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FR2393609A1 - Hydrocarbon catalyst on inorganic oxide boron phosphate carrier - from mixt. of hydrogel and predried hydrogel, esp. carrying nickel and molybdenum for hydrorefining residual oils - Google Patents

Hydrocarbon catalyst on inorganic oxide boron phosphate carrier - from mixt. of hydrogel and predried hydrogel, esp. carrying nickel and molybdenum for hydrorefining residual oils

Info

Publication number
FR2393609A1
FR2393609A1 FR7717277A FR7717277A FR2393609A1 FR 2393609 A1 FR2393609 A1 FR 2393609A1 FR 7717277 A FR7717277 A FR 7717277A FR 7717277 A FR7717277 A FR 7717277A FR 2393609 A1 FR2393609 A1 FR 2393609A1
Authority
FR
France
Prior art keywords
hydrogel
catalyst
mixt
predried
hydrorefining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7717277A
Other languages
French (fr)
Other versions
FR2393609B1 (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honeywell UOP LLC
Original Assignee
UOP LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UOP LLC filed Critical UOP LLC
Priority to FR7717277A priority Critical patent/FR2393609A1/en
Publication of FR2393609A1 publication Critical patent/FR2393609A1/en
Application granted granted Critical
Publication of FR2393609B1 publication Critical patent/FR2393609B1/fr
Granted legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Catalyst is prepd. by (a) pptg. an oxide hydrogel from a hydrosol of Al2O3, SiO2, ZrO2, ThO2 and/or B2O3, (b) mixing the hydrogel with a dried, finely divided form of the hydrogel to provide 5-50 wt.% of the catalyst, (c) impregnating the mixt. with an aq. soln. of H3BO3 and H3PO4 to give 13-35 wt.% B phosphate in the catalyst. This is followed by (d) drying the mixt. and impregnating with a decomposable Gp. VIII metal cpd. and a decomposable Gp. VIB metal cpd., to incorporate 0.1-10 wt.% Gp. VIII metal and 5-20% Gp. VIB metal into the catalyst, and (e) drying the mixt. and calcining in an oxidising atmos. Heptane-insol. asphaltenes are converted to heptanesol. hydrocarbons, without rapid deposition of coke on the catalyst. Depending on reaction conditions, much of the feed is hydrocracked to gasoline, kerosene and fuel oil. The catalyst has improved activity and stability.
FR7717277A 1977-06-06 1977-06-06 Hydrocarbon catalyst on inorganic oxide boron phosphate carrier - from mixt. of hydrogel and predried hydrogel, esp. carrying nickel and molybdenum for hydrorefining residual oils Granted FR2393609A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7717277A FR2393609A1 (en) 1977-06-06 1977-06-06 Hydrocarbon catalyst on inorganic oxide boron phosphate carrier - from mixt. of hydrogel and predried hydrogel, esp. carrying nickel and molybdenum for hydrorefining residual oils

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7717277A FR2393609A1 (en) 1977-06-06 1977-06-06 Hydrocarbon catalyst on inorganic oxide boron phosphate carrier - from mixt. of hydrogel and predried hydrogel, esp. carrying nickel and molybdenum for hydrorefining residual oils

Publications (2)

Publication Number Publication Date
FR2393609A1 true FR2393609A1 (en) 1979-01-05
FR2393609B1 FR2393609B1 (en) 1981-08-14

Family

ID=9191732

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7717277A Granted FR2393609A1 (en) 1977-06-06 1977-06-06 Hydrocarbon catalyst on inorganic oxide boron phosphate carrier - from mixt. of hydrogel and predried hydrogel, esp. carrying nickel and molybdenum for hydrorefining residual oils

Country Status (1)

Country Link
FR (1) FR2393609A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11318453B2 (en) 2009-04-21 2022-05-03 Albemarle Catalysts Company B.V. Hydrotreating catalyst containing phosphorus and boron

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11318453B2 (en) 2009-04-21 2022-05-03 Albemarle Catalysts Company B.V. Hydrotreating catalyst containing phosphorus and boron
US11986813B2 (en) 2009-04-21 2024-05-21 Ketjen Netherlands B.V. Hydrotreating catalyst containing phosphorus and boron

Also Published As

Publication number Publication date
FR2393609B1 (en) 1981-08-14

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Legal Events

Date Code Title Description
ST Notification of lapse