HUT68199A - Composition, and procedure for manufacturing of foam material, and foam material made by this procedure - Google Patents

Abstract

The subject invention provides a urethane foam which does not require chlorofluorocarbons to manufacture and which conforms to the Montreal Protocol. The compositions of the subject invention are usable in a spray and a pourable form, and may be used in a variety of applications such as in the production of siding, shingles, building panels, marine floatation, and roofing materials.

Description

The convention signed by most industrialized countries in 1987, the verb Ilont r ca ii Jc contains food for use in the production of chlorine, which is used in the production of urethane foam in 1998. the amount is reduced by half. It is expected that by the summer of this year, the use of chlorinated and fluorinated hydrocarbons will be completely banned by tightening the Convention. In addition, the mild repressor of k / mibMn found the transmitters of such topical tfimms. Therefore, other sources of materials for the production of foam should be used. The currently used substitutes for chlorinated and fluorinated hydrocarbons increase the cost of producing urethane foams. Accordingly, there is a need for a cheap process for producing these foams.

The present invention provides a composition which, when combined with the phenyl phenol 1-methane diisocyanate, provides a hard foamed material. The present invention provides a water-foaming material having a density of 4.86-81 kg / m ³ or more useful for industrial application. In summary, the invention provides a low cost, environmentally safe alternative to conventional urethane foams.

A t a 1 á I v ν y ο 1 y n ur> -1 ar h a b o t la i z t o r s, m c 1 y n e k to produce aie-s; / Ik ség ség kl í kl / / / att att att i i i i.

The bowl 1 1 m ′ a egy egy ikk ikk 1 1 1 ak) 8 8 8 8 8 ak 8 8 8 8 8 8 8 1 8 8 1 8 ak 1 8 8 c 0 1 aid ζ ^- ο x ι 1 sz; a 1; x; x ι χ lki 1 · 'a * rt ρ ο 1 i ο it,

b) a chimney polyether polyol, polyester polyol or oxyalkylated bisphenol A,

c) agent vX'S surfactant, d)> ιη ι ι O. · T a i i a. .a t o r t,

(e) polé ι1οc1 n i t h i n g i n g i n g i n g

f) quartz crystallization of the inaniline salt or triazine at 1 m a z.

Another embodiment of the invention

a) 28-84) 0 hydroxy-substituted polyol,

(b) Kemeag polyether polyol, yoi: ίχ? tm -1aί? ai χ ipy οχ ίχ ü) ikreit bi'i / foiiol A,

c) a polyalkylene oxide / methyl siloxane copolymer,

(d) an amine catalyst,

(e) a polyisocyanurate catalyst; and

f) a glaze containing a quaternary ammonium salt or a triazine.

The compositions of the invention form a foam when polymeric diphenyl 1-methane diisocyanate 1 (MDI) or other suitable isocyanates known to those skilled in the art, such as hexamethylene diisocyanate 1, phenylene diisocyanate 1, toluene diisocyanate, 4,4 ' di-diphenyl-inetane diisocyanate, 2,4- or 2,6-1 to 10-ol isocyanate 1 or commercially available mixtures thereof. Diisocyanates are other known MDI search transcripts, mrlyck onecb i / nmr and analogue, which are also known as clegym papi rhymes. t. take 11 a 1 ma / r. containing a pre-reacted partial reaction of k, F ⁷ ene with an ether or polyester polyol.

In an embodiment of the present invention, the present invention is blended with a 1: 1 mixture. a polymer MDI plate, but the machine is smaller in color than the ratio of the color or the net _; rcg i> en also leaked. MDI is known in the state of theomol to be used for the production of oodlibers and polyols. At 1: 1 parts by weight, MDI is present in an amount smaller than the stoichiometric ratio. MDI and 1 '>? / <1 h mixture known in the shererocr, known as filter-smear qyobb molecule 1 rn 4,4 '· -dif'

·. 1 1 / mi 1 is the price of O, i z oc i your sons and can be obtained using sorting.

Accordingly, the present invention provides a composition for the manufacture of a foamed material which is

a) oxyalkylated polyols having a hydroxy number of 28 to 800 hydroxy;

b) hard polyether polyol, polyester polyol or oxy-1-alkylated bisphenol A,

(c) an organic surfactant or a polyalkylene

oxide / methyl1-siloxane copolymer,

(d) an amine catalyst,

e) a polyisocyanate catalyst or a polyisocyanurate catalyst;

catalyst and

f) a quaternary ammonium salt or ti : i a z i nt component c) is an agent. contains the proviso that that if f - P i e 1 ü 1 c t a k t í v: <ny a q, λ k k o r. -i 7 p.m. evpenens ρο1 i j ζ o c i a - ι> á t “k Which is a liter and if c) k Cg [gp Q! í '· í 1 S after 1 i a] kI lés oxrd / me 1 i 1 s z i 1 oxane k οpο 1 i rner, then the e) Cor ipinens after i i i zoc ianu ..... r z t k - = odi iát or. SUMMARY OF THE INVENTION Ί 1 - JC. .'d; TGI jyik va.it.ozat the

a) oxyalkylated polyols having a hydroxy number of 28 to 800,

b) Chemically polyetherpolyol, preferably greater than 3.0, mcg advantage, bben 3.8 to 1 higher f · ι nkc - ι o 1 itasuf> o 1 i - after 1 ol, after J 1 est er -po! ι o j t. or oxia Icylated bisphenol A,

(c) organic active principle .vvyacjot,

(d) an amine catalyst,

ο) a polyisocyanate catalyst and

(f) quaternary ammonium salt or tri in int ⁴ οη, ζζ. Drinking the oziikiLi Poly 1 f iokc a n d i n g 2-Ί, '>> vi a 1 k í 1 azet t he polyol still e 1 s a n n cxia J off J set gJ' cc .....

rin. The above composition is mixed with water and the individual components are present in an amount such that the composition is blended with diphenylmethane diisocyanate or other suitable isocyanate to provide a foamed material.

In preferred embodiments of the invention, the individual compounds are present in the amounts indicated below.

The oxyalkylated polyol having a hydroxyl number of 23 to 800 is present in an amount of 1 to 80% by weight of the composition. The oxyalkylated polyol is a viscosity modifier.

The most preferred compound of this type is LHT-240 Commercial (manufactured by Union Carbide).

The composition should include a hard polyether t c r p; ο 1 i <; 11 v a g y o x j a 1 k /: z a 11

A - t. 11 a λ ι · .η o ny ρo 1 i e t e i po 1 i olt 11a s z rí a 1 u 1ik, a i <: <a κ m c i; g is 20 - / o% by weight based on the small amount of thyme. A hands-on pjl i her -r-pa * drink a month 1 oza 1 ϊ ti-a o 'oxy 1 aga

3.0, most preferably at least 3.8. A preferred compound is a

350X. can be used (manufactured by Arco Chenical). This compound is a hard polyol which is useful for light days in this ion; Likasa shampoo, ja t? O 1 a.jgpi vant in terms of securing crosslinks.

a p c> 1 i and s. t e r pz ο 1 i ο 11 our water bag, r China k m ο η a y i s c- g e for the weight of the composition. Most preferably, the polyester polyols are based on terephthalate-based materials such as polyethylene terephthalate or dimethyl terephthalate. In this space, phthalates of your phthalothes should bobble the bottles of lo 1 collected as loose seeds. The most preferred dimethyl terephthalate is commercially available as j'ERA'1E-203 (manufactured by:

Cape Industries)

polyols in themselves and CHARDONAL-570: Oxid Chemicals, may include them under the trade name

Inc.). Polyester compounds which have an excess of dicarboxylic acids such as adipic acid in ethylene glycol or butanediol or an excess of lactone in walnuts such as

Claims (20)

The hydroxyl number of the polyester polyols is generally 100-700, preferably 100-400, the average value of the functionality 1-8, more preferably 2-3. xially substituted bisphenol A is used T ^{h e} substance ⁽ 177 ^c C) the foamed pathway is prepared organic surfactant composition can be determined. however, organ type surfactants The most preferred compound is the commercial product I.K-443 (manufactured by Air Products). Surface Curl The amine catalyst is present in an amount of 0.1 to 10.0% by weight of the composition. The preferred amine catalyst is N, N-dimethyl-cyclohexyl-1-amine. This compound, also known as polycat-8, is available under the trade name PC-8 (manufactured by Air Products). The amine catalyst initiates the r auction of the above composition with the isocyanate. Tertiary and delayed-action amines such as triethylenediamine and triethanolamine may also be used. Any compound of this type may be used as a polyisocyanate catalyst. However, the polyisocyclate catalyst preferably contains lead, so that it can be 24 wt.% Lead lead, which is 0.15.0 tcRC-p by weight of the composition. Other heavy metals hmi'al .-. I / h Patalysis, so tin at 1 i z. oh ok, plus k · ',! ium ...... catalysts may also be used. Water 0.4-0-0% by weight of the composition ...... A quaternary cmmcn luminal salt and / or triazine is a key component in providing a stable, low-density, water-foamed material. The quaternary ammonium salt precursor yes 1MR, on the guard n a cj y C 'b' 7 *: q y ü j t such that boly c a t 41, P ο 1 y - (.at 4 3 or Dabco li Β .ι. s h a s z n a 111 · : s. 7, -p. AV ¹ '1 , Oh 1, f, Z is C-. Γ i A t '1 7: 7η A  1 A S A j A: j y A A; A A] 7 5; /,; t A 1 1 b'- i TMR - which k <1 Γ bo ΙΊ S av quaterner í nnmonium salt - the composition is present in an amount of 0.1 to 3% by weight. TMR Trimerization Catalyst, available as TME1, TMR2, TMR3 and 1ER4, is available as Eede .1n (manufactured by Air Products). In your commercial trade, the greater the number after the TMR, the slower the reaction. The most preferred embodiment is a sprayable foam comprising: 47.50% by weight LHT-240, 47.25% by weight 350X, 1.00% by weight LK-443, 0.25% by weight PC-8, 0.20 24% lead naphthenate, 2.80% water and 1.00% NMR. The first embodiment of the present invention may also contain one or more flame retardants. Various flame retardants (including smoke suppressants, swelling compositions and coatings, anti-drip agents, and the like) may include, inter alia, the use of rhyme in 1 rhm of zinc, such as ammonia f OCT é sm ο η OAM _π, O η iam - phosphonic OCT me 1 am int, tetrakis ( '2 - - k 1 h r et i J) et ί 1 i - phosphonic braid _t yen jowl om i feminine female, 11 1 sz (1,3-dß k1o r-ρr o pi1) fos 2 fat ot, t ris ζ (β-k1o re t i1) -f os ató1ató., píOi 1 Jaz! é ís-t r iox j <1 ot, ninmo. n - ΪΊΟ 1 iboatot, dot .al o-az S i f i i i salt salt, i. r, i ka ez il phosphate, 2. id 11 ot ó ~ i-; > egoneol, hexyl bromodicyclododecane, dibromo-1-dibromo-cyclobenzene, tris (2,3-dibromopropyl) phosphate, tris (B-chloropropyl) ) containing phosphate, halogenated hydrocarbons, such as Chlorowax / 0KeKeCodeodorl, tetrachloride, i ... o · nj i am iot, sludge, or biuret. The most advantageous flame retardant material has the advantage that it is cheap and can even be used in fertilizer quality. The present invention also provides a copolymer composite for the production of foamed material (a) 28 800 hydroxy-1 hydroxy-fused polyols, b) a hard polyether polyol, preferably having a functionality of at least 3.0, most preferably at least 3.8, and A polyether polyol having a hydroxy number of 250-800, a polyester terpolyol or an oxyalkylated bisphenol A, c) a polyalkylene oxide / methylsiloxane copolymer, (d) an aminkal damper, e) a polyisocyanurate catarrh; (f) it contains a quaternary ammonium salt or a triazine. The functionality of the oxyalkylated polyol is preferably 2-4, most preferably the oxyalkylated polyol is oxyalkylated glycerol. The above composition is mixed with water, and each component is preferably present in an amount such that it diffuses with 1 me ¹ : ene-O- ¹ O 1 or other isocyanate in foam. In preferred embodiments of the second embodiment, for each of the compounds, the number ^of times discussed in á a is 11 κ jci ο Ώ. The oxyalkylated polyol having a hydroxyl number of 28 to 800 is present in an amount of from 1 to 80% by weight of the composition. Preposition requires either a poly cl p-1, a pom ester - a p ol or an oxyalkylated bisphenol A. 11 the hard polyether pmjiol.í we use is the Reiriras io toc. gere vctritkoz is present in 20-70 wt. The hard polyether polyol preferably has a functionality of at least 3.0, most preferably 3.8 and a hydroxy number of 250-800. This compound has a lexelicity value of 4 vm '-.oré ^ fy; os / u. * '' _{, 1} y (manufactured by Ol in Corp. or ion). If polysterol polyol is used, it will be present in an amount of 5 to 80% by weight of the composition. Most preferably, terephthalate-based polyester polyols such as polyethylene terephthalate or dimethyl-terephthalate are used. These terephthalates can also be provided from bottles and fibers collected as waste. The most preferred alternatives for dimethyl 1-terephthalate would be TERATE-203 (manufactured by Cape Industries) and CHARDONAL-570 (manufactured by Oxid Chemicals, Inc.). Polyester - polyols may also include those compounds in which a dicarboxylic acid diol excess etje such as adipic eti1én glycol or butanediol, or laklomnak s> o] phenyl 1 e ^c? 1 θ'iá ve 1 so caprolactone propi1én-G11 ~ lal 1 e c o f 1 o c h · a Change e 1: our púnk. The hydroxy-1 number of the polyesters of the polyester is generally 100-7. 0, banya-vm 100-4 00, a v-gyu lv? + - k itlvjos f snk tm on I i] 8, i ~ 1 Cm j y π 2 · ->, When oxia J.kylated bisphenol A is used, it is present in an amount of 50-95% by weight. Oxyalkylated Bisphenol The use of the foamed material makes the final product stable at temperatures above 177 ° C. Accordingly, with the use of oxyalkylated bisphenol A, the high lyomate (1) + u. cioyag. The alkyl alkene-oxide / methyl1-siloxane copolymer is present in the composition in an amount of 0.5 to 4.0% by weight. The pasture advantage & ch '. compound is L-5420 (q n lake company: Unión Cbr'side). The L-5420 improves mixing conditions and delivers fine cell structure. The amine catalyst is used in an amount of 0.1 to 10.0% by weight of the composition. Water was contained in the composition in an amount of 0.4-80% by weight. The polyisocyanurate catalyst in the composition is 0.5 to 4 It is present in an amount of 12 to 1.5% by weight. The most preferred catalyst is Curithane 52 (manufactured by Air Products). This compound has a positive effect on the final heat treatment, and also increases adhesion and thermal stability. In a preferred embodiment of the invention, the quaternary ammonium salt NMR, which is present in the composition in an amount of 0.1-3.0% by weight of the composition, is &quot; P &quot; .i CP Ώ 3 '1' MR Ί C can be TMR 1, TMR? ORR 3 v _{f d} .gy four TMR merchant Imi nova produces monyként. The second embodiment of the invention is characterized in that one or more of the alkaloids may also be eliminated. Various flame retardants (including anti-foaming agents, swelling compositions and coatings, drip inhibitors, and the like) include, but are not limited to, 1 k: I Na za L n nk u u i o l i ... d phosphate such as ammonia min. jro 1 ifosphate and monoammonium um-phosph ht, melamine, tetrakis (2 - k 1 reaches) ..... ot i 1 i ...... f ο ·. · z phonate _L a _{: f} gon t. > g _r om-d if on i 1 - ox i doth, iris (1, 3 ..... di k1 guard ..... propi1) -phosphate, tri (β-chlorine i1) ) -phosphate, molybdenum trioxide, ammonium molybdate, pentabrate-d if en i-ox time, t.resresil phosphate, 2,3-dibromo-pr opao l, hexT oone ...... czk , dabr hmc.ti 1- cli br om-c ic i b.exane, tris (2,3-di-bromo-propi J) -1'-phosphate, tris (B-chloropropi-1) -phosphate, a halogenated hydrocarbon such as Chlorowax 70, dicyandiamide, oxamide or biuret. The most preferred flame retardant is monoammonium phosphate. Monoammonium boiled wood has the advantage that it is cheap and can even be used as a fertilizer. Thus, the present invention provides a foamed material comprising, in addition to one of the two compositions discussed above, difcnni-methane diisocyanate or other suitable isocyanate. The first composition is preferably a sprayable composition which is preferably pourable in the roofing and the insulatingA second composition. The reaction mixture is mixed with diphenylmethane diisocyanate or other suitable isocyanate. X 1; e r e t k t h e description of 1 s zeniéi t e t g í j k. F i s e r 1 e t i i s z Gy · Gyo ma jiyosui ο ⁽ a''hala> Kha na slight suture is provided by the use of chlorinated and fluorinated blowing agents. The use of water-blown materials up to now is higher density foam materials, ie 162 kg / m ³ or less ¹ dd It is limited to the production of foam materials having a specific gravity which is due to the fact that the isocinolate is used for the reaction with water and thus for the production of CO _2. In contrast, the invention preferably uses a low density foam with a lower density than the stoichiometric ratio material. In the next section of the description, index 100 * · «· 1: 1 sto) denotes an ioreetric ratio. Prior art urethane foams have an isocyanate index of more than 100. The higher the value of the index, the greater the excess of the first component, namely the isocyanate. Foam material samples were mixed by varying proportions of polymer MDT (page A) and the preferred sprayable foam formulation of the invention (page B). The alk ο ι ore? z <: k falon no zoaraay ν ι r. eve icsevei e 1 oa 1 ι 11 e ct, <d> í í. ± - pushed substances for low and high rise i sex let u visíakecies -pori i more 1 a 1 í - i 1 ak A 'a 1 a a r _: yazaradn napoz 1 0 1 n 1) a? 1 o vctkez0 K Giiip · - Π r ii ' ¹ ' 4 7, 5 0 1 .. (Jj i 'í? KJ C BHT -2 4 0 4 7, 2 5 crowd% 3500 1.00 t old% LK-4 4 3 0.2 5 t% by weight PC-8 0.20 törogP 24 pounds 0 s he 1 0 n n a f t c- 5 4- w | WATER 1.00 w | TMR-3 As a control material, the control composition B, although not known in the art, containing a typical water-foamed material, containing the above composition c-powder a-ni s t pnii, contains a bionarazole h 7 iqy sapntt. The following values of the A / B ratio were examined: ·> ·· · * · «» «•» c: * »··» · · «· *» * «n» A / B Isoc i anat-i ndex 60/100 80/100 100/100 120/100 140/100 10 0 1 17 roe 'she -zC? - a% G i nex 3 el ^;, el'iyí be m υ a 'í ·! _{; ;} pf t Ϊ + í '1 i' ·] if you hero five a n \] ot * .c. · í ί t o 0 · Ο msei ' yot ^f e J "· R e / a 1 i v wet r'égt in drtahsú space 22 ^J C temperature ékletí n 2 4 hrs: thanks r o s z t ü 1 u t. old-fashioned Ithnk. THE )>, Ϊ b 1.5 C 1011 oriyeg two x o i o z <i t a t v i a z a. L t a. k , az p ^{ ^ yi κ a ta ; the 1 year Gums like that ! 11 i e ' i-oyos , S / órható U 1.> Y. j:,, benzene oh, ski writing k oc • d 1 g e, yeah, zen 7 k ο o i oz í c i oh a 1 MR-3 k's bosom x les n é 1 b _Ώ i. The Z killing / heokbcn down home cook that V i z sg ó 1 a t i maternal qokból b 0 , 8 htib elhass zus pany ú cube at end c> ok, a a e  1 y c · k e t It was tested at ~ 6.7 ° C. Another set of patterns It was studied at 121 ° C. The results are summarized in Table 1. »· · · · · · · · · · · · · · · · · · · · · · · · · · · · · -161_. spreadsheet A / B ratio I zoc i anát-i ndex Shrinkage At -6.7 ° C without NMR-NMR relay Time to onset of shrinkage at 121 ° C with TMR without TMR 60/100 5 0 . ~ i 'η. , * t. A HJ \ {? 1 y _ * <1 hour v n / ion 07 ... * V A 1; * * 1 '7 1 i ο ó / 1 0 0 8 3 > OS ok v Arc * * ' 6 hours 12 0/1 0 0 100 _ * _ λ c s c. 1: h 1 y * 140/100 1 17 __ THE k * 18 days after completion of the study The above experiments illustrate that they are unsuitable for water solubilization, while the liposins of the present invention provide a lighter foam material which is useful for industrial use, using a lower amount of stoichiometry relative to the stoichiometric ratio. The pourable foamable composition of the present invention, when tested under similar conditions, produces similar redemenes. although we have done quite a bit of detail on the tara i many t berry cummy versions, other versions are possible. Therefore, the spirit and scope of the appended claims are not limited by the preferred embodiments disclosed herein. ···· * «·« 4 · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · «· · 1 7 S 2 A B A D A LM I REQUIREMENTS 1. Composition for the manufacture of a foamed material, z a 1 j e 1 1 this is how the) 28-800 hydroxyalkyl oxyalkylated polyols, r) karion pol ifer-pco iol, pol (ester ..... pol isit vaey o x i a 1 k i] f- · / í 1 f b i s z f e η o 1 A -1, c) .g ·. organic surfactant or pol 2 a lk j len "ί X Ϊ ds X (X" i 1 - X. 7 Ί 1 XXX 7 \ k 'é X> 0 ^Ί J x; xrk XX; A HKx t X 2 / X f Xl t, X polyisocyanate catalyst or polyisocyanate - catalyst and She k vitet 'n c v a m m i n i 11 m s ó t v a q y t r 1 a z i n t t alt a ί a a z , with the ancestor that if component c) as a surfactant, component (e) is a polyisol (. Na t catalyst) and if component (c) is a polyalkoxy d / met. 1-to-1 oxane copolymer, then component (e) is a poly (z) c i n g i n g - 1 1 z a n d. The composition of claim 1, wherein said composition is. that a) 28-Synthesis: oxy Isopropyl oxy is a polyol of J.kXl, b) hard polyether polyol, polyester polyol or oxyalkylated bisphenol A, c) organic surfactant, d) aminkata, (e) a polyisocyanate catalyst; and (f) quaternary ammonium salt or triazine ». · · 4 ···· · · ·· «*« • · «» · · · · · · · - 18 included. Composition according to claim 2, characterized in that the oxyalkylated polyol, hard polyether polyol, polyester polyol or oxyalkylated bisphenol A, organic surfactant, amine catalyst, polyisocyanate catalyst and quaternary ammonium salt vaqy t rh / i r; t. c 1 i fon i 1 - m e t á a i - cl i j zoc í a na tt a 1 1 c- f rí 'y t a + < -v-1 k e - v - i. e s after habi e s í t o 11 .> Nyaq (k c 1 1 k tz z {. s e z triggering standard O> end- b is t .. <11 b a .1 iVid / z < Δ A A verb ¹ y t- mnt Ke '~ P ο z í c i ó, a z z a j e 1 1 e m e z V e, r,  '' -'- i 1 cl K'én ροζ j o i oh you can a a t κ O Z - It contains from 1 to 80% by weight of oxyalkylated polyol. Composition according to claim 2, characterized in that, by weight of the composition, l 0 '/ 0 fos e g -6 ί. o incny j. · o i i e t e r g ο 1 ι o i t tarts l m z. 6, THE 2 . claim according to a z z a 1 signal 1 e m e z v e that a k c 'η; g <> z i te r ó t. o m ege · r e v ο n a t k g z - t. a t. v a 5-8 0 crowd % ρ o 1.1 e s z t. c Contains' r-ρο1iol. 7th THE 2 . claim according to a z z a 1 signal 1 e honey v e that the weight of the composition vonatkoz- t t a ZC -9 n i. e. e % ox i a Ik 2 i farit bisphenol A tar t a J m a z. The composition of claim 2, wherein the composition comprises from 0.5% to 4.0% by weight of the organic surfactant. 9. The composition of claim 2, wherein the composition comprises from 0.1% to 10.0% by weight of the amine catalyst. 10th The composition of claim 2, wherein the polyisocyanate catalyst is present in an amount of from 0.1% to 5.0% by weight of the composition. Contains 24% by weight of lead naphthenate. signal The composition of claim 13, wherein the signal is braided, oxo-doped, m-ammonium-β-molar phenyl-oxide, tri- 3 - dibromo - propa η ο 11, dean, di-bromoethyl-1-dibromocyclohexane, arabipyl} thiophosphate, isos (β-chloro-pt opyl) isostate, baloge not / there containing hydrocarbon, dicyandiamide, oxamide or biuret. 15. A Composition according to claim 14, characterized in that it contains ammonium phosphate as a flame retardant. The composition of claim 1, characterized in that a) oxyalkyl polyols having a hydroxyl number of 23 to 800, b) hard polyether polyol, polyester polyol or oxyalkylated bisphenol A, c) a polyalkylene oxide / methylsiloxane copolymer, (d) aminkata 1, e) μυ1i1z oc i a11 u ι á t t 1 1 zátω t and (f) Quaternary water DRINK or TRI a z int cake ] r <(' _:: / 17th Claim 16 seried kei. £ _> 1 O i ó f cl Z Z a signal 1 e m e z v e that i Z Ο X 1 3 1 K 1 ι Ό QTt pC1 i O j t K t receipt pollen V r ..... p V 1 i ο 1 t, p C> 1 1 year z i - j ροΊ ι ρ · Ί t or ox i a 1 k i. ' dt b d f o vial A, polyalkylene ox j d / met i1 —s ziloxane copolir got it am i nka Lysator, polyisocyanurate cat.) And quad r n e r ammonium i bobbin or triazine d i feni 1 methane - d i i z o c i a n á t. bowl juice- 1 o j yi .. < tov.r Mix uranium if iveitou any. i g Kde t de c e r i r - 11 am m c η n y i s c g 1> c n tar t a 1 m <> Z Z 3 * 18. The 16th Claim Garden . z What is it? position, z a signal 1 e m e z v e that a k {j π ρ o z 5 c .i ó mass of train what z - t atva 1-80% by weight of oxyalkyl polyol contain. 19. The method of claim 16 according to z a It is noted that the kmp.zicio tciegete contains from 20% to 70% by weight of hard polyether polyol. 20. The composition of claim 16, wherein the composition comprises from 5% to 80% by weight of the polyester polyol. 21. The composition of claim 16, wherein the composition comprises 50-95% by weight of the oxyalkylated bisphenol A. 22. The composition of claim 16, wherein the composition comprises from 0.5% to 4.0% by weight of a polyalkylene oxide / methylsiloxane polymer. 23. The composition of claim 16, wherein the composition comprises from 0.1 to 10.0 t / m of our molecule per 1mg. 24. The composition of claim 16, wherein the polycarbonate anatate sulfate is 0.1-5.0% by weight of the carcinolizing agent, with a final concentration of 24 µg / kg of lead naphthenate. n contains. 25. The composition of claim 16, further comprising water. 26. The composition of claim 25, wherein the weight of the composition is about 0.4 to about 80% by weight of the composition. 27. According to IG 16, it is a cosmopolitan process characterized in that it also contains flame retardant material in z. 28. The composition of claim 16, wherein said flame retardant is a mono-sulfuric acid, not a 1-amine, strain racis (2 x 1 hr-1) and a lene-f stimulant. pentabrone diphenyl 1-ox time, tris (1,3-d 1 hour-propyl) phosphate, tris (β-chloroethyl) phosphate, molybdenum trioxide, ammonium molybdate, pentabromodiphenyl oxide, tricresyl phosphate, 2,3-dibromopropanol, hexabromobromocyclododecane, dibromoethyl dibromocyclohexane, tris (2,3-dibromopropyl) phosphate, tris (β-chloropropyl) phosphate , halogen 2, hydrocarbon, dicyano diamide, oxamide, or buretate. 29. The composition of claim 16, wherein the flame retardant is aroyonium phosphate. 3 0. H anodized material, z z a character e z - v e, ] so 1. ί ij é nypont Serbian, i k c m po z í c horse and dog 11 ..... et al "I from i it is a sham. j 1. A 3 0. i g c 11 y ρ ο n t s z e < admonished a a jjo baked material, the z - z a 1 j e 1 1 e m e ζ v e, that the 2 . J í e <) yp ¹ 'rj 1 3 ¹ 0 e 3 A ii t 1 i é · c- ·· j Ί -! / .11 months L rUINS: 32. THE 31st The words of claim i n t i taboo baked material, the z - z a 1 j θ 1 1 e m e ζ v e, h zat dust <3 colorable composite í c above cases t ara a 1 ma z. 3? , A> bow - j ^; j A .í iy ρ ο I i t .. a. / t: ; i n t i ir-djos ΐ t there substance _; the z - zal sign plate, 5 'θ9Υ' i 16, i q í? rí y ρο n t s z t r> i n t i ferry z iobo 1 and di ken i 1 meteor i d i i / ( ό .. · ΐ a na t bo 1 a 1 1 34 ; r int i foam os í tottar ι ya ej _t the- characterized by a pourable composition for 1 m. 3 5. } i: ar <o: at · o - - *; I r,> n _y ag - 'ö aj 1; characterized in that the composition according to claim 1 is mixed with di fcn-1-methane diisocyanate. 36. The method of claim 35, wherein the composition of claim 2 is used. 37. The method of claim 36, wherein the diphenylmethane diisocyanate is used in an amount lower than the stoichiometric ratio. 38. A 35. claim a z z a 1 characterized e that a According to claim 16 composite- c i ó t. h a s z n ours. ú Ο Ά Q M ...) uh. claim s z e r inti on procedure, a z z a 1 sign plate v e, houy a d i f e n i 1 ..... m e t á n d i i r ο i i a n á t o t a to uf-rian gold, zopíst r, i sebb m Híiyiieijhen MATERI Ab iTiCHNOLOG I E'S & SC1ENCES Inc.. instead of an authorized representative: