CN116547420A

CN116547420A - Nonwoven fabric comprising filament layering

Info

Publication number: CN116547420A
Application number: CN202180074332.2A
Authority: CN
Inventors: 迈克尔·考施克; 兹德涅克·迈克欧; 尼科尔·波拉斯科娃; 帕特里克·波尔; 克莉丝汀·诺克; 托比亚斯·瓦格纳
Original assignee: Finn Geek Ltd; Machine Factory Of Leffinhauser Co ltd; PFNonwovens Holding sro; PFNonwovens Czech sro
Current assignee: Finn Geek Ltd; Machine Factory Of Leffinhauser Co ltd; PFNonwovens Holding sro; PFNonwovens Czech sro
Priority date: 2020-11-02
Filing date: 2021-10-29
Publication date: 2023-08-04
Also published as: AR125105A1; US20230392310A1; IL302500A; JP2023547228A; CZ2020591A3; EP4237612A1; KR20230108283A; WO2022089676A1; MX2023004982A; ZA202305080B

Abstract

A nonwoven fabric comprising a plurality of filament layers, wherein the fabric comprises: -a first layer (a) forming the outer surface of the nonwoven fabric and comprising continuous multicomponent filaments comprising a component forming at least 20% of the surface of the filaments and bonded within the first layer (a) and having a melting point at least 5 ℃ lower than the melting point of the other components of the filaments of the first layer (a); and-a second layer (B) comprising continuous multicomponent filaments comprising components forming at least 20% of the surface of the filaments and bonded within the second layer (B) and having a melting point at least 5 ℃ lower than the melting point of the other components of the filaments of the second layer (B), -wherein the bulk density of the fabricBelow 60kg/m ³ 。

Description

Nonwoven fabric comprising filament layering

Technical Field

The present invention relates to nonwoven fabrics comprising filament layering.

Background

Nonwoven fabrics for use in various fields must meet various requirements based on the field of their intended use. Key properties in the areas of disposable hygiene articles, disposable cleaning articles, medical applications, etc., for example, include softness, high bulk and good recovery.

Carded materials are and have been used in many such applications. However, the production of nonwoven fabrics from carded fibers is complex and fiber bonding within such nonwovens results in significantly reduced bulk and softness, or insufficient bonding of the fibers and poor nonwoven mass, i.e., poor abrasion resistance.

Air through bonded spunlaid technology is a viable solution to the industry requirements, primarily because the longer the length of the fibers, the more drawbacks of carded materials are overcome. Different methods are known in the industry.

For example, the desired bulk and softness may be achieved as disclosed in patent application WO2018059610, which describes the use of coiled filaments with a so-called crimpable cross section (e.g. eccentric core/sheath), or as disclosed in patent application WO2020103964 of PF nonwovens (pfnox), which describes the use of filaments with a non-crimpable cross section (e.g. concentric core-sheath).

Nonwoven materials having good abrasion resistance as indicated by the martindale abrasion test are described for example in WO 2020112705.

WO2020107421 discloses a through-air bonding method for nonwoven fabrics, the purpose of which is to produce soft and bulky fabrics. A web of continuous fibers is directed between a porous rotating member and a porous belt, while heated air flows through the web first from one side and then from the other side. However, the description of this method is very ambiguous and does not provide any data about the resulting product.

Ideal fabrics for use in industry are nonwovens that meet both requirements, namely, provide softness-bulk (good compressible, drapable, bendable, non-rigid, pleasant feel, etc.) and 3D stability (abrasion resistance, fuzzing resistance, etc.). Clearly, softness and 3D stability are not simple values that can be easily measured, quantified and compared, but rather exhibit complex characteristics that cover various fabric characteristics and, in fact, also cover various fabrics under this term. It has been found that a number of patents or applications claim fabrics having softness, bulk (high caliper while low basis weight) and some durability. One skilled in the art will readily recognize that many of these patents or applications understand very different things under the term "soft" or "durable". For example, application WO2020103964, supra, describes softness as "softness-bulk" and defines fabric softness based on particular coefficients. In contrast, WO2020112705 described above defines softness based on the compression resilience test. Even though both fabrics are defined as soft, their behaviour and end user feel can be significantly different and it is not easy to compare them to each other.

The object of the present invention is to provide a nonwoven fabric which is soft and bulky and which does not fluff when used.

Disclosure of Invention

This object is achieved by a nonwoven fabric comprising a plurality of filament layers as defined in claim 1, wherein the fabric comprises

-a first layer (a) forming a first outer surface of the nonwoven fabric and comprising continuous multicomponent filaments comprising components that

Along the longitudinal extension of the filaments,

forming at least 20% of the surface of the filaments,

-forming filament-to-filament bonds within the first layer (a), and

-having a melting point at least 5 ℃ lower than the melting point of the other components of the filaments of the first layer (a), and

-a second layer (B) comprising continuous multicomponent filaments comprising components that

Along the longitudinal extension of the filaments,

forming at least 20% of the surface of the filaments,

-forming filament-to-filament bonds in the second ply (B), and

-having a melting point at least 5 ℃ lower than the melting point of the other components of the filaments of the second layer (B), and

-wherein the bulk of the fabric is lowAt 60kg/m ³ 。

Other embodiments of the invention are defined in the dependent claims.

Definition of the definition

The term "filaments" is defined herein as essentially endless filaments, while the term "staple fibers" relates to fibers cut to a defined length. The terms "fiber" and "filament" are used herein to impart the same meaning. In the case of staple fibers, the term "staple fibers" is used exclusively.

The term "inter-filament bonding" refers to all possible interactions between individual filaments or individual portions of filaments, i.e., bonded, partially bonded or unbonded contacts, crossovers, interconnections, parallel contacts, etc. Filament-to-filament bonding may form filament-to-filament bonding, but there may also be two independent filaments in contact with each other without any restriction on their mutual movement.

The term "bond between filaments" or "bond point" refers to a bond that typically connects two filaments at the location where the filaments intersect each other or where they contact or where they abut each other. More than two filaments or two parts of the same filament can be connected by means of a bonding point/consolidation bond. Thus, the term "bond point" herein means the interconnection of two or more fibers/filaments at a point of contact by their components exhibiting lower melting points. At the bond point, the forming composition of the filaments having the higher melting point is generally less affected than the forming composition of the filaments having the lower melting point, i.e., the sheath melts slightly while the core remains substantially unchanged. In contrast, the term "bond impression" refers to the surface on which the boss of the calender roll acts. The bond impressions have defined areas given by the dimensions of the bosses on the bond roll and generally have a smaller thickness than the adjacent areas. During bonding, the region of the bond impression is typically subjected to significant mechanical pressure, which, together with temperature, can affect the shape of all filament components within the region of the bond impression.

The term "monocomponent filament" or "monocomponent fiber" refers to a filament formed from a polymer or a polymer blend, where it is different from a bicomponent filament or multicomponent filament.

The term "multicomponent fiber" or "multicomponent filament" means a fiber or filament whose cross-section comprises more than one individual partial component, and each of these individual components in the cross-section consists of a different polymeric compound or a blend of different polymeric compounds. Thus, the term "multicomponent fiber/multicomponent filament" is a generic term that includes, but is not limited to, "bicomponent fiber/bicomponent filament". The different components of the multicomponent filaments are arranged substantially in well-defined regions arranged along the cross-section of the filaments and extend continuously outwardly along the length of the filaments. The multicomponent filaments may have a cross-section divided into several partial cross-sections consisting of various components of any shape or arrangement, including for example the partial components of the cross-section arranged coaxially, any mutual arrangement of the partial components of the cross-section in the form of a core and a sheath, radial or so-called islands-in-the-sea, etc.

The terms "bicomponent" and "biconstituent" as used to describe filaments are used interchangeably herein.

The design of the multicomponent filaments has a decisive influence on the crimping properties of these filaments. One good way to identify the design of a multicomponent filament is to observe and evaluate its cross-section, which makes the location of the different components of the filament visible. In most cases, the different components are made of different polymer formulations, which are selected and characterized by different melting temperatures and/or different shrinkage properties, for example after spinning, quenching, drawing and final fiber solidification. In general, rotationally symmetric locations of the filament components in their cross-sections (e.g., concentric cores/sheaths) will result in non-crimped filaments, while asymmetric locations of the filament components (e.g., side-by-side or eccentric cores/sheaths) will become different, potential crimping forces to achieve self-crimping and/or thermally activated crimped filaments. For simplicity of language in this application, we use the terms "crimpable cross section" and "non-crimpable cross section" instead of "filaments showing cross sections supporting crimps" and "filaments showing cross sections not supporting crimps". The term "crimpable cross-section" herein refers to multicomponent fibers in which components having different shrinkage properties are arranged on the cross-section such that the filaments will self-crimp during filament drawing and curing, or when heated to or above an activation temperature and then slowly cooled, the fibers crimp, which causes the fibers to follow the vector of shrinkage forces. Thus, when the fibers are released, it produces a so-called spiral crimp, although when contained in the fiber layers, the mutual adhesion of the fibers does not allow the desired spiral to be produced. For multicomponent fibers, we can determine the centroid of each individual component in the fiber cross-section (taking into account their area/position in the cross-section). Without being bound by theory, it is believed that the fibers are "uncrimped" when the center of gravity of all regions of each component are at substantially the same point as the concentric core/sheath, which is described as rotationally symmetric. For example, for round bicomponent fibers having a symmetrical or central core/sheath cross-sectional configuration, the centroid is located at the center of the cross-section (see fig. 1).

The measure "filament diameter" is expressed in μm. The term "grams per 9000m filament" (also denier or denier)) or "grams per 10000m filament" (dTex) is used to denote the fineness or coarseness of the filaments, as they relate to the filament diameter (assuming a circular filament cross section) multiplied by the density of the material or materials used.

"machine direction" (MD) -with respect to the manufacture of nonwoven fibrous materials and the actual nonwoven fibrous materials themselves, the term "machine direction" (MD) refers to a direction that corresponds substantially to the forward direction of movement of the nonwoven fibrous material on the manufacturing line from which the material is manufactured.

"cross-direction" (CD) -with respect to the manufacture of the nonwoven fibrous material and the actual nonwoven fibrous material itself, the term "cross-direction" (CD) refers to a direction that is substantially transverse to the forward direction of movement of the nonwoven fibrous material while lying in the plane of the nonwoven fibrous material on the manufacturing line from which the material is manufactured.

"z-direction" -related to the manufacture of nonwoven fibrous materials is the perpendicular direction to the plane MD x CD. The extension in the z-direction describes the thickness of the nonwoven.

"nonwoven" or"nonwoven fabric" is a tape or fibrous formation produced from oriented or randomly oriented filaments that are first formed during the creation of a layer of filaments, then consolidated together by friction or induced cohesion or adhesion, and finally consolidated by creating mutual bonds, with the consolidation being accomplished by heat (e.g., by the action of flowing air, calendaring, ultrasonic effects, etc.), chemical (e.g., using a binder), mechanical (e.g., hydroentanglement, etc.), or alternatively by a combination of these methods. The term does not refer to fabrics formed by weaving or knitting or fabrics using yarns or fibers to form a cohesive stitch. The fibers may be of natural or synthetic origin and may be staple yarns, continuous fibers or fibers made directly at the processing location. Commercially available fibers range in diameter from less than about 0.001mm to greater than about 0.2mm and are provided in various forms: staple fibers (called staple fibers or cut fibers), continuous filaments (filaments or monofilament fibers), untwisted bundles of filaments (combed fibers), and twisted bundles of filaments (yarns). Nonwoven fabrics can be manufactured using a number of processes including techniques such as melt blowing, spunbonding, spunmelting, spinning using solvents, electrospinning, carding, film fibrillation, air-laying, dry-laying, wet-laying with staple fibers, and various combinations of these processes as known in the art. The basis weight of nonwoven fabrics is typically measured in grams per square meter (g/m ² Or gsm).

A "spunbond" or "spunlaid" process is a nonwoven fabric manufacturing process that involves converting a polymer directly into filaments and then directly depositing the filaments so produced, thereby producing a nonwoven filament layer containing randomly arranged filaments. The nonwoven layer of filaments is then consolidated in such a way as to encase the nonwoven fabric by creating bonds between the filaments. The consolidation process may be performed using various methods, such as by the action of passing through air, calendaring, or the like.

The term "batt" refers to materials found in the form of filaments in a state prior to bonding, which is a process that may be carried out in various ways, such as through-air bonding, calendaring, and the like. "batts" are composed of individual filaments that have not generally formed a fixed mutual bond between them, even though the filaments may be pre-bonded/pre-consolidated in some manner, where such pre-consolidation may occur during or shortly after laying of the filaments during the spunlaying process. However, such pre-consolidation still allows for considerable filaments to be freely movable so that they can be repositioned. The "batts" described above may be composed of several layers formed by depositing filaments from several spinnerets in a spunlacing process.

The term "layer" as used herein relates to a portion of a component or element of a fabric. The "layer" may be in the form of a plurality of filaments produced on a single manifold or on two or more manifolds arranged in series, which produce substantially identical filaments. For example, two consecutively arranged spinbars for performing a spunbond process have substantially the same setup, and processing polymers having substantially the same composition may be combined to produce a monolayer. Conversely, two spunbond spinners, one of which produces, for example, monocomponent filaments and the other of which produces, for example, bicomponent filaments, will form two different layers. The composition of the layer may be determined based on knowledge of the individual settings and components that determine the composition of the resin (polymer) used to produce the layer, or by analysis of the nonwoven fabric itself, for example by using an electron microscope, or by analysis of the composition of filaments used to make the layer using DSC or NMR methods. Adjacent filament layers do not necessarily have to be strictly separated, and layers in the boundary region may mix together due to filaments of the rear deposited layer falling into gaps between filaments of the front deposited layer. The layers in the nonwoven fabric may form a typical structure (e.g., SMS), independent of the layered structure. A layer may contain one, two or even more layers.

The term "layering" as used herein refers to a region of filaments extending substantially in the plane of the MD and CD directions of the nonwoven fabric and having a thickness achieved in the z-direction of the fabric and having a substantially uniform filament density (i.e., mass of filaments per volume). The density of layered filaments within a nonwoven fabric cannot be accurately measured, however, this can be assessed when viewed in cross-section of the nonwoven fabric. Delamination may also be characterized by a substantially uniform density of filament-to-filament bonds and/or a substantially uniform content of stronger and weaker filament-to-filament bonds (although there may be a slight gradient of these values from the outer surface of the outer layer toward the middle region). It should be understood that the layering of filaments within a nonwoven fabric is likewise never completely uniform; because the filaments of the nonwoven are randomly arranged and oriented, filaments from one layer may enter another layer, and further, certain regions of the layer may locally protrude or extend out of the plane in which most of the layers lie, portions of the filaments of the layer may reach into adjacent layers, or beyond the surface of the nonwoven. The layered structure may be observed by analyzing the nonwoven fabric itself, for example by using an electron microscope (in particular from a cross-sectional view), or by for example tomography or micro CT measurements.

The term "compressibility" herein relates to the distance in millimeters that a nonwoven fabric is compressed by the action of a load defined during an "elastic" measurement.

The term "restorability" herein refers to the ability of a fabric to recover its original shape after being compressed. This relates mainly to the ability to regenerate (recover) the bulk based on the ratio between the thickness of the fabric after release of the applied load and the initial thickness of the fabric.

The term "draw ratio" or "stretch ratio" herein refers to a value calculated by dividing the capillary cross-sectional area by the filament cross-sectional area. Filament cross-sectional area was calculated using fiber fineness based on its apparent diameter measurement. Other non-circular cross sections cannot be calculated in this way, so in this case SEM images showing the actual cross sections need to be analysed.

Drawings

Preferred embodiments of the present invention will be described in more detail below with reference to the drawings, photographs and 3D models, wherein is shown

Figure 1 is an example of a crimpable cross-section,

figure 2 is an SEM microscope of a cross-section of an embodiment of the invention,

figure 3 is a schematic diagram of a cross-section of an embodiment of the present invention,

figure 4 is a schematic representation of a cross section of another embodiment of the invention,

Figure 5A is a schematic plan view of bonding between filaments of the unbonded type,

figure 5B is a schematic cross-section of the inter-filament bonding of figure 5A,

figure 6A is a schematic plan view of the bonding between filaments of the weakly bonded type,

figure 6B is a schematic cross-section of the inter-filament bonding of figure 6A,

figure 7A is a schematic plan view of the bonding between filaments of the fully bonded type,

figure 7B is a schematic cross-section of the inter-filament bonding of figure 7A,

figure 8A is a schematic plan view of the inter-filament bonding of the trunk bond type,

figure 8B is a schematic cross-section of the inter-filament bonding of figure 8A,

figure 9 is a photograph of a cross section of an embodiment of the present invention when immobilized in a resin,

figure 10 is an SEM microscope of a cross-section of an embodiment of the invention,

figure 11 is a schematic cross-sectional view of a fabric having a very low filament-to-filament bond density level and a relatively large void volume,

figure 12 is a schematic cross-sectional view of a fabric having a uniform low filament-to-filament bond density,

figure 13 is a schematic cross-sectional view of a uniform higher filament-to-filament inter-bond density level fabric having a relatively small void volume,

figure 14 is a schematic cross-sectional view of a fabric having a very high level of filament-to-filament inter-bonding density and a small void volume,

Fig. 15-19 show SEM microscopy of nonwoven fabrics according to the present invention after delamination, where cracked bonded scars are visible,

figure 20A shows SEM microscopy of a cross-section of an embodiment of the invention containing non-crimped filaments,

figure 20B shows SEM microscopy of a cross-section of an embodiment of the invention comprising non-crimped filaments,

figure 21 is a schematic diagram of a cross section of yet another embodiment of the invention,

figure 22 is an SEM microscope of a cross-section of an embodiment of the invention,

figure 23 is a schematic view of a production line for producing the nonwoven fabric of the present invention,

figure 24 is an SEM microscope of the cross-section of example 1,

figure 25 is an SEM microscope of the cross-section of example 2,

figure 26 is a photograph of a cross section of example 2 immobilized in a resin,

figure 27 is a 3D model of the X-ray tomography of example 1,

figure 28 is a digital cut of the 3D model of figure 27,

figure 29 SEM microscopy of a cross-section of example 3,

figure 30 SEM microscopy of the cross-section of example 4,

figure 31 SEM microscopy of the cross-section of example 5,

figure 32 SEM microscopy of a cross-section of example 6,

figure 33 SEM microscopy of a cross-section of example 7,

figure 34 SEM microscopy of a cross-section of example 8,

Figure 35 SEM microscopy of a cross-section of example 9,

figure 37 SEM microscopy of a cross-section of example 11,

figure 38 is a perspective view of an apparatus for martindale average wear rating test,

figure 39 is a rating scale for fuzzing assessment in a martindale average wear rating test,

figures 40 and 41 are schematic diagrams of delamination tests,

figures 42A and 42B are photographs of a sample holder for SEM microscopy,

figures 43A to 43C are photographs of a holder for 3D tomography,

fig. 44-46 are 3D models of micro CT analysis of samples according to the present invention.

Detailed description of the preferred embodiments

Spunbond and/or spunmelt nonwoven fabrics are well known in the industry. Endless filaments manufactured using a manifold are laid down on a production belt to form batts, which are then pre-consolidated and bonded together to form a fabric. The bonding step may be selected from several known options, such as:

mechanical entanglement, for example by needles or water jets;

chemical bonding using binders or other additives added for bonding purposes;

thermal bonding by exposing the batt to heat to create bond points by melting and curing at least a portion of the polymer composition. For example, heat may be provided by a pair of calender rolls, by radiant heat, or by a hot fluid passing through the batt.

Each of the listed methods with particular advantages and disadvantages also imparts a typical appearance and performance to the corresponding fabric, which can be controlled using process settings within a given range. The list of examples provided above is for illustrative purposes only, and those skilled in the art will appreciate that other bonding methods or various combinations thereof may be used to achieve the desired properties of the fabric.

Fabrics consolidated by hot fluid streams are known in the industry, in particular carding techniques using staple fibers are known for producing soft thermally bonded fabrics. The main advantage of thermal fluid bonding is that the bonding is performed over the entire fabric, where each individual fiber-to-fiber intersection can form a bond. The bonds are small and form between two or more fibers that are in contact with each other. The staple fiber technology can take advantage of the following: the fibers are mixed together into a uniform fiber blend and the amount of fibers containing a polymer with a lower melting temperature (binder polymer) is precisely controlled. For example, when very soft and lofty fabrics are desired, only a small amount of fibers with binding polymer may be present in the fiber premix, and vice versa.

In contrast, spunmelt nonwoven fabrics are typically produced from one type of filament and the amount of binding polymer can be controlled only by the content of binding polymer in each fiber (polymer ratio in bicomponent filaments). The melt spinning line may contain multiple spinning beams and, by a combination of the various ratios from each beam, layered fabrics with different binder polymers may be produced. Layers with different binding polymer ratios can provide different properties and fabrics can use synergy between layers that are highly and moderately bound. Using the proportion of binding polymer in the filament composition as an example herein, further technical features may be combined together, such as described in application EP 19189238.9 (not yet published) to reihenhauser, beginning in 2018, where a fabric of at least two layers is described, one layer providing high abrasion resistance and the other layer providing softness and bulk.

The above solution provides a fabric with a combination of desired properties, but it conceals a drawback from the point of view of the process for the fabric producer. When the first layer forms a thinner skin on the second layer only, optimal wear resistance and softness (in the sense of flexibility or drapability) are obtained, which means that the first layer presents a lower basis weight, so that a double-tank production line cannot achieve its optimal throughput with the first tank.

Our inventive solution provides a spunmelt wherein the "skin" on the "soft-loft" portion can be formed by a set thermal fluid flow bonding process, wherein the thickness of the "skin" can be controlled according to the desired final properties of the fabric.

Fabrics according to the present invention may be made from batts comprising multicomponent filaments that include a binding polymer having a lower melting temperature on at least a portion of their surfaces. The batts on the moving belt are exposed to a heat treatment. Heat may be transferred to the batt by a hot fluid, such as hot air. Typically, heat may be transferred into the batt at various stages of the production process, for example, directly after laying the filaments on a belt to pre-cure the structure, during a heat activation process, during a bonding process, and the like.

The hot fluid penetrates the surface of the filament batt, flows around the filaments, and a portion of the heat carried by the hot fluid is transferred to the cooler filaments. When some heat is transferred to the filaments on the surface of the batt, the temperature of the hot fluid decreases slightly as does the temperature difference between the filaments and the hot fluid. Those skilled in the art will recognize that as the filaments at the surface acquire such heat, the temperature of the filaments increases while the temperature differential between the hot fluid and the filaments decreases. With sufficient time and heat, all filaments within the fabric may be heated to a uniform temperature and the fiber-to-fiber bonding may be uniform throughout the fabric thickness. Thus, the fabric can be uniformly, completely or well bonded.

It has surprisingly been found that a fabric having a non-uniform bond point density throughout its thickness can provide additional advantages. The fabric according to the invention comprises regions with greater inter-filament bonding (more filaments are in contact with each other, for example, so that more filament-to-filament bonding can be formed and/or stronger bonding can be formed) and regions with less inter-filament bonding when viewed in the cross-sectional area; where bonding is defined as all possible interactions between individual filaments, i.e., bonded, partially bonded or unbonded contacts, crossovers, interconnections, parallel contacts, etc. (defined in more detail below). For one type of filament (based on fiber surface characteristics), this distinction in area is related to the filament density (number of filaments in a given area) of the one type of filament. Areas of higher bonding are typically formed on the outer surfaces of the filament batts where the hot fluid enters the fabric. Areas with higher or lower filament densities (delamination) are generally well identifiable, however, there is generally no strict boundary between them. The fabric according to the invention comprises at least two different filament layering in its thickness.

Delamination is generally defined as 3D regions oriented in the planar MD-CD direction having a generally uniform filament-to-filament bonding level and/or filament density. The formation of such a hierarchy may be affected by various factors, and the hierarchy may be identified by several methods.

For example, a delamination having a higher level of inter-filament bonding also has a higher filament density or fiber density. Filaments are closer to each other than at the layering formed by the same batt, but have less fiber-to-fiber bonding. The fiber density level may be estimated by observing, for example, SEM microscope cross-sections, as shown in fig. 2, or it may be analyzed and calculated by, for example, tomography or micro CT measurements, wherein 2-dimensional digital cross-sections may be generated and used to accurately determine filament density.

For example (see fig. 3), wherein a fabric according to the invention may comprise at least two different filament layering (A, B) with different filament densities in its thickness. Preferably, the ratio of the filament density of layer a to the filament density of layer B is at least 1.5; more preferably at least 2.0; more preferably at least 2.5; more preferably at least 3, even more preferably at least 5.

For example, a fabric according to the present invention may comprise at least two different filament layering, wherein a first layering (a) with a higher filament density forms one surface of the nonwoven fabric and a second layering (B) with a lower filament density forms a middle region or second surface of the nonwoven fabric.

For example (see fig. 4), a fabric according to the invention may comprise at least 3 different layers, wherein there is a first layer (a) forming a first outer surface of the fabric, a second layer (B) and a third layer (C) forming a second outer surface of the fabric, wherein the second layer (B) is arranged between the first layer (a) and the third layer (C). The filament density of the second layer (B) forming the intermediate region is lower than the filament density of the first layer (a) and the third layer (C). It should be noted that the outer layers (A, C) may, but need not, have the same properties, as long as they have a higher filament density than the (inner) second layer (B). Preferably, the ratio of the filament density of the first layer (a) to the filament density of the second layer (B) is at least 1.5; more preferably at least 2.0; more preferably at least 2.5; more preferably at least 3, even more preferably at least 5. Also preferably, the ratio of the filament density of the third layer (C) to the filament density of the second layer (B) is at least 1.5; more preferably at least 2.0; more preferably at least 2.5; more preferably at least 3, even more preferably at least 5.

For example, the inter-filament bond density can be measured directly. For example, it can be estimated using optical or SEM microscopy. Both methods can only be used for analysis of the surface of a fabric sample. For complete sample analysis, a "method of determining geometric fiber statistics of nonwoven fabrics" is known in the industry, in which three-dimensional micro-CT images are converted into models of fabrics. The method uses a machine learning method to identify individual fibers present in a sample, and then performs a geometric analysis on these fibers to obtain statistical information suitable for characterizing the material. The results included the orientation and density distribution of the fibers. The analytical workflow was developed by Math2Market GmbH and is part of the GeoDict digital materials laboratory.

For example, a fabric according to the present invention may include at least two different filament layering (A, B) having different inter-filament bonding densities in its thickness. Preferably, the ratio of the inter-filament bond density of the first layer (a) to the inter-filament bond density of the second layer (B) is at least 2; more preferably at least 3; more preferably at least 4; more preferably at least 5, even more preferably at least 7.

For example, a fabric according to the invention may comprise at least 3 different layers, wherein there is a first layer (a) forming a first outer surface of the nonwoven; a second layer (B) and a third layer (C) forming a second outer surface of the fabric, wherein the second layer (B) is disposed between the first layer (a) and the third layer (C). The first (a) and third (C) layers have a higher inter-filament bond density than the layer (B) forming the middle region of the fabric. It should be noted that the outer layer (A, C) may, but need not, have the same characteristics, so long as both have a higher inter-filament bonding density than the (inner) third layer (B) having the lowest inter-filament bonding density. Preferably, the ratio of the inter-filament bond density of layer (a) (or third layer (C)) to the inter-filament bond density of layer (B) is at least 2; more preferably at least 3.0; more preferably at least 4; more preferably at least 5, even more preferably at least 7.

Inter-filament bonding

The inter-filament bond density is related to the bond density within the fabric, or to the length of the filament portions between the bond points. Here, it should be noted that not every filament bond forms a bond, if so, different types of bonds may be found based on the composition of the filaments and the surrounding conditions. Without being bound by theory, we believe that 4 typical cases can be named:

1) Unbonded-two filaments can be in contact with each other but without producing bonding (see fig. 5A, 5B). For example, in the case of side/side fiber types, where polymer bonding is made to exist only on a portion of the surface of the filaments, the filaments may face each other through the portion where bonding polymer is not present. Thus, the filaments may contact each other but may not be connected or bonded to each other. In addition, for example, in the event that the fabric is bonded and then the filament crimp is reactivated using a procedure that does not reach the melting temperature of the bonding polymer, the filaments may become entangled and thereby create more filament-to-filament contact points, however, no new/additional filament-to-filament bonding is created.

2) Weak bond or tangential bond—the two filaments may "tangentially" touch each other and the bonding polymer creates a "neck" between them (see FIG. 6A, FIG. 6B). This may occur, for example, where the fibers only slightly contact each other, or when there is only a relatively small amount of available binding polymer, for example.

3) Fully bonded-two filaments meet each other, the bonding polymer covers them by a combined sheath (see fig. 7A, 7B). This may occur, for example, in the case of fibers slightly pressed against each other, or, for example, when there is a large amount of binding polymer available for forming the coating.

4) "trunk" -two filaments are in longitudinal contact with each other and the binding polymer creates a neck or combined coating for the two fibers along a length, e.g., along a length, that is greater than the sum of the diameters of the two binding filaments (see fig. 8A, 8B).

It should be noted that more than 2 fibers may form bonds, and that different bond types may be combined together. For example, a trunk with weak bond/tangential bond may be bonded to a third fiber, etc. It should also be noted that the categories presented are typical examples for explanatory purposes and that in practice various types of bonds can be found in the fabric, especially temporary types of bonds between weak bonds and full bonds, and that trunks can also be formed from very short bonds to very long bonds.

For example, a layer with a higher number of inter-filament bonds may have a higher density of bonds 3 (full bonds) and 4 (trunk) than a layer with a lower number of inter-filament bonds.

For example, a fabric according to the present invention may include at least two different filament layering (A, B) having different levels of full bond density and trunk type bond density throughout its thickness. Preferably, the ratio of the full bond density to the trunk-type bond density in the first and second layers (a, B) is at least 1.5; more preferably at least 2.0; more preferably at least 3.0; more preferably at least 4.0, even more preferably at least 5.

For example, a fabric according to the invention may comprise at least 3 different layers, wherein there is a first layer (a) forming a first outer surface of the nonwoven; a second layer (B) and a third layer (C) forming a second outer surface of the fabric, wherein the second layer (B) is disposed between the first layer (a) and the third layer (C). The combined density of the full bond and trunk type bond in the first layer (a) and the combined density of the full bond and trunk type bond in the third layer (C) are higher than the combined density of the full bond and trunk type bond in the second layer (B). It should be noted that the outer layer (A, B) may, but need not, have the same properties, as long as both have a higher combined full bond and trunk type bond density than the (inner) second layer (B). Preferably, the ratio of the total bond and trunk type bond density of the combination of the first layer (a) (or third layer (C)) and layer (B) is at least 1.5; more preferably at least 2.0; more preferably at least 3.0; more preferably at least 4.0 and even more preferably at least 5.0.

All four types of bonds can be found in one fabric sample. The bond strength is increased from the first option (unbonded) to a weak bond/tangential bond to a full bond and trunk bond. The number and proportion of different types of bond points in the fabric can affect the final fabric properties. For example, a higher number of bonds with higher strength may support the durability and tensile strength of the fabric, but may also impart rigidity to the fabric. In particular, a higher number of trunk bonds in combination with a larger void volume may be formed to create, for example, undesirable internal hard spots that may be negatively rated as rough or uncomfortable wear.

For example, when viewed in cross-section, a variety of void volumes can be seen in the nonwoven fabric. The larger void volume, referred to as the "cavity," is visible in the nonwoven web cross-section and is three-dimensional. Generally, regions with higher levels of inter-filament bonding have smaller void volumes, and the total void volume of the entire region is generally lower. Conversely, for a given region, the region with less inter-filament bonding exhibits a greater void volume as well as a greater total void volume. Large voids, known as cavities, can also be observed in the cross-section of the fabric. In cross section along the longitudinal axis (MD) of the nonwoven, the length of the cavity is significantly greater than the height of the cavity.

For example, a nonwoven fabric according to the present invention may comprise a layer B comprising cavities, wherein the cavity length to height ratio L: H is at least 3:1, preferably 5:1, most preferably 10:1. See, for example, fig. 9 and 10.

The nonwoven fabric itself may be analyzed using different types of microscopy or other visualization techniques to describe differences in its fibrous structure, but the fabric properties are a key advantage from the end user's perspective. Without being bound by theory and assuming that the nonwoven fabric is made from a uniform filament batt comprised of identical filaments, where the level of inter-filament bonding is proportional to the density of bonding, we can predict the final properties based on the level of inter-filament bonding.

For example, a single layer batt exposed to a spunbond air-through bonding process would be exposed to pre-consolidation on the belt, where the hot fluid enters the fabric from the upper portion, and then the batt moves to the air-through bonding unit and bonds to the belt or drum, where the hot fluid enters the batt from the same side as the pre-consolidation air. Based on the exact technology and process conditions, various structures with different properties can be formed:

when insufficient heat enters the batt filaments, the binding polymer does not soften or melt sufficiently and any bonds formed are typically weak. The formed fabric generally provides a very low level of inter-filament bond density and a relatively large void volume. Such fabrics may be referred to as "under bonded". In general, it is easy to disintegrate filaments or take out part of filaments from them, and durability (surface and delamination/disintegration) is very low. Fabrics may even be considered unstable. On the other hand, such fabrics may be very soft in terms of compressibility, flexibility, drape, etc. See fig. 11.

When heat (which may be at a lower level in the proper heat range) enters the batt filaments, particularly when the heat has sufficient time to enter the filaments as uniformly as possible throughout the batt, or for example when the batt is so permeable to heat flow, the heat flow is caused to pass through the batt filaments at all locations with the same temperature gradient (suitable process settings can be readily determined by those skilled in the art). The polymer is allowed to soften or melt sufficiently (at the lower end of the suitable bonding range) and to produce filament-to-filament bonding. The resulting fabric generally provides a uniform low level of inter-filament bond density and still relatively large void volume. Such fabrics may be referred to as "low adhesion". In general, it is bulky (fluffy), soft in terms of compressibility, flexibility, drape, etc., but it maintains a certain (lower) level of surface and delamination resistance. See fig. 12.

A layered structure may be formed when the heat is not evenly distributed into the batt filaments so that the fibers in the outer region receive more heat and the fibers in the inner portion of the fabric receive less heat (as viewed from the direction of the incoming heat flow).

The layered structure requires a higher level of inter-filament bonding density on the outer surface and a lower level of inter-filament bonding density inside the fabric. See fig. 3.

Heat may enter the filament batts from one side or from both sides (e.g., a hot air stream and a hot surface from one side, such as a belt, table, drum, etc., from the other side) or from both sides in separate steps (from one side and then from the other side). In this case, a first layer (a) having a higher level of inter-filament bonding density may be formed on the first outer surface, a third layer (C) having a higher level of inter-filament bonding density may be formed on the second outer surface, and the intermediate region may include a second layer (B) having the lowest level of inter-filament bonding density. See fig. 4.

Without being bound by theory, we believe that more process elements and parameters may work together to form a layered structure. For example, a slight compressive force under heat (e.g., the tension of the fabric on a cylindrical surface, such as a drum or roller) may horizontally support the outer laminate formation at a higher inter-filament bond density. For example, heat entering the filaments may soften or partially soften the non-binding polymer in the polymer composition, and the partial softening of the filaments closest to the heat source may aid in the formation of the outer layer. For example, filaments having a crimpable cross-section or containing a shrinkable polymer may attempt to move from a semi-stable state to a more stable state under the influence of heat, and internal filament forces may support delamination even if the process is insufficient to form crimps. Patent application WO2020103964 describes the theory of internal shrinkage forces and fiber/filament durability thresholds to explain the formation of a fluffy structure with an uncrimped cross-section. Without being bound by theory, we believe that in a furnace, a similar principle can be used to describe the force that moves a portion of the filaments in the z-direction to form a layered structure. For example, cooling just after exiting the oven may help to form or at least set the formed layered structure.

The fabric formed according to the present invention provides a very good combination of properties in its structural layering with higher and lower levels of inter-filament bond density, where good durability (surface durability of the layering with higher levels of inter-filament bond density and higher force required for delamination given by bond strength of the weakest layering B with low levels of inter-filament bond density) combines good bulk and softness (in the sense of compressibility, flexibility, drape, etc.) supported by loose layering with lower levels of inter-filament bond density.

Without being bound by theory, it is believed that the balance between softness/bulk and durability/tensile strength properties may also take advantage of the synergy provided by the unclear boundaries between adjacent layers. For example, some filaments may have some portions extending into the first or third layers (a, C) with a higher level of inter-filament bonding density, while other portions extend into the second layer (B) with a lower level of inter-filament bonding density. For example, layered structures formed within a layer of filament batts provide better internal complexity than similar structures formed from different fiber layers. When heat (perhaps at a medium to higher level of the appropriate heat range) enters the batt filaments, particularly when there is enough time for the heat to enter the filaments as uniformly as possible throughout all locations of the fabric, or for example when the batt is so permeable to heat flow that the heat flow passes through the batt filaments at all locations with the same heat gradient (a more appropriate process setting can be readily determined by those skilled in the art), the polymer is sufficiently softened or melted (at the higher limits of the appropriate bonding temperature range) and filament-to-filament bonding occurs. The resulting fabric generally provides a uniform, higher level of inter-filament bonding density with a relatively small void volume. Such a fabric may be referred to as "fully bonded". Typically, it is relatively small and stiff. It also maintains a high level of surface resistance, especially delamination resistance. See fig. 13.

When too much heat enters the batt filaments, the bonding polymer melts completely and mainly forms a complete bond or trunk-type bond. In addition, other polymers from the filament composition may be affected, e.g., they may bend more easily, and the filament batts may collapse on themselves. The resulting fabric generally provides a very high level of inter-filament bond density and a small void volume. Such fabrics may be referred to as "overbonding". In general, it is very hard and durable. It may also be less fluffy and have a poor softness feel. See fig. 14.

It should be noted that the above assumption that the fabric thickness decreases with increasing heat absorption is valid for filaments that do not undergo significant changes that trigger internal forces that alter filament shape (e.g., crimp activation, controlled shrinkage, etc.) during their bonding. In this case, the fabric may have a different thickness than the heat absorption curve, one or more chevrons at the optimum curl/shrink value, and a lower thickness for both under-bonded and over-bonded fabrics. The bonding principle is generally the same and a layered structure can be formed with all its advantages.

It is well known in the industry that certain combinations of polymers with different shrinkage levels arranged in so-called crimpable cross sections provide so-called crimps. This may be direct self-crimping or latent crimping, wherein the fibers must be activated to exhibit crimping (e.g., by thermal activation). Fibers having a crimpable cross-section provide a regular crimp that forms a so-called spiral crimp. With considerable simplification, we can say that fibers with a crimpable cross section tend to bend in a direction towards components with higher shrinkage, which results in a substantially uniform spiral crimp. In other words, the crimpable cross-section causes a regular movement of the internal force vectors of the first and second components towards each other. Without being bound by theory, we believe that the regularity of displacement is the primary cause of regularity of the curl of the free filaments. In contrast, without being bound by theory, on fibers having an uncrimped cross-section, we believe that the internal shrinkage force vectors of the first and second components do not provide any regular offset from each other, such that the fibers form an irregular bow or wave shape in any direction. By considerable simplification, we can say that the fiber does not have a uniform tendency to bend towards a specific portion of its cross section or edge, which results in its irregular final shape. After activation, the fiber cross-section remains substantially uncrimped

For example, a fabric according to the present invention may include multiple-component filaments having a binding polymer on at least a portion of their surface. The binding polymer may be selected from the group consisting of polyolefins (i.e. polypropylene or polyethylene), low melting polymers (including low melting polyester grades (i.e. aliphatic compounds such as polylactic acid, or aromatic compounds such as polyethylene terephthalate)), copolymers or blends of suitable polymers. Within the scope of the present invention, the binding polymer consists of or consists essentially of a plastic of the group of polyesters that also include a polyester copolymer (coPET) or a polylactide Copolymer (COPLA).

For example, a fabric according to the present invention may comprise multiple-component filaments having a first polymer with a melting temperature that is higher than the melting temperature of the binding polymer, preferably with a difference in melting temperatures of at least 5 ℃. The first polymer may be selected from a polyolefin (i.e. polypropylene or polyethylene), a polyester (i.e. an aliphatic compound such as polylactic acid, or an aromatic compound such as polyethylene terephthalate), a copolymer or blend of suitable polymers. Within the scope of the present invention, the first polymer consists of or consists essentially of a plastic of the group of polyesters that also include a polyester copolymer (coPET) or a polylactide Copolymer (COPLA).

Preferred combinations of components for the bicomponent filaments according to the invention are PP/PE, PET/PP, PET/COPET, PLA/COPLA, PLA/PE and PLA/PP.

For example, fabrics according to the present invention may include multicomponent filaments, preferably bicomponent filaments.

The fabric according to the invention is formed from a lofty batt, preferably from a batt comprising crimped filaments or also comprising filaments having latent crimps that self-crimp upon appropriate activation.

For example, fabrics according to the present invention may comprise multicomponent filaments having a crimpable cross-section, preferably bicomponent filaments having a crimpable cross-section, more preferably filaments having an eC/S or S/S cross-section. For example, some preferred combinations for the eC/S cross section are: PP/PE, PET/PE, PLA/PE, PET/PP, PLA/PP, PP/coPP, PET/coPET, PLA/coPLA, wherein the specified polymer forms at least 75% of the filament component.

For example, a fabric according to the present invention may comprise multicomponent filaments having a non-crimpable cross-section comprising a shrinkable polymer, preferably bicomponent filaments having a C/S cross-section comprising polyester in its composition, preferably in the core. For example, some preferred combinations for C/S cross-sections are: PET/PE, PET/PP, PET/coPET, PLA/PE, PLA/PP, PLA/coPLA, wherein the specified polymer forms at least 75% of the filament component.

Without being bound by theory, we believe that in some cases a layered structure may be formed, but because of the low amount of binding polymer available on the filament surface, the resulting bond is too weak to hold it in place and the desired structure is no longer present. On the other hand, if the filaments contain too much binding polymer that melts during the binding process, the remaining solid portion of the filaments that do not melt becomes too weak to retain their structure when subjected to heat flow, and the desired structure is again no longer present.

For example, a fabric according to the present invention may comprise at least 15 wt% of binding polymer, preferably at least 18 wt% of binding polymer.

For example, a fabric according to the present invention may comprise up to 75% by weight of binding polymer, preferably up to 80% by weight of binding polymer.

Different levels may be used for various polymer combinations. For example, a fabric with PP/PE filaments according to the present invention may comprise at least 25 wt.% of binding polymer, preferably at least 30 wt.% of binding polymer, more preferably at least 35 wt.% of binding polymer. For example, a fabric with PP/PE filaments according to the present invention may comprise at most 75 wt.% of binding polymer, preferably at most 70 wt.% of binding polymer, more preferably at most 65 wt.% of binding polymer.

It should also be noted that the binding polymer should be present on the filament surface. In the case of a core-sheath or an eccentric core-sheath, the binding polymer should be part of the sheath or preferably form the sheath.

For example, a fabric according to the present invention may include a binding polymer that forms at least 20% of the filament surface area, preferably at least 35% of the filament surface area, and even more preferably at least 50% of the filament surface area. The layered structure according to the invention provides a balance of fabric durability and softness/bulk.

For example, fabric durability is always required. The fabric needs to be durable enough to withstand the process of conversion to the final product without damage and also needs to withstand the use of the final product. Two very important parts of the durability are fabric surface stability (durability of releasing fibers from the surface) and fabric delamination stability (durability of tearing the upper part of the fabric from the lower part). In general, these two types of durability are evaluated together with other types of durability, such as wear resistance using a martindale test method with a set number of cycles, and then the results are manually evaluated on a scale of 1 to 5. Such a test is very good for setting a threshold level for one particular product with a binary pass/fail evaluation, however, it is not the best choice for describing the sufficiently detailed distinction required for the advantages of the present invention due to its rough rating and lack of additional information for comparing the sample passing the test with the best results.

In other words, we can say that the tensile strength of the fabric in the z-direction is lower for delamination with a smaller level of inter-filament bonding. The tensile strength of the fabric in the z-direction may be measured, for example, using a delamination strength test. The fabric tears in its weakest layer. When the delamination strength is too low, the fabric is not sufficiently stable and under the load of conversion or normal operation it may delaminate and tear into individual layers or may delaminate only in certain areas where the delaminated portions remain partially connected and tend to produce undesirable caking. Similarly, even if the surface of the fabric is very abrasion resistant, delamination can deteriorate the results during the martindale abrasion test, producing a caking or so-called spider web effect.

Without being bound by theory, it is believed that for fabrics with a formed layered structure, a key value describing durability is delamination strength. A fully bonded fabric that does not have a layered structure or has a low level of layered structure will have good surface stability and high delamination strength. The well formed layered structure is characterized by good surface stability and moderate delamination strength. Fabrics with weak or no delamination structure that are not sufficiently cohesive are characterized by easy surface disintegration and low delamination/disintegration strength.

For example, a fabric according to the present invention may comprise at least two different layers, wherein the delamination strength is equal to or higher than 0.5N or preferably higher than 0.6N or preferably higher than 0.7N or preferably higher than 0.8N.

For example, a fabric according to the present invention may comprise at least 2 different layers, wherein the delamination strength is equal to or lower than 2.0N.

Delamination force is the force required to pull the outer portion/outer layer of the nonwoven along the weakest area within the nonwoven. Assuming the fabric has a layered formation structure, delamination will occur within the layer having the lowest level of inter-filament bond density. Here, it should be noted that for typical nonwoven compositions, the binding polymer provides lower tensile strength than the other polymers, meaning that the weakest point is typically the bond rather than the filaments themselves. This property is also often affected by the cross section of the fiber. For example, polyethylene as the binding polymer provides lower tensile strength than polypropylene or polyester. For example, the bonding between the core/sheath structural filaments with polyethylene in the sheath is relatively weak, as the sheath is typically a coating of a relatively thin inner core. Thus, filament-to-filament bonding is generally easier to break than the filaments themselves. See fig. 15 to 19.

For example, bulk is one of the key features. As noted above, the filament batts should be sufficiently fluffy to allow for proper flow of the hot fluid during bonding, such as during through-air bonding. The final fabric should also be bulky, as bulk is very important to human perception, and more bulky fabrics are often perceived as softer. The layered structure provides bulk, e.g., layer B is typically very bulk, increasing the bulk of the overall structure. On the other hand, one or more layering with higher levels of inter-filament bond density reduces the bulk of the overall structure, and in extremely bulk structures, one or more outer layering may not form at all.

For example, a fabric according to the invention may have a weight of less than 60kg/m ³ Preferably less than 58kg/m ³ More preferably less than 56kg/m ³ More preferably less than 54kg/m ³ Bulk density of (d).

For example, a fabric according to the invention may have a weight of more than 15kg/m ³ Preferably greater than 20kg/m ³ More preferably greater than 25kg/m ³ Most preferably greater than 30kg/m ³ Bulk density of (d).

Bulk/degree of bulk means the number of kilograms per cubic meter, so the lower the value, the more fluffy the material; at the same time, we can use dm ³ "ratio of caliper to basis weight" in/kg or l/kg means the volume of one kilogram of fabric in liters, where the higher the value, the higher the bulk/bulk.

For example, a fabric according to the present invention may have a thickness to basis weight ratio of at least 16.5l/kg, preferably at least 17.0l/kg, preferably at least 18.0l/kg, more preferably at least 18.5 l/kg.

For example, the fabric according to the invention may have a bulk density of at most 66l/kg, preferably not more than 50l/kg, preferably not more than 40l/kg, more preferably not more than 33 l/kg.

For example, a fabric according to the present invention may have a basis weight of at least 5gsm, preferably at least 10gsm, more preferably at least 15 gsm.

For example, a fabric according to the present invention may have a basis weight of no greater than 200gsm, preferably no greater than 150gsm, preferably no greater than 100 gsm.

For example, a fabric according to the present invention may have a recovery of at least 0.5 (which corresponds to 50% recovery of the original thickness), preferably at least 0.6, more preferably at least 0.7, more preferably at least 0.8, most preferably at least 0.9.

For example, a fabric according to the present invention may have a resilience of at least 5%, preferably at least 10%, more preferably at least 13%, more preferably at least 15%, more preferably at least 18%.

The above description of the layered structure, particularly as shown in the schematic drawing, assumes that the filaments are laid down uniformly in all three dimensions in the batt. This uniformity is ideal for most nonwoven applications. Non-uniformities are generally directly observable by the human eye. The fabric appears denser/thicker in some places and less dense/thinner/weaker in other places. In extreme cases, the fabric may appear to consist of dense islands at a distance from each other, connected by a sparse filament web. However, even a fabric that is judged to be uniform by a human observer may contain small areas of non-uniformity with higher and lower densities in all three dimensions of the fabric. Fibers having crimp, typically produced by self-crimping or activated crimping or by controlled shrinkage, have a tendency to form structures characterized by regions of higher and lower density, i.e., form microagglomerates in certain regions while leaving relatively empty microspaces in other regions. When examined on a microscopic scale in the cross-section of the fabric, the denser regions may partially form cover layers with less inter-filament bonding, and vice versa. See fig. 20A and 20B.

The object of the present invention is to describe a hierarchical structure and its advantages compared to layering methods. As described above, the layered structure may be formed in one layer of the nonwoven fabric, or in other words, the layered structure may be formed independently of the fabric layer.

The layered structure may advantageously be combined with layering. For example, a fabric according to the present invention may be comprised of two or more filament layers wherein the filaments of at least one outer layer are configured into at least one outer layer that provides a higher level of inter-filament bonding density and at least one other layer that has a lower level of inter-filament bonding density.

As described in detail above, a single layer may include one, two, or more layers. In general, a layer may form part of a layer, may be equal to a layer, or may be assumed to include more layers. Within the scope of the present invention we consider a layered fabric comprising at least one layer in which at least 2 layers are formed.

For example, a fabric according to the present invention comprises at least one layer of endless filaments, wherein at least 2 layers are formed.

For example, layers having different filament thicknesses and amounts of binding polymer may be combined together to obtain a fabric having one surface, for example, with very good abrasion resistance (provided by layers having finer fibers and a higher amount of binding polymer) and overall bulk (provided by layers having coarser fibers and a lower amount of binding polymer), as described, for example, in reifiehauser patent application No. EP19189238.9 (not yet published).

For example, layers having different amounts of binding polymer on the filament surface may be bonded together, e.g., S/S and C/S or eC/S filaments may be bonded together to make a fabric such as: which has enhanced soft loft properties provided by filament layers having a relatively low amount of binding polymer and very good abrasion resistance on filament surfaces having a relatively high amount of binding polymer.

Those skilled in the art may appreciate the various layer combinations utilizing the advantages of the layered structure formed in some or all of them. The filament layers of the layered structure may also be advantageously combined with one or more staple fiber layers, films, etc.

Layering may also achieve a specific layered structure created by exposing the batts to various heat sources. For example, a lofty fabric formed from 2 layers, which were made using 2 spinners, pre-consolidated with hot air and then bonded in a hot air oven, can form a structure in which 5 layers with alternating higher and lower levels of inter-filament bond density can be seen. See fig. 21 and 22.

Without being bound by theory, it is believed that in some cases an inner laminate having an inter-filament bond density level between two lower inter-filament bond density level layers may be supported by pre-consolidation of the batt, wherein, for example, a source of thermal fluid (e.g., a hot air knife) and/or a second or any other source of thermal fluid (as required by production) after one, some or each manufacturing box is brought together with vacuum equipment below the belt may help form a higher inter-filament bond density core and thus provide a higher likelihood of forming a laminate structure in the fabric with an internally higher inter-filament bond density level.

Similar structures may also be produced, for example, with specific combinations of layers. For example, a 2-layer fabric, both layers of which are formed from crimpable fibers having different levels of internal filament crimp forces (e.g., having different filament cross-sections, different composition ratios, different process settings that produce different levels of potential crimp, etc.), may result in independent filament movement in both layers, thereby forming a delamination on the surface of the layers having a higher level of inter-filament bond density, in other words, on both the fabric surface and the boundary region between layers.

Fabrics according to the present invention may be produced from a batt comprising multicomponent filaments which include a binding polymer having a lower melting temperature on at least a portion of their surfaces. The batts on the moving belt are subjected to a heat treatment. Heat may be transferred to the batt by a hot fluid, such as hot air. Typically, heat may be transferred into the batt at various stages of the production process, for example, immediately after laying the filaments on a belt to pre-cure the structure, during a heat activation process, during a bonding process, and so forth.

The hot fluid enters the filament batt surface, flows around the filaments, and a portion of the heat carried by the hot fluid is transferred to the cooler filaments. As some heat is transferred to the filaments on the surface of the batt, the temperature of the hot fluid is slightly reduced and the temperature differential between the filaments and the hot fluid is also slightly reduced. Those skilled in the art will recognize that as the filaments of the surface are heated, the filament temperature increases and the temperature differential between the hot fluid and the filaments decreases. With sufficient time and heat, all filaments within the fabric may be heated to a uniform temperature and the fiber-to-fiber bonding may be uniform throughout the thickness of the fabric. The fabric may be said to be uniformly, fully or well bonded.

It should be noted that the formation of filament-to-filament bonds also depends on the localized hydrodynamic pressure strength, i.e., the filaments may contact or intersect each other and they will not form bonds, or only form weak bonds, while more strongly contacting filaments will form stronger bonds by the melted low melting temperature polymer. The pressure created as the hot air passes through the fabric along its primary vertical hot fluid path through the fabric causes the temperature of the fluid and its ability to transfer energy to subsequently decrease, gradually decreasing from the first point of impact of the exposed fabric surface to the other side of the fabric, and decreasing in temperature and fluid flow rate as it exits the fabric. This results in a difference in bond density across the fabric cross-section, which is manifested in the formation of delamination within the fabric layer.

The product according to the invention claims a non-uniform inter-filament bonding density bond throughout its thickness. The process settings and machinery used to make such products from filament nonwoven batts should be able to provide the desired hot air constant by the flow rates and temperatures in both the CD and MD, which also means that they are constant over time. This requirement applies to all hot air supplies, such as hot air knives, hot air zones, hot bonding ovens with drums, flat belt ovens or a combination of drum bonding and flat belt bonding.

In a preferred form of construction of the invention, multicomponent or preferably bicomponent filaments are present, produced by spinning in a spinner or using a spinneret and then preferably through a cooler. Within this cooler, the filaments are typically cooled by a fluid flow, mainly by cooling air. The scope of the invention includes the following facts: the spun filaments then also pass through a drawing mechanism in which the filaments are processed by being drawn. The drawn (elongated) filaments are then deposited on a moving belt, where they form a long filament batt. In one advantageous configuration, filaments having a controlled degree of potential shrinkage can be produced in the batt by adjusting specific parameters that determine the draw ratio. In other advantageous combinations, filaments that provide self-crimp or have a desired level of potential crimp can be subsequently formed in the batt by providing a crimpable filament cross-section and adjusting specific parameters that determine draw rate and cooling.

According to a preferred form of the mechanical and method construction of the invention, the inserted diffuser will serve as a hopper mechanism that controls the deposition of filaments and is mounted between the drawing mechanism and the filament deposition location. The scope of the invention includes the fact that at least one diffuser is used, the opposite side walls of which diverge from each other with respect to the direction of passage of the filaments. A highly preferred form of construction of the invention is characterized in that the drive units of the cooling mechanism and the traction mechanism are designed as a closed system. Within the closed system, no additional air source is used, which would supplement the supply of external cooling medium or cooling air into the cooling mechanism. Such closure systems have proven themselves to be particularly suitable for the manufacture of nonwoven fabrics.

In the case of the production of the nonwoven fabric according to the invention by means of shrinkage, it has been found that the solution according to the invention, which eliminates the problems associated with filament shrinkage, is particularly functionally reliable and effectively feasible when using the above-described unit, in particular when using a diffuser in addition to the particularly preferred construction form, which is arranged between the drawing mechanism and the filament deposition location. It has been demonstrated that the shrinkage of nonwoven batts made by the spunbond process can be very specifically tailored or adjusted by the parameters of draw ratio, cooling air/polymer ratio and filament speed.

In the case of the manufacture of nonwoven fabrics according to the present invention using self-crimping filaments, these filaments are released from aerodynamic stretching forces upon exiting a diffuser located at the end of the stretching chamber and then laid down in a vacuum-supported web forming zone, wherein once the vacuum is at its lowest force (in the MD) at the edge of the suction zone, the filaments crimp and by such crimping filaments a final increase in fabric thickness can be obtained.

To consolidate the filament orientation and three-dimensional structure, resulting in the thickness/loft of the fabric batt, a subsequent step of unidirectional application of heated air through the batt is performed. The parameter settings of hot fluid/hot air temperature, penetration speed and volume are mainly dependent on:

Total throughput of spin melt tank;

fiber size and polymer combination

Linear velocity

The thickness of the batt is chosen to be the same,

basis weight of fabric g/m ² ，

In order to maintain the desired thickness without affecting the parameter settings of the final bonded fabric.

Since the above process steps can be applied multiple times by adding additional spin-melt bins with similar or different combinations of polymer, fiber size and basis weight, a hot fluid supported consolidation step on a common conveyor belt is preferably also applied to obtain preliminary product properties prior to the final bonding step.

As is apparent from the definition already set forth, fabrication using the spunbond process involves the direct conversion of the polymer into filaments that are subsequently randomly spread out at the deposition location to produce a nonwoven batt containing these filaments. The spunbond process determines the characteristics of the individual filaments and the characteristics of the final nonwoven fabric. The final manufactured nonwoven fabric cannot always be used to determine various characteristics and conditions of the individual filaments, such as the rheological properties, structural properties, activated curl, self-lap Qu Shuiping, and shrinkage of the polymer, which occur during the various manufacturing steps of the nonwoven fabric. The potential crimping or shrinking of the nonwoven fabric generally determines its ability to produce a lofty nonwoven fabric by utilizing the crimping or shrinking of the individual filaments to achieve an increased thickness of the filament batt, however, without disintegrating the fabric structure and/or without significantly altering the length and width of the filament batt. The scope of the invention includes the following facts: the crimping/shrinking of the filaments is defined by using the various raw materials contained in the filament composition and/or by setting different material processing conditions during the manufacture of the filaments for the nonwoven fabric and/or by using different filament cross-sectional shapes/arrangements and/or by adjusting the mass ratio between the various input materials and/or by setting different filament orientations.

The recommended form of the structure of the invention does not distinguish between filaments having a cross section that supports crimping and filaments having a cross section that does not support crimping. Both types may be advantageously used for certain applications. Also, suitable combinations can be created by using layers of crimped and uncrimped filaments. It is obvious to those skilled in the art that there are technical advantages provided by filaments having a cross section that does not support crimping compared to crimped filaments in obtaining a loose and soft yielding material.

The method according to the invention may comprise one or more different bonding steps, see fig. 23. For example, a batt of filaments may be laid on a moving belt and bonded from one or both sides in a bonding unit placed directly after the filaments are laid from the manifold.

For various reasons, it may be advantageous to have a greater distance between the filament spinning beam and the bonding unit. More than one manifold is typically used to form the laminate structure, or for process reasons, filament batts may need to pass through the gap between the moving belt and the bonding unit. In this case, which is common to spinning melt production lines, a pre-consolidation of the batt is required to increase the batt stability so that it can withstand the production process prior to bonding. Further, for example, thermal activation of the latent crimp may be required prior to bonding. The pre-consolidation and/or activation may be performed using rollers (e.g., compact rollers), hot air (e.g., HAK, HAF units), heat radiation (e.g., infrared pre-consolidation), and the like. For further explanation, the process is described with the selection of 3 different bonding steps. It should be noted that the layered structure of the present invention may also be formed by a production process with different combinations of pre-consolidation/activation and bonding units.

For example, one configuration of the present invention also includes the fact that the filament batt is thermally pre-consolidated, i.e., it is pre-consolidated and may contain thermally formed bonds. One of the advantageous configurations of the present invention is also the fact that the resulting nonwoven fabric is heat activated in order to achieve controlled shrinkage and/or crimping of the filaments in at least one layer. Consolidation and possible thermal activation are preferably carried out by at least one action in contact with the flow of the thermal medium (for example by hot air or infrared radiation) and/or with the hot surface. Examples of such hot surfaces may be mainly part of the roll. It is desirable to perform the thermal activation under conditions that act uniformly over the entire surface of the fibrous layer. The thermal activation may be carried out in a chamber in which hot air is supplied, or through a furnace by a layer of filaments. Thermal activation and consolidation may also be performed by infrared or ultraviolet light, transmitted microwaves and/or laser radiation. It is emphasized that within the scope of this described process being performed "on-line", thermal consolidation may also occur directly after completion of the preceding steps of the manufacturing process, or that both steps of the process, i.e. thermal activation and consolidation, may be performed "off-line", i.e. separate from the preceding steps of the manufacturing process. Thus, thermal activation may be performed substantially "off-line" at different times and locations.

For the solution according to the invention it is advantageous when the flow of the heat medium passes through the fabric and thus results in heat transfer throughout the whole volume of the nonwoven fabric.

The desired pre-consolidation of the fibrous batts of filaments depends to a large extent on the conditions of the manufacturing process. An important prerequisite might be to set the level of mutual cohesion of the filaments inside the filament batt correctly, and thus also to control the level of mutual cohesion of the filaments based on the requirements of the subsequent steps in the manufacturing process. In the case of a manufacturing process carried out on a manufacturing line and activation carried out on the conveyor belt itself, the required cohesion is relatively low, since it only needs to prevent disintegration or thinning caused by significant undesired movements during activation. In special cases, for example when the filaments themselves provide a very good cohesion during contact with each other or with their substrate, this can be achieved, for example, by the shape/arrangement of their cross-sections, the interlacing speed or their material composition, the cohesion properties of the filament batts being sufficiently good even without thermal pre-consolidation. In other cases, such as when the manufacturing process is split into two steps or when the filament batts are pre-consolidated prior to full activation and transferred, for example, in rolls, then the required cohesion will be much higher, with the result that much higher levels of pre-consolidation are also required. Those skilled in the art who are well-qualified and well-known for the conditions of the manufacturing process will be able to easily determine the level of pre-cure required for their particular situation.

For example, in the case of controlled shrinkage, the activation temperature should be in the range between the glass transition temperature and the softening temperature of component a (vicat softening temperature according to ISO DIN 306). Those skilled in the art will be able to determine the activation temperature that is optimal for a given component composition.

Inside the convection cooler, the filaments are typically cooled by a flowing fluid, mainly by cooling air. As noted above, the latent shrinkage or crimp of the filaments must be evenly distributed throughout the length, width and thickness of the batt exhibiting shrinkage. The characteristics associated with the filaments can be varied by adjusting the draw ratio, the cooling air/polymer ratio and the speed of the filaments, while these parameters are in fact the same for each individual filament according to the invention.

The scope of the present invention includes the fact that the nonwoven fabric formed is preferably formed by a spunbonding process in a manifold1And is formed thereon. At the same time, it is obvious that layers can be deposited on top of each other, which layers are then deposited on at least one forming belt2Together transferred to the mechanism3For final consolidation.

Filament yarn4By spinning in a spinneret5And (3) producing the intermediate spinning. The arrangement of the filaments can be optimized by their alternating arrangement, by means of which the condition can be obtained that each individual filament has a very similar weight and is supplied with cooling air of very similar temperature. The spinneret can have different numbers of capillaries and likewise different diameters (d) and lengths (l) of the capillaries. The length (l) is typically calculated as a multiple of the capillary diameter and is selected in the range of 2l/d to 10l/d for this application area. The number of capillaries needs to be selected according to the desired final diameter of the filaments and the desired or planned total processing of the polymer as well as the desired filament spinning speed. The number of capillaries can be 800 to 7000 hairs per meter The tubule varies within the range in which filaments having a diameter of 8 to 45 μm can be obtained. The diameter of the capillary and filament speed are chosen to enable the correct level of potential shrinkage of the final filament. For filaments having a cross section that does not support crimping and that exhibits a shrinkage of 3000 to 5500m/min, the speed of the filaments should be limited to 1000 to 10000m/min and the diameter of the capillary should be selected to be 200 to 1000 μm, which enables a suitable process draw ratio of 200 to 1300 to be achieved in the case of round capillaries. Although in the case of these round capillaries, a draw ratio of 300 to 800 is most advantageous in order to achieve the desired level of manufacturing line manufacturing rate. Generally, non-circular capillaries exhibit a higher draw ratio, which depends to a large extent on the shape of the capillary and the relative ratio of its surface to volume. The volume and temperature of the cooling air are set in such a way that the correct draw ratio and the correct cooling conditions can be achieved. It has been found useful for the present invention when the ratio of cooling air volume to spun polymer is from 20:1 to 45:1. The volume and the temperature of the cooling air are controlled in a cooler (6). The temperature may be set at 10 to 90 ℃, preferably 15 to 80 ℃, thus in such a way that cooling conditions may be used for the specific case to control the shrinkage process. The cooling conditions determine the rate at which the filaments cool from the melting temperature to the glass transition temperature during spinning. For example, setting a higher cooling air temperature results in delayed cooling of the filaments. Indeed, for the purposes of the present invention, it is easier to achieve a desired and usable cooling air temperature range when the cooler is divided into two zones, wherein the temperature ranges can be controlled individually. In a first zone located near the spinneret 6aThe temperature may be set to 10 to 90 ℃, preferably 15 to 80 ℃, most preferably 15 to 70 ℃. In a second zone located in the immediate vicinity of the first zone6bThe temperature may be set to 10 to 80 ℃, preferably 15 to 70 ℃, most preferably 15 to 45 ℃.

Thereafter, the filaments are guided through a stretching zone7. Here, the filaments are drawn by a drawing force generated by the action of the cooling air velocity. Adjustable table of cooling air volume and stretching areaThe geometry enables a certain air velocity to be obtained, which is then transferred to the filament velocity. The filament speed, together with the amount of polymer processed, then defines the diameter of the filament. The potential shrinkage/compaction is regulated by filament speed, draw ratio and cooling air/polymer ratio.

In a next step, the filaments are fed into a diffuser8Diffuser8Is separated from each other with respect to the direction of travel of the filaments. The position of these walls can be adjusted in a manner that enables a nonwoven fabric of uniform composition to be obtained, wherein the individually deposited filaments form an arrangement that exhibits an omni-directional orientation in the MD/CD plane.

At the same time, it is evident that the deposited filament layer is affected by air, by which the filaments are fed into the diffuser. The air flow can be regulated in a manner that creates various arrangements, from distinct zigzag filaments to truly circular loops, and further similarly, elliptical structures oriented in the CD direction. The filaments being deposited on a forming belt and fed to at least one mechanism for pre-consolidation 9. The cooling air flows through the deposited filament layer and through the forming belt and is then directed out of the processing zone. The volume of the suction air can be adjusted in such a way that deposition of the filaments is made easier and, as such, effective contact of the filament layer with the forming belt is ensured. The pre-consolidation mechanism is located near the diffuser. The formation of the filament layer is controlled by sucking air over the entire range of the path between the diffuser and the pre-consolidation means. The pre-consolidation of the filament layers is performed by hot air.

The amount of energy transferred to the filament layer is controlled by a method that enables the filaments to soften or pre-melt only to a certain extent, which ensures that good cohesion is obtained between the individual filaments. After the necessary cohesion between the filaments has been achieved, the fibrous layer can be transferred to the forming belt without the additional aid of any auxiliary means and without being affected or risked damage due to the forces generated during this transfer. This pre-consolidation method is also sufficient to move the filament layers to different deposition areas on a manufacturing line consisting of multiple spinbars. The energy transferred to the filaments is insufficient to activate the shrinkage of the filaments.

The method according to the invention comprises determining a balance between pre-consolidation parameters: pre-consolidation temperature, pre-consolidation air velocity and pre-consolidation time. The preconsolidation time is understood to mean the time during which the filament layer is modified by preconsolidation air.

The pre-consolidation time of the filament layer is recommended to be 1ms to 10000ms, preferably 2ms to 1000ms, most preferably 4ms to 200ms.

The velocity of the pre-consolidation air used in the pre-consolidation unit is set to 0.1m/s to 10m/s, preferably 0.8m/s to 4m/s. The consolidation temperature during pre-consolidation is recommended to be 80 ℃ to 200 ℃, preferably 100 ℃ to 180 ℃. In one form of construction, the pre-consolidation temperature is from 90 ℃ to 150 ℃, mainly from 110 ℃ to 140 ℃.

In an advantageous embodiment, which is arranged in the region of the production line downstream of the diffuser, the filament wadding is fed to at least one activation unit10. The filaments are activated by hot air. Also, it is understood that the actual crimp or shrinkage of the shrinkable component of the filaments is a function of temperature and also of the duration of time that the filaments are subjected to the temperature effects. Furthermore, it is evident that the speed of the crimping/shrinking process is also dependent on the temperature. The result that can be achieved by this control of the process is that a cohesive and uniform structure of the nonwoven fabric with reduced filament structure density is obtained, which likewise results in an increased thickness of the nonwoven fabric.

According to one of the embodiments of the invention, the execution of the steps of the pre-consolidation and activation method, during which the time of pre-consolidation and/or activation, the air velocity required for pre-consolidation and/or activation and the temperature of pre-consolidation and activation are controlled by the combined method in the combined mechanism for pre-consolidation and activation.

One of the advantageous methods according to the invention comprises determining a balance between the following activation parameters: activation temperature, activation air velocity, and activation time. Activation time is understood to mean the time during which the filament mat is modified by the activating air. Obviously, these parameters may be varied within specific ranges in response to the potential level of filament shrinkage, again with the aim of setting the desired combination of activation time, activation temperature and activation air velocity.

The activation time of the filament batt is recommended to be 20ms to 5000ms, preferably 30ms to 3000ms, most preferably 50ms to 1000ms.

The velocity of the activation air used in the activation unit is set to 0.1m/s to 2.5m/s, preferably 0.3m/s to 1.5m/s. The activation temperature during thermal activation is recommended to be 80 to 200 ℃, preferably 100 to 160 ℃. In one configuration, the activation temperature is 90 ℃ to 140 ℃, primarily 110 ℃ to 130 ℃.

One embodiment according to the invention may include one or more gaps between the manufacturing units or the processing units. Advantageously, when releasing the preliminary fabric or batt from the belt along the MD web path, the release is performed at the lowest possible preliminary differential speed between the belt and the downstream first friction point, so as to remain without changing the overall geometry, particularly the original thickness, and original tactile properties such as soft surface of the fabric or batt.

The resulting product properties may also depend on the tension that needs to be applied in order to release the pre-consolidated batt from the conveyor belt and from each moving surface in the machine direction, which may also be referred to as a friction point.

In particular, the release tension of the batt from the belt may be critical.

Controlled tension is generally described as the force per linear web dimension and its extension across the width, but for a defined and controlled parameter setting there is a recognized way to "interpret" tension by differential speed between two downstream adjacent friction points.

Since it depends primarily on fabric weight, linear speed, surface friction between the fabric and the support surface, differential setting is a straightforward way of adjusting the active drive surface speed.

For example, a method according to the invention may comprise: the differential between the conveyor belt and the air intake roller of the air-passing bonding unit must be less than 1.0%; more preferably less than 0.5%, even more preferably less than 0.3%. A differential speed of less than 1.0% means that the speed of the second device may be in the interval +1.0% to-1.0%.

An embodiment according to the invention comprises a conveyor belt (2) and is carried out under the following conditions: the nonwoven batt has a fabric strength in the Machine Direction (MD) of from 0.5 to 5N/5cm, preferably from 0.7 to 3.5N/5cm, more preferably from 0.8 to 3.5N/5cm, before the nonwoven batt is transferred from the pre-consolidation step to the consolidation unit (3).

Other embodiments according to the invention comprise a conveyor belt (2) and are carried out under the following conditions: the nonwoven batt has a fabric strength in the Machine Direction (MD) of greater than 6N/5cm, preferably greater than 8N/5cm, and more preferably greater than 10N/5cm, before the nonwoven batt is transferred from the pre-consolidation step to the consolidation unit (3).

One embodiment according to the present invention includes intermediate cooling between the pre-consolidation step and the final consolidation step. For example, the nonwoven batt may be exposed to a cooling medium, preferably air, on its way to a temperature of equal to or less than 70 ℃, preferably equal to or less than 60 ℃, most preferably equal to or less than 55 ℃. For example, the intermediate cooling may be performed by exposing the pre-consolidated batt to ambient air. Without being bound by theory, we believe that intermediate cooling, wherein at least one surface of the nonwoven in particular is heated during pre-consolidation, exposed to lower temperatures, and then heated during the consolidation step, is advantageous for denser outer delamination formation.

Advantageous configurations according to the invention include a final consolidation process that involves the use of hot air in the consolidation means (3) to modify the filament batts. Inside the consolidation mechanism, the filament batts are consolidated into a fabric having filament-to-filament bonds formed. This can be achieved by a variety of means including, for example, a consolidation mechanism with a bell-shaped roller, a consolidation mechanism with a flat belt, or a multi-roller consolidation mechanism.

It should be noted that thermoplastic polymers and blends thereof are characterized by the following phenomena: when exposed to heat, they exhibit progressively increasing plastic softening states (reduced viscosities) above their glass transition point (when all amorphous portions begin to soften) and below the melting point (when all crystalline portions melt). The melting point is generally within a very narrow temperature range (max. 2.0 ℃) and is defined by the homo-or copolymer used. In the case of polymer blends, a narrow temperature range can be determined when the polymer blend becomes tacky and is capable of forming filament-to-filament bonds.

An advantageous configuration according to the invention comprises using at least 3 different consolidation sections to perform the final consolidation procedure. Basically, the air flow is substantially perpendicular to the fabric and maintains a uniform, low variation of temperature and volume flow.

The first consolidation section preheats the fabric to a temperature near below the melting point of the binding polymer. Preferably, the temperature is set to 5-20 ℃ below the melting point temperature of the binding polymer, more preferably, the temperature is set to 5-15 ℃ below the melting point temperature of the binding polymer, advantageously, the temperature is set to 5-10 ℃ below the melting point temperature of the binding polymer. Advantageously, the first consolidation section comprises alternating heat flow directions entering from the first and second outer surfaces of the fabric.

The second consolidation zone is set to achieve a narrow melting temperature window for the low temperature molten polymer composition to allow for the formation of a fusion bond. On the other hand, the set temperature relative to the basis weight of the fabric, fiber size and cross-sectional ratio between the constituent polymers should be in the range of no more than 5.0 ℃ below to no more than 3.0 ℃ above the melting temperature of the binder polymer. For example, when the melting point is 130 ℃, the set temperature should be in the range of 125 ℃ (130-5) to 133 ℃ (130+3). Preferably, the temperature is set in a range of 5 ℃ below the melting temperature of the binding polymer to equal to the melting temperature of the binding polymer, more preferably, the temperature is set in a range of 4 ℃ below the melting temperature of the binding polymer to 1 ℃. Advantageously, the second consolidation section comprises alternating heat flow directions into the first and second outer surfaces of the fabric.

The third consolidation zone is a cooling zone providing cooler air, preferably at a temperature of 10-40 ℃, more preferably 20-30 ℃. Ambient air may be used. The cooling section helps to solidify filaments on the fabric surface, or at least on the fabric surface, and solidifies the formed layered structure of the fabric. Advantageously, no additional tension is directly applied before and during the cooling process. Advantageously, a further cooling step may be applied after the consolidation unit. Further cooling may be provided by further air flows, cooling rolls, etc. Advantageously, when the temperature of the fabric leaving the third consolidation zone has not reached ambient temperature, further cooling is performed. Advantageously, the fabric will reach ambient temperature, preferably the fabric will reach a temperature of 40-10 ℃, even more preferably the fabric will reach a temperature of 20-30 ℃. For advantageous economic reasons, the process produces a bulky, soft and low-fuzzing nonwoven fabric at high throughput and high production speeds.

For example, in one embodiment according to the present invention, a 4-drum hot air through-cure device may be used. The apparatus enables a short residence time process even at high speeds, but is also capable of sufficient exposure to the necessary hot air flow and hot air volume along the maximum web path to achieve the necessary low viscosity melt flow to produce fusion bonds in a defined narrow parameter window. The rollers in the machine direction allow a contact angle of at least 100 °, preferably at least 130 °, more preferably at least 150 °, advantageously at least 160 °.

The precise parameter setting window of the selected device depends on the selected binding polymer and the mass ratio between filament size, filament cross section and polymer component formulation.

The 4-drum apparatus is also capable of passing a strong, alternating, substantially vertical flow of hot air through the substrate in a short period of time. The first pair of rollers is configured to preheat the fabric structure to just below the softening point and melting point of the low melting polymer composition. A second pair of rollers is provided to achieve a melting temperature window for the low melting polymer composition, allowing a fusion bond to form. In order to maintain the structure of the fabric and to keep the fusion bond intact, the final drum comprises a heating section and a cooling section along its circumference in the machine direction. Advantageously, the textile structure is cured, or at least the surface of the textile structure is cured before it is released from the consolidation means. A separate additional cooling roll with a high flow of cooling air through the fabric is located at the shortest possible distance from the last roll of the air-through bonding consolidation device which, by immediate cooling, finally completes the curing of the fabric.

The consolidated nonwoven is wound onto a spool (11) in the final stage. In the event that it is desired to change the surface characteristics of the nonwoven fabric, for example to achieve improved fluid transport or to increase their ability to be discharged, a spray mechanism or dip roll is located between the moving belt and the final consolidation mechanism, or between the final consolidation mechanism and the reel.

One form of construction of the present invention includes combining activation and consolidation steps wherein activation time and/or consolidation time, air velocity required for activation and/or consolidation, and activation and/or consolidation temperature are controlled within the consolidation mechanism.

The important factor is to determine the balance between the following consolidation parameters: consolidation temperature, velocity of consolidation air and consolidation time. Consolidation time is understood to mean the time during which the filament mat is altered by consolidation air. Obviously, these parameters may be varied within specific ranges in response to the potential consolidation level of the filament mat, and as such, the objective is to achieve a desired combination of consolidation time, consolidation temperature, and consolidation air velocity.

The consolidation time of the filament mat is recommended to be 200 to 20000ms, preferably 200 to 15000ms, most preferably 200 to 10000ms.

The velocity of the consolidation air used in the consolidation unit is set to 0.2 to 4.0m/s, preferably 0.4 to 1.8m/s. The consolidation temperature during thermal consolidation is recommended to be 100 ℃ to 250 ℃, preferably 120 ℃ to 220 ℃. In one form of construction, the consolidation temperature is from 90 ℃ to 140 ℃, primarily from 110 ℃ to 130 ℃.

Examples

Further details and specific features of the invention will be explained on the basis of embodiments. The examples illustrate the practice of the invention but are not intended to be construed as limiting thereof. Other embodiments and modifications within the scope of the claimed invention will be apparent to those of ordinary skill in the art. Accordingly, the scope of the invention is to be defined by the appended claims.

Examples use is made ofReicofil GmbH&And R5 type spinning melting production line provided by Co.KG. The production line comprises two spunbond tanks (a, D), each of which is adapted to produce bicomponent filaments. In example 1, only one spunbond tank was used, and in examples 2 to 13, two tanks were used. Filaments from a first tank are laid down on a moving belt to form a first layer, and filaments from a second tank are laid down on the first layer to form a second layer of batt. After each box, the batt is pre-consolidated using hot air, thus after the first box, one layer is pre-consolidated and after the second box, the two layers are pre-consolidated together. The resulting double batt was moved to an air through bonding unit containing 4 rolls. The batts are air through bonded from a first side by a first roller, then air through bonded from a second side by a second roller, then air through bonded again from the first side by a third roller, and then air through bonded from the second side by a fourth roller. The first two drums present a first consolidation section, and the third drum, and the portion of the fourth drum present a second consolidation section. The cooling of the nonwoven begins at the fourth drum (third consolidation zone) with most of its contact surface for the final stage of air through bonding by hot air (second consolidation zone) and the final portion corresponding to 30 ° of the drum contact surface serves as the first stage of cooling the fabric, i.e. as the air through cooling stage (i.e. the final surface in direct contact with the nonwoven before the fabric leaves the air through bonding unit is used for initial cooling of the fabric. The resulting nonwoven is further cooled by air immediately after leaving the air through bonding unit. Specific features of the production examples are defined below and the resulting features of the resulting examples are indicated in the tables below.

EXAMPLE 1 the present invention

The first box produced filament batts, each filament having a core/sheath structure (non-crimpable cross section), wherein the core formed 70% by weight of the filament and comprised polyethylene terephthalate (model 5520 from Invista) and the sheath formed 30% by weight of the filament and comprised polyethylene (Aspun 6834 from Dow Chemicals).

The second tank is closed.

The first tank throughput was 220 kg/hour/meter width of the first tank.

The air-through bonding unit was set to 121 deg.c for the first and second drums, 127 deg.c for the third and most parts of the fourth drum, and 24 deg.c for the last part of the fourth drum (the last part corresponding to 30 deg. of the contact surface of the drums) was set to use ambient air.

The resulting nonwoven had 75gsm and the layered structure in its cross section was well identifiable (as shown in figure xx). Denser layers a and C form the outer surface of the fabric, and a very fluffy layer B with a cavity in the middle provides the fabric with fluffiness. It should be noted that the layering may or may not be uniformly formed. For example, here, tier a is much thicker than tier C, see fig. 24.

EXAMPLE 2 the present invention

The first box produced a first layer of filaments having an eccentric core/sheath structure, wherein the core formed 40% by weight of the filaments and comprised a polypropylene blend (model 3155 from Exxonmobil, HG475FB from Borealis, white colorant TiO2 and erucamide), and the sheath formed 60% by weight of the filaments and comprised polyethylene (Aspun 6850 from Dow Chemicals).

The second box produced a second layer of filaments having a side-to-side structure, with each side forming 50% by weight of the filaments. One side comprised a polypropylene blend (model 3155 from Exxonmobil, model HG475FB from Borealis, white colorant TiO2 and erucamide) and the second side comprised polyethylene (ASPUN 6834 from Dow Chemicals).

The first tank throughput was 160 kg/hour/meter of the width of the first tank and the second tank throughput was 240 kg/hour/meter of the width of the second tank.

The air-through bonding unit was set to 125 ℃ for the first and second drums, 129 ℃ for the majority of the third and fourth drums, 24 ℃ for the last part of the fourth drum (the last part corresponding to 30 ° of the contact surface of the drums), and a cooling unit arranged after the consolidation unit in the MD.

The resulting nonwoven fabric had 25gsm and the layered structure was well identifiable. The layered structure was determined by 3 different methods:

1) SEM microscopy of the cross-section was performed. The outer tier a, outer tier C, and inner tier B are easily identified. Since SEM microscopy provides a view of "entering" the fabric, determining filament-to-filament bonding, sticking, or measuring cavities can be very complex.

(FIG. 25).

2) The nonwoven fabric is fixed in a resin and a cross section is prepared. We now see only the cross section, where the filaments (in this micron scale they are randomly oriented) are considered as black dots. It is evident that the filaments (dots) are denser in layers a and C and form cavities in inner layer B. (FIG. 26)

3) The nonwoven fabric was analyzed by X-ray tomography to increase the spatial resolution of the fabric/filaments on the X-ray image, and the sample was metallized in the same manner as SEM microscopy. A 3D model of the fabric is created on a computer (fig. 27) and then digitally cut into two-dimensional fabric cross sections (fig. 28). The metallized filaments appear as white spots (the size of the white areas may be affected by the amount of metal on the surface of the filaments). The areas with filaments closer to each other (denser areas) may also be represented by white areas. Layers a and C and inner layer B are well visible here.

All 3 methods showed a distinctly formed layered structure in the samples. Different views at different portions of the fabric sample also show that the inner layer B may be formed closer to one fabric surface, in the middle or closer to the other fabric surface. It is apparent (especially in SEM pictures) that intra-layering does not have to be formed at the layer/layer boundary. Also, the fabric properties shown in Table XX show a good combination of durability and softness of the samples.

Examples 3 to 5-the present invention

Example 3, example 4 and example 5 are almost identical to example 2. They differ in basis weight and filament thickness (given by different means prior to filament laying). The bonding process setup was also the same as in example 2. The layered structure is well identifiable (the fabric cross-section is shown in figure xx). The fabric properties are shown in table xx.

EXAMPLE 6 the present invention

The first box produced a first layer of filaments having an eccentric core/sheath structure, where the core formed 40% by weight of filaments and comprised a polypropylene blend (model 3155 from Exxonmobil, HG475 FB from Borealis, white colorant TiO2 and erucamide), and the sheath formed 60% by weight of filaments and comprised polyethylene (Aspun 6850 from Dow Chemicals).

The second box produced a second layer of filaments having a side-to-side structure, with each side forming 50% by weight of the filaments. One side comprised a polypropylene blend (model 3155 from Exxonmobil, model HG475 FB from Borealis, white colorant TiO 2) and the second side comprised polyethylene (Aspun 6834 from Dow Chemicals).

The first tank throughput was 120 kg/hour/meter of the width of the first tank and the second tank throughput was 240 kg/hour/meter of the width of the second tank.

The air-through bonding unit was set to 124 ℃ for the first and second drums, 128 ℃ for the majority of the third and fourth drums, the last part of the fourth drum (the last part corresponding to 30 ° of the contact surface of the drums) was set to use ambient air with a temperature of 24 ℃, and a cooling unit arranged after the consolidation unit in the MD.

The resulting nonwoven fabric had 25gsm and the layer structure was well identifiable.

EXAMPLE 7 the present invention

The first box produced a first layer of filaments having an eccentric core/sheath structure, wherein the core formed 40% by weight of the filaments and comprised a polypropylene blend (model 3155 from Exxonmobil, HG475 FB from Borealis, white colorant TiO2 and erucamide), and the sheath formed 60% by weight of the filaments and comprised polyethylene (Aspun 6850 from Dow Chemicals).

The second box produced a second layer of filaments having a side-to-side structure, wherein the first side formed 75% by weight of the filaments. The first side comprised a polypropylene blend (model 3155 from Exxonmobil, model HG475 FB from Borealis, white colorant TiO2 and erucamide), and the second side formed from 25 wt% filaments comprised polyethylene (Aspun 6834 from Dow Chemicals).

The first tank throughput was 220 kg/hour/meter of the width of the first tank and the second tank throughput was 240 kg/hour/meter of the width of the second tank.

The air-through bonding unit was set to 117 ℃ for the first and second drums, 123 ℃ for the majority of the third and fourth drums, 24 ℃ for the last part of the fourth drum (the last part corresponding to 30 ° of the contact surface of the drums), and a cooling unit arranged after the consolidation unit in the MD.

The resulting nonwoven had 55gsm and the layer structure was well identifiable.

EXAMPLE 8 the present invention

The second box produced a second layer of filaments having a side-to-side structure, wherein the first side formed 50% by weight of the filaments. The first side comprised a polypropylene blend (model 3155 from Exxonmobil, model HG475 FB from Borealis, white colorant TiO2 and erucamide), and the second side formed from 50 wt% filaments comprised polyethylene (Aspun 6834 from Dow Chemicals).

EXAMPLE 9 the present invention

The first box produced a first layer of filaments having an eccentric core/sheath structure, wherein the core formed 50% by weight of the filaments and comprised a polypropylene blend (model 3155 from Exxonmobil, HG475 FB from Borealis, white colorant TiO2 and erucamide), and the sheath formed 50% by weight of the filaments and comprised polyethylene (Aspun 6850 from Dow Chemicals).

The air-through bonding unit was set to 124 ℃ for the first and second drums, 129 ℃ for the majority of the third and fourth drums, 24 ℃ for the last part of the fourth drum (the last part corresponding to 30 ° of the contact surface of the drums), and a cooling unit arranged after the consolidation unit in the MD.

The resulting nonwoven had 22gsm and the layer structure was well identifiable.

EXAMPLE 10 the present invention

The first tank throughput was 200 kg/hour/meter of the width of the first tank and the second tank throughput was 240 kg/hour/meter of the width of the second tank.

The air-through bonding unit was set to 124 deg.c for the first and second drums, 131 deg.c for the most part of the third and fourth drums, the last part of the fourth drum (the last part corresponding to 30 deg. of the contact surface of the drums) had been set to use ambient air having a temperature of 24 deg.c, and the cooling unit was arranged close to the cooling unit in MD.

The resulting nonwoven had 65gsm and the layer structure was well identifiable.

It should be noted that examples 9 and 10 can be used for many applications that are considered to be under-bonded because they have lower tensile and bond strengths. However, even here, a layered structure providing higher durability on the outer fabric surface is formed.

The multilayer embodiments described above use a combination of eC/S and S/S filaments, it being noted that even such a combination may bring advantages, which is not important to the present invention. Example 11 below shows a two layer fabric in which both layers are formed from filaments having an eC/S cross section.

EXAMPLE 11 the present invention

The first box produced a first layer of filaments having an eccentric core/sheath structure, wherein the core formed 60% by weight of the filaments and comprised a polypropylene blend (model 3155 from Exxonmobil, model HG475 FB from Borealis, white colorant TiO2 and erucamide), and the sheath formed 40% by weight of the filaments and comprised polyethylene (Aspun 6850 from Dow Chemicals).

The second box produced a second layer of filaments having an eccentric core/sheath structure, wherein the core formed 50% by weight of the filaments. The core comprised a polypropylene blend (type 3155 from Exxonmobil, type HG475 FB from Borealis, white colorant TiO2 and erucamide), and the sheath formed from 50 wt% filaments comprised polyethylene (Aspun 6834 from Dow Chemicals).

EXAMPLE 12 the present invention

The first box produced a first layer of filaments having an eccentric core/sheath structure, wherein the core formed 50% by weight of the filaments and comprised a polypropylene blend (model 3155 from Exxonmobil, HG712 FB from Borealis, white colorant TiO2 and erucamide), and the sheath formed 50% by weight of the filaments and comprised polyethylene (Aspun 6850 from Dow Chemicals).

The second box produced a second layer of filaments having a side-to-side structure with the core forming 50% by weight of the filaments. The first side comprised a polypropylene blend (model 3155 from Exxonmobil, model HG712 FB from Borealis, white colorant TiO2 and erucamide), and the second side formed from 50 wt% filaments comprised polyethylene (Aspun 6834 from Dow Chemicals).

The air-through bonding unit was set to 120 ℃ for the first and second drums, 128 ℃ for the majority of the third and fourth drums, 24 ℃ for the last part of the fourth drum (the last part corresponding to 30 ° of the contact surface of the drums), and a cooling zone arranged in the MD after the consolidation unit.

The resulting nonwoven had a 35gsm and the layer structure was well identifiable.

EXAMPLE 13 the present invention

The first box produced a first layer of filaments having an eccentric core/sheath structure, wherein the core formed 40% by weight of the filaments and comprised a polypropylene blend (model 3155 from Exxonmobil, HG712 FB from Borealis, white colorant TiO2 and erucamide), and the sheath formed 60% by weight of the filaments and comprised polyethylene (Aspun 6850 from Dow Chemicals).

The air-through bonding unit was set to 123 ℃ for the first and second drums, 128 ℃ for the majority of the third and fourth drums, the last part of the fourth drum (the last part corresponding to 30 ° of the contact surface of the drums) was set to use ambient air with a temperature of 19 ℃, and a cooling zone arranged after the consolidation unit in the MD.

EXAMPLE 14 the present invention

The first tank throughput was 140 kg/hour/meter of the width of the first tank and the second tank throughput was 240 kg/hour/meter of the width of the second tank.

The air-through bonding unit was set to 124 ℃ for the first and second drums, 129 ℃ for the majority of the third and fourth drums, 21 ℃ for the last part of the fourth drum (the last part corresponding to 30 ° of the contact surface of the drums), and a cooling zone arranged in the MD after the consolidation unit.

The resulting nonwoven had 20gsm and the layer structure was well identifiable.

EXAMPLE 15 the present invention

The air-through bonding unit was set to 124 ℃ for the first and second drums, 129 ℃ for the majority of the third and fourth drums, 18 ℃ for the last part of the fourth drum (the last part corresponding to 30 ° of the contact surface of the drums), and a cooling unit arranged after the consolidation unit in the MD.

The resulting nonwoven had 18gsm and the layer structure was well identifiable.

I. Test method

The "basis weight" of the nonwoven fabric was measured using a test method according to standard EN ISO 9073-1:1989 (corresponding to method WSP 130.1). For measurement, 10 layers of nonwoven fabric were used, and the sample size was 10x 10cm ² 。

The "tensile strength" and "elongation" of the nonwoven fabric were measured according to WSP 110.4.r4 (12) standard using the test method.

The "thickness" or "measurement height" of the nonwoven material is determined by a test measurement method according to European standard EN ISO 9073-2:1995 (corresponding to method WSP 120.6), which is modified in the following manner:

1. the material is measured by using samples taken from the manufacture which are not subjected to high deformation forces or to pressure forces exceeding one day (for example by the pressure exerted by rollers on the manufacturing equipment), but which have to be placed on the surface free for at least 24 hours.

2. The total weight of the top arm of the measuring machine including the additional ballast was 130g.

"bulk", "bulk" or "bulk" of a nonwoven fabric is expressed as kg/m ³ And by "basis weight" (g/m) ² ) Calculated as divided by the "thickness" (mm).

The "thickness to basis weight ratio" of a nonwoven fabric is expressed as dm ³ Kg or l (liters)/kg and calculating the "thickness" (mm. Times.1000) divided by the "basis weight" (g/m) ² )。

The stiffness of the nonwoven textile, which is represented by the measure "Handle-O-Meter" (HOM), was determined according to International Standard WSP 90.3. Unless otherwise indicated for the measurements, the dimensions of the samples were 100×10mm. HOM was measured in the MD and CD directions, respectively. An arithmetic average of these two values is employed unless the MD or CD direction is specified.

The term "regeneration" or "recovery" of bulk herein refers to the ratio between the thickness of the fabric after release of the applied load and the initial thickness of the fabric. The thickness of the fabric was measured according to EN ISO 9073-2:1995 standard while using an initial load force corresponding to a pressure of 0.5 kPa.

The procedure for measuring regeneration consisted of the following steps:

1. preparation of a textile sample 10x 10cm in size

2. Measuring thickness of a piece of fabric

3. Thickness (Ts) of five fabrics stacked on each other was measured by using an initial loading force equivalent to a pressure of 0.5kPa

4. Load 5 pieces of fabric placed on top of each other (by a pressure of 2.5 kPa) on a thickness measuring device for 5 minutes

5. Release the device and wait 5 minutes

6. Thickness (Tr) of five fabrics placed on top of each other was measured by using an initial loading force corresponding to a pressure of 0.5kPa

7. The regeneration is calculated according to the following equation:

regeneration=tr/Ts (without unit)

Ts = thickness of fresh sample

Tr = thickness of regenerated sample

The term "compressibility" herein relates to the distance in millimeters that a nonwoven fabric is compressed by the action of a load defined during a "flexibility" measurement. It can also be calculated as the product of resilience (no units) times thickness (mm). The "elasticity" or "resilience" of the nonwoven fabric was measured using a test method according to standard EN ISO 964-1, modified in the following manner:

1. the thickness of one fabric layer was measured.

2. Several fabric samples were prepared such that their total thickness after being placed on top of each other was at least 4mm, desirably 5mm. The fabric piece group placed on top of each other comprises at least 1 piece of fabric.

3. Measuring the thickness of these stacked fabric samples

4. Allowing a force of magnitude 5N to act on the set of stacked fabric samples at a load speed of 5mm/min

5. Measuring distance corresponding to movement of clamping element

6. The rebound resilience was calculated according to the equation:

r (no unit) =t1 (mm)/T0 (mm)

Or (b)

R(％)＝T1(mm)/T0(mm)*100％

T1=distance corresponding to movement of the clamping element under a load of 5N magnitude [ mm ] =degree of compression of the stacked fabric pieces

T0=thickness (initial load force applied 1.06N according to standard EN ISO 9073-2:1995) [ mm ]

Martindale average wear rating test or Martindale "

Fig. 38 is a perspective view of an apparatus for martindale average wear rating test. FIG. 39 is a scale of the pile evaluation in the Martindale average wear rating test herein as described in published patent application US20200170853A1 of the company Procter and Gamble

The average abrasion resistance rating of the nonwoven was measured using a martindale abrasion tester. Drying and testing.

The nonwoven samples were conditioned at 23.+ -. 2 ℃ and 50.+ -. 2% relative humidity for 24 hours.

Circular samples of 162mm (6.375 inches) diameter were cut from each nonwoven sample. A piece of standard felt was cut into a circle 140mm in diameter.

Each sample was fixed in place on each test grind table of martindale by first placing a cut felt and then placing a cut nonwoven sample. The clamping ring is then secured so that no wrinkles are visible on the nonwoven sample.

Assembled abrasive rack. The abrasive was 38mm diameter FDA compliant 1/32 inch thick silicone rubber (available from McMaster Carr, item 86045K 21-50A). The required weight was placed in the abrasive holder to apply 9kPa pressure to the sample. The assembled abrasive holder was placed in model #864 such that the abrasive contacted the NW sample as indicated in the operator guide.

Martindale abrasion was operated under the following conditions:

mode o: wear test

Rate o: 47.5 cycles/min; and

circulation o: 16 cycles

After the test was stopped, the ground nonwoven was placed on a smooth, matte, black surface and its pile level was graded using the scale provided in fig. 14. Each sample was evaluated by looking from the top to determine the size and number of defects, and from the side to determine the bulk height of the defects. Numbers from 1 to 5 are assigned based on the best match to the hierarchical scale. The martindale average wear rating was then calculated as the average rating of all samples and reported as the nearest tenth.

The "delamination strength" or "bond" can be determined by the following method (see fig. 40 and 41):

1) Samples having a length (MD) of 120mm and a width of at least 30mm were cut.

2) Two 145mm long strips of tape were cut and each strip was folded over on one side for the last 25mm. The sample was reinforced with 25.4mm wide tape and then bonded by rolling it once in one direction with a 7kg hand roller. The sample was cut along the strip to a CD width of 25mm. Separating the free ends of the strip.

3) The tensile strength tester has the following characteristics: the two jaws have gripping surfaces on the same plane parallel to the direction of movement of the applied stress. They must be aligned so that they hold the specimen in this plane throughout the test without slipping and without damaging the specimen. The four sides of the jaws should be padded with thin strips of soft loop rubber to prevent sliding and damage to the test specimen. A Thwing Albert, instron, zwick or equivalent can be used for a constant rate transverse tensile tester according to ASTM D76-99.

4) Parameters were set as follows:

a) Gauge length........................................50 mm

b) Crosshead speed....................................305 mm/min

c) Pre-stretching length................................. Mm

d) Measuring length..................................... Mm

e) Sample scanning frequency..................................50 Hz

5) When properly positioned in the upper clamp, the test specimen is placed in the testing machine (fig. 41) by clamping the free end of the strip. The free end of the strip is returned and clamped in the lower clamp. The free ends of the test pieces are symmetrically aligned in the clamp so that the tension is evenly distributed. The load range is adjusted as needed to bring the reading between 30% and 80% of the total load range.

6) The tensile tester was started.

7) 10 samples were measured and the average calculated.

8) The average separation force was reported, remaining to 0.01N.

The "type of fiber cross section" is known from the process conditions defined by the fiber forming die. In the case where the process conditions are unknown, the following estimates may be used:

a sample of the fabric was taken and a photograph of a cross section of at least 20 fibers was taken. The cross-section is measured on the free portion of the fiber, not at the bond point where deformation would be expected or at the location of contact with another fiber. For each cross section, the component surface is marked on the image for each component separately. Determining a centroid for each component based on the determination of the centroid or geometric center of the planar object, and using a geometric model having a center [0;0 the position of which is recorded in a Cartesian coordinate system of the geometric center of the fiber cross-section. The shift (D) of the centroid of each component in each fiber cross section is calculated according to the following equation:

d=absolute value (x y), where x and y are the coordinates of the centroid. When one of the x value and the y value is equal to 0 and the other is not equal to 0, the sample is discarded from the evaluation

The mean and standard deviation of each component were calculated.

Fibers are considered uncrimped when the ratio of ((average offset) plus (standard deviation)) to total fiber cross-sectional surface is less than 5%.

Fibers are expected to be uncrimped when the ratio of ((mean deviation) minus (standard deviation)) to total fiber cross-sectional surface is less than 10%.

The "inter-filament bond density", "filament density", "length and height of the cavity" and "percent of cavity in thickness of the nonwoven" can be determined from the fabric cross-section.

At least 10 samples were taken in the MD and 10 samples were taken in the CD. Fabrics are considered to have a layered structure provided over at least 50% of the sample, which is identified.

The material will be measured by using samples taken from the manufacture without experiencing higher deformation forces or experiencing pressures longer than a day (e.g., pressures exerted by rollers on the manufacturing equipment) otherwise the material must remain free to lay down on the surface for at least 24 hours.

The cross section can be prepared and analyzed by several methods:

method for producing a textile cross-section

1) Simple cross section:

the fabric is placed on a suitable table and cut with a sharp razor blade. The cut is inspected to have approximately the same thickness as the fabric (e.g., the filaments are not compressed or "cut bonded" together).

2) Resin cross section:

The fabric sample was placed in a container and the liquid resin was poured and cured. The resin needs to be chosen such that in liquid form it easily fills all void volume in the fabric and in solid form it can be easily distinguished from the fabric polymer.

The solid resin block was cut in half to make a fabric sample cross section.

3) Digital cross section:

the sample is scanned (e.g., tomography, micro-CT) and a digital cross-section is created in a computer.

Method of sample cross-section analysis:

1) SEM microscopy

a) If desired, the filament sample is placed in a suitable holder (see, e.g., FIGS. 42A and 42B) and analyzed

b) The sample is metallized with gold (e.g., using an Au/Pd metallization apparatus SC 7640 sputter coater).

c) Samples were analyzed using an electron microscope (e.g., tescan, using a BSE detector) using 30kV and appropriate magnification (30 x-1000 x).

2) 3D tomography

a) If desired, the sample is coated with a thin layer of contrast material. For example, when using 3D X radiography (Skyscan), the polyolefin is not well visible. For example, the sample may be metallized using gold (e.g., using an Au/Pd metallization apparatus SC 7640 sputter coater).

b) Placing the sample in an analysis chamber and scanning

3) 3D μCT-see "method of determining geometric fiber statistics for nonwoven Material"

All the above methods and analyses (except 3D muct) may be performed, for example, at the University of thomson, czochralski (University ofBat' a in ZlIgn) (CZ technical college).

The obtained cross-sectional pictures were then analyzed:

1) "inter-filament bond Density", "filament Density"

a) The fabric cross-section is divided into regular segments, where each segment represents a maximum of 0.05mm thickness (e.g., a 0.45mm thick fabric is divided into 9 0.05mm thick segments).

b) Each segment has a length of at least 0.5mm, preferably a length visible on a cross-sectional picture

c) Set density

i) Calculating the number of inter-filament bonds for each segment and expressing as the density of inter-filament bonds (number of bonds/segment area); or (b)

ii) the area occupied by filaments in each segment is calculated and expressed as filament density (area occupied by filaments/segment area)

d) Segments adjacent to each other that provide the same or very similar densities may be joined together to form a hierarchy

e) Layer a, layer B and possibly layer C are indicated and their average values are calculated.

f) Calculating the value of the ratio

2) "length and height of cavity" and "% of cavity in nonwoven thickness"

a) Taking the above-determined hierarchical structure and further researching the region of hierarchy B

b) Void volume areas are highlighted

c) Marking a cavity (if the area within the thickness of the fabric (z-direction of the fabric) is greater than 3 times the average filament thickness and its length (MD CD plane direction of the fabric) is greater than 5 times the average filament thickness) is considered a cavity

d) The area of all cavities was calculated and expressed as%of the area of layer B

e) Each cavity was measured in the height = fabric thickness direction and its length = MD x CD plane direction of the fabric, and the maximum value was used to calculate the L: H ratio

Method for determining the geometry of a nonwoven fabric "

Hereinafter, we describe a software-based method for analyzing nonwoven samples to characterize their geometric properties. The method uses a machine learning method to identify individual fibers present in a sample, and then performs a geometric analysis on these fibers to obtain statistics suitable for characterizing the material. The results included the orientation and density distribution of the fibers. The analytical workflow was developed by Math2Market GmbH, which is part of the GeoDict digital materials laboratory.

Step 1: obtaining a three-dimensional μCT image of a sample

First, nonwoven samples were digitized using a μct scanner to obtain 3D images. The 3D image consists of a uniform cartesian grid, wherein each grid cell (volume element: voxel) stores the X-ray attenuation of the sample at a corresponding location. The pore space typically exhibits the lowest attenuation (minimum gray level value) while the material phase exhibits a larger value, depending on the material and the configuration of the μct apparatus.

Step 2: fragment μCT images separating material from pore space

For further analysis, the gray scale image is noise filtered using a non-local mean approach [1]. It is then binarized using a global threshold derived using the Otsu algorithm [2]. Binarization classifies each image voxel as containing either pore space or fibrous material. Voxels with gray values below the threshold are classified as hole spaces. All other voxels are classified as fibrous material. For both noise filtering and thresholding, the inportgeo module of geodic software is used.

Step 3: analysis of material Density distribution

Further, the material density distribution in the z direction was calculated. For each slice of the image (at a given depth Z), the material density is calculated as the number of white material voxels divided by the number of total voxels in the slice. The analysis was performed using a geodct matdic module.

Step 4: using neural networks to identify fiber centerlines

The main challenge in identifying individual fibers in a μct image is that after binarization, the fibers are not spatially separated at the point of contact. This may result in a hyposegmentation in which multiple objects (fibers) are incorrectly classified as single fibers.

To separate the fibers, math2Market GmbH has developed a method of identifying the centerline curve of the fiber. These centerlines are represented in a binary voxel image of the same size as the original image. In this image, voxels within about 1 to 2 voxels of the center of the fiber are labeled.

For this purpose we have used a semantic segmentation method using neural networks [3]. The image is analyzed by considering a 3D sliding input window that moves over the image. For each input window, a smaller output window centered on the input window is defined. The neural network analyzes the binary voxel values in the input window and generates a prediction for each voxel of the output window. The predictor determines whether a voxel within the output window is part of a centerline. By combining the results of all these output windows we obtain a binary image classifying each voxel of material in the original image. The image transformation is implemented by the FiberFind-AI module in geodicot using Tensorflow [4].

Step 5: creating training data for neural networks

To train the neural network to achieve the above transformation, the Math2Market GmbH has created artificial 3D images of several nonwoven materials using a random fiber Geo structure generation module in GeoDict. The module generates an analytical geometric representation of the fiber as a series of line segments. Meanwhile, the method outputs a binary image of the fiber structure, which is equivalent to the binarization result of the step 2.

By modifying the fiber diameter in the analytical expression to about 2 to 3 voxels, we can also obtain an image corresponding to the centerline of the rayon structure.

These image pairs (fiber and centerline) are then used to train the neural network to transform the fiber image into a centerline image. The network effectively learns to "shrink" the fibers to their centerline curves.

Step 6: tracking fiber centerlines for obtaining geometric representations of fibers

After reducing the fibers to their centerline, we assume that the centerlines do not touch. Then, the individual centerlines are separated from each other by analyzing the connected components of the centerline image, assuming each component corresponds to the centerline of an individual fiber. The connected components are defined as a subset of material voxels, which all have the same color and cannot be enlarged by adding any contact voxels of the same color.

For each centerline we trace the curve through the voxel group to obtain a geometric representation of the corresponding fiber in the form of a sequence of connected line segments (polylines). This step is also part of the FiberFind-AI in geodicot.

A digital 3D model of the fabric is thus obtained, examples of which can be seen in fig. 44 to 46, including layered structures.

Step 7: computational analysis of samples

To obtain the "inter-filament bond density", "filament density", "length and height of the cavity" and "percent of cavity in nonwoven thickness", each cross-sectional filament segment was projected into a plane, divided into sub-segments (each thickness of 0.05mm max) and analyzed. The values between the segments are compared and, if possible, segments adjacent to each other with the same or similar results may be incorporated into the hierarchy. The tiers A, B and possible C are indicated and the values for each tier are averaged by the segment data.

[1]Buades,Antoni,Bartomeu Coll,and J-M.Morel."A non-local algorithm for image denoising."Computer Vision and Pattern Recognition,2005.CVPR 2005.IEEE Computer Society Conference on.Vol.2.IEEE,2005。

[2]Otsu,Nobuyuki."A threshold selection method from gray-level histograms."IEEE transactions on systems,man,and cybernetics 9.1(1979):62-66。

[3]Noh,Hyeonwoo,Seunghoon Hong,and Bohyung Han."Learning deconvolution network for semantic segmentation."Proceedings of the IEEE international conference on computer vision.2015。

[4]Martín Abadi,Ashish Agarwal,Paul Barham,Eugene Brevdo,Zhifeng Chen,Craig Citro,Greg S.Corrado,Andy Davis,Jeffrey Dean,Matthieu Devin,Sanjay Ghemawat,Ian Goodfellow,Andrew Harp,Geoffrey Irving,Michael Isard,Rafal Jozefowicz,Yangqing Jia,Lukasz Kaiser,Manjunath Kudlur,Josh Levenberg,Dan Mané,Mike Schuster,Rajat Monga,Sherry Moore,Derek Murray,Chris Olah,Jonathon Shlens,Benoit Steiner,Ilya Sutskever,Kunal Talwar,Paul Tucker,Vincent Vanhoucke,Vijay Vasudevan,Fernanda Viégas,Oriol Vinyals,Pete Warden,Martin Wattenberg,Martin Wicke,Yuan Yu,and Xiaoqiang Zheng."TensorFlow:Large-scale machine learning on heterogeneous systems",2015.Software available from tensorflow.org。

Industrial applicability

The present invention is applicable wherever a balanced softness/durability of a lofty nonwoven web is desired, for example in the hygiene industry as various components of absorbent hygiene products (e.g., baby diapers, incontinence products, feminine hygiene products, changing pads, etc.), or in the healthcare field, for example as part of wound sponges and/or protective garments, surgical drapes, liners, and other barrier material products. Other uses are also available for industrial applications, for example as part of protective apparel, for filtration, insulation, packaging, sound absorption, footwear industry, automotive, furniture, and the like. The invention is particularly advantageous in applications where it is desirable to increase the bulk, compressibility, and recovery of the fabric in combination with the need for endless fibers.

Claims

1. A nonwoven fabric comprising a plurality of filament layers, wherein the fabric comprises

-a first layer (a) forming a first outer surface of the nonwoven fabric and comprising continuous multicomponent filaments comprising a first component which

Along the longitudinal extension of the filaments,

forming at least 20% of the surface area of the filaments,

-forming filament-to-filament bonds within the first layer (a), and

-a second layer (B) comprising continuous multicomponent filaments comprising a first component, said first component

Along the longitudinal extension of the filaments,

forming at least 20% of the surface area of the filaments,

-forming filament-to-filament bonds within the second layer (B), and

-wherein the bulk of the fabric is lower than 60kg/m ³ 。

2. The nonwoven fabric of claim 1 wherein the fabric comprises a third layer (C) forming a second outer surface of the nonwoven fabric such that the second layer (B) is positioned between the first layer (a) forming the first outer surface of the nonwoven fabric and the third layer (C) forming the second outer surface of the nonwoven fabric, and the third layer (C) comprises continuous multicomponent filaments comprising a first component that is

Along the longitudinal extension of the filaments,

forming at least 20% of the surface of the filaments,

-forming filament-to-filament bonds within the third layer (C), and

-having a melting point at least 5 ℃ lower than the melting point of the other components of the filaments of the third layer (C).

3. The nonwoven fabric according to any one of the preceding claims, wherein the ratio of the filament density of the first layer (a) to the filament density of the second layer (B) is at least 1.5; more preferably at least 2.0; more preferably at least 2.5; more preferably at least 3, even more preferably at least 5.

4. The nonwoven fabric according to any of the preceding claims, wherein the ratio of the filament density of the third layer (C) to the filament density of the second layer (B) is at least 1.5; more preferably at least 2.0; more preferably at least 2.5; more preferably at least 3, even more preferably at least 5.

5. The nonwoven fabric according to any one of the preceding claims, wherein the ratio of the inter-filament bond density of the first layer (a) to the inter-filament bond density of the second layer (B) is at least 2; more preferably at least 3.0; more preferably at least 4; more preferably at least 5, even more preferably at least 7.

6. The nonwoven fabric according to any one of the preceding claims, wherein the ratio of the inter-filament bond density of the third layer (C) to the inter-filament bond density of the second layer (B) is at least 2; more preferably at least 3.0; more preferably at least 4; more preferably at least 5, even more preferably at least 7.

7. The nonwoven fabric according to any one of the preceding claims, wherein the second layer (B) comprises cavities, wherein the cavities have a length extending along a plane defined by the machine direction and the cross-machine direction and a height extending perpendicular to the plane, wherein the ratio of the length to the height of at least some of the cavities is at least 3:1, preferably 5:1 and most preferably 10:1.

8. The nonwoven fabric according to claim 7, wherein the height of the cavity forms at least 15% of the thickness of the nonwoven fabric, more preferably at least 20% of the thickness of the nonwoven fabric.

9. The nonwoven fabric according to any of the preceding claims, wherein the second layer (B) comprises cavities, wherein the cavities have a length extending along a plane defined by a machine direction and a cross direction, and the nonwoven fabric has a thickness extending perpendicular to the plane, wherein for at least some of the cavities the ratio of the length of the cavities to the thickness of the nonwoven fabric is at least 3:1, preferably at least 5:1, and most preferably at least 10:1.

10. The nonwoven fabric according to any one of the preceding claims, wherein the fabric comprises filaments having a crimpable cross-section.

11. The nonwoven fabric according to any one of claims 1 to 9, wherein the fabric comprises filaments having a non-crimpable cross-section, the filaments comprising a shrinkable polymer.

12. The nonwoven fabric according to any of the preceding claims, wherein the first component of the first layer (a) and/or the first component of the second layer (B) comprises a binding polymer selected from a polyolefin, an aliphatic polyester, an aromatic polyester or a copolymer thereof.

13. The nonwoven fabric according to any of the preceding claims, wherein the first component of the first layer (a) and/or the first component of the second layer (B) comprises a binding polymer selected from polypropylene, polyethylene, polylactic acid (PLA), polyethylene terephthalate (PET) or copolymers thereof (coPLA, coPET, coPP, coPE).

14. The nonwoven fabric according to any of the preceding claims, wherein the other component of the first layer (a) and/or the other component of the second layer (B) comprises a polymer selected from a polyolefin, an aliphatic polyester, an aromatic polyester or a copolymer thereof.

15. The nonwoven fabric according to any of the preceding claims, wherein the other component of the first layer (a) and/or the other component of the second layer (B) comprises a polymer selected from polypropylene, polyethylene, polylactic acid (PLA), polyethylene terephthalate (PET) or copolymers thereof (copa, coPET).

16. The nonwoven fabric according to any of the preceding claims, wherein at least 65% by weight of the filaments of the first layer (a) and/or the filaments of the second layer (B) consist of one or more polyolefin polymers.

17. The nonwoven fabric according to any one of claims 1 to 15, wherein at least one of the filament components comprises at least 65 wt% polyester polymer.

18. The nonwoven fabric according to any of the preceding claims, wherein

a. The continuous filaments are bicomponent, and

b. the first component comprises a polyolefin, preferably polyethylene, and

c. the other component comprises a polyolefin, preferably polypropylene.

19. The nonwoven fabric according to any one of claims 1 to 15, wherein

a. The continuous filaments are bicomponent, and

b. the first component comprises a polyolefin, preferably polyethylene or polypropylene, and

c. other components include polyesters, preferably polylactic acid (PLA), polyethylene terephthalate (PET) or their copolymers (coPLA, coPET).

20. The nonwoven fabric according to any one of claims 1 to 15, wherein

a. The continuous filaments are bicomponent, and

b. The first component comprises a polyester, preferably polylactic acid (PLA), polyethylene terephthalate (PET) or a copolymer thereof (coPLA, coPET), and

c. the other components include polyesters, preferably polylactic acid (PLA), polyethylene terephthalate (PET) or their copolymers (copa, coPET).

21. The nonwoven fabric according to any of the preceding claims, wherein the fabric delamination strength is equal to or higher than 0.5N, preferably higher than 0.6N, more preferably higher than 0.7N, and most preferably higher than 0.8N.

22. The nonwoven fabric according to any of the preceding claims, wherein the fabric delamination strength is equal to or lower than 10.0N, preferably equal to or lower than 8.0N, more preferably equal to or lower than 6.0N, advantageously equal to or lower than 4.0N.

23. The nonwoven fabric according to any one of the preceding claims, wherein the fabric comprises filaments of at least a first layer (i) and a second layer (ii).

24. The nonwoven fabric of claim 23, wherein at least one layer of the nonwoven fabric comprises at least 2 layers.

25. The nonwoven fabric according to claim 23 or 24, wherein the first layer (i) comprises at least the first layer (a).

26. The nonwoven fabric according to any one of claims 23 to 25, wherein the filaments in all the layers of a layer comprise the same components arranged in the same manner over the filament cross-section.

27. The nonwoven fabric according to any one of claims 23 to 26, wherein the filaments in the first layer and the filaments in the second layer are different in at least one of: at least one of the components, the arrangement of the components over the cross section, the median fiber diameter.

28. The nonwoven fabric according to any one of claims 23 to 27, wherein the first layer (i) comprises bicomponent filaments having a concentric core/sheath structure or an eccentric core/sheath structure.

29. The nonwoven fabric according to any one of claims 23 to 28, wherein the second layer (ii) comprises bicomponent filaments having a side/side structure or an eccentric core/sheath structure.

30. The nonwoven fabric according to claim 28 or 29, wherein the core of the bicomponent filaments of the first layer (i) comprises polypropylene or a polypropylene blend and/or the core component or one side component of the bicomponent filaments of the second layer (ii) comprises polypropylene or a polypropylene blend.

31. The nonwoven fabric of claim 30, wherein the sheath of the bicomponent filaments of the first layer (i) comprises polyethylene or a polyethylene blend and the sheath component or side component of the bicomponent filaments of the second layer (ii) comprises polyethylene or a polyethylene blend.

32. The nonwoven fabric of claim 31, wherein the melt flow rate of the polyethylene or polyethylene blend in the sheath of the bicomponent filaments of the first layer (i) is higher than the melt flow rate of the polyethylene or polyethylene blend of the bicomponent filaments of the second layer (ii).

33. The nonwoven fabric of claim 31, wherein the sheath of bicomponent filaments of the first layer (i) forms 30 to 45 weight percent of the filaments and the polyethylene or polyethylene blend of bicomponent filaments of the second layer (ii) forms 30 to 55 weight percent of the filaments.

34. The nonwoven fabric according to any one of claims 23 to 33, wherein

-the filaments of the first layer (i) have a median fiber diameter of 10 to 17 microns, more preferably 13 to 14 microns, and/or

-the filaments of the second layer (ii) have a median fiber diameter of 15 to 22 microns, more preferably 18 to 19 microns, and/or

The filaments of the first layer (i) have a lower median fiber diameter than the filaments of the second layer (ii).

35. An absorbent hygiene product comprising the nonwoven fabric according to any of the preceding claims.

36. A method of making a nonwoven fabric comprising the steps of

a) Melting

a. At least a first polymeric material forming a first component, and

b. forming a second polymeric material of at least one other component and having a lower melting point than the first polymeric material (A), and

b) The molten polymeric material is fed to and extruded through a nozzle of a manifold,

a. endless filaments are formed from the molten polymeric material exiting the nozzle,

b. wherein the first polymeric material extends in the longitudinal direction of the filaments and forms at least a portion of the surface of the filaments, an

c) Cooling the formed filaments by a fluid medium having a temperature of 10 ℃ to 90 ℃ and stretching the filaments at a draw ratio of 200 to 1300 to achieve a semi-stable crystalline state of at least the second polymeric material, an

d) Randomly laying the filaments on a forming belt to form a nonwoven filament batt, an

e) Pre-consolidating the nonwoven filament batt by heat flow for a period of 1ms to 10000ms, an

f) Preheating the filament batt by a heat flow having a temperature of 5 ℃ to 20 ℃ below the melting temperature of the first polymeric material, preferably at a temperature of 5 ℃ to 15 ℃ below the melting temperature of the first polymeric material, more preferably at a temperature of 5 ℃ to 10 ℃ below the melting temperature of the first polymeric material, and

g) Consolidating the filament batt by a heat flow having a temperature not more than 5 ℃ lower than the melting temperature of the first polymeric material and not more than 3 ℃ higher than the melting temperature of the first polymeric material, and cooling the thus consolidated filament batt by an air flow having a temperature of 10 ℃ to 40 ℃, preferably 20 ℃ to 30 ℃.

37. The method of making a nonwoven fabric according to claim 36, wherein an intermediate cooling is performed between the pre-consolidation step e) and the pre-heating step f).

38. The method of making a nonwoven fabric according to claim 37, wherein the intermediate cooling is performed by exposing the pre-consolidated batt to air.

39. The method of manufacturing a nonwoven fabric according to claim 37 or 38, wherein the intermediate cooling is performed by air having a temperature equal to or lower than 70 ℃, preferably equal to or lower than 60 ℃, most preferably equal to or lower than 55 ℃.

40. The method of making a nonwoven fabric according to any one of claims 37-39, wherein the intermediate cooling is performed by exposing the pre-consolidated batt to ambient air.

41. The method of making a nonwoven fabric according to any one of claims 36-40, wherein during consolidation of the batt in step g), the heat flow is applied from alternating directions such that it enters the batt from one side of the batt and then enters the batt from the other side of the batt.

42. The method of manufacturing a nonwoven fabric according to any one of claims 36 to 41, wherein the heat flow in step e) and/or step f and/or step g) is provided by hot air.

43. The method of making a nonwoven fabric according to any one of claims 36-42, wherein no additional tension is applied to the batt during the preheating in step f).

44. The method of manufacturing a nonwoven fabric according to any one of claims 36 to 43, wherein during the preheating in step f) the filament batt reaches a temperature of 10 ℃ to 40 ℃, preferably 20 ℃ to 30 ℃.

45. The method of making a nonwoven fabric according to any one of claims 36-44, wherein at least a portion of step f) and/or step h) is performed by guiding the batt along a drum of an air-through consolidation device.

46. The method of making a nonwoven fabric according to any one of claims 36-45, wherein at least a portion of step f) and/or step h) is performed by directing the batt through a flat bed oven consolidation device.

47. The method for producing a nonwoven fabric according to any one of claims 36 to 46, wherein during the pre-consolidation step e), the pre-consolidation air velocity is set at 0.1m/s to 10m/s, preferably 0.8m/s to 4m/s.

48. The method for producing a nonwoven fabric according to any one of claims 36 to 47, wherein during the pre-consolidation step e) the pre-consolidation air temperature is 80 ℃ to 200 ℃, preferably 100 ℃ to 180 ℃.

49. The method for producing a nonwoven fabric according to any one of claims 36 to 48, wherein during the pre-consolidation step e) the pre-consolidation air temperature is from 90 ℃ to 150 ℃, preferably from 110 ℃ to 140 ℃.

50. The method of manufacturing a nonwoven fabric according to any one of claims 36 to 49, wherein during the pre-consolidation in step e), the filament batt is exposed to the heat flow using air for a time of 2ms to 1000ms and most preferably 4ms to 200 ms.

51. The method of manufacturing a nonwoven fabric according to any one of claims 36 to 50, wherein during step g), step h), step i) are performed in different sections, preferably combined into one unit.