EP3628035A1 - Verfahren zum abkühlen eines dreidimensionalen bauteils und abkühlvorrichtung - Google Patents
Verfahren zum abkühlen eines dreidimensionalen bauteils und abkühlvorrichtungInfo
- Publication number
- EP3628035A1 EP3628035A1 EP18731412.5A EP18731412A EP3628035A1 EP 3628035 A1 EP3628035 A1 EP 3628035A1 EP 18731412 A EP18731412 A EP 18731412A EP 3628035 A1 EP3628035 A1 EP 3628035A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fluid medium
- cooling
- dimensional object
- building material
- cooling device
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/30—Auxiliary operations or equipment
- B29C64/364—Conditioning of environment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/20—Direct sintering or melting
- B22F10/28—Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/30—Process control
- B22F10/32—Process control of the atmosphere, e.g. composition or pressure in a building chamber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/20—Cooling means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/70—Gas flow means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/16—Cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/141—Processes of additive manufacturing using only solid materials
- B29C64/153—Processes of additive manufacturing using only solid materials using layers of powder being selectively joined, e.g. by selective laser sintering or melting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/188—Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/20—Apparatus for additive manufacturing; Details thereof or accessories therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/30—Auxiliary operations or equipment
- B29C64/379—Handling of additively manufactured objects, e.g. using robots
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y40/00—Auxiliary operations or equipment, e.g. for material handling
- B33Y40/20—Post-treatment, e.g. curing, coating or polishing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/70—Recycling
- B22F10/73—Recycling of powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/16—Cooling
- B29C2035/1658—Cooling using gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/16—Cooling
- B29C2035/1691—Cooling using gas-liquid mixtures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/30—Auxiliary operations or equipment
- B29C64/357—Recycling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y99/00—Subject matter not provided for in other groups of this subclass
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Definitions
- the invention relates to a method for cooling a three-dimensional object produced by layer-wise selective solidification of a powdery building material and unconsolidated building material, in which the three-dimensional object is embedded, and to a corresponding cooling device.
- Methods and apparatus for producing a three-dimensional object by layer-wise selective solidification of a powdery building material are used, for example, in rapid prototyping, rapid tooling or additive manufacturing.
- An example of such a method is known as "selective laser sintering" or “selective laser melting”.
- a thin layer of powdery build material is repeatedly applied and the build material in each layer is selectively solidified by selectively irradiating locations corresponding to a cross section of the object to be manufactured with a laser.
- the document DE 195 14 740 C1 describes a method for producing a three-dimensional object by means of selective laser sintering or laser melting and a device for carrying out this method.
- the three-dimensional object and the unconsolidated building material in which the three-dimensional object is embedded are cooled.
- a cooling fluid e.g. Nitrogen to pass through the powder cake containing the manufactured object to cool it quickly.
- the method according to the invention serves to cool a three-dimensional object produced by layer-wise selective solidification of a pulverulent construction material and non-reinforced building material, into which the three-dimensional object embedded, by treatment with a fluid medium.
- the fluid medium is formed from a carrier gas which is specifically enriched with an additional component which comprises a further gas and / or a liquid.
- the fluid medium can also be formed from a gas mixture, which is deliberately at least partially removed from at least one mixture component.
- the treatment according to the invention with a fluid medium which is enriched with an additional component or which is obtained by the at least partial removal of one or more mixture components from the gas mixture, the reusability of the unconsolidated building material and / or the quality of a three-dimensional object, for example, improved with at least partial reuse of unconsolidated building material.
- Another advantageous effect, which can be achieved thereby, may be, for example, that the unconsolidated Aufaumaterial easier to handle, in particular better sieved.
- the treatment according to the invention in particular the
- the following effects can be achieved:
- a chemical effect can be achieved, for example, if the building material contains a polymer.
- the water may cause hydrolytic cleavage reactions in the polymer chains of the building material on cooling, thereby reducing the average molecular weight or at least partially compensating for an increase in molecular weight which would otherwise occur in the course of producing a three-dimensional object.
- This can be improved, for example, the reusability of the unresolved building material and / or the quality of a three-dimensional object produced with at least partial reuse of unconsolidated building material.
- the treatment can be used to create a water sheath which separates the powder particles so as to reduce or even prevent sticking of the powder particles. Furthermore, the electrostatic charge of the powder particles is reduced or prevented. Accordingly, the unconsolidated building material can be handled easier, in particular better sieved.
- the fluid medium can be enriched, for example, with an acid, preferably with a carboxylic acid, in particular with formic acid and / or acetic acid.
- the additional component with which the carrier gas is enriched in a targeted manner preferably comprises H 2 O.
- the H 2 O content of the additional component is more preferably at least 90, more preferably at least 95, particularly preferably at least
- the reusability and / or the sievability of the unconsolidated building material can be achieved in a particularly effective manner. can be increased because the unconsolidated building material charges less strongly or not at all electrostatically.
- the additional component comprises a surfactant.
- a surfactant for example, ionic surfactants such as sodium lauryl sulfate, sodium dodecylbenzenesulfonate, sodium benzene sulfonate or nonionic surfactants such as the surfactants marketed under the brand name "Triton.”
- the carrier gas comprises an inert gas, in particular nitrogen
- the advantageous effects described above can be achieved with simultaneous protection against (thermo) oxidative damage to the unconsolidated building material
- another inert gas such as argon can also be used.
- the carrier gas is preferably at least half, more preferably at least 80%, even more preferably at least 90%, saturated at the prevailing temperature and pressure with the additional component.
- concentrations of the additional component for example, the advantageous effects of the method according to the invention described above can be particularly pronounced.
- Preferably, at least a portion of the liquid in the fluid medium is distributed in the form of droplets.
- the fluid medium is then an aerosol.
- a particularly effective cooling effect can be achieved, for example, by evaporating the liquid.
- the fluid medium is no longer an aerosol, but a gaseous fluid medium.
- the fluid medium per cubic meter contains at least 10, more preferably at least 50, even more preferably at least 75 grams and / or at most 300, more preferably at most 200, even more preferably at most 150 grams of the additional component.
- the fluid medium flows through the unconsolidated building material, in which the three-dimensional object is embedded, wherein in a preferred embodiment, the flow takes place substantially from below or in a direction opposite to gravity and / or to the direction of gravity. By flowing through, for example, it can be ensured that the fluid medium comes into close contact with the unconsolidated building material, as a result of which the advantageous effects described above can be achieved in a particularly effective manner.
- the flow through takes place substantially in the direction of gravity.
- the unconsolidated building material into which the three-dimensional object is embedded is at least partially fluidized by means of the fluid medium.
- the powder cake is preferably first broken up, and then it is flowed through. Both steps are carried out with the same fluid medium.
- the fluid medium is preferably conducted into the interior of a cooling container and brought into contact with the three-dimensional object and the unconsolidated building material inside the cooling container.
- the fluid medium is preferably passed through a fluidizing into the interior of the cooling vessel.
- a fluidizing plate for example, the unconsolidated building material can be fluidized in an effective manner.
- a gas-permeable plate such as, for example, a perforated plate or a metal frit can be used as the fluidizing plate.
- a cooling container can be used in particular a building container.
- the produced three-dimensional object and the unconsolidated building material in which the three-dimensional object is embedded are easily taken out of a device for producing a three-dimensional object by layerwise selectively consolidating a powdery building material and inserted into a cooling device.
- the outer material contains a polymer, more preferably a polyaryletherketone and / or a polyamide, more preferably polyamide 12 and / or polyamide 11 and / or polyamide 6.
- a polymer more preferably a polyaryletherketone and / or a polyamide, more preferably polyamide 12 and / or polyamide 11 and / or polyamide 6.
- the advantageous effects of the above-described inventive method be particularly pronounced.
- water only leads to a change in material properties of a polymer material as long as it is present in it. If the polymer material is subsequently dried, these changes in material properties are generally reversible. As stated above, the presence of water is advantageous for subsequent processes such as sieves.
- the building material comprises at least one polymer selected from the group consisting of polyetherimides, polycarbonates, polyphenylene sulfones, polyphenylene oxides, polyethersulfones, acrylonitrile-butadiene-
- Styrene copolymer polyacrylates, polyesters, polyolefins, polypropylene, Polyetherblockamid and their copolymers and their polymer blends is selected.
- old powder powdery building material
- new powder powdery building material
- the carrier gas and / or the additive component and / or the building material are selected and / or matched so that the refresh rate of the building material is lowered.
- the cooling device according to the invention serves to cool by the method according to the invention by three-dimensional object produced by layer-wise selective solidification of a powdery building material and unconsolidated building material in which the three-dimensional object is embedded, by Behanderes with a fluid medium.
- the cooling apparatus includes a cooling vessel for the three-dimensional object and the unconsolidated building material in which the three-dimensional object is embedded, with a cooling vessel wall having at least in one area a boundary permeable to the fluid medium, a manufacturing unit for producing the fluid medium, in particular contains a nebulizer for nebulizing a liquid, and a first line tion for directing the fluid medium from the manufacturing unit to the permeable area for the fluid medium.
- a cooling vessel for example, a device is available with which the method according to the invention can be carried out.
- the cooling device further includes a second conduit for conducting the fluid medium from the cooling vessel to the manufacturing unit and a compressor for generating a circulation of the fluid medium, the circuit passing through the cooling vessel, the second conduit, the manufacturing unit and the first conduit ,
- a second conduit for conducting the fluid medium from the cooling vessel to the manufacturing unit
- a compressor for generating a circulation of the fluid medium, the circuit passing through the cooling vessel, the second conduit, the manufacturing unit and the first conduit
- the cooling device includes a filter for filtering the fluid medium, wherein the filter is more preferably arranged so that it filters out of the cooling tank exiting fluid medium.
- the filter is more preferably arranged so that it filters out of the cooling tank exiting fluid medium.
- the permeable area for the fluid medium forms at least a portion of a bottom of the Abkühlbenzol- ters.
- the fluid medium in a direction substantially opposite to the force acting on the powder particles of the unconsolidated building material or in a direction which is angled towards it and thus has a direction component directed counter to the force of gravity which makes the unam- solidified on aumaterial loosened and for the fluid medium is made easier to flow through.
- the area permeable to the fluid medium is configured as a fluidization plate.
- the cooling device has a vibrating device, which is designed to set the cooling container in a vibrating motion.
- the vibrator is designed as a vibrator, knocker or shaker plate.
- a shaking movement it is possible, for example, to prevent cracks and / or cavities from forming in the powder cake, and it can be achieved that cracks which have formed in the powder cake close again as otherwise unconsolidated building material trickles into the cracks or flows.
- the frequency range of at least 25 Hz and / or at most 40 Hz for the shaking movement in the sense of optimal crack prevention can be advantageous.
- the optimum frequency depends on the component geometry and must be adapted to the complexity or filigree structures in individual cases. Massive components often tolerate higher vibrating frequencies than filigree components.
- FIG. 1 is a schematic, partially sectioned view of an apparatus for producing a three-dimensional object by layer-by-layer selectively solidifying a powdery build material.
- Fig. 2 is a schematic, partially sectional view of a cooling apparatus according to a first embodiment of the present invention.
- Fig. 3 is a schematic, partially sectional view of a cooling apparatus according to a second embodiment of the present invention.
- Fig. 4 is a schematic, partially sectional view of a cooling apparatus according to a third embodiment of the present invention.
- Fig. 5 is a schematic, partially sectional view of a cooling apparatus according to a fourth embodiment of the present invention.
- the apparatus shown in FIG. 1 is a laser sintering or laser melting apparatus 1 which is basically known in the prior art.
- a process chamber 3 For producing an object 2, it contains a process chamber 3 with a chamber wall 4.
- an upwardly open building container 5 with a Bau actuallyerwandung 6 is arranged.
- a working level 7 is defined, wherein the area lying within the opening of the working plane 7, which can be used to construct the object 2, is referred to as construction field 8.
- V be wegbarer carrier 10 is arranged, on which a base plate 11 is mounted, which closes the building container 5 down and thus forms its bottom.
- the base plate 11 may be a plate formed separately from the carrier 10, which is fixed to the carrier 10, or it may be integrally formed with the carrier 10.
- a construction platform 12 as a construction document on which the object 2 is constructed.
- the object 2 can also be built on the base plate 11 itself, which then serves as a construction document.
- FIG. 1 the object 2 to be formed in the construction container 5 on the construction platform 12 is shown below the working plane 7 in an intermediate state with a plurality of solidified layers, surrounded by the unconsolidated construction material 13.
- the building container 5 can be designed as a swap body, which can be removed from the apparatus 1 for producing a three-dimensional object and can be inserted into a cooling apparatus according to the invention which is described below. The building container 5 can then serve as a cooling container in the cooling device.
- the laser sintering apparatus 1 further contains a reservoir 14 for a pulverulent material which can be solidified by electromagnetic radiation and a coater 16 movable in a horizontal direction H for applying the building material 15 within the construction field 8 Coater 16 extends transversely to its direction of movement over the entire area to be coated.
- a radiant heater 17 is arranged, which serves for heating the applied on aumaterials 15.
- radiant heater 17 for example, an infrared radiator can be provided.
- the laser sintering apparatus 1 further includes an exposure device 20 with a laser 21 which generates a laser beam 22 which is deflected by a deflection device 23 and by a focusing device 24 via a coupling window 25 which is mounted on the top of the process chamber 3 in the chamber wall 4 , is focused on the working level 7.
- the laser sintering device 1 contains a control unit 29, via which the individual components of the device 1 are controlled in a coordinated manner for carrying out the method for producing a three-dimensional object 2.
- the control unit 29 can also be mounted partially or completely outside the device 1.
- the control unit 29 may include a CPU whose operation is controlled by a computer program (software).
- the computer program can be stored separately from the device 1 on a storage medium, from which it can be loaded into the device 1, in particular into the control unit 29.
- the carrier 10 In operation, for the application of a powder layer, first of all the carrier 10 is lowered by a height which corresponds to the desired layer thickness.
- the coater 16 first moves to the storage container 14 and receives from it a sufficient amount of the building material 15 to apply a layer. Then he drives over the construction field 8 and brings there a thin layer of the powdery building material 15 on the construction substrate or an already existing powder layer.
- the application takes place at least over the entire cross section of the object 2 to be produced, preferably over the entire construction field 8, ie the area of the working plane 7 delimited by the building container wall 6.
- the powdery building material 15 is heated to a working temperature by means of a radiant heater 17.
- the cross section of the object 2 to be produced is scanned by the laser beam 22, so that the powdery building material 15 is solidified at the points corresponding to the cross section of the object 2 to be produced.
- powder particles are partially or completely melted at these points by the energy that is introduced by the radiation, so that they are connected to each other after cooling as a solid state.
- the produced three-dimensional object 2 and the unconsolidated building material 13, in which the three-dimensional object is embedded are cooled.
- the cooling takes place preferably outside of the process chamber 3.
- the process chamber can be available during the cooling for the production of a further three-dimensional object.
- FIG. 2 schematically shows a cooling device 30 according to a first exemplary embodiment of the present invention.
- the cooling apparatus 30 includes, as a cooling vessel 31 in this embodiment, the building container 5 formed as a swap body, which is intended to receive the three-dimensional object 2 and the unconsolidated building material 13 in which the three-dimensional object 2 is embedded in its interior.
- the cooling tank 31 is made permeable in the region of its bottom, for example by a fluidizing plate 32 for the fluid medium.
- a fluidizing plate 32 is provided in the region of the bottom of the cooling vessel 31, via which the fluid medium the interior of the Abkühl disposers 30 is passed.
- the cooling device 30 includes a manufacturing unit 33 for producing the fluid medium.
- the manufacturing unit 33 is preferably a humidifier designed to enrich a carrier gas with a liquid, more preferably an atomizer.
- the cooling device 30 includes a first pipe 34 for guiding the fluid medium from the manufacturing unit 33 to the fluid medium permeable portion of the cooling tank 31, so that the fluid medium is supplied from the manufacturing unit 33 to the inside of the cooling tank 31 and inside of the cooling container 31 can contact the unconsolidated build-up material 13 and the manufactured object 2.
- the flow direction from the manufacturing unit 33 to the Cooling container 31 is indicated in Fig. 2 by the arrow 35.
- the cooling device 30 contains a second line 37 for conducting the fluid emerging from the cooling tank 31 to the manufacturing unit.
- the direction of the gas flow in the second conduit 37 is indicated by the arrow 38.
- the fluid medium is at least partially recirculated in the cooling device, i. Fluid medium is passed through the first line 34 from the manufacturing unit 33 in the cooling tank 31 and, after it has exited the cooling tank 31 again, returned through the second line 37 in the manufacturing unit 33.
- fluid fluid is not returned to the manufacturing unit 33, but disposed of.
- Fig. 3 is a cooling device 30 according to a second
- the cooling device has a filter 36 arranged in the flow direction (arrows 35, 38) in front of the manufacturing unit 33.
- a filter 36 arranged in the flow direction (arrows 35, 38) in front of the manufacturing unit 33.
- solids and / or liquid droplets are removed from the fluid medium before the fluid medium enters the production unit 33, so that these solids and / or liquids do not enter the production unit 33 and contaminate or even block them.
- the fluid medium is preferably in the cooling device in
- the cooling device 30 has a compressor 39, for example a pump, which is arranged in the flow direction (arrows 35 and 38) in front of the production unit 33 and downstream of the filter 36.
- a circulation of the fluid medium is generated in the cooling device.
- a cooling device 30 according to a fourth embodiment of the present invention is shown schematically.
- the manufacturing unit 33 comprises a container, which can receive a liquid 44 in its interior, and an atomizer 43.
- a carrier gas which is conveyed through the manufacturing unit 33, for example with a compressor (not shown in FIG. 5), is enriched with a liquid 44.
- the cooling device 30 When flowing through a powder bed with a fluid medium can lead to the formation of cracks in the powder bed.
- the cooling device 30 optionally has, in the area of the wall of the cooling tank 31, a vibrator 40, which preferably contains a vibrator and / or knocker. Alternatively or in addition (not shown in the drawings) may be provided as a vibrator 40 also a shaking plate, on which the cooling vessel 31 is mounted.
- the cooling tank 31 has a swap body 41, which is closed by a cover 42 upwards. On the cover 42, the second conduit 37, through which fluid medium can escape from the cooling tank 31, connected; otherwise, the lid closes the cooling tank 31 upwards substantially gas-tight.
- the interchangeable container 41 is the structural container 5, in which the three-dimensional object 2 has been produced by layer-wise selective solidification of a pulverulent structural material 13.
- the construction tank 5 and the cooling tank 31 may be different from each other.
- the three-dimensional object 2 to be cooled and the unconsolidated build-up material 13 to be cooled are in this case transferred from the construction container 5 into the cooling container 31 before the cooling process according to the invention is carried out.
- the cooling tank 31 could also be designed so that it can receive the building container 5 in its interior.
- the building container 5 together with the cooled three-dimensional object 2 contained therein and the unconsolidated building material 13 to be cooled are introduced into the cooling tank 31 before the cooling method of the present invention is performed.
- the cooling device 30 additionally or alternatively has one arranged upstream of the manufacturing unit 33 and downstream of the filter 36
- Compressor 39 at least one compressor, which is arranged in front of the filter 36 and / or after the manufacturing unit 33.
- the building container 5, inside which a manufactured three-dimensional object 2 and the unconsolidated powdery building material 13, in which the three-dimensional object 2 is embedded is taken from the laser sintering or laser melting apparatus 1 and as a cooling container 31 is inserted into the cooling device 30.
- a fluid medium is supplied to the inside of the cooling tank 31 to thereby treat the unbonded building material 13 and the three-dimensional object 2 inside the cooling tank 31.
- the cooling tank 31 and thus the powder bed formed by the unconsolidated building material 13 are flowed through from below with the fluid medium and at least partially fluidized.
- the fluid medium is prepared in the illustrated embodiment by bringing nitrogen, which has room temperature, in contact with liquid water, which also has room temperature, in the manufacturing unit 33, for example by means of the atomizer 43.
- the nitrogen is almost or completely saturated with water.
- the fluid medium is passed through the conduit 34 into the cooling vessel and brought into contact with the unconsolidated abhesive material 13 to be cooled and with the three-dimensional object 2 to be cooled in the interior of the cooling vessel 31, whereby the fluid medium is heated.
- the fluid medium also gives off water inside the cooling tank 31.
- the fluid medium is recirculated in the cooling device 30, wherein the fluid medium exiting from the cooling tank 31, is passed through the conduit 37 in the manufacturing unit 33, in which the fluid medium again receives water until saturation with Water is almost or completely reached. In the manufacturing unit 33, the temperature of the fluid medium may drop again.
- the moisture of unconsolidated building material 13, which had been cooled together with a three-dimensional object 2 produced by laser sintering according to the above-described exemplary embodiment of the method according to the invention was measured with a moisture meter having a capacitive humidity sensor.
- the unconsolidated build-up material was a polyamide 12 powder with a mean particle size d 50 of 50 to 65 ⁇ m, which is, for example, sold by EOS GmbH Electro Optical Systems under the trade name "EOS PA2200”.
- the cooling took place over a period of about 10 hours during which the unreacted building material was continuously flowed through by the fluid medium.
- the fluid medium was nitrogen gas saturated with water.
- the measurement showed a moisture content of 22.1%.
- the moisture meter used (“moisture lance") has a measuring tip, which is held in the unbonded building material 13 for measuring the moisture.
- the moisture was unfixed on Auumaterials 13, which after completion of the laser sintering process together with the three-dimensional object 2 in the interior of the laser sintering device 1 over a period of time allowed to cool down for 18 hours (non-inventively cooled building material 13) measured with the same moisture meter.
- the measurement gave a humidity of 6.2%.
- the method according to the invention therefore results in the unconsolidated building material having a significantly higher moisture content, ie a significantly higher water content. As a result, a better manageable, in particular a better screenable, unconsolidated building material 13 is obtained.
- the method according to the invention gives unconsolidated build-up material 13 which is better suited for reuse, as for the concrete example a comparison of the following values for the melt volume flow rate (MVR as an abbreviation for melt volume flow rate).
- MVR melt volume flow rate
- cooled unsolidified building material 13 a MVR value of 12.51 cm 3/10 min was obtained, while for the non-inventive cooled build material 13 under the same measuring conditions, a MVR value of 8.08 cm 3/10 min was obtained.
- a higher MVR value is equivalent to a better reusability of the powdered building material.
- the MVR values were measured in accordance with the requirements of ISO 1133: 2011. The features of the embodiments described above may be combined and changed as far as possible.
- the invention it is possible to stop the degradation of the unconsolidated building material 13, whereby the refresh rate can be lowered.
- the invention further makes it possible to cool unconsolidated build material 13 more rapidly and thereby shorten the duration of cooling of a three-dimensional object 2 produced by layer-wise selective solidification of a powdery build material and unconsolidated build material 13 into which the three-dimensional object is embedded.
- the cooling is carried out by treatment with a fluid medium.
- the fluid medium may be formed from a carrier gas, which is enriched specifically with a further gas and / or a liquid. That is, the fluid medium is a gas mixture or a
- Aerosol having a composition that is set in a predetermined manner by adding another gas and / or a liquid The terms “enrichment with a gas” and “enrichment with a liquid” mean that another gas (gaseous pure substance or gaseous mixture) or a liquid (liquid pure substance or liquid mixture) is added to the carrier gas, whereby it depends on the state of aggregation What the added gas added to the carrier gas has before adding is important and not whether the added one has this aggregate state after being added.
- the fluid medium can also be formed from a gas mixture which is at least partially removed at least partially a mixture component, ie, the fluid medium may be a gas, the composition by partial or complete withdrawal of one or more mixture components of a gas mixture in a predetermined manner (targeted ) is set.
- the carrier gas used is preferably inert gas, in particular N 2 (nitrogen), which is enriched with water to produce the fluid medium.
- N 2 nitrogen
- a fluid medium can be produced from readily available, inexpensive and environmentally friendly starting materials, in the use of which the above-described advantages of the present invention are particularly pronounced.
- argon can be used as a carrier gas.
- the process according to the invention has proved to be particularly advantageous when the powdery building material contains a polymer or consists of a polymer, since polymers at higher temperatures are susceptible to thermal and / or thermo-oxidative damage, which is the reusability of the unconsolidated Minimize building materials or make reuse impossible.
- polymers present in powder form tend to electrostatic charge.
- the exposure device may comprise, for example, one or more gas or solid-state lasers or any other type of laser such as laser diodes, in particular Vertical Cavity Surface Emitting Laser (VCSEL) or Vertical External Cavity Surface Emitting Laser (VECSEL), or a line of these lasers.
- VCSEL Vertical Cavity Surface Emitting Laser
- VECSEL Vertical External Cavity Surface Emitting Laser
- any device can be used with which energy can be selectively applied as wave or particle radiation to a layer of the building material.
- a laser for example, another light source, an electron beam or any other energy or radiation source can be used which is suitable for solidifying the Aufaumaterial.
- an electron beam or any other energy or radiation source can be used which is suitable for solidifying the Aufaumaterial.
- deflecting a beam it is also possible to use exposure with a movable line imagesetter.
- selective mask sintering using an extended light source and a mask, or high-speed sintering (HSS), which selectively applies to the build material a material that increases the radiation absorption at the respective sites (absorption sintering) ) or reduced (inhibition sintering) and then exposed unselectively over a large area or with a movable line imagesetter the invention can be applied.
- HSS high-speed sintering
- various materials can be used, preferably plastic powder, metal powder, ceramic powder, sand, filled or mixed powder.
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Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE102017211381.2A DE102017211381A1 (de) | 2017-07-04 | 2017-07-04 | Verfahren zum Abkühlen und Abkühlvorrichtung |
PCT/EP2018/065543 WO2019007647A1 (de) | 2017-07-04 | 2018-06-12 | Verfahren zum abkühlen eines dreidimensionalen bauteils und abkühlvorrichtung |
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EP3628035A1 true EP3628035A1 (de) | 2020-04-01 |
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EP18731412.5A Pending EP3628035A1 (de) | 2017-07-04 | 2018-06-12 | Verfahren zum abkühlen eines dreidimensionalen bauteils und abkühlvorrichtung |
Country Status (4)
Country | Link |
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US (1) | US11911968B2 (de) |
EP (1) | EP3628035A1 (de) |
DE (1) | DE102017211381A1 (de) |
WO (1) | WO2019007647A1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110691685B (zh) * | 2017-07-20 | 2022-03-18 | 惠普发展公司,有限责任合伙企业 | 三维(3d)打印机的构建材料再生装置 |
EP3524430B1 (de) | 2018-02-07 | 2021-12-15 | Ricoh Company, Ltd. | Pulver zur feststofffreiformfertigung, und verfahren zur feststofffreiformfertigung von objekten |
US11541602B2 (en) * | 2018-04-06 | 2023-01-03 | Hewlett-Packard Development Company, L.P. | Controlling moisture content of build material in a three-dimensional (3D) printer |
DE102019131059A1 (de) | 2019-11-18 | 2021-05-20 | Heraeus Additive Manufacturing Gmbh | Wechselbaubehälter und Vorrichtung für die Additive Fertigung eines Werkstücks, Prozessstation und System dafür |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4818562A (en) * | 1987-03-04 | 1989-04-04 | Westinghouse Electric Corp. | Casting shapes |
DE19514740C1 (de) | 1995-04-21 | 1996-04-11 | Eos Electro Optical Syst | Vorrichtung und Verfahren zum Herstellen eines dreidimensionalen Objektes |
DE19937260B4 (de) | 1999-08-06 | 2006-07-27 | Eos Gmbh Electro Optical Systems | Verfahren und Vorrichtung zum Herstellen eines dreidimensionalen Objekts |
US7468405B2 (en) | 2002-10-23 | 2008-12-23 | Atofina | Increase in the melting point and the enthalpy of melting of polyamides by a water treatment |
FR2846333B1 (fr) * | 2002-10-23 | 2004-12-03 | Atofina | Augmentation du point de fusion et de l'enthalpie de fusion des polyamides par un traitement a l'eau |
US7521652B2 (en) * | 2004-12-07 | 2009-04-21 | 3D Systems, Inc. | Controlled cooling methods and apparatus for laser sintering part-cake |
US20100155985A1 (en) | 2008-12-18 | 2010-06-24 | 3D Systems, Incorporated | Apparatus and Method for Cooling Part Cake in Laser Sintering |
DE102012106141B4 (de) | 2012-07-09 | 2018-04-26 | Exone Gmbh | Verfahren und vorrichtung zum entpacken eines bauteils |
DE102012216515A1 (de) * | 2012-09-17 | 2014-03-20 | Evonik Industries Ag | Verfahren zur schichtweisen Herstellung von verzugsarmen dreidimensionalen Objekten mittels Kühlelementen |
DE102013212620A1 (de) | 2013-06-28 | 2014-12-31 | Trumpf Gmbh + Co. Kg | Verfahren und Bearbeitungsmaschine zum Generieren eines dreidimensionalen Bauteils durch selektives Laserschmelzen |
DE102014000415A1 (de) * | 2014-01-17 | 2015-07-23 | Cl Schutzrechtsverwaltungs Gmbh | Vorrichtung zum Herstellen von dreidimensionalen Objekten durch aufeinanderfolgendes Verfestigen von Schichten |
CN108436082A (zh) * | 2014-06-20 | 2018-08-24 | 维洛3D公司 | 用于三维打印的设备、系统和方法 |
DE102017200773A1 (de) * | 2017-01-18 | 2018-07-19 | Eos Gmbh Electro Optical Systems | Verfahren zum Nachbehandeln und Nachbehandlungssytem |
US10406751B2 (en) * | 2017-04-14 | 2019-09-10 | Desktop Metal, Inc. | Automated de-powdering with level based nesting |
-
2017
- 2017-07-04 DE DE102017211381.2A patent/DE102017211381A1/de active Pending
-
2018
- 2018-06-12 WO PCT/EP2018/065543 patent/WO2019007647A1/de unknown
- 2018-06-12 EP EP18731412.5A patent/EP3628035A1/de active Pending
- 2018-06-12 US US16/628,141 patent/US11911968B2/en active Active
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WO2019007647A1 (de) | 2019-01-10 |
US11911968B2 (en) | 2024-02-27 |
DE102017211381A1 (de) | 2019-01-10 |
US20200223140A1 (en) | 2020-07-16 |
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