EP1765481A2 - Water-filtering media and filters - Google Patents
Water-filtering media and filtersInfo
- Publication number
- EP1765481A2 EP1765481A2 EP05724413A EP05724413A EP1765481A2 EP 1765481 A2 EP1765481 A2 EP 1765481A2 EP 05724413 A EP05724413 A EP 05724413A EP 05724413 A EP05724413 A EP 05724413A EP 1765481 A2 EP1765481 A2 EP 1765481A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- alcohol
- filter
- fuel
- filtering media
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G33/00—Dewatering or demulsification of hydrocarbon oils
- C10G33/06—Dewatering or demulsification of hydrocarbon oils with mechanical means, e.g. by filtration
Definitions
- Ethanol have been blended into gasoline to act as an oxygenate to reduce the amount of semi-combusted hydrocarbons that are discharged into the atmosphere by motor vehicles.
- Ethanol i.e., Ethanol
- MTBE's have been determined to be a potential contaminant to aquifers and well water due to their ability to resist biodegradation.
- MTBE's are possibly hazardous as a carcinogen.
- Ethanol is a possible alternative to MTBE's, but attracts water more aggressively than MTBE alcohol. As a result, the amount of water that may be drawn into Ethanol-blended fuels is increased.
- Ethanol blended fuels as high as eighty-five percent Ethanol to fifteen percent gasoline (E-85 Fuel) are being investigated for use in the fuel dispensing industry.
- E-85 Fuel the objective of fuels such as E-85 is to provide a fuel that reduces atmospheric pollutions over that produced from hydrocarbon fuels and to reduce dependence on foreign oil.
- the auto industry has begun producing engines capable of using both regular gasoline fuel and E-85 fuel.
- the fuel dispensing industry has developed fuel dispensers capable of dispensing E-85 without rusting or otherwise damaging the dispensers.
- improvements in filtration technology are needed to effectively remove water from alcohol-blended fuels such as E-85.
- phase-separate fuel i.e., phase-separate fuel
- lower burn temperatures e.g., temperatures produced by a fuel containing less alcohol than expected
- higher burn temperatures e.g., temperatures produced by a fuel containing more alcohol than expected
- a lower burn temperature increases pollutants and a higher burn temperature is potentially damaging to engine parts.
- phase-separated water acts as an abrasive causing damage to engine parts.
- Existing water filters implement water-absorbing polymers having an anionic (negative) valence.
- water-absorbing polymers attract and bond with the cationic (positive) valence of the water (H 2 O) molecules that are passing through the water-absorbing media of the filter.
- the alcohol due to its strong negative valence field
- the combined influence of the covalent bond between alcohol- water molecules and the repulsion of the alcohol molecules from the water-absorbing polymers prevents current water-absorbing polymers from filtering (i.e., removing or retaining) water effectively.
- the water-absorbing polymers are derived from organic biomass such as cornstarch or cellulose with a methacrylic or other acid to form the water-absorbing polymers.
- the organic base of these water-absorbing polymers is subject to being degraded by bacteria and other microorganisms (i.e., life forms) that are normally found in water that is in gasoline or diesel storage tanks.
- the carbohydrate (starch) portion of these polymers acts as a food source that allows the life forms that are in water to proliferate within the filter. These life forms can disarm the filter's ability to remove water from fuel or to hold water that had previously been removed.
- a filter comprises a filtering media.
- the filtering media is impregnated with chemical compounds that effectively retain water molecules and water-alcohol molecules but not alcohol molecules.
- the filter also comprises a liquid channeling structure, wherein the liquid channeling structure directs liquid entering an input of the filter to flow through the filtering media before exiting an output of the filter.
- the filtering media comprises a polymer backbone and monomer groups on the polymer backbone. The monomer groups exhibit a negative valence upon exposure to water and a positive valence upon exposure to alcohol, wherein water-alcohol molecules that are introduced to the water-filtering media bond with at least one negative valence monomer group and at least one positive valence monomer group.
- the monomer groups are selected from non-naturally occurring monomers that are resistant to biodegradation due to life- forms found in water.
- the filters may be implemented in the form of spin-on filters, in-line filters or cartridge filters. Also, the filters may be implemented in fuel dispensing systems, vehicles or portable units to filter alcohol-blended fuels such as E-85. If the filter retains more than a threshold amount of water molecules or water-alcohol molecules, the filter prevents the flow of fuel.
- a user of the filter is able to monitor the amount of water being collected in a fuel tank by tracking how often a filter needs to be replaced. In this manner, a user can approximate when phase- separation of water in a fuel tank has occurred or will soon occur.
- Figure 1 illustrates a filtering media in accordance with embodiments of the invention
- Figure 2 illustrates using the filter media in accordance with embodiments of the invention
- Figure 3 illustrates a cross-section view of a filter in accordance with embodiments of the invention
- Figure 4 illustrates a portion of the filter of Figure 3 before filtering water in accordance with embodiments of the invention
- Figure 5 illustrates a portion of the filter of Figure 3 after filtering water in accordance with embodiments of the invention
- Figure 6 illustrates a fuel dispensing system in accordance with embodiments of the invention
- Figure 7 illustrates a filtering process in accordance with alternative embodiments of the invention
- Figure 8 illustrates a method in accordance with embodiments of the invention.
- FIG. 1 illustrates a filtering media 100 (e.g., a laminated media) in accordance with embodiments of the invention.
- the filtering media 100 comprises a water-absorbing structure 102 between a particle-removing medium 104 and another medium 106.
- the particle-removing medium 104 comprises a micro-glass or cellulose medium capable of filtering particles that range in size, for example, between 5 and 50 microns.
- the particle-removing medium 104 may comprise another particle-removing medium now known or later developed (e.g., a paper medium).
- the other medium 106 may comprise a layer of woven or non-woven material.
- the water-absorbing structure 102 comprises a fiber-glass matting 108 that has been impregnated with a water-absorbing polymer 110.
- the water- absorbing polymer 110 comprises a non-organic based crossed-linked polymer.
- the water-absorbing polymer 110 may be based on synthetically-produced non-naturally occurring monomers. Because the water-absorbing polymer 110 does not contain organic constituents or carbohydrates, biodegradation from bacteria and microorganisms that are in water found in fuel storage tanks is avoided.
- the constituents of the water-absorbing polymer 110 are chosen from non-naturally occurring monomers that exhibit a strong negative valence field on exposure to water and a less strong positive valence field on exposure to an alcohol.
- the valence of the water-absorbing polymer 110 is unique due to the selection of monomers of the polymerization formula.
- the water-absorbing polymer 110 contains both cationic and anionic groups that are attached to the backbone of the polymeric structure. The magnetic fields exhibited by the cationic groups and the anionic groups facilitate the water-absorbing polymer's ability to encapsulate water even if the water is covalently bonded to alcohol groups of an alcohol-blended fuel such as E-85.
- the cationic and anionic groups can be derived from non-organic groups that exhibit a negative charge upon exposure to water and a positive charge upon exposure to an alcohol.
- the water-absorbing polymer 110 is derived from non-organic and non- naturally occurring monomers that are selected from carboxylate, sulfate, phosphate, sulfonates, phosphonates, propenoic acids, alpha-methyl-propenoic acids, beta-methyl-propenoic acids, poly- acrylic acids, acrylic acids, maleic acids, fumaric acids, maleic anhydrides, fumaric anhydrides, alpha-ethylenically unsaturated mono- carboxycilic acids, beta-ethylenically unsaturated mono- carboxycilic acids, alpha-ethylenically unsaturated di-carboxycilic acids, beta-ethylenically unsaturated di-carboxycilic acids, alpha-ethylenically unsaturated mono-carboxycilic an
- the monomers of the water-absorbing polymer 110 comprise salts such as alkali ions, lithium ions, sodium ions, potassium ions. Additionally or alternatively, the monomers of the water-absorbing polymer 110 comprise earth metals such as magnesium ions, calcium ions, strontium ions, barium ions, zinc ions and aluminum ions.
- the polymer chemistry is selected to provide a crossed-linked water-absorbing polymer that is able to absorb water even if an alcohol is covalently bonded to the water.
- Figure 2 illustrates using the filtering media 100 in accordance with embodiments of the invention. As shown in Figure 2, contaminated blended fuel 202 is introduced to the filtering media 100.
- the contaminated blended fuel 202 contains water-alcohol groups 204 (i.e., water covalently bonded to an alcohol), fuel groups 206 and alcohol groups 210.
- the contaminated blended fuel 202 also may contain water groups 208 (i.e., water that is not covalently bonded to an alcohol) and solid particles 212.
- the filtering media 100 removes the contaminants (e.g., water-alcohol groups 204, the water groups 208 and the particles groups 212) such that substantially only the fuel groups 206 and the alcohol groups 210 of the blended fuel are able to pass through the filtering media 100.
- the solid particles 212 are filtered by the particle-removing medium 104.
- the water-alcohol groups 204 and the water groups 208 are filtered by the water-absorbing structure 102 which comprises both positive valence groups HOP and negative valence groups 1 ION.
- the water-alcohol groups 204 orient themselves and bond to at least one positive valence group HOP and at least one negative valence group HON.
- the water portion (which has a positive valence) of each water-alcohol group 204 is attracted to and bonds with at least one negative valence group 11 ON while the alcohol portion (which has a negative valence) of each water-alcohol group 204 is attracted to and bonds with at least one positive valence group HON.
- each water group 208 is bonded to at least one negative valence group 1 ION.
- the negative valence field exhibited by each negative valence group 1 ION may be stronger than the positive valence field exhibited by each positive valence group HOP such that water groups 208 and water-alcohol groups 208 are effectively held by the water-absorbing structure 102.
- a filtered blended fuel 220 containing substantially only fuel groups 206 and alcohol groups 210 remains.
- Figure 3 illustrates a simplified cross-section view of a filter 300 in accordance with embodiments of the invention.
- the filter 300 comprises two end caps 302 and 314 and an outer cover or sheath 320.
- the end cap 302 has an opening 304 that allows blended fuel to enter the filter 300 and the end cap 314 has an opening 316 that allows filtered blended fuel to exit the filter 300.
- the filter 300 also comprises a center tube 306 having perforations 308.
- the center tube 306 having perforations 308.
- the filtering media 100 is pleated as will later be described. Both the center tube 306 and the filtering media 100 are secured to the end caps 302 and 314 using an adhesive 310 that is not solvated by water, alcohol, diesel or gasoline.
- the dashed lines 312 illustrate the flow of a blended fuel such as E-85 through the filter
- the blended fuel may enter through the opening 304 of the end cap 302.
- the blended fuel is forced to the outer perimeter of filter's inner chamber such that the blended fuel must pass through the filtering media 100.
- the filtering media 100 is configured to filter contaminants such as particles, water molecules and water-alcohol molecules. As the filtering media 100 retains water molecules and water-alcohol molecules, the filtering media 100 expands. Thus, space 318 is provided within the filter 300 to allow the filtering media 100 to expand.
- the blended fuel After passing though the filtering media 100, the blended fuel enters the inside of the center tube 306 via the perforations 308.
- the filtered blended fuel exits the filter 300 through the opening 316 of the end tube 314.
- Embodiments of the invention are not limited to the filter 300 illustrated in Figure 3.
- the filter 300 illustrates one of many possible embodiments that would force a blended fuel to pass through the filtering media 100 thereby filtering the blended fuel as desired.
- Various filter sizes such as 4"x5" and 7"xl8" filters are intended.
- various types of filters such as spin-on filters, inline filters and cartridge filters are intended.
- Figure 4 illustrates a portion of the filter 300 before filtering water in accordance with embodiments of the invention.
- the outer cover of the filter is not shown.
- the filter 300 comprises a center tube 306 having perforations 308.
- the center tube 306 is surrounded by the filtering media 100 in a pleated arrangement 320.
- FIG. 5 illustrates a portion of the filter 300 after filtering water in accordance with embodiments of the invention.
- the pleats 320 of the filtering media 100 have swelled.
- the water-absorbing structure 102 shown in Figures 1 and 2 swells and presses against the particle-filtering medium 104 and the other medium 106 previously described.
- the mediums 104 and 106 are flexible, the swelling expands the pleats 320 to press against the inside chamber of the filter 300 (between the center tube 306 and the outer cover or sheath 320).
- the filter 300 and the filtering media 100 enable water retention that is significantly greater than existing water-absorbing filters of comparable size.
- a 4"x5" filter embodiment retains approximately 12 ounces of water and a 7"xl8" filter embodiment retains approximately one gallon of water.
- the filter 300 absorbs a threshold amount of water (e.g., approximately 10 ounces for a 4"x5" filter)
- the pleats 320 press together with sufficient pressure to prevent fuel flow though the filter 300. hi this manner, contaminated fuel is prevented from being dispensed to a vehicle or to a vehicle's engine.
- phase-separated fuel relates to an uneven distribution of alcohol in an alcohol-blended fuel (i.e., the fuel is separating from the alcohol or vice versa) and phase-separated water relates to water that is unable to be dissolved by an alcohol-blended fuel (e.g., water in excess of a threshold amount that is dissolvable in the alcohol-blended fuel becomes phase-separated water).
- FIG. 6 illustrates a fuel dispensing system 600 in accordance with embodiments of the invention.
- the fuel dispensing system 600 comprises a fuel tank 602 and a fuel dispenser 610.
- the fuel dispenser 610 comprises a fuel pump 612 and a filter 614 that uses the filtering media 100.
- the fuel tank 602 contains alcohol-blended fuel (i.e., alcohol molecules 210 blended with fuel molecules 206) such as E-85.
- alcohol-blended fuel i.e., alcohol molecules 210 blended with fuel molecules 206
- water molecules 208 and solid particles 212 may contaminate the alcohol-blended fuel.
- water molecules 208 from the atmosphere 630 may be drawn to the alcohol molecules 210 in the fuel tank 602 creating water- alcohol molecules 204.
- phase-separated fuel and phase-separated water can occur within the fuel tank 602.
- a vehicle 620 e.g., a car, a truck or another vehicle having an engine
- a user is able to fill a fuel tank 622 of the vehicle 620 by accessing the fuel dispenser 610.
- the fuel tank 602 and the fuel dispenser 610 may be part of a service station that provides fuel to consumers.
- the fuel dispenser 610 pumps the fuel from the fuel tank 602 through the filter 614.
- the filtering media 100 of the filter 614 is able to filter solid particles 212, water molecules 208 and water-alcohol molecules 204.
- the filtering occurs as the alcohol-blended fuel is pumped from the fuel dispenser 610 to the fuel tank 622 of the vehicle 620.
- water molecules 208 and solid particles 212 may contaminate the alcohol- blended fuel in the vehicle's fuel tank 622.
- water molecules 208 from the atmosphere 630 may be drawn to the alcohol molecules 210 in the fuel tank 622 creating water- alcohol molecules 204.
- phase-separated fuel and phase-separated water can occur within the fuel tank 622.
- a filter 626 that uses the filtering media 100 is placed between the vehicle's fuel pump 624 and the engine 628.
- the filtering media 100 is able to filter solid particles 212, water molecules 208 and water-alcohol molecules 204 from the alcohol- blended fuel in the fuel tank 622.
- the filtering occurs as the fuel pump 624 pumps the alcohol-blended fuel from the fuel tank 622 to the engine 628.
- the engine 628 is able to burn uncontaminated fuel thereby improving fuel performance and reducing occurrences of engine damage caused high temperatures and/or water.
- Embodiments of the invention are not limited to the fuel dispensing system 600 illustrated in Figure 6. Rather, the system 600 illustrates that one or more filters which implement the filtering media 100 are able to effectively filter water and other particles from alcohol-blended fuel such as E-85.
- Such filters may be implemented in the fuel dispenser 610 and/or in a vehicle 620 as shown.
- the filtering media 100 is designed to be resistant to biodegradation caused by bacteria and other life-forms found in water. Thus, filters that implement the filtering media 100 are able to retain water for long periods of time without failure.
- a filter absorbs a threshold amount of the water (i.e., a maximum water capacity)
- the filter automatically stops the flow of fuel even against the force of a fuel pump (e.g., the pump 612 or 622). Thereafter, a new filter may be used to continue the filtering process.
- FIG. 7 illustrates a filtering process 700 in accordance with embodiments of the invention.
- the filtering process 700 involves a portable unit 710 that connects to a fuel tank 702.
- the fuel tank 702 contains an alcohol-blended fuel such as E-85.
- the portable unit 710 comprises a pump 712 and a filter 714 that uses the filtering media 100.
- the pump 712 of the portable unit 710 pumps the alcohol-blended fuel from the fuel tank 702 through the filter 714.
- the filtering media 100 is able to filter solid particles 212, water molecules 208 and water-alcohol molecules 204 from the alcohol-blended fuel.
- the alcohol-blended fuel is returned to the fuel tank 702.
- the portable unit 710 may operate for a predetermined amount of time. If the filter 714 reaches maximum water capacity during operation, the filter 714 stops the flow of fuel even against the pressure of the pump 712. An operator is then able to turn the pump 712 off, replace the filter 714, turn the pump 712 on and continue the filtering process. As shown, the filtering process 700 removes the contaminants from the alcohol-blended fuel. Embodiments of the invention are not limited to the filtering process 700 illustrated in Figure 7.
- the pump 712 is separate from the portable unit 710.
- some embodiments may temporarily store the filtered fuel in a separate fuel tank until all the fuel and contaminants are emptied from the fuel tank 702. Thereafter, the filtered alcohol-blended fuel may be dispensed from the separate fuel tank or returned to the fuel tank 702.
- the filtering process 700 is used to prevent phase- separation of fuel or phase-separation of water.
- the filtering process 700 may be used before phase- separation of fuel or phase-separation of water occurs within a fuel tank. Even if phase- separation of fuel or phase-separation of water has occurred within a fuel tank, the filtering process 700 may be used to remove the contaminant water on-site (the filter 714 may be replaced several times if needed).
- embodiments provide efficient and cost-effective solutions to filtering water from alcohol-blended fuels before or after phase-separation of fuel or phase- separation of water occurs.
- Figure 8 illustrates a method 800 in accordance with embodiments of the invention.
- the method 800 comprises impregnating a laminated media with non-naturally occurring monomers that exhibit a strong negative valence upon exposure to water and less strong positive valence upon exposure to alcohol (block 802).
- the method 800 further comprises filtering alcohol-blended fuel using the impregnated laminated media while dispensing the fuel (block 804).
- the filtered alcohol-blended fuel may be dispensed from a bulk storage tank to the fuel tank of a vehicle or from a vehicle's fuel tank to the vehicle's engine.
- alcohol-blended fuel is filtered using the impregnated laminated media without dispensing the fuel (block 808).
- a portable unit may be used to pump and filter contaminated fuel of a bulk storage tank without dispensing the fuel to a consumer or to the consumer's vehicle. If the fuel tank is part of a vehicle, a portable unit may pump and filter contaminated fuel of the vehicle's fuel tank without dispensing fuel to the engine. If a threshold amount of water is not filtered within a predetermined amount of time (determination block 806), alcohol-blended fuel is filtered using the impregnated laminated media while dispensing the fuel (block 804).
- the filtering media 100 and filters that implement the filtering media 100 may be used in other applications now known or later developed and are not limited to filtering alcohol-blended fuel intended for vehicles. Rather, the filtering media 100 and filters that implement the filtering media 100 are able to effectively filter water from alcohol and may be useful in any application that involves such a process. As an example, in the distillation process of producing alcohol, it is desirable that water not be present in the final alcohol product. Thus, filters containing the filtering media 100 can be used to remove the water. Also, filters containing the filtering media 100 are able to effectively remove water from non-blended fuels such as gasoline or diesel. It is intended that the following claims be inteipreted to embrace all such variations and modifications.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Filtering Materials (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US55012604P | 2004-03-04 | 2004-03-04 | |
US11/072,043 US7425266B2 (en) | 2004-03-04 | 2005-03-03 | Water-filtering media and filters |
PCT/US2005/006866 WO2005089114A2 (en) | 2004-03-04 | 2005-03-04 | Water-filtering media and filters |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1765481A2 true EP1765481A2 (en) | 2007-03-28 |
EP1765481A4 EP1765481A4 (en) | 2009-11-11 |
Family
ID=43015400
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05724413A Withdrawn EP1765481A4 (en) | 2004-03-04 | 2005-03-04 | Water-filtering media and filters |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1765481A4 (en) |
BR (1) | BRPI0508372A (en) |
CA (1) | CA2557491C (en) |
MX (1) | MXPA06010010A (en) |
PL (1) | PL382303A1 (en) |
WO (1) | WO2005089114A2 (en) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4885077A (en) * | 1988-11-17 | 1989-12-05 | Becton, Dickinson And Company | Composite membrane, method for its preparation and electrolyte sensor including same |
GB2333737A (en) * | 1998-02-03 | 1999-08-04 | Kobe Steel Europ Ltd | Fibre reinforced compositions and method for their production |
EP0941760A1 (en) * | 1998-02-25 | 1999-09-15 | Dainichiseika Color & Chemicals Mfg. Co. Ltd. | Charge mosaic membrane, its production process, method of its use, and apparatus provided with the same |
DE19936992A1 (en) * | 1998-08-03 | 2000-05-25 | Poly An Gmbh | Novel template-embossed materials, processes for their production and their use |
EP1166860A2 (en) * | 2000-06-27 | 2002-01-02 | Creavis Gesellschaft für Technologie und Innovation mbH | Polyelectrolyte-coated permeable composite material, method for producing the same and its use |
US20020077011A1 (en) * | 1993-01-19 | 2002-06-20 | Blanch Robert M. | Binders based on alpha-olefin/carboxylic acid/polyamide polymers and their ionomers |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5795496A (en) * | 1995-11-22 | 1998-08-18 | California Institute Of Technology | Polymer material for electrolytic membranes in fuel cells |
US6800117B2 (en) * | 2000-09-05 | 2004-10-05 | Donaldson Company, Inc. | Filtration arrangement utilizing pleated construction and method |
-
2005
- 2005-03-04 WO PCT/US2005/006866 patent/WO2005089114A2/en active Application Filing
- 2005-03-04 MX MXPA06010010A patent/MXPA06010010A/en active IP Right Grant
- 2005-03-04 PL PL382303A patent/PL382303A1/en not_active Application Discontinuation
- 2005-03-04 BR BRPI0508372-9A patent/BRPI0508372A/en not_active IP Right Cessation
- 2005-03-04 EP EP05724413A patent/EP1765481A4/en not_active Withdrawn
- 2005-03-04 CA CA2557491A patent/CA2557491C/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4885077A (en) * | 1988-11-17 | 1989-12-05 | Becton, Dickinson And Company | Composite membrane, method for its preparation and electrolyte sensor including same |
US20020077011A1 (en) * | 1993-01-19 | 2002-06-20 | Blanch Robert M. | Binders based on alpha-olefin/carboxylic acid/polyamide polymers and their ionomers |
GB2333737A (en) * | 1998-02-03 | 1999-08-04 | Kobe Steel Europ Ltd | Fibre reinforced compositions and method for their production |
EP0941760A1 (en) * | 1998-02-25 | 1999-09-15 | Dainichiseika Color & Chemicals Mfg. Co. Ltd. | Charge mosaic membrane, its production process, method of its use, and apparatus provided with the same |
DE19936992A1 (en) * | 1998-08-03 | 2000-05-25 | Poly An Gmbh | Novel template-embossed materials, processes for their production and their use |
EP1166860A2 (en) * | 2000-06-27 | 2002-01-02 | Creavis Gesellschaft für Technologie und Innovation mbH | Polyelectrolyte-coated permeable composite material, method for producing the same and its use |
Non-Patent Citations (1)
Title |
---|
See also references of WO2005089114A2 * |
Also Published As
Publication number | Publication date |
---|---|
CA2557491C (en) | 2013-07-16 |
CA2557491A1 (en) | 2005-09-29 |
WO2005089114A3 (en) | 2007-03-01 |
BRPI0508372A (en) | 2007-07-31 |
EP1765481A4 (en) | 2009-11-11 |
MXPA06010010A (en) | 2007-03-01 |
WO2005089114A2 (en) | 2005-09-29 |
PL382303A1 (en) | 2007-08-06 |
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