CN113028270B

CN113028270B - Hydrogen storage device with identity recognition function and hydrogen fuel electric bicycle

Info

Publication number: CN113028270B
Application number: CN202110282525.9A
Authority: CN
Inventors: 孙继胜; 周婵鸣; 岑健; 钱程; 仄伟杰
Original assignee: Youon Technology Co Ltd
Current assignee: Youon Technology Co Ltd
Priority date: 2021-03-16
Filing date: 2021-03-16
Publication date: 2022-10-11
Anticipated expiration: 2041-03-16
Also published as: CN113028270A

Abstract

The invention discloses a hydrogen storage device with identity recognition and a hydrogen fuel electric bicycle, and belongs to the field of energy equipment. The hydrogen storage device includes: a bottle for storing a solid hydrogen storage material and hydrogen gas; the protective cover is arranged at the air outlet of the bottle body; the low-pressure air inlet or outlet is arranged on one side of the protective cover and is connected with the air outlet of the bottle body; and the identity identification label is arranged on the protective cover or the bottle body. According to the invention, the identity identification tag is arranged on the surface of the hydrogen storage device, so that on one hand, a user obtains relevant information of the hydrogen storage device through scanning equipment; on the other hand, the user can judge the directionality of the hydrogen storage device through the direction of the identity identification tag, and the installation and placement direction of the hydrogen storage device is ensured to meet the requirements.

Description

Hydrogen storage device with identity recognition function and hydrogen fuel electric bicycle

Technical Field

The invention belongs to the field of energy equipment, and particularly relates to a hydrogen storage device with identity recognition and a hydrogen fuel electric bicycle.

Background

It is quite common to use a hydrogen storage tank as a storage device for hydrogen gas, and hydrogen gas is required to be supplied to any hydrogen fuel cell system or other products using a hydrogen fuel cell. At present, the hydrogen storage technology can be mainly divided into three types, namely high-pressure gas, liquid hydrogen and hydrogen storage alloy, wherein the high-pressure gas has higher energy, weight and density, but has larger volume and poorer safety. Although the energy, weight and density of the liquid hydrogen storage mode are higher, the liquefied energy consumption is large, and meanwhile, a heat insulation storage tank is required to be used, so that the liquid hydrogen storage mode is generally suitable for large storage tanks; the energy, weight and density of the hydrogen storage mode of the hydrogen storage alloy can meet the basic use requirement, but the safety is higher.

In the general application field, the hydrogen storage method of the hydrogen storage alloy is practical. Among them, the hydrogen storage alloy technology mainly uses a hydrogen storage tank as a storage container of hydrogen, and no matter a mobile carrier or a stationary portable power supply system using the hydrogen storage tank, after the hydrogen storage tank is supplied with hydrogen, the hydrogen needs to be supplemented. On one hand, the specification, the quality and the use condition of the existing hydrogen storage device are different, so that the existing statistical mode is difficult to quickly and accurately obtain relevant data of the hydrogen storage device. On the other hand, since the hydrogen storage containers are placed in a directional manner, there may be a safety risk when the installation placement direction is wrong.

Disclosure of Invention

In order to overcome the technical defects, the invention provides a hydrogen storage device with identity recognition and a hydrogen fuel electric bicycle, so as to solve the problems related to the background technology.

The invention provides a hydrogen storage device with identity recognition, which comprises:

a bottle for storing a solid hydrogen storage material and hydrogen gas;

the protective cover is arranged at the air outlet of the bottle body and is connected with the bottle body in a sealing way;

the low-pressure air inlet or outlet is arranged on one side of the protective cover and is connected with the air outlet of the bottle body;

and the identity identification label is arranged on the protective cover or the bottle body and has the same placement direction as the standard installation of the hydrogen storage device.

As a preferred scheme, the identity identification tag is an RFID or a two-dimensional code;

the identification tag at least comprises or can obtain one or more information of the number of the hydrogen storage device, the production date, relevant parameters of the hydrogen storage device, the most recent charging time and the hydrogen charging amount, and the hydrogen storage amount in the hydrogen storage device.

As a preferred scheme, the identification label is fixedly arranged on the inner side of the protective cover, and the identification area of the identification label is exposed out of the outer side of the protective cover through a hollow or transparent area arranged on the protective cover.

As a preferable aspect, the hydrogen storage vessel further comprises: the multifunctional integrated combination valve is arranged on the air outlet of the bottle body; the combination valve includes:

a valve body;

the connecting port is communicated with the gas outlet of the bottle body and transmits hydrogen into the valve body;

the air vent is communicated with the connecting port, receives and transmits hydrogen to the bottle body and/or transmits hydrogen to the galvanic pile;

a control valve provided at a connection point between the vent port and the connection port, for controlling opening and closing of the connection port and the vent passage;

the safety valve is communicated with the connecting port to ensure that the internal pressure of the bottle body is controlled within a low pressure range of 1-3 MPa;

and the pressure regulating valve is arranged on a passage between the connecting port and the vent and is used for controlling the air pressure in the valve body.

As a preferable scheme, the air vent is connected with a sealing joint, penetrates through the protective cover and is exposed out of the protective cover to form a low-pressure air outlet;

the sealing joint comprises: the first joint is connected with the air vent, and the second joint is connected with a gas supply pipeline of the galvanic pile;

when the first connector and the second connector are in a disconnected state, the first connector has a current-cut function and forms an open circuit;

when the second connector is plugged into the first connector, a passage is formed, and hydrogen is supplied to the electric pile through a pipeline.

As a preferred scheme, the bottle body is made of an aluminum alloy seamless material and an aluminum alloy liner carbon fiber winding composite material.

As a preferable scheme, the bottle body is provided with a groove body along the axial direction of the bottle body, and the groove body is separated from the interior of the bottle body through the shell wall of the bottle body;

the tank body comprises an inner layer and an outer layer, a preset gap is reserved between the inner layer and the outer layer to form a first cavity, and a heating medium is filled in the first cavity.

As a preferable scheme, the hydrogen storage device also comprises a temperature reduction element;

the temperature reducing element comprises at least one endothermic reactant capable of inducing an endothermic effect in response to a trigger.

As a preferable scheme, the cooling element is arranged in or on one side of the first cavity, and is separated from the first cavity by a trigger type partition to form a second cavity, and at least one endothermic reactant is stored in the second cavity;

the trigger type separator is a baffle made of a material capable of fusing automatically at high temperature or a valve capable of being opened automatically by high-temperature triggering.

The invention also discloses a hydrogen fuel electric bicycle which comprises a motor and a galvanic pile connected with the motor, wherein the galvanic pile is connected to the hydrogen storage device.

The invention relates to a hydrogen storage device with identity recognition and a hydrogen fuel electric bicycle, compared with the prior art, the hydrogen storage device has the following beneficial effects:

1. by arranging the identity identification tag on the surface of the hydrogen storage device, on one hand, a user obtains relevant information of the hydrogen storage device through scanning equipment; on the other hand, the user can judge the directionality of the hydrogen storage device through the direction of the identity identification tag, and the installation and placement direction of the hydrogen storage device is ensured to meet the requirements.

2. Through solid-state hydrogen storage material with the low pressure mode storage, the security is high, when needs use, can use heating element to the heating of solid-state hydrogen storage material, improves and puts out hydrogen performance, is applicable to the use scene of hydrogen fuel electric bicycle under the extreme weather.

3. Through making up a plurality of functional valve and designing into the combination valve, the design structure of combination valve is reasonable, the integrated level is high, the security performance is good, long service life. The pipeline arrangement of the hydrogen fuel electric bicycle is further simplified, the possibility of mutual staggered winding between pipelines is reduced, and the difficulty of later maintenance is reduced.

4. The hydrogen storage device and the solid-state hydrogen storage material are heated through the configuration of the heat conduction path, so that the temperature rise process of the hydrogen storage device and the solid-state hydrogen storage material is smoother, and the stability and the safety of the hydrogen storage device are improved.

5. Through the design of the cooling element, when high temperature or fire and other conditions occur, the internal temperature of the hydrogen storage device is reduced, the solid hydrogen storage material is rapidly cooled, the internal pressure of the hydrogen storage device is controlled to be maintained in a low-pressure range of 1-3MPa, and temperature pressure relief is realized.

6. Through connecting sealing joint at the gas outlet, when transportation, change hydrogen storage device, first joint is in the state of opening a circuit, self-sealing combination valve's gas outlet, has improved combination valve's gas tightness, further reduces hydrogen and reveals the volume.

7. The protection casing combines together with the valve body and forms a safe combination valve, can be used to the safety control of gas leakage, and the project organization is reasonable, the integrated level is high, the security performance is good, long service life.

Drawings

FIG. 1 is a schematic view of a prior art hydrogen storage device and its wiring structure.

FIG. 2 is a schematic cross-sectional view of a hydrogen storage vessel according to the present invention.

FIG. 3 is a schematic cross-sectional view of a hydrogen storage container and a shield according to the present invention.

FIG. 4 is a schematic cross-sectional view of the hydrogen storage container of the present invention at the gas outlet.

Fig. 5 is a schematic structural view of the combination valve of the present invention.

Fig. 6 is a schematic connection diagram of the combination valve of the present invention.

Fig. 7 is a schematic view showing the installation of the handle in the present invention.

Fig. 8 is a schematic structural diagram of a temperature control system according to a preferred embodiment of the present invention.

FIG. 9 is a flow chart illustrating a temperature control method according to a preferred embodiment of the present invention.

Fig. 10 is a schematic structural view of a hydrogen-fueled electric bicycle according to a preferred embodiment of the present invention.

The reference signs are:

hydrogen storage 100, galvanic pile 200, functional valve 300;

the bottle body 110, a groove body 111, a heating layer 112, an anti-slip groove 113, an accommodating step 115, a first cavity 111a, an inner layer 111b and an outer layer 111c;

a heating element 120;

an electrical connection element 130;

a combination valve 140, a connecting port 141, an inflation port 142, a safety valve 143, a pressure regulating valve 144, an air outlet 145, a control valve 146 and a valve body 147;

a cooling element 150, a second cavity 151, a triggered partition 152;

a sealing joint 160, a first joint 161;

a protective cover 171, an identity recognition label 172 and a low-pressure air outlet 173;

handle 180, mounting groove 181, handle 182, spout 183, connecting rod 184.

Detailed Description

In the following description, numerous specific details are set forth in order to provide a more thorough understanding of the present invention. It will be apparent, however, to one skilled in the art, that the present invention may be practiced without one or more of these specific details. In other instances, well-known features have not been described in order to avoid obscuring the invention.

Referring to fig. 1, a hydrogen storage device and a wiring structure thereof in the prior art are shown; various functional valves 300 are connected with bottle 110 as independent main body through pipeline among the prior art, and the other end passes through pipe connection multistage relief pressure valve, then is connected with galvanic pile 200 again, realizes hydrogen storage bottle's hydrogen filling, decompression and play hydrogen, and the hydrogen supply of galvanic pile leads to hydrogen fuel electric bicycle's pipeline complicacy from this, and crisscross winding each other increases the later maintenance degree of difficulty.

In order to simplify the piping arrangement and improve the structural rationality of the hydrogen fuel electric bicycle, the invention provides a low-pressure safety hydrogen storage device, comprising: the combined valve is arranged on the gas outlet of the bottle body, and the solid hydrogen storage material is arranged in the bottle body; the bottle body and the combined valve are in an integrated connecting structure instead of pipeline connection or line connection, integrated installation and production are directly carried out by a factory according to design requirements, and the connecting structure comprises but not limited to fixed connecting modes such as threaded fit, clamping fit and welding, so that the hydrogen storage bottle and the combined valve form a closed cavity. Solid hydrogen storage materials are stored in the closed cavity, and after the solid hydrogen storage materials are heated, hydrogen pressure is provided for the galvanic pile through the combination valve to be 15-65kpa, so that when the hydrogen storage bottle is not used, the internal pressure of the hydrogen storage bottle is small (low-pressure hydrogen storage in a general sense), and the hydrogen storage bottle cannot harm users.

In a further embodiment, the combination valve is a multifunction integrated valve, the combination valve comprising: the valve body, the connecting port, the inflation inlet, the air outlet, the control valve, the safety valve and the pressure regulating valve; the connecting port is communicated with the gas outlet of the bottle body and transmits hydrogen into the valve body; the inflation inlet is communicated with the connecting port, and is used for unidirectionally receiving hydrogen and transmitting the hydrogen to the connecting port; the gas outlet is communicated with the connecting port, receives hydrogen, is connected to an electric pile and provides 15-65kpa of hydrogen to the electric pile, and it needs to be noted that, for a person skilled in the art, the gas charging port and the gas outlet are combined into one on the premise of not influencing the realization of functions of the person; the control valve is arranged on the connection points of the inflation inlet, the air outlet and the connecting port and controls the opening and closing of the connecting port and the inflation inlet passage as well as the connecting port and the air outlet passage; the safety valve is communicated with the connecting port to ensure that the internal pressure of the bottle body is controlled within a low pressure range of 1-3 MPa; the pressure regulating valve is arranged on the connecting port and the air outlet passage and used for controlling the air pressure in the valve body. Through making up a plurality of functional valve and designing into the combination valve, the design structure of combination valve is reasonable, the integrated level is high, the security performance is good, long service life. The pipeline arrangement of the hydrogen fuel electric bicycle is further simplified, the possibility of mutual staggered winding between pipelines is reduced, and the difficulty of later maintenance is reduced.

In a further embodiment, the sealing joint has a flow stopping function, and comprises a first joint part and a second joint part; the first joint is connected with the air outlet, and the second joint is connected with the galvanic pile through a pipeline and used for gas supply of the galvanic pile. When the first joint and the second joint are in a disconnected state, the first joint has a flow stopping function, so that an open circuit is formed, and hydrogen leakage is avoided; when the second joint is inserted into the first joint, a passage is formed and is connected to the galvanic pile through a pipeline to provide hydrogen for the galvanic pile; the valve port at the gas outlet is connected with the sealing joint, so that the first joint is in an open circuit state when the hydrogen storage device is transported and replaced, the gas outlet of the combined valve is automatically closed, the gas tightness of the combined valve is improved, and the hydrogen leakage amount is further reduced.

In a further embodiment, the bottle body sequentially comprises an inner container, a winding layer and a shell from inside to outside; the bottle body is made of an aluminum alloy seamless material and an aluminum alloy liner carbon fiber winding composite material, the volume is 1000-5000 ml, compared with a common steel bottle, the weight can be reduced by 40% -70%, and meanwhile, the bottle body has the characteristics of high safety and easiness in carrying, and the aluminum alloy has a unique corrosion resistance characteristic after being oxidized.

In a further embodiment, in order to realize that the hydrogen storage device can store hydrogen at low pressure, the hydrogen storage device further comprises a heating element and an electric connection element. The heating element is arranged to enable the hydrogen storage container to store less solid hydrogen storage materials when the solid hydrogen storage materials are prestored in the hydrogen storage container, or liquid hydrogen, hydrogen storage powder and the like are stored in the hydrogen storage container, the internal pressure of the hydrogen storage bottle is controlled within a low-pressure range of 1-3MPa, and the hydrogen pressure is supplied to the stack by the combined valve pressure regulator and is 15-65kpa. When the heating element heats the internal solid hydrogen storage material, the pressure of the internal solid hydrogen storage material is gradually increased due to the temperature rise of the solid hydrogen storage material and the sealing property of the hydrogen storage device, and the internal solid hydrogen storage material is vaporized into hydrogen until reaching the pressure range which can be used, so that the hydrogen storage device can be used in a high-pressure use scene. In this regard, the heating element will extend from the bottom of the bottle into the middle of the bottle in the axial direction (i.e., the length direction) of the hydrogen storage device, and the extension length is limited and is not the same as the entire axial direction of the hydrogen storage device, so that after the heating element extends, the farthest end, or the heating end, is spaced from the mouth of the bottle, and does not hinder the mouth of the hydrogen storage device from transferring the solid hydrogen storage material outwards.

It will be understood that the heating element extends into the hydrogen storage vessel and is not limited to extending into the interior of the hydrogen storage vessel. Conversely, when the hydrogen storage container is in an irregular shape, the heating element may protrude into the outer center of the body, and when the hydrogen storage container is in a regular shape, the heating element may protrude into the interior of the body, or a portion of the heating element may protrude into the outer center of the body and another portion may protrude into the interior of the body, and heat may be transferred to the solid-state hydrogen storage material by contact conduction or radiation conduction after generating heat, thereby heating the solid-state hydrogen storage material.

In a further embodiment, a groove body which is sunken towards the interior of the bottle body is arranged on the bottle body and used for placing the groove body heating element. The tank body comprises an inner layer and an outer layer, a first cavity is formed between the inner layer and the outer layer, a heating medium is filled in the first cavity, the heating medium comprises but is not limited to water, silicon oil and heat conducting oil and serves as a conducting medium and a heat insulation medium, and the hydrogen storage device and the solid hydrogen storage material are heated through the configuration of a heat conducting path, so that the heating process of the solid hydrogen storage material is more stable and safer. In the present invention, the heating medium is preferably water; because water has higher specific heat capacity, the temperature rising process is smoother, and the heating process of the solid hydrogen storage material is more stable and safer.

Besides the heating element, the hydrogen storage device also comprises an electric connecting element which is electrically connected with the heating element and is exposed out of the bottle body. The energy source of the heating element is from the electric connecting element, the electric connecting element is connected with an external power supply, after the power is on, the external power supply transmits electric energy to the electric connecting element, then the electric energy is transmitted to the heating element by the electric connecting element, and the heating element converts the electric energy into heat after receiving the electric energy, thereby heating the solid hydrogen storage material and improving the pressure of the solid hydrogen storage material in the hydrogen storage device.

Conversely, when the temperature of the hydrogen storage vessel is too high, the pressure inside the hydrogen storage vessel becomes too high, and hydrogen leakage or even explosion may occur. Therefore, the hydrogen storage device also comprises a cooling element, the cooling element is used as an emergency protection element, when continuous high temperature or fire and other conditions occur, the internal temperature of the hydrogen storage device is reduced, the solid hydrogen storage material is rapidly cooled, the internal pressure of the hydrogen storage bottle is controlled to be maintained within a low pressure range of 1-3MPa, temperature pressure relief is realized, and the safety performance of the hydrogen storage bottle is improved; specifically, when the temperature reaches the threshold value, triggering the instruction, sending to the cooling component, starting the cooling component based on the instruction, and cooling the hydrogen storage bottle. The cooling element can take various forms such as physical cooling (e.g., a circulating refrigeration system) or chemical cooling. In the invention, the temperature reduction element is preferably chemical temperature reduction and comprises at least one endothermic reactant, wherein the endothermic reactant is an endothermic effect caused by responding to triggering; for example, when the temperature reaches a threshold value, ammonium salt and nitrate are dissolved in water, an endothermic reaction is triggered, and a cooling effect is achieved.

In a further embodiment, the hydrogen storage device further comprises a protective cover for protecting the gas outlet and the combination valve of the hydrogen storage device; an identity identification label, such as an RFID/two-dimensional code, is printed on one side of the protective cover; since the installation and placement direction of the hydrogen storage device is unique, the printing direction of the identification tag is the same as the standard placement direction of the hydrogen storage device. The user can judge the directionality of the hydrogen storage device through the direction of the identity identification tag, and the installation and placement direction of the hydrogen storage device is ensured to meet the requirements.

The technical solution is further explained with reference to the drawings and the specific embodiments.

Examples

A low pressure hydrogen storage vessel comprising: the bottle body 110, the groove body 111, the heating layer 112, the anti-slip groove 113, the accommodating step 115, the first cavity 111a, the inner layer 111b, the outer layer 111c, the heating element 120, the electrical connecting element 130, the combination valve 140, the connecting port 141, the air charging port 142, the safety valve 143, the pressure regulating valve 144, the air outlet 145, the control valve 146, the valve body 147, the temperature reducing element 150, the second cavity 151, the trigger type separating element 152, the sealing connector 160, the protective cover 171 of the first connector 161, the identification tag 172, the low-pressure air outlet 173, the handle 180, the mounting groove 181, the handle 182, the chute 183 and the connecting rod 184.

Referring to fig. 2 to 4, in this embodiment, the heating element 120 does not extend into the interior of the bottle 110, i.e., the heating element 120 heats the solid hydrogen storage material by indirect conduction heating, rather than direct contact heating. In this regard, the bottle body 110 is provided with a groove 111 along the axial direction thereof, the groove 111 may be formed such that the bottom of the bottle body 110 extends toward the inside of the bottle body 110, but the whole bottle body 110 is kept in a closed state, and the irregular shape formed by the protruding portion is the groove 111, so that the groove 111 is separated from the inside of the bottle body 110 by the wall of the bottle body 110, so that the groove 111 is separated from the inside of the bottle body 110, and the groove 111 is still communicated with the outside space of the bottle body 110.

The tank body is of a double-layer structure and comprises an inner layer 111b and an outer layer 111c, a preset gap is reserved between the inner layer 111b and the outer layer 111c to form a closed first cavity 111a, a heating medium is filled in the first cavity 111a and serves as a conducting medium and a heat insulation medium, and the hydrogen storage device and the solid hydrogen storage material are heated through the configuration of a heat conduction path, so that the heating process of the solid hydrogen storage material is more stable and safer.

After the tank 111 is provided, the heating element 120 penetrates into the tank 111 and is in clearance fit with the tank 111, that is, the outer surface of the heating element 120 is in close contact with the inner wall of the tank 111, after the heating element 120 generates heat, the heating element 120 first needs to heat the heating medium, then heats the bottle body 110, and then the bottle body 110 conducts heat to the solid hydrogen storage material. The heating medium is preferably water; because water has higher specific heat capacity, the temperature rise process is smoother, the heating efficiency of the solid hydrogen storage material can be slowed down, and the heating temperature of the solid hydrogen storage material can be controlled more accurately.

It will be appreciated that the engagement of the heating element 120 with the channel 111 is not limited to the side edges of the heating element 120 each engaging an interior of the channel 111 with a clearance fit. The outer surface of the heating element 120 may be in a tooth shape or a wave shape, the tooth-shaped high position or the wave peak position is in contact with the groove body 111 for conduction, an air layer is also arranged between the tooth-shaped low position or the wave trough position and the inner wall of the groove body 111, the air layer is a heat insulation layer and a conduction layer, the heat generated by the heating element 120 can be indirectly conducted to the bottle body 110 through the air layer, and the total heat conduction amount of the heating element 120 can be controlled.

Further, the heating end of the heating element 120 far from the electrical connection element 130 is not in direct contact with the tank body 111, whereas the length of the tank body 111 in the axial direction of the bottle body 110 is greater than the length of the heating element 120 in the axial direction of the bottle body 110, so that a heating layer 112 is provided between the heating end of the heating element 120 and the tank bottom of the tank body 111, the heating layer 112 is similar to the above air layer, and the heat of the heating element 120 is conducted to the bottle body 110 through the heating layer 112, thereby preventing excessive heating of the solid hydrogen storage material. That is, having the heating layer 112, it acts as both a conductive medium and a thermal insulating medium, somewhat controlling the heating efficiency of the heating element 120 to the solid-state hydrogen storage material.

The solid-state hydrogen storage material is heated more stably and safely by configuring the heat conduction path to heat the solid-state hydrogen storage material in the bottle 110 of the heating element 120.

In another aspect, the hydrogen storage vessel further comprises a temperature reducing element 150. The temperature reducing element 150 is disposed inside or on one side of the first cavity 111a, and is separated from the first cavity 111a by a trigger-type partition 152 to form a second cavity 151, and at least one endothermic reactant, in this embodiment, ammonium salt or nitrate, is stored inside the second cavity 151. Under the high temperature condition, trigger formula separator 152 opens, communicates second cavity 151 and first cavity 111a trigger endothermic reactant mixes ammonium salt, nitrate and water, arouses the endothermic effect, reduces heating medium's temperature, and then the cooling of bottle, solid-state hydrogen storage material reduces the temperature in the bottle, realizes the temperature pressure release.

The triggered separating member 152 may be a shutter made of a material that automatically fuses at a high temperature, or a valve that automatically opens when triggered at a high temperature. For example, the valve includes but is not limited to a magnetic switch, a magnetic material with a suitable curie point is selected as a controller, the magnetic material may be a neodymium iron boron magnet, when the temperature is higher than a predetermined temperature, the magnetic material is converted into paramagnetism to play a role in magnetic isolation, the separator is automatically opened to communicate the second cavity 151 and the first cavity 111a, and the cooling element 150 is triggered; conversely, the trigger spacer 152 remains isolated at all times.

The automatic triggering of the cooling element 150 is realized through material characteristics, temperature information does not need to be obtained, the response time of the cooling element 150 is prolonged, the internal temperature of the hydrogen storage device is reduced, and the internal pressure of the hydrogen storage device is controlled to be maintained in a low-pressure range of 1-3 MPa.

When the heating element 120 is installed, the installation end of the heating element 120 is provided with an external thread, and the notch of the groove body 111 is provided with an internal thread; the external threads mate with the internal threads to secure the heating element 120 within the tank 111. Alternatively, the bottom of the bottle body 110 is flush with the notch of the tank body 111 such that the bottom of the bottle body 110 is flat, and thus, when the hydrogen storage container 100 is placed, the bottom of the bottle body 110 may be directly attached to the placement surface, which is different from the shape of the hydrogen storage container 100 in the prior art, and thus, the installation is more convenient. In order to prevent the hydrogen storage container 100 from falling down, at least one anti-slip groove 113 is formed on the bottom end surface of the bottle body 110, and the anti-slip groove 113 is formed in a direction along the radial direction of the bottle body 110 or at a predetermined angle, such as being inclined, with respect to the radial direction of the bottle body 110, or a plurality of anti-slip grooves 113 at predetermined angles, so as to generate friction forces in different directions, thereby further enhancing the anti-slip effect.

Preferably or optionally, the heating element 120 is a resistance wire, and a temperature sensor is disposed in the resistance wire, or the temperature sensor is disposed outside the resistance wire, and detects the temperature of the resistance wire, so that a user can monitor the heating process of the heating element 120 in real time. On the other hand, the electrical connection member 130 has a socket into which an external power source is inserted to receive power.

Preferably or alternatively, the bottle body 110 is provided with a receiving step 115 at the position where the electrical connection element 130 is received, the radial width of the receiving step 115 is greater than that of the heating element 120, so that the heating element 120 can penetrate through the receiving step 115, and the radial width of the electrical connection element 130 is matched with that of the receiving step 115, so that when the electrical connection element 130 is installed in contact with the receiving step 115, the electrical connection element 130 is blocked by the receiving step 115 as the heating element 120 extends, the displacement of the electrical connection element extending into the middle of the bottle body 110 is limited by the receiving step 115, and the electrical connection element 130 partially protrudes out of the bottle body 110, so that a user can conveniently plug an external power supply. With the above design, the accommodating step 115 may be additionally fixedly connected to the electrical connection element 130, such as a snap-fit type or a screw type, to further secure the mounting relationship between the heating element 120 and the bottle 110, thereby preventing the heating element 120 from being pushed out after the pressure of the internal solid hydrogen storage material is increased.

It is understood that the electrical connection element 130 may not protrude from the bottle body 110, for example, be slightly recessed at the receiving step 115, or be flush with the receiving step 115, in order to achieve the uniformity of the overall shape of the hydrogen storage container 100. When the electrical connection element 130 is slightly recessed in the accommodation step 115, a sealing end may be additionally disposed at the accommodation step 115, and when the electrical connection element 130 is not connected to an external power source, the sealing end seals the accommodation step 115 to hide the electrical connection element 130 inside, and the electrical connection element 130 is opened when it is needed.

Preferably or alternatively, referring to fig. 5 to 6, the hydrogen storage container 100 further includes a combination valve 140 provided at the mouth of the bottle body 110; the combination valve 140 includes: a valve body 147; a connection port 141 which communicates with the gas outlet of the bottle body and transmits hydrogen gas into the valve body 147; the inflation inlet 142 is communicated with the connection port 141, and is used for unidirectionally receiving hydrogen and transmitting the hydrogen to the connection port 141; a gas outlet 145 which is communicated with the connection port 141, receives hydrogen gas, is connected to a stack, and supplies the hydrogen gas to the stack; a control valve 146, which is disposed at a connection point between the inflation inlet 142 and the air outlet 145 and the connection port 141, and controls the opening and closing of the passage between the connection port 141 and the inflation inlet 142 and the passage between the connection port 141 and the air outlet 145; the safety valve 143 is communicated with the connecting port 141 to ensure that the internal pressure of the bottle body is controlled within a low pressure range of 1-3 MPa; and a pressure regulating valve 144 provided in a path between the connection port 141 and the outlet port 145 to control the pressure in the valve body 147. Through combining a plurality of functional valves and designing into combination valve 140, combination valve 140's design structure is reasonable, the integrated level is high, the security performance is good, long service life. The pipeline arrangement of the hydrogen fuel electric bicycle is further simplified, the possibility of mutual staggered winding between pipelines is reduced, and the difficulty of later maintenance is reduced.

Preferably or optionally, the inflation port 142 and the air outlet 145 are combined into a whole to form an air vent, and a two-way valve is arranged on a channel between the air vent and the connection port 141, and ensures one-way circulation of hydrogen from the air vent to the connection port 141 in the inflation process; during the air outlet process, the two-way valve ensures that the hydrogen gas flows from the connecting port 141 to the air vent in one way. Alternatively, referring to fig. 6, two vent lines are disposed between the vent hole and the connection port 141, and one-way valves are disposed on the two vent lines, respectively, one-way valve ensuring air supply to the stack, and one-way valve ensuring air inflation to the inside of the bottle body. Through designing the vent line in the valve body, reduce the external connection interface of combination valve, make the integrated level of valve body high, compact structure is reasonable, light in weight, reduce the risk of gas leakage.

Preferably or optionally, the sealing joint 160 has a shut-off function, and the sealing joint 160 comprises two parts, namely a first joint 161 and a second joint; the first joint 161 is connected with the air outlet 145, and the second joint is connected with the electric pile through a pipeline and used for supplying air to the electric pile. When the first connector 161 and the second connector are in a disconnected state, the first connector 161 has a cut-off function, so that an open circuit is formed, and hydrogen leakage is avoided; when the second connector is plugged into the first connector 161, a passage is formed and connected to the stack through a pipeline, and hydrogen is supplied to the stack; by connecting the sealing joint 160 to the valve port of the gas outlet 145, the first joint 161 is in an open circuit state during transportation and replacement of the hydrogen storage device, and automatically closes the gas outlet 145, thereby improving the gas tightness of the combination valve 140 and further reducing the leakage of hydrogen.

Preferably or optionally, the hydrogen storage device further comprises a shield 171, the shield 171 being mounted at the gas outlet of the hydrogen storage bottle in sealing connection with the bottle body; the protection cover 171 and the combination valve 140 are of an integrated structure, on one hand, the protection cover is used for protecting the gas outlet of the hydrogen storage device and the combination valve 140, on the other hand, the protection cover 171 and the combination valve 140 are combined to form a safety combination valve which can be used for safety control of gas leakage; an identification tag 172, such as an RFID/two-dimensional code, is printed on one side of the protective cover 171, and the sealing joint 160 on the other side of the protective cover 171 penetrates through the protective cover 171 and is exposed out of the protective cover 171 to form a low-pressure air outlet 173, which is conveniently connected with a second joint to provide low-pressure hydrogen for the galvanic pile; since the installation and placement direction of the hydrogen storage container is unique, the printing direction of the identification tag 172 is the same as the standard installation and placement direction of the hydrogen storage container in the present invention. The user can further judge the directionality of the hydrogen storage device through the direction of the identity identification tag 172, and the installation and placement direction of the hydrogen storage device is ensured to meet the requirements.

When the identification tag 172 is used, the user obtains the tag ID of the RFID/two-dimensional code associated with the hydrogen storage device through the scanning device, and then transmits the tag ID to the service terminal through the communication unit, so as to obtain the relevant information of the hydrogen storage device, including but not limited to the following information: the number of the hydrogen storage device, the production date, relevant parameters of the hydrogen storage device, the most recent charging time and the hydrogen charging amount, and the hydrogen storage amount in the hydrogen storage device. It should be noted that the above information is updated in real time with the processing, transportation and use of the hydrogen storage device.

Preferably or optionally, the identification tag 172 is fixedly mounted inside the protective cover, and its identification area is exposed outside the protective cover 171 through a hollow or transparent area disposed on the protective cover 171, so as to identify and update information of the identification device. Based on the above design, the user can only open under the prerequisite of protection casing 171, dismantle or install identification label 172, work as the protection casing is installed on the bottle after, can't install and dismantle identification label 172 in the protection casing outside. Therefore, the stability is better, and the falling off of the identification label 172 caused by human factors or natural factors is avoided.

Preferably or optionally, a handle 180 is mounted on the bottle body 110 or the protective cover 171, and the handle 180 is a foldable handle 180, and particularly, referring to fig. 7, the handle includes: the bottle body comprises a mounting groove 181 arranged inside the bottle body shell or connected outside the shell, a handle 182 with one end hinged with the top of the mounting groove 181, an axial sliding groove 183 arranged at the other end of the handle 182, and a connecting rod 184 with one end hinged with the bottom of the mounting groove 181 and the other end clamped on the sliding groove 183. When the user uses the handle 180, the user only needs to pull the bottom of the handle grip 182 outward, and the link moves downward, so that a space exists between the handle grip 182 and the mounting groove 181 to form the handle 180. On the contrary, when the handle 180 is not needed, the handle 182 is only needed to be placed in the mounting groove 181, so that the occupied space of the hydrogen storage device 100 is greatly reduced, and the transportation efficiency of the hydrogen storage device is improved in the process of batch transportation. It should be noted that the handle 180 is exemplarily installed outside the bottle body 110 in fig. 7, and the installation position of the handle 180 is not to be construed as a limitation, and it is obvious to those skilled in the art that the handle 180 may be installed on the bottle body 110, the protective cover 171, or other conveniently fixed positions.

After the hydrogen storage device is arranged, the hydrogen storage device can be applied to a hydrogen fuel electric bicycle which comprises a motor and a galvanic pile connected with the motor, wherein the galvanic pile is further connected to the hydrogen storage device to receive the discharged hydrogen so as to generate electric energy by utilizing the hydrogen pressure.

Referring to fig. 8, a temperature control system for a low pressure hydrogen storage vessel is shown for improving the hydrogen discharge efficiency of the hydrogen storage vessel. The hydrogen storage device comprises a bottle body and a valve body arranged at the gas outlet of the bottle body, wherein after the solid hydrogen storage material in the hydrogen storage device is heated, the valve body pressure regulator provides hydrogen pressure to the galvanic pile to be 15-50kpa, so that when the hydrogen storage device is not used, the internal pressure of the hydrogen storage device is small (low-pressure hydrogen storage in the general sense), and the harm to users can not be caused, and liquid hydrogen, hydrogen powder and the like can be stored in the hydrogen storage device. When the hydrogen storage device is used or the internal hydrogen discharging efficiency is improved, the hydrogen storage device can be heated, and therefore, the temperature control system further comprises temperature monitoring equipment and heating equipment, the temperature monitoring equipment is arranged in the hydrogen storage device, for example, the temperature monitoring equipment can be arranged at the same position of a pressure valve for monitoring the pressure of the hydrogen storage device, a temperature sensor is fixedly installed and used as the temperature monitoring equipment, when the temperature monitoring equipment works, the temperature in a bottle body of the hydrogen storage device is monitored, namely, the temperature of the solid hydrogen storage material is directly monitored in real time, and for the temperature of the solid hydrogen storage material, the temperature monitoring equipment generates a temperature signal which carries the current temperature information of the solid hydrogen storage material. On the other hand, the heating device can be arranged in the hydrogen storage device or outside the hydrogen storage device, and when the heating device works, the solid hydrogen storage material can be directly or indirectly heated, for example, when the heating device is arranged outside the hydrogen storage device, the heat generated by the heating device is firstly transmitted to the bottle body and is then transmitted to the solid hydrogen storage material; when the heating device is placed inside the bottle, the heat generated by the heating device will be radiated or transferred directly to the solid-state hydrogen storage material, thereby raising the temperature of the solid-state hydrogen storage material. Due to the sealing property of the hydrogen storage device, the pressure of the solid hydrogen storage material is increased when the mass is constant, namely, the solid hydrogen storage material is converted from a low-pressure state to a high-pressure state.

The temperature control system also comprises a temperature control module which is electrically connected with the temperature monitoring device and the heating device respectively, a temperature signal formed by the temperature monitoring device is sent to the temperature control module, and a temperature threshold value is prestored in the temperature control module and reflects the expected working temperature of the hydrogen storage device or the temperature of the solid hydrogen storage material in the temperature control module at the expected hydrogen discharge speed. The temperature control module compares the current temperature with a temperature threshold value, if the information of the current temperature carried by the temperature signal is lower than the temperature threshold value, the temperature of the solid hydrogen storage material under low pressure is indicated to be lower, and the hydrogen release speed at the moment cannot be expected, so that the temperature control module generates an activation instruction and sends the activation instruction to the heating equipment, the heating equipment starts to work based on the activation instruction and heats the solid hydrogen storage material in the hydrogen storage device, and the hydrogen release speed of the solid hydrogen storage material is increased after the temperature of the solid hydrogen storage material is increased, so that the requirement of normal use is met.

In a preferred embodiment, the temperature control module comprises a temperature comparison circuit, a heating control circuit and a heating protection circuit. Specifically, the temperature comparison circuit is electrically connected to the temperature monitoring device, and the temperature threshold (which may be a specific value or a data range) is stored in the temperature comparison circuit, and is configured to receive a temperature signal and compare the current temperature with the temperature threshold; the heating control circuit is electrically connected with the temperature comparison circuit and the heating equipment, the comparison result of the temperature comparison circuit, such as the current temperature is greater than the temperature threshold, the current temperature is equal to the temperature threshold, the current temperature is less than the temperature threshold and the like, is sent to the heating control circuit, and different instructions are generated based on different comparison results, for example, when the current temperature is greater than the temperature threshold or the current temperature is equal to the temperature threshold, the hydrogen discharging speed in the hydrogen storage device is sufficient, and when the current temperature is less than the temperature threshold, the activation instruction is generated; the heating protection circuit is arranged between the heating control circuit and the heating equipment, monitors the working state of the whole temperature control module, and cuts off a heating link from the heating control circuit to the heating equipment when the temperature control module has faults, such as open circuit, short circuit and the like, so as to protect the heating equipment.

Furthermore, the temperature control module further comprises a clock unit which is electrically connected with the heating control circuit and adds clock information to the activation instruction, wherein the clock information comprises heating time t; the heating time t is calculated based on the following formula: t = (temperature threshold-current temperature) × time threshold/temperature threshold difference, the temperature threshold difference and the time threshold are prestored based on a test temperature and a test time. In addition to the above-mentioned heating time t, the heating time t may also be set to a fixed value, the activation of the heating device is maintained during the set heating time t, and the activation is terminated after the heating time t is completed. In the calculation formula of the heating time t, a weight value can be added, and the heating time t is adjusted according to the used scenes (region information, season information and the like), so that the heating time t can be adjusted at any time according to different use conditions.

Preferably, in an embodiment, even in the activated state of the heating device, the heating state is adjusted in real time, for example, after the heating time t, when the monitoring result of the temperature monitoring device on the hydrogen storage device is that the updated current temperature is still lower than the temperature threshold, the temperature control module generates the activation command again, and sends the activation command to the heating device, so as to control the heating device to continue to operate. It is understood that, if the current temperature is still lower than the temperature threshold value under the condition of reheating, the above steps are repeatedly executed until the current temperature is higher than or equal to the temperature threshold value; if the heating process provides enough heat within the heating time t, that is, if the current temperature is higher than the temperature threshold during the heating process, the temperature control module calculates a difference between the current temperature and the temperature threshold, compares the difference with a preset difference pre-stored in the temperature control module, and sends a turn-off command to the heating device in advance within the heating time t when the difference between the current temperature and the temperature threshold is greater than the preset difference, that is, within the heating time t, the heating effect is satisfied, not only just satisfied, but has a part of redundancy, and ends the heating process in advance.

In a preferred embodiment, the temperature monitoring device is a temperature sensor, is fixed in the bottle body, is connected with the valve body, and can be arranged in a same position with the pressure sensor for monitoring the pressure in the hydrogen storage device. The heating device is in a belt shape and is arranged around the outside of the bottle body. Or in other preferred embodiments, the heating device extends into the bottle body for heating the hydrogen storage device, while the temperature monitoring device is fixed on the heating device, integrally formed with the heating device (the heating device itself is a heating assembly with the temperature monitoring device) or mounted on the heating device. The end of the heating device is provided with a socket, the temperature control module is provided with an electric connecting piece, the electric connecting piece is inserted into the socket to be connected with the heating device, and the electric energy is converted into heat energy by the heating device by providing the electric energy for the heating device. In another embodiment, the electrical connector further comprises a heat conduction element, and the residual heat of the temperature monitoring device is transmitted to the heating device through the heat conduction element, so that the energy can be further saved through the mechanism of heat compensation.

Referring to fig. 9, in one embodiment, a method for temperature control of a hydrogen storage vessel is also shown, comprising the steps of:

s100: the temperature monitoring device arranged in the hydrogen storage device monitors the temperature in the hydrogen storage device and forms a temperature signal comprising the current temperature;

s200: the temperature control module is electrically connected with the temperature monitoring equipment, receives the temperature signal, compares the current temperature with a preset temperature threshold value, and generates an activation instruction when the current temperature is lower than the temperature threshold value;

s300: a heating device receives the activation command and heats the solid-state hydrogen storage material in the hydrogen storage vessel.

Referring to fig. 10, in another embodiment, a hydrogen-fueled electric bicycle is further shown, which includes the temperature control system as described above, the hydrogen storage device is connected to a cell stack control module of the hydrogen-fueled electric bicycle to provide hydrogen to a cell stack control unit, and the cell electric propulsion control unit is connected to a lithium battery pack to supply electric energy to the lithium battery, so that the lithium battery can function as a power-assisted vehicle; the battery cell stack control unit is also connected with the moped control unit, the moped control unit controls the working states of a vehicle lock and a motor in the moped, and the control logic of the working states is generated by the battery cell stack control unit. Preferably, the cell stack control unit can also provide heat energy to the temperature control system, that is, waste heat generated when the fuel cell stack operates compensates the heat to the temperature monitoring device, thereby saving energy.

It should be noted that the various features described in the above embodiments may be combined in any suitable manner without departing from the scope of the invention. The invention is not described in detail in order to avoid unnecessary repetition.

Claims

1. A hydrogen storage device with identification, comprising:

a bottle for storing a solid hydrogen storage material and hydrogen gas; the bottle body is provided with a groove body along the axial direction of the bottle body, and the groove body is separated from the interior of the bottle body through the shell wall of the bottle body; the tank body comprises an inner layer and an outer layer, a preset gap is reserved between the inner layer and the outer layer to form a first cavity, and a heating medium is filled in the first cavity;

the combination valve, for multi-functional integrated combination valve, set up in on the bottle gas outlet, be connected with the gas outlet of bottle, the combination valve includes: a valve body, a connecting port and an air vent; the connecting port is communicated with the gas outlet of the bottle body and transmits hydrogen into the valve body; the air vent is communicated with the connecting port, receives and transmits hydrogen to the bottle body and transmits the hydrogen to the galvanic pile; the air vent is connected with a sealing joint, penetrates through the protective cover and is exposed out of the protective cover to form a low-pressure air outlet, and the low-pressure air outlet is arranged on one side of the protective cover;

and the identity identification tag is arranged on the protective cover or the bottle body, and the arrangement direction of the identity identification tag is the same as the standard installation and placement direction of the hydrogen storage device.

2. The hydrogen storage device with identity recognition of claim 1, wherein the identity recognition tag is an RFID or a two-dimensional code;

3. The hydrogen storage device with identity recognition of claim 1, wherein the identity recognition tag is fixedly installed inside the protection cover, and the recognition area is exposed outside the protection cover through a hollow or transparent area arranged on the protection cover.

4. The hydrogen storage device with identification as claimed in claim 1, wherein the combination valve further comprises:

5. The hydrogen storage device with identification as claimed in claim 1, wherein the sealing joint comprises: the first joint is connected with the air vent, and the second joint is connected with a gas supply pipeline of the galvanic pile;

6. The hydrogen storage device with identity recognition of claim 1, wherein the bottle body is made of an aluminum alloy inner container, a carbon fiber winding layer and a stainless steel outer shell.

7. The hydrogen storage device with identity recognition of claim 1, wherein the bottle body or the protective cover is provided with a handle, and the handle is a foldable handle.

8. A hydrogen-fueled electric bicycle comprising an electric motor and a stack connected to the electric motor, the stack being connected to the hydrogen storage device of any one of claims 1 to 7.