JP2006028062A - Gel-like cleaning composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a gel-like cleaning composition having improved feel in use and excellent stability with time. <P>SOLUTION: The gel-like cleaning composition comprises (a) a blocked alkylene oxide derivative represented by formula (I) R<SP>1</SP>O-[(AO)<SB>m</SB>(EO)<SB>n</SB>]-R<SP>2</SP>(AO is a 3-4C oxyalkylene group; EO is an oxyethylene group; 1≤m≤70; 1≤n 70; AO and EO are added in a block state and the ratio of EO to the total of AO and EO is 20-80 mass %. R<SP>1</SP>and R<SP>2</SP>are each the same or different and a 1-4C hydrocarbon group or a hydrogen atom; the ratio of the number of hydrogen atoms to the number of hydrocarbon groups of R<SP>1</SP>and R<SP>2</SP>is ≤0.15) and has ≥ 1,000 molecular weight, (b) sucrose fatty acid ester, (c) a polyhydric alcohol containing three or more hydroxy groups in the molecule and (d) an oil. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

  The present invention relates to a gel-like cleaning composition, and more particularly to improvement in the feel of use and stability over time.

Cleansing cosmetics are used as cosmetics for the purpose of cleaning skin dirt and makeup cosmetics. Cleansing cosmetics are usually used after being applied to the skin and then washed off with water or wiped off with a tissue or the like. Conventionally, as these cosmetics, various types and dosage forms such as oily, oil-in-water / water-in-oil emulsions and creams are commercially available.
However, although the oil-in-water type has a good feeling in use, it has a drawback that the cleaning effect is low. On the other hand, although the water-in-oil type and the oily type have a high cleaning effect, they have the disadvantage that the oil component is sticky to the hand when used and is difficult to wash off with water.

Therefore, in recent years, gel-like cleaning agents have been developed to achieve both a cleaning effect and a feeling of use. For example, makeup using a liquid crystal gel composed of a water-soluble substance having a hydroxyl group, oil, water, and a hydrophilic nonionic surfactant. (Patent Document 1), a sucrose fatty acid ester, a polyhydric alcohol having three or more hydroxyl groups, a gel-like detergent containing oil (Patent Document 2), and the like are known.
JP-A-62-53910 JP-A-5-229916

However, the cosmetic using the liquid crystal gel of Patent Document 1 is not satisfactory in terms of stability, for example, the moisture is volatilized over time and the gel is broken and the viscosity is lowered. Moreover, the gel-type cleaning agent of the above-mentioned Patent Document 2 was not sufficiently satisfactory in terms of use feeling such as a phase inversion feeling not being obtained.
The present invention has been made in view of the above-described problems, and an object of the present invention is to provide a gel cleaning composition having a good use feeling and excellent stability over time.

  As a result of intensive studies in view of the above-described problems, the present inventors have found that an alkylene oxide derivative having a specific structure is added to a gel-like cleaning composition together with a sucrose fatty acid ester, a polyhydric alcohol having three or more hydroxyl groups, and an oil component. By blending, it was found that a gel cleaning composition having a good use feeling and excellent stability over time can be obtained, and further by adding a nonionic surfactant and / or an anionic surfactant, the cleaning effect and It has been found that the feeling of use is further improved, and the present invention has been completed.

That is, the gel cleaning composition of the present invention is
(A) a block-type alkylene oxide derivative represented by the following formula (I) and having a molecular weight of 1000 or more;
(B) sucrose fatty acid ester;
(C) a polyhydric alcohol having three or more hydroxyl groups in the molecule;
(D) It contains an oil component.
(Chemical formula 1)
_{^{R 1 O - [(AO)}} m (EO) n] -R 2 (I)
(In the formula, AO is an oxyalkylene group having 3 to 4 carbon atoms, EO is an oxyethylene group, m and n are average addition moles of the oxyalkylene group and oxyethylene group, respectively, 1 ≦ m ≦ 70, 1 ≦ n ≦ 70 The oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group are added in a block form, and the ratio of the oxyethylene group to the total of the oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group is R ¹ and R ² may be the same or different and each is a hydrocarbon group having 1 to 4 carbon atoms or a hydrogen atom, and the number of hydrogen atoms relative to the number of hydrocarbon groups represented by R ¹ and R ² The ratio is 0.15 or less.)

In the composition, it is preferable to further blend a nonionic surfactant and / or an anionic surfactant.
Moreover, it is suitable that the compounding quantity of the said alkylene oxide derivative is 0.01-15 mass%.
Furthermore, the ester substitution degree of the sucrose fatty acid ester is preferably 1.8 or less.

According to the present invention, by blending an alkylene oxide derivative having a specific structure with a sucrose fatty acid ester, a polyhydric alcohol having three or more hydroxyl groups, and an oil component into a gel-like cleaning composition, the feel of use and stability over time are achieved. A gel cleaning composition having excellent properties can be obtained.
Further, by adding a nonionic surfactant and / or an anionic surfactant, it is possible to further improve the cleaning effect and the feeling of use.

Hereinafter, preferred embodiments of the present invention will be described.
(A) Block-type alkylene oxide derivative (Formula 2)
_{^{R 1 O - [(AO)}} m (EO) n] -R 2 (I)
In the alkylene oxide derivative represented by the above formula (I), AO is an oxyalkylene group having 3 to 4 carbon atoms. Specifically, oxypropylene group, oxybutylene group, oxyisobutylene group, oxytrimethylene group, oxy Examples include a tetramethylene group. Preferably, an oxypropylene group and an oxybutylene group are mentioned.

m is the average number of added moles of the oxyalkylene group having 3 to 4 carbon atoms, and 1 ≦ m ≦ 70, preferably 2 ≦ m ≦ 50. n is the average number of added moles of oxyethylene groups, and 1 ≦ n ≦ 70, preferably 5 ≦ n ≦ 55. When the oxyalkylene group or oxyethylene group having 3 to 4 carbon atoms is 0, the moist feeling is lowered, and when it exceeds 70, the sticky feeling is produced.
Moreover, it is preferable that the ratio of the oxyethylene group with respect to the sum total of a C3-C4 oxyalkylene group and an oxyethylene group is 20-80 mass%. If the ratio of the oxyethylene group is less than 20% by mass, skin irritation may occur in rare cases, and if it exceeds 80% by mass, the cleaning effect tends to be inferior.

  The oxyethylene group and the oxyalkylene group having 3 to 4 carbon atoms must be added in a block form, but the order of addition of ethylene oxide and the alkylene oxide having 3 to 4 carbon atoms is not particularly specified. The block shape includes not only two-stage blocks but also three or more stages.

R ¹ and R ² are each a hydrocarbon group having 1 to 4 carbon atoms or a hydrogen atom, and examples of the hydrocarbon group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, Examples thereof include a tert-butyl group. A methyl group and an ethyl group are preferred. Hydrocarbon groups having 5 or more carbon atoms tend to have poor hydrophilicity and cause skin irritation. R ¹ and R ² may be the same or different.

R ¹ and R ² may be the same type, or a mixture of a hydrocarbon group having 1 to 4 carbon atoms and a hydrogen atom, or a mixture of different hydrocarbon groups having 1 to 4 carbon atoms. Good. However, among the hydrocarbon groups of R ¹ and R ^2, the proportion of hydrocarbon groups and hydrogen atoms is such that the ratio Y / X of the number of hydrogen atoms (Y) to the number of hydrocarbon groups (X) is 0.15. Hereinafter, it is preferably 0.06 or less. When the ratio of Y / X exceeds 0.15, a sticky feeling comes out.

  The molecular weight of the block type alkylene derivative is preferably 1000 or more, more preferably 3000 or more. If the molecular weight is less than 1000, the cleaning effect is low. The upper limit of the molecular weight cannot be specified, but as the molecular weight increases, the rinsing ease during washing and the sticky feeling after washing tend to occur.

Specific examples of the block-type alkylene oxide derivative of the present invention include POE (14) POP (7) dimethyl ether, POE (17) POP (4) dimethyl ether, POE (10) POP (10) dimethyl ether, POE (7) POP. (12) Dimethyl ether, POE (15) POP (5) Dimethyl ether, POE (25) POP (25) Dimethyl ether, POE (27) POP (14) Dimethyl ether, POE (55) POP (28) Dimethyl ether, POE (22) POP (40) Dimethyl ether, POE (35) POP (40) Dimethyl ether, POE (50) POP (40) Dimethyl ether, POE (36) POP (41) Dimethyl ether, POE (55) POP (30) Dimethyl ether, POE (30) OP (34) dimethyl ether, POE (25) POP (30) dimethyl ether, POE (14) POB (7) dimethyl ether, POE (10) POP (10) diethyl ether, POE (10) POP (10) dipropyl ether, POE (10) POP (10) dibutyl ether and the like can be mentioned.
The POE, POP, and POB are abbreviations for polyoxyethylene, polyoxypropylene, and polyoxybutylene, respectively, and may be abbreviated as follows.

The compounding quantity of an alkylene oxide derivative is 0.01-15 mass%, Preferably it is 0.5-10 mass%. If it is less than 0.01% by mass, the effect of the blending may not be sufficiently exhibited. If it exceeds 15% by mass, a sticky feeling may be produced after washing.
The block-type alkylene oxide derivative of the present invention can be produced by a known method. For example, it can be obtained by subjecting a compound having a hydroxyl group to addition polymerization of ethylene oxide and an alkylene oxide having 3 to 4 carbon atoms, and then subjecting an alkyl halide to an ether reaction in the presence of an alkali catalyst. Hereinafter, synthesis examples are shown.

<Synthesis example Block type alkylene oxide derivative>
Polyoxyethylene (10 mol) Polyoxypropylene (10 mol) Dimethyl ether
CH ₃ O [(EO) ₁₀ (PO) ₁₀ ] CH ₃ (Block polymer)
76 g of propylene glycol and 3.1 g of potassium hydroxide as a catalyst were charged into an autoclave. After the air in the autoclave was replaced with dry nitrogen, the catalyst was completely dissolved at 140 ° C. with stirring. Next, 522 g of propylene oxide was dropped with a dropping device and stirred for 2 hours. Subsequently, 440 g of ethylene oxide was dropped with a dropping device and stirred for 2 hours. Next, 224 g of potassium hydroxide was charged and the inside of the system was replaced with dry nitrogen, and then 188 g of methyl chloride was injected at a temperature of 80 to 130 ° C. and reacted for 5 hours. Thereafter, the reaction composition was taken out from the autoclave, neutralized with hydrochloric acid to pH 6 to 7, and treated at a reduced pressure of -0.095 MPa (50 mmHg) at 100 ° C for 1 hour in order to remove the contained water. Further, filtration was performed to remove the salt produced after the treatment, and the block type alkylene oxide derivative was obtained.
Samples that were sampled and reacted before reacting with methyl chloride had a hydroxyl value of 110, the resulting compound had a hydroxyl value of 0.3, and the ratio of the number of hydrogen atoms to the number of terminal methyl groups was 0.003. An atom is converted to a methyl group.

<Reference Synthesis Example Random alkylene oxide derivative>
Polyoxyethylene (10 mol) Polyoxypropylene (10 mol) Dimethyl ether CH ₃ O [(EO) ₁₀ / (PO) ₁₀ ] CH ₃ (Random polymer)
76 g of propylene glycol and 3.1 g of potassium hydroxide as a catalyst were charged into an autoclave. After the air in the autoclave was replaced with dry nitrogen, the catalyst was completely dissolved at 140 ° C. with stirring. Next, a mixture of 440 g of ethylene oxide and 522 g of propylene oxide was dropped with a dropping device and stirred for 2 hours. Next, 224 g of potassium hydroxide was charged and the inside of the system was replaced with dry nitrogen, and then 188 g of methyl chloride was injected at a temperature of 80 to 130 ° C. and reacted for 5 hours. Thereafter, the reaction composition was taken out from the autoclave, neutralized with hydrochloric acid to pH 6 to 7, and treated at a reduced pressure of -0.095 MPa (50 mmHg) at 100 ° C for 1 hour in order to remove the contained water. Further, filtration was performed to remove the salt generated after the treatment, and the random alkylene oxide derivative was obtained.
Samples that were sampled and reacted before reacting with methyl chloride had a hydroxyl value of 107, the resulting compound had a hydroxyl value of 0.4, and the ratio of the number of hydrogen atoms to the number of terminal methyl groups was 0.004. An atom is converted to a methyl group.

(B) Sucrose fatty acid ester All the (b) sucrose fatty acid esters used in the present invention include those having an ester substitution degree of 1.8 or less. The degree of substitution here refers to the average number of ester-bonded fatty acids per molecule of sucrose constituting the sucrose fatty acid ester. As monoester content, it is about 20-80 mass% of the whole ester. Moreover, carbon number of the fatty acid couple | bonded is 8-22, and is a single or mixed fatty acid among derivatives, such as a saturated or unsaturated linear or branched fatty acid and a hydroxy body.
As the sucrose fatty acid ester used in the present invention, a substitution degree of 1.65 or less and a monoester content of about 40% by mass or more are particularly preferable, and the composition ratio is 0.5 to 30%, more preferably 1 to 10%. . If it is 0.5% or less, a primary gel composition of a polyhydric alcohol and a sucrose fatty acid ester described below is difficult to produce and is not preferable in terms of stability. If it is 30% or more, it becomes difficult to disperse.

Specific examples of the sucrose fatty acid ester of the present invention include sucrose laurate, sucrose myristic ester, sucrose palmitate, sucrose stearate, sucrose oleate, sucrose palmitate stearate Mixed ester etc. are mentioned.
The compounding quantity of sucrose fatty acid ester is about 0.5-5 mass% with respect to gel cleaning composition whole quantity, Preferably it is 1-3 mass%. If it is less than 0.5% by mass, gel formation and phase inversion may not be sufficient. If it exceeds 5% by mass, a sticky feeling after use tends to appear.

(C) Polyhydric alcohol having 3 or more hydroxyl groups Specific examples of the polyhydric alcohol having 3 or more hydroxyl groups in the molecule of the present invention include glycerin, diglycerin, triglycerin, tetraglycerin, Examples include pentaglycerin, hexaglycerin, octaglycerin, nonaglycerin, decaglycerin, glucose, sorbitol, maltitol, sucrose, raffinose, trehalose, and the like, and particularly preferred are glycerin, diglycerin, triglycerin, sorbitol, and maltitol. Can be mentioned. The polyhydric alcohol can use 1 type (s) or 2 or more types.
The compounding quantity of the polyhydric alcohol which has a 3 or more hydroxyl group is about 5-50 mass% with respect to the gel cleaning composition whole quantity, Preferably it is 15-30 mass%. If it is less than 5% by mass, gel formation and phase inversion may not be sufficient. If it exceeds 50% by mass, a sticky feeling after use tends to appear.

(D) Oil content (d) The oil content used in the present invention is a liquid oil, solid oil, wax, hydrocarbon oil, higher fatty acid, higher alcohol, ester oil, silicone oil ordinarily used in cosmetics, quasi drugs, etc. Is used arbitrarily.
Specific examples of liquid fats include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanca oil, castor oil, flaxseed Oil, safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.
Specific examples of solid fats and oils include cocoa butter, coconut oil, horse fat, hydrogenated coconut oil, palm oil, beef tallow, sheep fat, hardened beef tallow, palm kernel oil, pork fat, beef bone fat, owl kernel oil, hydrogenated oil, Examples include beef leg fat, mole, and hardened castor oil.

Specific examples of waxes include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugarcane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced Lanolin, jojoballow, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol,
POE hydrogenated lanolin alcohol ether and the like.
Specific examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax and the like.

Specific examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, toluic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA) etc. are mentioned.
Specific examples of higher alcohols include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl) Alcohol), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, octyldodecanol and the like.

Specific examples of ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, Myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate , Diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, trimetriisostearate Roll propane, tetra-2-ethylhexanoic acid pentaerythritol, tri-2-ethylhexanoic acid glycerin, trioctanoic acid glycerin, triisopalmitic acid glycerin, triisostearic acid trimethylolpropane, cetyl 2-ethylhexanoate, 2-ethylhexyl Palmitate, glyceryl trimyristate, glyceride tri-2-heptylundecanoate, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid 2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyl adipate Decyl, diisopropyl sebacate, 2-ethylhexyl succinate, and triethyl citrate.
Specific examples of the silicone oil include chain polysiloxanes (eg, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (eg, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethyl). (Cyclohexasiloxane, etc.) Silicone resin, silicone rubber, various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.) that form a three-dimensional network structure, etc. Can be mentioned.

  The blending amount of the oil is about 20 to 90% by mass, preferably 40 to 80% by mass with respect to the total amount of the gel cleaning composition. If it is less than 20% by mass, gel formation and detergency may not be sufficient, and if it exceeds 90% by mass, a sticky feeling will appear after use.

In the present invention, by further blending a nonionic surfactant and / or an anionic surfactant, the detergency can be improved and the usability can be further enhanced.
Specific examples of the nonionic surfactant used in the present invention include lipophilic nonionic surfactants such as sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate). Sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate); glycerin polyglycerin fatty acids (for example, Mono cotton seed oil fatty acid glycerin, glyceryl monoerucate, glyceryl sesquioleate, glyceryl monostearate, α, α'-oleic acid pyroglutamic acid glycerin, monostearic acid glycerin malic acid, etc.); propi Examples include lenglycol fatty acid esters (for example, propylene glycol monostearate); hardened castor oil derivatives; glycerin alkyl ethers and the like.

Examples of hydrophilic nonionic surfactants include POE-sorbitan fatty acid esters (for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate, etc. POE sorbite fatty acid esters (eg, POE-sorbite monolaurate, POE-sorbite monooleate, POE-sorbite pentaoleate, POE-sorbite monostearate, etc.); POE-glycerin fatty acid esters (eg, POE) -Glycerol monostearate, POE-glycerin monoisostearate, POE-monooleate such as POE-glycerin triisostearate, etc .; POE-fatty acid esters (eg POE-distearate, POE-monodiolate, ethylene glycol distearate, etc.) POE-alkyl ethers (eg POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic type (for example, Pluronic, etc.); POE / POP- Alkyl ethers (for example, POE / POP-cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether);
POE / tetra-POP-ethylenediamine condensates (eg, Tetronic); POE-castor oil hardened castor oil derivatives (eg, POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE -Hydrogenated castor oil triisostearate, POE-hardened castor oil monopyroglutamic acid monoisostearic acid diester, POE-hardened castor oil maleic acid, etc.); POE-honey beeswax lanolin derivatives (eg POE-sorbite beeswax etc.); alkanolamides (For example, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid ester; POE-alkylamine; POE-fatty acid amide; alkylethoxydimethylamine oxide; trioleyl phosphate etc. Can be mentioned.

  Specific examples of anionic surfactants include fatty acid soaps (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (eg, sodium lauryl sulfate, potassium lauryl sulfate); alkyl ether sulfates ( For example, POE-lauryl sulfate triethanolamine, POE-sodium lauryl sulfate, etc .; N-acyl sarcosine acid (eg, sodium lauroyl sarcosine); higher fatty acid amide sulfonate (eg, N-myristoyl-N-methyl taurate sodium) Coconut oil fatty acid methyl taurine sodium, lauryl methyl taurine sodium, etc .; phosphate ester salt (POE-oleyl ether sodium phosphate, POE-stearyl ether phosphate, etc.); sulfosuccinate (eg, di-2-ethylhexyl sulfocolate) Sodium succinate, monolauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc.); alkyl benzene sulfonates (for example, sodium linear dodecyl benzene sulfonate, triethanol amine linear dodecyl benzene sulfonate, linear dodecyl) Higher fatty acid ester sulfates (for example, hydrogenated coconut oil fatty acid sodium glycerol sulfate); N-acyl glutamate (for example, monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, N-myristoyl) -L-glutamic acid monosodium, etc.); sulfated oil (eg funnel oil); POE-alkyl ether carboxylic acid; POE-alkyl allyl ether catalyst Α-olefin sulfonates; higher fatty acid ester sulfonates; secondary alcohol sulfates; higher fatty acid alkylolamide sulfates; lauroyl monoethanolamide sodium succinate; N-palmitoyl aspartate ditriethanolamine ; Sodium caseinate and the like.

  The compounding quantity of a nonionic surfactant and / or an anionic surfactant is 0.1-10 mass% with respect to the gel cleaning composition whole quantity, Preferably it is 0.5-3 mass%. If it is less than 0.1% by mass, the cleaning effect may not be sufficient. If it exceeds 10% by mass, stickiness may be felt after use.

In addition to the above essential components, the gel cleaning composition of the present invention can be blended with components that are usually used in gel cleaning compositions for cosmetics and quasi-drugs, and are produced according to conventional methods. Specific components that can be blended are listed below, and the gel cleaning composition of the present invention can be prepared by blending the above essential components and one or more of the following components.
Examples of the powder component include inorganic powders (for example, talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, saucite, biotite, permiculite, magnesium carbonate, calcium carbonate, silicic acid. Aluminum, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (baked gypsum), calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder , Metal soap (eg, zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc .; organic powder (eg, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene Powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, etc.); inorganic white pigment (eg, titanium dioxide, zinc oxide, etc.); inorganic red pigment (eg, Iron oxide (Bengara), iron titanate, etc .; Inorganic brown pigments (eg, γ-iron oxide, etc.); Inorganic yellow pigments (eg, yellow iron oxide, loess, etc.); Inorganic black pigments (eg, black oxide) Iron, low-order titanium oxide, etc.); inorganic purple pigments (eg, mango violet, cobalt violet, etc.); inorganic green pigments (eg, chromium oxide, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigments (eg, Pearl pigments (eg titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored oxidation) Tan-coated mica, bismuth oxychloride, fish scale foil, etc.); metal powder pigments (eg, aluminum powder, copper powder, etc.); organic pigments such as zirconium, barium or aluminum lake (eg, red 201, red 202, red 204) No., red 205, red 220, red 226, red 228, red 405, orange 203, orange 204, yellow 205, yellow 401, and blue 404, organic pigments such as red 3 , Red 104, Red 106, Red 227, Red 230, Red 401, Red 505, Orange 205, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Green 3 and Blue No. 1 etc.); natural pigments (for example, chlorophyll, β-carotene, etc.) and the like.

Examples of amphoteric surfactants include imidazoline-based amphoteric surfactants (eg, 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide). Side-1-carboxyethyloxy disodium salt, etc.); betaine surfactants (for example, 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide betaine) , Sulfobetaine, etc.).
Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (eg, cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; Poly (N, N'-dimethyl-3,5-methylenepiperidinium chloride); alkyl quaternary ammonium salt; alkyldimethylbenzylammonium salt; alkylisoquinolinium salt; dialkyl morpholinium salt; POE-alkylamine; Examples include alkylamine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride and the like.

Examples of natural water-soluble polymers include plant-based polymers (for example, gum arabic, gum tragacanth, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (guckweed extract), starch (Rice, corn, potato, wheat), glycyrrhizic acid); microbial polymers (eg, xanthan gum, dextran, succinoglucan, bullulan, etc.); animal polymers (eg, collagen, casein, albumin, gelatin, etc.), etc. Is mentioned.
Semi-synthetic water-soluble polymers include, for example, starch polymers (eg, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate) Hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder and the like); alginic acid polymers (for example, sodium alginate, propylene glycol alginate, etc.) and the like.

Synthetic water-soluble polymers include, for example, vinyl polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer); polyoxyethylene polymers (eg, polyethylene glycol 20,000, 40,000, 60,000). Polyoxyethylene polyoxypropylene copolymer, etc.); acrylic polymers (for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethyleneimine; cationic polymers, and the like.
Examples of the thickener include gum arabic, carrageenan, caraya gum, gum tragacanth, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, CMC, hydroxyethylcellulose, hydroxypropyl Cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, cellulose dialkyldimethylammonium sulfate, xanthan gum, magnesium aluminum silicate, bentonite, hectorite, silicate A1Mg (vee gum), Examples thereof include laponite and silicic anhydride.

Examples of UV absorbers include benzoic acid UV absorbers (eg, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester. N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester, etc.); anthranilic acid-based UV absorbers (for example, homomenthyl-N—
Acetyl anthranilate, etc.); salicylic acid-based UV absorbers (for example, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc.); , Octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p-methoxycinnamate , Isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate)
, 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2 -Ethylhexanoyl-diparamethoxycinnamate, etc.); benzophenone UV absorbers (eg 2,4-dihydroxybenzophenone, 2,2'-
Dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2 ', 4,4'-tetrahydroxybenzophenone, 2-hydroxy-4-
Methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2- Carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc.); 3- (4′-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l- Camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-methylphenylbenzotriazole; 2- (2'-hydroxy-5'-t-octylphenyl)
2- (2'-hydroxy-5'-methylphenylbenzotriazole;dibenzalazine;dianisoylmethane;4-methoxy-4'-t-butyldibenzoylmethane; 5- (3,3-dimethyl-2- Norbornylidene) -3-pentan-2-one and the like.

Examples of the sequestering agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, tetrasodium edetate Sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, trisodium ethylenediaminehydroxyethyl triacetate and the like.
Examples of the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

Monosaccharides include, for example, tricarbon sugars (eg, D-glyceryl aldehyde, dihydroxyacetone, etc.); tetracarbon sugars (eg, D-erythrose, D-erythrulose, D-treose, erythritol, etc.); pentose sugars (eg, , L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc .; hexose (eg, D-glucose, D-talose, D) -Bucicose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc.); pentose sugar (eg, aldheptose, heproose, etc.); octose sugar (eg, octulose, etc.); For example, 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, etc .; amino sugar (eg, D-glucosamine, D-galactosamine, shea Acid, Aminouron acid, muramic acid); uronic acid (e.g., D- glucuronic acid, D- mannuronic acid, L- guluronic acid, D- galacturonic acid, L- iduronic acid) and the like.
Examples of the oligosaccharides include sucrose, gnocyanose, umbelliferose, lactose, planteose, isoliquinoses, α, α-trehalose, raffinose, lycnose, umbilicin, stachyose verbus courses and the like.

Examples of the polysaccharide include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran, kerato sulfate. , Locust bean gum, succinoglucan, caronic acid and the like.
Examples of amino acids include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.) and the like. Examples of amino acid derivatives include acyl sarcosine sodium (lauroyl sarcosine sodium), acyl glutamate, acyl β-alanine sodium, glutathione, and pyrrolidone carboxylic acid.

Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol. Is mentioned.
Examples of the polymer emulsion include an acrylic resin emulsion, a polyethyl acrylate emulsion, an acrylic resin liquid, a polyacryl alkyl ester emulsion, a polyvinyl acetate resin emulsion, and a natural rubber latex.
Examples of the pH adjusting agent include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate.
Examples of vitamins include vitamins A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, biotin and the like.

Examples of the antioxidant include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.
Examples of the antioxidant assistant include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.

  Other components that can be blended include, for example, preservatives (ethyl paraben, butyl paraben, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.); whitening agents (for example, Extract, placenta extract, saxifrage extract, arbutin, etc.); various extracts (eg, buckwheat, auren, shikon, peonies, assembly, birch, sage, loquat, carrot, aloe, mallow), iris, grape, yokuinin, loofah, lily , Saffron, nematode, ginger, hypericum, onionis, garlic, red pepper, chimney, red snapper, seaweed, etc.), activator (eg, royal jelly, photosensitizer, cholesterol derivative, etc.); Acid Gyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin , Γ-oryzanol, etc.); antiseborrheic agents (eg, sulfur, thianthol, etc.); anti-inflammatory agents (eg, tranexamic acid, thiotaurine, hypotaurine, etc.) and the like. In addition, a fragrance | flavor, a scrub agent, purified water, etc. can be mix | blended.

The gel-like cleaning composition of the present invention refers to those applied to the skin of the face, scalp, hair, body, etc. for the purpose of cleaning the skin of the face, scalp, hair, body and the like.
The present invention will be described more specifically with reference to the following examples. In addition, this invention is not limited by this.

First, the prescription of the cosmetic material (foundation having a strong film property) used in the test will be described.
(mass%)
(1) Decamethylcyclopentasiloxane 14.0
(2) Octamethylcyclotetrasiloxane 24.0
(3) Siliconized pullulan 15.0
(4) Isostearic acid 1.0
(5) Titanium oxide 5.0
(6) Octyl methoxycinnamate 5.0
(7) Dextrin fatty acid-coated powder 25.0
(8) Alcohol balance (9) Perfume appropriate amount

Next, the evaluation method used in the present invention will be described.
Evaluation (1): Gel forming ability The gel forming state after sample preparation was observed. The evaluation criteria are as follows.
○ ... A gel is formed.
X: No gel was formed.
Evaluation (2): Cleaning effect The foundation was overcoated, and after 2 hours, the face was washed with the sample, and the cosmetic removal effect after cleaning was tested by 10 professional panelists. The evaluation criteria are as follows.
A: Eight or more out of 10 people recognized that the cosmetic removal effect was high.
○ 6 to 10 out of 10 people recognized that the cosmetic removal effect was high.
Δ: From 3 to less than 6 out of 10 people recognized that the effect of removing cosmetics was high.
X: Less than 3 out of 10 people recognized that the cosmetic removal effect was high.

Evaluation (3): Phase inversion feeling Overcoating with the above foundation, after 2 hours, using the sample on the skin, whether there is a feeling of phase inversion within 10 to 30 seconds (feeling that the spread becomes light) It was tested by 10 expert panelists. The evaluation criteria are as follows.
A: Eight or more out of 10 people recognized that there was a sense of phase inversion.
○ 6 to 10 out of 10 people recognized that there was a sense of phase inversion.
Δ: More than 3 but less than 6 out of 10 people recognized that there was a phase inversion.
X: Less than 3 out of 10 people recognized that there was a sense of phase inversion.
Evaluation (4): Ease of rinsing The foundation was overcoated, and after 2 hours, the sample was washed with a face and tested by 10 professional panelists for rinsing ease during washing. The evaluation criteria are as follows.
◎ ... 8 or more out of 10 people recognized that it was easy to rinse.
○ ... 6 or more but less than 8 out of 10 people recognized that it was easy to rinse.
Δ: More than 3 but less than 6 out of 10 people found it easy to rinse.
X: Less than 3 out of 10 people recognized that it was easy to rinse.

Evaluation (5): No sticky feeling The above foundation was repeatedly applied, the face was washed with a sample after 2 hours, and the presence or absence of sticky feeling after washing was tested by 10 professional panelists. The evaluation criteria are as follows.
◎… 8 or more out of 10 people recognized that they were not sticky.
○ ... 6 or more of 10 but less than 8 recognized that they were not sticky.
Δ: More than 3 but less than 6 out of 10 people recognized that they were not sticky.
X: Less than 3 out of 10 people recognized that they were not sticky.
Evaluation (6): Skin irritation A block patch for 24 hours was applied to the inner side of the upper arm of 10 panelists, and the average value was calculated according to the following criteria.
0: No abnormality is observed.
1 ... Slight redness is observed.
2… Redness is recognized.
3 ... Redness and papules are observed.
Evaluation criteria for skin irritation are as follows.
A: Average value of 10 panelists: 0 or more and less than 0.15 A: Average value of 10 panelists: 0.15 or more and less than 0.2 Δ: Average value of 10 panelists: 0.2 or more and less than 0.3 × ... Average value of 10 panelists: 0.3 or more

Evaluation (7): Stability over time After the sample was prepared, it was placed in a 50 ml sample tube (diameter 3 cm), and the state after standing for 4 weeks in a thermostatic bath at 50 ° C. was observed with the naked eye. The evaluation criteria are as follows.
◎… The gel state is stable.
○: The viscosity of the gel is slightly reduced.
Δ: Gel softened.
X: Separation.

（製法） ６０℃に加熱した水相部に、低速ホモミキサーをかけながら６０℃に加熱した油相部を徐々に添加し乳化する。その後室温まで冷却し、洗浄組成物を得た。 The sample which consists of a mixing | blending composition described in following Table 1 was manufactured, and the evaluation test was done about said evaluation (1)-(7). The results are shown in Table 1.
(Table 1)

(Manufacturing method) The oil phase part heated to 60 degreeC was gradually added and emulsified to the water phase part heated to 60 degreeC, applying a low speed homomixer. Thereafter, it was cooled to room temperature to obtain a cleaning composition.

In Test Example 4 which does not contain an alkylene oxide derivative, the use feeling is not sufficiently obtained.
Test Example 5 containing no sucrose fatty acid ester does not provide gel-forming ability and phase inversion.
Further, in Test Example 6 in which a polyhydric alcohol having two hydroxyl groups is used instead of a polyhydric alcohol having three hydroxyl groups in the molecule, gel forming ability and phase inversion are not obtained, and stability over time is poor. Furthermore, in Test Example 7 in which no oil component is blended and in Test Example 8 in which a nonionic surfactant or an anionic surfactant is not blended, there is no gel-forming ability, and a feeling of use and a cosmetic removal effect are sufficient. The stability over time is inferior.
On the other hand, Test Examples 1 and 2 in which an alkylene oxide derivative, a sucrose fatty acid ester having a substitution degree of 1.5, a polyhydric alcohol having 3 or more hydroxyl groups, and an oil were blended were used for any evaluation of (1) to (7). It was excellent.
Moreover, although the sucrose fatty acid ester is included, in Test Example 3 in which the substitution degree of the sucrose fatty acid ester is 2.0, the gel forming ability and the phase inversion feeling are not obtained, and the temporal stability is inferior. It was confirmed that the effects of the present invention can be obtained when further studies have been made.

（製法） ６０℃に加熱した水相部に、低速ホモミキサーをかけながら６０℃に加熱した油相部を徐々に添加し乳化する。その後室温まで冷却し、洗浄組成物を得た。 Subsequently, in order to further examine the suitability of the alkylene oxide derivative, various alkylene oxide derivatives were prepared, and the evaluation tests were performed on the above evaluations (1) to (7) for the samples having the blending composition described in Table 2 below. . The test results are shown in Table 2.
(Table 2)

(Manufacturing method) The oil phase part heated to 60 degreeC was gradually added and emulsified to the water phase part heated to 60 degreeC, applying a low speed homomixer. Thereafter, it was cooled to room temperature to obtain a cleaning composition.

From Test Examples 12 and 13, when only an oxyethylene group or an oxypropylene group is used, there is no gel-forming ability, and inferior in terms of phase inversion, skin irritation, and stability over time. Furthermore, in the case of the oxyethylene group alone, no effect can be obtained in terms of ease of rinsing and lack of stickiness.
Moreover, when the oxyethylene group is 80 mol or more, it is not preferable in terms of rinsing and stickiness (Test Example 14). Furthermore, when the molecular weight is 1000 or less (Test Example 15) or random type (Test Example 18), there is no gel-forming ability, phase inversion, and stability over time.
When both ends were hydrogen (Test Example 16), it was not preferable in terms of phase inversion, ease of rinsing and stickiness, and skin irritation, while both ends were hydrocarbon groups having 6 carbon atoms. In the case (Test Example 17), the point of phase inversion and skin irritation are not sufficient.
On the other hand, Test Examples 9 to 11 in which the alkylene oxide derivative represented by the formula (I) of the present invention was blended were excellent in any of the evaluations (1) to (7).

As described above, the alkylene oxide derivative is a block type, R ¹ and R ² are each a hydrocarbon group having 1 to 4 carbon atoms or a hydrogen atom, and the average added mole number of the oxyalkylene group and oxyethylene group is 1 ≦ m ≦ 70 and 1 ≦ n ≦ 70 were confirmed to be preferable.
The ratio of the oxyethylene group to the total of the oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group is 20 to 80% by mass, and the ratio of the number of hydrogen atoms to the number of hydrocarbon groups of R ¹ and R ² is 0.15 or less. I also found it preferable.

  Subsequently, in order to examine the suitable blending amount of the alkylene oxide derivative of the present invention, the above-mentioned evaluations (1) to (1) were performed on samples having the blending composition described in Table 3 below by changing the blending amount of the alkylene oxide derivative. An evaluation test was conducted for 7). The test results are shown in Table 3.

(Table 3)

  In any case, it is excellent in all the evaluations (1) to (7), and the blending amount of the alkylene oxide derivative is preferably 0.01 to 15% by mass, particularly preferably 0.5 to 10% by mass. confirmed.

As described above, (a) an alkylene oxide derivative having a specific structure, (b) a sucrose fatty acid ester, (c) a polyhydric alcohol having three or more hydroxyl groups in the molecule, d) By blending an oil component, a gel cleaning composition excellent in use feeling and stability over time can be obtained, and further by blending a nonionic surfactant and / or an anionic surfactant. It was revealed that the cleaning effect and the feeling of use were further improved.
Hereinafter, although other examples of the gel-like cleaning composition concerning the present invention are shown, the present invention is not limited to this.

(mass%)
Maltitol 10.0
Sorbitol 15.0
Sucrose palmitic acid stearic acid mixed ester (degree of substitution 1.5) 2.0
POE (60) hydrogenated castor oil 2.0
Polyoxyalkylene-modified polysiloxane 1.0
CH ₃ O [(EO) ₅₅ (PO) ₂₈ ] CH ₃ (Block polymer) 2.0
Liquid paraffin 40.0
Tetra-2-ethylhexanoic acid pentaerythritol 10.0
Trioctanoic acid glycerin 10.0
Laurylmethyl taurine sodium 2.0
Sodium alginate 0.1
Fragrance
Appropriate amount EDTA-3Na · 2H2O
Appropriate amount citric acid
Suitable amount Sodium citrate
Suitable amount Purified water
Residue (Manufacturing method and evaluation)
The above components were mixed by a conventional method to prepare a gel-like cleaning composition. The obtained gel-like cleaning composition was safe and excellent in use feeling, particularly in phase inversion, ease of rinsing and stickiness, and excellent in stability over time and cleaning effect.

(mass%)
Diglycerin 10.0
Sorbitol 15.0
Sucrose oleate (substitution degree 1.25) 2.0
POE (60) hydrogenated castor oil 1.0
Polyoxyalkylene-modified polysiloxane 1.0
CH ₃ O [(EO) ₂₇ (PO) ₁₄ ] CH ₃ (Block polymer) 3.0
Liquid paraffin 35.0
Cetyl octoate 15.0
Lactic acid myristyl 10.0
N-myristoyl-N-methyltaurine sodium 2.0
Sodium alginate 0.1
Fragrance
Appropriate amount EDTA-3Na · 2H2O
Appropriate amount succinic acid
Suitable amount Sodium succinate
Suitable amount Purified water
Residue (Manufacturing method and evaluation)
The above components were mixed by a conventional method to prepare a gel-like cleaning composition. The obtained gel-like cleaning composition was safe and excellent in use feeling, particularly in phase inversion, ease of rinsing and stickiness, and excellent in stability over time and cleaning effect.

(mass%)
Triglycerin 15.0
Maltitol 15.0
Sucrose palmitate (degree of substitution 1.35) 2.0
POE (60) hydrogenated castor oil 2.0
Polyoxyalkylene-modified polysiloxane 1.0
CH ₃ O [(EO) ₂₅ (PO) ₃₀ ] CH ₃ (Block polymer) 2.0
Squalane 25.0
Methylphenylpolysiloxane 15.0
Dimethylpolysiloxane 15.0
POE-glycerin monostearate 2.0
Fragrance
Appropriate amount EDTA-3Na · 2H2O
Appropriate amount citric acid
Suitable amount Sodium citrate
Suitable amount Purified water
Residue (Manufacturing method and evaluation)
The above components were mixed by a conventional method to prepare a gel-like cleaning composition. The obtained gel-like cleaning composition was safe and excellent in use feeling, particularly in phase inversion, ease of rinsing and stickiness, and excellent in stability over time and cleaning effect.

Claims (4)

(A) a block-type alkylene oxide derivative represented by the following formula (I) and having a molecular weight of 1000 or more;
(B) sucrose fatty acid ester;
(C) a polyhydric alcohol having three or more hydroxyl groups in the molecule;
(D) A gel-like cleaning composition comprising an oil component.
(Chemical formula 1)
_{^{R 1 O - [(AO)}} m (EO) n] -R 2 (I)
(In the formula, AO is an oxyalkylene group having 3 to 4 carbon atoms, EO is an oxyethylene group, m and n are average addition moles of the oxyalkylene group and oxyethylene group, respectively, 1 ≦ m ≦ 70, 1 ≦ n ≦ 70 The oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group are added in a block form, and the ratio of the oxyethylene group to the total of the oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group is R ¹ and R ² may be the same or different and each is a hydrocarbon group having 1 to 4 carbon atoms or a hydrogen atom, and the number of hydrogen atoms relative to the number of hydrocarbon groups represented by R ¹ and R ² The ratio is 0.15 or less.)   The gel-like cleaning composition according to claim 1, further comprising a nonionic surfactant and / or an anionic surfactant.   The gel-like cleaning composition according to claim 1 or 2, wherein the amount of the alkylene oxide derivative is 0.01 to 15% by mass. The gel-like cleaning composition according to any one of claims 1 to 3, wherein the sucrose fatty acid ester has an ester substitution degree of 1.8 or less.