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CN102675024B - Separation process for preparing low-carbon olefin gas through methanol conversion - Google Patents

Separation process for preparing low-carbon olefin gas through methanol conversion Download PDF

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Publication number
CN102675024B
CN102675024B CN201110059244.3A CN201110059244A CN102675024B CN 102675024 B CN102675024 B CN 102675024B CN 201110059244 A CN201110059244 A CN 201110059244A CN 102675024 B CN102675024 B CN 102675024B
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tower
separating tank
tank
sections
cooling
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CN102675024A (en
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熊献金
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China Petroleum and Chemical Corp
Sinopec Luoyang Guangzhou Engineering Co Ltd
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China Petroleum and Chemical Corp
Sinopec Luoyang Petrochemical Engineering Corp
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0219—Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0238—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0242—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 3 carbon atoms or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0252—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/40—Features relating to the provision of boil-up in the bottom of a column
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/74—Refluxing the column with at least a part of the partially condensed overhead gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/06—Splitting of the feed stream, e.g. for treating or cooling in different ways
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/12—Refinery or petrochemical off-gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00—Processes characterised by the type or other details of the product stream
    • F25J2215/62—Ethane or ethylene
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/30—Compression of the feed stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/04—Internal refrigeration with work-producing gas expansion loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/12—External refrigeration with liquid vaporising loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/60—Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention discloses a separation process for preparing low-carbon olefin gas through methanol conversion, aiming at overcoming the defects that products such as high-purity hydrogen, methane, ethane and propane cannot be obtained, dimethyl ether and oxygen and carbon monoxide in flue gas impurities are not effectively removed and the like in the prior art. A carbon monoxide and oxygen removal step is added in the process. Methanol-to-olefin gas with the carbon monoxide and the oxygen being removed passes through six separation tanks and then enters a high-pressure demethanation tower, a deethanization tower, an acetylene hydrogenation reactor, an ethylene rectifying tower, an allylene hydrogenation reactor, a propylene rectifying tower and the like for separation, wherein liquid which comes out from the bottoms of the first five separation tanks sequentially enters the middle-to-upper part of the demethanation tower. By adopting the separation process, polymer-grade ethylene and propylene products can be obtained and products such as high-purity hydrogen, methane, ethane and propane can also be obtained.

Description

A kind of separating technology of converting methanol to prepare low carbon olefin gas
Technical field:
The present invention relates to a kind of separating technology of converting methanol to prepare low carbon olefin gas.Particularly, the present invention relates to from comprise hydrogen, oxygen, nitrogen, carbon monoxide, carbonic acid gas, methane, ethane, ethene, acetylene, propane, propylene, cyclopropane, propine and propadiene to reclaim in one or more mixture the technique of ethene, propylene.
Background technology:
Alkene, particularly low-carbon alkene (light olefin), as ethene and propylene, are needed as preparing the raw materials such as higher alkene, polyethylene and polypropylene.Adopting petroleum naphtha is that the pyrolysis in tubular furnace device that raw material is produced ethene and propylene through steam pyrolysis is current topmost ethene and propylene industrial installation.The splitting gas that hydrocarbon cracking is produced is the mixture that contains hydrogen, methane, ethane, ethene, propane, propylene, mixed c 4 carbon five, pyrolysis gasoline etc.The separation method of this mixture has six kinds of order separation process, front-end deethanization flow process, predepropanization process, low investment separation process, progressive separation process and oily absorption extraction flow processs etc. conventionally.
But oxygenatedchemicals is becoming the surrogate of the petroleum of preparing low-carbon alkene.Promising especially oxidation raw material is that alcohols is as methyl alcohol and ethanol, dme, methyl ethyl ether, diethyl ether, methylcarbonate and methyl-formiate.These oxygenatedchemicalss are many can be produced by plurality of raw materials, and described raw material comprises the synthetic gas, petroleum liquid, carbonaceous material (comprising coal), reprocessed plastic(s), municipal wastes or any suitable organic materials that are obtained by Sweet natural gas.Owing to there being source widely, therefore, as the economic non-petroleum source of producing for low-carbon alkene, alcohol, alcohol derivate and other oxygenatedchemicals are promising.A kind of method of producing alkene is to utilize the catalyzed conversion of the methyl alcohol of aluminosilicophosphate (SAPO) molecular sieve catalyst.For example, US4,499,327 have disclosed and have utilized any of various SAPO molecular sieve catalysts, by the method for converting methanol to prepare low carbon olefin (MTO) gas.The method is the temperature between 300 DEG C and 500 DEG C, and 0.1 atmosphere is pressed onto the pressure between 100 normal atmosphere during this period, and 0.1 and 40hr -1between weight hourly space velocity (WHSV) under carry out.The method is high selectivity for manufacturing ethene and propylene.
US6,121,504 also disclose a kind of method of utilizing molecular sieve catalyst to be prepared olefin product by oxygen-containing compound material.By contacting with quenching medium from olefin product except anhydrating and other undesired by product.After contacting with quenching medium, obtain comprising wanted alkene but also comprise that dme, methane, carbon monoxide, carbonic acid gas, ethane, propane and other minor component are as the lighter products cut of water and unreacted oxygenate raw materials of compound.
MTO gas composition and naphtha cracking gas are very different, and maximum difference is in MTO gas that propylene and propane content are apparently higher than propylene and propane content in naphtha cracking gas.The flue gas foreign matter content that contains oxygen of bringing into because of catalyst regeneration in MTO gas is also higher than naphtha cracking gas.In MTO gas, also contain the oxygen-containing organic compound such as methyl alcohol and dme.
Prepare the method for olefin product for oxygen-containing compound material, for example MTO technique, one of undesired especially by product is dme.Do not solve satisfactorily so far the problem of removing dme from olefin product stream always.Consider to infer the special absorptive agent that can remove dme from described product stream.But be difficult to find the absorption agent or the sorbent material that are applicable to this.Conventionally need to reduce or remove in olefin stream undesired hydro carbons by product amount further to process described alkene, particularly ethene and propylene.This is because derivative production process may be used the catalyzer quite responsive for the existence of some hydrocarbon.For example dme can make the polyethylene of many routines and polypropylene form poisoning of catalyst, this just means if the ethene that rectifying separation hydro carbons system is obtained and propylene stream carry out further catalytic treatment, must ensure that ethene and propylene stream are hardly containing dme.Thereby very other method of removing dme from olefin stream is found in hope.CN1833017A discloses the effective separation method of novel high and the system for separation of polymeric level ethene and propylene from one or more the initial flow discharging stream that comprises ethane, ethene, propylene, dme and propane, acetylene, propadiene, methane, hydrogen, carbon monoxide, carbonic acid gas and C4+ component.Fig. 1 has shown an embodiment of the method, the initial flow discharging stream 200 that contains ethane, ethene, dme, propane and propylene is incorporated into the first tripping device 201, and it is preferably suitable for removing the washing tower of most non-dme oxygenatedchemicals from initial flow discharging stream 200.In the first tripping device 201, initial flow discharging stream 200 contacts oxygenatedchemicals and removes medium 202, particular methanol under the condition of effectively removing some oxygenatedchemicalss.This means, ethane, ethene, propane, propylene and at least some dme can reclaim in the first top stream 203, and wherein most of oxygenatedchemicals removal medium 202, non-dme oxygenatedchemicals and at least some dme can reclaim in the first tower bottoms stream 204.The first top stream 203 also may contain a small amount of residual oxygenatedchemicals removes medium.The first tripping device 201 optionally comprises reflux line and/or reboiler pipeline and corresponding interchanger (not shown), to be conducive to the separation of these components.
Then the first top stream 203 is introduced in the second tripping device 210, and it is preferably suitable for separating the water wash column of any residual oxygenatedchemicals removal medium 202 carrying via the first top stream 203 from the first tripping device 201.Specifically, in the second tripping device 210, the first top stream 203 contacts water 209 under the condition of effectively therefrom removing at least most residual oxygenatedchemicals removal medium.Therefore, can in the second top stream 211, reclaim from ethane, ethene, propane, propylene and the dme of the first top stream 203, wherein most residual oxygenatedchemicals removal medium 202 and water 209 can reclaim in the second tower bottoms stream 218.The second tripping device 210 optionally comprises reflux line and/or reboiler pipeline and corresponding interchanger (not shown), to promote the separation of these components.
Optionally, the second top stream 211 is incorporated into caustic alkali washing device (not shown) and/or the drying installation (not shown) for removing carbonic acid gas.Get back to Fig. 1, the second top stream 211 is preferably introduced in demethanizing apparatus for feeding group 212.Demethanizing apparatus for feeding group 212 is preferably by serial water cooler and cooling the second top stream 211 and form " ice chest " that the knockout drum (not shown) of multiple cooled stream 214A-C forms.Cooled stream 214A-C can be liquid and/or steam form.Cooled stream 214A-C is introduced in the 3rd tripping device 215, for further processing.The 3rd tripping device 215 is preferably suitable for separating lighting end as the rectifying tower of methane, hydrogen and/or carbon monoxide and ethane, ethene, propane, dme and propylene.Specifically, cooling material stream 214A-C is altogether separated into the 3rd top stream 216 and the 3rd tower bottoms stream 217 by the 3rd tripping device 215, the former contains the most lighting end being present in cooled stream 214A-C, and the latter is preferably contained most ethane, ethene, propane, dme and the propylene being present in cooled stream 214A-C.The 3rd tripping device 215 optionally comprises reflux line and/or reboiler pipeline and corresponding interchanger (not shown), to be conducive to separating of lighting end and ethane, ethene, propane, dme and propylene.In one embodiment, the 3rd top stream 216 is introduced in demethanizing apparatus for feeding group 212, so that as heat-eliminating medium.
The 3rd tower bottoms stream 217 is preferably introduced in the 4th tripping device 206.The 4th tripping device 206 is preferably suitable for the distillation tower that C3+ component is separated with C2-component.Specifically, the 3rd tower bottoms stream 217 is separated into the 4th top stream 207 (wherein containing most ethane and the ethene being present in the 3rd tower bottoms stream 217) by the 4th tripping device 206, with the 4th tower bottoms stream 208 (it preferably contains most propane, dme and the propylene being present in the 3rd tower bottoms stream 217).The 4th tripping device 206 optionally comprises reflux line and/or reboiler pipeline and corresponding interchanger (not shown), to promote separating of C2-component and C3+ component.
The 4th top stream 207 is incorporated into the 5th tripping device 224, for further processing.The 5th tripping device 224 is preferably suitable for the distillation tower of separating ethene and ethane.Specifically, the 4th top stream 207 is separated into the 5th top stream 225 and the 5th tower bottoms stream 226 by the 5th tripping device 224, the former contains the most ethene being present in the 4th top stream 207, and the latter is preferably contained the most ethane being present in the 4th top stream 207.The 5th tripping device 224 optionally comprises reflux line and/or reboiler pipeline and corresponding interchanger (not shown), to be conducive to separating of ethene and ethane.The 5th top stream 225 contains quite pure ethene, and it be directed into poly-unit (not shown), for polymerization.The 5th tower bottoms stream 226 is preferably introduced in demethanizing apparatus for feeding group 212, as heat-eliminating medium.Optionally, the 5th tower bottoms stream 226 is combined with the heat-eliminating medium that comes from the 3rd top stream 216, as shown in the dotted line by demethanizing apparatus for feeding group 212.In addition, a part that is rich in the 5th tower bottoms stream 226 of ethane can be used in the reflux line of the 3rd tripping device 215.Preferably, ethane is excessively cold, then be sent to the 3rd tripping device 215.By adding ethane as phegma, ethane becomes sorbent material, preferentially ethene is transported to the bottom of the 5th tripping device, thereby improves separating of methane and ethene.In demethanizing apparatus for feeding group 212, after the cooling steam from the second top stream 211, heat-eliminating medium is discharged from demethanizing apparatus for feeding group 212 by exhaust pipe 213.
If initial flow discharging stream lacks C 4 +component, depends on propane in initial flow discharging stream and the amount of dme so, and the 4th tower bottoms stream 208 can contain main propylene and a small amount of dme and propane, and is suitable for poly-unit.If need the propylene of very high-quality, so the 4th tower bottoms stream 208 is optionally incorporated in the 6th tripping device 236.The 6th tripping device 236 is preferably suitable for the distillation tower of separation of propylene and propane and dme.Therefore the 6th tripping device 236 can be used as C 3splitter operation.Specifically, the 4th tower bottoms stream 208 is separated into the 6th top stream 237 and the 6th tower bottoms stream 238 by the 6th tripping device 236, the former contains the most propylene being present in the 4th tower bottoms stream 208, and the latter is preferably contained most propane, dme and the optional any residual C being present in the 4th tower bottoms stream 208 4 +component.The 6th tripping device 236 optionally comprises reflux line and/or reboiler pipeline and corresponding interchanger (not shown), to be conducive to separating of propylene and propane.The propylene that the 6th top stream 237 contains very high-quality, it is suitable for polymerization.The 6th tower bottoms stream 238 is preferably as fuel combustion.
If initial flow discharging stream contains any C that can measured quantity 4 +component, process scheme so according to the present invention preferably includes depropanizing tower (not shown).Depropanizing tower is applicable to separation of C 4 +component and C 3 -component, for example lighting end, ethene, ethane, propylene, propane and dme.The layout of depropanizing tower can alter a great deal.In the embodiment depicted in fig. 1, depropanizing tower optionally receives and removes at least most C coming from following material stream one or more 4 +component: initial flow discharging stream 200, the second top stream 211, the three tower bottoms stream 217, the four tower bottoms stream 208 or the 6th tower bottoms stream 238.If initial flow discharging stream 200 contains acetylene, methylacetylene, propadiene or other how unsaturated component, optimum system choosing so of the present invention comprises hydrogenation convertor, for example acetylene or MAPD (propine and propadiene) convertor (not shown).If be incorporated in the present invention, hydrogenation convertor preferably receives and processes one or more following logistics so: the second top stream 211, the three tower bottoms stream 217, the four top stream 207 and/or the 4th tower bottoms stream 208.In hydrogenation convertor, acetylene contacts hydrogen and carbonic acid gas under the condition that is effectively ethene by the acetylene conversion of at least a portion.Similarly, methylacetylene and/or propadiene are effectively converted into the methylacetylene of at least a portion and/or propadiene under the condition of propylene and contact hydrogen and carbonic acid gas.Component except being present in acetylene, methylacetylene and the propadiene in above-mentioned material stream is preferably intactly by hydrogenation convertor.Then the poor material stream of gained acetylene processed as described above with reference to Figure 1.
Find after deliberation, the embodiment of the disclosed method of above-mentioned CN1833017A exists following shortcoming:
1) there is very large defect in the part that is connected between the second tripping device 210 and demethanizing apparatus for feeding group 212, because two kinds of whereabouts of the second top stream 211 that contains ethane, ethene, propane, propylene and dme all have problems.If the second top stream 211 is preferably introduced in to demethanizing apparatus for feeding group 212, because the second top stream 211 exists moisture, follow-up the 3rd tripping device, the 4th tripping device top and the 5th tripping device top is operation at low temperatures but, water can form solid hydrate and blocking pipe with the component such as ethane, ethene, and consequence is serious.If the second top stream 211 is incorporated into caustic alkali washing device (not shown) and/or the drying installation (not shown) for removing carbonic acid gas.Surely can be entrained with residual alkali lye from the caustic alkali washing device gas streams that contains ethane, ethene, propane, propylene and dme out.Residual alkali lye not only can etching apparatus, also can affect the activity of the catalyzer in effect and the hydrogenation convertor (acetylene or MAPD convertor) of the siccative in drying installation, when serious, can cause siccative to lose efficacy and catalyst deactivation.And in the disclosed method of CN1833017A and reckon without the impact of this material of residual alkali lye on equipment and siccative and catalyzer.Thereby do not provide the method for removing residual alkali lye yet.
2) factor that affects operational condition due to dme etc. exists, and can not obtain respectively the products such as methane, ethane and propane that purity is higher in the 3rd tripping device, the 5th tripping device and the 6th tripping device.And methane, ethane and propane are important Organic Chemicals.As can be seen from Figure 1, the 3rd tripping device top is rich in logistics that the logistics of methane and the 5th separation unit bottoms be rich in ethane and is merged and process as tail gas.The 6th separation unit bottoms is rich in the logistics of propane because containing a certain amount of dme, naturally affects the purity of propane.Dme is because being organic oxygen-containing compound, and the hydro carbons such as it and methane, ethane, ethene, propane and propylene enter the unsafe factor that has potential explosion hazard in demethanizing apparatus for feeding group 212 (being preferably ice chest) and exist.
3) in demethanizing apparatus for feeding group 212, can not obtain the hydrogen that purity is higher.And the higher hydrogen of purity is that hydrogenation convertor (acetylene or MAPD convertor) is essential.Must separately look for hydrogen source if adopt hydrogenation convertor (acetylene or MAPD convertor).
4) removing medium 202 when methyl alcohol and three (glycol) as oxygenatedchemicals is added in the first tripping device 201.In the first tower bottoms stream 204, not only there is most of oxygenatedchemicals to remove medium, non-dme oxygenatedchemicals and at least some dme; And also have a considerable amount of by ethene and the propylene component of methyl alcohol and three (glycol) absorption.Can bring certain loss to main products ethene and propylene.In addition, also can increase the cost that methyl alcohol and three (glycol) reclaims.
5) embodiment reckons without the impact of the flue gas impurity that catalyst regeneration brings into.For converting methanol to prepare low carbon olefin gas, the flue gas impurity that catalyst regeneration is brought into contains oxygen, if do not remove before entering soda-wash tower and ice chest, can in soda-wash tower, bring out hydro carbons polymerization, thereby causes butter to produce; Can cause gathering of ice chest position explosion hazard thing, cause system unsafe factor to increase.Too high oxygen level, also can cause murder by poisoning to ethene or propylene polymerization catalyst system, thereby reduces the activity of catalyzer and the quality of polyethylene or polypropylene product.
6) described in embodiment, tripping device all lacks the elementary operation conditions such as temperature and pressure.Tripping device is knockout tower or separating tank specifically, and scheme is not narrated clear.The difference of the elementary operation conditions such as temperature and pressure is extremely important concerning some tripping devices, is the notable feature of flow process, as high pressure demethanizer and low pressure demethanizer.
Summary of the invention:
The present invention is can not obtain the products such as hydrogen, methane, ethane and propane that purity is higher and there is no effectively to remove the shortcoming such as oxygen and carbon monoxide in dme and flue gas impurity for the disclosed method of CN1833017A is existing, according to the component of converting methanol to prepare low carbon olefin gas and compositing characteristic, proposed a kind of from low carbon olefin gas the effective separating technology of novel high of separation of polymeric level ethene and propylene.This technique can not only obtain polymer grade ethylene and propylene product, and can also obtain the products such as hydrogen, methane, ethane and propane that purity is higher.
The invention provides a kind of separating technology of converting methanol to prepare low carbon olefin gas.Particularly, the technique that the present invention relates to from comprise hydrogen, oxygen, nitrogen, carbon monoxide, carbonic acid gas, methane, ethane, ethene, acetylene, propane, propylene, cyclopropane, propine and propadiene to reclaim in one or more mixture ethene, propylene, is characterized in that comprising the steps:
1) converting methanol to prepare low carbon olefin gas logistics removes contained oxygenatedchemicals, water and C 4and C 4after above hydro carbons as low-carbon alkene logistics, carry out successively primary dewatering, heat exchange, removal of carbon monoxide, cooling and middle dehydration, then carry out deoxidation treatment, alkali cleaning and washing are carried out in low-carbon alkene logistics after deoxidation after heat exchange, after the low-carbon alkene logistics after alkali cleaning and washing mixes with vapour phase, the vapour phase of vapor-liquid separation tank and the vapour phase of methane stripper return tank of ethylene rectification tower return tank, become alkene mixture;
2) from step 1) alkene mixture through heat exchange, deep dehydration with cooling after enter the first separating tank and separate, the first separating tank top gas out enters the second separating tank after cooling, the second separating tank top gas out enters the 3rd separating tank after cooling, the 3rd separating tank top gas out enters the 4th separating tank after cooling, the 4th separating tank top gas out enters the 5th separating tank after cooling, the 5th separating tank top gas out enters the 6th separating tank after cooling, wherein the first separating tank bottom liquid out enters demethanizing tower middle and upper part through pump pressurization, the second separating tank bottom liquid out enters demethanizing tower middle and upper part, the 3rd separating tank bottom liquid out, the 4th separating tank bottom liquid and the 5th separating tank bottom liquid out out enters demethanizing tower top, opening for feed is arranged from bottom to top in turn along demethanizing tower middle and upper part and top, the 5th separating tank bottom liquid opening for feed is in the top, the 6th separating tank bottom liquid is out low-pressure methane product, the 6th separating tank top gas is out as thick hydrogen production,
3) gaseous mixture that demethanizer column overhead produces, after cooling and condensation, enter demethanizing return tank, the liquid phase of demethanizing return tank is returned to demethanizer column overhead as backflow, the gas phase of demethanizing return tank is methane gaseous products, demethanizing tower tower base stream enters deethanizing column, the gaseous mixture that deethanizer overhead produces, after cooling and condensation, enter deethanizing column return tank, the liquid phase of deethanizing column return tank is returned to deethanizer overhead as backflow, the gas phase of deethanizing column return tank is for containing ethene, the gas phase mixture logistics of ethane and acetylene, in the time that acetylene molar content is less than 1ppm, after drying and heat exchange, enter ethylene rectification tower, in the time that acetylene molar content is more than or equal to 1ppm, enter acetylene hydrogenation reactor, what acetylene hydrogenation reactor bottom produced contains ethene, after the gaseous mixture drying of ethane and heat exchange, enter ethylene rectification tower, ethylene rectification tower bottom product is ethane liquid-phase product, the lateral line withdrawal function ethylene product logistics of ethylene rectification tower top, deliver to device outer or as the raw material of polyethylene device, the gaseous mixture that ethylene distillation column overhead produces, after cooling and condensation, enter ethylene rectification tower return tank, the liquid phase of ethylene rectification tower return tank is returned to ethylene distillation column overhead as backflow, the vapour phase of ethylene rectification tower return tank is mixed with the low-carbon alkene logistics after alkali cleaning and washing,
4) deethanizer bottoms stream is the liquid mixture containing propylene, propane, cyclopropane, propine and propadiene, in the time that its propine molar content is less than 5ppm and propadiene molar content and is less than 10ppm, through pressurization, heat exchange, dry and again after heat exchange, enter propylene rectification tower; In the time that its propine molar content is more than or equal to 5ppm or propadiene molar content and is more than or equal to 10ppm, through pressurization, heat exchange, dry and cooling after, enter propine hydrogenator, propine hydrogenator bottom mixture flow out separates through vapor-liquid separation tank, the vapour phase of vapor-liquid separation tank is mixed with the low-carbon alkene logistics after alkali cleaning and washing, the liquid phase of vapor-liquid separation tank is divided into two strands after supercharging, one turns back to propine hydrogenator, after another stock-traders' know-how interchanger heat exchange, enters methane stripper;
5) at the bottom of methane stripper tower, logistics out enters propylene rectification tower after by pressurization and heat exchange, the gas phase mixture that methane stripper tower top produces enters methane stripper return tank after cooling and condensation, the liquid phase of methane stripper return tank is returned to methane stripper tower top as backflow after pressurization, and the vapour phase of methane stripper return tank is mixed with the low-carbon alkene logistics after alkali cleaning and washing;
6) gaseous mixture that propylene rectification tower tower top produces, after cooling and condensation, enter propylene rectification tower return tank, the liquid phase of propylene rectification tower return tank is returned to propylene rectification tower tower top as backflow after pressurization, the gas phase of propylene rectification tower return tank is propylene product logistics, and propylene rectification tower tower base stream is propane product stream.
The further technical characterictic of the present invention is: described alkene mixture through heat exchange, deep dehydration and cooling after be divided into two-way, one tunnel the first ice chest is cooling, another road is cooling through demethanizing tower bottom reboiler, propylene water cooler successively, mix with the first via afterwards, then enter the first separating tank after the first ethylene chiller is cooling.
The further technical characterictic of the present invention is: described the first separating tank top gas out enters the second separating tank through the second ice chest and the second ethylene chiller after cooling.
The further technical characterictic of the present invention is: described the first separating tank top gas is out after heat exchange, enter four sections, compressor and five sections of pressurizations, then after five sections of compressed gas water coolers, the second ice chest and the second ethylene chiller are cooling, enter the second separating tank successively.
The further technical characterictic of the present invention is: described the second separating tank top gas out enters the 3rd separating tank through the 3rd ice chest and triethylene water cooler after cooling.
The further technical characterictic of the present invention is: described the second separating tank top gas is out after heat exchange, enter four sections, compressor and five sections of pressurizations, then after five sections of compressed gas water coolers, the 3rd ice chest and triethylene water cooler are cooling, enter the 3rd separating tank successively; The second separating tank bottom liquid out enters demethanizing tower middle and upper part after pump pressurization.
The further technical characterictic of the present invention is: described the 3rd separating tank top gas out enters the 4th separating tank after the 4th ice chest is cooling.
The further technical characterictic of the present invention is: described the 3rd separating tank top gas out, after heat exchange, enters four sections, compressor and five sections of pressurizations, then enters the 4th separating tank through five sections of compressed gas water coolers and the 4th ice chest after cooling; The second separating tank bottom liquid out enters demethanizing tower middle and upper part after pump pressurization, and the 3rd separating tank bottom liquid out enters demethanizing tower top after pump pressurization.
The further technical characterictic of the present invention is: described the 4th separating tank top gas out enters the 5th separating tank after the 5th ice chest is cooling.
The further technical characterictic of the present invention is: described the 4th separating tank top gas out, after heat exchange, enters four sections, compressor and five sections of pressurizations, then enters the 5th separating tank through five sections of compressed gas water coolers and the 5th ice chest after cooling; The second separating tank bottom liquid out enters demethanizing tower middle and upper part after pump pressurization, and the 3rd separating tank bottom liquid and the 4th separating tank bottom liquid out out enters demethanizing tower top respectively after pump pressurization.
The further technical characterictic of the present invention is: described the 5th separating tank top gas out enters the 6th separating tank after the 6th ice chest is cooling.
The further technical characterictic of the present invention is: described the 5th separating tank top gas out, after heat exchange, enters four sections, compressor and five sections of pressurizations, then enters the 6th separating tank through five sections of compressed gas water coolers and the 6th ice chest after cooling; The second separating tank bottom liquid out enters demethanizing tower middle and upper part through pump pressurization, and the 3rd separating tank bottom liquid, the 4th separating tank bottom liquid and the 5th separating tank bottom liquid out out out enters demethanizing tower top respectively after pump pressurization.
The further technical characterictic of the present invention is: described the 6th separating tank bottom liquid out, after decompression throttling, after the 6th ice chest, the 5th ice chest, the 4th ice chest, the 3rd ice chest, the second ice chest and the first ice chest heat exchange, deliver to outside device as low-pressure methane product successively.
The further technical characterictic of the present invention is: described the 6th separating tank top gas is out delivered to outside device as thick hydrogen production successively after the 6th ice chest, the 5th ice chest, the 4th ice chest, the 3rd ice chest, the second ice chest and the first ice chest heat exchange; Or deliver to pressure-swing absorption apparatus or membrane separation unit and further purify that to obtain molar content be more than 99.9% highly purified hydrogen.
The further technical characterictic of the present invention is: the gas phase of described demethanizing tower return tank temperature after methane decompressor expands is reduced to-120～-160 DEG C, then reclaim cold through the 5th ice chest, the 4th ice chest, the 3rd ice chest, the second ice chest and the first ice chest successively, as methane gaseous products, or as Organic Chemicals or fuel gas carrying device.
The further technical characterictic of the present invention is: described demethanizing tower tower base stream is divided into two-way, one tunnel is cold liquid mixture, after the heat exchange of cold feed interchanger, enter deethanizing column middle and upper part as cold feed, another road is hot liquid mixture, after the heat exchange of hot feed interchanger, enter deethanizing column middle and lower part as hot feed.
The further technical characterictic of the present invention is: the gaseous mixture containing ethene, ethane that described acetylene hydrogenation reactor bottom produces enters green oil tank after the charging heat exchange by interchanger and acetylene hydrogenation reactor again after cooling, from the gaseous mixture drying and heat exchange out of green oil tank top, enter ethylene rectification tower, the green oil that green oil pot bottom produces can be used as the raw material of converting methanol to prepare low carbon olefin device or delivers to outside device, preferentially as converting methanol to prepare low carbon olefin device raw material.
The present invention is further characterized in that: described deethanizing column bottom reboiler utilizes steam or circulating water heating.
The present invention is further characterized in that: described ethylene rectification tower bottom reboiler utilizes circulating water heating.
The present invention is further characterized in that: described ethylene rectification tower bottom product is that ethane content is 85 % by mole of above ethane liquid-phase products, delivers to outside device as Organic Chemicals.
The present invention is further characterized in that: described propylene rectification tower bottom reboiler utilizes steam or circulating water heating.
The present invention is further characterized in that: described propylene rectification tower tower base stream is that propane content is 90 % by mole of above propane liquid-phase products, delivers to outside device as Organic Chemicals.
The present invention is further characterized in that: described the first separating tank working pressure is 0.01～4.0MPa, is preferably 0.1～2.0MPa; Service temperature is-100～30 DEG C, is preferably-80～10 DEG C.
The present invention is further characterized in that: described the second separating tank working pressure is 0.01～4.0MPa, is preferably 0.1～2.0MPa; Service temperature is-130～0 DEG C, is preferably-110～-20 DEG C.
The present invention is further characterized in that: described the 3rd separating tank working pressure is 0.01～4.0MPa, is preferably 2.0～4.0MPa; Service temperature is-170～-30 DEG C, is preferably-160～-60 DEG C.
The present invention is further characterized in that: described the 4th separating tank working pressure is 0.01～4.0MPa, is preferably 2.0～4.0MPa; Service temperature is-180～-40 DEG C, is preferably-170～-70 DEG C.
The present invention is further characterized in that: described the 5th separating tank working pressure is 0.01～4.0MPa, is preferably 2.0～4.0MPa; Service temperature is-190～-50 DEG C, is preferably-180～-80 DEG C.
The present invention is further characterized in that: described the 6th separating tank working pressure is 0.01～4.0MPa, is preferably 2.0～4.0MPa; Service temperature is-200～-60 DEG C, is preferably-190～-90 DEG C.
The further technical characterictic of the present invention is: described low-carbon alkene logistics removal of carbon monoxide adopts removal of carbon monoxide Cu-series catalyst, as C18 catalyzer.
The further technical characterictic of the present invention is: it is that dehydrogenation catalyst or manganese are dehydrogenation catalyst that described low-carbon alkene logistics deoxidation treatment adopts nickel.Preferential use manganese is dehydrogenation catalyst.
The further technical characterictic of the present invention is: the dehydration of described low-carbon alkene logistics or dry all employings molecular sieve.
The further technical characterictic of the present invention is: the alkali cleaning of described low-carbon alkene logistics and washing are carried out in soda-wash tower, and soda-wash tower bottom is that alkali cleaning section is carried out alkali cleaning, and soda-wash tower top is that washing section is washed, the water inlet of washing section top.
The further technical characterictic of the present invention is: alkali lye is entered on described soda-wash tower alkali cleaning section top, and alkali lye is that concentration is that aqueous sodium hydroxide solution or the concentration of 0.001～50 % by weight is the potassium hydroxide aqueous solution of 0.001～50 % by weight.
The further technical characterictic of the present invention is: described demethanizer column overhead working pressure is 0.01～5.0MPa, is preferably 2.0～4.0MPa; Demethanizing tower column bottom temperature is-60 DEG C～70 DEG C, is preferably-50～60 DEG C.Demethanizing tower return tank service temperature is-160～-60 DEG C, is preferably-150～-70 DEG C, and mole reflux ratio is 0.01～40.
The further technical characterictic of the present invention is: described demethanizing tower has 30～60 theoretical stages.
The further technical characterictic of the present invention is: described demethanizing tower the first opening for feed is opened at 1-5 piece theoretical stage place; The second opening for feed is opened at 6-9 piece theoretical stage place; The 3rd opening for feed is opened at 10-14 piece theoretical stage place; The 4th opening for feed is opened at 15-20 piece theoretical stage place; The 5th opening for feed is opened at 21-26 piece theoretical stage place, and opening for feed and number of theoretical plate are all counted from top to bottom along demethanizing tower.
The further technical characterictic of the present invention is: described deethanizer overhead working pressure is 1.5～3.0MPa, is preferably 1.7～2.5MPa; Deethanizing column column bottom temperature is 0 DEG C～100 DEG C, is preferably 20～80 DEG C.Deethanizing column return tank service temperature is-60～0 DEG C, is preferably-40～-10 DEG C; Mole reflux ratio is 0.01～40.
The further technical characterictic of the present invention is: described deethanizing column is divided into two sections, tower top is rectifying section to hot feed entrance, hot feed entrance is stripping section at the bottom of tower, deethanizing column has 20～50 theoretical stages, cold feed entrance is opened at 3-20 piece theoretical stage place, hot feed entrance is opened at 16-30 piece theoretical stage place, and cold feed entrance is positioned at hot feed entrance top, and number of theoretical plate is from tower top to the tower truth of a matter.
The further technical characterictic of the present invention is: described ethylene distillation column overhead working pressure is 0.01～2.0MPa, is preferably 1.1～1.8MPa; Ethylene rectification tower column bottom temperature is-50 DEG C～50 DEG C, is preferably-30～30 DEG C; Ethylene rectification tower return tank service temperature is-60～-10 DEG C, is preferably-50～-20 DEG C; Mole reflux ratio is 0.1～500.
The further technical characterictic of the present invention is: described ethylene rectification tower is divided into two sections, and tower top is rectifying section to feed entrance, and feed entrance is stripping section at the bottom of tower, and ethylene rectification tower has 70～100 theoretical stages, and its opening for feed is opened at 50-70 piece theoretical stage place; Lateral line withdrawal function mouth is opened at 2-15 piece theoretical stage place, and number of theoretical plate is from tower top to the tower truth of a matter.
The further technical characterictic of the present invention is: propylene rectification tower tower top working pressure of the present invention is 0.01～2.0MPa, is preferably 1.0～1.7MPa; Propylene rectification tower column bottom temperature is 10 DEG C～100 DEG C, is preferably 30～70 DEG C.Propylene rectification tower return tank service temperature is 10～80 DEG C, is preferably 20～70 DEG C, and mole reflux ratio is 0.1～40.
The further technical characterictic of the present invention is: described propylene rectification tower is divided into two sections, tower top is rectifying section to feed entrance, feed entrance is stripping section at the bottom of tower, propylene rectification tower has 110～140 theoretical stages, its opening for feed is opened at 60-90 piece theoretical stage place, and number of theoretical plate is from tower top to the tower truth of a matter.
Low-carbon alkene logistics of the present invention can be provided by any conventional source.This low-carbon alkene logistics comprises that for example petroleum streams cracking or oxygenatedchemicals catalyzed reaction form low-carbon alkene.
To the process of alkene, oxygenate feed stream (being typically methyl alcohol or methyl alcohol blend) is converted into low-carbon alkene logistics at oxygenatedchemicals (as methyl alcohol).Low-carbon alkene logistics of the present invention comprises a large amount of ethene and propylene and a large amount of water, and low-carbon alkene logistics also includes methane, ethane, acetylene, propane, propine, mixed c 4, mixing carbon five, mix the hydrocarbons such as carbon six and hydrogen, carbon monoxide, carbonic acid gas, nitrogen, oxygen etc.Described water is that methanol oxidation changes into the common by product in low-carbon alkene.In addition, low-carbon alkene logistics also includes the various oxygenated by-products of dme in interior difference amount, and it is to cause due to incomplete conversion or undesirable side reaction.Described oxygenatedchemicals (the various oxygenatedchemicalss in low-carbon alkene logistics) comprises at least one organic compound, the latter comprises at least one Sauerstoffatom, as fatty alcohol, ether, carbonyl compound (aldehyde, ketone, carboxylic acid, carbonate, ester etc.).In the time that oxygenatedchemicals is alcohol, described alcohol comprises: have 1～10 carbon atom, the more preferably aliphatic part of 1～4 carbon atom.Representational alcohol is including, but not limited to fatty alcohol and the undersaturated corresponding part thereof of lower straight and side chain.The example of suitable oxygenatedchemicals includes, but are not limited to: methyl alcohol, ethanol, n-propyl alcohol, Virahol, C4～C20 alcohol, methyl ethyl ether, dme, diethyl ether, diisopropyl ether, methyl-formiate, ethyl acetate, formaldehyde, acetaldehyde, propionic aldehyde, butyraldehyde, acetone, methylethylketone, pentanone, hexanone, acetic acid, propionic acid, butyric acid and composition thereof.Preferred oxygenatedchemicals is methyl alcohol, dme, ethanol, Virahol, propionic aldehyde, acetic acid, acetone, methylethylketone, pentanone, hexanone or its mixture.
Low-carbon alkene logistics of the present invention can be directly that oxygenatedchemicals is converted into the low-carbon alkene logistics that olefine reaction system produces, and now low-carbon alkene logistics water content is high, and water weight content is greater than 50%, but is generally less than 60%.Low-carbon alkene logistics of the present invention can be also that oxygenatedchemicals is converted into low-carbon alkene logistics that olefine reaction system produces by contact the low-carbon alkene logistics of having removed after most of water and other undesired oxygenated by-products from low-carbon alkene product with quenching medium.In now low-carbon alkene logistics, water weight content is less than 50%.
Oxygenatedchemicals, water and the C of removing of the present invention 4and C 4low-carbon alkene logistics after above hydro carbons can be directly oxygenatedchemicals be converted into olefine reaction system produce low-carbon alkene logistics remove oxygenatedchemicals, water and the C including methyl alcohol and dme by the method described in number of patent application 200910065721.X or other method 4and C 4low-carbon alkene logistics after above hydro carbons; Also can be that oxygenatedchemicals is converted into into low-carbon alkene logistics that olefine reaction system produces by contact the low-carbon alkene logistics of having removed after most of water and other undesired oxygenated by-products from low-carbon alkene product with quenching medium, then remove oxygenatedchemicals, water and the C including methyl alcohol and dme by the method described in number of patent application 200910065721.X or other method 4and C 4low-carbon alkene logistics after above hydro carbons.From low-carbon alkene logistics, remove oxygenatedchemicals, water and C including methyl alcohol and dme 4and C 4method after above hydro carbons, those skilled in the art can select as the case may be, can adopt the method described in number of patent application 200910065721.X, also can adopt other method.
The separating technology of a kind of converting methanol to prepare low carbon olefin gas logistics of the present invention.Be specially adapted to from comprise hydrogen, oxygen, nitrogen, carbon monoxide, carbonic acid gas, methane, ethane, ethene, acetylene, propane, propylene, cyclopropane, propine and propadiene one or more mixture (be oxygenatedchemicals be converted into that olefine reaction system produces remove oxygenatedchemicals, water and C 4and C 4low-carbon alkene logistics after above hydro carbons) middle ethene, the propylene of reclaiming.It compared with prior art has following beneficial effect:
1) technique of the present invention can obtain the propylene product of ethylene product and the polymerization-grade of polymerization-grade.
2) technique of the present invention is in obtaining the ethene and propylene of polymerization-grade, and can also obtain molar content is more than 90% methane, and obtaining molar content is more than 85% ethane, and obtaining molar content is more than 90% propane.Methane, ethane and propane that purity is higher are all important Organic Chemicals, have avoided these materials to use as cheap fuel.Obtaining molar content is more than 90% hydrogen, and this hydrogen can be made ammonia synthesis hydrogen feed, and also can obtain molar content by pressure-swing absorption apparatus or membrane separation unit is more than 99.9% highly purified hydrogen.
3) technique of the present invention has been considered regenerated flue gas this important factor in low-carbon alkene logistics of bleeding, and adds deoxidation equipment in scheme, avoids oxygen and hydro carbons combustible material at low temperature and in having the ice chest of certain pressure, too assembles and set off an explosion.
4) technique of the present invention has considered that in MTO gas, carbon monoxide content, higher than this important factor of naphtha cracking gas, added removal of carbon monoxide equipment before entering ice chest, has reduced the cryogen amount required for cooling carbon monoxide.
5) technique of the present invention can with existing oxygenatedchemicals, water and the C of removing 4and C 4the method combination of above hydro carbons, after deethanizer bottoms stream hydrogenation and removing propine and propadiene, directly enters propylene rectification tower.Save depropanizing tower, reduced equipment cost and running cost.
6) technical process of the present invention is reasonable, and in flow process, each knockout tower is arranged according to the size of liquid Equilibrium, and light constituent is removed one by one, saves utility cost.
7), compared with the disclosed method of CN1833017A, technique of the present invention is owing to there not being C in ice chest 4and C 4above hydro carbons, the ice chest blockage problem that can not occur to be caused by heavy constituent; Also reduced the component that enters cold-zone, made demethanizing tower more stable.Because there is not C in hydrogenation convertor (acetylene hydrogenation reactor and propine hydrogenator) 4and C 4above hydro carbons, has avoided catalyzer green coke in hydrogenation convertor, and research shows, C 4and C 4above hydro carbons, thus particularly the unsaturated hydro carbons such as divinyl can cause catalyzer green coke inactivation.In addition, in technique of the present invention there is not C in demethanizing tower and follow-up deethanizing column and propylene rectification tower 4and C 4above hydro carbons, has reduced energy consumption.
8) technique of the present invention is compared with the disclosed method of CN1833017A, because the former removes oxygen compound, water and C 4and C 4low-carbon alkene logistics after above hydro carbons is containing dme, avoided dme in depress and can form inflammable and explosive superoxide, thereby eliminated it, device is brought to uncertain hidden danger.Reduce system unsafe factor.
9), compared with common naphtha cracking air pressure contracting and deep cooling separating method, technique of the present invention has reduced four sections, compressor and five section feedings load significantly, has increased significantly hydrogen recovery rate.Prevent that hydrogen from more entering in demethanizing tower top methane gas, thereby reduced the content of ethene in demethanizing tower top methane gas, avoided ethylene loss.Because the 5th separating tank bottom liquid that contains a small amount of ethene is as demethanizing tower charging instead of as outside low-pressure methane tail gas discharger, also avoid ethylene loss.
10) alkali lye that in technique of the present invention, alkali cleaning adopts is that concentration is that aqueous sodium hydroxide solution or the concentration of 0.001～50 % by weight is the potassium hydroxide aqueous solution of 0.001～50 % by weight, instead of pure cerium hydroxide sodium or pure cerium hydroxide potassium.Can play the dual function of washing part of smoke and alkali cleaning carbonic acid gas.Avoid because of the high occluding device logistics corridor of concentration of lye.
11) what technique of the present invention can be used for that oxygenatedchemicals is converted into that olefine reaction system produces removes oxygenatedchemicals, water and C 4and C 4low-carbon alkene logistics after above hydro carbons; What also can be used for that other device produces contains one or more the lighter hydrocarbons logistics of mixture in hydrogen, oxygen, nitrogen, carbon monoxide, carbonic acid gas, methane, ethane, ethene, acetylene, propane, propylene, cyclopropane, propine and propadiene.
12) technique of the present invention is not added any absorption agent or sorbent material and is removed and remove oxygenatedchemicals, water and C in demethanizing tower 4and C 4any impurity in low-carbon alkene logistics after above hydro carbons, has avoided removing oxygenatedchemicals, water and C 4and C 4the loss that in low-carbon alkene logistics after above hydro carbons, staple product component ethene and propylene cause because adding absorption agent or sorbent material.Therefore, adopt the method for the invention, remove oxygenatedchemicals, water and C 4and C 4in low-carbon alkene logistics after above hydro carbons, staple product component ethene and propylene loss are minimum.
Describe the present invention in detail below by the drawings and specific embodiments, but do not limit the scope of the invention.
Accompanying drawing and brief description of the drawings
Fig. 1 is that publication number is the figure in the patent application of CN1833017A.
Fig. 2 and Fig. 3 are a kind of simple flow chart of technical solution of the present invention.
Shown in Fig. 2 and Fig. 3, Reference numeral is:
1-low-carbon alkene logistics pipeline, 2-the first moisture eliminator, 3-First Heat Exchanger, 4-removal of carbon monoxide tank, 5-the first water cooler, 6-the second moisture eliminator, 7-deoxidation tank, 8-the second interchanger, 9-soda-wash tower, 10-alkali lye, 11-Purified Water, the residual alkali lye of 12-, 13-the 3rd interchanger, 14-the 3rd moisture eliminator, 15-the second water cooler, 16-demethanizing tower bottom reboiler, 17-propylene water cooler, 18-the first ethylene chiller, 19-the first ice chest, 20-the first separating tank, 21-the second ice chest, 22-the second ethylene chiller, 23-the second separating tank, 24-the 4th interchanger, four sections and five sections, 25-compressor, five sections of compressed gas water coolers of 26-, 27-the 3rd ice chest, 28-triethylene water cooler, 29-the 3rd separating tank, 30-the 4th ice chest, 31-the 4th separating tank, 32-the 5th ice chest, 33-the 5th separating tank, 34-the 6th ice chest, 35-the 6th separating tank, 36-valve, 37-the first topping-up pump, 38-the second topping-up pump, 39-demethanizing tower, 40-demethanizing tower condenser, 41-demethanizing tower return tank, 42-demethanizing tower reflux pump, 43-methane decompressor, 44-methane gaseous products, 45-low-pressure methane product, the thick hydrogen production of 46-, 47-demethanizing tower tower base stream pipeline, 48-demethanizing tower tower base stream pump, 49-cold feed interchanger, 50-deethanizing column, 51-hot feed interchanger, 52-deethanizing column bottom reboiler, 53-deethanizing column condenser, 54-deethanizing column return tank, 55-deethanizing column reflux pump, 56-acetylene hydrogenation reactor hydrogen make-up, 57-reaction product interchanger, 58-steam heater, 59-acetylene hydrogenation reactor, 60-water cooler, 61-green oil tank, 62-green oil, 63-moisture eliminator, 64-ethylene rectification tower feed exchanger, 65-ethylene rectification tower, 66-ethylene rectification tower bottom reboiler, 67-ethane liquid-phase product, 68-ethylene rectification tower condenser, 69-ethylene rectification tower return tank, 70-ethylene rectification tower reflux pump, 71-ethylene rectification tower backflow tank deck non-condensable gas, 72-ethene liquid-phase product, 73-deethanizer bottoms stream pump, 74-carbon 3 material interchanger, 75-carbon 3 material moisture eliminator, 76-carbon 3 material water cooler, 77-propine hydrogenator hydrogen make-up, 78-propine hydrogenator, 79-reaction product water cooler, 80-vapor-liquid separation tank, 81-remaining hydrogen, 82-topping-up pump, 83-methane stripper feed exchanger, 84-methane stripper, 85-methane stripper bottom reboiler, 86-methane stripper condenser, 87-methane stripper return tank, 88-methane stripper reflux pump, 89-is containing the non-condensable gas of methane and hydrogen, 90-methane stripper tower base stream pump, 91-propylene rectification tower feed exchanger, 92-propylene rectification tower, 93-propane liquid-phase product, 94-propylene rectification tower condenser, 95-propylene rectification tower return tank, 96-propylene rectification tower reflux pump, 97-propylene gaseous products, 98-propylene rectification tower bottom reboiler.
Embodiment
As shown in Figure 2, in Fig. 2, four sections and five section 25, compressor is arranged between the second separating tank 23 and the 3rd separating tank 29.Four sections and five section 25, compressor also can be arranged between the first separating tank 20 and the second separating tank 23, or be arranged between the 3rd separating tank 29 and the 4th separating tank 31, or be arranged between the 4th separating tank 31 and the 5th separating tank 33, or be arranged between the 5th separating tank 33 and the 6th separating tank 35.Except comprising ethene and propylene, also comprise that in hydrogen, oxygen, nitrogen, carbon monoxide, carbonic acid gas, methane, ethane, acetylene, propane, cyclopropane, propine and propadiene, one or more mixture removes oxygenatedchemicals, water and C as converting methanol to prepare low carbon olefin gas 4and C 4low-carbon alkene logistics after above hydro carbons is (in-built through the first moisture eliminator 2 by low-carbon alkene logistics pipeline 1
Figure BSA00000449562000131
molecular sieve) carry out primary dewatering (note: water is the minor amount of water that low-carbon alkene logistics is carried secretly), after First Heat Exchanger 3 heat exchange, enter removal of carbon monoxide tank 4 (in-built removal of carbon monoxide Cu-series catalyst, as C18 catalyzer) slough part carbon monoxide, enter the second moisture eliminator 6 through the cooled low-carbon alkene logistics of the first water cooler 5 (in-built molecular sieve) carry out centre dehydration, (in-built nickel is that dehydrogenation catalyst or manganese are dehydrogenation catalyst then to enter deoxidation tank 7 tops.It is preferential that to use manganese be dehydrogenation catalyst) bring the oxygen (requiring oxygen level to be not more than 1 μ g/g) in flue gas while removing MTO device catalyst regeneration into, after the second interchanger 8 heat exchange, remove residual alkali lye through soda-wash tower 9 bottom alkali cleaning section decarbonations and soda-wash tower 9 top washing sections from the low-carbon alkene logistics out of deoxidation tank 7 bottoms.Alkali lye 10 is entered on soda-wash tower 9 alkali cleaning section tops; Purified Water 11 is entered on washing section top.Soda-wash tower 9 bottoms go out residual alkali lye 12.After mixing, the remaining hydrogen 81 that low-carbon alkene logistics from carbon dioxide removal and the residual alkali lye out of soda-wash tower 9 tops comes with the ethylene rectification tower backflow tank deck non-condensable gas 71 of ethylene rectification tower return tank 69, vapor-liquid separation tank 80 tops and the non-condensable gas 89 containing methane and hydrogen of methane stripper return tank 87 enter the 3rd interchanger 13.Then enter the 3rd moisture eliminator 14 from top (in-built
Figure BSA00000449562000141
molecular sieve) carry out deep dehydration (control water-content be less than 1 μ g/g).Enter the second water cooler 15 from the 3rd moisture eliminator 14 bottoms low-carbon alkene logistics out cooling.Then be divided into two-way.Mix with another road after the first ice chest 19 is cooling on one tunnel.Mix through demethanizing tower bottom reboiler 16, the cooling Hou Yu of propylene water cooler 17 mono-tunnel successively on another road, enters afterwards the first separating tank 20 after the first ethylene chiller 18 is cooling.After the first topping-up pump 37 pressurizations, enter demethanizing tower 39 middle and upper parts from the first separating tank 20 bottoms liquid out, this demethanizing tower opening for feed is the 5th opening for feed (according to demethanizing tower 39 Ser.No. from top to bottom, lower same).Enter second separating tank 23 through the second ice chest 21 and the second ethylene chiller 22 after cooling from the first separating tank 20 tops gas out.After the second topping-up pump 38 pressurizations, enter demethanizing tower 39 middle and upper parts from the second separating tank 23 bottoms liquid out, this demethanizing tower opening for feed is the 4th opening for feed, is positioned at the 5th opening for feed top.After the 4th interchanger 24 heat exchange, enter four sections, compressor and five section 25 pressurization from the second separating tank 23 tops gas out, from four sections and five section 25, compressor, the gases of five sections of outlets enter the 3rd separating tank 29 successively after five sections of compressed gas water coolers 26, the 3rd ice chest 27 and triethylene water cooler 28 are cooling.Enter demethanizing tower 39 tops from the 3rd separating tank 29 bottoms liquid out, this demethanizing tower opening for feed is the 3rd opening for feed, is positioned at the 4th opening for feed top.After the 4th ice chest 30 is cooling, enter the 4th separating tank 31 from the 3rd separating tank 29 tops gas out.Enter demethanizing tower 39 tops from the 4th separating tank 31 bottoms liquid out, this demethanizing tower opening for feed is the second opening for feed, is positioned at the 3rd opening for feed top.After the 5th ice chest 32 is cooling, enter the 5th separating tank 33 from the 4th separating tank 31 tops gas out.Enter demethanizing tower 39 tops from the 5th separating tank 33 bottoms liquid out, this demethanizing tower opening for feed is the first opening for feed, is positioned at the second opening for feed top.After the 6th ice chest 34 is cooling, enter the 6th separating tank 35 from the 5th separating tank 33 tops gas out.After the 6th ice chest 34, the 5th ice chest 32, the 4th ice chest 30, the 3rd ice chest 27, the second ice chest 21 and the first ice chest 19 heat exchange, deliver to outside device through low-pressure methane compressor (not shown) as low-pressure methane product 45 successively after valve 36 reduces pressure throttling from the 6th separating tank 35 bottoms liquid out.From the 6th separating tank 35 tops out be that more than 90% gas is delivered to outside device as thick hydrogen production 46 successively after the 6th ice chest 34, the 5th ice chest 32, the 4th ice chest 30, the 3rd ice chest 27, the second ice chest 21 and the first ice chest 19 heat exchange containing a small amount of nitrogen and hydrogen molar content; Also can deliver to pressure-swing absorption apparatus or membrane separation unit and further purify that to obtain molar content be more than 99.9% highly purified hydrogen.
What demethanizing tower 39 tower tops produced contains methane and a small amount of nitrogen, hydrogen, the gaseous mixture of carbon monoxide and ethene, after the cooling and condensation of demethanizing tower condenser 40, enter demethanizing tower return tank 41, the liquid phase of demethanizing tower return tank 41 is returned to demethanizing tower 39 tower tops as refluxing after 42 pressurizations of demethanizing tower reflux pump, the methane gas phase product stream of demethanizing tower return tank 41 temperature after methane decompressor 43 expands is reduced to-120～-160 DEG C, then enter successively the 5th ice chest 32 as cryogen, the 4th ice chest 30, the 3rd ice chest 27, the second ice chest 21 and the first ice chest 19 heat exchange.Methane gaseous products 44 after heat exchange is as Organic Chemicals or fuel gas carrying device.The liquid mixture containing ethane, ethene, acetylene, propane, cyclopropane, propylene, propine and propadiene producing at the bottom of demethanizing tower 39 towers enters the flow process shown in Fig. 3 by demethanizing tower tower base stream pipeline 47.
As shown in Figure 3, the liquid mixture containing ethane, ethene, acetylene, propane, cyclopropane, propylene, propine and propadiene producing at the bottom of demethanizer is divided into two-way by demethanizing tower tower base stream pipeline 47 and enters deethanizing column 50 after 48 pressurizations of demethanizing tower tower base stream pump.Wherein a road is cold liquid mixture, after 49 heat exchange of cold feed interchanger, enters deethanizing column 50 middle and upper parts as cold feed; Another road is hot liquid mixture, after 51 heat exchange of hot feed interchanger, enters deethanizing column 50 middle and lower parts as hot feed.Deethanizing column bottom reboiler 52 utilizes steam or circulating water heating.The gaseous mixture containing ethene, ethane and acetylene that deethanizing column 50 tower tops produce, after the cooling and condensation of deethanizing column condenser 53, enter deethanizing column return tank 54, the liquid phase of deethanizing column return tank 54 is returned to deethanizing column 50 tower tops as refluxing after 55 pressurizations of deethanizing column reflux pump, and the gas phase of deethanizing column return tank 54 is the gas phase mixture logistics containing ethene, ethane and acetylene.If be less than 1ppm containing acetylene molar content in the gas phase mixture logistics of ethene, ethane and acetylene, directly pass through moisture eliminator 63 containing the gas phase mixture logistics of ethene, ethane and acetylene (in-built molecular sieve) enter ethylene rectification tower 65 after dry and ethylene rectification tower feed exchanger 64 heat exchange, if containing ethene, in the gas phase mixture product of ethane and acetylene, acetylene molar content is more than or equal to 1ppm, containing ethene, the gas phase mixture logistics of ethane and acetylene is as the raw material of acetylene hydrogenation reactor 59, first allocate acetylene hydrogenation reactor hydrogen make-up 56 into, both pass through reaction product interchanger 57 and acetylene hydrogenation reactor 59 product heat exchange after mixing, after steam heater 58 heating, enter acetylene hydrogenation reactor 59 (in-built BC-H-20 catalyst series, as BC-H-20A catalyzer, BC-H-20A1 catalyzer and BC-H-20B catalyzer etc., the preferential BC-H-20B catalyzer that uses) top.The gaseous mixture containing ethene, ethane that acetylene hydrogenation reactor 59 bottoms produce enters green oil tank 61 after the charging heat exchange by reaction product interchanger 57 and acetylene hydrogenation reactor 59 again after water cooler 60 is cooling.Enter again moisture eliminator 63 from green oil tank 61 tops gaseous mixture out (in-built
Figure BSA00000449562000152
molecular sieve) top.By 64 heat exchange of ethylene rectification tower feed exchanger, enter ethylene rectification tower 65 from moisture eliminator 63 bottoms gaseous mixture out.The green oil 62 that green oil tank 61 bottoms produce can be used as the raw material of converting methanol to prepare low carbon olefin device or delivers to outside device, the preferential raw material as converting methanol to prepare low carbon olefin device.
Ethylene rectification tower bottom reboiler 66 utilizes circulating water heating.At the bottom of ethylene rectification tower 65 towers, going out ethane molar content is more than 85% ethane liquid-phase product 67, delivers to outside device as Organic Chemicals.
The gaseous mixture containing ethene, ethane, methane and hydrogen that ethylene rectification tower 65 tower tops produce, after the cooling and condensation of ethylene rectification tower condenser 68, enter ethylene rectification tower return tank 69, the liquid phase of ethylene rectification tower return tank 69 is returned to ethylene rectification tower 65 tower tops as backflow after 70 pressurizations of ethylene rectification tower reflux pump, and the vapour phase of ethylene rectification tower return tank 69 is the entrance that ethylene rectification tower backflow tank deck non-condensable gas 71 (non-condensable gas of hydrogen and methane) returns to the 3rd interchanger 13.The ethene molar content of ethylene rectification tower 65 top side line extraction is more than 99.95% ethene liquid-phase product 72, delivers to outside device or preferentially enters polyethylene device as the raw material of polyethylene device.
At the bottom of deethanizing column 50 towers, go out the liquid mixture containing propylene, propane, cyclopropane, propine and propadiene, if its propine molar content is less than 5ppm and propadiene molar content is less than 10ppm, at the bottom of deethanizing column 50 towers the liquid mixture containing propylene, propane, cyclopropane, propine and propadiene out through deethanizer bottoms stream pump 73 pressurize and 74 heat exchange of carbon 3 material interchanger after, enter carbon 3 material moisture eliminator 75 (in-built
Figure BSA00000449562000161
molecular sieve) bottom, from carbon 3 material moisture eliminator 75 tops, the liquid mixture containing propylene, propane, cyclopropane, propine and propadiene of sloughing after the minor amount of water of carrying secretly C3 fraction out directly enters propylene rectification tower 92 after 91 heat exchange of propylene rectification tower feed exchanger; If its propine molar content is more than or equal to 5ppm or propadiene molar content while being more than or equal to 10ppm, at the bottom of deethanizing column 50 towers the liquid mixture containing propylene, propane, cyclopropane, propine and propadiene out through deethanizer bottoms stream pump 73 pressurize and 74 heat exchange of carbon 3 material interchanger after, enter carbon 3 material moisture eliminator 75 (in-built
Figure BSA00000449562000162
molecular sieve) bottom.From carbon 3 material moisture eliminator 75 tops out slough after the minor amount of water of carrying secretly C3 fraction containing propylene, propane, cyclopropane, the liquid mixture of propine and propadiene, after carbon 3 material water cooler 76 is cooling, mix with one recycle stream of topping-up pump 82, then allocate propine hydrogenator hydrogen make-up 77 into, enter propine hydrogenator 78 (in-built BC-L-83 catalyzer or BC-H-30A catalyzer, the preferential BC-H-30A catalyzer that uses) top, after shortening removes propine and propadiene, propine hydrogenator 78 bottoms out containing propylene, the gas-fluid two-phase mixture of propane enters reaction product water cooler 79, then enter vapor-liquid separation tank 80.Vapor-liquid separation tank 80 tops vapour phase is out the entrance that remaining hydrogen 81 removes the 3rd interchanger 13; Vapor-liquid separation tank 80 bottoms liquid phase is out divided into two strands after topping-up pump 82 superchargings, one turns back to the entrance of propine hydrogenator 78, another stock-traders' know-how methane stripper feed exchanger 83 enters methane stripper 84, and methane stripper bottom reboiler 85 utilizes steam or circulating water heating.Enter propylene rectification tower 92 from logistics out at the bottom of methane stripper 84 towers by 90 pressurizations of methane stripper tower base stream pump and 91 heat exchange of propylene rectification tower feed exchanger.What methane stripper 84 tower tops produced enters methane stripper return tank 87 through methane stripper condenser 86 after cooling and condensation containing the gas phase mixture of methane, hydrogen and C3 fraction, the liquid phase of methane stripper return tank 87 is returned to methane stripper 84 tower tops as backflow after 88 pressurizations of methane stripper reflux pump, and the vapour phase of methane stripper return tank 87 is to return to the entrance of the 3rd interchanger 13 containing the non-condensable gas 89 of methane and hydrogen.
The gaseous mixture that contains propylene, propane that propylene rectification tower 92 tower tops produce, after the cooling and condensation of propylene rectification tower condenser 94, enter propylene rectification tower return tank 95, the liquid phase of propylene rectification tower return tank 95 is returned to propylene rectification tower 92 tower tops as backflow after 96 pressurizations of propylene rectification tower reflux pump, the vapour phase of propylene rectification tower return tank 95 is that propylene molar content is more than 99.6% propylene product 97, delivers to outside device or preferentially enters polypropylene plant as the raw material of polypropylene plant.Propylene rectification tower bottom reboiler 98 utilizes steam or circulating water heating.At the bottom of propylene rectification tower 92 towers, go out propane molar content and be more than 90% propane liquid-phase product 93, deliver to outside device as Organic Chemicals.

Claims (63)

1. a separating technology for converting methanol to prepare low carbon olefin gas, is characterized in that comprising the steps:
1) converting methanol to prepare low carbon olefin gas logistics removes contained oxygenatedchemicals, water and C 4and C 4after above hydro carbons as low-carbon alkene logistics, carry out successively primary dewatering, heat exchange, removal of carbon monoxide, cooling and middle dehydration, then carry out deoxidation treatment, alkali cleaning and washing are carried out in low-carbon alkene logistics after deoxidation after heat exchange, after the low-carbon alkene logistics after alkali cleaning and washing mixes with vapour phase, the vapour phase of vapor-liquid separation tank and the vapour phase of methane stripper return tank of ethylene rectification tower return tank, become alkene mixture;
2) from step 1) alkene mixture through heat exchange, dehydration with cooling after enter the first separating tank and separate, the first separating tank top gas out enters the second separating tank after cooling, the second separating tank top gas out enters the 3rd separating tank after cooling, the 3rd separating tank top gas out enters the 4th separating tank after cooling, the 4th separating tank top gas out enters the 5th separating tank after cooling, the 5th separating tank top gas out enters the 6th separating tank after cooling, wherein the first separating tank bottom liquid out enters demethanizing tower middle and upper part through pump pressurization, the second separating tank bottom liquid out enters demethanizing tower middle and upper part, the 3rd separating tank bottom liquid out, the 4th separating tank bottom liquid and the 5th separating tank bottom liquid out out enters demethanizing tower top, opening for feed is arranged from bottom to top in turn along demethanizing tower middle and upper part and top, the 5th separating tank bottom liquid opening for feed is in the top, the 6th separating tank bottom liquid is out low-pressure methane product, the 6th separating tank top gas is out as thick hydrogen production,
3) gaseous mixture that demethanizer column overhead produces, after cooling and condensation, enter demethanizing tower return tank, the liquid phase of demethanizing tower return tank is returned to demethanizer column overhead as backflow, the gas phase of demethanizing return tank is methane gaseous products, demethanizing tower tower base stream enters deethanizing column, the gaseous mixture that deethanizer overhead produces, after cooling and condensation, enter deethanizing column return tank, the liquid phase of deethanizing column return tank is returned to deethanizer overhead as backflow, the gas phase of deethanizing column return tank is for containing ethene, the gas phase mixture logistics of ethane and acetylene, in the time that acetylene molar content is less than 1ppm, after drying and heat exchange, enter ethylene rectification tower, in the time that acetylene molar content is more than or equal to 1ppm, enter acetylene hydrogenation reactor, what acetylene hydrogenation reactor bottom produced contains ethene, after the gaseous mixture drying of ethane and heat exchange, enter ethylene rectification tower, ethylene rectification tower bottom product is ethane liquid-phase product, the lateral line withdrawal function ethylene product logistics of ethylene rectification tower top, deliver to device outer or as the raw material of polyethylene device, the gaseous mixture that ethylene distillation column overhead produces, after cooling and condensation, enter ethylene rectification tower return tank, the liquid phase of ethylene rectification tower return tank is returned to ethylene distillation column overhead as backflow, the vapour phase of ethylene rectification tower return tank is mixed with the low-carbon alkene logistics after alkali cleaning and washing,
4) deethanizer bottoms stream is the liquid mixture containing propylene, propane, cyclopropane, propine and propadiene, in the time that its propine molar content is less than 5ppm and propadiene molar content and is less than 10ppm, through pressurization, heat exchange, dry and again after heat exchange, enter propylene rectification tower; In the time that its propine molar content is more than or equal to 5ppm or propadiene molar content and is more than or equal to 10ppm, through pressurization, heat exchange, dry and cooling after, enter propine hydrogenator, propine hydrogenator bottom mixture flow out separates through vapor-liquid separation tank, the vapour phase of vapor-liquid separation tank is mixed with the low-carbon alkene logistics after alkali cleaning and washing, the liquid phase of vapor-liquid separation tank is divided into two strands after supercharging, one turns back to propine hydrogenator, after another stock-traders' know-how interchanger heat exchange, enters methane stripper;
5) at the bottom of methane stripper tower, logistics out enters propylene rectification tower after by pressurization and heat exchange, the gas phase mixture that methane stripper tower top produces enters methane stripper return tank after cooling and condensation, the liquid phase of methane stripper return tank is returned to methane stripper tower top as backflow after pressurization, and the vapour phase of methane stripper return tank is mixed with the low-carbon alkene logistics after alkali cleaning and washing;
6) gaseous mixture that propylene rectification tower tower top produces, after cooling and condensation, enter propylene rectification tower return tank, the liquid phase of propylene rectification tower return tank is returned to propylene rectification tower tower top as backflow after pressurization, the gas phase of propylene rectification tower return tank is propylene product logistics, and propylene rectification tower tower base stream is propane product stream;
Four sections, compressor and five sections are set between any two adjacent separating tanks in these 6 separating tanks of the first separating tank, the second separating tank, the 3rd separating tank, the 4th separating tank, the 5th separating tank and the 6th separating tank.
2. technique according to claim 1, it is characterized in that: described alkene mixture through heat exchange, dehydration and cooling after be divided into two-way, one tunnel the first ice chest is cooling, another road is cooling through demethanizing tower bottom reboiler, propylene water cooler successively, mix with the first via afterwards, then enter the first separating tank after the first ethylene chiller is cooling.
3. technique according to claim 1, is characterized in that: described the first separating tank top gas out enters the second separating tank through the second ice chest and the second ethylene chiller after cooling.
4. according to the technique described in claim 1 or 3, it is characterized in that: four sections, compressor and five sections are set between the first separating tank and the second separating tank, described the first separating tank top gas is out after heat exchange, enter four sections, compressor and five sections of pressurizations, then after five sections of compressed gas water coolers, the second ice chest and the second ethylene chiller are cooling, enter the second separating tank successively.
5. technique according to claim 1, is characterized in that: described the second separating tank top gas out enters the 3rd separating tank through the 3rd ice chest and triethylene water cooler after cooling.
6. technique according to claim 1 or 5, it is characterized in that: four sections, compressor and five sections are set between the second separating tank and the 3rd separating tank, described the second separating tank top gas is out after heat exchange, enter four sections, compressor and five sections of pressurizations, then after five sections of compressed gas water coolers, the 3rd ice chest and triethylene water cooler are cooling, enter the 3rd separating tank successively; The second separating tank bottom liquid out enters demethanizing tower middle and upper part after pump pressurization.
7. technique according to claim 1, is characterized in that: described the 3rd separating tank top gas out enters the 4th separating tank after the 4th ice chest is cooling.
8. according to the technique described in claim 1 or 7, it is characterized in that: four sections, compressor and five sections are set between the 3rd separating tank and the 4th separating tank, described the 3rd separating tank top gas is out after heat exchange, enter four sections, compressor and five sections of pressurizations, then enter the 4th separating tank through five sections of compressed gas water coolers and the 4th ice chest after cooling; The second separating tank bottom liquid out enters demethanizing tower middle and upper part after pump pressurization, and the 3rd separating tank bottom liquid out enters demethanizing tower top after pump pressurization.
9. technique according to claim 1, is characterized in that: described the 4th separating tank top gas out enters the 5th separating tank after the 5th ice chest is cooling.
10. according to the technique described in claim 1 or 9, it is characterized in that: four sections, compressor and five sections are set between the 4th separating tank and the 5th separating tank, described the 4th separating tank top gas is out after heat exchange, enter four sections, compressor and five sections of pressurizations, then enter the 5th separating tank through five sections of compressed gas water coolers and the 5th ice chest after cooling; The second separating tank bottom liquid out enters demethanizing tower middle and upper part after pump pressurization, and the 3rd separating tank bottom liquid and the 4th separating tank bottom liquid out out enters demethanizing tower top respectively after pump pressurization.
11. techniques according to claim 1, is characterized in that: described the 5th separating tank top gas out enters the 6th separating tank after the 6th ice chest is cooling.
12. according to the technique described in claim 1 or 11, it is characterized in that: four sections, compressor and five sections are set between the 5th separating tank and the 6th separating tank, described the 5th separating tank top gas is out after heat exchange, enter four sections, compressor and five sections of pressurizations, then enter the 6th separating tank through five sections of compressed gas water coolers and the 6th ice chest after cooling; The second separating tank bottom liquid out enters demethanizing tower middle and upper part through pump pressurization, and the 3rd separating tank bottom liquid, the 4th separating tank bottom liquid and the 5th separating tank bottom liquid out out out enters demethanizing tower top respectively after pump pressurization.
13. techniques according to claim 1, it is characterized in that: described the 6th separating tank bottom liquid out, after decompression throttling, after the 6th ice chest, the 5th ice chest, the 4th ice chest, the 3rd ice chest, the second ice chest and the first ice chest heat exchange, deliver to outside device as low-pressure methane product successively.
14. according to the technique described in claim 1 or 13, it is characterized in that: described the 6th separating tank top gas is out delivered to outside device as thick hydrogen production successively after the 6th ice chest, the 5th ice chest, the 4th ice chest, the 3rd ice chest, the second ice chest and the first ice chest heat exchange; Or deliver to pressure-swing absorption apparatus or membrane separation unit and further purify that to obtain molar content be more than 99.9% highly purified hydrogen.
15. techniques according to claim 1, it is characterized in that: the gas phase of described demethanizing tower return tank temperature after methane decompressor expands is reduced to-120～-160 DEG C, then reclaim cold through the 5th ice chest, the 4th ice chest, the 3rd ice chest, the second ice chest and the first ice chest successively, as methane gaseous products, or as Organic Chemicals or fuel gas carrying device.
16. techniques according to claim 1, it is characterized in that: described demethanizing tower tower base stream is divided into two-way, one tunnel is cold liquid mixture, after the heat exchange of cold feed interchanger, enter deethanizing column middle and upper part as cold feed, another road is hot liquid mixture, after the heat exchange of hot feed interchanger, enters deethanizing column middle and lower part as hot feed.
17. techniques according to claim 1, it is characterized in that: the gaseous mixture containing ethene, ethane that described acetylene hydrogenation reactor bottom produces enters green oil tank after the charging heat exchange by interchanger and acetylene hydrogenation reactor again after cooling, from the gaseous mixture drying and heat exchange out of green oil tank top, enter ethylene rectification tower, the green oil that green oil pot bottom produces can be used as the raw material of converting methanol to prepare low carbon olefin device or delivers to outside device.
18. techniques according to claim 17, is characterized in that: the green oil that described green oil pot bottom produces is as the raw material of converting methanol to prepare low carbon olefin device.
19. techniques according to claim 1, is characterized in that: described deethanizing column bottom reboiler utilizes steam or circulating water heating.
20. techniques according to claim 1, is characterized in that: described ethylene rectification tower bottom reboiler utilizes circulating water heating.
21. techniques according to claim 1, is characterized in that: described ethylene rectification tower bottom product is that ethane content is 85 % by mole of above ethane liquid-phase products, delivers to outside device as Organic Chemicals.
22. techniques according to claim 1, is characterized in that: described propylene rectification tower bottom reboiler utilizes steam or circulating water heating.
23. techniques according to claim 1, is characterized in that: described propylene rectification tower tower base stream is that propane content is 90 % by mole of above propane liquid-phase products, delivers to outside device as Organic Chemicals.
24. techniques according to claim 1, is characterized in that: described the first separating tank working pressure is 0.01～4.0MPa, and service temperature is-100～30 DEG C.
25. according to the technique described in claim 1 or 24, it is characterized in that: described the first separating tank working pressure is 0.1～2.0MPa, and service temperature is-80～10 DEG C.
26. techniques according to claim 1, is characterized in that: described the second separating tank working pressure is 0.01～4.0MPa, and service temperature is-130～0 DEG C.
27. according to the technique described in claim 1 or 26, it is characterized in that: described the second separating tank working pressure is 0.1～2.0MPa, and service temperature is-110～-20 DEG C.
28. techniques according to claim 1, is characterized in that: described the 3rd separating tank working pressure is 0.01～4.0MPa, and service temperature is-170～-30 DEG C.
29. according to the technique described in claim 1 or 28, it is characterized in that: described the 3rd separating tank working pressure is 2.0～4.0MPa, and service temperature is-160～-60 DEG C.
30. techniques according to claim 1, is characterized in that: described the 4th separating tank working pressure is 0.01～4.0MPa, and service temperature is-180～-40 DEG C.
31. according to the technique described in claim 1 or 30, it is characterized in that: described the 4th separating tank working pressure is 2.0～4.0MPa, and service temperature is-170～-70 DEG C.
32. techniques according to claim 1, is characterized in that: described the 5th separating tank working pressure is 0.01～4.0MPa, and service temperature is-190～-50 DEG C.
33. according to the technique described in claim 1 or 32, it is characterized in that: described the 5th separating tank working pressure is 2.0～4.0MPa, and service temperature is-180～-80 DEG C.
34. techniques according to claim 1, is characterized in that: described the 6th separating tank working pressure is 0.01～4.0MPa, and service temperature is-200～-60 DEG C.
35. according to the technique described in claim 1 or 34, it is characterized in that: described the 6th separating tank working pressure is 2.0～4.0MPa, and service temperature is-190～-90 DEG C.
36. techniques according to claim 1, is characterized in that: described low-carbon alkene logistics removal of carbon monoxide adopts removal of carbon monoxide Cu-series catalyst.
37. according to the technique described in claim 1 or 36, it is characterized in that: described low-carbon alkene logistics removal of carbon monoxide adopts C18 catalyzer.
38. techniques according to claim 1, is characterized in that: it is that dehydrogenation catalyst or manganese are dehydrogenation catalyst that described low-carbon alkene logistics deoxidation treatment adopts nickel.
39. according to the technique described in claim 1 or 38, it is characterized in that: it is dehydrogenation catalyst that described low-carbon alkene logistics deoxidation treatment adopts manganese.
40. techniques according to claim 1, is characterized in that: the dehydration of described low-carbon alkene logistics or dry all adopt 3 molecular sieve.
41. techniques according to claim 1, is characterized in that: the alkali cleaning of described low-carbon alkene logistics and washing are carried out in soda-wash tower, and soda-wash tower bottom is that alkali cleaning section is carried out alkali cleaning, and soda-wash tower top is that washing section is washed, the water inlet of washing section top.
42. according to the technique described in claim 41, it is characterized in that: alkali lye is entered on described soda-wash tower alkali cleaning section top, and alkali lye is that concentration is that aqueous sodium hydroxide solution or the concentration of 0.001～50 % by weight is the potassium hydroxide aqueous solution of 0.001～50 % by weight.
43. techniques according to claim 1, is characterized in that: described demethanizer column overhead working pressure is 0.01～5.0MPa, and demethanizing tower column bottom temperature is-60 DEG C～70 DEG C.
44. according to the technique described in claim 1 or 43, it is characterized in that: described demethanizer column overhead working pressure is 2.0～4.0MPa, and demethanizing tower column bottom temperature is-50～60 DEG C.
45. techniques according to claim 1, is characterized in that: described demethanizing tower return tank service temperature is-160～-60 DEG C, and mole reflux ratio is 0.01～40.
46. according to the technique described in claim 45, it is characterized in that: described demethanizing tower return tank service temperature is-150～-70 DEG C.
47. techniques according to claim 1, is characterized in that: described demethanizing tower has 30～60 theoretical stages.
48. techniques according to claim 1, is characterized in that: described demethanizing tower the first opening for feed is opened at 1-5 piece theoretical stage place; The second opening for feed is opened at 6-9 piece theoretical stage place; The 3rd opening for feed is opened at 10-14 piece theoretical stage place; The 4th opening for feed is opened at 15-20 piece theoretical stage place; The 5th opening for feed is opened at 21-26 piece theoretical stage place, and opening for feed and number of theoretical plate are all counted from top to bottom along demethanizing tower.
49. techniques according to claim 1, is characterized in that: described deethanizer overhead working pressure is 1.5～3.0MPa, and deethanizing column column bottom temperature is 0 DEG C～100 DEG C.
50. according to the technique described in claim 1 or 49, it is characterized in that: described deethanizer overhead working pressure is 1.7～2.5MPa, and deethanizing column column bottom temperature is 20～80 DEG C.
51. techniques according to claim 1, is characterized in that: described deethanizing column return tank service temperature is-60～0 DEG C, and mole reflux ratio is 0.01～40.
52. according to the technique described in claim 51, it is characterized in that: described deethanizing column return tank service temperature is-40～-10 DEG C.
53. techniques according to claim 16, it is characterized in that: described deethanizing column is divided into two sections, tower top is rectifying section to hot feed entrance, hot feed entrance is stripping section at the bottom of tower, deethanizing column has 20～50 theoretical stages, and cold feed entrance is opened at 3-20 piece theoretical stage place, and hot feed entrance is opened at 16-30 piece theoretical stage place, cold feed entrance is positioned at hot feed entrance top, and number of theoretical plate is from tower top to the tower truth of a matter.
54. techniques according to claim 1, is characterized in that: described ethylene distillation column overhead working pressure is 0.01～2.0MPa, and ethylene rectification tower column bottom temperature is-50 DEG C～50 DEG C.
55. according to the technique described in claim 1 or 54, it is characterized in that: described ethylene distillation column overhead working pressure is 1.1～1.8MPa; Ethylene rectification tower column bottom temperature is-30～30 DEG C.
56. techniques according to claim 1, is characterized in that: described ethylene rectification tower return tank service temperature is-60～-10 DEG C.
57. according to the technique described in claim 56, it is characterized in that: described ethylene rectification tower return tank service temperature is-50～-20 DEG C.
58. techniques according to claim 1, it is characterized in that: described ethylene rectification tower is divided into two sections, tower top is rectifying section to feed entrance, and feed entrance is stripping section at the bottom of tower, ethylene rectification tower has 70～100 theoretical stages, and its opening for feed is opened at 50-70 piece theoretical stage place; Lateral line withdrawal function mouth is opened at 2-15 piece theoretical stage place, and number of theoretical plate is from tower top to the tower truth of a matter.
59. techniques according to claim 1, is characterized in that: described propylene rectification tower tower top working pressure is 0.01～2.0MPa, and propylene rectification tower column bottom temperature is 10 DEG C～100 DEG C.
60. according to the technique described in claim 1 or 59, it is characterized in that: described propylene rectification tower tower top working pressure is 1.0～1.7MPa, and propylene rectification tower column bottom temperature is 30～70 DEG C.
61. techniques according to claim 1, is characterized in that: described propylene rectification tower return tank service temperature is 10～80 DEG C, and mole reflux ratio is 0.1～40.
62. according to the technique described in claim 61, it is characterized in that: described propylene rectification tower return tank service temperature is 20～70 DEG C.
63. techniques according to claim 1, it is characterized in that: described propylene rectification tower is divided into two sections, tower top is rectifying section to feed entrance, feed entrance is stripping section at the bottom of tower, propylene rectification tower has 110～140 theoretical stages, its opening for feed is opened at 60-90 piece theoretical stage place, and number of theoretical plate is from tower top to the tower truth of a matter.
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CN105276924B (en) * 2014-07-04 2017-09-01 中国石化工程建设有限公司 A kind of lighter hydrocarbons cryogenic separation retracting device and method
CN107285983B (en) * 2016-04-11 2020-06-16 中国石化工程建设有限公司 Production expansion process of propylene rectifying tower of gas fractionation device
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