CN101506344A - Cationic polymer stabilized microcapsule composition - Google Patents
Cationic polymer stabilized microcapsule composition Download PDFInfo
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- CN101506344A CN101506344A CNA2007800317503A CN200780031750A CN101506344A CN 101506344 A CN101506344 A CN 101506344A CN A2007800317503 A CNA2007800317503 A CN A2007800317503A CN 200780031750 A CN200780031750 A CN 200780031750A CN 101506344 A CN101506344 A CN 101506344A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to the use of a cationic polymer to provide stability to microcapsules in a composition, wherein the microcapsule comprises a shell encapsulating materials having an average ClogP of at least 2.5 and more than 60% by weight of the encapsulated materials have a Clog P of at least 3.3. The cationic polymer is derived from the polymerization of about 5 to 100 mole percent of a cationic vinyl addition monomer. 0 to about 95 percent acrylamide, and about 5 to about 500 ppm of a difunctional vinyl addition monomer cross-linking agent. The calionic polymer and encapsulated material may be used, for example, in a fabric softener composition.
Description
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] the application requires the right of priority of No. 11/479,679, the U.S. Patent application submitted on June 30th, 2006, and its content is attached to herein by reference.
Background of invention
[0002] know the consumer's goods in the art, fabric nursing articles for use, personal-care supplies and family articles for use of keeping a public place clean for example, they contain usually gives the consumer's goods and/or handles or one or more essence of the matrix fragrance of coating with the consumer's goods; But these essence in the consumer's goods or the matrix are passed disappearance in time.Another problem of essence is that they discharged before optimal release time in the consumer's goods, and the user of the consumer's goods can't experience the fragrance of essence.For example, need essence to be present in for a long time, and there is the trend of evaporation in time or diffusion in the essence in the clothing at the clothing of using after washing composition and/or fabric emulsifying agent are handled.
[0003] therefore, existing make minimum and make essence discharge the trial of fragrance the best because of essence loss due to volatility and the evaporation.A kind of such method is that essence is encapsulated in the shell, makes fragrance microcapsule.
[0004] be known in the art the theoretical log P (Clog P) of multiple essence, can be at for example Daylight Chemical Information Systems, Inc. (Daylight CIS) Irvine finds in Ponoma 92 databases that CA obtains.The also method of known calculations Clog P in the art.The bigger essence high volatility of the comparable Clog P of essence value that Clog P value is less, therefore water-soluble height is preferred for the consumer's goods.But when the less material of encapsulation ClogP, their leach or be diffused into the trend that shell enters the consumer's goods outward may strong (hindering the best of fragrance to discharge), and essence may finally be diffused into outside the consumer's goods before the human consumer uses.
[0005] developed the method that the essence that prevents in the fragrance microcapsule leaches.These methods can comprise one or more polymer-coated on shell inside or shell outside, or stablizer is mixed in the core.But there is continuous demand in the system that exploitation is discharged fragrance.The essence of more effective release system or more stable encapsulation can cause more effectively using essence, thereby reduces preparation cost.
[0006] contains solvent and/or tensio-active agent for example during the consumer's goods of shampoo when fragrance microcapsule is mixed, may produce stability problem.Packed essence may ooze out outside the shell.Shell also may absorb solvent, tensio-active agent or any other material in the consumer's goods, causes the integrity of shell impaired.Because other diffuse is in shell or core, shell also may expand, or because core material is diffused into outside the shell, shell also may shrink.Really, shell component even can be diffused in the consumer's goods.
[0007] similarly considers to be applied to use other material for example in the release of the micro-capsule of flavouring agent or antimicrobial substance that provides benefit for the human consumer.
[0008] therefore, need the development group compound, said composition is applicable in the composition that stability is provided for the micro-capsule that encapsulates fragrance or antimicrobial material and uses.
The invention summary
[0009] in one embodiment, the invention provides composition, said composition contains:
A. micro-capsule, this micro-capsule contain the shell that the average Clog P of encapsulation is at least about 2.5 material, and greater than the Clog P of 60% (weight) material be at least 3.3 and
B. cross-linked cationic type polymkeric substance, this polymkeric substance is obtained by the cationic vinyl addition of about 5-100% (mole) monomer, 0-about 95% (mole) acrylamide and monomer crosslinked dose of polymerization of the about 500ppm difunctional vinyl of about 5-addition.
[0010] in another embodiment, the invention provides the stability-enhanced method that makes the product that contains at least a micro-capsule, this method comprises makes product (before adding at least a micro-capsule, afterwards or simultaneously) with cross-linked cationic type mixed with polymers, this polymkeric substance is by the cationic vinyl addition of about 5-100% (mole) monomer, about 95% acrylamide of 0-and monomer crosslinked dose of polymerization of the about 500ppm difunctional vinyl of about 5-addition obtain, wherein micro-capsule contains the shell that the average ClogP of encapsulation is at least 2.5 material, and is at least 3.3 greater than the Clog P of 60% (weight) material.
Detailed Description Of The Invention
[0010] when using herein, scope is to use as the shorthand that is described in each value in this scope.Can select the terminal point of the interior any value of this scope as this scope.Unless otherwise indicated, the per-cent that below provides is total weight percent.
[0011] the present invention relates to the benefit by providing with cation type polymer in composition, said composition contains micro-capsule, and especially average Clog P is at least about 2.5 and be at least 3.3 micro-capsule greater than the Clog P of 60% (weight) material.Compare with the composition that lacks this cation type polymer, adding cation type polymer in composition has increased the stability of micro-capsule in the composition.
[0012] essence is known in the art, and can comprise odoriferous material, these materials can provide fragrance and/or give matrix fragrance to the consumer's goods, for example cologne, soap, reodorant, antiperspirant and the shower gels of the washing of the shampoo of treatment of hair and amendment, processing fabric and clothing washing composition and rinsing phase fabric softener, the glass cleaner of handling glass and crust, processing skin and hair.Essence also can be offset stench and/or fragrance is provided.Essence can be liquid state at ambient temperature, although solid essence also can be effective.Essence can comprise aldehydes, ketone, ester and other chemical substance and the compound that are known in the art, comprises natural, compound essence and composition thereof.Can be used for essence of the present invention and can have relatively simply composition, maybe can contain natural and the complex mixture synthetic chemistry composition, wherein all the components all is used for smell or fragrance being provided and/or offering matrix smell or fragrance at the consumer's goods.In this application, be appreciated that available spices as known in the art replaces essence, therefore term essence used herein also comprises spices.Usually, the essence that is present in the consumer's goods can be 0.00001-10%.
[0013] any aromatoising substance in being present in micro-capsule, preparation of the present invention also can comprise the not aromatoising substance of encapsulation.
[0014] fragrance microcapsule is known usually in the art, referring to for example WO/2004016234, US 2005/0153135, US 2005/0256027, US2004/0072719A1, US 2004/0072720A1, US 20040071742A1, US2004/0071746A1, US 6,194,375, WO 02/074430A1; US 6,620,777, and the content of each patent announcement is attached to herein by reference.Fragrance microcapsule has shell usually, and this shell is with essence and optional for example solvent, tensio-active agent, hydrophobic polymer and other material encapsulation as known in the art of other material.Shell can be considered to be made by the polymer strands set of densification, and its diameter can be less than 1000 μ m, and the mean diameter scope of these shells can be 1-500 μ m, preferred 1-300 μ m, more preferably 1-50 μ m, most preferably 1-10 μ m.Can regulate the size of shell by method as known in the art.The big young pathbreaker of preferred shell is depended on their intended purpose.
[0015] shell stops essence to ooze out from the consumer's goods usually.Shell also can with matrix bond, discharge essence under predetermined condition, promptly when the pressing fabric, the fragrance microcapsule on the fabric is broken suddenly because of temperature change, or when fabric was damaged, fragrance microcapsule was broken suddenly because of other physical/mechanical stress that friction, shearing or wearer's motion cause.
[0016] can prepare the micro-capsule shell by any currently known methods in this area.Shell can be polymkeric substance as known in the art or resin.By the shell of urethane, polymeric amide, polyolefine, polysaccharide, protein, polysiloxane, lipid, modified-cellulose, glue, polyacrylic ester, polyphosphate, polystyrene and polyester or combinations thereof applicable to the present invention.Preferred shell can be an aminoplastics, by make in the various kinds of amine as known in the art one or more aldehyde a kind of and as known in the art for example formaldehyde reaction form this aminoplastics.In preferred embodiments, can prepare aminoplastics by polycondensation.Preferred aminoplastics can be melamine-formaldehyde or urea-formaldehyde condensates, for example melamine resin or urea-formaldehyde resin.The preferred melamine resin of aminoplastics can use separately or use with following combinations of substances: other suitable amide as known in the art, linking agent as known in the art (for example tolylene diisocyanate, Vinylstyrene, diacrylate butanediol ester) and secondary polymerization thing as known in the art be the polymkeric substance and the multipolymer of maleic anhydride for example.Aminoplastics also can be the hybrid resin of urea aldehyde, copolymer-maleic anhydride and melamine-formaldehyde.
[0017] micro-capsule of the present invention has shell, and this shell has internal surface and outside surface.Can be with for example polymer-coated internal surface and/or outside surface at shell.Coating on internal surface and/or the outside surface can be improved the barrier of shell, therefore can increase the residence time of material in containing the tensio-active agent and/or the solvent-laden consumer's goods of encapsulation.
[0018] water-soluble polymers of band cationic charge as known in the art can be coated on the shell.Water-soluble polymers also can be an amphiphilic polymers, and this amphiphilic polymers has that to cause clean total charge be 0 and positive positively charged ion and anionic functional group's ratio.Also known in the art will be with the polymer-coated method on micro-capsule of cationic charge.
[0019] can coating be coated in the internal surface of shell capsule (she1lcapsule) by several different methods as known in the art.A kind of method as known in the art relates to and is used to the suitable material that is coated with, and this material is insoluble to material to be packaged, but water soluble soluble solvent for example ethanol, Trivalin SF, and they and material to be packaged are miscible.The coating that is generally polymkeric substance is dissolved in solvent, then solution is dissolved in material to be packaged.Then material to be packaged is emulsified into the aqueous solution of formation standard aminoplastics capsule.Along with emulsion forms, solvent and water sepn precipitates from solution at the surface aggregate thing of emulsion droplet and to separate out, at the interface formation film of the material of water/to be packaged.Can implement method for packing as known in the art then, coating can be deposited on the internal surface of shell.
[0020] in the another kind of method that is known in the art, the coating of use for example polysiloxane can with material unmixing to be packaged, and with the water unmixing, but can form film in water termination.Can be by material to be packaged be dispersed in the polysiloxane, then with this emulsifying mixture, so that the formation emulsion, wherein polysiloxane film surrounds the drop of the material of encapsulation, prepares the capsule encapsulant (encapsulate) that contains polysiloxane coating on the shell internal surface.Carry out encapsulation process by currently known methods in this area then.Perhaps, can add for example polysiloxane of second kind of material, allow it to apply the packaged material drop then, form film on the surface by material to be packaged is dispersed in the water.Also can prepare coating on inner surface, for example: poly-(ethene-maleic anhydride), polyvidone by film-forming polymer known in the art; Wax is polyoxyethylene glycol for example; Polyvinylpyrrolidone (PVP) and multipolymer thereof be polyvinylpyrrolidone-ethyl propenoate (PVP-EA) for example; The multipolymer of polyvinylpyrrolidone-vinyl acrylate, polyvinylpyrrolidone methacrylic ester (PVP-MA), polyvinylpyrrolidone/vinyl-acetic ester, polyvinylacetal, polyvinyl butyral acetal, polysiloxane, poly-(propylene maleic anhydride), maleic anhydride derivative and above material is polyvinyl methyl ether/maleic anhydride for example.Preferably, inside coating comprises polysiloxane, PVP or PVP multipolymer, more preferably PVP or PVP multipolymer, even more preferably PVP multipolymer, especially PVP-MA or PVP-EA.
[0021] can for example comprise spraying, fluidized-bed coating or precipitation by techniques known in the art, coating is applied to the outside surface of shell.For example coating for example polymer coating can be from aqueous solution for example with capsule slurry form precipitation, condense on the outside surface of shell or micro-capsule, and precipitation is by changing temperature, pH; Adding salt and other variable as known in the art and condition causes.Therefore before coating is coated on the outside surface of shell wall, independently forming shell capsule to be coated in the first step.According to the composition of external surface coating, can be by for example shell capsule of cohesion or polycondensation preparation coating.
[0022] external surface coating can comprise high molecular film-forming polymer as known in the art, their optionally crosslinkables." high molecular " expression molecular-weight average is preferably greater than 4000Da, more preferably greater than 5000Da greater than 2000Da.Polymkeric substance can be water-soluble or water-insoluble, preferably water dissolubility.The polymkeric substance that is suitable for can comprise polyvinyl alcohol (PVOH), styrene-butadiene latex, gelatin, gum arabic, carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, Natvosol, other modified-cellulose, sodiun alginate, chitosan, casein, pectin, treated starch, polyvinylacetal, polyvinyl butyral acetal, polyvinyl methyl ether/maleic anhydride, PVP and multipolymer thereof (polyvinylpyrrolidone/vinyl-acetic ester (PVP/VA) for example, gather (vinyl pyrrolidone/methylacrylic acid dimethylamino ethyl ester) (PVP/DMAEMA), poly-(vinyl pyrrolidone/methacrylamidopropyltrimethyl trimethyl ammonium chloride), melamine-formaldehyde and urea aldehyde.Preferably, be coated with the outside surface of shell with PVOH, PVP or PVP multipolymer.
[0023] shell of preferred coating can be the aminoplastics capsule, and this capsule has film-forming polymer (preferred PVP-EP) coating having on the outside surface of shell on PVOH, PVP or copolymer p VP (preferred PVP/DMAEMA) coating and/or the internal surface.
[0024] coating (internal layer and/or skin) can be crosslinked by any known way, for example by interface-cross-linked.In this article, effectively the shell outside surface of shell capsule can have more than one coating.
[0025] wall thickness of Tu Bu shell capsule is generally the about 30 μ m of about 0.01-, the about 5 μ m of preferably about 0.01-, the more preferably from about about 1 μ m of 0.03-, the most preferably from about about 0.5 μ m of 0.03-.Can regulate and the control wall thickness according to the encapsulant size with by changing the relative proportion of coating and shell polymeric.The weight ratio of coating and shell wall is generally the about 10:1 of about 0.01-, the about 10:1 of preferably about 0.1:1-, the more preferably from about about 3:1 of 0.1:1-.
[0026] common, the weight ratio of the material of polymer shell wall material and encapsulation is the about 3:2 of about 1:10-, the about 1:2 of preferably about 1:10-.Coating on internal surface and/or the outside surface will increase these weight ratios.
[0027] after shell applies, average Clog P value can be equal to or greater than 2.5, the material encapsulation of preferably about 3-about 5.It is about 3.3 that the material that is used for uncoated microcapsules can comprise that wherein the Clog P at least about 60% material is equal to or greater than, and is preferably greater than about 4 material." average Clog P " represents the average Clog P of the material of all encapsulation.Therefore, for example can have high ClogP for example about 6 or bigger solvent by adding, wherein the material of this solvent and other encapsulation is miscible, improves the average Clog P of the material of encapsulation.
[0028] in the present invention, can be used as the essence mixture and use one or more essence.Therefore, for micro-capsule with uncoated shell, can use the essence mixture, wherein greater than the Clog P of the spices of about 60% (weight) greater than about 3.3, the Clog P value that is preferably greater than about 80% (weight) spices is greater than about 4.0, more preferably greater than the Clog P value of about 90% (weight) spices greater than about 4.5.
[0029] contain core in the micro-capsule shell, core contains essence or other beneficial agent for example flavouring agent or antimicrobial substance, and can choose wantonly and contain other material as known in the art, for example for example triglyceride oil, monoglyceride and diester of hydrophobic solvent; Mineral oil, silicone oil, diethyl phthalate, polyalphaolefin, Fatty Alcohol(C12-C14 and C12-C18), Viscotrol C and Isopropyl myristate.Vehicle substance can be miscible with beneficial agent.For the micro-capsule with uncoated shell on interior or the outside surface, suitable solvent comprises those solvents that essence had appropriate avidity, and the Clog P of this kind solvent can be preferably greater than 6 greater than 3.3, most preferably greater than 10.Preferred solvent can be Isopropyl myristate.Preferred solvent also can be polysiloxane, as polydimethylsiloxane and polydimethylcyclosil.xane.In another embodiment of the invention, preferred solvent can be a diethyl phthalate.In core, solvent can be preferably greater than about 50% (weight) greater than about 30% (weight), more preferably greater than about 70% (weight).
[0030] in the art, the known hydrophobic polymer that adds in micro-capsule is by delaying the stability of essence diffusion also can raising micro-capsule in the shell.In micro-capsule, the amount of hydrophobic polymer can be less than 80%, preferably less than 50%, most preferably less than 20% (weight).Hydrophobic polymer can be the polymeric amide of ethyl cellulose, hydroxypropylcellulose, cellulose acetate butyrate, ethylene vinyl acetate, polystyrene and PVP and end capped polymeric amide of ester or amido end-blocking.
[0031] as previously mentioned, when the consumer's goods that micro-capsule added some solvent and/or contain tensio-active agent for example during shampoo, can cause stability problem.Therefore in the present invention, cation type polymer is added the consumer's goods, to increase micro-capsule stability.
[0032] cation type polymer is a cross-linked polymer among the present invention, and with about 5-500ppm, the about 300ppm of preferably about 70-, the about 200ppm of preferably about 75-, most preferably from about the difunctional vinyl addition monomer of the about 150ppm level of 80-makes crosslinked polymer.Cation type polymer can be cationic vinyl polymer.Cationic vinyl polymer can be obtained by about 5-100% (mole) cationic vinyl addition monomer and 0-about 95% (mole) acrylamide polymerization.Difunctional vinyl addition monomer can be 300-3 for weight-average molecular weight, 000 polyethyleneglycol diacrylate.
[0033] cation type polymer can be obtained by the cationic vinyl addition of about 5-100% (mole) monomer, 0-about 95% (mole) acrylamide and monomer crosslinked dose of polymerization of the about 300ppm difunctional vinyl of about 70-addition.Difunctional vinyl addition monomer can be the polyethyleneglycol diacrylate of weight-average molecular weight for about 300-about 3,000.
[0034] cation type polymer also can be a cross-linked cationic type vinyl addition polymer, and this polymkeric substance is obtained with the polymerization of about 0.005-about 0.025% (weight) polyethyleneglycol diacrylate by quaternary ammonium salt and about 30-about 85% (mole) acrylamide of about 15-about 70% (mole) dimethyl/amino-ethyl methacrylic acid ester.Polyethyleneglycol diacrylate can be a polyethylene glycol dimethacrylate.
[0035] cation type polymer can be made water-in-oil emulsion, wherein make cross-linked polymer be dispersed in oil, in the preferred mineral oil.Cation type polymer can be acrylate or methacrylate quaternary ammonium salt and acrylamide comonomer bonded cross-linking copolymer.Other argumentation that can be used for cation type polymer of the present invention can be at United States Patent (USP) 4,806, and 345 and 6,864, find for No. 223, this patent is attached to herein by reference.
[0036] composition can contain that to account for the about 0.001%-of gross weight about 40%, and preferably about 0.01%-is about 10%, more preferably from about the cation type polymer of 0.01%-about 5%.The amount of contained cation type polymer will depend on composition and use therein micro-capsule.Can be before micro-capsule adds the consumer's goods, during or afterwards, cation type polymer is mixed with the consumer's goods.
[0037] as described herein, cation type polymer is highly suitable for the various consumer's goods of knowing that contain micro-capsule, for example dental care products, toothpaste, mouthwash, personal care articles, lotion, ointment, shampoo, amendment, hair gel, antiperspirant, reodorant, shaving cream, hair jelly, cologne, body wash, home care product, washing washing composition, fabric softener, liquid dishwashing detergent, tumble dryer sheet, automatic dishwasher washing composition and hard surface cleaner.These consumer's goods can use tensio-active agent, solvent and the emulsifying system of knowing in this area.During using this product and afterwards, in consumer's goods matrix, use spices to provide joyful fragrance or cover the not well smell of some functional component that is used for product to the human consumer.As mentioned above, using the problem of encapsulated fragrance in product matrix is perfume loss before the Best Times that spices discharges.
[0038] in the present invention, micro-capsule can be in consumer's goods aqueous solution.Perhaps, micro-capsule can be in the external phase of the O/w emulsion of the consumer's goods.Perhaps, micro-capsule can be in the discontinuous phase of the O/w emulsion of the consumer's goods.Perhaps, micro-capsule can be in the discontinuous phase of the water-in-oil emulsion of the consumer's goods.Perhaps, micro-capsule can be in the external phase of the water-in-oil emulsion of the consumer's goods.
[0039] although use glycol, polyvalent alcohol, alcohol or silicone oil as main solvent or carrier in some product, the available hydrated matrix that contains tensio-active agent prepares the consumer's goods.Be used for suitable surfactant of the present invention and be included in the consumer's goods those tensio-active agents commonly used, for example washing washing composition, fabric softener etc.These products comprise the cationic surfactant that also is used as fabric softener usually; With nonionic as known in the art and aniorfic surfactant.The contents level of tensio-active agent is generally about 1-30% (weight).In some cases, in preparation, the tensio-active agent carrying capacity can usually greater than 95% weight, be higher than about 99% weight greater than 85% weight.
[0040] further sets forth the present invention in for example use in the fabric softener composition of the consumer's goods.Fabric softener composition is known in the art, and contains fabric-softening composition and other optional materials for example essence, sequestrant, sanitas, dyestuff, soil release polymer and thickening material.Other optional ingredients also can comprise solvent, alcohol, both sexes and nonionogenic tenside, Fatty Alcohol(C12-C14 and C12-C18), lipid acid, organic or inorganic salt, pH buffer reagent, defoamer, sterilant, mycocide, oxidation inhibitor, corrosion inhibitor, enzyme, white dyes, antifoams and other material as known in the art.
[0041] fabric softener composition can be substantially free of anion surfactant as known in the art for example lithium dodecyl sulfate or sodium lauryl sulphate.Be substantially free of and represent that fabric softener composition contains the anion surfactant less than 5% (weight),, be more preferably less than .5% (weight), also be more preferably less than the anion surfactant of 0.1% (weight) preferably less than 1% (weight).
[0042] fabric softener composition can be substantially free of for example alkali metal phosphate of water soluble builder salt as known in the art, for example sodium phosphate and potassiumphosphate.Be substantially free of and represent that fabric softener composition contains the builder salt less than 5% (weight),, be more preferably less than 0.5% (weight), also be more preferably less than the water soluble builder salt of 0.1% (weight) preferably less than 1% (weight).
[0043] the fabric-softening composition in the fabric softener composition is known in the art, and can comprise cats product, quaternary ammonium salt (vinylformic acid quaternary ammonium salt, ester quat, the ring-type quaternary ammonium salt, the diamido quaternary ammonium salt, biodegradable quaternary ammonium salt, the polymer ammonium salt), poly quaternary ammonium compound, uncle's aliphatic amide, carboxylic acid, the ester of polyvalent alcohol, Fatty Alcohol(C12-C14 and C12-C18), ethoxylized fatty alcohol, alkylphenol, ethoxylated alkylphenol, ethoxylated fatty amine, two fat (difatty), ethoxylated glycerol monoesters (monolycerides), the ethoxylated glycerol diester, mineral oil, clay and polyvalent alcohol.
[0044] fabric softener composition can contain one or more fabric-softening compositions of about 35% (weight) of about 0.01%-.Preferably, the present invention can contain the fabric-softening composition of about 25% (weight) of about 0.5%-.Optional, the present invention can contain the fabric-softening composition of about 1.5%-about 12%.Optional, the present invention can contain the fabric-softening composition of about 15%-about 24%.
[0045] amount of composition will depend on the purpose of preparation in the fabric softener composition, and promptly preparation is dense or rare.Therefore, it is about 50% that the fabric-softening composition can account for for example about 0.1%-of composition gross weight, for example about 25% for about 10%-for concentrated composition, and be about 1%-about 10% for rare composition.Fabric softener composition also can contain one or more sequestrants, dyestuff, Fatty Alcohol(C12-C14 and C12-C18), sanitas and/or essence, and/or other composition as known in the art.
[0046] the fabric-softening composition can be the ester based quaternary ammonium salt (esterquat) (or mixture of ester based quaternary ammonium salt) with structural formula 1
Structure 1
Wherein
R
1Representative-(CH
2)
tR
6, R wherein
6Represent benzyl, phenyl, (C
1-C
4Phenyl, OH or H that)-alkyl replaces;
R
2And R
3Representative-(CH
2)
s-R
5, R wherein
5Representative contains acyloxy, benzyl, the phenyl of 8-22 carbon atom, phenyl, OH or the H of (C1-C4)-alkyl replacement;
R
4Representative has the aliphatic hydrocarbyl of 8-22 carbon atom;
Q, s and t independently represent the integer of 1-3 separately; And
X-is the tenderizer compatible anionic.
[0047] by making the reaction of 2 moles of fatty acids methyl esters and 1 mole of triethanolamine, carry out with methyl-sulfate then that quaternized (this preparation method's more details are at United States Patent (USP) 3,915, and are open in 867, it is attached to herein by reference), preparation is used for specific tenderizer of the present invention.The distribution of reaction product is as follows: (a) 50% 2 ester based quaternary ammonium salt material; (b) 20% monoesters based quaternary ammonium salt; (c) 30% 3 ester based quaternary ammonium salt.
[0048] according to the esterification treatment condition, 3 kinds of products (single-, two-and three-ester based quaternary ammonium salt) distribution can change.Quaternized by the fatty acid part and the condensation reaction products between at least a functionalized tertiary amine that will contain at least a saturated or unsaturated straight or branched lipid acid or derivative, wherein the mol ratio of fatty acid part and tertiary amine is about 1.7:1, prepares described ester based quaternary ammonium salt compound herein.At United States Patent (USP) 5,637, among 743 (Stepan) method for preparing this esterquat surfactant has been described, this patent content is attached to herein by reference.
[0049] aforementioned molar ratio will determine in the product single-, two-and three-ester based quaternary ammonium salt compound between balance.For example, the mol ratio with about 1.7 produces the normal distribution of about 34% monoesters based quaternary ammonium salt, about 56% 2 ester based quaternary ammonium salt and about 10% 3 ester based quaternary ammonium salt, and these ester based quaternary ammonium salts are fatty acid ester quarternary ammonium salt compounds of the present invention.On the other hand, for example obtain the normal distribution of about 21% monoesters based quaternary ammonium salt, 61% 2 ester based quaternary ammonium salt and 18% 3 ester based quaternary ammonium salt with about 1.96 mol ratio.
[0050] therefore, preferred fabric-softening composition can comprise quaternary fatty acid triethanolamine ester salts, for example trolamine-ester based quaternary ammonium salt tallow.Preferred fabric-softening composition of the present invention can comprise the dialkyl of triethanol ammonium Methylsulfate, or two (hydrogenated-tallow group ethyl) hydroxyethyl ammonium methoxyl group vitriol.Can buy the fabric-softening composition from Kao Corporation, its name of product is Tetranyl L1/90 or Tetranyl AT1-75.
[0051] fabric softener composition also can contain soil release polymer (SRP).SRP knows in the art, and can comprise the polymkeric substance that is adsorbed on the fabric fibre, and it is dirty again that wherein they stop fiber.This base polymer can comprise polyester and multipolymer, the polyester of ethylene glycol and multipolymer and poly-(ethylene glycol terephthalate) of multipolymer, ethylene glycol and benzene of terephthalic acid.Polymkeric substance can comprise nonionic polyesters.Polymkeric substance can be modified, and wherein ethylene glycol is partly removed, and replaces with the end capped polyoxyethylene glycol of high molecular weight hydroxy.
[0052] sequestrant is known in the art, and its contents level in fabric softening compositions can be at least about 0.001% (weight), and preferably about 0.001%-is about 1%, and more preferably from about 0.01%-is about 0.5%, more preferably from about 0.06%-0.1% (weight).Wherein sequestrant can be selected from amino carboxylic acid compounds, organic aminophosphonic acid compound and their mixture.Suitable amino carboxylic acid compounds can comprise: ethylenediamine tetraacetic acid (EDTA), N-HEDTA, nitrilotriacetic acid(NTA) and diethylene triaminepentaacetic acid(DTPA).Suitable organic aminophosphonic acid compound can comprise methylene phosphonic acid, 1-hydroxyl ethane 1,1-di 2 ethylhexyl phosphonic acid and Amino Trimethylene Phosphonic Acid.Preferred sequestrant can be Amino Trimethylene Phosphonic Acid, its can Dequest 2000 from Solutia, (St.Louis, Missouri USA) obtain Inc..
[0053] sanitas is known in the art, and can comprise lactic acid, formaldehyde or other sanitas as known in the art.It is about 10% that fabric softener composition can contain 0%-, and preferably about 0.01%-is about 2%, more preferably from about 0.05%-about 0.5% (weight) sanitas.In the present invention, preferred sanitas can be a lactic acid.
[0054] Fatty Alcohol(C12-C14 and C12-C18) and fatty alcohol are known in the art.Fatty Alcohol(C12-C14 and C12-C18) can have saturated or undersaturated carbochain fully.Preferred Fatty Alcohol(C12-C14 and C12-C18) comprises C
10-C
28Alcohol, preferred C
16-18, C
13-C
15Alcohol and composition thereof.Fabric softener composition can contain the Fatty Alcohol(C12-C14 and C12-C18) of 0%-about 10% (weight), and preferably about 0.1%-is about 5%, more preferably from about the Fatty Alcohol(C12-C14 and C12-C18) of 0.1%-about 0.5%.
[0055] dyestuff is known in the art, and it can account for the 0%-about 5% of product.
[0056] in another embodiment, the invention provides the method that fragrance in the product or antimicrobial material are discharged, this method comprises sneaks into the consumer's goods with any composition.These type of consumer's goods can be oral care product, toothpaste, collutory, personal care articles, lotion, ointment, shampoo, amendment, hair gel, antiperspirant, reodorant, antiperspirant and reodorant, shaving cream, hair jelly, cologne, body wash, home care product, washing with washing composition, fabric softener, liquid dishwashing detergent, tumble dryer sheet, automatic dishwasher with washing composition or hard surface cleaner.
Embodiment
Embodiment 1
[0057] by in deionized water, mixing, form emulsion, prepare following composition (per-cent is total weight percent):
| FC#1 | FC#2 | |
| TEA-ester based quaternary ammonium salt tallow | 8.667％ | 8.667％ |
| Cation type polymer | 0.268％ | - |
| Amino Trimethylene Phosphonic Acid | 0.1％ | 0.1％ |
| Lactic acid | 0.063％ | 0.063％ |
| Fragrance microcapsule | 3.6％ | 3.6％ |
| Water | Surplus | Surplus |
[0058] water and TEA-ester based quaternary ammonium salt tallow are heated to 65 ℃ separately separately.Amino Trimethylene Phosphonic Acid is added in the entry, mix.By about 25-40 gram/minute speed, the TEA-ester based quaternary ammonium salt is added in the entry.Mixed 10 minutes, and in ice/water-bath, be cooled to temperature and reach 35 ℃, stir simultaneously.Add lactic acid, mix.Add cation type polymer, mixed 10 minutes.Add fragrance microcapsule, with solution remix 30 minutes.
Embodiment 2
[0059] in washing machine, the heavy fleece cotton towel is washed with equivalent composition F C#1 and FC#2.After the washing, towel is in line at room temperature dry 1 day.Require 20 people's judge groups according to the towel of smell evaluation with FC#1 and FC#2 washing.The towel that 63% judge preferably washs with FC#1.With the towel friction, require the judge to revalue towel then.The preferred FC#1 of 70% judge.The result shows, the towel that washs with the FC#1 of cation type polymkeric substance and fragrance microcapsule provides the fragrance of increase.
Embodiment 3
[0060] by in deionized water, mixing, form emulsion, prepare following composition (per-cent is total weight percent):
| FC#3 | FC#4 | |
| Tetranyl?L1/90 | 8.667％ | 8.667％ |
| Cation type polymer | 0.268％ | 0.268％ |
| Dequest2000 | 0.1％ | 0.1％ |
| Lactic acid | 0.063％ | 0.063％ |
| Spices | 0.99％ | - |
| Fragrance microcapsule (17.3% spices) | - | 5.723% (0.99% spices) |
| Water | Surplus | Surplus |
[0061] water and Tetranyl L1/90 are heated to 65 ℃ separately separately.Dequest2000 is added in the entry, mix.By about 25-40 gram/minute speed, Tetranyl L1/90 is added in the entry.Mixed 10 minutes, and in ice/water-bath, be cooled to and reach 35 ℃ temperature, mix simultaneously.Add lactic acid, mix.Add cation type polymer, mixed 10 minutes.Fragrance microcapsule and spices are added corresponding preparation, with solution remix 30 minutes.
Embodiment 4
[0062] in washing machine, the heavy fleece cotton towel is washed with equivalent composition F C#3 and FC#4.After the washing, towel was stored for 1 week down in the room temperature (temperature) in 1 week, stored 3 months down and stored 1 month down at 43 ℃ at 35 ℃.After the storage, require 20 people's judge groups, after towel friction several times, again the essence intensity on the towel is classified the graduation of the essence intensity on the towel.The results are shown in shown in figure below.The towel that is better than using the FC#3 washing that does not contain encapsulated fragrance with the towel of the FC#4 washing that contains encapsulated fragrance and cation type polymer.
[0063] content that proposes herein only illustrates for example provides, as restriction.Though show and set forth specific embodiment, to those skilled in the art, can carry out changes and improvements and the broad scope that do not deviate from invention is conspicuous.When examining their proper perspective closely according to prior art, the actual range of seeking to protect will be defined by the claims.
Claims (34)
1. composition, described composition comprises:
(a) micro-capsule, this micro-capsule comprise that the average Clog P of described material is at least about 2.5 with the shell of material encapsulation, and greater than the Clog P of 60% weight substance at least 3.3 and
(b) crosslinked cation type polymer, this cation type polymer is obtained by the cationic vinyl addition of about 5-100% mole monomer, the about 95% mol propylene acid amides of 0-and monomer crosslinked dose of polymerization of the about 500ppm difunctional vinyl of about 5-addition.
2. the composition of claim 1, wherein said shell has internal surface and outside surface, and described shell is at internal surface, outside surface or have the polymeric film coating on internal surface and outside surface.
3. the composition of claim 1, wherein said linking agent level is 70-200ppm.
4. the composition of claim 1, wherein said linking agent level is 80-150ppm.
5. the composition of claim 1, wherein said crosslinked cation type polymer comprises the quaternary ammonium salt of (methyl) acrylate.
6. the composition of claim 1, wherein said crosslinked cation type polymer comprises the quaternary ammonium salt of methylacrylic acid dimethylamino ethyl ester.
7. the composition of claim 1, wherein said shell comprises aminoplastics.
8. the composition of claim 7, wherein said aminoplastics comprises the resin of melamine and formaldehyde.
9. the composition of claim 1, wherein said shell comprises the hybrid resin of urea-formaldehyde resin, copolymer-maleic anhydride and melamine resin.
10. the composition of claim 1, the average ClogP value of wherein said material is equal to or greater than 3.3.
11. the composition of claim 2, wherein said internal surface has the coating that has polymeric film.
12. the composition of claim 11, wherein said polymkeric substance are selected from the multipolymer and the combination thereof of poly-(ethene-maleic anhydride), polyamine, wax, polyvinylpyrrolidone, polyvinylpyrrolidone multipolymer, polyvinylpyrrolidone-ethyl propenoate, polyvinylpyrrolidone-vinyl acrylate, polyvinylpyrrolidone methacrylic acid ester, polyvinylpyrrolidone/vinyl-acetic ester, polyvinylacetal, polyvinyl butyral acetal, polysiloxane, poly-(propylene maleic anhydride), maleic anhydride derivative, maleic anhydride derivative.
13. the composition of claim 2, wherein said outside surface has the polymeric film coating, and described polymeric film coating comprises outside polymkeric substance.
14. the composition of claim 13, the polymkeric substance of wherein said outside is selected from polyvinyl alcohol, styrene-butadiene latex, gelatin, gum arabic, carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, Natvosol, other modified-cellulose, sodiun alginate, chitosan, casein, pectin, treated starch, polyvinylacetal, polyvinyl butyral acetal, polyvinyl methyl ether/maleic anhydride, polyvinylpyrrolidone and multipolymer thereof, poly-(V-Pyrol RC/methacryloyl aminopropyl trimethyl ammonium chloride), polyvinylpyrrolidone/vinyl-acetic ester, poly-(V-Pyrol RC/methylacrylic acid dimethylamino ethyl ester) and combination thereof.
15. the composition of claim 1, wherein said material comprises spices.
16. the composition of claim 1, wherein said material comprises antimicrobial material.
Be at least 6 solvent 17. the composition of claim 1, described composition also comprise ClogP in the described micro-capsule that contains material, described solvent and described material are miscible.
18. the composition of claim 1, wherein said material comprises spices.
19. the composition of claim 1, described composition also comprise at least a fabric-softening composition.
20. the composition of claim 19, wherein said fabric-softening composition is an ester based quaternary ammonium salt.
21. the composition of claim 20, wherein said ester based quaternary ammonium salt are the mixture of structure 1 compound or this compound
Structure 1
Wherein
R
1Representative-(CH
2)
tR
6, R wherein
6The phenyl, OH or the H that represent benzyl, phenyl, (C1-C4)-alkyl to replace;
R
2And R
3Representative-(CH
2)
s-R
5, R wherein
5Representative comprises acyloxy, benzyl, the phenyl of 8-22 carbon atom, phenyl, OH or the H of (C1-C4)-alkyl replacement;
R
4Representative has the aliphatic hydrocarbyl of 8-22 carbon atom;
Q, s and t independently represent the integer of 1-3 separately; And
X
-Be the tenderizer compatible anionic.
22. the composition of claim 20, wherein said ester based quaternary ammonium salt comprise list-alkyl, two-alkyl and the three-alkyl ester mixture of triethanol ammonium Methylsulfate.
23. the composition of claim 22, being distributed as of wherein said ester-formin
A) monoesters: 15-40%
B) diester: 50-65%
C) three esters: 5-30%.
24. the composition of claim 22, being distributed as of wherein said ester-formin
A) monoesters: 32-36%
B) diester: 54-58%
C) three esters: 8-12%.
25. the composition of claim 22, being distributed as of wherein said ester-formin
A) monoesters: 19-23%
B) diester: 59-63%
C) three esters: 16-20%.
26. the composition of claim 22, being distributed as of wherein said ester-formin
A) monoesters: 18-22%
B) diester: 48-52%
C) three esters: 28-32%.
27. the composition of claim 19, wherein said fabric-softening composition accounts for the about 0.1%-of described composition total weight about 50%.
28. the composition of claim 19, wherein said micro-capsule encapsulated fragrance, and exist with the amount that accounts for the about 0.0001%-of described composition total weight about 10%.
29. a raising comprises the method for the product stability of at least a micro-capsule, described method comprises mixes described product with crosslinked cation type polymer, described crosslinked cation type polymer is obtained by the polymerization of monomer crosslinked dose of the cationic vinyl addition of about 5-100% mole monomer, about 95% acrylamide of 0-and the addition of the about 500ppm difunctional vinyl of about 5-, wherein said micro-capsule comprises the shell of encapsulated substance, the average ClogP of described material is at least 2.5, and is at least 3.3 greater than the Clog P of the described material of 60% weight.
30. the method for claim 29, wherein said shell has internal surface and outside surface, and has the polymeric film coating on the internal surface of described shell, outside surface or internal surface and the outside surface.
31. the method for claim 29, wherein said linking agent level is 70-300ppm.
32. the method for claim 29, wherein said linking agent level is 80-150ppm.
33. the method for claim 29, wherein said crosslinked cation type polymer comprises the quaternary ammonium salt of (methyl) acrylate.
34. the method for claim 29, wherein said crosslinked cation type polymer comprises the quaternary ammonium salt of methylacrylic acid dimethylamino ethyl ester.
Applications Claiming Priority (2)
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|---|---|---|---|
| US47967906A | 2006-06-30 | 2006-06-30 | |
| US11/479,679 | 2006-06-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101506344A true CN101506344A (en) | 2009-08-12 |
Family
ID=38658485
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007800317503A Pending CN101506344A (en) | 2006-06-30 | 2007-06-21 | Cationic polymer stabilized microcapsule composition |
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| Country | Link |
|---|---|
| EP (1) | EP2046935A2 (en) |
| CN (1) | CN101506344A (en) |
| AU (1) | AU2007269428A1 (en) |
| BR (1) | BRPI0713074A2 (en) |
| CA (1) | CA2656326A1 (en) |
| IL (1) | IL196157A0 (en) |
| MX (1) | MX2008016479A (en) |
| NO (1) | NO20090477L (en) |
| RU (1) | RU2009102970A (en) |
| WO (1) | WO2008005693A2 (en) |
| ZA (1) | ZA200900074B (en) |
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| CN104160008A (en) * | 2012-01-30 | 2014-11-19 | 赢创工业集团股份有限公司 | Fabric softener active composition |
| CN104837976A (en) * | 2012-12-11 | 2015-08-12 | 高露洁-棕榄公司 | Esterquat composition having high triesterquat content |
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-
2007
- 2007-06-21 BR BRPI0713074-0A patent/BRPI0713074A2/en not_active IP Right Cessation
- 2007-06-21 CN CNA2007800317503A patent/CN101506344A/en active Pending
- 2007-06-21 AU AU2007269428A patent/AU2007269428A1/en not_active Abandoned
- 2007-06-21 EP EP07798887A patent/EP2046935A2/en not_active Withdrawn
- 2007-06-21 WO PCT/US2007/071782 patent/WO2008005693A2/en active Application Filing
- 2007-06-21 RU RU2009102970/04A patent/RU2009102970A/en not_active Application Discontinuation
- 2007-06-21 MX MX2008016479A patent/MX2008016479A/en unknown
- 2007-06-21 CA CA002656326A patent/CA2656326A1/en not_active Abandoned
-
2008
- 2008-12-24 IL IL196157A patent/IL196157A0/en unknown
-
2009
- 2009-01-05 ZA ZA200900074A patent/ZA200900074B/en unknown
- 2009-01-29 NO NO20090477A patent/NO20090477L/en not_active Application Discontinuation
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101935949B (en) * | 2010-08-27 | 2012-01-18 | 上海制皂有限公司 | Clothes softener |
| CN101935949A (en) * | 2010-08-27 | 2011-01-05 | 上海制皂有限公司 | Clothes softener |
| CN104039944B (en) * | 2011-08-25 | 2017-04-26 | 荷兰联合利华有限公司 | Encapsulated benefit agent |
| CN104039944A (en) * | 2011-08-25 | 2014-09-10 | 荷兰联合利华有限公司 | Encapsulated benefit agent |
| CN104160008A (en) * | 2012-01-30 | 2014-11-19 | 赢创工业集团股份有限公司 | Fabric softener active composition |
| CN104160008B (en) * | 2012-01-30 | 2017-05-03 | 赢创德固赛有限公司 | Fabric softener active composition |
| CN104837975B (en) * | 2012-12-11 | 2018-04-27 | 高露洁-棕榄公司 | Ester quat compositions with high three ester quats content |
| CN104837975A (en) * | 2012-12-11 | 2015-08-12 | 高露洁-棕榄公司 | Esterquat composition having high triesterquat content |
| CN104837976A (en) * | 2012-12-11 | 2015-08-12 | 高露洁-棕榄公司 | Esterquat composition having high triesterquat content |
| CN110573244A (en) * | 2017-04-28 | 2019-12-13 | 奇华顿股份有限公司 | Improvements in or relating to organic compounds |
| CN110573244B (en) * | 2017-04-28 | 2022-04-01 | 奇华顿股份有限公司 | Improvements in or relating to organic compounds |
| CN110636978A (en) * | 2017-05-31 | 2019-12-31 | 罗门哈斯公司 | Self-supporting dispersant membranes |
| CN110636978B (en) * | 2017-05-31 | 2022-01-11 | 罗门哈斯公司 | Self-supporting dispersant film and unit dose package comprising same |
| CN111065673A (en) * | 2017-09-15 | 2020-04-24 | 株式会社Lg化学 | Polymerizable composition, polymer capsule comprising the same, and fabric softener composition |
| CN111065673B (en) * | 2017-09-15 | 2021-10-01 | 株式会社Lg化学 | Polymerizable composition, polymer capsule comprising the same, and fabric softener composition |
| US11214759B2 (en) | 2017-09-15 | 2022-01-04 | Lg Chem, Ltd. | Polymerizable composition, polymer capsule and fabric softener composition comprising the same |
| CN114845803A (en) * | 2019-12-27 | 2022-08-02 | 花王株式会社 | Aqueous dispersion of microcapsules |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0713074A2 (en) | 2012-07-17 |
| RU2009102970A (en) | 2010-08-10 |
| AU2007269428A1 (en) | 2008-01-10 |
| IL196157A0 (en) | 2009-09-22 |
| EP2046935A2 (en) | 2009-04-15 |
| NO20090477L (en) | 2009-01-29 |
| ZA200900074B (en) | 2010-03-31 |
| CA2656326A1 (en) | 2008-01-10 |
| WO2008005693A2 (en) | 2008-01-10 |
| WO2008005693A3 (en) | 2008-02-21 |
| MX2008016479A (en) | 2009-01-22 |
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