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GB1311013A - Process for the polymerization of olefins - Google Patents

Process for the polymerization of olefins

Info

Publication number
GB1311013A
GB1311013A GB2864470A GB2864470A GB1311013A GB 1311013 A GB1311013 A GB 1311013A GB 2864470 A GB2864470 A GB 2864470A GB 2864470 A GB2864470 A GB 2864470A GB 1311013 A GB1311013 A GB 1311013A
Authority
GB
United Kingdom
Prior art keywords
aluminium
olefins
ethylene
magnesium
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2864470A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Farbwerke Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Farbwerke Hoechst AG filed Critical Hoechst AG
Publication of GB1311013A publication Critical patent/GB1311013A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1311013 Polymerizing olefins FARBWERKE HOECHST AG 12 June 1970 [12 June 1969] 28644/70 Heading C3P Low molecular weight olefin polymers are prepared by solution polymerization of olefins at 110‹ to 180‹ C. and pressures up to 50 atmospheres in the presence of a catalyst comprising (A) a reaction product of a titanium tetrahalide and a magnesium alcoholate and (B) an organo aluminium compound and hydrogen as molecular weight regulator in such an amount that the waste gas remaining after polymerization contains at least 60 volume per cent of hydrogen. Specified olefins are ethylene, propylene, butene, pentene, 4-methylpentene-1 and octene-1. The magnesium alcoholate may be derived from methanol, ethanol, propanols, butanols or #- phenylethanol, and may be a half halide, sulphate or carboxylate. The aluminium compound may be an aluminium trialkyl or a dialkyl hydride or alkyl halide. The process may be effected batchwise or continuously in hydrocarbon liquids, and the products purified by treating with alcohols and/or steam distilling. Many suitable catalyst ingredients are specified, and examples describe the polymerization of (1 to 5) ethylene and (6) ethylene and propylene in the presence of catalysts formed from magnesium ethylate and titanium tetrachloride with (1, 2 and 6) triisobutyl aluminium, (3 and 4) diisobutyl aluminium hydride and (5) triethyl aluminium, or from (2) magnesium propylate and titanium tetraohloride with isoprenyl aluminium.
GB2864470A 1969-06-12 1970-06-12 Process for the polymerization of olefins Expired GB1311013A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19691929863 DE1929863A1 (en) 1969-06-12 1969-06-12 Process for the polymerization of olefins

Publications (1)

Publication Number Publication Date
GB1311013A true GB1311013A (en) 1973-03-21

Family

ID=5736796

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2864470A Expired GB1311013A (en) 1969-06-12 1970-06-12 Process for the polymerization of olefins

Country Status (10)

Country Link
AT (1) AT305619B (en)
AU (1) AU1617470A (en)
BE (1) BE751909A (en)
CA (1) CA919348A (en)
DE (1) DE1929863A1 (en)
ES (1) ES380594A1 (en)
FR (1) FR2051159A5 (en)
GB (1) GB1311013A (en)
NL (1) NL7008604A (en)
ZA (1) ZA703988B (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4244838A (en) 1979-06-25 1981-01-13 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
US4246383A (en) 1979-06-25 1981-01-20 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from an organomagnesium component which does not reduce TiCl4
US4426316A (en) 1982-09-10 1984-01-17 The Dow Chemical Company Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4434282A (en) 1982-10-04 1984-02-28 The Dow Chemical Company Process for polymerizing olefins
US4456547A (en) * 1982-10-21 1984-06-26 Fuentes Jr Ricardo Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and complex formed from admixture of a transition metal compound and an organozinc compound
US4496660A (en) * 1980-10-01 1985-01-29 The Dow Chemical Company Catalyst prepared from organo-magnesium compound; oxygen- or nitrogen-containing compound; halide source; transition metal compound and reducing agent
US4544647A (en) * 1982-07-29 1985-10-01 The Dow Chemical Company Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4604374A (en) * 1982-09-20 1986-08-05 The Dow Chemical Company Catalyst prepared from organomagnesium compound, epihalohydrin reducing halide source and transition metal compound
US4605715A (en) * 1982-09-20 1986-08-12 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from organomagnesium compound, epihalohydrin reducing halide source and transition metal compound
US4661465A (en) * 1985-10-31 1987-04-28 The Dow Chemical Company Method for preparing transition metal component of Ziegler-Natta catalysts
US5045612A (en) * 1990-04-18 1991-09-03 The Dow Chemical Company Catalyst and process for polymerizing olefins
US5114897A (en) * 1990-04-18 1992-05-19 The Dow Chemical Company Catalyst and process for polymerizing olefins
US5723705A (en) * 1992-05-26 1998-03-03 Hoechst Aktiengesellschaft Process for the preparation of polyolefin waxes in the presence of a metallocene catalyst and a co-catalyst
US5750813A (en) * 1992-12-15 1998-05-12 Clarian & Gmbh Process for the preparation of polyolefin waxes
US5917100A (en) * 1993-01-07 1999-06-29 Clariant Gmbh Process for producing low molecular-weight poly-1-olefins

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2329641C3 (en) * 1973-06-09 1978-09-28 Hoechst Ag, 6000 Frankfurt Process for the polymerization of ct-olefins
LU77489A1 (en) * 1977-06-06 1979-01-19

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4246383A (en) 1979-06-25 1981-01-20 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from an organomagnesium component which does not reduce TiCl4
US4244838A (en) 1979-06-25 1981-01-13 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
US4496660A (en) * 1980-10-01 1985-01-29 The Dow Chemical Company Catalyst prepared from organo-magnesium compound; oxygen- or nitrogen-containing compound; halide source; transition metal compound and reducing agent
US4544647A (en) * 1982-07-29 1985-10-01 The Dow Chemical Company Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4426316A (en) 1982-09-10 1984-01-17 The Dow Chemical Company Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
US4604374A (en) * 1982-09-20 1986-08-05 The Dow Chemical Company Catalyst prepared from organomagnesium compound, epihalohydrin reducing halide source and transition metal compound
US4605715A (en) * 1982-09-20 1986-08-12 The Dow Chemical Company Process for polymerizing olefins in the presence of a catalyst prepared from organomagnesium compound, epihalohydrin reducing halide source and transition metal compound
US4434282A (en) 1982-10-04 1984-02-28 The Dow Chemical Company Process for polymerizing olefins
US4456547A (en) * 1982-10-21 1984-06-26 Fuentes Jr Ricardo Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and complex formed from admixture of a transition metal compound and an organozinc compound
US4661465A (en) * 1985-10-31 1987-04-28 The Dow Chemical Company Method for preparing transition metal component of Ziegler-Natta catalysts
US5045612A (en) * 1990-04-18 1991-09-03 The Dow Chemical Company Catalyst and process for polymerizing olefins
US5114897A (en) * 1990-04-18 1992-05-19 The Dow Chemical Company Catalyst and process for polymerizing olefins
US5723705A (en) * 1992-05-26 1998-03-03 Hoechst Aktiengesellschaft Process for the preparation of polyolefin waxes in the presence of a metallocene catalyst and a co-catalyst
US5750813A (en) * 1992-12-15 1998-05-12 Clarian & Gmbh Process for the preparation of polyolefin waxes
US5917100A (en) * 1993-01-07 1999-06-29 Clariant Gmbh Process for producing low molecular-weight poly-1-olefins

Also Published As

Publication number Publication date
ES380594A1 (en) 1973-04-01
BE751909A (en) 1970-12-14
AU1617470A (en) 1971-12-16
CA919348A (en) 1973-01-16
NL7008604A (en) 1970-12-15
AT305619B (en) 1973-03-12
DE1929863A1 (en) 1970-12-17
FR2051159A5 (en) 1971-04-02
ZA703988B (en) 1971-03-31

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Legal Events

Date Code Title Description
CSNS Application of which complete specification have been accepted and published, but patent is not sealed