Nothing Special   »   [go: up one dir, main page]

CN103173049A - Compound modifier-containing anticorrosive coating - Google Patents

Compound modifier-containing anticorrosive coating Download PDF

Info

Publication number
CN103173049A
CN103173049A CN2013100605809A CN201310060580A CN103173049A CN 103173049 A CN103173049 A CN 103173049A CN 2013100605809 A CN2013100605809 A CN 2013100605809A CN 201310060580 A CN201310060580 A CN 201310060580A CN 103173049 A CN103173049 A CN 103173049A
Authority
CN
China
Prior art keywords
parts
mentioned
raw material
weight part
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2013100605809A
Other languages
Chinese (zh)
Other versions
CN103173049B (en
Inventor
徐冉阳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui ruicai Construction Engineering Co.,Ltd.
Original Assignee
ANHUI MINGZHU PIGMENT TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI MINGZHU PIGMENT TECHNOLOGY Co Ltd filed Critical ANHUI MINGZHU PIGMENT TECHNOLOGY Co Ltd
Priority to CN201310060580.9A priority Critical patent/CN103173049B/en
Publication of CN103173049A publication Critical patent/CN103173049A/en
Application granted granted Critical
Publication of CN103173049B publication Critical patent/CN103173049B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a compound modifier-containing anticorrosive coating which comprises two components A and B, wherein the component A comprises the following raw materials in parts by weight: 75-85 parts of epoxy resin E51, 15-20 parts of high chlorinated polyethylene resin, 5-10 parts of titanium dioxide, 3-5 parts of aluminium silicate, 3-5 parts of sodium dodecyl sulfate, 2-4 parts of sodium diacetate, 3-4 parts of coumarone, 3-4 parts of ethyl acrylate, 4-6 parts of nanometer argil, 2-3 parts of polyacrylamide, 2-3 parts of diethylamine, 2-3 parts of dibutyl phthalate, 4-6 parts of ethylene glycol, 3-4 parts of ferrocene, 1-2 parts of ethylene diamine tetra (methylene phosphonic acid) sodium, 2-3 parts of triethanolamine, 1-2 parts of fatty alcohol-polyoxyethylene ether, 10-16 parts of compound modifier, 25-30 parts of dimethylbenzene, 8-10 parts of n-butyl alcohol, 0.8-1 part of N-phenyl-3-amino propyl trimethoxy silane and 0.5-1 part of simethicone. The coating disclosed by the invention has the advantages of good adhesive force to metal, small structural pore, compact structure, excellent adhesive force, good flexibility, high impact strength and good corrosion resistance, and is capable of playing an efficient protection role to base metal.

Description

A kind of protective system that contains composite modifier
Technical field
The present invention relates generally to a kind of coating, relates in particular to a kind of protective system that contains composite modifier.
Background technology
Along with the industrial technology progress, the use of metallic substance is more and more extensive, and the etching problem of metal and member thereof has spreaded all over the every field of national economy, has caused massive losses to human society.In order to reduce the loss of corrosion, people have taked a lot of safeguard procedures, but general, most economical, the most practical sfgd. or coating protection up to now, in various aseptic technics, the aseptic technic of coating is most widely used general.Anticorrosion with coat is with characteristics such as its easy construction, economic and practical, the constraints that is not subjected to device area, shape and be widely used;
Epoxy resin occupies critical role in protective system in the numerous paint kind; by a kind of coated material of extensively using as anti-corrosion of metal; have excellent cohesive force, chemical-resistant resistance, protection against corrosion and water resistance; its output increases day by day; new variety occur in succession; it is extremely rising coating variety; by adding the kind of different fillers and adjustment solidifying agent; can make the different anti-corrosive paint of epoxy resin of performance; be applicable to the anticorrosion needs of different occasions, reach good protection effect.
But metal current exists the problems such as the anticorrosion time limit is short, abrasion resistance is poor, paint film is unstable, environmental pollution to limit its fast development with the protective system technology, in order to improve the performance that epoxy is coating, it is carried out modification have important scientific meaning and commercial value.
Summary of the invention
The object of the invention just is to provide a kind of protective system that contains composite modifier.
The present invention is achieved by the following technical solutions:
A kind of protective system that contains composite modifier, it is comprised of first and second liang of components, and described first component is comprised of the raw material of following weight parts:
epoxy resin E51 75-85, HCPE 15-20, titanium dioxide 5-10, pure aluminium silicate 3-5, sodium laurylsulfonate 3-5, sodium Diacetate 2-4, coumarone 3-4, ethyl propenoate 3-4, nanometer potter's clay 4-6, polyacrylamide 2-3, diethylamine 2-3, dibutyl phthalate 2-3, ethylene glycol 4-6, ferrocene 3-4, ethylenediamine tetramethylene fork Alendronate 1-2, trolamine 2-3, fatty alcohol-polyoxyethylene ether 1-2, composite modifier 10-16, dimethylbenzene 25-30, propyl carbinol 8-10, N-phenyl-3-TSL 8330 0.8-1, dimethyl silicone oil 0.5-1,
Described composite modifier is comprised of the raw material of following weight parts:
35-40 degree Beaume water glass 40-50, Tai-Ace S 150 90-100, nanometer silicon dioxide particle 35-45, sorbitan monooleate 1-2, Soxylat A 25-7 1-2, Xylo-Mucine 1-2, Sodium dodecylbenzene sulfonate 2-4, dicumyl peroxide 1-2, N-phenyl-3-TSL 8330 0.8-1, vinyltriethoxysilane 0.6-1, hydrochloric acid, water are appropriate;
The preparation method of described composite modifier comprises the following steps:
(1) dropwise adding concentration in the 35-40 of above-mentioned weight part degree Beaume water glass is the hydrochloric acid soln of 8-10%, constantly measures the PH of mixed solution, when PH is 4.5-5, stops adding, standby;
(2) Xylo-Mucine and the Sodium dodecylbenzene sulfonate mixing with above-mentioned weight part is dissolved in 15-20 times of water, must expect B;
(3) add suitable quantity of water in the Tai-Ace S 150 of above-mentioned weight part, slowly add the 35-40 degree Beaume water glass solution after above-mentioned acidifying under agitation condition, constantly drip during this time above-mentioned material B, the PH of regulation system is between 9-10, the temperature of reaction of system is 75-85 ℃, 35-40 degree Beaume water glass solution after above-mentioned acidifying dropwises rear continuation and stirred 3-5 minute, and reaction finishes;
(4) will react mixed solution after finishing at 85-95 ℃ of lower ageing 2-3 hour;
(5) nanometer silicon dioxide particle with above-mentioned weight part is distributed in water, obtain the suspension of nano-silica-containing, mix with the batch mixing after above-mentioned ageing, add each raw material of residue, high speed 1500-2000 rev/min centrifugal mixer 20-30 minute, oven dry is ground into ultrafine powder, is described composite modifier;
The preparation method of described first component is:
(1) with epoxy resin E51, HCPE, dimethylbenzene and the propyl carbinol mixing and stirring of above-mentioned weight part;
(2) add again each raw material of residue fully to be uniformly dispersed, then be ground to fineness and reach 50-60 μ m, namely get described first component;
Described component B is comprised of the raw material of following weight parts:
M-xylene diamine 80-90,1,2-phenylenediamine 7-10, dimethylbenzene 10-16, propyl carbinol 6-10, vinyl acetic monomer 6-10;
The preparation method of described component B is:
Each raw material mixing of above-mentioned weight part is added in dispersion tank, start height and stir, be uniformly dispersed, filter, namely get described component B;
First and second liang of components obtained above are mixed according to the 6-10:1 weight ratio, stir 30-40 minute to evenly, can apply or be sprayed on the metallic surface through oil removing, processing of rust removing.
Advantage of the present invention is:
The paint film that the present invention produces is good to metal adhesion; the structure pore is little; compact structure; has good sticking power; snappiness is good, excellent in cushion effect, corrosion resistance nature is strong, and matrix metal is played efficient provide protection, and the composite modifier that adds has further improved surface gloss and the physical and mechanical properties of paint film; make paint film have better scrub resistance, weathering resistance, strengthened the quality of paint film.
Embodiment
Embodiment 1
A kind of protective system that contains composite modifier, it is comprised of first and second liang of components, and described first component is comprised of the raw material of following weight parts (kilogram):
epoxy resin E51 75-85, HCPE (cl content 65%-M) 15-20, titanium dioxide 5-10, pure aluminium silicate 3-5, sodium laurylsulfonate 3-5, sodium Diacetate 2-4, coumarone 3-4, ethyl propenoate 3-4, nanometer potter's clay 4-6, polyacrylamide 2-3, diethylamine 2-3, dibutyl phthalate 2-3, ethylene glycol 4-6, ferrocene 3-4, ethylenediamine tetramethylene fork Alendronate 1-2, trolamine 2-3, fatty alcohol-polyoxyethylene ether 1-2, composite modifier 10-16, dimethylbenzene 25-30, propyl carbinol 8-10, N-phenyl-3-TSL 8330 0.8-1, dimethyl silicone oil 0.5-1,
Described composite modifier is comprised of the raw material of following weight parts:
35-40 degree Beaume water glass 50, Tai-Ace S 150 100, nanometer silicon dioxide particle 45, sorbitan monooleate 2, Soxylat A 25-7 2, Xylo-Mucine 1, Sodium dodecylbenzene sulfonate 4, dicumyl peroxide 2, N-phenyl-3-TSL 8330 0.8, vinyltriethoxysilane 1, hydrochloric acid, water are appropriate;
The preparation method of described composite modifier comprises the following steps:
(1) dropwise adding concentration in the 35-40 of above-mentioned weight part degree Beaume water glass is 10% hydrochloric acid soln, constantly measures the PH of mixed solution, when PH is 4.5, stops adding, standby;
(2) Xylo-Mucine and the Sodium dodecylbenzene sulfonate mixing with above-mentioned weight part is dissolved in 20 times of water, must expect B;
(3) add suitable quantity of water in the Tai-Ace S 150 of above-mentioned weight part, slowly add the 35-40 degree Beaume water glass solution after above-mentioned acidifying under agitation condition, constantly drip during this time above-mentioned material B, the PH of regulation system is between 10, the temperature of reaction of system is 85 ℃, 35-40 degree Beaume water glass solution after above-mentioned acidifying dropwises rear continuation and stirred 5 minutes, and reaction finishes;
(4) will react mixed solution after finishing 95 ℃ of lower ageings 3 hours;
(5) nanometer silicon dioxide particle with above-mentioned weight part is distributed in water, obtains the suspension of nano-silica-containing, mixes with batch mixing after above-mentioned ageing, add each raw material of residue, 2000 rev/mins of centrifugal mixers of high speed 30 minutes, oven dry, be ground into ultrafine powder, be described composite modifier;
The preparation method of described first component is:
(1) with epoxy resin E51, HCPE, dimethylbenzene and the propyl carbinol mixing and stirring of above-mentioned weight part;
(2) add again each raw material of residue fully to be uniformly dispersed, then be ground to fineness and reach 60 μ m, namely get described first component;
Described component B is comprised of the raw material of following weight parts:
M-xylene diamine 90,1,2-phenylenediamine 10, dimethylbenzene 16, propyl carbinol 10, vinyl acetic monomer 10;
The preparation method of described component B is:
Each raw material mixing of above-mentioned weight part is added in dispersion tank, start height and stir, be uniformly dispersed, filter, namely get described component B;
First and second liang of components obtained above are mixed according to the 10:1 weight ratio, stir 40 minutes to evenly, can apply or be sprayed on the metallic surface through oil removing, processing of rust removing.
Performance test:
100 days cut salt mist experiments: paint film without bubble, without come off, cut place's corrosion diffusion 0.9mm;
100 days salt mist experiments: paint film without bubble, without come off, non-corroding;
Abrasion resistance test: pass through for 10000 times, paint film is without breakage;
Acid resistance (5% sulphuric acid soln, 25 ℃, 50h): paint film without bubble, without come off, non-corroding;
Alkali resistance (5% sodium hydroxide solution, 25 ℃, 600h): paint film without bubble, without come off, non-corroding;
Resistance to salt water (5% sodium chloride solution, 25 ℃, 800h): paint film without bubble, without come off, non-corroding;
Snappiness 1mm;
Sticking power 13Mpa.

Claims (1)

1. a protective system that contains composite modifier, is characterized in that it is comprised of first and second liang of components, and described first component is comprised of the raw material of following weight parts:
epoxy resin E51 75-85, HCPE 15-20, titanium dioxide 5-10, pure aluminium silicate 3-5, sodium laurylsulfonate 3-5, sodium Diacetate 2-4, coumarone 3-4, ethyl propenoate 3-4, nanometer potter's clay 4-6, polyacrylamide 2-3, diethylamine 2-3, dibutyl phthalate 2-3, ethylene glycol 4-6, ferrocene 3-4, ethylenediamine tetramethylene fork Alendronate 1-2, trolamine 2-3, fatty alcohol-polyoxyethylene ether 1-2, composite modifier 10-16, dimethylbenzene 25-30, propyl carbinol 8-10, N-phenyl-3-TSL 8330 0.8-1, dimethyl silicone oil 0.5-1,
Described composite modifier is comprised of the raw material of following weight parts:
35-40 degree Beaume water glass 40-50, Tai-Ace S 150 90-100, nanometer silicon dioxide particle 35-45, sorbitan monooleate 1-2, Soxylat A 25-7 1-2, Xylo-Mucine 1-2, Sodium dodecylbenzene sulfonate 2-4, dicumyl peroxide 1-2, N-phenyl-3-TSL 8330 0.8-1, vinyltriethoxysilane 0.6-1, hydrochloric acid, water are appropriate;
The preparation method of described composite modifier comprises the following steps:
(1) dropwise adding concentration in the 35-40 of above-mentioned weight part degree Beaume water glass is the hydrochloric acid soln of 8-10%, constantly measures the PH of mixed solution, when PH is 4.5-5, stops adding, standby;
(2) Xylo-Mucine and the Sodium dodecylbenzene sulfonate mixing with above-mentioned weight part is dissolved in 15-20 times of water, must expect B;
(3) add suitable quantity of water in the Tai-Ace S 150 of above-mentioned weight part, slowly add the 35-40 degree Beaume water glass solution after above-mentioned acidifying under agitation condition, constantly drip during this time above-mentioned material B, the PH of regulation system is between 9-10, the temperature of reaction of system is 75-85 ℃, 35-40 degree Beaume water glass solution after above-mentioned acidifying dropwises rear continuation and stirred 3-5 minute, and reaction finishes;
(4) will react mixed solution after finishing at 85-95 ℃ of lower ageing 2-3 hour;
(5) nanometer silicon dioxide particle with above-mentioned weight part is distributed in water, obtain the suspension of nano-silica-containing, mix with the batch mixing after above-mentioned ageing, add each raw material of residue, high speed 1500-2000 rev/min centrifugal mixer 20-30 minute, oven dry is ground into ultrafine powder, is described composite modifier;
The preparation method of described first component is:
(1) with epoxy resin E51, HCPE, dimethylbenzene and the propyl carbinol mixing and stirring of above-mentioned weight part;
(2) add again each raw material of residue fully to be uniformly dispersed, then be ground to fineness and reach 50-60 μ m, namely get described first component;
Described component B is comprised of the raw material of following weight parts:
M-xylene diamine 80-90,1,2-phenylenediamine 7-10, dimethylbenzene 10-16, propyl carbinol 6-10, vinyl acetic monomer 6-10;
The preparation method of described component B is:
Each raw material mixing of above-mentioned weight part is added in dispersion tank, start height and stir, be uniformly dispersed, filter, namely get described component B;
First and second liang of components obtained above are mixed according to the 7-10:1 weight ratio, stir 30-40 minute to evenly, can apply or be sprayed on the metallic surface through oil removing, processing of rust removing.
CN201310060580.9A 2013-02-26 2013-02-26 A kind of protective system containing composite modifier Active CN103173049B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310060580.9A CN103173049B (en) 2013-02-26 2013-02-26 A kind of protective system containing composite modifier

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310060580.9A CN103173049B (en) 2013-02-26 2013-02-26 A kind of protective system containing composite modifier

Publications (2)

Publication Number Publication Date
CN103173049A true CN103173049A (en) 2013-06-26
CN103173049B CN103173049B (en) 2016-03-30

Family

ID=48633267

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310060580.9A Active CN103173049B (en) 2013-02-26 2013-02-26 A kind of protective system containing composite modifier

Country Status (1)

Country Link
CN (1) CN103173049B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103603205A (en) * 2013-10-24 2014-02-26 安徽柏拉图涂层织物有限公司 Coating material for gymnastic mat fabric
CN103709896A (en) * 2013-12-07 2014-04-09 铜陵新九鼎铜文化产业有限公司 Flexible and antiseptic epoxy resin paint for copper sculptures
CN103756529A (en) * 2013-12-07 2014-04-30 铜陵新九鼎铜文化产业有限公司 Copper sculpture paint with characteristics of heat resistance, ultraviolet resistance and aging resistance
CN104524645A (en) * 2014-12-19 2015-04-22 常熟市雷号医疗器械有限公司 Carotid endarterectomy suction head
CN106590349A (en) * 2016-12-28 2017-04-26 毛葵燕 Anticorrosive coating containing compound modifier
CN113385536A (en) * 2021-06-29 2021-09-14 山东德利铝业科技有限公司 Battery aluminum foil production method for improving surface dyne value

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6090266A (en) * 1983-10-24 1985-05-21 Onahama Sakai Kagaku Kk Novel pigment
CN1085585A (en) * 1993-09-26 1994-04-20 徐晓南 Protective system
CN1175608A (en) * 1996-09-03 1998-03-11 武汉市高校新技术研究所 High polymer corrosion-proof paint for alloy with rust
CN1580153A (en) * 2004-05-20 2005-02-16 中国人民解放军海军装备技术研究所 Modified perchloride polyethylene special coating
CN101691464A (en) * 2009-09-07 2010-04-07 郭再春 High performance chlorinated polyethylene-epoxy resin anticorrosive coating system
CN102120909A (en) * 2010-12-23 2011-07-13 天津科瑞达涂料化工有限公司 Anticorrosive paint for weather-resistant corrosion-resistant steel pipe outer wall

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6090266A (en) * 1983-10-24 1985-05-21 Onahama Sakai Kagaku Kk Novel pigment
CN1085585A (en) * 1993-09-26 1994-04-20 徐晓南 Protective system
CN1175608A (en) * 1996-09-03 1998-03-11 武汉市高校新技术研究所 High polymer corrosion-proof paint for alloy with rust
CN1580153A (en) * 2004-05-20 2005-02-16 中国人民解放军海军装备技术研究所 Modified perchloride polyethylene special coating
CN101691464A (en) * 2009-09-07 2010-04-07 郭再春 High performance chlorinated polyethylene-epoxy resin anticorrosive coating system
CN102120909A (en) * 2010-12-23 2011-07-13 天津科瑞达涂料化工有限公司 Anticorrosive paint for weather-resistant corrosion-resistant steel pipe outer wall

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103603205A (en) * 2013-10-24 2014-02-26 安徽柏拉图涂层织物有限公司 Coating material for gymnastic mat fabric
CN103603205B (en) * 2013-10-24 2016-01-13 安徽柏拉图涂层织物有限公司 A kind of mat fabric coating
CN103709896A (en) * 2013-12-07 2014-04-09 铜陵新九鼎铜文化产业有限公司 Flexible and antiseptic epoxy resin paint for copper sculptures
CN103756529A (en) * 2013-12-07 2014-04-30 铜陵新九鼎铜文化产业有限公司 Copper sculpture paint with characteristics of heat resistance, ultraviolet resistance and aging resistance
CN104524645A (en) * 2014-12-19 2015-04-22 常熟市雷号医疗器械有限公司 Carotid endarterectomy suction head
CN106590349A (en) * 2016-12-28 2017-04-26 毛葵燕 Anticorrosive coating containing compound modifier
CN113385536A (en) * 2021-06-29 2021-09-14 山东德利铝业科技有限公司 Battery aluminum foil production method for improving surface dyne value
CN113385536B (en) * 2021-06-29 2023-03-14 山东德利铝业科技有限公司 Battery aluminum foil production method for improving surface dyne value

Also Published As

Publication number Publication date
CN103173049B (en) 2016-03-30

Similar Documents

Publication Publication Date Title
CN103173102A (en) Anticorrosive coating containing rron oxide red
CN103173049A (en) Compound modifier-containing anticorrosive coating
CN104356935B (en) Waterborne organic silicon coating and preparation method thereof
CN103173103A (en) Anticorrosive paint containing sepiolite powder
CN103173094A (en) Anticorrosive paint containing dimethyl sulfoxide
CN103319974B (en) Based on the high temperature resistant hydrophobic coating and preparation method thereof of epoxy resin modification silicon sol
CN103173101A (en) Salt spray resistant anticorrosive paint
CN102533082A (en) Aqueous environment-friendly anti-aging floor coating and preparation method thereof
CN102061126B (en) Ceramic coating film composite and preparation method thereof
CN104403463A (en) Aqueous low-surface treatment coating for iron power transmission tower surface protection and preparation method for aqueous low-surface treatment coating
CN107513325B (en) A kind of weather-proof epoxy thickness slurry anticorrosive paint and preparation method thereof
CN101445676B (en) High-efficient zinc-rich anti-corrosive paint and preparation method thereof
CN103173100B (en) A kind of acid proof protective system
CN103173092A (en) Anticorrosive paint with high adhesive force
CN104004448A (en) Single-component cathodic electrophoretic coating for automotive primer
CN103173050B (en) A kind of protective system containing ferrocene
CN105348899A (en) Coupling agent
CN108250957A (en) A kind of graphene modified water coating type anti-corrosion resin and preparation method
CN107286803A (en) The environment-friendly type aqueous protective paint of engineering derrick crane and preparation method
CN102604537B (en) Water-based metal antiseptic paint and preparation method thereof
CN103173093B (en) A kind of protective system
CN106590349A (en) Anticorrosive coating containing compound modifier
CN116200096B (en) Corrosion-spreading-resistant water-based zinc-rich anticorrosive paint and preparation method thereof
CN110054958A (en) A kind of preparation method and application of extra-weather-proof aqueous one-component anti-corrosive primer
CN103173048B (en) A kind of protective system of alkali resistance

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20160224

Address after: 244100 new road, West Lake Town Development Zone, lion mountain, Tongling, Anhui

Applicant after: Anhui Mingzhu Pigment Technology Co., Ltd.

Address before: Wu Song Zhen Tongling County of Anhui province Tongling 244100 Union City Village

Applicant before: Anhui Mingzhu Pigment Technology Co., Ltd.

C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20190415

Address after: 246127 Yangtang Formation No. 31, Jiliu Village, Chaling Town, Huaining County, Anqing City, Anhui Province

Patentee after: Huaining Sanhe Cleaning Services Ltd.

Address before: 244100 New Town Road, West Lake Town Development Zone, Tongling, Anhui

Patentee before: Tongling Guofang Plumbing Technology Co., Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20220110

Address after: 230000 room 322, Zhangji Township People's government, Feidong County, Hefei City, Anhui Province

Patentee after: Anhui ruicai Construction Engineering Co.,Ltd.

Address before: 246127 Yangtang Formation No. 31, Jiliu Village, Chaling Town, Huaining County, Anqing City, Anhui Province

Patentee before: HUAINING SANHE CLEANING SERVICE CO.,LTD.

TR01 Transfer of patent right