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GB1164361A - Aqueous Emulsions of Vinyl-Type Copolymers - Google Patents

Aqueous Emulsions of Vinyl-Type Copolymers

Info

Publication number
GB1164361A
GB1164361A GB2838667A GB2838667A GB1164361A GB 1164361 A GB1164361 A GB 1164361A GB 2838667 A GB2838667 A GB 2838667A GB 2838667 A GB2838667 A GB 2838667A GB 1164361 A GB1164361 A GB 1164361A
Authority
GB
United Kingdom
Prior art keywords
ester
itaconic
acid
hydroxypropyl
polyoxyalkylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2838667A
Inventor
Michael Edgar Hall
Richard House
Ronald William James Williams
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pfizer Ltd
Original Assignee
Pfizer Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pfizer Ltd filed Critical Pfizer Ltd
Priority to GB2838667A priority Critical patent/GB1164361A/en
Priority to DE19681770661 priority patent/DE1770661A1/en
Priority to FR1570974D priority patent/FR1570974A/fr
Publication of GB1164361A publication Critical patent/GB1164361A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/064—Polymers containing more than one epoxy group per molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02—Esters of monocarboxylic acids
    • C08F218/04—Vinyl esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

1,164,361. Vinyl ester/polyoxyalkylene ester copolymers. PFIZER Ltd. 19 June, 1968 [20 June, 1967], No. 28386/67. Headings C3P and C3R. An aqueous emulsion of a copolymer of a vinyl ester and a polyoxyalkylene ester of an α,#-unsaturated carboxylic acid, the polyoxyalkylene ester containing at least one -CO/OR) n X group linked to an ethylenically unsaturated group, where R is a vicinal alkylene group, X is an hydroxyl group or a halogen atom and n is at least 3. Suitable α,#-unsaturated carboxylic acids are acrylic, methacrylic, crotonio, achloroacrylic, a monoalkyl or mono-2-hydroxyalkyl ester of fumaric, maleic, itaconic or 2- methylene glutaric acid, fumaric, maleic, itaconic or 2-methylene glutaric acid. The polyoxyalkylene ester may be the reaction product of propylene oxide with a 2-hydroxy alkyl ester of an α,#-unsaturated carboxylic acid. In the examples polyoxypropylene esters are prepared from 2-hydroxypropyl di-ester of itaconic acid, 2-hydroxypropyl acrylate, 2-hydroxypropyl methacrylate, 2-hydroxyethyl di-ester of itaconic acid, 2-hydroxypropyl mono-ester of itaconic acid and propylene oxide in the presence of boron trifluoride diethyletherate. These esters are copolymerized with vinyl acetate in the presence of gum acacia, sodium dioctyl sulphosuccinate, water, potassium persulphate, hydroxyethyl cellulose, sodium lauryl sulphate, sodium persulphate and sodium tetradecyl sulphate.
GB2838667A 1967-06-20 1967-06-20 Aqueous Emulsions of Vinyl-Type Copolymers Expired GB1164361A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB2838667A GB1164361A (en) 1967-06-20 1967-06-20 Aqueous Emulsions of Vinyl-Type Copolymers
DE19681770661 DE1770661A1 (en) 1967-06-20 1968-06-19 Copolymers of polyoxyalkylene esters of unsaturated carboxylic acids and vinyl esters
FR1570974D FR1570974A (en) 1967-06-20 1968-06-20

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2838667A GB1164361A (en) 1967-06-20 1967-06-20 Aqueous Emulsions of Vinyl-Type Copolymers

Publications (1)

Publication Number Publication Date
GB1164361A true GB1164361A (en) 1969-09-17

Family

ID=10274817

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2838667A Expired GB1164361A (en) 1967-06-20 1967-06-20 Aqueous Emulsions of Vinyl-Type Copolymers

Country Status (3)

Country Link
DE (1) DE1770661A1 (en)
FR (1) FR1570974A (en)
GB (1) GB1164361A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5110859A (en) * 1987-09-02 1992-05-05 Peter Flesher Polymers, their production and uses
US5273676A (en) * 1989-05-09 1993-12-28 Basf Aktiengesellschaft Copolymers with monomers containing polyalkylene oxide blocks, preparation thereof and use thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4708999A (en) * 1985-04-26 1987-11-24 Air Products And Chemicals, Inc. Copolymers of vinyl acetate and poly(alkyleneoxy) acrylates
US4618648A (en) * 1985-04-26 1986-10-21 Air Products And Chemicals, Inc. Copolymers of vinyl alcohol and poly(alkyleneoxy)acrylates
EP0272012B1 (en) * 1986-11-27 1992-08-19 Ciba Specialty Chemicals Water Treatments Limited Polymers, their production and uses

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5110859A (en) * 1987-09-02 1992-05-05 Peter Flesher Polymers, their production and uses
US5273676A (en) * 1989-05-09 1993-12-28 Basf Aktiengesellschaft Copolymers with monomers containing polyalkylene oxide blocks, preparation thereof and use thereof

Also Published As

Publication number Publication date
DE1770661A1 (en) 1972-04-06
FR1570974A (en) 1969-06-13

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees