DE59309424D1 - Verfahren zur Herstellung von Polyolefinen - Google Patents
Verfahren zur Herstellung von PolyolefinenInfo
- Publication number
- DE59309424D1 DE59309424D1 DE59309424T DE59309424T DE59309424D1 DE 59309424 D1 DE59309424 D1 DE 59309424D1 DE 59309424 T DE59309424 T DE 59309424T DE 59309424 T DE59309424 T DE 59309424T DE 59309424 D1 DE59309424 D1 DE 59309424D1
- Authority
- DE
- Germany
- Prior art keywords
- meso
- zirconium dichloride
- rac
- methyl
- dimethylsilylbis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
- C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
- C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Diaphragms And Bellows (AREA)
- Emergency Protection Circuit Devices (AREA)
- Materials For Medical Uses (AREA)
- Cell Separators (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4227049 | 1992-08-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE59309424D1 true DE59309424D1 (de) | 1999-04-15 |
Family
ID=6465634
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE59309424T Expired - Lifetime DE59309424D1 (de) | 1992-08-15 | 1993-08-05 | Verfahren zur Herstellung von Polyolefinen |
Country Status (12)
Country | Link |
---|---|
US (4) | US5672668A (de) |
EP (2) | EP0882731A3 (de) |
JP (1) | JP3548755B2 (de) |
KR (2) | KR100283825B1 (de) |
AT (1) | ATE177436T1 (de) |
AU (1) | AU666565B2 (de) |
CA (1) | CA2104036A1 (de) |
DE (1) | DE59309424D1 (de) |
ES (1) | ES2128371T3 (de) |
FI (1) | FI110103B (de) |
TW (1) | TW309524B (de) |
ZA (1) | ZA935924B (de) |
Families Citing this family (100)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5504169A (en) * | 1989-09-13 | 1996-04-02 | Exxon Chemical Patents Inc. | Process for producing amorphous poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
TW309523B (de) * | 1991-11-30 | 1997-07-01 | Hoechst Ag | |
US5830821A (en) * | 1991-11-30 | 1998-11-03 | Targor Gmbh | Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands |
TW294669B (de) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
DE59309424D1 (de) | 1992-08-15 | 1999-04-15 | Targor Gmbh | Verfahren zur Herstellung von Polyolefinen |
USRE39156E1 (en) | 1992-08-15 | 2006-07-04 | Basell Polyolefine Gmbh | Process for the preparation of polyolefins |
IT1271406B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
US5817590A (en) * | 1993-10-14 | 1998-10-06 | Tosoh Corporation | Catalyst for αE --olefin polymerization containing a Lewis base |
IT1270253B (it) * | 1994-06-20 | 1997-04-29 | Spherilene Srl | Copolimeri dell'etilene e procedimento per la preparazione di polimeri dell'etilene |
ATE188972T1 (de) * | 1994-06-24 | 2000-02-15 | Exxon Chemical Patents Inc | Polymerisationskatalysatorsystem, ihre herstellung und gebrauch |
EP0745099B1 (de) * | 1994-12-20 | 2000-09-13 | Montell Technology Company bv | Polypropylenreaktionsmischung und verfahren zu ihrer herstellung |
WO1996019504A1 (fr) * | 1994-12-20 | 1996-06-27 | Mitsui Petrochemical Industries, Ltd. | Procede de production de polymere d'ethylene et polymere d'ethylene obtenu |
IT1272922B (it) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | Procedimento per la preparazione di composti metallocenici |
IT1272923B (it) * | 1995-01-23 | 1997-07-01 | Spherilene Srl | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
US5516848A (en) * | 1995-01-31 | 1996-05-14 | Exxon Chemical Patents Inc. | Process to produce thermoplastic elastomers |
US5539056A (en) * | 1995-01-31 | 1996-07-23 | Exxon Chemical Patents Inc. | Thermoplastic elastomers |
TR28706A (tr) * | 1995-02-14 | 1997-01-13 | Royal Mobilya Dekorasyon Ve Ak | Yatak haline dönüsebilen koltuk ya da kanepeler icin hareket mekanizmalari. |
BR9602268A (pt) * | 1995-05-16 | 1998-04-07 | Union Carbide Chem Plastic | Processo para a produção de polietileno e polietileno |
UA47394C2 (uk) * | 1995-05-16 | 2002-07-15 | Юнівейшн Текнолоджіз, Ллс | Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер |
US6787618B1 (en) | 1995-12-01 | 2004-09-07 | Basell Polypropylen Gmbh | Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms |
DE19544828A1 (de) * | 1995-12-01 | 1997-06-05 | Hoechst Ag | Hochmolekulare Copolymere |
FI104826B (fi) * | 1996-01-30 | 2000-04-14 | Borealis As | Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi |
US6211310B1 (en) | 1997-06-05 | 2001-04-03 | Union Carbide Chemicals & Plastics Technology Corporation | Manufacture of stereoregular polymers |
US5693727A (en) * | 1996-06-06 | 1997-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Method for feeding a liquid catalyst to a fluidized bed polymerization reactor |
DE69720609T2 (de) * | 1996-07-16 | 2003-11-13 | Basell Polyolefine Gmbh | Verfahren zur Modifikation von die Rac/Meso-Verhältnis einer Metallocenverbindung |
DE19637669A1 (de) * | 1996-09-16 | 1998-03-19 | Hoechst Ag | Verfahren zur Herstellung einer methylenverbrückten Biscyclopentadienylverbindung |
US5847176A (en) * | 1997-06-30 | 1998-12-08 | Boulder Scientific Company | Preparation of chiral titanocenes |
WO1998022477A1 (en) * | 1996-11-22 | 1998-05-28 | Boulder Scientific Company | Preparation of chiral titanocenes |
FI971565A (fi) * | 1997-04-14 | 1998-10-15 | Borealis As | Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä |
US6160072A (en) * | 1997-05-02 | 2000-12-12 | Ewen; John A. | Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes |
KR20000068602A (ko) * | 1997-07-22 | 2000-11-25 | 나까니시 히로유끼 | 에틸렌/α-올레핀 공중합체, 그 조성물 및, 공중합체 및 조성물 |
US6265512B1 (en) | 1997-10-23 | 2001-07-24 | 3M Innovative Company | Elastic polypropylenes and catalysts for their manufacture |
KR100274973B1 (ko) * | 1997-11-24 | 2000-12-15 | 성재갑 | 올레핀계 단량체의 중합 촉매 |
DE19806918A1 (de) * | 1998-02-19 | 1999-08-26 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
EP0953582A1 (de) * | 1998-04-27 | 1999-11-03 | Fina Research S.A. | Herstellung von Polyolefin |
US6207750B1 (en) | 1998-05-13 | 2001-03-27 | Exxon Chemical Patents, Inc. | Propylene homopolymers and methods of making the same |
US6306960B1 (en) | 1998-05-13 | 2001-10-23 | Exxonmobil Chemical Patents Inc. | Articles formed from foamable polypropylene polymer |
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US6746780B1 (en) | 1999-10-08 | 2004-06-08 | The Procter & Gamble Company | Bodies of polymeric material comprising linear, isotactic polymers |
US6863989B1 (en) | 1999-10-08 | 2005-03-08 | The Procter & Gamble Company | Adhesives comprising linear isotactic polymers |
DE60006146T2 (de) | 1999-11-04 | 2004-09-30 | Exxonmobil Chemical Patents Inc., Baytown | Propylencopolymerschäume und deren verwendung |
US6809168B2 (en) * | 1999-12-10 | 2004-10-26 | Exxonmobil Chemical Patents Inc. | Articles formed from propylene diene copolymers |
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DE60019637T2 (de) * | 1999-12-10 | 2006-03-09 | Exxonmobil Chemical Patents Inc., Baytown | Propen dien copolymerisate |
DE60034151T2 (de) | 1999-12-21 | 2008-01-10 | Exxon Chemical Patents, Inc., Baytown | Klebstoffe auf der basis von alpha-olefinpolymeren |
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US6492465B1 (en) | 2000-02-08 | 2002-12-10 | Exxonmobil Chemical Patents, Inc. | Propylene impact copolymers |
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US6706828B2 (en) * | 2002-06-04 | 2004-03-16 | Crompton Corporation | Process for the oligomerization of α-olefins having low unsaturation |
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US20080153997A1 (en) * | 2006-12-20 | 2008-06-26 | Exxonmobil Research And Engineering | Polymer production at supercritical conditions |
US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
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JP4972284B2 (ja) | 2002-10-15 | 2012-07-11 | エクソンモービル・ケミカル・パテンツ・インク | オレフィン重合のための複数触媒系及びそれらから生成されたポリマー |
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US20050234198A1 (en) * | 2004-04-20 | 2005-10-20 | Fina Technology, Inc. | Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system |
EP1753792B1 (de) * | 2004-05-04 | 2009-10-14 | Basell Polyolefine GmbH | Verfahren zur herstellung von ataktischen 1-butenpolymeren |
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US7169864B2 (en) * | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
US7232869B2 (en) * | 2005-05-17 | 2007-06-19 | Novolen Technology Holdings, C.V. | Catalyst composition for olefin polymerization |
US7868197B2 (en) | 2005-12-14 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization |
US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
ATE547469T1 (de) | 2007-04-09 | 2012-03-15 | Exxonmobil Chem Patents Inc | Weiche heterogene isotaktische polypropylenzusammensetzungen |
JP2010529253A (ja) | 2007-06-04 | 2010-08-26 | エクソンモービル・ケミカル・パテンツ・インク | 非常に均一なプロピレンの溶液重合法 |
US20090053959A1 (en) * | 2007-08-21 | 2009-02-26 | Sudhin Datta | Soft and Elastic Nonwoven Polypropylene Compositions |
US7906588B2 (en) * | 2007-10-26 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Soft heterogeneous isotactic polypropylene compositions |
US7812104B2 (en) | 2008-01-18 | 2010-10-12 | Exxonmobil Chemical Patents Inc. | Production of propylene-based polymers |
US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
DE102008005949A1 (de) | 2008-01-24 | 2009-07-30 | Evonik Degussa Gmbh | Polyolefine mit Isotaktischen Strukturelementen, Verfahren zu deren Herstellung und deren Verwendung |
US8227392B2 (en) * | 2008-01-25 | 2012-07-24 | Exxonmobil Research And Engineering Company | Base stocks and lubricant blends containing poly-alpha olefins |
DE102009027447A1 (de) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
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DE102009027446A1 (de) | 2009-07-03 | 2011-01-05 | Evonik Degussa Gmbh | Modifizierte Polyolefine mit besonderem Eigenschaftsprofil, Verfahren zu deren Herstellung und deren Verwendung |
GB0918736D0 (en) | 2009-10-26 | 2009-12-09 | Isis Innovation | Catalysts |
WO2012149391A1 (en) | 2011-04-28 | 2012-11-01 | Adherent Laboratories, Inc. | Polyolefin based hot melt adhesive composition |
EP2573091A1 (de) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen |
KR101499819B1 (ko) * | 2011-11-03 | 2015-03-10 | 주식회사 엘지화학 | 비담지 비균일계 폴리올레핀 중합용 촉매 조성물 및 그의 제조 방법 |
KR102354757B1 (ko) * | 2014-02-11 | 2022-02-08 | 유니베이션 테크놀로지즈, 엘엘씨 | 폴리올레핀 생성물의 제조 방법 |
GB201407000D0 (en) * | 2014-04-17 | 2014-06-04 | Isis Innovation | Catalysts |
WO2015161241A1 (en) | 2014-04-18 | 2015-10-22 | IFS Industries Inc. | Low density and high performance packaging hot melt |
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DK3245258T3 (da) | 2015-01-06 | 2019-10-07 | Scg Chemicals Co Ltd | SiO2-LAGDELTE DOBBELTHYDROXIDMIKROKUGLER OG FREMGANGSMÅDER TIL FREMSTILLING HERAF |
GB201608384D0 (en) | 2016-05-12 | 2016-06-29 | Scg Chemicals Co Ltd | Unsymmetrical metallocene catalysts and uses thereof |
US11993699B2 (en) | 2018-09-14 | 2024-05-28 | Fina Technology, Inc. | Polyethylene and controlled rheology polypropylene polymer blends and methods of use |
EP3927765A1 (de) | 2019-02-20 | 2021-12-29 | Fina Technology, Inc. | Polymerzusammensetzungen mit geringem verzug |
US20220389133A1 (en) | 2019-10-30 | 2022-12-08 | China Petroleum & Chemical Corporation | Metallocene compound, and preparation method therefor and application thereof |
EP4330316A1 (de) | 2021-04-26 | 2024-03-06 | Fina Technology, Inc. | Dünne, vor ort katalysierte polymerfolien |
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DE3826075A1 (de) * | 1988-07-30 | 1990-02-01 | Hoechst Ag | 1-olefin-isoblockpolymer und verfahren zu seiner herstellung |
EP0485823B1 (de) * | 1990-11-12 | 1995-03-08 | Hoechst Aktiengesellschaft | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation |
US5243001A (en) * | 1990-11-12 | 1993-09-07 | Hoechst Aktiengesellschaft | Process for the preparation of a high molecular weight olefin polymer |
DE59209964D1 (de) | 1991-03-09 | 2002-10-10 | Basell Polyolefine Gmbh | Metallocen und Katalysator |
TW300901B (de) * | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
JP3394997B2 (ja) * | 1991-10-15 | 2003-04-07 | バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | 特異的に置換されたインデニル配位子を持つメタロセンを用いてオレフィンポリマーを製造する方法 |
EP0549900B1 (de) * | 1991-11-30 | 1996-08-21 | Hoechst Aktiengesellschaft | Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
TW318184B (de) * | 1991-11-30 | 1997-10-21 | Hoechst Ag | |
TW309523B (de) * | 1991-11-30 | 1997-07-01 | Hoechst Ag | |
ATE162529T1 (de) * | 1992-06-13 | 1998-02-15 | Hoechst Ag | Verfahren zur herstellung von verbrückten, chiralen metallocenkatalysatoren des types bisindenyl |
TW294669B (de) * | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
DE59309424D1 (de) | 1992-08-15 | 1999-04-15 | Targor Gmbh | Verfahren zur Herstellung von Polyolefinen |
-
1993
- 1993-08-05 DE DE59309424T patent/DE59309424D1/de not_active Expired - Lifetime
- 1993-08-05 ES ES93112580T patent/ES2128371T3/es not_active Expired - Lifetime
- 1993-08-05 EP EP98116079A patent/EP0882731A3/de not_active Withdrawn
- 1993-08-05 AT AT93112580T patent/ATE177436T1/de not_active IP Right Cessation
- 1993-08-05 EP EP93112580A patent/EP0584609B1/de not_active Expired - Lifetime
- 1993-08-12 JP JP20082293A patent/JP3548755B2/ja not_active Expired - Lifetime
- 1993-08-12 FI FI933573A patent/FI110103B/fi not_active IP Right Cessation
- 1993-08-13 KR KR1019930015663A patent/KR100283825B1/ko not_active IP Right Cessation
- 1993-08-13 CA CA002104036A patent/CA2104036A1/en not_active Abandoned
- 1993-08-13 AU AU44591/93A patent/AU666565B2/en not_active Expired
- 1993-08-13 ZA ZA935924A patent/ZA935924B/xx unknown
- 1993-08-16 US US08/107,187 patent/US5672668A/en not_active Expired - Lifetime
- 1993-09-18 TW TW082107677A patent/TW309524B/zh active
-
1995
- 1995-06-07 US US08/484,457 patent/US5693836A/en not_active Ceased
-
1997
- 1997-08-18 US US08/914,387 patent/US6028152A/en not_active Expired - Lifetime
-
1999
- 1999-10-28 US US09/428,843 patent/US6359095B1/en not_active Expired - Fee Related
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2000
- 2000-06-22 KR KR1020000034444A patent/KR100301337B1/ko not_active IP Right Cessation
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Publication number | Publication date |
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KR100283825B1 (ko) | 2001-03-02 |
US6359095B1 (en) | 2002-03-19 |
AU666565B2 (en) | 1996-02-15 |
FI933573A (fi) | 1994-02-16 |
JPH06157662A (ja) | 1994-06-07 |
US5693836A (en) | 1997-12-02 |
AU4459193A (en) | 1994-02-17 |
EP0584609B1 (de) | 1999-03-10 |
ZA935924B (en) | 1994-02-11 |
JP3548755B2 (ja) | 2004-07-28 |
EP0882731A3 (de) | 2000-05-31 |
US5672668A (en) | 1997-09-30 |
US6028152A (en) | 2000-02-22 |
KR940003974A (ko) | 1994-03-14 |
FI110103B (fi) | 2002-11-29 |
ES2128371T3 (es) | 1999-05-16 |
EP0584609A3 (en) | 1994-08-24 |
EP0584609A2 (de) | 1994-03-02 |
KR100301337B1 (ko) | 2001-09-22 |
FI933573A0 (fi) | 1993-08-12 |
EP0882731A2 (de) | 1998-12-09 |
TW309524B (de) | 1997-07-01 |
ATE177436T1 (de) | 1999-03-15 |
CA2104036A1 (en) | 1994-02-16 |
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Legal Events
Date | Code | Title | Description |
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8364 | No opposition during term of opposition | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: BASELL POLYPROPYLEN GMBH, 55116 MAINZ, DE |
|
8327 | Change in the person/name/address of the patent owner |
Owner name: BASELL POLYOLEFINE GMBH, 50389 WESSELING, DE |