EP2905348B1 - Hochfestes Stahlflachprodukt mit bainitisch-martensitischem Gefüge und Verfahren zur Herstellung eines solchen Stahlflachprodukts - Google Patents
Hochfestes Stahlflachprodukt mit bainitisch-martensitischem Gefüge und Verfahren zur Herstellung eines solchen Stahlflachprodukts Download PDFInfo
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- EP2905348B1 EP2905348B1 EP14154354.6A EP14154354A EP2905348B1 EP 2905348 B1 EP2905348 B1 EP 2905348B1 EP 14154354 A EP14154354 A EP 14154354A EP 2905348 B1 EP2905348 B1 EP 2905348B1
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- 229910000831 Steel Inorganic materials 0.000 title claims description 110
- 239000010959 steel Substances 0.000 title claims description 110
- 229910000734 martensite Inorganic materials 0.000 title claims description 32
- 238000004519 manufacturing process Methods 0.000 title claims description 28
- 238000000034 method Methods 0.000 title claims description 15
- 238000005096 rolling process Methods 0.000 claims description 36
- 238000005098 hot rolling Methods 0.000 claims description 32
- 229910001563 bainite Inorganic materials 0.000 claims description 23
- 238000001816 cooling Methods 0.000 claims description 22
- 229910052804 chromium Inorganic materials 0.000 claims description 15
- 229910052750 molybdenum Inorganic materials 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- 229910001566 austenite Inorganic materials 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 229910052748 manganese Inorganic materials 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 11
- 229910052720 vanadium Inorganic materials 0.000 claims description 11
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 239000012535 impurity Substances 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000000314 lubricant Substances 0.000 claims description 8
- 229910052796 boron Inorganic materials 0.000 claims description 7
- 239000000470 constituent Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 229910052787 antimony Inorganic materials 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000000161 steel melt Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 238000005266 casting Methods 0.000 claims 1
- 239000011651 chromium Substances 0.000 description 15
- 239000011572 manganese Substances 0.000 description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 239000010955 niobium Substances 0.000 description 9
- 239000010949 copper Substances 0.000 description 7
- 229910000859 α-Fe Inorganic materials 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 238000005275 alloying Methods 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 230000008092 positive effect Effects 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 238000005496 tempering Methods 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910004709 CaSi Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000005088 metallography Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/002—Heat treatment of ferrous alloys containing Cr
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/005—Heat treatment of ferrous alloys containing Mn
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
Definitions
- the invention relates to a high-strength steel flat product with a ferrite-free structure, which consists for the most part of martensite and bainite, wherein in the microstructure in addition small amounts of retained austenite may be present.
- the invention relates to a method for producing a flat steel product according to the invention.
- Flat steel products of the type in question are typically rolled products, such as steel strips or sheets, as well as blanks and blanks made therefrom.
- High-strength strip sheets are becoming increasingly important, as not only technical performance, but also resource efficiency and climate protection play an important role today play.
- the reduction of the dead weight of a steel structure can be achieved by increasing the strength properties.
- high-strength steel strips and sheets have to meet high demands on toughness properties and brittle fracture resistance, behavior in cold forming, and weldability.
- From the EP 1 669 470 A1 is a hot rolled steel sheet having a steel composition comprising (in wt%) 0.01-0.2 wt% C, 0.01-2% Si, 0.1-2% Mn, up to 0, 1% P, up to 0.03% S, 0.001-0.1% Al, up to 0.01% N and the remainder being Fe and unavoidable impurities.
- the flat steel product has a substantially homogeneous and continuously cooled microstructure with an average particle size of 8 .mu.m to 30 .mu.m . To achieve this, a slab of the above composition is pre-rolled.
- the obtained pre-rolled slab is then hot rolled to a hot strip at a hot rolling end temperature of at least 50 ° C above the Ar3 temperature of the steel. Subsequently, the finished hot-rolled hot strip is cooled after a break of at least 0.5 seconds at a cooling rate of at least 80 ° C / sec of the Ar3 temperature to a less than 500 ° C amounting coiler temperature and finally wound into a coil.
- WO 03/031669 A1 Furthermore, a high-strength thin steel sheet is known, which is deep drawable and thereby has an excellent dimensional stability. Moreover, this publication describes a method for producing such a flat steel product.
- the steel sheet in question is characterized by a certain ratio of the X-ray intensities of certain crystallographic orientations and has a certain roughness Ra and a certain friction coefficient of the steel sheet surface at up to 200 ° C and has a lubricant effect.
- a suitably assembled hot strip is produced by hot rolling at a total reduction ratio of at least 25% at a temperature which is in a range between the Ar3 temperature and the Ar3 temperature + 100 ° C. All flat steel products produced by this process contain ferrite in the microstructure.
- a steel sheet consisting of a high-strength, low-alloy steel, which (in wt .-%) of C: 0.08 - 0.20%; Si: 0.10-0.60%; Mn: 1.00-2.00%; B: 0.0005 - 0.0040%; Cr: up to 1.50%; Mo: up to 0.80%; Ni: up to 1.50%; Nb: up to 0.080%; V: up to 0.080%; Ti: up to 0.060%; Al: 0.010-0.080%, Ca: 0.0010-0.0080%, N: up to 0.0080%, O: up to 0.0080%, H: up to 0.0004%, P: up to 0.015 %, S: up to 0.010%, remainder iron and unavoidable impurities, wherein for the Cr, Mn and B content 0.20 ⁇ (Cr / 5 + Mn / 6 + 50B) ⁇ 0.55%, for Mo, Ni and Nb
- the composite steel sheets have a structure consisting of fine martensite, which may contain up to 5% by volume of retained austenite as the only other constituent of the structure.
- the sheets produced in this way have thicknesses of at least 16 mm and are suitable for applications in which they are exposed to high wear loads.
- the object of the invention was to provide a flat steel product which can be produced with reduced expenditure and not only has optimum mechanical properties, such as high strength and at the same time good toughness, but also one has good weldability.
- the solution according to the invention of the above-stated object is that during the production of flat steel products according to the invention, the working steps enumerated in claim 5 are run through.
- a flat steel product according to the invention has a bainitic-martensitic structure in the hot-rolled state, which does not have ferrite, but consists of at least 95% by volume of martensite and bainite with a martensite content of at least 5% by volume.
- a total of up to 5% by volume of retained austenite and production-related unavoidable microstructural constituents are permitted.
- a flat steel product according to the invention contains 0.08-0.10% C, 0.015-0.5% Si, 1.20-2.00% Mn, 0.020-0.040% Al , 0.30-1.00% Cr, 0.20-0.30% Mo, 0.020-0.030% Nb, 0.0015-0.0025% B, up to 0.025% P, up to 0.010% S, to to 0.006% N, especially 0.001-0.006% N.
- Contaminants include up to 0.12% Cu, up to 0.090% Ni, up to 0.0030% Ti, up to 0.009% V, up to 0.0090% Co, up to 0.004% Sb and up to 0.0009% W.
- a flat steel product according to the invention when hot-rolled, has a minimum yield strength of 900 MPa with simultaneously good elongation at break.
- the yield strengths of flat steel products according to the invention are in the range of 900-1200 MPa.
- the elongation at break is typically at least 8% and the tensile strength is typically 950 - 1300 MPa.
- the notch impact work at -20 ° C is also typically in the range of 65-115 J. At -40 ° C, the notch impact work on flat steel products according to the invention is typically 40-120 years.
- An essential advantage of the invention over the known prior art is that a Steel flat product according to the invention which achieves high strength and good toughness in the hot rolling state without additional heat treatment.
- steel according to the invention has a structure of bainite and at least 5% by volume of martensite, but has no ferrite.
- the Martensitanteil in the structure of the steel according to the invention contributes significantly to its strength.
- the microstructure of the flat steel product according to the invention is fine-grained and thus ensures good elongation at break and toughness.
- the average grain size of the structure is a maximum of 20 ⁇ m.
- Copper, nickel, titanium, vanadium, cobalt, tungsten, antimony are the steel from which a flat steel product according to the invention consists, not selectively alloyed, but occur as production-related unavoidable accompanying elements.
- the Cu content is limited to 0.12 wt% in order to avoid adverse effects on weldability and toughness in the heat affected zone of a weld made on the flat steel product.
- the other production-related unavoidable existing, above-mentioned alloy components are likewise to be limited in their contents in such a way that in each case they have no influence on the properties of the flat steel product according to the invention.
- W meets the condition: CE ⁇ W ⁇ 0.5
- the rough-rolling temperature is in the temperature range from 950 ° C to 1250 ° C.
- the lower limit of the roughing temperature range and the minimum value of the sum of the number of passes obtained by roughing are set so that the recrystallization processes can still be completed. This results in a fine-grained austenite before finish rolling, which has a positive effect on the toughness properties and elongation at break.
- the final rolling temperature of the hot rolling carried out in a rolling scale usually comprising a plurality of rolling stands is 810 ° C. to 875 ° C.
- the upper limit of the predetermined according to the invention for the final rolling temperature range is set so that no recrystallization of the austenite takes place during rolling in the Fertigwarmwalz Sounds. Accordingly, a fine-grained structure is created after the phase transformation.
- the lower limit of the finish rolling temperature range is 810 ° C. At this temperature, no ferrite is formed during hot rolling, so that the hot strip is free of ferrite at the exit from the hot rolling mill.
- the interval between the end of hot rolling and the start of cooling should not exceed 10 s in order to prevent unwanted microstructure constituents from forming in the flat steel product.
- the structure of the thus-cooled hot rolled flat steel product according to the invention already comprises at least 95% by volume of bainite and martensite on arrival in the coiling station, in which the flat steel product is wound into a coil.
- the inventively prescribed range of reel temperature is chosen so that the desired bainitic - martensitic microstructure in the finished invention flat steel product is safe. At a reel temperature above 500 ° C., the desired bainitic-martensitic structure would not be achieved, with the result that the mechanical properties desired according to the invention, such as high strength and toughness, would not be achieved either.
- the lower limit of the coiler temperature should not be exceeded in order to ensure optimum flatness and surface of the flat steel product according to the invention without subsequent treatment and at the same time to achieve the desired tempering effect in the coil.
- the residual microstructures present in addition to bainite and martensite in martensite, bainite or retained austenite, as well as other production-related unavoidable components, but ineffective with regard to the properties of the flat steel product according to the invention.
- the thickness of hot-rolled flat steel products produced according to the invention is 2 to 12 mm.
- the hot strip produced in each case is therefore directly from the rolling heat after the thermomechanical rolling, by the combination of a pre-rolling performed according to the invention with a finished hot rolling also carried out according to the invention is cooled at high cooling rates, in such a way that the desired structure and thus the mechanical properties are set without subsequent heat treatment.
- the hot rolling in the hot rolling mill is carried out according to the invention specifically without application of lubricant to the hot strip, the surface of the flat steel product is free of lubricant on leaving the hot rolling stand.
- Dispensing with lubricant has the advantage that the effort associated with the application of lubricant in the rolling process is eliminated and thus ensures greater efficiency of the overall process. At the same time, by eliminating lubricants, resources are conserved and the environmental and climate impact minimized.
- the procedure according to the invention in the production of flat steel products according to the invention has the advantage that the phase transformation takes place after the end of hot rolling from a dislocation-rich austenite with high cooling rates. In this way, a fine-grained bainitic-martensitic structure and good toughness or elongation at break properties are achieved.
- the method according to the invention requires a composition of the steel flat product produced according to the invention, which is characterized by low-cost alloying elements present in comparatively low contents. Expensive and rare alloying elements are not required for the production of a flat steel product according to the invention, so that in this respect too, the production of flat steel products according to the invention is associated Production costs are minimized.
- the alloy concept based on minimized alloy contents contributes to optimum weldability of flat steel products according to the invention.
- the surface finishes of hot-rolled flat steel products according to the invention are improved over conventionally produced high-strength hot strips. At the same time, the production costs are reduced.
- the inventively provided manufacturing path is much simpler, so that it can be carried out with less effort and secure success.
- One of the essential features of the method of manufacture according to the invention is therefore that the mechanical properties are adjusted by the rolling process, the subsequent rapid cooling and the reeling. Further heat treatments after reeling are not necessary with the procedure according to the invention in order to set the desired properties of the particular flat steel product according to the invention.
- the high toughness and elongation at break of a flat steel product according to the invention is rather achieved without subsequent heat treatment.
- the invention thus provides a flat steel product with a minimum yield strength of 900 MPa, whose range of properties make it particularly suitable for the lightweight construction of commercial vehicle chassis and other body parts that are exposed to high loads during use.
- melts S1, S2 Two steel melts S1, S2 have been produced in the laboratory, the compositions of which are given in Table 1.
- the melts S1, S2 have each been cast into slabs. Due to the laboratory conditions, the dimensions of the slabs cast from the steels S1, S2 each were 150 mm ⁇ 150 mm ⁇ 500 mm.
- the slabs were each heated to an austenitizing temperature T A.
- the slabs thus heated or held at the respective austenitizing temperature T A are then pre-rolled at roughing temperatures T V and Vorwalzumformgraden e V and then hot rolled at Fertigwalzumformgraden e F and hot rolling end temperatures T WE to hot strips W1 - W17 with a thickness d of 3-10 mm ,
- the obtained hot strips W1-W17 were accelerated at a cooling rate dT to a coiling temperature T H , at which they were subsequently wound into a coil.
- the steel from which the respective hot strip W1-W17 was produced is shown, as well as the respectively set austenitizing temperature T A , the rough-rolling temperature T V , the pre-rolling deformation degree e V , the hot rolling end temperature T WE , the total degree of deformation e F achieved via the finish hot rolling, the thickness d, the cooling rate dT and the reel temperature T H.
- the structural analysis was carried out by means of light and Scanning electron microscopy on longitudinal sections. For this, the samples were taken from a quarter of the bandwidth of the hot strips W1 - W17 and etched with Nital or sodium disulfite.
- the microstructure of the hot strips W1-W9 produced according to the invention and the hot strips W12-W16 likewise produced according to the invention has between 5% and 33% martensite, with the remainder each consisting of bainite.
- the hot strips produced according to the invention each have high strength values in combination with good elongation properties.
- the structure consists only of bainite.
- the hot strips W10, W11 and W17 not according to the invention do not reach the optimum combination of properties which characterizes the hot strips W1-W9 and W12-W16 produced according to the invention.
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- Chemical & Material Sciences (AREA)
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- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14154354.6A EP2905348B1 (de) | 2014-02-07 | 2014-02-07 | Hochfestes Stahlflachprodukt mit bainitisch-martensitischem Gefüge und Verfahren zur Herstellung eines solchen Stahlflachprodukts |
RU2016135949A RU2675191C2 (ru) | 2014-02-07 | 2015-02-03 | Высокопрочный плоский стальной прокат с бейнитно-мартенситной микроструктурой и способ изготовления такого плоского стального проката |
US15/116,958 US10724113B2 (en) | 2014-02-07 | 2015-02-03 | High-strength flat steel product having a bainitic-martensitic microstructure and method for producing such a flat steel product |
PCT/EP2015/052135 WO2015117934A1 (de) | 2014-02-07 | 2015-02-03 | Hochfestes stahlflachprodukt mit bainitisch-martensitischem gefüge und verfahren zur herstellung eines solchen stahlflachprodukts |
AU2015215080A AU2015215080B2 (en) | 2014-02-07 | 2015-02-03 | High-strength flat steel product having a bainitic-martensitic microstructure and method for producing such a flat steel product |
BR112016016949-2A BR112016016949B1 (pt) | 2014-02-07 | 2015-02-03 | produto plano de aço e método para produzir um produto plano de aço |
MX2016009530A MX2016009530A (es) | 2014-02-07 | 2015-02-03 | Producto plano de acero de alta resistencia con estructura bainitica-martensitica y procedimiento para la fabricacion de un producto plano de acero de este tipo. |
CA2936733A CA2936733C (en) | 2014-02-07 | 2015-02-03 | High-strength flat steel product having a bainitic-martensitic microstructure and method for producing such a flat steel product |
Applications Claiming Priority (1)
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EP14154354.6A EP2905348B1 (de) | 2014-02-07 | 2014-02-07 | Hochfestes Stahlflachprodukt mit bainitisch-martensitischem Gefüge und Verfahren zur Herstellung eines solchen Stahlflachprodukts |
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EP2905348B1 true EP2905348B1 (de) | 2019-09-04 |
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US (1) | US10724113B2 (es) |
EP (1) | EP2905348B1 (es) |
AU (1) | AU2015215080B2 (es) |
BR (1) | BR112016016949B1 (es) |
CA (1) | CA2936733C (es) |
MX (1) | MX2016009530A (es) |
RU (1) | RU2675191C2 (es) |
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RU2810463C1 (ru) * | 2023-08-04 | 2023-12-27 | Публичное акционерное общество "Северсталь" (ПАО "Северсталь") | Способ производства высокопрочного горячекатаного проката |
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JP6536331B2 (ja) * | 2015-10-05 | 2019-07-03 | 日本製鉄株式会社 | 高強度鋼板及びその製造方法 |
ES2824461T3 (es) * | 2017-02-10 | 2021-05-12 | Outokumpu Oy | Componente de acero fabricado por conformado en caliente, método de fabricación y uso del componente |
CN108315662B (zh) * | 2018-03-30 | 2019-11-01 | 湖南华菱涟源钢铁有限公司 | 一种屈服强度900MPa级热轧钢板及其生产工艺 |
EP3719147A1 (de) * | 2019-04-01 | 2020-10-07 | ThyssenKrupp Steel Europe AG | Warmgewalztes stahlflachprodukt und verfahren zu seiner herstellung |
US11965224B2 (en) * | 2020-02-17 | 2024-04-23 | Nippon Steel Corporation | Steel sheet for can and manufacturing method thereof |
CN111394650A (zh) * | 2020-03-27 | 2020-07-10 | 武汉钢铁有限公司 | 具有优良成形性的高r值800MPa级冷轧钢及生产方法 |
CN111500940B (zh) * | 2020-06-08 | 2020-10-16 | 南京工程学院 | 具有抑制摩擦火花特性的合金钢锻造制动盘及其制造方法 |
CN112647014B (zh) * | 2020-11-23 | 2022-03-22 | 首钢集团有限公司 | 一种适用于海洋大气环境用建筑结构钢及其生产方法 |
CN112981230B (zh) * | 2021-01-20 | 2022-07-29 | 江阴兴澄特种钢铁有限公司 | 一种双电源切换开关齿轮轴销用钢及其制造方法 |
JP7533413B2 (ja) | 2021-09-29 | 2024-08-14 | Jfeスチール株式会社 | 耐疲労き裂伝播特性に優れた鋼板の製造方法 |
CN114525388A (zh) * | 2022-02-21 | 2022-05-24 | 刘鑫 | 一种上贝氏体层状组织钢及其制备方法 |
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EP1832667A1 (fr) * | 2006-03-07 | 2007-09-12 | ARCELOR France | Procédé de fabrication de tôles d'acier à très hautes caractéristiques de résistance, de ductilité et de tenacité, et tôles ainsi produites |
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- 2014-02-07 EP EP14154354.6A patent/EP2905348B1/de active Active
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2015
- 2015-02-03 WO PCT/EP2015/052135 patent/WO2015117934A1/de active Application Filing
- 2015-02-03 MX MX2016009530A patent/MX2016009530A/es unknown
- 2015-02-03 AU AU2015215080A patent/AU2015215080B2/en not_active Ceased
- 2015-02-03 BR BR112016016949-2A patent/BR112016016949B1/pt active IP Right Grant
- 2015-02-03 CA CA2936733A patent/CA2936733C/en active Active
- 2015-02-03 RU RU2016135949A patent/RU2675191C2/ru active
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Also Published As
Publication number | Publication date |
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CA2936733C (en) | 2019-02-26 |
US10724113B2 (en) | 2020-07-28 |
MX2016009530A (es) | 2016-10-26 |
EP2905348A1 (de) | 2015-08-12 |
RU2016135949A (ru) | 2018-03-15 |
US20170081739A1 (en) | 2017-03-23 |
CA2936733A1 (en) | 2015-08-13 |
BR112016016949B1 (pt) | 2021-03-09 |
RU2016135949A3 (es) | 2018-07-24 |
AU2015215080A1 (en) | 2016-08-18 |
RU2675191C2 (ru) | 2018-12-17 |
WO2015117934A1 (de) | 2015-08-13 |
AU2015215080B2 (en) | 2019-04-11 |
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