CN110144134A - A kind of material for air purification, preparation method and coating - Google Patents
A kind of material for air purification, preparation method and coating Download PDFInfo
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- CN110144134A CN110144134A CN201910488381.5A CN201910488381A CN110144134A CN 110144134 A CN110144134 A CN 110144134A CN 201910488381 A CN201910488381 A CN 201910488381A CN 110144134 A CN110144134 A CN 110144134A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of material for air purification, preparation method and a kind of air purifying paints.The material for air purification includes the raw material of following weight percent: polarity electrical stone 30%-45%, carbon nanotube 5%-15%, molybdenum oxide 5%-12%, acrylic resin 20%-30%, titanium dioxide compound 15%-20%.Material for air purification provided by the invention can remove 80% or more indoor harmful gas under the action of above-mentioned raw materials keep appropriate proportion, and bactericidal properties are strong, and water paint is added in use, will not influence the performance of former coating itself.
Description
Technical field
The present invention relates to environmental improvement field of material technology more particularly to a kind of material for air purification, preparation method and
A kind of air purifying paint.
Background technique
Indoor furniture, ornaments and household chemical product etc. cause different degrees of pollution to indoor environment respectively.Currently,
Scientists have detected 500 gas chromatographies from room air, wherein common indoor pollutant mainly has formaldehyde, benzene, first
Benzene, dimethylbenzene, ammonia and total volatile organic compounds (TVOC).These pollutants directly affect people's lives quality and body
Body health.
In the related technology, the material for air purification in interior wall coating can be added and receive everybody generally favor.So
And about above-mentioned technical proposal, at least there is the following technical problem in inventor's discovery: in for example material for air purification is added
After wall coating, the performance of interior wall coating is changed, so that wall surface coating is easy cracking or adhesiveness is bad；In other are added
Although the material for air purification of wall coating, there is no the performance for changing coating, the effect of absorption indoor pollutant is simultaneously bad.Cause
This, it is necessary to improve one or more problem present in above-mentioned related art scheme.
It should be noted that this section is intended to provide an explanation of the embodiments of the present invention set forth in the claims background or
Context.Description herein recognizes it is the prior art not because not being included in this section.
Summary of the invention
The purpose of the present invention is to provide a kind of material for air purification, preparation method and a kind of air purifying paint, into
And one or more is overcome the problems, such as caused by the limitation and defect due to the relevant technologies at least to a certain extent.
According to a first aspect of the embodiments of the present invention, a kind of material for air purification is provided, including following weight percent
Raw material: polarity electrical stone 30%-45%, carbon nanotube 5%-15%, molybdenum oxide 5%-12%, acrylic resin 20%-30%,
Titanium dioxide compound 15%-20%.
Further, the titanium dioxide compound is the compound of cuprous oxide and titanium dioxide.
Further, the polarity electrical stone include dravite, iron tourmaline, iron dravite, in elbaite
It is at least one.
Further, the particle size range of the powder of the polarity electrical stone is 0.1 μm -5 μm.
According to a second aspect of the embodiments of the present invention, a kind of preparation method of material for air purification, including following step are provided
It is rapid:
Polarity electrical stone and carbon nanotube are smashed and ground respectively, are sieved as 0.1 μm -5 μm of partial size of powder, by molybdenum oxide
It is ground up, sieved the powder for 1 μm -10 μm；
It weighs quantitative cuprous oxide to be added to absolute ethanol, the butyl titanate ethanol solution of preset concentration is added, mix
Uniformly, sufficiently reaction after centrifugation, alcohol wash, be dried in vacuo cuprous oxide and titanium dioxide compound；
The polarity electrical mountain flour body of 30%-45%, the carbon of 5%-15% after weighing sieving by weight percentage respectively are received
The acrylic resin of 20%-30% is added in mitron powder, is uniformly mixed, adds the molybdenum oxide powder and 15%- of 5%-12%
20% cuprous oxide and the compound of titanium dioxide.
Further, the concentration of the butyl titanate ethanol solution is 0.12%.
According to a third aspect of the embodiments of the present invention, a kind of air purifying paint is provided, including described in any of the above embodiments
Material for air purification.
Further, the air purifying paint is aqueous air purifying paint.
The technical solution that the embodiment of the present invention provides can include the following benefits:
In the embodiment of the present invention, material for air purification includes polarity electrical stone, carbon nanotube, molybdenum oxide, acrylic acid tree
Rouge and titanium dioxide compound.Wherein, polarity electrical stone it is capable of releasing negative ion, it is radiation infrared purify air, and carbon
Nanotube can have stronger bactericidal property with adsorbing indoor harmful gases, molybdenum oxide, and acrylic resin not only increases oxidation
The bactericidal property of molybdenum can also reinforce the suitability of entire material for air purification and coating, and the compound of titanium dioxide has better
Except ammonia performance.By the present invention in that above-mentioned raw materials keep proportion appropriate, obtained material for air purification can remove 80% with
On indoor harmful gas, bactericidal properties are strong, and be added water paint in use, will not influence the performance of former coating itself.
Detailed description of the invention
The drawings herein are incorporated into the specification and forms part of this specification, and shows the implementation for meeting the disclosure
Example, and together with specification for explaining the principles of this disclosure.It should be evident that the accompanying drawings in the following description is only the disclosure
Some embodiments for those of ordinary skill in the art without creative efforts, can also basis
These attached drawings obtain other attached drawings.
Fig. 1 shows the preparation method flow chart of material for air purification in disclosure exemplary embodiment.
Specific embodiment
Example embodiment is described more fully with reference to the drawings.However, example embodiment can be with a variety of shapes
Formula is implemented, and is not understood as limited to example set forth herein；On the contrary, thesing embodiments are provided so that the present invention will more
Fully and completely, and by the design of example embodiment comprehensively it is communicated to those skilled in the art.Described feature or
Characteristic can be incorporated in any suitable manner in one or more embodiments.
This example embodiment provides firstly a kind of material for air purification, which may include following heavy
Measure the raw material of percentage: polarity electrical stone 30%-45%, carbon nanotube 5%-15%, molybdenum oxide 5%-12%, acrylic resin
20%-30%, titanium dioxide compound 15%-20%.
In one example, polarity electrical stone may include dravite, iron tourmaline, iron dravite, elbaite
At least one of.Polarity electrical stone is a kind of silicate mineral, its chemical component is mainly silicate, boron, magnesium, aluminium etc.,
And polarity electrical mountain flour physical efficiency continues permanent release anion, for example, by polarity electrical mountain flour breakdown mill to 0.1 μm -5 of partial size
μm powder when, the hydroxyl group anion per cubic centimeter that can release more than 1200, and it is radiation-curable go out wavelength at 2 μm -18 μm
Far infrared in range.Anion and far infrared, which can play the role of purification air, especially anion, to be passed through
Physical absorption, chemical breakdown, the electrically comprehensive functions such as neutralization, have to purify aldehyde, ammonia, benzene etc. that finishing material and furniture release
Evil gas.
Carbon atom has good Bonding property, can not only form structurally consummate diamond and graphite, can also form tool
There are high adsorption, the unformed porous carbon of abundant fault of construction.The aperture system of conventional porous carbon is mainly by its knot abundant
Structure defect is formed, different from the aperture system that zeolite molecular sieve etc. has pore structure to construct completely, and aperture system has certain
Randomness, therefore its pore forming process and final pore structure are difficult to control.And the appearance of carbon nanotube makes the shape in carbon structure
It is possibly realized at completely regular pore structure.Especially single-walled carbon nanotube is made of single layer cylindricality graphite linings, and diameter is big
Small distribution is small, and defect is few, uniformity consistency with higher, with more regular 1-dimention nano grade hole.
Carbon nanotube in the present embodiment material for air purification has good suction to pernicious gases such as aldehyde, ammonia, benzene, TVOC
Attached performance.The study found that the key between sorbate and surface is than between sorbate when carbon nanotube adsorbs organic gas
Key it is strong, while to the desorption temperature of organic gas, desorption activation energy will be higher than conventional activated carbon.
Molybdenum oxide in the present embodiment material for air purification is very stable in air, and can be with the minor amount of water knot in environment
Output hydrogen ion is closed, subacidity superficiality is formed, causes bacterium that can not survive to change environment.It is found by many experiments,
Molybdenum oxide and acrylic resin have good suitability, when the dosage of molybdenum oxide is the 4% of acrylic resin, in 6h
Kill 108Escherichia coli and staphylococcus aureus.
Acrylic resin in the present embodiment not only increases the bactericidal property of molybdenum oxide, and occupies material for air purification
The acrylic resin of 20%-30% also adds amalgamation and suitability between material for air purification and coating, in very great Cheng
Influence of the material for air purification to coating performance itself is reduced on degree, when this material for air purification is added in coating, and is made
When painting metope with the coating, wall surface coating does not allow the phenomenon for occurring cracking or adhesiveness is bad.
In one embodiment, titanium dioxide compound can be the compound of cuprous oxide and titanium dioxide.Titanium dioxide
Titanium itself can serve as a kind of material for air purification, and harmful organic substance in environment and the nitrogen oxygen in atmosphere can be catalytically decomposed in it
Compound and sulfide also have the function of purification, antifouling deodorization etc..But since the catalysis of titanium dioxide reaction is light provocative reaction,
When there is no light, catalysis reaction will not occur.In the prior art, overcome usually using titanium dioxide package metal nano powder
This defect, but the optically catalytic TiO 2 adsorption capacity being prepared is weak, immobilized difficulty, it is big using difficulty in coating.And
Test proves that the compound of cuprous oxide and titanium dioxide in the material for air purification that the disclosure provides, not only has
Higher anti-microbial property, while possessing again preferably except ammonia performance.
In one embodiment, the material for air purification that the disclosure provides can also include a small amount of active carbon or hydroxyl phosphorus
Lime stone is to further strengthen the absorption to pernicious gases such as indoor aldehyde, ammonia, benzene, TVOC.
A kind of preparation method of material for air purification is additionally provided in this example embodiment, as shown in Figure 1, this method can
With the following steps are included:
Step S101: polarity electrical stone and carbon nanotube are smashed and ground respectively, are sieved as 0.1 μm -5 μm of partial size of powder
Molybdenum oxide is ground up, sieved the powder for 1 μm -10 μm by body；
Step S102: weighing quantitative cuprous oxide and be added to absolute ethanol, and the butyl titanate ethyl alcohol of preset concentration is added
Solution, be uniformly mixed, sufficiently reaction after centrifugation, alcohol wash, be dried in vacuo cuprous oxide and titanium dioxide compound；
Step S103: polarity electrical mountain flour body, the 5%- of the 30%-45% after weighing sieving by weight percentage respectively
The acrylic resin of 20%-30% is added in 15% carbon nanotube dust, is uniformly mixed, adds the molybdenum oxide of 5%-12%
The compound of the cuprous oxide and titanium dioxide of powder and 15%-20%.
In step s101, polarity electrical stone can first pass through the impurity of washing, pickling removal surface in advance before smashing and grinding.
The partial size of molybdenum oxide is thinner, and the bactericidal effect reached is better, and industrial molybdenum oxide can be put into Raymond mill and ground, to subtract
The partial size of small molybdenum oxide.
In step s 102, the concentration of butyl titanate ethanol solution is 0.12%.
Embodiment 1
A kind of preparation method of material for air purification, comprising the following steps:
Polarity dravite and polarity elbaite are chosen, after washing, pickling, drying, is put into ball mill pulverizer and carries out
Powder after grinding is sieved by smashing and grinding, and it is spare to choose 0.1 μm -5 μm of partial size of tourmaline powder；Carbon nanotube is put into
It is smashed and ground in ball mill pulverizer, the powder after grinding is sieved, it is standby to choose 0.1 μm -5 μm of partial size of carbon nanotube dust
With；Industrial molybdenum oxide is put into Raymond mill and is ground, it is spare that 1 μm -10 μm of powder progress is chosen after sieving.
It weighs 6.8g cuprous oxide to be added in 100ml dehydrated alcohol, and makes cuprous oxide in dehydrated alcohol with ultrasound
It is uniformly dispersed, the butyl titanate ethanol solution 25ml that concentration is 0.12% is added, be uniformly mixed, sufficiently centrifugation, alcohol after reaction
Wash 4 times, be dried in vacuo cuprous oxide and titanium dioxide compound；
30% polarity electrical mountain flour body, 12% carbon nanotube dust after weighing sieving by weight percentage respectively,
30% acrylic resin is added, is uniformly mixed, adds 12% molybdenum oxide powder and 16% cuprous oxide and titanium dioxide
The compound of titanium, drying are simultaneously dispersed with ultrasonic wave, obtain material for air purification.
Embodiment 2
A kind of preparation method of material for air purification, comprising the following steps:
Polarity dravite and polarity elbaite are chosen, after washing, pickling, drying, is put into ball mill pulverizer and carries out
Powder after grinding is sieved by smashing and grinding, and it is spare to choose 0.1 μm -5 μm of partial size of tourmaline powder；Carbon nanotube is put into
It is smashed and ground in ball mill pulverizer, the powder after grinding is sieved, it is standby to choose 0.1 μm -5 μm of partial size of carbon nanotube dust
With；Industrial molybdenum oxide is put into Raymond mill and is ground, it is spare that 1 μm -10 μm of powder progress is chosen after sieving.
It weighs 6.8g cuprous oxide to be added in 100ml dehydrated alcohol, and makes cuprous oxide in dehydrated alcohol with ultrasound
It is uniformly dispersed, the butyl titanate ethanol solution 25ml that concentration is 0.12% is added, be uniformly mixed, sufficiently centrifugation, alcohol after reaction
Wash 4 times, be dried in vacuo cuprous oxide and titanium dioxide compound；
35% polarity electrical mountain flour body, 15% carbon nanotube dust after weighing sieving by weight percentage respectively,
22% acrylic resin is added, is uniformly mixed, adds 8% molybdenum oxide powder and 20% cuprous oxide and titanium dioxide
Compound, it is dry simultaneously to be dispersed with ultrasonic wave, obtain material for air purification.
Embodiment 3
A kind of preparation method of material for air purification, comprising the following steps:
Polarity dravite and polarity elbaite are chosen, after washing, pickling, drying, is put into ball mill pulverizer and carries out
Powder after grinding is sieved by smashing and grinding, and it is spare to choose 0.1 μm -5 μm of partial size of tourmaline powder；Carbon nanotube is put into
It is smashed and ground in ball mill pulverizer, the powder after grinding is sieved, it is standby to choose 0.1 μm -5 μm of partial size of carbon nanotube dust
With；Industrial molybdenum oxide is put into Raymond mill and is ground, it is spare that 1 μm -10 μm of powder progress is chosen after sieving.
It weighs 6.8g cuprous oxide to be added in 100ml dehydrated alcohol, and makes cuprous oxide in dehydrated alcohol with ultrasound
It is uniformly dispersed, the butyl titanate ethanol solution 25ml that concentration is 0.12% is added, be uniformly mixed, sufficiently centrifugation, alcohol after reaction
Wash 4 times, be dried in vacuo cuprous oxide and titanium dioxide compound；
45% polarity electrical mountain flour body, 10% carbon nanotube dust after weighing sieving by weight percentage respectively,
20% acrylic resin is added, is uniformly mixed, adds 5% molybdenum oxide powder and 20% cuprous oxide and titanium dioxide
Compound, it is dry simultaneously to be dispersed with ultrasonic wave, obtain material for air purification.
Embodiment 4
A kind of preparation method of material for air purification, comprising the following steps:
Polarity dravite and polarity elbaite are chosen, after washing, pickling, drying, is put into ball mill pulverizer and carries out
Powder after grinding is sieved by smashing and grinding, and it is spare to choose 0.1 μm -5 μm of partial size of tourmaline powder；Carbon nanotube is put into
It is smashed and ground in ball mill pulverizer, the powder after grinding is sieved, it is standby to choose 0.1 μm -5 μm of partial size of carbon nanotube dust
With；Industrial molybdenum oxide is put into Raymond mill and is ground, it is spare that 1 μm -10 μm of powder progress is chosen after sieving.
It weighs 6.8g cuprous oxide to be added in 100ml dehydrated alcohol, and makes cuprous oxide in dehydrated alcohol with ultrasound
It is uniformly dispersed, the butyl titanate ethanol solution 25ml that concentration is 0.12% is added, be uniformly mixed, sufficiently centrifugation, alcohol after reaction
Wash 4 times, be dried in vacuo cuprous oxide and titanium dioxide compound；
40% polarity electrical mountain flour body, 5% carbon nanotube dust after weighing sieving by weight percentage respectively, add
Enter 27% acrylic resin, is uniformly mixed, adds 10% molybdenum oxide powder and 18% cuprous oxide and titanium dioxide
Compound, it is dry simultaneously to be dispersed with ultrasonic wave, obtain material for air purification.
Weather will be respectively placed in by 4 resulting four embodiment 1, embodiment 2, embodiment 3, embodiment material for air purification
The test except formaldehyde, benzene, dimethylbenzene, toluene is carried out in cabin:
Keep climate compartment in temperature be (23 ± 0.5) DEG C, relative humidity be (45 ± 3) %, load-carry duty be (1.0 ±
0.02)m2/m3, air displacement rate is (1.0 ± 0.05) h-1, specimen surface air velocity is (0.1~0.3) m/s.
1 piece of wooden boards is taken, exposed area 1m2(two-sided meter length=1000mm ± 2mm, wide=500mm ± 2mm),
It is put into 1m3Climate compartment, climate compartment runs and measures formaldehyde, benzene,toluene,xylene concentration as soiling value in 24 hours；Again should
Plate takes out, and coats the material for air purification in above-described embodiment in exposure (two-sided and four sides), it is small to expose 24 in air
When, it is 1m that the plate, which is then put into volume,3Climate compartment, climate compartment run 24 hours, measure formaldehyde, benzene,toluene,xylene
Concentration is as purification value.Shown in specifically the experimental data are shown in the following table:
Temperature will be respectively placed in by 4 resulting four embodiment 1, embodiment 2, embodiment 3, embodiment material for air purification
Be 22 DEG C, humidity 60%RH, atmospheric pressure be 102850Pa environment in, and using ITC-201A type airion concentration detect
Instrument carries out the test of negative ion concentration, through bearing of test that four material for air purification obtained in above-described embodiment are discharged from
Sub- concentration is all larger than equal to 1200/cubic centimetre.
According to GB 6566-2010 " radioactive material radionuclides limitation " standard, naturally put in A class decorating and renovating material
Penetrating property nucleic radium-226, thorium -232, kalium-40 specific radioactivity and meanwhile meet Ira≤ 1.0 and Ir≤1.3。
To be in temperature respectively by 4 resulting four embodiment 1, embodiment 2, embodiment 3, embodiment material for air purification
20 DEG C, under conditions of humidity is 60%RH, radioactive nucleus is carried out using the full-automatic radioactivity detector for building materials of FYFS-2002E type
The detection of element.Shown in specifically the experimental data are shown in the following table:
| External Exposure Index Ira | Outreach services Ir | |
| Embodiment 1 | 0.30 | 0.81 |
| Embodiment 2 | 0.35 | 0.96 |
| Embodiment 3 | 0.31 | 0.84 |
| Embodiment 4 | 0.42 | 0.88 |
It can be seen that from upper table, the radionuclide index of four resulting material for air purification of specific embodiment of the application is complete
Portion reaches the standard of national standard A class decorating and renovating material, and also complies with Hangzhou radioactive material radionuclides limitation standard.
This example embodiment additionally provides a kind of air purifying paint, including the air cleaning in any of the above-described embodiment
Material.In one example, which is aqueous air purifying paint, for example, above-mentioned material for air purification is added
Enter aqueous latex paint, white cement, in powder of lacquer putty for use on etc..
Specifically, the material for air purification in any of the above-described embodiment can be added in the ingredient before water paint slurrying,
Have no need to change the technique and formula of former coating, wherein the amount of the material for air purification of addition is water paint ingredients by weight
1.6%.
Material for air purification made from embodiment 1, embodiment 2, embodiment 3, embodiment 4 is separately added into aqueous latex paint
In, following table is the experimental data of specific coating properties:
| Removing and harmful gas rate | Bactericidal properties | Amalgamation | |
| 1 coating of embodiment | 80% | 59% | 93% |
| 2 coating of embodiment | 88% | 65% | 90% |
| 3 coating of embodiment | 84% | 60% | 90% |
| 4 coating of embodiment | 81% | 61% | 91% |
It can be seen that from above data, the air cleaning that the material for air purification that the disclosure provides is formed after being added in coating
Coating, i.e., performance and the former coating amalgamation for not influencing former coating itself are good, and can remove 80% or more indoor harmful gas,
Bactericidal properties are also strong.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show
The description of example " or " some examples " etc. means that specific features, material or feature described in conjunction with this embodiment or example include
In at least one embodiment of the present invention or example.In the present specification, schematic expression of the above terms need not be directed to
Be identical embodiment or example.Moreover, particular features, structures, materials, or characteristics described can be at any one
Or it can be combined in any suitable manner in multiple embodiment or examples.In addition, those skilled in the art can will retouch in this specification
The different embodiments or examples stated are engaged and are combined.
Those skilled in the art after considering the specification and implementing the invention disclosed here, will readily occur to of the invention its
Its embodiment.This application is intended to cover any variations, uses, or adaptations of the invention, these modifications, purposes or
Person's adaptive change follows general principle of the invention and including the undocumented common knowledge in the art of the present invention
Or conventional techniques.The description and examples are only to be considered as illustrative, and true scope and spirit of the invention are by appended
Claim is pointed out.
Claims (8)
1. a kind of material for air purification, which is characterized in that the raw material including following weight percent: polarity electrical stone 30%-
45%, carbon nanotube 5%-15%, molybdenum oxide 5%-12%, acrylic resin 20%-30%, titanium dioxide compound 15%-
20%.
2. material for air purification according to claim 1, which is characterized in that the titanium dioxide compound be cuprous oxide and
The compound of titanium dioxide.
3. material for air purification according to claim 2, which is characterized in that the polarity electrical stone includes dravite, iron
At least one of tourmaline, iron dravite, elbaite.
4. material for air purification according to claim 3, which is characterized in that the particle size range of the powder of the polarity electrical stone
It is 0.1 μm -5 μm.
5. a kind of preparation method of material for air purification, which comprises the following steps:
Polarity electrical stone and carbon nanotube are smashed and ground respectively, are sieved as 0.1 μm -5 μm of partial size of powder, molybdenum oxide is ground
Mill, the powder that sieving is 1 μm -10 μm；
It weighs quantitative cuprous oxide to be added to absolute ethanol, the butyl titanate ethanol solution of preset concentration is added, be uniformly mixed,
Sufficiently reaction after centrifugation, alcohol wash, be dried in vacuo cuprous oxide and titanium dioxide compound；
Weigh the polarity electrical mountain flour body of the 30%-45% after being sieved, the carbon nanotube of 5%-15% by weight percentage respectively
The acrylic resin of 20%-30% is added in powder, is uniformly mixed, adds the molybdenum oxide powder and 15%-20% of 5%-12%
Cuprous oxide and titanium dioxide compound.
6. the preparation method of material for air purification according to claim 5, which is characterized in that the butyl titanate ethyl alcohol is molten
The concentration of liquid is 0.12%.
7. a kind of air purifying paint, which is characterized in that including the described in any item material for air purification of claim 1-4.
8. air purifying paint according to claim 7, which is characterized in that the air purifying paint is aqueous air cleaning
Coating.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110922211A (en) * | 2019-12-19 | 2020-03-27 | 亚细亚建筑材料股份有限公司 | Negative ion ceramic tile and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101480499A (en) * | 2008-12-25 | 2009-07-15 | 杭州轩爱科技有限公司 | Air purification material and preparation method thereof |
| CN109603522A (en) * | 2018-12-24 | 2019-04-12 | 河南普绿环保科技有限公司 | A kind of efficient air purification material |
-
2019
- 2019-06-05 CN CN201910488381.5A patent/CN110144134A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101480499A (en) * | 2008-12-25 | 2009-07-15 | 杭州轩爱科技有限公司 | Air purification material and preparation method thereof |
| CN109603522A (en) * | 2018-12-24 | 2019-04-12 | 河南普绿环保科技有限公司 | A kind of efficient air purification material |
Non-Patent Citations (1)
| Title |
|---|
| 郑康: "Cu2O/TiO2的制备及其在家纺领域的多功能应用研究", 《中国优秀硕士学位论文全文数据库（电子期刊）工程科技Ⅰ辑》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110922211A (en) * | 2019-12-19 | 2020-03-27 | 亚细亚建筑材料股份有限公司 | Negative ion ceramic tile and preparation method thereof |
| CN110922211B (en) * | 2019-12-19 | 2022-04-01 | 亚细亚建筑材料股份有限公司 | Negative ion ceramic tile and preparation method thereof |
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