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IT1281195B1 - 2-idrossifeniltriazina di elevata durata, loro preparazione e uso per la stabilizzazione a lungo termine di materiali organici - Google Patents

2-idrossifeniltriazina di elevata durata, loro preparazione e uso per la stabilizzazione a lungo termine di materiali organici

Info

Publication number
IT1281195B1
IT1281195B1 IT95MI002019A ITMI952019A IT1281195B1 IT 1281195 B1 IT1281195 B1 IT 1281195B1 IT 95MI002019 A IT95MI002019 A IT 95MI002019A IT MI952019 A ITMI952019 A IT MI952019A IT 1281195 B1 IT1281195 B1 IT 1281195B1
Authority
IT
Italy
Prior art keywords
long
hydroxyphenyltriazine
lasting
preparation
organic materials
Prior art date
Application number
IT95MI002019A
Other languages
English (en)
Inventor
Vien Van Toan
David George Leppard
Gerhard Rytz
Norbert Wurms
Pascal Hayoz
Original Assignee
Ciba Geigy Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy Ag filed Critical Ciba Geigy Ag
Publication of ITMI952019A0 publication Critical patent/ITMI952019A0/it
Publication of ITMI952019A1 publication Critical patent/ITMI952019A1/it
Application granted granted Critical
Publication of IT1281195B1 publication Critical patent/IT1281195B1/it

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/76Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/815Photosensitive materials characterised by the base or auxiliary layers characterised by means for filtering or absorbing ultraviolet light, e.g. optical bleaching
    • G03C1/8155Organic compounds therefor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D251/00Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/14Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
    • C07D251/24Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to three ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/14Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
    • C08F12/26Nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/34Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F20/36Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06Hydrocarbons
    • C08F212/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02Monomers containing only one unsaturated aliphatic radical
    • C08F212/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/14Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04Acids; Metal salts or ammonium salts thereof
    • C08F220/06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42Nitriles
    • C08F220/44Acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52Amides or imides
    • C08F220/54Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/56Acrylamide; Methacrylamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F226/08N-Vinyl-pyrrolidine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F226/10N-Vinyl-pyrrolidone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/48Stabilisers against degradation by oxygen, light or heat
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • C08K5/34926Triazines also containing heterocyclic groups other than triazine groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Wood Science & Technology (AREA)
  • General Physics & Mathematics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Hydrogenated Pyridines (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Silicon Polymers (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Materials For Photolithography (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
IT95MI002019A 1994-10-04 1995-10-03 2-idrossifeniltriazina di elevata durata, loro preparazione e uso per la stabilizzazione a lungo termine di materiali organici IT1281195B1 (it)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH298994 1994-10-04
CH303994 1994-10-10
CH36495 1995-02-08

Publications (3)

Publication Number Publication Date
ITMI952019A0 ITMI952019A0 (it) 1995-10-03
ITMI952019A1 ITMI952019A1 (it) 1997-04-03
IT1281195B1 true IT1281195B1 (it) 1998-02-17

Family

ID=27172042

Family Applications (1)

Application Number Title Priority Date Filing Date
IT95MI002019A IT1281195B1 (it) 1994-10-04 1995-10-03 2-idrossifeniltriazina di elevata durata, loro preparazione e uso per la stabilizzazione a lungo termine di materiali organici

Country Status (17)

Country Link
US (2) US5672704A (it)
JP (1) JP4126400B2 (it)
KR (2) KR960014109A (it)
CN (1) CN1070186C (it)
AT (1) AT405515B (it)
AU (1) AU698297B2 (it)
BE (1) BE1008871A5 (it)
BR (1) BR9504276A (it)
CA (1) CA2159694A1 (it)
CZ (1) CZ255695A3 (it)
DE (1) DE19536730A1 (it)
ES (1) ES2106684B1 (it)
FR (1) FR2725204B1 (it)
GB (1) GB2293823B (it)
IT (1) IT1281195B1 (it)
NL (1) NL1001338C2 (it)
SK (1) SK123095A3 (it)

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US6297377B1 (en) 1998-06-22 2001-10-02 Cytec Technology Corporation Benzocycle-substituted triazine and pyrimidine ultraviolet light absorbers
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WO2000014076A1 (en) * 1998-09-04 2000-03-16 Ciba Specialty Chemicals Holding Inc. Process for making 2,4-dihydroxyphenyl and 2-hydroxy-4-alkoxyphenyl substituted triazine compounds
TWI259182B (en) 1998-11-17 2006-08-01 Cytec Tech Corp Process for preparing triazines using a combination of Lewis acids with reaction promoters
EP1144496B1 (en) * 1998-12-23 2004-03-17 Ciba SC Holding AG Polymeric stabilizers having low polydispersity
KR20010106124A (ko) 1999-04-12 2001-11-29 이와시타 마사히로 고분자재료 조성물
US6191199B1 (en) * 1999-05-03 2001-02-20 Ciba Speciatly Chemicals Corporation Stabilized adhesive compositions containing highly soluble, high extinction photostable hydroxyphenyl-s-triazine UV absorbers and laminated articles derived therefrom
US6867250B1 (en) 2000-10-30 2005-03-15 Cytec Technology Corp. Non-yellowing ortho-dialkyl aryl substituted triazine ultraviolet light absorbers
US6855269B2 (en) 2001-11-09 2005-02-15 Cytec Technology Corp. Phenyl ether-substituted hydroxyphenyl triazine ultraviolet light absorbers
WO2003046068A1 (en) * 2001-11-30 2003-06-05 Ciba Specialty Chemicals Holding Inc. 2-hydroxyphenyl-s-triazine crosslinkers for polymer networks
JP2004099115A (ja) * 2002-07-16 2004-04-02 Misawa Homes Co Ltd 木質様成形品、製造装置及び製造方法
ES2262033T3 (es) * 2003-01-09 2006-11-16 Alcon, Inc. Absorvedores de luz uv con doble funcion para materiales de lentes oftalmicas.
US7279527B2 (en) * 2005-04-22 2007-10-09 Bridgestone Corporation Method of converting anionic living end to protected free radical living end and applications thereof
RU2418791C2 (ru) 2005-06-10 2011-05-20 Циба Спешиалти Кемикэлз Холдинг Инк. Гидроксифенилтриазины, содержащие ароматическую карбоциклическую конденсированную кольцевую систему
US20080008620A1 (en) * 2006-06-23 2008-01-10 Alkis Alexiadis Bimodal light bulb and devices for sterilizing and cleansing
US7560509B2 (en) * 2006-12-29 2009-07-14 Bridgestone Corporation Method of directing grafting by controlling the location of high vinyl segments in a polymer
US8030410B2 (en) * 2006-12-29 2011-10-04 Bridgestone Corporation Method for generating free radical capable polymers using carbonyl-containing compounds
US7737218B2 (en) * 2006-12-29 2010-06-15 Bridgestone Corporation Method for generating free radical capable polymers using tin or silicon halide compounds
US7396887B1 (en) * 2006-12-29 2008-07-08 Bridgestone Corporation Insitu removal of chelator from anionic polymerization reactions
US20080157641A1 (en) * 2006-12-31 2008-07-03 Rachael Wren Grout Multi-use Free Standing Seating and Storage Unit
JP5342442B2 (ja) * 2007-07-13 2013-11-13 昭和電工株式会社 トリアジン環含有高分子化合物および該高分子化合物を用いた有機発光素子
CN102292397B (zh) 2009-01-19 2014-12-10 巴斯夫欧洲公司 有机黑色颜料及其制备
JP5613481B2 (ja) * 2009-07-29 2014-10-22 富士フイルム株式会社 新規なトリアジン誘導体、紫外線吸収剤
JP2012114125A (ja) * 2010-11-19 2012-06-14 Fujifilm Corp 太陽電池封止材及びそれを用いた太陽電池モジュール
WO2013083565A1 (en) * 2011-12-05 2013-06-13 Arizona Chemical Company, Llc Uv-protecting rosin
EP2888058A1 (de) 2012-08-23 2015-07-01 Bayer Materialscience AG Gasphasenabscheidung organischer uv-absorber auf kunststoffsubstraten
SG11201504889VA (en) 2012-12-20 2015-07-30 3M Innovative Properties Co Fluoropolymer composition including an oligomer having an ultraviolet absorbing group
US9593088B2 (en) 2013-02-01 2017-03-14 Covestro Deutschland Ag Method for producing a polymerizable UV absorber
CN104955910A (zh) 2013-02-01 2015-09-30 拜耳材料科技股份有限公司 可uv固化的涂料组合物
WO2015200655A1 (en) 2014-06-25 2015-12-30 3M Innovative Properties Company Fluoropolymer composition including at least one oligomer
WO2015200669A1 (en) * 2014-06-25 2015-12-30 3M Innovative Properties Company Pressure sensitive adhesive composition including ultraviolet light-absorbing oligomer
US11110689B2 (en) 2014-06-25 2021-09-07 3M Innovative Properties Company Pressure sensitive adhesive composition including ultraviolet light-absorbing oligomer
KR20180021094A (ko) 2015-06-25 2018-02-28 쓰리엠 이노베이티브 프로퍼티즈 캄파니 자외광-흡수 기를 포함하는 공중합체 및 그것을 포함하는 조성물
WO2018216750A1 (ja) * 2017-05-25 2018-11-29 株式会社Adeka トリアジン化合物、硬化性組成物、硬化物の製造方法およびその硬化物
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CH484695A (de) * 1962-10-30 1970-01-31 Ciba Geigy Verwendung von neuen Hydroxyphenyl-1,3,5-triazinen als Ultraviolettschutzmittel ausserhalb der Textilindustrie
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CH469053A (de) * 1963-07-26 1969-02-28 Ciba Geigy Verwendung von neuen Hydroxyphenyl-1,3,5-triazinen als Schutzmittel gegen Ultraviolettstrahlung für nichttextile organische Materialien
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DE59208921D1 (de) * 1991-06-03 1997-10-30 Ciba Geigy Ag UV-Absorber enthaltendes photographisches Material
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DE59208885D1 (de) * 1991-09-05 1997-10-16 Ciba Geigy Ag UV-Absorber enthaltendes photographisches Material

Also Published As

Publication number Publication date
NL1001338A1 (nl) 1996-04-04
CA2159694A1 (en) 1996-04-05
DE19536730A1 (de) 1996-04-11
AU698297B2 (en) 1998-10-29
ATA163695A (de) 1999-01-15
FR2725204A1 (fr) 1996-04-05
AU3304995A (en) 1996-04-18
KR100496131B1 (ko) 2005-06-17
GB2293823B (en) 1997-01-22
KR960014109A (ko) 1996-05-22
CN1130625A (zh) 1996-09-11
AT405515B (de) 1999-09-27
FR2725204B1 (fr) 1997-06-06
SK123095A3 (en) 1996-06-05
US5869588A (en) 1999-02-09
GB9520046D0 (en) 1995-12-06
CN1070186C (zh) 2001-08-29
BR9504276A (pt) 1996-10-01
GB2293823A (en) 1996-04-10
JPH08259545A (ja) 1996-10-08
ES2106684B1 (es) 1998-07-01
ITMI952019A1 (it) 1997-04-03
CZ255695A3 (en) 1996-04-17
US5672704A (en) 1997-09-30
NL1001338C2 (nl) 1996-04-12
BE1008871A5 (fr) 1996-08-06
ITMI952019A0 (it) 1995-10-03
ES2106684A1 (es) 1997-11-01
JP4126400B2 (ja) 2008-07-30

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