150 ° C., preferably It can be 10-100 degreeC.

  The polybutadiene may be obtained by reacting a terminal modifier with the active terminal of the polymer subsequent to the polymerization using the rare earth element-based catalyst.

  Specific examples of terminal modifiers and methods for reacting include those described in JP-A-11-35633, JP-A-7-268132, JP-A-2002-293996, and the like. it can.

  The polybutadiene is not particularly limited, but is 60% by mass or more in the base rubber, preferably 70% by mass or more, more preferably 80% by mass or more, most preferably 90% by mass or more, and the upper limit is 100% by mass. % Or less, preferably 98% by mass or less, more preferably 95% by mass or less is recommended. If the blending amount is insufficient, it may be difficult to obtain a golf ball with good resilience.

  In addition, rubbers other than the above polybutadiene can be used and blended together as long as the object of the present invention is not impaired. Specific examples include polybutadiene rubber (BR), styrene butadiene rubber (SBR), natural rubber, polyisoprene rubber, ethylene propylene diene rubber (EPDM), and the like. These can be used individually by 1 type or in combination of 2 or more types.

  The first layer is a rubber composition in which a predetermined amount of an additive such as an unsaturated carboxylic acid or a metal salt thereof, an organic sulfur compound, an inorganic filler, an organic peroxide, and an antioxidant is added to the base rubber. Is formed.

  Specific examples of the unsaturated carboxylic acid include acrylic acid, methacrylic acid, maleic acid, and fumaric acid, and acrylic acid and methacrylic acid can be particularly preferably used.

  Moreover, as a metal salt of unsaturated carboxylic acid, the zinc salt of unsaturated fatty acids, such as zinc methacrylate and zinc acrylate, a magnesium salt, etc. can be illustrated, and especially zinc acrylate can be used conveniently.

  The amount of the unsaturated carboxylic acid and / or metal salt thereof is not particularly limited, but is preferably 10 parts by mass or more, more preferably 15 parts by mass or more with respect to 100 parts by mass of the base rubber. be able to. On the other hand, the upper limit is not particularly limited, but is recommended to be 50 parts by mass or less. If the amount is too large, it becomes too hard, resulting in an unbearable feel, and if it is too small, the resilience may be lowered.

  An organic sulfur compound can be mix | blended as needed. This organic sulfur compound is preferably used for imparting excellent resilience. Specifically, it is recommended to blend thiophenols, thionaphthols, halogenated thiophenols or their metal salts, and more specifically, pentachlorothiophenol, pentafluorothiophenol, pentabromothio Examples include zinc salts such as phenol, parachlorothiophenol, pentachlorothiophenol, diphenyl polysulfide having 2 to 4 sulfur atoms, dibenzyl polysulfide, dibenzoyl polysulfide, dibenzothiazoyl polysulfide, dithiobenzoyl polysulfide, etc. A zinc salt of pentachlorothiophenol and diphenyl disulfide can be preferably used.

  The compounding amount of the organic sulfur compound can be more than 0, preferably 0.1 parts by mass or more, more preferably 0.2 parts by mass or more, still more preferably 0.00 parts by mass with respect to 100 parts by mass of the base rubber. It can be 4 parts by mass or more. The upper limit of the amount is not particularly limited, but is preferably 5 parts by mass or less, more preferably 4 parts by mass or less, still more preferably 3 parts by mass or less, and most preferably 2 parts by mass or less. If the amount is too large, the hardness becomes too soft, and if it is too small, improvement in resilience cannot be expected.

  Examples of the inorganic filler include zinc oxide, barium sulfate, and calcium carbonate. The blending amount is not particularly limited, but is preferably 5 parts by mass or more, more preferably 6 parts by mass or more, further preferably 7 parts by mass or more, and most preferably 8 parts by mass or more with respect to 100 parts by mass of the base rubber. It can be. Moreover, the upper limit of the amount is preferably 80 parts by mass or less, more preferably 60 parts by mass or less, still more preferably 40 parts by mass or less, and most preferably 20 parts by mass or less. If the amount is too large or too small, the weight may not be appropriate or a suitable resilience may not be obtained.

  As the organic peroxide, it is preferable to use an organic peroxide having a relatively short half-life in order to increase the hardness distribution. Specifically, an organic peroxide having a half-life at 155 ° C. of 5 seconds or more, more preferably 10 seconds or more, and further preferably 15 seconds or more is used. Further, those having a half-life at 155 ° C. of 120 seconds or less, more preferably 90 seconds or less, and still more preferably 60 seconds or less. Examples of organic peroxides that satisfy the above conditions include 1,1-bis (t-hexylperoxy) cyclohexane (trade name “Perhexa HC”), 1,1-bis (t-hexylperoxy) 3,3,5- Trimethylcyclohexane (trade name “PerhexaTMH”), 1,1-bis (t-butylperoxy) 3,3,5-trimethylcyclohexane (trade name “Perhexa 3M”), 1,1-bis (t-butylperoxy) ) Cyclohexane (trade name “Perhexa C”) and the like. These are all manufactured by NOF Corporation.

  The compounding amount of the organic peroxide is not particularly limited, but is preferably 0.3 parts by mass or more, more preferably 0.4 parts by mass or more, and further preferably 0.5 parts by mass with respect to 100 parts by mass of the base rubber. More than a part. The upper limit of the blending amount is not particularly limited, but preferably 4 parts by mass or less, more preferably 3 parts by mass or less, still more preferably 2 parts by mass or less, and most preferably 1.5 parts by mass or less. Is done. In the present invention, the blending amount is preferably set in the above range in order to obtain suitable resilience and durability. If the amount is too large, the resilience and durability may decrease. On the other hand, if the amount is too small, the time required for crosslinking will increase, resulting in a significant decrease in productivity and a significant decrease in compression. There is.

  An anti-aging agent can be blended with the rubber composition as necessary. As this anti-aging agent, for example, “NOCRACK NS-6”, “Same NS-30” (manufactured by Ouchi Shinsei Chemical Industry Co., Ltd.), “Yoshinox 425” (manufactured by Yoshitomi Pharmaceutical Co., Ltd.) and the like can be mentioned.

  The compounding amount of the anti-aging agent can be more than 0, preferably 0.03 parts by mass or more, and more preferably 0.05 parts by mass or more with respect to 100 parts by mass of the base rubber. The upper limit of the amount is not particularly limited, but is preferably 0.4 parts by mass or less, more preferably 0.3 parts by mass or less, and still more preferably 0.2 parts by mass or less. In the present invention, it is recommended that the blending amount of the anti-aging agent is in the above range from the viewpoint that suitable resilience and durability can be obtained.

  Moreover, sulfur can be mix | blended as needed. Specifically, a trade name “sulfur Z (Zet)” (manufactured by Tsurumi Chemical Co., Ltd.) and the like are exemplified. The compounding amount of sulfur can be more than 0, preferably 0.005 parts by mass or more, more preferably 0.01 parts by mass or more with respect to 100 parts by mass of the base rubber. The upper limit of the amount is not particularly limited, but is preferably 0.5 parts by mass or less, more preferably 0.4 parts by mass or less, and still more preferably 0.1 parts by mass or less. The addition of sulfur can increase the hardness distribution of the core. In addition, when there is too much compounding quantity of sulfur, in the case of heat molding, there exists a possibility of producing malfunctions, such as an explosion of a rubber composition, or a rebounding property falling large.

  When the first layer (thermoformed product) is formed using a rubber composition, the rubber composition described above is appropriately selected so that the cross-sectional hardness described later can be obtained, and is similar to a known golf ball rubber composition. It can be produced by vulcanization and curing by the method described above. As for the vulcanization conditions, for example, the vulcanization temperature can be 100 to 200 ° C. and the vulcanization time can be 10 to 40 minutes. In this case, from the viewpoint of obtaining a desired crosslinked rubber for core of the present invention, the vulcanization temperature is preferably 150 ° C or higher, particularly preferably 155 ° C or higher, and the upper limit is 200 ° C or lower, more preferably 190 ° C. or lower, more preferably 180 ° C. or lower, and most preferably 170 ° C. or lower.

  Next, when the first layer is formed using a thermoplastic resin, there is no particular limitation, but specifically, nylon, polyarylate, ionomer resin, polypropylene resin, polyurethane thermoplastic elastomer, polyester thermoplastic elastomer A thermoplastic resin such as can be used. Commercially available products can be used for these resins, such as “Surlin AD8512” (DuPont's ionomer resin), “High Milan 1706”, “Same 1707” (Mitsui / DuPont's ionomer resin), “Rilsan BMNO”. (Nylon resin manufactured by Arkema Co., Ltd.), “U polymer U-8000” (polyarylate resin manufactured by Unitika) and the like can be suitably used.

In the present invention, among the above thermoplastic resins, it is particularly preferable to use an ionomer resin, an unneutralized product thereof, or a highly neutralized ionomer resin. As the ionomer resin or its non-neutralized product, the following (AI) and (A-II)
(AI) olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ternary random copolymer and / or metal salt thereof, and (A-II) olefin-unsaturated carboxylic acid binary random copolymer and / or Or the resin composition which used the resin component of the metal salt as base resin can be employ | adopted suitably. Hereinafter, this resin composition will be described.

  The weight average molecular weight (Mw) of the olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ternary random copolymer and / or metal salt thereof as the component (AI) is preferably 100,000 or more, more preferably 110,000 or more, more preferably 120,000 or more. On the other hand, the upper limit is preferably 200,000 or less, more preferably 190,000 or less, and still more preferably 180,000 or less. The ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn) of the copolymer is preferably 3 or more, more preferably 4.5 or more, and the upper limit is preferably 7 or less, more preferably. Is 6.5 or less.

  Moreover, the weight average molecular weight (Mw) of the olefin-unsaturated carboxylic acid binary random copolymer and / or its metal salt as the component (A-II) is preferably 150,000 or more, more preferably 160,000 or more. More preferably, it is 170,000 or more. On the other hand, the upper limit is preferably 200,000 or less, more preferably 190,000 or less, and still more preferably 180,000 or less. The ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn) of the copolymer is preferably 3 or more, more preferably 4.5 or more, and the upper limit is preferably 7 or less. Preferably it is 6.5 or less.

  In this case, the weight average molecular weight (Mw) and the number average molecular weight (Mn) are calculated in terms of polystyrene in GPC (gel permeation chromatography). Regarding the GPC molecular weight measurement, the binary copolymer and the ternary copolymer cannot be subjected to GPC measurement as they are because the molecules are adsorbed to the GPC column by the unsaturated carboxylic acid group in the molecule. Usually, GPC measurement is performed after esterification of an unsaturated carboxylic acid group, and average molecular weights Mw and Mn in terms of polystyrene are calculated.

  Here, the olefin contained in the components (AI) and (A-II) preferably has, for example, 2 or more carbon atoms and an upper limit of 8 or less, particularly 6 or less. , Propylene, butene, pentene, hexene, heptene, octene and the like, and ethylene is particularly preferable.

  Moreover, as unsaturated carboxylic acid, acrylic acid, methacrylic acid, maleic acid, fumaric acid etc. can be mentioned, for example, It is especially preferable that they are acrylic acid and methacrylic acid.

  Furthermore, as the unsaturated carboxylic acid ester contained in the component (AI), the above-mentioned lower alkyl esters of unsaturated carboxylic acid and the like are suitable. Specifically, methyl methacrylate, ethyl methacrylate, methacrylic acid, etc. Examples thereof include propyl acid, butyl methacrylate, methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, and the like, and particularly butyl acrylate (n-butyl acrylate, i-butyl acrylate). preferable.

  The random copolymer of the (AI) component and the (A-II) component can be obtained by random copolymerizing the above components according to a known method. Here, the content (acid content) of the unsaturated carboxylic acid contained in the random copolymer is not particularly limited, but is preferably 2% by mass or more, more preferably 6% by mass or more, and still more preferably. It can be 8 mass% or more. Also, the upper limit is not particularly limited, but it is recommended that it is preferably 25% by mass or less, more preferably 20% by mass or less, and still more preferably 15% by mass or less. If the acid content is low, the resilience may be reduced, and if it is high, the processability of the material may be reduced.

  The mixing ratio of the component (A-I) and the component (A-II) is usually 100: 0 to 0: 100, preferably 100: 0 to 25:75, more preferably 100: 0 to 50 in terms of mass ratio. : 50, more preferably 100: 0 to 75:25, and most preferably 100: 0.

The metal salt of the copolymer of the components (A-I) and (A-II) is partly a metal ion of the acid group in the random copolymer of the components (A-I) and (A-II) described above. Can be obtained by neutralization with Here, specific examples of the metal ion that neutralizes the acid group include, for example, Na ⁺ , K ⁺ , Li ⁺ , Zn ⁺⁺ , Cu ⁺⁺ , Mg ⁺⁺ , Ca ⁺⁺ , Co ⁺⁺ , and Ni ^{+. +} , Pb ^{++ and the} like. In the present invention, among these, Na ⁺ , Li ⁺ , Zn ⁺⁺ , Mg ⁺⁺ , Ca ^{++ and the} like can be preferably used, and Zn ⁺⁺ and Mg ⁺⁺ are further recommended. .

  Moreover, when using the said metal neutralized product of the said copolymer as (AI) and (A-II) component, ie, when using ionomer resin, the kind and neutralization of the metal neutralized product are used. There is no particular limitation on the degree. As an example, specifically, an ethylene-acrylic acid copolymer of 60 mol% Zn (zinc neutralization degree), an ethylene-acrylic acid copolymer of 40 mol% Mg (magnesium neutralization degree), and 40 mol%. Examples thereof include an ethylene-methacrylic acid-isobutylene acrylate terpolymer of Mg (magnesium neutralization degree), an ethylene-methacrylic acid-isobutylene acrylate terpolymer of 60 mol% Zn (degree of zinc neutralization), and the like.

  Specific examples of the olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ternary random copolymer of the component (AI) include the trade names “Nucrel AN4318”, “Same AN4319”, “Same AN4311”, “Same N035C "and" N0200H "(Mitsui / DuPont Polychemical Co., Ltd.). Specific examples of the metal salt of the olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ternary random copolymer include trade names “Himilan AM7316”, “AM7331”, “1855”, “1856”. (Mitsui / DuPont Polychemical Co., Ltd.) and trade names “Surlin 6320”, “Same 8120” (DuPont, USA), and the like.

  Specific examples of the (A-II) component olefin-unsaturated carboxylic acid binary random copolymer include trade names “Nucrel 1560”, “Same 1525”, “Same 1035” (Mitsui / DuPont Polychemicals). Manufactured) and the like. Specific examples of the metal salt of the olefin-unsaturated carboxylic acid binary random copolymer include trade names “Himilan 1605”, “Same 1601”, “Same 1557”, “Same 1705”, “Same 1706” (Mitsui -DuPont Polychemical Co., Ltd.) and trade names "Surlin 7930", "Same 7920" (DuPont, USA), as well as trade names "Escor 5100", "Escol 5200" (ExxonMobil Chemical) .

  Furthermore, in order to obtain good resilience, (B) a fatty acid having a molecular weight of 280 or more and 1500 or less, or a derivative thereof, and (C) a basic inorganic metal compound, which will be described later, on the components (AI) and (A-II). A highly neutralized ionomer resin whose degree of neutralization has been improved by heating and mixing can be used.

  Component (B) is a fatty acid having a molecular weight of 280 to 1500, or a derivative thereof, which contributes to improving the fluidity of the heated mixture, and has a very small molecular weight compared to the thermoplastic resin of component (A) above. It contributes to a significant decrease in the melt viscosity of the mixture. In addition, the fatty acid (derivative) in the component (B) has a molecular weight of 280 to 1500 and contains a high content of acid groups (derivatives), so that there is little loss of resilience due to addition.

  Even if the fatty acid of component (B) or a derivative thereof is an unsaturated fatty acid (derivative) containing a double bond or a triple bond in the alkyl group, a saturated fatty acid in which the bond in the alkyl group is composed of only a single bond ( It is recommended that the number of carbon atoms in one molecule is usually 18 or more and 80 or less, particularly 40 or less as the upper limit. If the number of carbon atoms is small, the heat resistance is poor, the content of acid groups is too high, and the desired fluidity cannot be obtained due to the interaction with the acid groups contained in the base resin. Therefore, the fluidity may be lowered and the material may be difficult to use.

  Specific examples of the fatty acid (B) include stearic acid, 12-hydroxystearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid, lignoceric acid and the like, and in particular, stearic acid and arachidinic acid. Acid, behenic acid, lignoceric acid and oleic acid can be preferably used.

Examples of the fatty acid derivative include those obtained by substituting protons contained in the acid group of the fatty acid. Examples of such fatty acid derivatives include metal soaps substituted with metal ions. Examples of metal ions used for the metal soap include Li ⁺ , Ca ⁺⁺ , Mg ⁺⁺ , Zn ⁺⁺ , Mn ⁺⁺ , Al ⁺⁺⁺ , Ni ⁺⁺ , Fe ⁺⁺ , Fe ⁺⁺⁺ , and Cu. ⁺⁺ , Sn ⁺⁺ , Pb ⁺⁺ , Co ^++, etc. are mentioned, and Ca ⁺⁺ , Mg ⁺⁺ , Zn ⁺⁺ are particularly preferable.

  Specific examples of the fatty acid derivative of the component (B) include magnesium stearate, calcium stearate, zinc stearate, 12-hydroxy magnesium stearate, 12-hydroxy calcium stearate, zinc 12-hydroxy stearate, magnesium arachidate, and arachidin. Calcium acid, Zinc arachidate, Magnesium behenate, Calcium behenate, Zinc behenate, Magnesium lignocerate, Calcium lignocerate, Zinc lignocerate, etc. Especially magnesium stearate, calcium stearate, zinc stearate, magnesium arachidate , Calcium arachidate, zinc arachidate, magnesium behenate, calcium behenate, zinc behenate, magnesium lignocerate Um, calcium lignoceric acid, can be preferably used zinc lignocerate.

  (B) The compounding quantity of a component is 30 mass parts or more with respect to 100 mass parts of said base resins, Preferably it is 45 mass parts or more, More preferably, it is 60 mass parts or more, More preferably, it is 80 mass parts or more. Moreover, the upper limit of the amount is 170 parts by mass or less, preferably 150 parts by mass or less, more preferably 130 parts by mass or less, and still more preferably 110 parts by mass or less.

  In addition, when using the component (A) described above, a known metal soap-modified ionomer resin (US Pat. No. 5,312,857, US Pat. No. 5,306,760, WO 98/46671, etc.) should be used. You can also.

  The basic inorganic metal compound (C) is blended to neutralize the acid groups in the components (A) and (B). As mentioned in the conventional example, when only the components (A) and (B), particularly only the metal-modified ionomer resin (for example, only the metal soap-modified ionomer resin described in the above-mentioned patent publication) are mixed by heating, as shown below. In addition, a fatty acid is generated by an exchange reaction between the metal soap and the unneutralized acid group contained in the ionomer resin. This generated fatty acid has low thermal stability and is easily vaporized at the time of molding, so it not only causes molding defects, but when the generated fatty acid adheres to the surface of the molded product, the adhesion of the coating is significantly reduced. Cause.

  In order to solve such a problem, as the component (C), a basic inorganic metal compound that neutralizes the acid group contained in the components (A) and (B) is blended as an essential component. (C) The blending of the components neutralizes the acid groups in the above components (A) and (B), and the synergistic effect of blending these components increases the thermal stability of the resin composition and at the same time provides good molding. And the excellent properties of improving the resilience of the golf ball material.

  The component (C) is a basic inorganic metal compound capable of neutralizing the acid groups in the components (A) and (B), but is preferably a monoxide or hydroxide. The Since these compounds are highly reactive with ionomer resins and do not contain organic substances in the reaction by-products, the degree of neutralization of the resin composition can be increased without impairing thermal stability.

Here, examples of the metal ions used for the basic inorganic metal compound include Li ⁺ , Na ⁺ , K ⁺ , Ca ⁺⁺ , Mg ⁺⁺ , Zn ⁺⁺ , Al ⁺⁺⁺ , Ni ⁺ , and Fe ^++. , Fe ⁺⁺⁺ , Cu ⁺⁺ , Mn ⁺⁺ , Sn ⁺⁺ , Pb ⁺⁺ , Co ^{++ and the} like. Examples of inorganic metal compounds include basic inorganic fillers containing these metal ions, specifically Examples thereof include magnesium oxide, magnesium hydroxide, magnesium carbonate, zinc oxide, sodium hydroxide, sodium carbonate, calcium oxide, calcium hydroxide, lithium hydroxide, lithium carbonate and the like. Among these, as described above, monoxide or hydroxide is preferable, and magnesium oxide or calcium hydroxide having high reactivity with the ionomer resin can be preferably used.

  The blending amount of the component (C) can be appropriately selected in order to obtain a desired degree of neutralization, and is not particularly limited, but with respect to the acid groups in the components (A) and (B). Thus, it can be preferably 30 mol% or more, more preferably 45 mol% or more, still more preferably 60 mol% or more, and most preferably 70 mol% or more. The upper limit is preferably 130 mol% or less, more preferably 110 mol% or less, still more preferably 100 mol% or less, and most preferably 90 mol% or less. Moreover, if said compounding quantity is expressed on a mass basis, it is preferable that it is 0.1-10 mass parts with respect to 100 mass parts of said base resins. In this case, a more preferable lower limit is 0.5 parts by mass or more, further preferably 0.8 parts by mass or more, and most preferably 1 part by mass or more. On the other hand, a more preferable upper limit is 8 parts by mass or less, further preferably 5 parts by mass or less, and most preferably 4 parts by mass or less.

  The melt flow rate (JIS K 6760 (measured at a test temperature of 190 ° C. and a test load of 21 N (2.16 kgf))) of the resin composition is preferably 1 g / 10 min or more, more preferably 2 g / 10 min or more, still more preferably. Is 3 g / 10 min or more. The upper limit is preferably 30 g / 10 min or less, more preferably 20 g / 10 min or less, still more preferably 15 g / 10 min or less, and most preferably 10 g / 10 min or less. If the melt flow rate of this resin composition is low, the processability is significantly reduced.

  Although there is no restriction | limiting in particular as a manufacturing method of said resin composition, The ionomer resin or unneutralized polymer of (AI) and (A-II) component, (B) component, and (C) component are included. It is possible to adopt a method in which they are put together into a hopper and extruded under desired conditions. Moreover, about (B) component, you may throw in from another feeder. In this case, the neutralization reaction to the carboxylic acid in the components (A-I), (A-II) and (B) by the metal cation source which is the component (C) can be performed by various extruders. . In this case, as the extruder, either a single screw extruder or a twin screw extruder can be used, but a twin screw extruder having a large kneading effect can be used more suitably. Moreover, the connection type | mold of these extruders may be sufficient, for example, connection types, such as a single screw extruder-2 screw extruder, a 2 screw extruder-2 screw extruder, are mentioned. The configuration of these apparatuses is not special, and an existing extruder is sufficient.

  In addition, the method for forming the first layer using a thermoplastic resin is not particularly limited, and a known method such as molding or injection molding can be adopted, and it is particularly preferable to manufacture by injection molding. . In this case, a method of injecting the above-described thermoplastic resin material into the cavity of the core forming mold can be suitably employed.

  The diameter of the first layer is set to 3 to 24 mm. In this case, the preferable lower limit of the diameter is 5 mm or more, more preferably 7 mm or more. On the other hand, the preferable upper limit of the diameter is 20 mm or less, more preferably 15 mm or less, and still more preferably 12 mm or less. If the above diameter deviates from the above range, there may be a case where a sufficient initial speed cannot be obtained at the time of W # 1 hit or the spin amount becomes too large to increase the flight distance.

  The second layer is a layer covering the first layer, and is a layer located in the middle of the three layers constituting the solid core. The second layer is not particularly limited, but can be formed using a material similar to the material used for forming the first layer. That is, a rubber composition or a thermoplastic resin using the above polybutadiene as a base rubber can be preferably used.

  The method for forming the second layer using the rubber composition may employ a known method, and is not particularly limited, but the following method can be suitably employed. First, the material for forming the second layer is put into a predetermined mold, and primary vulcanization (semi-vulcanization) is performed to produce a pair of hemispherical half cups. Next, secondary vulcanization (total vulcanization) is performed in a state where the spherical first layer produced in advance is wrapped in the half cup produced above. That is, a method in which the vulcanization process is divided into two stages can be suitably employed. Further, a method of injecting and molding a second layer forming material around the first layer can also be suitably employed.

  In addition, when the first layer is formed of a thermoplastic resin, the interface between the first layer and the second layer is firmly bonded by previously applying an adhesive to the surface of the first layer. be able to. By firmly bonding the two together with an adhesive, the durability of the golf ball can be further improved and high resilience can be obtained. Further, the surface of the first layer is subjected to pretreatment such as polishing treatment with a barrel grinder, plasma treatment, corona discharge, or chemical treatment to form fine irregularities on the surface, whereby the first layer And the second layer can be further improved in adhesion.

  The method for forming the second layer using a thermoplastic resin is not particularly limited, but a known method can be adopted. For example, the second layer forming material is formed around the sphere of the first layer. A pair of hemispherical half cups are prepared in advance using a second layer forming material, and the first layer is wrapped with these half cups and heated at 140 to 180 ° C. for 2 to 10 minutes. A method of pressure heating molding or the like can be employed.

  The diameter of the sphere obtained by coating the first layer with the second layer (second layer-coated sphere) is not particularly limited, but may be 18 to 35 mm. In this case, the preferable lower limit of the diameter is 20 mm or more, more preferably 22 mm or more. On the other hand, a preferable upper limit is 32 mm or less, and more preferably 30 mm or less.

  The third layer is a layer covering the second layer, and is the outermost layer among the three layers constituting the solid core. In the present invention, this third layer needs to be formed of a rubber composition mainly composed of polybutadiene, and in particular, the same as the rubber composition that can be suitably used for forming the first layer. A rubber composition can be used.

  The method for forming the third layer is not particularly limited, but a method similar to the method for forming the second layer can be suitably employed. That is, the third layer forming material is put into a predetermined mold, and primary vulcanization (semi-vulcanization) is performed to produce a pair of hemispherical bowl-shaped half cups. A method of performing secondary vulcanization (total vulcanization) in a state of being wrapped in a half cup produced in step 1 above, or a method of injecting and molding a third layer forming material around the second layer can be suitably employed.

  In addition, when the second layer is formed of a thermoplastic resin, an adhesive is previously applied to the surface of the second layer to firmly bond the interface between the second layer and the third layer. be able to. By firmly bonding the two together with an adhesive, the durability of the golf ball can be further improved and high resilience can be obtained. Further, the surface of the second layer is subjected to polishing treatment with a barrel grinder or the like, plasma treatment, corona discharge, or chemical treatment to form fine irregularities on the surface, whereby the second layer and the second layer are formed. The adhesion with the three layers can be further enhanced.

  The diameter of the solid core in which the first to third layers are laminated as described above is not particularly limited, but is preferably 33 to 41 mm. A more preferable lower limit of the diameter is 35 mm or more, and more preferably 37 mm or more. Moreover, a more preferable upper limit is 40 mm or less, More preferably, it is 39 mm or less.

In the solid core having the first to third layers, the present invention is optimized by setting the cross-sectional hardness of the second layer to be lower than that of the first and third layers. More specifically, the cross-sectional hardness in the JIS-C hardness at the core center in the cross section when the solid core is cut in half is (a),
(B) the cross-sectional hardness in JIS-C hardness of the first layer 1 mm inside from the boundary surface between the first layer and the second layer,
(C) the cross-sectional hardness in JIS-C hardness of the second layer 1 mm outside the boundary surface,
The cross-sectional hardness in JIS-C hardness of the first layer 1 mm inside from the boundary surface between the second layer and the third layer is (d),
The cross-sectional hardness in JIS-C hardness of the third layer 1 mm outside from the boundary surface is (e),
When the surface hardness in the JIS-C hardness of the third layer is (f),
The value of (b)-(c) is 0-40,
The value of (e)-(d) is 0-40,
The value of (a) + (b) + (c) + (d) + (e) + (f) needs to be in the range of 380 to 460.
Hereinafter, the hardness (a) to (f) of each part of the solid core cross section will be described in detail.

  The cross-sectional hardness (a) at the core center is not particularly limited, but may be 60 or more, preferably 65 or more, more preferably 70 or more in JIS-C hardness. Further, the upper limit is not particularly limited, but it can be 95 or less, preferably 90 or less, more preferably 85 or less in JIS-C hardness. If the cross-sectional hardness (a) is too small, a sufficient initial speed may not be obtained at the time of W # 1 strike. On the other hand, if it is too large, the spin rate may be too high at the time of W # 1 strike.

  The cross-sectional hardness (b) of the first layer 1 mm inside 1 mm from the boundary surface between the first layer and the second layer is not particularly limited, but the JIS-C hardness is 65 or more, preferably 70 or more, more preferably. Can be 75 or more. The upper limit is not particularly limited, but it can be 95 or less, preferably 92 or less, more preferably 90 or less in JIS-C hardness.

  The cross-sectional hardness (c) of the second layer 1 mm outside the boundary surface is not particularly limited, but it can be JIS-C hardness of 35 or more, preferably 40 or more, more preferably 45 or more. . The upper limit is not particularly limited, but it can be JIS-C hardness of 70 or less, preferably 65 or less, more preferably 60 or less.

  The cross-sectional hardness (d) of the second layer 1 mm inside from the boundary surface between the second layer and the third layer is not particularly limited, but is 50 or more, preferably 55 or more, in terms of JIS-C hardness. Can be 60 or more. The upper limit is not particularly limited, but it can be JIS-C hardness of 75 or less, preferably 70 or less, more preferably 65 or less.

  The cross-sectional hardness (e) of the third layer 1 mm outside the boundary surface is not particularly limited, but can be 60 or more, preferably 65 or more, more preferably 70 or more in terms of JIS-C hardness. . Also, the upper limit is not particularly limited, but it can be JIS-C hardness of 90 or less, preferably 85 or less, more preferably 80 or less.

  The surface hardness (f) of the third layer is not particularly limited, but can be 70 or more, preferably 75 or more, more preferably 80 or more in terms of JIS-C hardness. The upper limit is not particularly limited, but it can be 95 or less, preferably 90 or less in JIS-C hardness.

  The value of (b)-(c) needs to be 0-40 as described above. In this case, a preferable lower limit is 5 or more, more preferably 10 or more. Moreover, the preferable upper limit of the value is 30 or less, More preferably, it is 25 or less. If the value of (b)-(c) is too large, the crack durability may not be sufficient, and if it is too small, a sufficient initial speed may not be obtained when W # 1 is hit.

  The value of (e)-(d) needs to be 0-40 as above-mentioned. In this case, a preferable lower limit is 5 or more, more preferably 10 or more. Moreover, the preferable upper limit of the value is 30 or less, More preferably, it is 25 or less. If the value of (e)-(d) is too large, the crack durability may not be sufficient, and if it is too small, a sufficient initial speed may not be obtained when W # 1 is hit.

  The value of (f)-(a) is not particularly limited, but is preferably -10-20. In this case, a more preferable lower limit value is −5 or more, and further preferably 0 or more. Moreover, the more preferable upper limit of the value is 15 or less, More preferably, it is 12 or less. If the value of (f)-(a) is too large, the crack durability may not be sufficient.

  The value of (a) + (b) + (c) + (d) + (e) + (f) needs to be in the range of 380 to 460 as described above. In this case, a more preferable lower limit value is 390 or more, and further preferably 400 or more. Moreover, the more preferable upper limit of the value is 450 or less, More preferably, it is 440 or less. If the value of (a) + (b) + (c) + (d) + (e) + (f) is too large, the hit feeling may become too hard. Sufficient initial speed may not be obtained.

  As described above, by optimizing the cross-sectional hardness (a) to (f) of each part of the solid core cross-section, the resilience at the time of actual hitting is very high and a good hitting feeling can be obtained.

  The diameter ratio between the first layer and the second layer-coated sphere (first layer / second layer-coated sphere) is not particularly limited, but is preferably 0.20 to 0.50. In this case, a more preferable lower limit value of the diameter ratio is 0.25 or more. Further, the upper limit value of the diameter ratio is more preferably 0.40 or less, and still more preferably 0.30 or less. If the value of the diameter ratio is too large, the spin amount may be excessive when hitting W # 1, and if it is too small, a sufficient initial speed may not be obtained when hitting W # 1.

  The ratio of the volume of the second layer (the volume of only the second layer not including the first layer) and the volume of the solid core (second layer / solid core) is not particularly limited, but is 0.10. It is preferable to set it to -0.50. In this case, the more preferable lower limit of the volume ratio is 0.15 or more, and further preferably 0.20. Further, the upper limit value of the volume ratio is more preferably 0.40 or less, further preferably 0.30 or less, and most preferably 0.24 or less. If the volume ratio is too large, a sufficient initial speed may not be obtained when W # 1 is hit. If it is too small, the spin amount may be too high when W # 1 is hit.

  The multi-piece solid golf ball of the present invention is formed by covering the solid core with a cover of one layer or two layers or more. In the present invention, although there is no particular limitation, a known cover material can be used as a material for forming the cover. Specific examples include known thermoplastic resins, ionomer resins, highly neutralized ionomer resin compositions as described above, thermoplastic and thermosetting polyurethanes, and thermoplastic elastomers such as polyamides and polyesters. be able to. Further, normal injection molding can be suitably employed for forming the cover.

  In the present invention, among the above-described cover materials, it is preferable to employ an ionomer resin, a highly neutralized ionomer resin composition, a thermoplastic polyurethane, a polyester-based thermoplastic elastomer, or the like. Further, when the cover has a single layer, the thickness is not particularly limited, but the thickness is preferably 0.5 to 2.0 mm, and the material hardness of the cover is 30 to 65 in Shore D hardness. It is preferable to set. The material hardness of the cover means the hardness when the cover material is formed into a sheet having a predetermined thickness.

  When the cover has two or more layers, the thickness of the inner layer cover is not particularly limited, but is preferably 0.5 mm or more, more preferably 0.7 mm or more, still more preferably 0.9 mm or more, most preferably Preferably it can be 1.1 mm or more. The upper limit is not particularly limited, but it is preferably 3 mm or less, more preferably 2.7 mm or less, still more preferably 2.5 mm or less, and most preferably 2.3 mm or less. On the other hand, the material hardness of the inner layer cover is not particularly limited, but is preferably 51 or more in Shore D hardness, more preferably 53 or more, still more preferably 55 or more, and most preferably 57 or more. Can do. Moreover, the upper limit is not particularly limited, but is preferably 70 or less, more preferably 67 or less, and even more preferably 64 or less.

  The thickness of the outer layer cover is not particularly limited, but is preferably 0.3 mm or more, more preferably 0.5 mm or more, and even more preferably 0.7 mm or more. The upper limit is not particularly limited, but it is preferably 2 mm or less, more preferably 1.7 mm or less, still more preferably 1.4 mm or less, and most preferably 1.2 mm or less. On the other hand, the material hardness of the outer layer cover is not particularly limited, but the Shore D hardness is preferably 30 or more, more preferably 35 or more, still more preferably 40 or more, and most preferably 42 or more. The upper limit is not particularly limited, but is preferably 57 or less, more preferably 56 or less, and even more preferably 55 or less.

  By forming the cover as described above, in addition to the effect of increasing the flight distance, the spin performance in the approach is also improved, and both controllability and flight distance can be achieved.

  The diameter of the golf ball on which the core and cover described above are formed is preferably 42.67 mm or more so as to correspond to the standard of the golf ball. The upper limit value is not particularly limited, but is preferably 44 mm or less, more preferably 43.8 mm or less, still more preferably 43.5 mm or less, and most preferably 43 mm or less. .

  Further, in the range of the diameter of the golf ball, the amount of deformation (also called product hardness) when the entire ball is loaded from the initial load 98N (10 kgf) to the final load 1275N (130 kgf) is particularly limited. However, it is preferably 2.0 mm or more, more preferably 2.2 mm or more, and still more preferably 2.4 mm or more. The upper limit is not particularly limited, but is preferably 5.0 mm or less, more preferably 4.5 mm or less, still more preferably 4.0 mm or less, and most preferably 3.5 mm or less. If the amount of deformation is too large, a sufficient initial speed may not be obtained when the W # 1 is hit. If it is too small, the spin amount may be too high when the W # 1 is hit.

  Further, the amount of deformation when the entire ball is loaded from an initial load of 98 N (10 kgf) to a final load of 5880 N (600 kgf) is not particularly limited, but is preferably 7.2 mm or more, more preferably 7.6 mm or more. More preferably, it is 8 mm or more. Moreover, the upper limit in particular is not restrict | limited, However, Preferably it is 14 mm or less, More preferably, it is 12 mm or less, More preferably, it is 10 mm or less. If the amount of deformation is too large, a sufficient initial speed may not be obtained when the W # 1 is hit. If it is too small, the spin amount may be too high when the W # 1 is hit.

  Although not particularly limited, the amount of deformation when the initial load 98N (10 kgf) to the final load 1275N (130 kgf) of the second layer coated sphere and the initial load 98N (10 kgf) of the solid core are applied. To a final load of 1275 N (130 kgf), the ratio of the deformation (second layer coated sphere / solid core) is preferably 1.50 to 1.80. In this case, the more preferable lower limit value of the deformation amount ratio is 1.55 or more, and more preferably 1.60 or more. Further, a more preferable upper limit value of the deformation amount ratio is 1.75 or less. If the value of the deformation amount ratio is too large, the spin amount may be excessive when hitting W # 1, and if it is too small, a sufficient initial speed may not be obtained when hitting W # 1.

  Further, although not particularly limited, the amount of deformation when the solid core is loaded from the initial load 98N (10 kgf) to the final load 1275N (130 kgf), and the initial load 98N (10 kgf) of the entire ball is finished. It is preferable that the ratio (solid core / ball) to the deformation amount when loading up to a load of 1275N (130 kgf) is 1.20 to 1.40. In this case, the more preferable lower limit value of the deformation amount ratio is 1.23 or more, and further preferably 1.26 or more. Further, a more preferable upper limit value of the deformation amount ratio is 1.37 or less, and further preferably 1.34 or less. If the value of the deformation amount ratio is too large, the hit feeling may be too hard, and if it is too small, the spin amount may be too large when W # 1 is hit.

  Further, although not particularly limited, the deformation amount when the entire ball is loaded from the initial load 98N (10 kgf) to the final load 5880N (600 kgf), and the above-mentioned whole ball initial load 98N (10 kgf) to the final load. It is preferable that the ratio (600 kgf / 130 kgf) to the deformation amount when loading up to 1275 N (130 kgf) is 3.50 to 3.80. In this case, a more preferable lower limit value of the deformation amount ratio is 3.55 or more, and further preferably 3.60 or more. Further, the more preferable upper limit value of the deformation amount ratio is 3.75 or less, and further preferably 3.70 or less. If the value of the deformation amount ratio is too large, a sufficient initial speed may not be obtained when the W # 1 is hit. If it is too small, the spin amount may be too high when the W # 1 is hit.

  In the golf ball of the present invention, in order to further increase the aerodynamic characteristics and increase the flight distance, a large number of dimples can be formed on the surface of the cover in the same manner as a normal golf ball. In this case, the number of dimples formed on the ball surface is not particularly limited, but is preferably 280 or more, more preferably 300 or more, and further preferably 320 or more. The upper limit is not particularly limited, but it is preferably 400 or less, more preferably 380 or less, and still more preferably 350 or less. If the number of dimples exceeds the above range, the trajectory of the ball may be lowered and the flight distance may not be achieved. On the other hand, when the number of dimples is less than the above range, the trajectory becomes high and the flight distance may not be extended.

  On the other hand, as the geometric arrangement of dimples, octahedrons, icosahedrons, etc. can be adopted. Furthermore, the shape of the dimples is not only circular but also various polygons such as square type, hexagon type, pentagon type, triangle type, etc. One type or two or more types can be appropriately used from drop shapes, elliptical shapes, and the like. The diameter (diagonal length in a polygon) is not particularly limited, but is preferably 2.5 to 6.5 mm. Further, the depth is not particularly limited, but is preferably 0.08 to 0.30 mm.

Further, a value V _{0 obtained} by dividing the space volume of the dimple below the plane surrounded by the edge of the dimple by the cylindrical volume having the plane as the bottom surface and the maximum depth of the dimple from the bottom surface as a height is particularly limited. However, in the present invention, it can be set to 0.35 to 0.80.

  The ratio SR of the total surface area of the phantom sphere assuming that the dimple area defined by the plane surrounded by the edge of the dimple does not exist on the ball surface is not particularly limited. From the viewpoint of reduction, it is preferably 60 to 90%. In addition to increasing the number of dimples to be formed, the SR is increased by mixing a plurality of types of dimples having different diameters or by forming a shape in which the distance between adjacent dimples (bank width) is substantially zero. be able to.

  The ratio VR of the total volume of the dimple space formed downward from the plane surrounded by the edge of the dimple to the volume of the phantom sphere assuming that no dimple exists on the ball surface is not particularly limited. In this invention, it can be set as 0.6-1.

In the present invention, by setting the above V ₀ , SR, and VR within the above ranges, air resistance can be reduced, and a trajectory with a good flight distance can be easily obtained, and the flight performance can be improved.

  In the present invention, in order to improve the design and durability of the golf ball, it is optional to perform various treatments such as ground treatment, stamping and painting on the cover surface.

  EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not restrict | limited to the following Example.

[Examples 1-8, Comparative Examples 1-10]
After preparing the rubber composition shown in Table 1 below, a spherical molded product of the first layer was produced by vulcanization molding at 155 ° C. for 15 minutes. However, Example 2 is No. in Table 3. Using the resin material shown in No. 1, a spherical molded product was obtained by injection molding.
For the second layer, first, the rubber composition shown in Table 2 was kneaded using a kneading roll and subjected to primary vulcanization (semi-vulcanization) at 130 ° C. for 6 minutes to produce a pair of hemispherical bowl-shaped half cups. did. Next, the first layer is wrapped with the obtained half cup, and second vulcanization (total vulcanization) is performed in a mold at 155 ° C. for 15 minutes to form a second layer. Coated spheres were produced.
The third layer was also formed by the same method as the second layer. More specifically, first, the rubber composition shown in Table 2 is kneaded using a kneading roll, and primary vulcanization (semi-vulcanization) is performed at 130 ° C. for 6 minutes to form a pair of hemispherical bowl-shaped half cups. Produced. Next, the above-mentioned second layer coated sphere is wrapped with the obtained half cup, and the whole is subjected to secondary vulcanization (total vulcanization) at 155 ° C. for 15 minutes in a mold to form a third layer. A solid core having a three-layer structure was produced. In Comparative Example 10, No. 1 in Table 3 was used. The third layer was formed by injecting the resin material shown in 2 around the second layer.

  Next, for each solid core, a resin material (cover material) having the composition shown in Table 3 is injection-molded to form an inner layer cover (intermediate layer) and an outer layer cover having the same shape, arrangement, and number of dimples on the surface. And a multi-piece solid golf ball having a three-layer solid core covered with a two-layer cover. At this time, the dimples shown in FIG. 1 were formed on the cover surface. Details of the dimples are shown in Table 4.

Details of the materials described in Tables 1 and 2 are as follows.
Polybutadiene rubber: “BR730” manufactured by JSR, polybutadiene rubber obtained using an Nd-based catalyst, cis-1,4-bond content of 96 mass%, Mooney viscosity “55”, molecular weight distribution “3”
Zinc acrylate: Nippon Distillation Co., Ltd. Peroxide: NOF Corporation “Perhexa C-40”, 1,1-bis (t-butylperoxy) cyclohexane diluted to 40% with inorganic filler, 155 ° C. halved The period is about 50 sec
Zinc oxide: Barium sulfate manufactured by Sakai Chemical Industry Co., Ltd .: “Precipitated barium sulfate 100” manufactured by Sakai Chemical Industry Co., Ltd.
Anti-aging agent: “NOCRAK NS-6” manufactured by Ouchi Shinsei Chemical Industry Co., Ltd.

Details of the materials listed in Table 3 are as follows.
Surlyn: Ionomer resin Nucrel N035C manufactured by Dupont Co., Ltd .: Ethylene-methacrylic acid-ester terpolymer made by Mitsui DuPont Polychemical Himiran: Ionomer resin Dynalon 6100P manufactured by Mitsui DuPont Polychemical Co., Ltd. Hydrogenated polymer pandex manufactured by JSR : DIC Bayer Polymer MDI-PTMG type thermoplastic polyurethane magnesium stearate: NOF "Magnesium stearate G"
Magnesium oxide: “Kyowa Mag MF150” manufactured by Kyowa Chemical Industry Co., Ltd.
Behenic acid: “NAA-222S” manufactured by NOF Corporation
Calcium hydroxide: “CLS-B” manufactured by Shiraishi Calcium
Polyisocyanate compound: 4,4′-diphenylmethane diisocyanate Hytrel: Thermoplastic polyester elastomer titanium oxide manufactured by Toray DuPont, Ltd. “Typaque R550” manufactured by Ishihara Sangyo Co., Ltd.
Polyethylene wax: Sanyo Chemical Co., Ltd. “Sun Wax 161P”

Dimples Definition <br/> diameter: diameter depth flat plane circumscribed by an edge of the dimple: maximum depth of the dimple from the plane surrounded by the edge of the dimple V _0: under flat plane circumscribed by an edge of the dimple A value obtained by dividing the spatial volume of the dimple by a cylindrical volume having the above-mentioned plane as the bottom surface and the maximum depth of the dimple from the bottom surface as a height SR: Total sum of dimple areas defined by the plane surrounded by the edge of the dimple However, the ratio of the surface area of the phantom sphere assuming that no dimples exist on the ball surface VR: If the total dimple space volume formed below the plane surrounded by the edges of the dimples is not present on the ball surface Percentage of hypothetical sphere in volume

  The following physical properties of the obtained golf ball were examined. Moreover, the flying test was done by the following method and the feeling was also evaluated. The results are shown in Tables 5 to 8.

Cross section hardness and surface hardness of solid core (JIS-C hardness)
The center of the solid core and the cross-sectional hardness were measured by cutting the core so as to pass through the center of the core to make the cross-section flat, and pressing a hardness meter needle vertically onto a predetermined portion of the cross-section. It is shown by the value of JIS-C hardness.
Regarding the surface hardness of the solid core, a hardness meter was set to be perpendicular to the surface portion of the spherical core, and the hardness was measured based on the JIS-C hardness standard. It is shown by the value of JIS-C hardness. It is a measured value after temperature adjustment to 23 ° C.
Specific measurement locations of the cross-sectional hardness and surface hardness are as follows.
(A) the center of the core (b) the first layer 1 mm inside the interface between the first layer and the second layer (c) the second layer (d) 1 mm outside the interface between the first layer and the second layer (d ) The second layer 1 mm inside the interface between the second layer and the third layer (e) The third layer 1 mm outside the interface between the second layer and the third layer (f) The surface of the third layer

Intermediate layer and cover material hardness (Shore D hardness)
The material hardness is a value measured by a type D durometer based on ASTM-D2240 for a measurement sample in which a material to be measured is a sheet of 6 mm thickness.

The deformation ball, the second layer coated sphere, and the solid core were compressed at a speed of 10 mm / min using an Instron Corporation model 4204, and an initial load of 98 N (10 kgf) was applied to a final load of 1275 N (130 kgf). ) The amount of deflection deformation until the load was measured. Similarly, the amount of deflection deformation from when the initial load 98N (10 kgf) was applied to when the final load 5880N (600 kgf) was applied was measured.

Initial velocity of the ball The initial velocity of the ball was measured using an initial velocity measuring device of the same type as a USGA drum rotation type initial velocity meter approved by R & A. The balls were conditioned at a temperature of 23 ± 1 ° C. for more than 3 hours and tested in a room at room temperature 23 ± 2 ° C. Ten balls were struck twice, the time required to pass between 6.28 ft (1.91 m) was measured, and the initial velocity was calculated.

Each ball at a head speed (HS) of 50 m / s with a driver (W # 1) of “Tour Stage X-Drive” (loft angle 10.5 °) manufactured by Bridgestone Sports as a flying golf ball hitting robot at W # 1 Were hit 10 times, and the spin rate (rpm) and total flight distance (m) were measured. The initial speed was measured using a high-speed camera. The flight distance evaluation criteria are as follows.
○: 250 m or more ×: less than 250 m

Feeling (feeling)
Three top amateur golfers evaluated the hit feeling when hitting the ball with a driver (W # 1) at a head speed (HS) of 40 to 50 m / s according to the following criteria.
○: Good hitting feeling ×: Too hard or too soft

In Comparative Example 1, since the core has two layers and the initial speed is not sufficient, the flight distance does not come out.
In Comparative Example 2, the core has two layers, the spin amount is large, and the flight distance does not come out.
In Comparative Example 3, since the core is a single layer and the spin amount is large, a sufficient flight distance is not obtained.
In Comparative Example 4, since the diameter of the first layer of the core is large and the spin amount is large, a sufficient flight distance is not obtained.
Since the comparative example 5 has a large value of (a) + (b) + (c) + (d) + (e) + (f), the hit feeling is bad. Also, the spin amount is large and the flight distance is not sufficient.
In Comparative Example 6, since the value of (a) + (b) + (c) + (d) + (e) + (f) is small, the initial speed is slow and the flight distance is not sufficient.
In Comparative Example 7, since the values of (b)-(c) are less than 0, the spin is small, but the initial speed is not sufficient, so the flight distance does not come out.
In Comparative Example 8, since the value of (e)-(d) is less than 0, the spin amount is large and a sufficient flight distance is not obtained.
In Comparative Example 9, since the values of (b)-(c) and (e)-(d) are less than 0, the spin amount is large and the flight distance is not output.
In Comparative Example 10, since the third layer of the core is formed using a thermoplastic resin, the spin amount is large and the flight distance does not come out.

Claims (11)

A solid core is covered with one or more covers, and the solid core has a spherical first layer, a second layer that covers the first layer, and a third layer that covers the second layer. In the multi-piece solid golf ball having, the diameter of the first layer is 3 to 24 mm, the third layer is formed of a rubber composition mainly composed of polybutadiene rubber, and the solid core is cut in half. (A), the cross-sectional hardness in the JIS-C hardness of the core center in the cross section when
(B) the cross-sectional hardness in JIS-C hardness of the first layer 1 mm inside from the boundary surface between the first layer and the second layer,
(C) the cross-sectional hardness in JIS-C hardness of the second layer 1 mm outside the boundary surface,
(D) the cross-sectional hardness in JIS-C hardness of the second layer 1 mm inside from the boundary surface between the second layer and the third layer,
The cross-sectional hardness in JIS-C hardness of the third layer 1 mm outside from the boundary surface is (e),
When the surface hardness in the JIS-C hardness of the third layer is (f),
The value of (b)-(c) is 0-40,
The value of (e)-(d) is 0-40,
A multi-piece solid golf ball having a value of (a) + (b) + (c) + (d) + (e) + (f) in a range of 380 to 460.   The multi-piece solid golf ball according to claim 1, wherein the solid core has a value of (f) − (a) in a range of −10 to 20.   The multi-piece solid golf ball according to claim 1 or 2, wherein the first layer is formed of a rubber composition mainly composed of polybutadiene rubber.   The multi-piece solid golf ball according to any one of claims 1 to 3, wherein the solid core has a cross-sectional hardness (a) in a JIS-C hardness of 60 to 95.   The multi-piece solid golf ball according to claim 1, wherein the second layer is formed of a rubber composition containing polybutadiene rubber as a main material.   6. The multi-piece solid golf ball according to claim 1, wherein a diameter of the sphere (second layer-covered sphere) in which the first layer is covered with the second layer is 20 to 33 mm.   The diameter ratio (first layer / second layer coated sphere) of a sphere (second layer coated sphere) in which the first layer and the first layer are coated with the second layer is 0.20 to 0.50. The multi-piece solid golf ball according to claim 6.   The multi-piece solid golf ball according to claim 1, wherein a volume ratio of the second layer and the solid core (second layer / solid core) is 0.10 to 0.50.   The amount of deflection from when the initial load 98N (10 kgf) is applied to when the final load 1,275N (130 kgf) is applied to the sphere (second layer-coated sphere) having the first layer covered with the second layer, The ratio of the amount of deflection (second layer covered sphere / solid core) from when the initial load of 98 N (10 kgf) is applied to when the final load of 1,275 N (130 kgf) is applied to the solid core is 1.50. The multi-piece solid golf ball according to claim 1, which is ˜1.80.   The amount of deflection from when the initial load of 98 N (10 kgf) is applied to the solid core to when the final load of 1,275 N (130 kgf) is applied, and the initial load of 98 N (10 kgf) is applied to the ball The multi-piece solid according to any one of claims 1 to 9, wherein a deflection ratio (solid core / ball) from when the load is applied to a final load of 1,275 N (130 kgf) is 1.20 to 1.40. Golf ball.   The amount of deflection from when the initial load of 98 N (10 kgf) is applied to when the final load of 5,880 N (600 kgf) is applied to the ball, and from the state of applying the initial load of 98 N (10 kgf) to the final load of 1,275 N The multi-piece solid golf ball according to any one of claims 1 to 10, wherein a ratio (600 kgf / 130 kgf) of a deflection amount until (130 kgf) is loaded is 3.50 to 3.80.

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