DE60138657D1 - Ligand für einen Metallocenkatalysator für die Polymerisation von Propylen und dessen Herstellungsverfahren - Google Patents
Ligand für einen Metallocenkatalysator für die Polymerisation von Propylen und dessen HerstellungsverfahrenInfo
- Publication number
- DE60138657D1 DE60138657D1 DE60138657T DE60138657T DE60138657D1 DE 60138657 D1 DE60138657 D1 DE 60138657D1 DE 60138657 T DE60138657 T DE 60138657T DE 60138657 T DE60138657 T DE 60138657T DE 60138657 D1 DE60138657 D1 DE 60138657D1
- Authority
- DE
- Germany
- Prior art keywords
- propylene
- ligand
- polymerization
- production process
- metallocene catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title abstract 3
- 239000003446 ligand Substances 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000012968 metallocene catalyst Substances 0.000 title 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 230000003213 activating effect Effects 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
- C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00200193 | 2000-01-18 | ||
EP00202791 | 2000-08-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE60138657D1 true DE60138657D1 (de) | 2009-06-18 |
Family
ID=26071752
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60138657T Expired - Lifetime DE60138657D1 (de) | 2000-01-18 | 2001-01-12 | Ligand für einen Metallocenkatalysator für die Polymerisation von Propylen und dessen Herstellungsverfahren |
DE60109680T Expired - Lifetime DE60109680T2 (de) | 2000-01-18 | 2001-01-12 | Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60109680T Expired - Lifetime DE60109680T2 (de) | 2000-01-18 | 2001-01-12 | Verfahren zur herstellung von im wesentlichen amorphen polymeren auf propylen-basis |
Country Status (11)
Country | Link |
---|---|
US (1) | US6730754B2 (de) |
EP (2) | EP1533324B1 (de) |
JP (1) | JP2003520869A (de) |
KR (1) | KR100675053B1 (de) |
CN (1) | CN100457787C (de) |
AT (2) | ATE292148T1 (de) |
AU (1) | AU3729501A (de) |
BR (1) | BR0105177A (de) |
DE (2) | DE60138657D1 (de) |
ES (2) | ES2326537T3 (de) |
WO (1) | WO2001053360A1 (de) |
Families Citing this family (69)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2760599A (en) * | 1998-02-04 | 1999-08-23 | Friedman, Robert F. | Method and apparatus for combining transponders on multiple satellites into virtual channels |
CN1347423A (zh) | 1999-02-22 | 2002-05-01 | 伊斯曼化学公司 | 含有n-吡咯基取代的氮给电体的催化剂 |
ATE394407T1 (de) | 2001-04-10 | 2008-05-15 | Basell Polyolefine Gmbh | Verfahren zur herstellung von mono oder bis halogensubstituierten metallozenverbindungen |
US6759361B2 (en) * | 2001-06-04 | 2004-07-06 | Equistar Chemicals, Lp | Aluminoboronate activators for single-site olefin polymerization catalysts |
US7365137B2 (en) | 2001-07-17 | 2008-04-29 | Basell Polyolefine Gmbh | Multistep process for the (co) polymerization of olefins |
ES2312629T3 (es) * | 2001-09-14 | 2009-03-01 | Basell Polyolefine Gmbh | Metodo para la polimerizacion de olefinas. |
DE10145453A1 (de) * | 2001-09-14 | 2003-06-05 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus |
JP4062929B2 (ja) | 2002-02-08 | 2008-03-19 | 住友化学株式会社 | 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
AU2003216477A1 (en) * | 2002-03-14 | 2003-09-29 | Dow Global Technologies Inc. | Polycyclic, fused heteroring compounds, metal complexes and polymerization process |
CA2494611C (en) | 2002-08-02 | 2012-01-24 | Equistar Chemicals, Lp | Catalyst comprising bridged indeno[1,2-b]indolyl metal complex |
US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
US7271209B2 (en) | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
US7998579B2 (en) | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
US7662885B2 (en) | 2002-08-12 | 2010-02-16 | Exxonmobil Chemical Patents Inc. | Method to make an article comprising polymer concentrate |
JP2005535748A (ja) | 2002-08-12 | 2005-11-24 | エクソンモービル・ケミカル・パテンツ・インク | 可塑性ポリオレフィン組成物 |
US7531594B2 (en) | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
US6841500B2 (en) | 2002-12-03 | 2005-01-11 | Equistar Chemicals, Lp | Bimetallic indenoindolyl catalysts |
US6683150B1 (en) * | 2002-12-19 | 2004-01-27 | Equistar Chemicals, Lp | High molecular weight polypropylene process |
DE10303225A1 (de) * | 2003-01-28 | 2004-08-05 | Inventis Technologies Gmbh | Katalysatorkombination, isotaktische Polymere sowie ein Verfahren zur Herstellung von linearen isotaktischen Polymeren und dessen Verwendung |
US6693155B1 (en) * | 2003-03-05 | 2004-02-17 | Equistar Chemicals, Lp | Propylene polymerization process |
US6794468B1 (en) | 2003-05-12 | 2004-09-21 | Equistar Chemicals, Lp | Olefin polymerization process |
US6927264B2 (en) | 2003-05-28 | 2005-08-09 | Dow Global Technologies Inc. | Metal complexes and polymerization process using same |
US6998451B2 (en) | 2003-07-01 | 2006-02-14 | Equistar Chemicals, Lp | Olefin polymerization process |
US6933353B2 (en) | 2003-07-07 | 2005-08-23 | Equistar Chemicals, Lp | Olefin polymerization process |
US6818713B1 (en) | 2003-08-11 | 2004-11-16 | Equistar Chemicals, Lp | Process for making polyethylene |
US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
US6939930B2 (en) | 2003-09-09 | 2005-09-06 | Equistar Chemicals, Lp | Hydrosilane additives for increased polyolefin molecular weight |
US6958377B2 (en) | 2003-10-15 | 2005-10-25 | Equistar Chemicals, Lp | Olefin polymerization process |
US7589145B2 (en) | 2004-04-15 | 2009-09-15 | Exxonmobil Chemical Patents Inc. | Syndiotactic rich polyolefins |
US6995220B2 (en) | 2004-04-29 | 2006-02-07 | Equistar Chemicals, Lp | Ethylene polymerization process |
US6967231B1 (en) | 2004-09-23 | 2005-11-22 | Equistar Chemicals, Lp | Olefin polymerization process |
GB2420348B (en) * | 2004-10-28 | 2009-11-18 | Exxonmobil Chem Patents Inc | Syndiotactic rich polyolefins |
ATE435887T1 (de) * | 2004-12-17 | 2009-07-15 | Exxonmobil Chem Patents Inc | Folien aus polymerblends |
US8389615B2 (en) | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
US7196147B2 (en) | 2005-07-01 | 2007-03-27 | Equistar Chemicals, Lp | Olefin polymerization process with improved operability and polymer properties |
US7230056B2 (en) | 2005-07-01 | 2007-06-12 | Equistar Chemicals, Lp | Catalyst preparation method |
ATE555166T1 (de) | 2005-07-15 | 2012-05-15 | Exxonmobil Chem Patents Inc | Elastomere zusammensetzungen |
WO2007011462A1 (en) | 2005-07-19 | 2007-01-25 | Exxonmobil Chemical Patents Inc. | Lubricants from mixed alpha-olefin feeds |
US8696888B2 (en) | 2005-10-20 | 2014-04-15 | Exxonmobil Chemical Patents Inc. | Hydrocarbon resid processing |
US7423098B2 (en) | 2006-01-17 | 2008-09-09 | Equistar Chemicals, Lp | Polyethylene process |
US7638584B2 (en) | 2006-06-20 | 2009-12-29 | Equistar Chemicals, Lp | Olefin polymerization process |
US7638586B2 (en) | 2006-09-26 | 2009-12-29 | Equistar Chemicals, Lp | Olefin polymerization process |
US7829641B2 (en) | 2008-07-16 | 2010-11-09 | Equistar Chemicals, Lp | Process for the preparation of multimodal polyethylene resins |
US7816478B2 (en) | 2008-09-03 | 2010-10-19 | Equistar Chemicals, Lp | Polyethylene thick film and process for preparing polyethylene |
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US10723824B2 (en) | 2014-02-07 | 2020-07-28 | Eastman Chemical Company | Adhesives comprising amorphous propylene-ethylene copolymers |
US11267916B2 (en) | 2014-02-07 | 2022-03-08 | Eastman Chemical Company | Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins |
US10308740B2 (en) | 2014-02-07 | 2019-06-04 | Eastman Chemical Company | Amorphous propylene-ethylene copolymers |
KR101637982B1 (ko) * | 2014-11-07 | 2016-07-11 | 주식회사 엘지화학 | 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물 |
KR101719064B1 (ko) | 2014-11-13 | 2017-03-22 | 주식회사 엘지화학 | 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물 |
KR101910701B1 (ko) * | 2015-07-02 | 2018-10-22 | 주식회사 엘지화학 | 전이금속 화합물 및 이를 포함하는 촉매 조성물 |
KR102531558B1 (ko) * | 2017-06-28 | 2023-05-15 | 주식회사 엘지화학 | 리간드 화합물 및 전이금속 화합물의 제조방법 |
KR102584264B1 (ko) * | 2017-06-28 | 2023-10-05 | 주식회사 엘지화학 | 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물 |
WO2019022569A1 (ko) * | 2017-07-27 | 2019-01-31 | 주식회사 엘지화학 | 신규한 전이금속 화합물 및 이를 제조하는 방법 |
KR102328690B1 (ko) * | 2017-07-27 | 2021-11-18 | 주식회사 엘지화학 | 신규한 전이금속 화합물 및 이를 제조하는 방법 |
KR102217767B1 (ko) * | 2017-09-25 | 2021-02-22 | 주식회사 엘지화학 | 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물 |
WO2019132477A1 (ko) * | 2017-12-26 | 2019-07-04 | 주식회사 엘지화학 | 올레핀계 중합체 |
ES2924381T3 (es) | 2018-05-04 | 2022-10-06 | Lg Chemical Ltd | Copolímero de etileno/alfa-olefina y método de preparación del mismo |
US11505631B2 (en) | 2018-05-04 | 2022-11-22 | Lg Chem, Ltd. | Ethylene/alpha-olefin copolymer and method for preparing the same |
EP3715389B1 (de) | 2018-05-04 | 2023-05-17 | Lg Chem, Ltd. | Klebstoffzusammensetzung mit einem ethylen/alpha-olefin-copolymer |
KR102601720B1 (ko) * | 2018-09-07 | 2023-11-14 | 주식회사 엘지화학 | 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물 |
JP7308644B2 (ja) * | 2019-03-29 | 2023-07-14 | 三井化学株式会社 | オレフィン・環状オレフィン共重合体の製造方法 |
JP7423332B2 (ja) * | 2019-03-29 | 2024-01-29 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法 |
CN116212948B (zh) * | 2023-02-14 | 2024-07-09 | 四川九天五洋新材料有限责任公司 | 一种丙烯气相环氧化成型催化剂及其制备方法 |
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WO2001048040A1 (en) | 1999-12-28 | 2001-07-05 | Basell Technology Company B.V. | Process for the preparation of ethylene polymers |
ATE373669T1 (de) | 1999-12-28 | 2007-10-15 | Basell Polyolefine Gmbh | Heterocyclische metallocene und ihre verwendung in katalysatorsystemen zur herstellung von olefin polymeren |
EP1226193B1 (de) | 1999-12-28 | 2006-07-19 | Basell Polyolefine GmbH | Verfahren zur herstellung von äthylen polymere |
US6559251B1 (en) | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
-
2001
- 2001-01-12 EP EP05100258A patent/EP1533324B1/de not_active Expired - Lifetime
- 2001-01-12 CN CNB018005721A patent/CN100457787C/zh not_active Expired - Fee Related
- 2001-01-12 JP JP2001553831A patent/JP2003520869A/ja active Pending
- 2001-01-12 ES ES05100258T patent/ES2326537T3/es not_active Expired - Lifetime
- 2001-01-12 BR BR0105177-6A patent/BR0105177A/pt not_active Application Discontinuation
- 2001-01-12 AU AU37295/01A patent/AU3729501A/en not_active Abandoned
- 2001-01-12 EP EP01909617A patent/EP1159310B1/de not_active Expired - Lifetime
- 2001-01-12 AT AT01909617T patent/ATE292148T1/de not_active IP Right Cessation
- 2001-01-12 US US09/936,832 patent/US6730754B2/en not_active Expired - Fee Related
- 2001-01-12 DE DE60138657T patent/DE60138657D1/de not_active Expired - Lifetime
- 2001-01-12 ES ES01909617T patent/ES2239665T3/es not_active Expired - Lifetime
- 2001-01-12 AT AT05100258T patent/ATE430753T1/de not_active IP Right Cessation
- 2001-01-12 WO PCT/EP2001/000339 patent/WO2001053360A1/en active IP Right Grant
- 2001-01-12 DE DE60109680T patent/DE60109680T2/de not_active Expired - Lifetime
- 2001-01-12 KR KR1020017011897A patent/KR100675053B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ES2326537T3 (es) | 2009-10-14 |
KR100675053B1 (ko) | 2007-01-26 |
ES2239665T3 (es) | 2005-10-01 |
KR20010112350A (ko) | 2001-12-20 |
EP1533324B1 (de) | 2009-05-06 |
ATE292148T1 (de) | 2005-04-15 |
US6730754B2 (en) | 2004-05-04 |
EP1533324A3 (de) | 2006-06-07 |
JP2003520869A (ja) | 2003-07-08 |
CN1372571A (zh) | 2002-10-02 |
DE60109680D1 (de) | 2005-05-04 |
EP1533324A2 (de) | 2005-05-25 |
US20020147286A1 (en) | 2002-10-10 |
EP1159310B1 (de) | 2005-03-30 |
CN100457787C (zh) | 2009-02-04 |
ATE430753T1 (de) | 2009-05-15 |
AU3729501A (en) | 2001-07-31 |
BR0105177A (pt) | 2002-01-15 |
DE60109680T2 (de) | 2006-02-02 |
EP1159310A1 (de) | 2001-12-05 |
WO2001053360A1 (en) | 2001-07-26 |
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