FR2337737A1 - Catalyst for olefin polymerisation - of transition metal cpd. on carrier from reaction of organic magnesium, aluminium and hydroxy cpds. - Google Patents
Catalyst for olefin polymerisation - of transition metal cpd. on carrier from reaction of organic magnesium, aluminium and hydroxy cpds.Info
- Publication number
- FR2337737A1 FR2337737A1 FR7639661A FR7639661A FR2337737A1 FR 2337737 A1 FR2337737 A1 FR 2337737A1 FR 7639661 A FR7639661 A FR 7639661A FR 7639661 A FR7639661 A FR 7639661A FR 2337737 A1 FR2337737 A1 FR 2337737A1
- Authority
- FR
- France
- Prior art keywords
- cpd
- catalyst
- transition metal
- reaction
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Catalyst for (co) polymerisation of olefins, contg. a transition metal cpd. (A) and an organo-metallic cpd. (B) in which (A) is made by reactor of (1) a reaction prod. of (a) a cpd. of formula R MgX, (in which R is 1-20C alkyl or aryl and X is halogen, with (b) a cpd. of formula AlRE'X3-n (in which R1 is 1-20 C alkyl or aryl, X is halogen and n is 0-3), and subsequently with (c) a cpd. of formula R"OH (in which R" is a 1-20C hydrocarbon gp), with (2) a Ti and/or V cpd. (Co)polymerisation of a-olefins, e.g. ethylene, propylen, and/or 1-butene, and copolymerisation of an olefin and a diene. Extremely active, allowing catalyst removal to be omitted and giving polymers of increased bulk density. Polymers of higher melt index can be made, or the hydrogen concn. to produce a given melt index reduced.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP147076A JPS5285278A (en) | 1976-01-09 | 1976-01-09 | Production of polyolefin |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2337737A1 true FR2337737A1 (en) | 1977-08-05 |
FR2337737B1 FR2337737B1 (en) | 1980-10-10 |
Family
ID=11502339
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR7639661A Granted FR2337737A1 (en) | 1976-01-09 | 1976-12-30 | Catalyst for olefin polymerisation - of transition metal cpd. on carrier from reaction of organic magnesium, aluminium and hydroxy cpds. |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPS5285278A (en) |
CA (1) | CA1085811A (en) |
DE (1) | DE2700163A1 (en) |
FR (1) | FR2337737A1 (en) |
IT (1) | IT1067562B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0204340A1 (en) * | 1985-06-06 | 1986-12-10 | The Dow Chemical Company | Novel catalyst and method for producing relatively narrow molecular weight distribution olefin polymers |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1104298A (en) * | 1978-02-23 | 1981-06-30 | Akinobu Shiga | Catalysts for the polymerization of olefins |
JPS6050836U (en) * | 1983-09-19 | 1985-04-10 | 株式会社クボタ | Riding rice transplanter |
NL8700322A (en) * | 1987-02-11 | 1988-09-01 | Stamicarbon | CATALYST SYSTEM FOR (CO) POLYMERIZATION OF ETHENE IN SOLUTION. |
JP6393707B2 (en) | 2016-04-28 | 2018-09-19 | 川崎重工業株式会社 | Spot joining apparatus, spot joining method and joint structure |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1275641A (en) * | 1969-01-06 | 1972-05-24 | Solvay | Catalysts for the polymerisation and copolymerisation of olefins |
US3907759A (en) * | 1972-10-06 | 1975-09-23 | Nissan Chemical Ind Ltd | Catalyst for polymerization of olefins and process for polymerization of olefins with use of said catalyst |
FR2212346B1 (en) * | 1972-12-28 | 1978-12-01 | Nippon Oil Co Ltd | |
JPS5439876B2 (en) * | 1973-08-24 | 1979-11-30 | ||
JPS5236791B2 (en) * | 1974-05-25 | 1977-09-17 |
-
1976
- 1976-01-09 JP JP147076A patent/JPS5285278A/en active Granted
- 1976-12-09 IT IT3021776A patent/IT1067562B/en active
- 1976-12-30 FR FR7639661A patent/FR2337737A1/en active Granted
-
1977
- 1977-01-04 CA CA269,137A patent/CA1085811A/en not_active Expired
- 1977-01-04 DE DE19772700163 patent/DE2700163A1/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0204340A1 (en) * | 1985-06-06 | 1986-12-10 | The Dow Chemical Company | Novel catalyst and method for producing relatively narrow molecular weight distribution olefin polymers |
Also Published As
Publication number | Publication date |
---|---|
DE2700163C2 (en) | 1989-02-16 |
JPS5285278A (en) | 1977-07-15 |
DE2700163A1 (en) | 1977-07-14 |
IT1067562B (en) | 1985-03-16 |
CA1085811A (en) | 1980-09-16 |
JPS565405B2 (en) | 1981-02-04 |
FR2337737B1 (en) | 1980-10-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
ST | Notification of lapse |