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ES347738A1 - Cellular Polyurethanes - Google Patents

Cellular Polyurethanes

Info

Publication number
ES347738A1
ES347738A1 ES347738A ES347738A ES347738A1 ES 347738 A1 ES347738 A1 ES 347738A1 ES 347738 A ES347738 A ES 347738A ES 347738 A ES347738 A ES 347738A ES 347738 A1 ES347738 A1 ES 347738A1
Authority
ES
Spain
Prior art keywords
component
weight
blowing agent
isocyanate
methylene bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES347738A
Other languages
Spanish (es)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pharmacia and Upjohn Co
Original Assignee
Upjohn Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Upjohn Co filed Critical Upjohn Co
Publication of ES347738A1 publication Critical patent/ES347738A1/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/6576—Compounds of group C08G18/69
    • C08G18/6582—Compounds of group C08G18/69 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6603—Compounds of groups C08G18/42, C08G18/48, or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0033—Foam properties having integral skins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/0066—≥ 150kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2350/00—Acoustic or vibration damping material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2410/00—Soles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

Cellular polyurethanes having a density in excess of 10 pounds per cubic foot are prepared by reacting in a one-step process (a) a polyisocyanate component comprising methylene bis- (phenyl isocyanate), (b) a polyol component which is a polyester diol of equivalent weight from 75 to 1700 or a polyether polyol of equivalent weight from 300 to 1600 and an average functionality of 2 to 4, or a mixture thereof and (c) a blowing agent which is (i) up to 0À5% by weight based on the weight of component (6) of water and/or (ii) one or more aliphatic halogenated hydrocarbons having a b.p. not more than 110 C., the ratio of isocyanate groups to active hydrogen in the reaction components, including the water when used as a blowing agent, being in the range of 0À95:1À0 to 1À2:1À0. Suitably, the polyisocyanate component (c) comprises a mixture of polymethylene polyphenyl isocyanates containing from 35 to 85% by weight of methylene bis-(phenyl isocyanate) or comprises methylene bis-(phenyl isocyanate) which has previously been heated at 160 to 250 C. in the presence of 0À1 to 3% of a trialkylphosphate until the isocyanate equivalent is from 130 to 150. The reaction mixture may also contain a component (d) which is an aromatic primary diamine wherein each of the amino groups is attached directly to an aromatic nucleus, e.g. 3,31-dichlorobenzidine, and/or an aliphatic hydrocarbon diol containing 1 to 6 carbon atoms. Aliphatic halogenated hydrocarbons are suitably used as the blowing agent (ii). Conventional catalysts, surfactants and plasticizers may be added to the reaction mixture. The compositions may be poured into moulds to prepare shoe soles and heels, pouredin-place gaskets for the air filter case of an automobile engine or spring pads.
ES347738A 1966-12-27 1967-11-28 Cellular Polyurethanes Expired ES347738A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US60462566A 1966-12-27 1966-12-27

Publications (1)

Publication Number Publication Date
ES347738A1 true ES347738A1 (en) 1969-03-01

Family

ID=24420360

Family Applications (1)

Application Number Title Priority Date Filing Date
ES347738A Expired ES347738A1 (en) 1966-12-27 1967-11-28 Cellular Polyurethanes

Country Status (5)

Country Link
AT (1) AT283761B (en)
DE (1) DE1719292B2 (en)
ES (1) ES347738A1 (en)
FR (1) FR1548164A (en)
GB (1) GB1177097A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2647482A1 (en) * 1976-10-21 1978-04-27 Bayer Ag PROCESS FOR THE MANUFACTURING OF COLD-CARDING FOAMS CONTAINING URETHANE GROUPS
US4294951A (en) 1980-07-14 1981-10-13 Mitsui-Nisso Corporation Rapid curing polyurethane elastomer prepared from a diphenylmethanediisocyanate based liquid prepolymer and a curing agent containing a polytetramethylene ether glycol, a diol and an organometallic catalyst
US4622361A (en) * 1985-03-29 1986-11-11 Union Carbide Corporation Flame retarded high modulus polyurethane elastomers and method of making same
JPH02196816A (en) * 1989-01-26 1990-08-03 M D Kasei Kk Production of integral skin foam

Also Published As

Publication number Publication date
GB1177097A (en) 1970-01-07
FR1548164A (en) 1968-11-29
DE1719292A1 (en) 1970-10-22
AT283761B (en) 1970-08-25
DE1719292B2 (en) 1972-11-23

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