CN112267074B - High-strength high-toughness bainite non-quenched and tempered steel for high-power engine crankshaft and preparation method thereof - Google Patents
High-strength high-toughness bainite non-quenched and tempered steel for high-power engine crankshaft and preparation method thereof Download PDFInfo
- Publication number
- CN112267074B CN112267074B CN202011086245.2A CN202011086245A CN112267074B CN 112267074 B CN112267074 B CN 112267074B CN 202011086245 A CN202011086245 A CN 202011086245A CN 112267074 B CN112267074 B CN 112267074B
- Authority
- CN
- China
- Prior art keywords
- steel
- less
- strength
- quenched
- equal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000010959 steel Substances 0.000 title claims abstract description 109
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 108
- 229910001563 bainite Inorganic materials 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 24
- 238000005096 rolling process Methods 0.000 claims abstract description 24
- 238000005242 forging Methods 0.000 claims abstract description 22
- 238000001816 cooling Methods 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 16
- 230000006698 induction Effects 0.000 claims abstract description 15
- 238000007670 refining Methods 0.000 claims abstract description 11
- 238000005452 bending Methods 0.000 claims abstract description 10
- 238000009749 continuous casting Methods 0.000 claims abstract description 8
- 230000009467 reduction Effects 0.000 claims abstract description 7
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 7
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 6
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 6
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 6
- 238000009489 vacuum treatment Methods 0.000 claims abstract description 6
- 238000003723 Smelting Methods 0.000 claims abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- 229910052796 boron Inorganic materials 0.000 claims abstract description 5
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 5
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 5
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 5
- 239000000126 substance Substances 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 12
- 238000010583 slow cooling Methods 0.000 claims description 12
- 238000002791 soaking Methods 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- 230000008569 process Effects 0.000 abstract description 9
- 238000010891 electric arc Methods 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 21
- 230000000694 effects Effects 0.000 description 10
- 239000010936 titanium Substances 0.000 description 10
- 230000009466 transformation Effects 0.000 description 10
- 239000011572 manganese Substances 0.000 description 8
- 238000005728 strengthening Methods 0.000 description 8
- 229910000859 α-Fe Inorganic materials 0.000 description 6
- 229910001566 austenite Inorganic materials 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 238000010791 quenching Methods 0.000 description 5
- 230000000171 quenching effect Effects 0.000 description 5
- 230000035882 stress Effects 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005261 decarburization Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000005098 hot rolling Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 229910001562 pearlite Inorganic materials 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241000519995 Stachys sylvatica Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000009661 fatigue test Methods 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/46—Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
- Shafts, Cranks, Connecting Bars, And Related Bearings (AREA)
Abstract
The invention discloses high-strength and high-toughness bainite non-quenched and tempered steel for a high-power engine crankshaft and a preparation method thereof, wherein the high-strength and high-toughness bainite non-quenched and tempered steel comprises the following chemical components in percentage by weight: c: 0.30-0.40%, Si: 0.60 to 1.50%, Mn: 1.40-2.00%, Cr: 0.60-0.90%, Mo: 0.05-0.15%, V: 0.05-0.20%, Ni: 0.10-0.20%, Ti: 0.020-0.030%, B: 0.0010-0.0035%, Al: 0.010-0.060%, P: less than or equal to 0.010 percent, S: 0.025-0.040%, T.O: less than or equal to 10ppm, [ H ]]:≤1.0ppm,[N]: 60-90ppm, X is more than or equal to 200 and less than or equal to 260; the yield strength R of the bainite non-quenched and tempered steel prepared by adopting the process production of electric arc furnace/converter smelting, LF refining, RH vacuum treatment, round billet/square billet continuous casting, rolling, induction heating, forging, finishing and temperature-controlled cooling finished productp0.2Not less than 750MPa, tensile strength Rm: 1100-; elongation after fracture A is more than or equal to 12 percent, reduction of area Z is more than or equal to 40 percent, and normal temperature impact KU2Not less than 35J, and rotary bending fatigue limit sigma‑1≥550MPa。
Description
Technical Field
The invention belongs to the field of non-quenched and tempered steel, and relates to high-strength and high-toughness bainite non-quenched and tempered steel for a high-power engine crankshaft and a preparation method thereof.
Background
The non-quenched and tempered steel is an environment-friendly steel which meets the requirements of high performance and low cost, and the application of the non-quenched and tempered steel to automobile parts is more and more extensive along with the increase of the pressure of environmental protection, energy conservation, cost reduction and the like of automobiles and related supporting industries. The crankshaft is one of core parts of an automobile engine, is a typical die forging in the automobile industry, and the first generation of non-quenched and tempered steel 49MnVS3 for the crankshaft is developed as early as 70 years in the 20 th century by German and Saidisen.
The quality of the crankshaft performance determines the reliability and the service life of the engine to a great extent. The service condition of the engine crankshaft is severe, and the engine crankshaft has both torsional stress and bending stress and is simultaneously acted by torsion and impact bending force, so that the service condition of the crankshaft determines that the crankshaft material has high tensile strength and fatigue strength and also needs to have good toughness. The currently used non-quenched and tempered steel for the crankshaft is ferrite and pearlite type non-quenched and tempered steel, such as F38MnVS, and the mechanical property control range R of the steelp0.2≥550MPa,RmNot less than 850 MPa; elongation A after fracture is more than or equal to 12 percent and fracture surface is contractedShrinkage rate is more than or equal to 25 percent, and normal temperature impact KU2≥25J。
Along with the improvement of the power of an automobile engine, the requirement on steel for the engine crankshaft is higher and higher, and the high-strength and high-wear-resistance performance of the crankshaft during high-speed operation is further improved, and the good toughness is also ensured. The performance of the traditional pearlite and ferrite type non-quenched and tempered steel gradually cannot meet the performance requirements of the steel for the engine crankshaft. Therefore, it is necessary to provide a bainite non-quenched and tempered steel with high toughness and high fatigue performance to meet the material requirement of high-power engine crankshafts.
Disclosure of Invention
In order to solve the technical problems, the invention provides high-strength and high-toughness bainite non-quenched and tempered steel for a high-power engine crankshaft, wherein the bainite non-quenched and tempered steel has high strength and good plasticity and can meet the requirements of the high-power engine crankshaft on strength and toughnessp0.2Not less than 750MPa, tensile strength Rm: 1100-; elongation after fracture A is more than or equal to 12 percent, reduction of area Z is more than or equal to 40 percent, and normal temperature impact KU2Not less than 35J, and rotary bending fatigue limit sigma-1≥550MPa。
The invention also provides a preparation method of the high-strength and high-toughness bainite non-quenched and tempered steel for the high-power engine crankshaft, which adopts the process production of electric arc furnace/converter smelting, LF refining, RH vacuum treatment, round billet/square billet continuous casting, rolling, induction heating, forging, finishing, temperature-controlled cooling and forming, and the high-strength and high-toughness bainite non-quenched and tempered steel for the high-power engine crankshaft with required performance is obtained by controlling and stably producing each process step and process steps.
The technical scheme adopted by the invention is as follows:
a high-strength and high-toughness bainite non-quenched and tempered steel for a high-power engine crankshaft comprises the following chemical components in percentage by weight: c: 0.30-0.40%, Si: 0.60 to 1.50%, Mn: 1.40-2.00%, Cr: 0.60-0.90%, Mo: 0.05-0.15%, V: 0.05-0.20%, Ni: 0.10-0.20%, Ti: 0.020-0.030%, B: 0.0010-0.0035%, Al: 0.010-0.060%, P: less than or equal to 0.010 percent, S: 0.025-0.040%, T.O: less than or equal to 10ppm, [ H ]: 1.0ppm or less, [ N ]: 60-90ppm, X is more than or equal to 200 and less than or equal to 260, and the balance is Fe and inevitable impurity elements; wherein,
x is [25.4(0.003+0.53C) × (1+0.7Si) × (-1.12+5.1Mn) × (1+2.16Cr) × (1+1.74V) × (1+0.364Ni) × (1+3Mo) ], where each element is expressed as the content of the element × 100 in the steel.
Further, the high-strength and high-toughness bainite non-quenched and tempered steel for the high-power engine crankshaft preferably comprises the following chemical components in percentage by weight: c: 0.32-0.38%, Si: 0.63-1.25%, Mn: 1.60-1.90%, Cr: 0.65-0.85%, Mo: 0.08-0.12%, V: 0.07-0.15%, Ni: 0.10-0.18%, Ti: 0.022-0.029%, B: 0.0020 to 0.0030%, Al: 0.020-0.030%, P: less than or equal to 0.010 percent, S: 0.027-0.035%, T.O: less than or equal to 10ppm, [ H ]: 1.0ppm or less, [ N ]: 65-85ppm, 205 is less than or equal to X, 245, and the balance is Fe and inevitable impurity elements.
The invention provides a preparation method of high-strength and high-toughness bainite non-quenched and tempered steel for a high-power engine crankshaft, which comprises the following steps of: smelting, LF refining, RH vacuum treatment, continuous casting, rolling, slow cooling, induction heating, forging, finishing, and temperature control cooling.
Furthermore, in the rolling step, in order to promote the dissolution of sulfides, reduce the component segregation and the like, the heating temperature and the heating time of the billet are properly increased, the soaking temperature of the billet in a heating furnace is controlled to be 1210-1250 ℃, and the total time of preheating, heating and soaking is controlled to be 6.0h-12.0 h; the initial rolling temperature is 1090-1130 ℃, and the final rolling temperature is 900-.
Furthermore, the soaking temperature of the heating furnace is preferably 1235-1250 ℃, and the total time of preheating, heating and soaking is preferably 7.0-8.0 h; the initial rolling temperature is preferably 1100-1125 ℃, and the final rolling temperature is preferably 920-.
Further, the rolling step is followed by a finishing step.
Further, in order to ensure the structure performance and proper hardness reduction of the bainite non-quenched and tempered steel, in the slow cooling step, the steel is cooled to 480-560 ℃ through a cooling bed after rolling, is put into a pit for slow cooling, the slow cooling time is not less than 48h, and is polished and scalped after being taken out of the pit.
Furthermore, after rolling, the steel is cooled to the temperature of 500-525 ℃ by a cooling bed and is put into a pit for slow cooling, and the slow cooling time is 45-50 h.
Further, on the premise of ensuring the grain size of the material, in order to promote the dissolution of sulfide, the improvement of the metal flow property and the uniformity of the overall structure of the crankshaft, in the step of induction heating, the temperature is controlled to 1240-1260 ℃, preferably 1245-1257 ℃ during medium frequency induction heating.
Further, in the forging step, the initial forging temperature is 1150- & lt 1200 & gt, and the final forging temperature is 850- & lt 950 & gt.
Further, the initial forging temperature is preferably 1160-1175 ℃, and the final forging temperature is preferably 910-920 DEG C
Further, in order to ensure the structure and performance of the crankshaft, in the temperature-controlled cooling and forming step, air cooling is performed after the forging is performed to 420-.
In the components of the high-strength high-toughness bainite non-quenched and tempered steel for the high-power engine crankshaft, the functions and the control of all elements are as follows:
c: c is the most effective strengthening element in steel, is the most effective element for influencing strength, hardness and hardenability, in order to ensure sufficient strength, hardness and hardenability of the material, because the surface of the crankshaft needs to be subjected to induction quenching strengthening, in order to ensure the surface hardness after induction quenching, the C content cannot be lower than 0.30 percent, but the C content is too high, which can cause the toughness and plasticity of the steel to be too low, therefore, the C content cannot be higher than 0.40 percent, so the C content is determined to be 0.30-0.40 percent, and is preferably 0.32-0.38 percent.
Si: si is a deoxidizer, has a strong solid solution strengthening effect, improves the hardness and the strength of steel, can inhibit the precipitation of brittle carbides during bainite transformation in the steel during a cooling process, enables certain residual austenite to be reserved in the steel, is beneficial to improving the toughness of the steel, and can improve the elastic modulus of the steel and improve the rigidity of a crankshaft, so that the content of Si cannot be lower than 0.60 percent, but excessive silicon increases the activity of C, promotes the decarburization and graphitization tendency of the steel during rolling and heat treatment, deteriorates the toughness of the steel, and cannot be higher than 1.50 percent. The Si content is controlled between 0.60% and 1.50%, preferably between 0.63% and 1.25%.
Mn: mn is an effective element for deoxidation and desulfurization, the hardness and the strength of steel are improved, the stability of an austenite structure can be improved by Mn, the hardenability of the steel is obviously improved, and meanwhile, bainite transformation can be promoted, and the effect is difficult to achieve when the content is less than 1.40%. However, the Mn content is too high, the plasticity of the steel is reduced, the toughness of the steel is deteriorated during hot rolling, the content of residual austenite after phase transformation is too high, the bainite phase transformation temperature is too low, the yield strength and yield ratio of the steel are too low, the internal stress is too large, and the fatigue performance of the bainite non-quenched and tempered steel is deteriorated. Therefore, the Mn content is controlled to be 1.40-2.00%, preferably 1.60-1.90%.
Cr: cr can effectively improve the hardenability of steel and delay bainite transformation so as to obtain required high strength, and the hardness of bainite ferrite can be obviously improved through solid solution strengthening; meanwhile, Cr can also reduce the activity of C, can reduce the decarburization tendency of the surface of steel in the heating, rolling and forging processes, and is beneficial to obtaining high fatigue resistance. Too high Cr can reduce the toughness of steel, Cr is a strong carbide precipitation element, a large amount of carbide can be generated in the structure of an induction quenching layer, the performance of the induction quenching layer is influenced, and the content of Cr cannot be higher than 0.90%. The Cr content is controlled to be 0.60-0.90%, preferably 0.65-0.85%.
Mo: mo can obviously improve the hardenability of steel and promote bainite transformation. Mo can form strong carbide, block the diffusion of atoms, the movement of dislocation and the migration of grain boundaries, and effectively prevent the recrystallization of deformed austenite. Mo provides the strength of the steel mainly through precipitation strengthening and solid solution strengthening forms of carbides. The carbide particles of Mo are fine and can not cause stress concentration of a microstructure, and the impact toughness of the steel can be improved. But Mo has higher cost and is used as little as possible under the condition of meeting the performance requirement. Therefore, the Mo content is controlled to be 0.05 to 0.15%, preferably 0.08 to 0.12%.
V: v is a strengthening element in steel, both V and C, N have extremely strong affinity, the V exists in the steel in the form of carbide mainly due to precipitation strengthening of VC and V (CN), the V plays a main role in refining structure grains in the steel, the solid-dissolved V can obviously inhibit C diffusion in the bainite phase transformation process due to lower bainite phase transformation temperature, the bainite ferrite can be refined, the strength and toughness of the steel can be improved, and the grain boundary proportion of the refined material is increased due to refining of material grains, so that the strength of the steel is increased, and the sensitivity of the material to cracks is greatly reduced. However, when the V content is high, the cost is high. Therefore, the V content is controlled to be 0.05 to 0.20%, preferably 0.07 to 0.15%.
Ni: ni can effectively improve the core toughness of steel, reduce the ductile-brittle transition temperature and improve the low-temperature impact property, and has the effect of improving the fatigue strength of steel materials, and the Ni has higher cost, and the machinability after hot working can be reduced due to the excessively high Ni content. Therefore, the Ni content is controlled to 0.10 to 0.20%, preferably 0.10 to 0.18%.
Ti: ti and C, O, N have strong affinity, TiN and TiC phases separated out by combining with C, N effectively block the growth of austenite grain size within the hot rolling/forging temperature range and play a role in refining grains, and when V-Ti is added in a compounding way, the refining effect on the structure is better. Meanwhile, the solid-solution Ti can strongly inhibit the diffusion of C in the bainite phase transformation process, can play a role in refining bainite ferrite and M-A islands, and can effectively improve the toughness of the bainite non-quenched and tempered steel. Titanium can also increase the yield point of the material. If the Ti content is too high, TiN point-like inclusions are easy to liquify, the impact toughness and the fatigue life of the material are reduced, and forging cracks are easy to generate during forging. Therefore, the present invention controls the Ti content to 0.020 to 0.030%, preferably 0.022 to 0.029%.
B: b can improve the high-temperature plasticity and hardenability of the steel and promote the transformation of bainite. The effect is not significant when the B content is less than 0.0010%, and the effect is not significantly increased when the B content is more than 0.0035%, which is close to saturation. Therefore, the B content should be controlled to 0.0010 to 0.0035%, preferably 0.0020 to 0.0030%.
Al: al is an effective deoxidizer, and can form AlN refined grains, the effect is not obvious when the Al content is less than 0.010%, coarse inclusions are easily formed when the Al content is more than 0.060%, and the VN content is reduced, so that the performance of the steel is deteriorated. Therefore, the Al content should be controlled to 0.010-0.060%, preferably 0.020-0.030%.
[ N ]: can form compounds with V, B, Ti, Al and the like, refine grains, and N can promote the precipitation of V, reduce the consumption of V and reduce the cost. And too high [ N ] can form continuous casting defects such as bubbles and the like, and is easy to combine with Ti to form liquated TiN inclusions, so that the performance of the steel is reduced. Therefore, the N content should be controlled to 60 to 90ppm, preferably 65 to 85 ppm.
P and S: the sulfur is easy to form MnS inclusion with manganese in the steel, so that the steel generates hot brittleness, but the addition of a small amount of S can obviously improve the cutting performance of the non-quenched and tempered steel while not influencing the performance of products, and the MnS has the effect of refining grains; p is an element with strong segregation tendency, increases the cold brittleness of steel, reduces the plasticity and is harmful to the uniformity of the product structure and performance. Controlling P to be less than or equal to 0.010 percent, and S: 0.025-0.035%, S is preferably 0.027-0.035%.
T.O and [ H ]: forming oxide inclusions in the steel by the T.O, and controlling the T.O to be less than or equal to 10 ppm; [H] white spots are formed in steel, the product performance is seriously influenced, and the [ H ] is controlled to be less than or equal to 1.0 ppm.
X: the X reaction is the control of hardenability in the production process of the steel, C, Si, Mn, Cr, V, Ni and Mo elements have different influences on the properties of the steel such as hardness, plastic toughness and terminal hardenability, and in order to ensure that the steel meets the design requirements, through theoretical calculation and experimental determination, the bainite non-quenched and tempered steel needs to form a bainite structure under the control of a cooling process, so that the hardenability of the bainite non-quenched and tempered steel is ensured to reach a certain value, but the structure stress and the thermal stress generated by the overhigh hardenability during heating and cooling are larger, especially in the induction quenching stage. Therefore, X should be controlled to 200-260, preferably 205 ≦ X ≦ 245.
The invention adopts the specific components and the reasonable preparation method to produce the high strength and toughness bainite non-quenched and tempered steel for the high-power engine crankshaft and the crankshaft blank, the mechanical property inspection is carried out according to GB/T228.1 and GB/T229, and the yield strength R of the high strength and toughness bainite non-quenched and tempered steel isp0.2Not less than 750MPa, tensile strength Rm: 1100-; elongation after fracture A is more than or equal to 12 percent, reduction of area Z is more than or equal to 40 percent, and normal temperature impact KU2Not less than 35J. The rotary bending fatigue test is carried out according to GB/T4337, and the forging can be guaranteedMaterial rotary bending fatigue limit sigma of rear crankshaft-1≥550MPa。
Drawings
FIG. 1 is a metallographic structure diagram of a steel in example 1;
FIG. 2 is a metallographic structure diagram of a steel in example 2;
FIG. 3 is a metallographic structure chart of steel in example 3;
FIG. 4 is a metallographic structure chart of steel in example 4
FIG. 5 is a metallographic structure diagram of steel in comparative example 1;
FIG. 6 is a metallographic structure chart of steel in comparative example 2;
fig. 7 is a metallographic structure diagram of steel in comparative example 3.
Detailed Description
The present invention will be described in detail with reference to examples.
The invention adopts non-quenched and tempered steel with specific components as shown in table 1, produces 4 furnaces of the steel of the invention (examples 1-4) in a co-production way, and adopts the process of electric arc furnace smelting, LF refining, RH vacuum treatment, continuous casting, rolling (finishing) into a material, induction heating, forging, finishing and temperature-controlled cooling to produce, and specifically comprises the following steps: heating the continuous casting billet at 1210-1250 ℃, rolling round steel after the total heating time is more than or equal to 6 hours, wherein the initial rolling temperature is as follows: 1090-1130 ℃ and 900-950 ℃ of final rolling temperature, cooling the rolled round steel to 560 ℃ of 480-550 ℃ of temperature through a cooling bed, inserting the round steel into a pit for slow cooling, wherein the slow cooling time is not less than 48h, the round steel is subjected to intermediate frequency induction heating 1240-1260 ℃, the initial forging temperature 1150-1200, the final forging temperature 850-950 ℃, and air cooling is carried out after the round steel is subjected to air cooling to 450 ℃.
And referring to the production of 1 furnace F38MnVS steel (low sulfur neutral line) required in GB/T15712 as the comparative steel (comparative example 1), and adopting the process of electric arc furnace smelting-LF refining-RH vacuum treatment-continuous casting-rolling (finishing) finished product-induction heating-forging-finishing-temperature control cooling for production, which specifically comprises the following steps: in the RH vacuum treatment step, the vacuum time is 22 min; carrying out round steel rolling on the continuous casting billet after heating and heat preservation at 1200-mangling temperature of 1250 ℃ for more than or equal to 4h, wherein the rolling temperature is as follows: 1100-.
The following is a specific example of the high strength and toughness bainite non-quenched and tempered steel for a high power engine crankshaft of the present invention.
TABLE 1 examples and comparative examples chemical compositions (T.O, [ N ]: ppm, others:%)
TABLE 2X values in the examples and comparative examples
X:25.4(0.003+0.53C)×(1+0.7Si)×(-1.12+5.1Mn)×(1+2.16Cr)×(1+1.74V)×(1+0.364Ni)×(1+3Mo) | |
Example 1 | 207.3 |
Example 2 | 226.3 |
Example 3 | 240.0 |
Example 4 | 221.4 |
Comparative example 1 | 74.8 |
Comparative example 2 | 175.9 |
Comparative example 3 | 274.1 |
TABLE 3 vacuum and Steel Rolling production Process parameters
TABLE 4 forging production Process parameters
Table 4 shows the mechanical properties of the non-heat treated steel crankshafts of examples 1 to 4 of the present invention, which are shown in Table 4, have both high strength and high toughness, and the properties of the non-heat treated steel crankshafts far exceed the performance level of comparative example 1. Comparative example 2 has a lower X value, and the structure has more ferrite, resulting in better ductility and toughness and insufficient strength; on the contrary, comparative example 3 has a high X value, a good strength and insufficient ductility and toughness.
TABLE 5 mechanical Properties of examples of the present invention
Examples | Rp0.2/MPa | Rm/MPa | A/% | Z/% | KU at Normal temperature2/J |
F38MnVS requirement | ≥550 | ≥850 | ≥12 | ≥25 | ≥25 |
Steel requirements of invention | ≥750 | 1100-1160 | ≥12 | ≥40 | ≥35 |
Example 1 | 770 | 1124 | 14 | 46 | 43 |
Example 2 | 788 | 1139 | 13 | 44 | 40 |
Example 3 | 793 | 1151 | 13 | 43 | 37 |
Example 4 | 801 | 1150 | 14 | 47 | 39 |
Comparative example 1 | 595 | 910 | 13 | 42 | 32 |
Comparative example 2 | 757 | 1088 | 17 | 51 | 50 |
Comparative example 3 | 810 | 1170 | 10 | 38 | 31 |
TABLE 5 shows turning angles of examples and comparative examplesFlexural fatigue performance, cycle characteristic R-1, the test was run until specimen break or 107Until now. As can be seen from Table 5, the selected bending fatigue limits of the non-quenched and tempered steel crankshafts in examples 1 to 4 of the invention are all more than or equal to 575MPa, and the fatigue properties exceed the comparative example performance levels.
TABLE 6 rotary bending fatigue Properties of examples of the present invention
Examples | Fatigue limit/MPa |
Example 1 | 554 |
Example 2 | 561 |
Example 3 | 569 |
Example 4 | 575 |
Comparative example 1 | 510 |
Comparative example 2 | 520 |
Comparative example 3 | 559 |
As is clear from tables 1 to 6, the steels of the present invention are formed by alloying componentsThe reasonable production process control is taken into consideration, the high-strength high-toughness bainite non-quenched and tempered steel for the crankshaft of the high-power engine is provided, and after the high-strength high-toughness bainite non-quenched and tempered steel is forged into the crankshaft, the mechanical property of the high-strength high-toughness bainite non-quenched and tempered steel meets the yield strength Rp0.2Not less than 750MPa, tensile strength Rm: 1100-; elongation after fracture A is more than or equal to 12 percent, reduction of area Z is more than or equal to 40 percent, and normal temperature impact KU2Not less than 35J, and rotary bending fatigue limit sigma-1Not less than 550MPa, without greatly increasing the cost, and has great comprehensive advantages of cost, performance and the like in the field of non-quenched and tempered steel for crankshafts.
The above detailed description of a high strength and toughness bainitic non-heat-treated steel for a crankshaft of a high power engine and a method for manufacturing the same with reference to the embodiments is illustrative and not restrictive, and several embodiments may be cited within the limits of the present invention, so that changes and modifications that do not depart from the general concept of the present invention are intended to be within the scope of the present invention.
Claims (7)
1. A high-strength and high-toughness bainite non-quenched and tempered steel for a high-power engine crankshaft is characterized by comprising the following chemical components in percentage by weight: c: 0.32-0.38%, Si: 0.63-1.25%, Mn: 1.60-1.90%, Cr: 0.65-0.85%, Mo: 0.08-0.12%, V: 0.07-0.15%, Ni: 0.10-0.18%, Ti: 0.022-0.029%, B: 0.0020 to 0.0030%, Al: 0.020-0.030%, P: less than or equal to 0.010 percent, S: 0.027-0.035%, T.O: less than or equal to 10ppm, [ H ]: 1.0ppm or less, [ N ]: 65-85ppm, 205 is less than or equal to X, 245, and the balance is Fe and inevitable impurity elements;
wherein, X =25.4(0.003+0.53C) × (1+0.7Si) × (-1.12+5.1Mn) × (1+2.16Cr) × (1+1.74V) × (1+0.364Ni) × (1+3Mo), wherein each element indicates a value = the content of the element in the steel × 100;
the yield strength R of the high-strength high-toughness bainite non-quenched and tempered steel for the high-power engine crankshaftp0.2Not less than 750MPa, tensile strength Rm: 1100-1160MPa, rotation bending fatigue limit sigma-1550MPa or more, elongation A after fracture of 12% or more, reduction of area Z of 40% or more, and normal temperature impact KU2≥35J。
2. The method for preparing the high-strength and high-toughness bainite non-quenched and tempered steel for the crankshaft of the high-power engine according to claim 1, wherein the preparation method comprises the following steps: smelting, LF refining, RH vacuum treatment, continuous casting, rolling, slow cooling, induction heating, forging, finishing, and temperature control cooling.
3. The preparation method according to claim 2, wherein in the rolling step, the soaking temperature of the billet in the heating furnace is controlled to be 1210-1250 ℃, and the total time of preheating, heating and soaking is controlled to be 6.0-12.0 h; the initial rolling temperature is 1090-1130 ℃, and the final rolling temperature is 900-950 ℃.
4. The preparation method as claimed in claim 2, wherein in the slow cooling step, the rolled steel sheet is cooled to 480-560 ℃ by a cooling bed and then is put into a pit for slow cooling, the slow cooling time is not less than 48h, and the steel sheet is polished and scalped after being taken out of the pit.
5. The method as set forth in claim 2, wherein the temperature in the induction heating step is controlled to 1240-1260 ℃ at the time of the medium frequency induction heating.
6. The method as claimed in claim 2, wherein the forging step has a start forging temperature of 1150-.
7. The method as claimed in claim 2, wherein in the step of temperature-controlled cooling, the forged material is air-cooled to 420-450 ℃ and then air-cooled.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011086245.2A CN112267074B (en) | 2020-10-12 | 2020-10-12 | High-strength high-toughness bainite non-quenched and tempered steel for high-power engine crankshaft and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202011086245.2A CN112267074B (en) | 2020-10-12 | 2020-10-12 | High-strength high-toughness bainite non-quenched and tempered steel for high-power engine crankshaft and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN112267074A CN112267074A (en) | 2021-01-26 |
CN112267074B true CN112267074B (en) | 2022-01-25 |
Family
ID=74337842
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202011086245.2A Active CN112267074B (en) | 2020-10-12 | 2020-10-12 | High-strength high-toughness bainite non-quenched and tempered steel for high-power engine crankshaft and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN112267074B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112981237B (en) * | 2021-01-28 | 2022-10-11 | 江阴兴澄特种钢铁有限公司 | Steel for ball cage type universal joint retainer and production method thereof |
CN114921722B (en) * | 2022-05-19 | 2023-06-23 | 中天钢铁集团(南通)有限公司 | Production process for preventing bending degree of medium carbon manganese chromium alloy steel continuous casting billet from exceeding standard |
CN115418590B (en) * | 2022-08-31 | 2023-08-29 | 马鞍山钢铁股份有限公司 | High-strength and high-toughness non-quenched and tempered steel with good corrosion resistance for wind power bolts and production method thereof |
CN115896614A (en) * | 2022-10-31 | 2023-04-04 | 中国第一汽车股份有限公司 | Niobium-containing bainite non-quenched and tempered steel material, steering knuckle and preparation method |
CN118241126B (en) * | 2024-05-29 | 2024-08-06 | 江苏永钢集团有限公司 | Medium-carbon bainite non-quenched and tempered steel for large-scale direct cutting and production process thereof |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5821260B2 (en) * | 2011-04-26 | 2015-11-24 | Jfeスチール株式会社 | High-strength hot-dip galvanized steel sheet excellent in formability and shape freezing property, and method for producing the same |
CN102899589A (en) * | 2012-09-25 | 2013-01-30 | 长城汽车股份有限公司 | High-strength non-tempered bainite steel and preparation method thereof |
CN104532168B (en) * | 2015-01-09 | 2016-06-15 | 江西理工大学 | High-quality Micro Alloying seamless steel tube for drilling and manufacture method thereof |
WO2018215813A1 (en) * | 2017-05-22 | 2018-11-29 | Arcelormittal | Method for producing a steel part and corresponding steel part |
-
2020
- 2020-10-12 CN CN202011086245.2A patent/CN112267074B/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN112267074A (en) | 2021-01-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN112342462B (en) | Nb-Ti microalloyed high-strength high-toughness bainite non-quenched and tempered steel for high-power engine crankshaft and preparation method thereof | |
CN112267074B (en) | High-strength high-toughness bainite non-quenched and tempered steel for high-power engine crankshaft and preparation method thereof | |
CN112195412B (en) | Nb-V microalloyed high-strength high-toughness bainite non-quenched and tempered steel for high-power engine crankshaft and preparation method thereof | |
CN110846580B (en) | high-Mo high-performance Mn-Cr series steel for wind power output gear and production method thereof | |
CN113862558B (en) | Low-cost high-toughness high-strength tempered steel with yield strength of 700MPa and manufacturing method thereof | |
CN111394639B (en) | Manufacturing method of high-wear-resistance gear steel | |
CN105154774A (en) | Free-cutting medium-carbon non-quenching and tempering steel for fracture splitting connecting rod and manufacturing method thereof | |
CN113737087B (en) | Ultrahigh-strength dual-phase steel and manufacturing method thereof | |
CN113862576B (en) | Non-quenched and tempered steel, crankshaft and production method thereof | |
CN113637915B (en) | Nb-Ti-B microalloyed carburized gear steel and preparation method thereof | |
CN112981239A (en) | Quenched and tempered low-carbon alloy steel and manufacturing method thereof | |
JP3562192B2 (en) | Component for induction hardening and method of manufacturing the same | |
JPH0892690A (en) | Carburized parts excellent in fatigue resistance and its production | |
CN109609729B (en) | Stainless steel plate with 650 MPa-grade yield strength and manufacturing method thereof | |
CN113737086A (en) | Economical 780 MPa-grade cold-rolled annealed dual-phase steel and manufacturing method thereof | |
CN112342463B (en) | high-Ti high-strength high-toughness bainite non-quenched and tempered steel for high-power engine crankshaft and preparation method thereof | |
CN111647801A (en) | 690 MPa-grade ferrite-martensite dual-phase steel, and preparation method and application thereof | |
JP3606024B2 (en) | Induction-hardened parts and manufacturing method thereof | |
CN115627423B (en) | 1600 MPa-grade hot rolled coil and production method thereof | |
CN116555680A (en) | Steel for high-strength speed reducer gear of new energy automobile and manufacturing method thereof | |
CN111471938B (en) | Carbide bainite-free steel for electric automobile gear and production method thereof | |
CN111876663B (en) | Alloy structural steel plate for knitted panel and manufacturing method thereof | |
CN115058655A (en) | Non-quenched and tempered steel for Nb microalloying medium-carbon expansion-broken connecting rod, expansion-broken connecting rod produced by using non-quenched and tempered steel and forging-controlled cooling process | |
JP3644217B2 (en) | Induction-hardened parts and manufacturing method thereof | |
CN115537646A (en) | Non-quenched and tempered steel and manufacturing method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant |