EP0720642B1

EP0720642B1 - Thickneded aqueous detergent compositions with improved cleaning performance

Info

Publication number: EP0720642B1
Application number: EP94928070A
Authority: EP
Inventors: Panos Iakovides
Original assignee: Procter and Gamble Co
Current assignee: Procter and Gamble Co
Priority date: 1993-09-20
Filing date: 1994-09-12
Publication date: 2001-08-08
Anticipated expiration: 2014-09-12
Also published as: EP0720642A4; WO1995008611A1; JPH09503012A; ES2159304T3; DE69427916D1; DE69427916T2; CA2171709C; EP0720642A1; CA2171709A1

Abstract

The present invention is an aqueous liquid detergent composition comprising a short chain surfactant for improved cleaning performance. Said composition further comprises a mixture of long chain amine oxide and alkyl sulphate to restore viscosity.

Description

TECHNICAL FIELD

The present invention relates to thickened aqueous detergent compositions.

BACKGROUND OF THE INVENTION

Liquid detergent compositions comprising long chain surfactants such as amine oxides are well known in the art. Such compositions are typically those as in US-A-4 282 109, EP-A-274 885, EP-A-233 666, DE-A-28 37 880 and EP-A-30 401.
It is desirable that such compositions have good cleaning properties. However, it has been found that long chain amine oxides do not provide the optimum cleaning performance. It is a first object of the present invention to provide cleaning compositions comprising long chain surfactants with improved cleaning.
In response to this object, it has been found that the incorporation of short chain surfactants is beneficial and meets this object thereby enhancing the cleaning performance.
However, it has been observed that the incorporation of short chain surfactants at amounts needed to enhance performance in such compositions results in the decrease of viscosity of the composition. Yet, it is considered essential that the compositions should exhibit a high degree of viscosity so that the compositions adhere to the vertical surfaces and surfaces inclined to the horizontal.
Thus, it is a further object of the present invention to provide a liquid composition which comprises long chain surfactants and short chain surfactants, which retains viscosity.
In response to this object, it has been found that viscosity may be retained even upon the addition of short chain surfactants, by the use of a mixture of amine oxide and alkyl sulphate, more specifically a mixture of a C₁₂-C₁₆ chain amine oxide and a C₁₂-C₁₄ alkyl sulphate.
A further advantage of the present invention is that there is no need for an additional thickening agent.
Thickening compositions comprising long chain surfactants are well known in the art.
US-A-4 282 109 discloses a thickened bleach composition comprising hypochlorite and a thickening amount of a surfactant blend, comprising amine oxide C₁₀-C₁₈ and alkyl sulphate C₈-C₁₂ at a ratio of 3:4 or more.
EP-A-274 885 discloses thickened bleaching compositions comprising alkali metal hypochlorite and straight chain C₁₄ amine oxide with a mixture of branched and straight chain C₁₅ amine oxides. There is no mention of short chain surfactants.
US-A-5 244 593 relates to a detergent composition comprising anionic or nonionic surfactants, oxygen bleach, metal sequestering agent and a suds booster. The composition has a pH of 4 to 11 and a transmittance at 470 nm of greater than 85%.
EP-A-232 153 relates to a detergent composition in liquid or gel form containing active detergent mixture comprising an anionic detergent active other than alkyl ether sulfate and an alkyl ether sulfate in a ratio of 2:1 to 1:10.
EP-A-233 666 discloses a process for the manufacture of a thickened bleaching compositions comprising hypochlorite, a hypochlorite-soluble surfactant and an alkali metal salt of a fatty acid. The detergent actives include amine oxides, preferably lauryldimethylamine.
DE-A-28 37 880 covers bleaching compositions comprising alkali metal hypochlorite and mixtures of branched and linear amine oxides of varying chain length (C₅-C₁₇) for increased viscosity. There is no mention of other long or short chain surfactants.
EP-A-30 401 covers thickened bleaching compositions comprising hypochlorite and a certain number of product characteristics including pH and viscosity. Mixtures of C₈-C₁₈ amine oxides and fatty acids are preferred as thickening agents. No other surfactants are disclosed.

SUMMARY OF THE INVENTION

The compositions of the present invention have a viscosity of from 40 cps to 4000 cps measured using a Brookfield viscosimeter RVT at 25°C using spindle numbers 1 to 4 at 20-100 r.p.m.; comprising a viscosity-decreasing short chain surfactant, said surfactant comprising a hydrophobic portion and a hydrophilic portion and is selected from alkyl sulfates, alkyl ether sulfates, alkyl sulphanates, alkyl succinates, alkyl carboxylates, alkyl ether carboxylates, alkyl sarcosinates, alkyl sulpho succinates, amine oxide and betaine and wherein the chain length of the hydrophobic portion is C₆ to C₁₀.
The composition also comprises a viscosity restoring long chain surfactant mixture. Said mixture comprises an amine oxide according to the formula R₁R₂R₃NO, wherein R₁ is a linear C₁₂ to C₁₆ alkyl group and R₂ and R₃ are independently C₁ to C₃ alkyl groups and an alkali metal alkyl sulphate according to the formula R₄OSO₃M, wherein R₄ is a C₁₂ to C₁₄ alkyl group and M is an alkali metal.
The compositions also preferably comprise hypochlorite.
All ratios, percentages and parts given herein are by % weight of the total composition unless otherwise specified.

DETAILED DESCRIPTION OF THE INVENTION

1. SHORT CHAIN SURFACTANT

The compositions according to the present invention comprise a short chain surfactant. Said surfactant comprises a hydrophobic portion and a hydrophilic portion, wherein the chain length of the hydrophobic portion is C₆ to C₁₀. It has been found that the cleaning performance of the composition according to the present invention can be boosted by the incorporation of said short chain surfactant.
All surfactants have in common that they comprise a hydrophobic portion and a hydrophilic portion. By short chain surfactant, it is meant herein surfactants which comprise a C₆-C₁₀ alkyl chain as their hydrophobic portion. Such short chain surfactants are selected from C₆-C₁₀ alkyl sulfates (C₆-C₁₀SO₄), alkyl ether sulfates (C₆-C₁₀(OCH₂CH₂)eSO₄), alkyl sulphonates (C₆-C₁₀SO₃), alkyl succinates (C₆-C₁₀OOCCH₂CH₂COOZ), alkyl carboxylates (C₆-C₁₀COOM), alkyl ether carboxylates (C₆-C₁₀(OCH₂CH₂)_eCOOM), alkyl sarcosinates (C₆-C₁₀CON(CH₃)R), alkyl sulpho succinates (C₆-C₁₀OOCCH(SO₃M)CH₂COOZ), amine oxides (C₆-C₁₀RR'NO), and betaines (C₆-C₁₀N⁺(CH₃)₂CH₂COO-). In the formulae in brackets, e is from 0 to 20, Z is M or R, M is H or any counterion such as those known in the art, including Na, K, Li, NH₄, amine, R and R' are C₁-C₅ alkyl groups, possibly functionalized with hydroxyl groups, R and R' are preferably C₁-C₃, most preferably methyl. All these surfactants are well known in the art. The compositions according to the present invention may comprise any of the above surfactants alone, or any combination thereof, depending on the end use envisioned.
Preferred short chain anionic surfactants for use herein are , C₆-C₁₀ alkyl sulfates (C₆-C₁₀SO4) and alkyl sulphonates (C₆-C₁₀SO₃). Most preferred are the C6-C8 alkyl sulfates and sulphonates. Such short chain anionic surfactants can be made by well known sulphation or sulphonation processes followed by neutralization, but said anionic short chain surfactants are more conveniently commercially available, for instance from Rhone Poulenc under the trade name Rhodapon^@ OLS, or from Witco under the trade name Witconate^@.
Preferred short chain surfactants for use herein is octyl sulphate. Suitable short chain surfactants for use herein are preferably hypochlorite compatible. According to the present invention, the compositions comprise preferably from 1% to 5%, more preferably from 2% to 4%, of short chain surfactants.
It has been observed that the incorporation of short chain surfactants in compositions comprising typical amine oxides described in the art results in the decrease of said compositions viscosity. It has now been found that the viscosity of the compositions is restored by the use of a mixture of a C₁₂ to C₁₆ chain amine oxide and a C₁₂ to C₁₄ chain alkyl sulphate.

2.LONG CHAIN SURFACTANT MIXTURE

a. Long chain amine oxides

Suitable amine oxides for use herein are amine oxides according to the formula R₁R₂R₃NO, wherein R₁ is a linear C₁₂ to C₁₆ alkyl group, and R₂ and R₃ are independently C₁ to C₃ alkyl groups, preferably methyl and mixtures thereof.
Suitable long chain amine oxides for use herein can be C₁₄ amine oxide Genaminox^R MY-X, (available from Hoechst) C₁₂ and C₁₄ amine oxide Aromox^R DMMCD-W, (AKZO), and C₁₄ amine oxide Aromox DM14D-W, (AKZO). However, preferred for use herein are C₁₆ amine oxides, and mixtures of C₁₆ and C₁₄ amine oxides, which offer better suds profile, i.e. produce less foam. Suitable C₁₆ amine oxides are commercially available under the trade name Genaminox CE. According to the present invention, said compositions preferably comprise from 1% to 6%, more preferably from 2% to 5%, most preferably from 3% to 4% of said C₁₂ to C₁₄ amine oxide.

b. Long chain alkyl sulphates

Suitable alkyl sulphates for use herein are alkyl sulphates according to the formula R₄OSO₃M, wherein R₄ is a C₁₂ to C₁₄ alkyl group and mixtures thereof. M is an alkali metal. Preferred alkyl sulphates for use herein can be sodium dodecyl sulphate or sodium lauryl sulphate.
Compositions according to the present invention comprise preferably from 1% to 4%, more preferably from 2% to 3% by weight of the total compositions of said long chain alkyl sulphate. Suitable long chain surfactants for use herein are preferably hypochlorite compatible.
According to the present invention the ratio of the long chain amine oxide to the total amount of C₁₂-C₁₄ alkyl sulphate and short chain alkyl sulphate is less than 3:4, preferably less than 4:6.
According the present invention the compositions have a viscosity from 40 cps to 4000 cps, preferably from 100 cps to 2000 cps, most preferably from 150 cps to 600 cps, measured with a Brookfield viscosimeter RVT at a temperature of 25°C using spindle numbers 1 to 4 at 20-100 r.p.m.
The compositions according to the present invention may comprise a number of optional ingredients. A highly preferred optional ingredient according to the present invention is a hypochlorite bleaching agent, preferably an alkali metal hypochlorite. Although alkali metal hypochlorites are preferred other hypochlorite compounds may also be used herein and can be selected from calcium and magnesium hypochlorite. Preferred alkali metal hypochlorite for use herein is sodium hypochlorite. Compositions according to the present invention comprise said hypochlorite bleaching agents such that the content of active chlorine in the compositions is from 0.4% to 4%, preferably from 1% to 2%. According to the present invention the ingredients of the compositions are selected so that the compositions are hypochlorite compatible.
An optional requirement of the compositions according to the present invention is that the pH is greater than 10, preferably greater than 11, more preferably greater than 12. This is achieved by the addition of from 0.4% to 2% of a caustic alkali. Suitable caustic alkalis for use herein include sodium and potassium hydroxide. Compositions according to the present invention comprising hypochlorite preferably have a pH greater than 12 for hypochlorite stability.
Another optional component of the present invention is an alkali metal salt of a C₈-C₁₈ fatty acid. Said fatty acids are used as suds suppressors. Suitable fatty acids for use herein can be any C₈-C₁₈ fatty acid, preferably fully saturated, preferably a sodium, potassium or lithium salt, more preferably the sodium salt. Suitable fatty acids may be selected from caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid and mixtures of fatty acids suitably hardened, derived from natural sources such as tallow, coconut oil, ground oil and babassu oil.
Compositions according to the present invention comprise from 0.1% to 2%, preferably from 0.5% to 1% by weight of the composition of fatty acids.
The detergent compositions herein may additionally comprise as an optional ingredient an organic surface-active agent selected from anionic, nonionic, cationic and zwitterionic surface-active agents and mixtures thereof.
The compositions according to the present invention may also comprise a number of additional ingredients such as colourants and perfumes. Additionally, the compositions according to the present invention may comprise silicates used as corrosion inhibitors and silicones as suds suppressors. The compositions according to the present invention are preferably aqueous and comprise from 80% to 95%, more preferably from 85% to 90% of water.
The compositions according to the present invention are prepared by methods well known in the art such as the methods described in GB-A-1 329 086. The compositions according to the present invention can be prepared by mixing all of the ingredients in a non-metallic apparatus at room temperature or in warm water. If fatty acid is used, it is melted before being added to the mixture. Preferably, the surfactant blend is first prepared by adding the short chain surfactant to the long chain components. Perfume and the alkali metal hypochlorite are then added whilst stirring. Colourants are added after all the other ingredients have been mixed.
The compositions of the present invention may be used for a variety of cleaning purposes such as cleaning hard surfaces whereby said compositions thickened nature results in longer adhesion to the surface than non-thickened compositions.
The compositions according to the present invention can be illustrated by the following examples.

EXAMPLES

Ingredients	1	2	3	4	5
octyl sulphate	3	3	3	4	3
C₁₂ amine oxide	-	3.2	-	-	-
C₁₄ amine oxide	3	-	3	4	3
C₁₂ alkyl sulphate	2	3	3	2	3.5
coconut fatty acid	0.9	0.9	0.9	0.9	0.9
sodium hypochlorite	1.6	1.6	1.6	1.6	1.6
sodium hydroxide
minors and water
viscosity	100	110	165	170	185
Ingredients	6	7	8	9	10
octyl sulphate	2	2	3	2	3
C₁₂ amine oxide	-	-	-	-	-
C₁₄ amine oxide	2.4	2.4	3.2	2.4	4
C₁₂ alkyl sulphate	2	2	3	2	3
coconut fatty acid	0.9	-	0.9	0.9	0.9
sodium hypochlorite	1.6	1.6	1.6	1.6	1.6
sodium hydroxide
minors and water
viscosity	215	230	250	280	3820
Ingredients	11	12	13	14	15	16
octyl sulphate	3	3	3	3	3	3
C₁₄ amine oxide	3	3	3	3	1.6	1.5
C₁₆ amine oxide	-	-	-	-	1.5	1.4
lauryl sulphate	1.5	1.5	1.5	1.5	1.2	1.5
palm kernel fatty acid	0.8	0.8	0.8	0.8	0.5	-
coconut fatty acid	-	-	-	-	-	0.7
sodium hypochlorite	2	3	4	5	1.65	1.5
sodium hydroxide	1.3	1.3	1.3	1.3	1.0	1.1
silicate	0.4	0.4	0.4	0.4	-	-
perfume	0.3	0.3	0.3	0.3	0.3	0.2
water and minors
viscosity	150	350	560	600	300	350

Claims

A detergent composition having a viscosity of from 40 cps to 4000 cps measured using a Brookfield viscosimeter RVT at 25°C using spindle numbers 1 to 4 at 20-100 rpm comprising;
a viscosity restoring long chain surfactant mixture, said mixture comprising;

an amine oxide according to the formula R₁R₂R₃NO, wherein R₁ is a linear C₁₂ to C₁₆ alkyl group and R₂ and R₃ are independently C₁ to C₃ alkyl groups, and

an alkali metal alkyl sulphate according to the formula R₄OSO₃M, wherein R₄ is a C₁₂ to C₁₄ alkyl group and M is an alkali metal, characterized in that the composition also comprises a viscosity decreasing short chain surfactant, said surfactant comprising a hydrophobic portion and a hydrophilic portion and is selected from alkyl sulfates, alkyl ether sulfates, alkyl sulphonates, alkyl succinates, alkyl carboxylates, alkyl ether carboxylates, alkyl sarcosinates, alkyl sulphosuccinates, amine oxide and betaine and wherein the chain length of said hydrophobic portion is C₆ to C₁₀.
A detergent composition according to claim 1, wherein said short chain surfactant is an alkyl sulphate.
A detergent composition according to claim 1, further
characterized in that the ratio of said long chain amine oxide to total amount of said C₁₂-C₁₄ alkyl sulphate and said short chain alkyl sulphate is less than 3 : 4.
A detergent composition according to any of the preceding claims, comprising from 2% to 5% by weight of said long chain C₁₂ to C₁₆ amine oxide.
A detergent composition according to any of the preceding claims, comprising from 1% to 4% by weight of said long chain C₁₂ to C₁₄ alkyl sulphate.
A detergent composition according to any of the preceding claims, comprising from 1% to 5% by weight of said short chain surfactants.
A detergent composition according to any of the preceding claims, wherein said C₁₂-C₁₆ amine oxide is a dimethyl amine oxide.
A detergent composition according to any of the preceding claims wherein said long chain amine oxide is a mixture of C₁₄ and C₁₆ amine oxides.
A detergent composition according to any of the preceding claims wherein the preferred C₁₂ to C₁₄ alkyl sulphates are selected from sodium dodecyl sulphate and sodium lauryl sulphate.
A detergent composition according to any of the preceding claims, having a viscosity of from 100 cps to 2000 cps.
A detergent composition according to any of the preceding claims, further characterized in that said composition comprises an alkali metal hypochlorite.
A detergent composition according to claim 11, comprising from 0.4% to 4% by weight of said hypochlorite.
A detergent composition according to claim 11, having a pH of above 10.