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GB1039756A - Improvements in or relating to methods of treating gases - Google Patents

Improvements in or relating to methods of treating gases

Info

Publication number
GB1039756A
GB1039756A GB40839/62A GB4083962A GB1039756A GB 1039756 A GB1039756 A GB 1039756A GB 40839/62 A GB40839/62 A GB 40839/62A GB 4083962 A GB4083962 A GB 4083962A GB 1039756 A GB1039756 A GB 1039756A
Authority
GB
United Kingdom
Prior art keywords
catalyst
tube
methane
burner
casing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB40839/62A
Inventor
George Percival
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gas Council
Original Assignee
Gas Council
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gas Council filed Critical Gas Council
Priority to GB40839/62A priority Critical patent/GB1039756A/en
Publication of GB1039756A publication Critical patent/GB1039756A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
    • B01J2208/00123—Fingers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00477—Controlling the temperature by thermal insulation means
    • B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0415—Purification by absorption in liquids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

<PICT:1039756/C4-C5/1> In a process for converting methane by reaction with steam over a nickel catalyst into CO and H2, the temperature of the catalyst is maintained by means of one or more tubular heating elements contained in the same vessel as the catalyst (said tubular heating elements each comprising an outer, substantially cylindrical casing closed at the forward end and having a flue outlet at the rear end, a tubular portion coaxial with the casing and a burner having a combustion chamber which converges towards an exit coaxial with the cylindrical casing for the discharge of hot products into the outer end of the partition tube which extends nearly from the exit to the closed forward end of the casing but leaves a space beyond its end for the re-circulation of hot products, as claimed in claim 1 of Specification 876,161) and also by means of mixing oxygen with the reactant gases so that combustion takes place with liberation of heat in the catalyst bed. The methane may be in the form of a methane-containing gas produced according to the process of Specification 820,257. Oxygen may be supplied as air. The catalyst temperature may be maintained at 550-800 DEG C. In Fig. 1 pressure vessel 1 encloses bed 3 of reforming catalyst surrounding radiant tube 4; inner tube 6 co-axial with 4 is such as to allow passage of flue gases in annulus 7 while burner tube 8 promotes recirculation of flue gases into 6; flue gases are withdrawn at 9. Steam and methane-containing gas are introduced at 10, and preheated air at 12, the mixture passing through the catalyst and being withdrawn at 11, tube 4 being heated by the passage of combustion products of burner 8 in annulus 7.
GB40839/62A 1962-10-29 1962-10-29 Improvements in or relating to methods of treating gases Expired GB1039756A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB40839/62A GB1039756A (en) 1962-10-29 1962-10-29 Improvements in or relating to methods of treating gases

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB40839/62A GB1039756A (en) 1962-10-29 1962-10-29 Improvements in or relating to methods of treating gases

Publications (1)

Publication Number Publication Date
GB1039756A true GB1039756A (en) 1966-08-24

Family

ID=10416876

Family Applications (1)

Application Number Title Priority Date Filing Date
GB40839/62A Expired GB1039756A (en) 1962-10-29 1962-10-29 Improvements in or relating to methods of treating gases

Country Status (1)

Country Link
GB (1) GB1039756A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0450872A1 (en) * 1990-04-03 1991-10-09 The Standard Oil Company Endothermic reaction apparatus
AU661877B2 (en) * 1990-04-03 1995-08-10 Standard Oil Company, The Endothermic reaction apparatus
US5567398A (en) * 1990-04-03 1996-10-22 The Standard Oil Company Endothermic reaction apparatus and method
US6096106A (en) * 1990-04-03 2000-08-01 The Standard Oil Company Endothermic reaction apparatus
US6153152A (en) * 1990-04-03 2000-11-28 The Standard Oil Company Endothermic reaction apparatus and method
FR2898518A1 (en) * 2006-03-17 2007-09-21 Inst Francais Du Petrole INTERNAL COMBUSTION HEAT EXCHANGER REACTOR FOR ENDOTHERMIC REACTION IN FIXED BED
FR2898517A1 (en) * 2006-03-17 2007-09-21 Inst Francais Du Petrole Exchanging reactor to carry out steam reforming reactions, comprises an enclosure, a distribution unit to distribute a charge through a fixed-bed catalytic zone, and a collection unit to collect an effluent from the catalytic zone
CN102278758A (en) * 2011-06-17 2011-12-14 中冶京诚工程技术有限公司 Radiant tube heating device
CN111542492A (en) * 2017-12-07 2020-08-14 俄罗斯天然气工业公开股份公司 Apparatus and method for producing hydrogen-containing gas
WO2022201020A3 (en) * 2021-03-25 2022-11-03 Nova Chemicals (International) S.A. Internally heated reactor for hydrocarbon conversion

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0450872A1 (en) * 1990-04-03 1991-10-09 The Standard Oil Company Endothermic reaction apparatus
AU661877B2 (en) * 1990-04-03 1995-08-10 Standard Oil Company, The Endothermic reaction apparatus
US5565009A (en) * 1990-04-03 1996-10-15 The Standard Oil Company Endothermic reaction process
US5567398A (en) * 1990-04-03 1996-10-22 The Standard Oil Company Endothermic reaction apparatus and method
US6096106A (en) * 1990-04-03 2000-08-01 The Standard Oil Company Endothermic reaction apparatus
US6153152A (en) * 1990-04-03 2000-11-28 The Standard Oil Company Endothermic reaction apparatus and method
WO2007118950A1 (en) * 2006-03-17 2007-10-25 Ifp Internal combustion exchanger reactor for endothermic reaction in fixed bed
FR2898517A1 (en) * 2006-03-17 2007-09-21 Inst Francais Du Petrole Exchanging reactor to carry out steam reforming reactions, comprises an enclosure, a distribution unit to distribute a charge through a fixed-bed catalytic zone, and a collection unit to collect an effluent from the catalytic zone
FR2898518A1 (en) * 2006-03-17 2007-09-21 Inst Francais Du Petrole INTERNAL COMBUSTION HEAT EXCHANGER REACTOR FOR ENDOTHERMIC REACTION IN FIXED BED
CN101432065B (en) * 2006-03-17 2012-07-18 Ifp公司 Internal combustion exchanger reactor for endothermic reaction in fixed bed
US8273314B2 (en) 2006-03-17 2012-09-25 IFP Energies Nouvelles Internal combustion exchanger-reactor for fixed bed endothermic reaction
CN102278758A (en) * 2011-06-17 2011-12-14 中冶京诚工程技术有限公司 Radiant tube heating device
CN102278758B (en) * 2011-06-17 2013-01-02 中冶京诚工程技术有限公司 Radiant tube heating device
CN111542492A (en) * 2017-12-07 2020-08-14 俄罗斯天然气工业公开股份公司 Apparatus and method for producing hydrogen-containing gas
CN111542492B (en) * 2017-12-07 2023-04-25 俄罗斯天然气工业公开股份公司 Apparatus and method for producing hydrogen-containing gas
WO2022201020A3 (en) * 2021-03-25 2022-11-03 Nova Chemicals (International) S.A. Internally heated reactor for hydrocarbon conversion

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