CN115024542A - Amphibious intelligent data glove and preparation method thereof - Google Patents
Amphibious intelligent data glove and preparation method thereof Download PDFInfo
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01505—Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01576—Protective gloves made of a patchwork of different materials
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
- A41D19/01594—Protective gloves with accessories, e.g. tools, receptacles
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/02—Layered materials
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/10—Impermeable to liquids, e.g. waterproof; Liquid-repellent
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/24—Resistant to mechanical stress, e.g. pierce-proof
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41H—APPLIANCES OR METHODS FOR MAKING CLOTHES, e.g. FOR DRESS-MAKING OR FOR TAILORING, NOT OTHERWISE PROVIDED FOR
- A41H43/00—Other methods, machines or appliances
- A41H43/02—Handling garment parts or blanks, e.g. feeding, piling, separating or reversing
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B7/00—Measuring arrangements characterised by the use of electric or magnetic techniques
- G01B7/16—Measuring arrangements characterised by the use of electric or magnetic techniques for measuring the deformation in a solid, e.g. by resistance strain gauge
- G01B7/18—Measuring arrangements characterised by the use of electric or magnetic techniques for measuring the deformation in a solid, e.g. by resistance strain gauge using change in resistance
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D2600/00—Uses of garments specially adapted for specific purposes
- A41D2600/20—Uses of garments specially adapted for specific purposes for working activities
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
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Abstract
The invention discloses an amphibious intelligent data glove and a preparation method thereof, wherein the amphibious intelligent data glove comprises a glove body, a soft plate and conductive fibers; the soft board and the conductive fibers are positioned on the back of the glove body and are connected through conductive wires; the conductive fibers are positioned at the positions of the five fingers of the glove body and arranged along the directions of the five fingers, and when the conductive fibers are bent, the resistance of the conductive fibers is increased along with the bending; the flexible board is used for collecting the conductive fiber resistance and wirelessly transmitting data to the data processing terminal. The amphibious intelligent data glove can work normally under water environment and air, and has high sensitivity, stability and mechanical robustness.
Description
Technical Field
The invention belongs to the field of intelligent equipment, and particularly relates to amphibious intelligent data gloves and a preparation method thereof.
Background
Under the influence of new crown epidemics, direct physical interaction between people is limited to prevent the spread of viruses, creating the need for non-contact control and mutual explosiveness. Thanks to artificial intelligence AI and 5G technologies, artificial intelligence oriented human machine interfaces (hmi) provide a human with the ability to remotely data with a machine or other people. Generally speaking, the hmi is a multifunctional electromechanical system that collects and transmits human motion information to a central processing unit, and the machine will then perform the appropriate function corresponding to the instruction.
The machine vision-based method is an important approach for acquiring human physiological information, but the key point is a proper optical environment. On one hand, the real-time recognition of the fine movements of the fingers is difficult to realize due to the shielding and shadowing effects of light, and on the other hand, the realization and operation of the system is costly and consumes much power. More importantly, in a water environment, machine vision based hand decoding does not perform well due to poor system water resistance and poor water transparency.
The wearable electronic device can directly acquire in situ characterization somatosensory signals which are insensitive to environmental conditions, wherein the sensor-based data glove is a perfect carrier for realizing hmi. At present, many strain sensors based on liquid metals, conductive polymers and triboelectric materials have been reported, but some problems are faced with devices that are incorporated into textile and hybrid power systems: 1) for liquid metal based strain sensors, low initial resistance (a few ohms) and relatively low specification current usually require large supply current, resulting in large working power and even system working failure; the problem of connecting liquid metal to metal electrodes is challenging due to the phenomenon of alloying liquid metal with most metals. 2) Liquid metal-based or triboelectric strain sensors have low sensitivity and often require a back-end amplifier to amplify the electrical signal corresponding to the strain change, increasing the complexity of the system. 3) The compatibility of the polymer strain sensor and the textile is poor, the processing difficulty of the sensing module part is large, and the air permeability of the textile is seriously influenced.
Meanwhile, considering that the environment in daily activities is complex and unstable, such as raining, sweating, accidental falling into rivers and the like, the wearable fiber is difficult to avoid contacting with moisture, such as water, sweat and the like, and suffers unpredictable mechanical deformation and even damage. Therefore, not only high sensitivity but also water resistance and mechanical robustness are required for smart fibers. Encapsulation is a simple but effective way to increase mechanical robustness and water resistance compared to chemical modification, providing additional protection of the internal functional material from external physical or chemical damage.
Disclosure of Invention
The invention aims to: in order to overcome the defects in the prior art, the invention aims to provide the high-sensitivity and stable amphibious intelligent data glove which can ensure normal work under the water environment and in the air, and the invention also aims to provide the preparation method of the high-sensitivity and stable amphibious intelligent data glove.
The technical scheme is as follows: an amphibious intelligent data glove comprises a glove body, a soft plate and conductive fibers; the soft board and the conductive fibers are both positioned on the back of the glove body and are connected through conductive wires; the conductive fibers are positioned at the positions of the five fingers of the glove body and arranged along the directions of the five fingers, and when the conductive fibers are bent, the resistance of the conductive fibers is increased along with the bending; the flexible board is used for collecting the conductive fiber resistance and wirelessly transmitting data to the data processing terminal. When the five fingers are bent, the resistance of the conductive fibers is changed, and the electric signals collected by the soft board are also changed, so that the action of which finger is acted can be judged.
Furthermore, the connection point of the conductive wire and the flexible board is coated with conductive silver paste for fixation, and the conductive silver paste is coated with packaging material for packaging.
Furthermore, the conductive fibers are provided with five sections which are respectively fixed on the thumb, the index finger, the middle finger, the ring finger and the little finger of the glove body and cover the second knuckle position of the finger on each glove body.
Furthermore, the conductive fiber adopts a three-layer core-shell structure and comprises a fiber base body, and an adhesive material layer, a conductive layer and a packaging material layer which are sequentially covered on the fiber base body. The thickness of the conductive layer is 10-30 μm, and the thickness of the packaging material layer is 20-60 μm. The fiber matrix is any one of spandex, terylene, chinlon, acrylic fiber, polyvinyl chloride fiber, vinylon and polyolefin stretch yarn; the viscous material layer is any one of modified polyvinyl alcohol, epoxy resin, polyvinyl chloride and acrylic structural adhesive with viscosity; the conducting layer is any one of MXene, graphene, carbon nano tube, carbon black and silver nano wire. The packaging material layer is any one of polydimethylsiloxane PDMS, polyvinyl alcohol and silica gel.
The invention discloses a preparation method of an amphibious intelligent data glove, which comprises the following steps:
Step 1.1, weaving a plurality of fiber wires into a braid shape to form a fiber matrix, fixing two ends of the fiber matrix, and uniformly coating adhesive material gel on the fiber matrix;
step 1.2, coating a conductive material on the viscous material to form a strain sensing layer, namely a conductive layer, attaching conductive wires to two ends of spandex by conductive silver paste and connecting the conductive wires with the conductive layer, wherein the conductive wires are used for leading out electric signals of the conductive layer;
specifically, an MXene conductive material can be coated on a polyvinyl alcohol adhesive material to form an MXene strain sensing layer;
step 1.3, brushing the packaging material spin coating agent on the surface of the conductive layer by using a brush, and curing to form a packaging material layer; obtaining conductive fibers with conductive wires;
and 4, packaging the soft plate and the interface of the soft plate and the electric lead by using a packaging material to obtain the amphibious intelligent data glove.
Specifically, a PDMS spin coating agent is adopted to encapsulate the soft board and the interface of the soft board and the conducting wire;
the PDMS spin coating agent is prepared by the following method: weighing 1-5 parts of PDMS prepolymer and 0.1-0.5 part of PDMS curing agent, mixing, dripping 0.01-0.1 part of n-hexane, stirring for 3-10 min, placing the mixed PDMS solution in a vacuum drying furnace, exhausting at room temperature, and maintaining the vacuum environment for 5-20 min to obtain the PDMS spin coating agent.
The working principle is as follows: we propose an amphibious intelligent data glove based on reliable and waterproof intelligent fibers, which adopts MXene conductive material adhered to spandex yarn by polyvinyl alcohol as a sensing layer, and pours, cures and encapsulates by using PDMS. This strategy enables MXene functional layers with high adhesion and stability, thus increasing mechanical and electrical robustness. Compared with the common intelligent data gloves, the amphibious intelligent data gloves packaged by PDMS have better electric circulation stability and long-term operation stability in water, sweat and physiological saline environments.
Has the beneficial effects that: compared with the prior art, the invention has the following remarkable characteristics:
1. the packaging method is adopted, so that the mechanical firmness and the water resistance are improved simply and effectively, and the additional protection is provided for the internal functional material to prevent the external physical or chemical damage;
2. three spandex threads are woven into a braid shape, so that the contact area with the modified polyvinyl alcohol can be greatly increased;
3. MXene is selected as a strain sensing layer, and can form good binding force and large contact area with adhesive polyvinyl alcohol, so that the conductive fiber has good sensitivity performance;
4. the preparation method has good controllability, adopts a layered manufacturing method, is beneficial to large-scale production, prepares the glove layer, the conductive fiber, the flexible sheet layer and the packaging material layer respectively without mutual influence, can correct problems in the preparation process independently, and saves cost.
Drawings
FIG. 1 is a schematic structural view of the present invention;
FIG. 2 is a schematic structural view of the conductive fiber of the present invention;
FIG. 3 is a flow chart of the preparation of the conductive fiber of the present invention;
FIG. 4 is an optical image of a conductive fiber of the present invention;
FIG. 5 is a gesture detection signal for a data glove of the present invention;
wherein, 1, conductive fiber; 2. a conductive wire; 3. a soft board; 4. a lithium battery.
Detailed Description
The invention discloses an amphibious intelligent data glove, which is shown in figure 1 and comprises a glove body, a soft plate 3 and conductive fibers 1; the soft board 3 and the conductive fiber 1 are positioned on the back of the glove body, and the back of the glove body is the back corresponding face of the hand when the glove is worn. The soft board 3 is connected with the conductive fiber 1 through a silver conductive wire 2; the silver conductive wire 2 is sewn at the connecting point of the soft board 3 and then is bonded and fixed by conductive silver paste, and the conductive silver paste is covered by PDMS packaging material for packaging and fixing, so that the robustness and the water resistance of the system are improved.
Specifically, the conductive fiber 1 is provided with five sections which are respectively positioned at the positions of five fingers of the glove body, when the conductive fiber 1 is bent, the resistance of the conductive fiber 1 is increased along with the bending of the fingers, and the conductive fiber 1 is used for representing the bending of the fingers; the flexible board 3 is used for collecting the resistance of the conductive fiber 1 and transmitting the resistance to the data processing terminal in a wireless mode.
The conductive fiber 1 adopts a three-layer core-shell structure, and as shown in fig. 2, comprises a fiber base body, and an adhesive material layer, a conductive layer and a packaging material layer which are sequentially covered on the fiber base body;
the fiber matrix is spandex, and can also be any one of terylene, chinlon, acrylic fiber, polyvinyl fiber, and polyolefin stretch yarn. The viscous material layer is modified polyvinyl alcohol with viscosity, and can be any one of epoxy resin, polyvinyl chloride and acrylic structural adhesive. The conducting layer is MXene, and can be any one of graphene, carbon nano tubes, carbon black and silver nanowires. The packaging layer is polydimethylsiloxane PDMS, and can also be any one of polyvinyl alcohol and silica gel.
The preparation method of the amphibious intelligent data glove disclosed by the invention is shown in figure 3 and comprises the following steps of:
Step 1.1, weaving three spandex threads into a braid shape, fixing two ends of the braid on a workbench through a double-sided adhesive tape, and uniformly coating polyvinyl alcohol gel on spandex, wherein the process is repeated for 3 times;
step 1.2, coating MXene on polyvinyl alcohol gel through a brush to form a strain sensing layer with the thickness of 10-30 microns, namely a conductive layer, attaching silver conductive wires 2 to two ends of spandex through conductive silver paste, connecting the conductive wires with the conductive layer, leading out electric signals of the conductive layer, and curing for 2-8 hours at 40 ℃;
step 1.3, brushing the PDMS spin coating agent on the surface of MXene by using a brush to form a packaging layer with the thickness of 20-60 mu m, and curing for 1-2h at 80 ℃; obtaining a conductive fiber 1 with a silver conductive wire 2, as shown in fig. 4;
fixing a flexible board 3 on the back of the glove layer, wherein the flexible board 3 has data conversion and wireless transmission functions and comprises an nRF52832 Bluetooth chip and a lithium battery 4, and the lithium battery 4 is used for supplying power to the flexible board 3;
and 4, coating the PDMS spin coating agent at the interface of the soft plate 3 and the silver conductive wire 2 and on the lithium battery 4 for packaging. And then, the system is placed on a heating table, and is cured for 1-2 hours at the temperature of 100 ℃ to obtain the amphibious intelligent data glove.
The PDMS spin coating is prepared by the following method: weighing 1-5 parts of PDMS prepolymer and 0.1-0.5 part of PDMS curing agent, mixing, dripping 0.01-0.1 part of n-hexane, stirring for 3-10 min, placing the mixed PDMS solution in a vacuum drying furnace, exhausting at room temperature, and maintaining the vacuum environment for 5-20 min to obtain the PDMS spin coating agent.
As shown in fig. 5, a resistance variation graph of each conductive fiber collected by the soft board when the glove of the present invention is worn and the four gestures "0", "2", "OK", and "I love you" are shown respectively.
In the following examples, the starting materials and the test apparatus were purchased and used as they were. The curing agent is tetramethyl tetravinylcyclotetrasiloxane.
Example 1
Respectively weighing 1 part of PDMS prepolymer, 0.1 part of curing agent and 0.01 part of normal hexane by using an electronic balance, mixing the PDMS prepolymer and the tetramethyltetravinylcyclotetrasiloxane curing agent, dripping the normal hexane, stirring for 3min, placing the mixed PDMS solution in a vacuum drying furnace, exhausting air at room temperature, and keeping a vacuum environment for 5min to obtain a PDMS spin-coating agent;
weaving three spandex threads into a braid shape, fixing two ends of the braid onto a self-made workbench through a double-sided adhesive tape, uniformly coating polyvinyl alcohol glue on the spandex, and repeating the process for 3 times;
coating MXene on polyvinyl alcohol gel by a brush to form a strain sensing layer with the thickness of 10 mu m, then attaching silver conductive wires 2 to two ends of spandex by conductive silver paste, and curing for 2h at 40 ℃; then brushing the PDMS spin coating agent on the MXene surface by using a brush to form a packaging material layer with the thickness of 20 microns, and curing for 1h at the temperature of 80 ℃;
placing the self-made soft board 3 on the back of the glove body, placing the glove body on a heating table, curing the glove body for 1 hour at the temperature of 100 ℃, and fixing the conductive fibers 1 on second knuckles of a thumb, an index finger, a middle finger, a ring finger and a little finger; sewing the guide lines on the two sides of the spandex into the interface of the flexible printed circuit board 3, coating conductive silver paste on the joint, and curing for 2 hours at 40 ℃;
and coating a PDMS spin coating agent at the interface of the soft plate 3 and the silver conductive wire 2 and on the lithium battery 4 to form an encapsulation material layer. And then, the system is placed on a heating table and cured for 1h at 100 ℃ to obtain the amphibious intelligent data glove.
Example 2
Respectively weighing 3 parts of PDMS prepolymer, 0.3 part of curing agent and 0.05 part of normal hexane by using an electronic balance, mixing the PDMS prepolymer and the tetramethyltetravinylcyclotetrasiloxane curing agent, dripping the normal hexane, stirring for 6min, placing the mixed PDMS solution in a vacuum drying furnace, exhausting air at room temperature, and keeping a vacuum environment for 12min to obtain a PDMS spin-coating agent;
weaving 3 spandex threads into a braid shape, connecting the braid shape to a self-made plastic bracket through a double-sided adhesive tape, and coating polyvinyl alcohol gel on the spandex on the other side, wherein the process is repeated for 3 times; coating MXene on polyvinyl alcohol gel by a brush to form a strain sensing layer with the thickness of 20 microns, attaching silver conductive wires 2 to two ends of spandex by conductive silver paste, and curing for 4 hours at 40 ℃; then brushing the PDMS spin coating agent on the MXene surface by using a brush to form a packaging material layer with the thickness of 30 microns, and curing for 1.5h at the temperature of 80 ℃;
fixing the conductive fiber 1 on the second knuckles of the thumb, the index finger, the middle finger, the ring finger and the little finger; sewing the guide lines on the two sides of the spandex into the interface of the flexible printed circuit board 3, coating conductive silver paste on the joint, and curing for 4 hours at 40 ℃; the soft plate 3 is placed on the back of the glove layer, and the PDMS spin coating agent is coated at the interface of the soft plate 3 and the silver conductive wire 2 and on the lithium battery 4 to form an encapsulation material layer. And then, the system is placed on a heating table, and is cured for 1.5 hours at the temperature of 100 ℃ to obtain the amphibious intelligent data glove.
Example 3
Respectively weighing 5 parts of PDMS prepolymer, 0.5 part of curing agent and 0.1 part of normal hexane by using an electronic balance, mixing the PDMS prepolymer and the tetramethyltetravinylcyclotetrasiloxane curing agent, dripping the normal hexane, stirring for 10min, placing the mixed PDMS solution in a vacuum drying furnace, exhausting air at room temperature, and keeping a vacuum environment for 20min to obtain a PDMS spin-coating agent; weaving 3 spandex threads into a braid shape, connecting the braid shape to a self-made plastic bracket through a double-sided adhesive tape, and coating polyvinyl alcohol gel on the spandex on the other side, wherein the process is repeated for 3 times; coating MXene on polyvinyl alcohol gel by a brush to form a strain sensing layer with the thickness of 30 mu m, then attaching silver conductive wires 2 to two ends of spandex by conductive silver paste, and curing for 8 hours at 40 ℃; then brushing the PDMS spin coating agent on the MXene surface by using a brush to form a packaging material layer with the thickness of 60 mu m, and curing for 2h at the temperature of 80 ℃;
fixing the conductive fiber 1 on the second knuckles of the thumb, the index finger, the middle finger, the ring finger and the little finger; sewing the guide lines on the two sides of the spandex into the interface of the flexible printed circuit board 3, coating conductive silver paste on the joint, and curing for 8 hours at 40 ℃; the soft plate 3 is placed on the back of the glove layer, and the PDMS spin coating agent is coated at the interface of the soft plate 3 and the silver conductive wire 2 and on the lithium battery 4 to form an encapsulation material layer. And then, the system is placed on a heating table and cured for 2 hours at 100 ℃ to obtain the amphibious intelligent data glove.
Example 4
Respectively weighing 4 parts of PDMS prepolymer, 0.4 part of curing agent and 0.08 part of normal hexane by using an electronic balance, mixing the PDMS prepolymer and the tetramethyltetravinylcyclotetrasiloxane curing agent, dripping the normal hexane, stirring for 7min, placing the mixed PDMS solution in a vacuum drying furnace, exhausting air at room temperature, and keeping a vacuum environment for 10min to obtain a PDMS spin-coating agent; weaving 3 spandex threads into a braid shape, connecting the braid shape to a self-made plastic bracket through a double-sided adhesive tape, and coating polyvinyl alcohol gel on the spandex on the other side, wherein the process is repeated for 3 times; coating graphene on polyvinyl alcohol gel through a brush to form a strain sensing layer with the thickness of 20 microns, then attaching silver conductive wires 2 to two ends of spandex through conductive silver paste, and curing for 4 hours at 40 ℃; then brushing PDMS spin coating agent on the surface of the graphene by using a brush to form a packaging material layer with the thickness of 40 microns, and curing for 2 hours at 80 ℃;
fixing the conductive fiber 1 on the second knuckles of the thumb, the index finger, the middle finger, the ring finger and the little finger; sewing guide lines on two sides of spandex into an interface of the flexible printed circuit board 3, coating conductive silver paste on the joint, and curing for 4 hours at 40 ℃; the soft plate 3 is placed on the back of the glove layer, and the PDMS spin coating agent is coated at the interface of the soft plate 3 and the silver conductive wire 2 and on the lithium battery 4 to form an encapsulation material layer. And then, the system is placed on a heating table and cured for 2 hours at the temperature of 100 ℃ to obtain the amphibious intelligent data glove.
Example 5
Respectively weighing 4 parts of PDMS prepolymer, 0.4 part of curing agent and 0.08 part of normal hexane by using an electronic balance, mixing the PDMS prepolymer and the tetramethyltetravinylcyclotetrasiloxane curing agent, dripping the normal hexane, stirring for 7min, placing the mixed PDMS solution in a vacuum drying furnace, exhausting air at room temperature, and keeping a vacuum environment for 10min to obtain a PDMS spin-coating agent; weaving 3 spandex threads into a braid shape, connecting the braid shape to a self-made plastic bracket through a double-sided adhesive tape, and coating polyvinyl alcohol gel on the spandex on the other side, wherein the process is repeated for 3 times; coating the carbon nano tube on polyvinyl alcohol gel through a brush to form a strain sensing layer with the thickness of 20 microns, then attaching silver conductive wires 2 to two ends of spandex through conductive silver paste, and curing for 4 hours at 40 ℃; then brushing the PDMS spin coating agent on the surface of the carbon nano tube by using a brush to form a packaging material layer with the thickness of 40 mu m, and curing for 2h at the temperature of 80 ℃;
fixing the conductive fiber 1 on the second knuckles of the thumb, the index finger, the middle finger, the ring finger and the little finger; sewing the guide lines on the two sides of the spandex into the interface of the flexible printed circuit board 3, coating conductive silver paste on the joint, and curing for 4 hours at 40 ℃; the soft plate 3 is placed on the back of the glove layer, and the PDMS spin coating agent is coated at the interface of the soft plate 3 and the silver conductive wire 2 and on the lithium battery 4 to form an encapsulation material layer. And then, the system is placed on a heating table and cured for 2 hours at the temperature of 100 ℃ to obtain the amphibious intelligent data glove.
Example 6
Respectively weighing 4 parts of PDMS prepolymer, 0.4 part of curing agent and 0.08 part of normal hexane by using an electronic balance, mixing the PDMS prepolymer and the tetramethyl tetravinylcyclotetrasiloxane curing agent, then dripping the normal hexane, stirring for 7min, then placing the mixed PDMS solution in a vacuum drying furnace, exhausting air at room temperature, and keeping a vacuum environment for 10min to obtain the PDMS spin-coating agent; weaving 3 polyolefin elastic yarns into a braid shape, connecting the braid shape to a self-made plastic bracket through a double-sided adhesive tape, coating polyvinyl alcohol gel on the polyolefin elastic yarns on the other side, and repeating the process for 3 times; coating MXene on polyvinyl alcohol gel by a brush to form a strain sensing layer with the thickness of 20 microns, attaching silver conductive wires 2 to two ends of a polyolefin elastic yarn by conductive silver paste, and curing for 4 hours at 40 ℃; then brushing PDMS spin coating agent on the surface of MXene by using a brush to form a packaging material layer with the thickness of 40 micrometers, and curing for 2 hours at 80 ℃;
fixing the conductive fiber 1 on the second knuckles of the thumb, the index finger, the middle finger, the ring finger and the little finger; sewing guide lines on two sides of the polyolefin elastic yarn into an interface of the soft board 3, coating conductive silver paste on a joint, and curing for 4 hours at 40 ℃; the soft plate 3 is placed on the back of the glove layer, and the PDMS spin coating agent is coated at the interface of the soft plate 3 and the silver conductive wire 2 and on the lithium battery 4 to form an encapsulation material layer. And then, the system is placed on a heating table and cured for 2 hours at the temperature of 100 ℃ to obtain the amphibious intelligent data glove.
Claims (9)
1. An amphibious intelligent data glove is characterized by comprising a glove body, a soft plate and conductive fibers;
the soft board and the conductive fibers are positioned on the back of the glove body and are connected through conductive wires;
the conductive fibers are positioned at the positions of the five fingers of the glove body and arranged along the directions of the five fingers, and when the conductive fibers are bent, the resistance of the conductive fibers is increased along with the bending;
the flexible board is used for collecting the conductive fiber resistance and wirelessly transmitting data to the data processing terminal.
2. The amphibious smart data glove of claim 1, wherein the connection point of the conductive wire and the flexible printed circuit board is fixed by coating conductive silver paste, and the conductive silver paste is encapsulated by coating an encapsulating material.
3. An amphibious intelligent data glove as claimed in claim 1, wherein the conductive fiber has five sections, and the five sections are respectively fixed on the thumb, index finger, middle finger, ring finger and little finger of the glove body and cover the second knuckle position of the finger on each glove body.
4. An amphibious intelligent data glove according to claim 1, wherein the conductive fiber is of a three-layer core-shell structure and comprises a fiber base body, and an adhesive material layer, a conductive layer and a packaging material layer which are sequentially covered on the fiber base body.
5. An amphibious intelligent data glove as defined in claim 4, wherein the fiber matrix is any one of spandex, terylene, chinlon, acrylic fiber, polyvinyl fiber, and polyolefin stretch yarn;
the viscous material layer is any one of modified polyvinyl alcohol, epoxy resin, polyvinyl chloride and acrylic structural adhesive with viscosity;
the conducting layer is any one of MXene, graphene, carbon nano tubes, carbon black and silver nanowires;
the packaging material layer is any one of polydimethylsiloxane PDMS, polyvinyl alcohol and silica gel.
6. The method for preparing an amphibious intelligent data glove according to claim 4, wherein the thickness of the conductive layer is 10-30 μm.
7. The method for preparing an amphibious intelligent data glove as defined in claim 4, wherein the thickness of the packaging material layer is 20-60 μm.
8. A method for preparing an amphibious intelligent data glove according to claim 1, comprising the steps of:
step one, preparing conductive fiber
Step 1.1, weaving a plurality of spandex fiber wires into a braid shape to form a fiber matrix, fixing two ends of the fiber matrix, and uniformly coating adhesive material gel on the fiber matrix;
step 1.2, coating a conductive material on the viscous material to form a strain sensing layer, namely a conductive layer, attaching conductive wires to two ends of spandex by conductive silver paste and connecting the conductive wires with the conductive layer, wherein the conductive wires are used for leading out electric signals of the conductive layer;
step 1.3, brushing the rotary coating agent of the packaging material on the surface of the conducting layer by using a brush, and curing to form a packaging material layer; obtaining conductive fibers with conductive wires;
step 2, fixing the conductive fibers on the five-finger positions of the glove bodies respectively, and covering the second knuckle of each finger on each glove body; fixing the soft board on the back of the glove body;
step 3, sewing the conductive threads on the conductive fibers into the soft board interface, coating conductive silver paste on the connecting part, and curing;
and step 4, packaging the soft plate and the interface of the soft plate and the electric lead by using a packaging material to obtain the amphibious intelligent data glove.
9. The method for preparing an amphibious intelligent data glove according to claim 8, wherein in step 4, the soft plate and the conductive wire interface are encapsulated by PDMS spin coating agent;
the PDMS spin coating agent is prepared by the following method: weighing 1-5 parts of PDMS prepolymer and 0.1-0.5 part of PDMS curing agent, mixing, dripping 0.01-0.1 part of n-hexane, stirring for 3-10 min, placing the mixed PDMS solution in a vacuum drying furnace, exhausting at room temperature, and maintaining the vacuum environment for 5-20 min to obtain the PDMS spin coating agent.
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