CN101415809A - Liquid laundry detergents containing cationic hydroxyethyl cellulose polymer - Google Patents
Liquid laundry detergents containing cationic hydroxyethyl cellulose polymer Download PDFInfo
- Publication number
- CN101415809A CN101415809A CNA2007800125838A CN200780012583A CN101415809A CN 101415809 A CN101415809 A CN 101415809A CN A2007800125838 A CNA2007800125838 A CN A2007800125838A CN 200780012583 A CN200780012583 A CN 200780012583A CN 101415809 A CN101415809 A CN 101415809A
- Authority
- CN
- China
- Prior art keywords
- composition
- liquid laundry
- aqueous liquid
- laundry detergent
- detergent compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Abstract
Disclosed are aqueous liquid laundry detergent compositions useful for cleaning fabrics wherein the compositions contain from about 0.05% to about 0.4%, by weight of the composition, of a cationic hydroxyethyl cellulose polymer having a degree of substitution of the cationic charge of from about 0.01 to about 0.20; from about 5% to about 30%, by weight of the composition, of a surfactant comprising at least one anionic surfactant and at least one nonionic surfactant; and from about 2% to about 15%, by weight of the composition, of fatty acid. Use of such aqueous liquid laundry detergent compositions for handwashing delicate fabrics is disclosed. Use of such aqueous liquid laundry detergent compositions for machine washing of delicate fabrics is disclosed, wherein the machine washing occurs at a delicate machine setting.
Description
Invention field
The present invention relates to the purposes of cationic hydroxyethyl cellulose at the liquid laundry detergent composition that is used for washing yarn fabric (for example clothes, linen, fabric).
Background of invention
There is a large amount of liquid laundry detergents to use for current human consumer.Though a lot of washing composition can fully remove dust, dirt and smell and can clean yarn fabric (for example clothes and so on) very effectively in traditional transverse axis and/or direct-insert washing machine; but continue expectation for the human consumer provide produce by their laundry detergent and by the additional fabric care benefit effect that cycles of washing produces, handle as the gentleness of softening, color protection, fabric abrasion protection and high-grade yarn fabric (as wool and silk).
Cationic polymers such as cationic hydroxyethyl cellulose polymer are provided by commerce traditionally and are used for being included in detergent composition, especially in hair products such as the shampoo.Recently, this type of cationic polymers has experimentized in the heavy duty type liquid laundry detergent to strengthen the deposition of other known materials, and these known materials are provided softening beneficial effect can for yarn fabric to be washed but can not be deposited well in the conventional washer working cycle.
It is shocking, have now found that this type of cationic polymers can combine with tensio-active agent and lipid acid, and in being comprised in selected aqueous liquid laundry detergent compositions the time, the fabric care benefit effect is provided for yarn fabric to be washed.
Summary of the invention
The present invention relates to be used to clean the aqueous liquid laundry detergent compositions of high-count fabric, described aqueous liquid laundry detergent compositions comprises the cationic hydroxyethyl cellulose polymer by the weight of described composition about 0.05% to about 0.4%, and described cationic hydroxyethyl cellulose polymer has about 0.01 to about 0.20 cationic charge substitution value; By the tensio-active agent of the weight of described composition about 5% to about 30%, described tensio-active agent comprises at least a anion surfactant and at least a nonionogenic tenside; With lipid acid by the weight of described composition about 2% to about 15%.
The invention still further relates to the aqueous liquid laundry detergent compositions that is used to clean high-count fabric, this detergent composition comprises the cationic hydroxyethyl cellulose polymer by the weight of described composition about 0.15% to about 0.2%, described cationic hydroxyethyl cellulose polymer has about 200,000 to about 800,000 molecular weight and about 0.01 to 0.20 cationic charge substitution value; By the tensio-active agent of the weight of described composition about 7% to about 15%, described tensio-active agent comprises a kind of alkyl ethoxylate sulfate tensio-active agent and at least a nonionogenic tenside; Lipid acid by the weight of described composition about 2% to about 10%; Wherein said composition is substantially free of white dyes; And wherein said composition is substantially free of the enzyme with cellulytic activity.
The present invention also relates to above-mentioned composition, wherein said cationic hydroxyethyl cellulose polymer has about 0.01 to about 0.1 cationic charge substitution value.
The present invention also relates to above-mentioned composition, wherein said cationic hydroxyethyl cellulose polymer has about 0.01 to the cationic charge substitution value that is less than 0.1.
The present invention also relates to above-mentioned composition, wherein said cationic hydroxyethyl cellulose polymer has about 200,000 to about 800,000 molecular weight.
The present invention also relates to above-mentioned composition, wherein said composition is substantially free of the enzyme with cellulytic activity.
The present invention also relates to above-mentioned composition, wherein said composition is substantially free of white dyes.
The present invention also relates to above-mentioned composition, wherein said composition comprises the cationic hydroxyethyl cellulose polymer by the weight of described composition about 0.1% to about 0.3%.
The present invention also relates to above-mentioned composition, wherein said composition comprises the cationic hydroxyethyl cellulose polymer by the weight of described composition about 0.15% to about 0.2%.
The present invention also relates to above-mentioned composition, wherein said composition comprises the tensio-active agent by the weight of described composition about 7% to about 15%.
The present invention also relates to above-mentioned composition, wherein said composition comprises the lipid acid by the weight of described composition about 2.5% to about 7%.
The present invention also relates to above-mentioned composition, wherein said composition also comprises opalizer.
The present invention also relates to above-mentioned composition, wherein said anion surfactant is selected from alkyl ethoxylate sulfate and linear alkylbenzene sulfonate.
The present invention also relates to above-mentioned composition, wherein said anion surfactant is selected from alkyl ethoxylate sulfate, and described alkyl ethoxylate sulfate has about 12 to about 14 chain length and about 1 to about 8 ethoxylation degree.
The present invention also relates to above-mentioned composition, wherein said composition also comprises suds suppressor.
The present invention also relates to above-mentioned composition, wherein said composition is substantially free of enzyme.
The present invention also relates to above-mentioned composition, wherein said composition also comprises the clothes washing auxiliary component, and described clothes washing auxiliary component is selected from soil release polymer, dye transfer inhibiting polymers, sequestrant, helping property polymkeric substance, sanitas, stablizer, structural agent, viscosity modifier and citric acid.
The present invention also relates to above-mentioned composition, wherein said composition also comprises about 0.01 to about 1% structural agent, and described structural agent is selected from hydrogenated castor oil.
The invention still further relates to above-mentioned composition in the purposes that is used to hand-wash aspect the high-count fabric.
The invention still further relates to the purposes of above-mentioned composition aspect the high-count fabric that is used to machine-wash, when wherein machine-washing machine is set at the washing high-count fabric.
Detailed Description Of The Invention
The All Files of quoting in detailed Description Of The Invention is all introduced for your guidance in relevant portion.Should not be interpreted as admitting that for quoting of any file it is relevant prior art of the present invention.When any implication of term in any implication of term among the present invention or definition and the file of introducing for your guidance or when defining contradiction, should obey the implication or the definition of giving this term in the present invention.
Except as otherwise noted, all percentage ratios, ratio and the ratio of this paper are all by weight.
The present invention relates to aqueous liquid laundry detergent compositions, said composition comprises tensio-active agent, the lipid acid that comprises at least a negatively charged ion and a kind of nonionogenic tenside and has about 0.01 to about 0.20 cationic charge substitution value and about 200, the cationic hydroxyethyl cellulose polymer of 000 to about 800,000 molecular weight.
Be not bound by theory, what it is believed that described cationic hydroxyethyl cellulose polymer at present is providing very important aspect the liquid laundry detergent product than low charge density, described liquid laundry detergent product comprises the tensio-active agent (at least a anion surfactant and a kind of nonionogenic tenside) of relative low levels, and fabric care benefit effect and good cleaning effect can be provided can for yarn fabric to be washed.
The compositions and methods of the invention help providing liquid laundry detergent composition aspect cheaply, and this liquid laundry detergent composition can provide good cleaning and softening beneficial effect by the washing to yarn fabric such as clothes and fabric.According to detailed Description Of The Invention, other purpose and advantage will become apparent.
Cationic hydroxyethyl cellulose polymer
Aqueous liquid laundry detergent compositions of the present invention comprises the cationic hydroxyethyl cellulose polymer by the weight of described composition about 0.05% to about 0.4%.In one embodiment, described composition comprises by the weight of described composition about 0.1% to about cationic hydroxyethyl cellulose polymer of 0.3%, perhaps about 0.15% to about 0.2%.
The cationic hydroxyethyl cellulose polymer that can be used for this paper has the cationic charge substitution value of about 0.01 (cationic charge of per 100 polymer repeat units) to about 0.20 (two cationic charges of per 10 polymer repeat units).Preferably, the cationic hydroxyethyl cellulose polymer that can be used for this paper has about 0.01 to about 0.1 cationic charge substitution value, and more preferably less than 0.1, about in one embodiment 0.01 to the cationic charge substitution value that is less than 0.1.Positive charge can be positioned on the main polymer chain or on the polymer lateral chain.
The available cationic hydroxyethyl cellulose polymer comprise can be or can not be hydrophobically modified and that have about 200,000 to about 800,000 molecular weight those.These cationic materials have multiple and replace dehydrated glucose unit, and its corresponding general formula I is as follows:
Structural formula I
Wherein R1, R2, R3 be independently of one another H, CH3, C8-24 alkyl (straight chain or side chain),
Or their mixture; Wherein n is about 1 to about 10; Rx be H, CH3, C8-24 alkyl (straight chain or side chain),
Or their mixture, wherein Z is a water soluble anion, preferred chlorion and/or bromide anion; R5 is H, CH3, CH2CH3 or their mixture; R7 is CH3, CH2CH3, phenyl, C8-24 alkyl (straight chain or side chain) or their mixture; With
R8 and R9 are CH3, CH2CH3, phenyl or their mixture independently of one another:
R4 be H,
Or their mixture, wherein P be the addition polymer that forms of the radical polymerization by cationic monomer repeating unit as
Wherein Z ' is a water soluble anion, preferred chlorion, bromide anion or their mixture, and q is about 1 to about 10.
The water soluble anion that can be used for this paper comprises: the alkyl-sulphate of C8-C24, the alkyl alkoxy sulfate of C8-C24, the alkylsulfonate of preferred alkyl ethoxy sulfate, C8-C24, the alkylbenzene sulfonate of C8-C16, xylenesulfonate, tosylate, cumene sulfonate, aliphatic alkyl carboxylate salt, chlorion, bromide anion or their mixture, wherein preferred chlorion and/or bromide anion.
Cationic hydroxyethyl cellulose can contain alkyl substituent on the anhydroglucose ring that polymer is arranged.When having this type of alkyl substituent, can be about 0% to 5% for each glucose unit, more preferably about 0% to 2% the polymeric material of each glucose unit.
When at room temperature being added in the water, cationic cellulose may with dialdehyde, as glyoxylyl, take place lightly crosslinked, to prevent to form agglomerate, nodule or other agglomerate.
The cationic hydroxyethyl cellulose ethers of structural formula I comprises those of commercially available acquisition equally, and comprises the material that can make by the conventional chemical modification of commercially available material.The plain ether of commercially available structural formula I fiber type that can be used for this paper comprises LR 400 and LK 400 polymkeric substance, preferred LK 400 polymkeric substance, and it is sold by Dow Chemical.
Tensio-active agent
Aqueous liquid laundry detergent product of the present invention comprises the tensio-active agent by the weight of described composition about 5% to about 30%.In one embodiment, aqueous liquid laundry detergent product of the present invention comprises by the weight of described composition about 5% to about 20%, perhaps by the tensio-active agent of the weight of described composition about 7% to about 15%.
The tensio-active agent of Betengent product of the present invention comprises at least a anion surfactant and at least a nonionogenic tenside.Betengent product of the present invention also can comprise other tensio-active agent such as zwitterionic, amphoteric or cationic, maybe can comprise these types and anion surfactant and nonionogenic tenside bonded compatible blend.
In one embodiment, described anion surfactant is selected from alkyl ethoxylate sulfate and linear alkylbenzene sulfonate.In another embodiment, described anion surfactant is selected from alkyl ethoxylate sulfate, and described alkyl ethoxylate sulfate has about 12 to about 14 chain length and about 1 to about 8 ethoxylation degree.
The detergent surfactant that can be used for this paper comprises the United States Patent (USP) of announcing as 23 days Mays in 1972 of Norris 3,664,961, the United States Patent (USP) of announcing people's such as Laughlin 30 days December in 1975 3,919,678, the United States Patent (USP) of announcing the 16 days December in 1980 of United States Patent (USP) of announcing on September 16th, 1980 of Cockrell 4,222,905 and Murphy 4, those that describe in 239,659.
The anion surfactant that is applicable to this paper comprises water-soluble salt, and the basic metal of preferred organic sulfonation reaction product and ammonium salt, this product contain in their molecular structure and have about 10 alkyl and sulfonic acid or sulfate groups to about 20 carbon atoms.(be included in being the moieties of acyl group in the term " alkyl ").The example of this class synthetic surfactant is sodium salt, sylvite and the amine salt of a) alkylsurfuric acid, especially by sulfation higher alcohols (C
8-C
18Carbon atom) resulting those, for example by in reduction butter or the Oleum Cocois glyceryl ester produced those; B) sodium sulfate salt of alkyl polyethoxylated, sylvite and amine salt, alkyl especially wherein comprise 10 to 22, preferred 12 to 18 carbon atoms, and polyethoxylated chain wherein comprises 1 to 15, those of preferred 1 to 6 ethoxylate part; And c) sodium salt of alkyl benzene sulphonate (ABS) and sylvite, wherein alkyl comprises about 9 to about 15 carbon atoms, is the straight or branched configuration, for example is described in United States Patent (USP) 2,220, those types in 099 and 2,477,383.Same available is the linear straight chain alkylbenzene sulfonate, and wherein the mean number of alkyl carbon atoms is about 11 to 13, is abbreviated as C
11-13LAS.
In one embodiment, the ionic surfactant pack that can be used for this paper is drawn together formula R
1(OC
2H
4)
nThose of OH, wherein R
1Be C
10-C
16Alkyl or C
8-C
12Alkyl phenyl, and n is 3 to about 80.In one embodiment, nonionogenic tenside is C
12-C
15Alcohols and every mol of alcohol about 5 condensation products, for example C to about 20 moles of ethylene oxide
12-C
13The about 6.5 moles of ethylene oxide condensations of pure and every mol of alcohol.
The ionic surfactant pack of Shi Heing is drawn together polyhydroxy fatty acid amide in addition, is shown below:
Wherein R is C
9-17Alkyl or alkenyl, R
1Be methyl, and Z is the glycidyl derived from reducing sugar or its oxyalkylated derivative.Example is N-methyl N-1-deoxy-glucose base coconut oleoyl amine and N-methyl N-1-deoxy-glucose base oil acid amides.The method for preparing polyhydroxy fatty acid amide is known, and this method is present in the United States Patent (USP) 2,703,798 of the United States Patent (USP) 2,965,576 of Wilson and Schwartz, and its disclosure is incorporated herein by reference.
Lipid acid
Aqueous liquid detergent compositions of the present invention comprises the lipid acid by the weight of described composition about 2% to about 15%.In one embodiment, described composition comprises by the weight of described composition about 2% to about lipid acid of 10%, perhaps about 2.5% to about 7%.
As used herein, " lipid acid " be meant to be included in and comprise about 8 to about 24 carbon atoms, perhaps about 12 lipid acid to those scopes of about 18 carbon atoms.The lipid acid that can be used for this paper comprises the mixture of saturated and undersaturated those and they.
The free white dyes
In one embodiment, aqueous liquid detergent compositions of the present invention is substantially free of white dyes.As used herein, " being substantially free of white dyes " is meant that aqueous liquid detergent compositions comprises and is less than 0.0001% white dyes, preferably be lower than the white dyes of detection limit.
Enzyme with cellulytic activity
In one embodiment, aqueous liquid detergent compositions of the present invention is substantially free of the enzyme that comprises cellulytic activity.Aqueous liquid detergent compositions of the present invention can comprise the enzyme that does not have cellulytic activity.As used herein, " being substantially free of the enzyme that comprises cellulytic activity " is meant that aqueous liquid detergent compositions comprises and is less than 0.001% the enzyme that comprises cellulytic activity, preferably be lower than the enzyme that comprises cellulytic activity of detection limit.
Be not bound by theory, it is believed that the cellulase that is present in some enzyme will hydrolysis cationic hydroxyethyl cellulose polymer molecule, perhaps combine, thereby destroy the fabric care benefit effect with cationic hydroxyethyl cellulose polymer.
Yet, if desired, might prepare the aqueous liquid detergent compositions of the present invention that comprises enzyme really with cellulytic activity, prerequisite is the cellulase inhibitor that described composition also comprises significant quantity.
Enzyme
When enzyme being incorporated in the preparation of the present invention, the content of involved enzyme is enough to provide " cleaning significant quantity ".Term " cleaning significant quantity " is meant can produce on matrix such as fabric that cleaning, rusty stain are removed, dirt is removed, brighten, any amount of deodorizing or enhancement freshness effect.In one embodiment, for every gram detergent composition, aqueous liquid detergent compositions of the present invention can comprise about at most by weight 5mg, the more typical about 0.01mg organized enzyme to about 3mg.In other words, composition of the present invention comprises by the weight of described composition about 0.001% usually to about 5%, preferred about 0.01% to about 1% commercially available zymin.Preferably, in above-mentioned commercial preparation, the content of proteolytic enzyme is enough to provide for every gram composition the activity of 0.005 to 0.1 Anson unit (AU).In highly spissated detergent formulations, may expect higher live vol.
The specified proteolytic enzyme that can be used for this paper comprises subtilisin, and it derives from the special bacterial strain of bacterial strain subtilis and Bacillus licheniformis.Preferred proteolytic enzyme derives from the bacterial strain of bacillus, has maximum activity in whole 8 to 12 pH value scope, with trade(brand)name
Novo Industries A/S (hereinafter being called " Novo ") exploitation and sale by Denmark.The preparation of this enzyme and similar enzyme is described among the GB 1,243,784 that authorizes Novo.Other suitable proteolytic enzyme comprises and derives from Novo's
With
And the International Bio-Synthetics that derives from Holland, Inc.'s
When needs, adsorptive power can be reduced and proteolytic enzyme that hydrolysis ability increases is included in the composition of this paper, as authorize Procter ﹠amp; Described in the WO 9507791 of Gamble.The proteolytic enzyme that is applicable to the another kind of recombinant trypsin class of washing composition of the present invention is described among the WO 9425583 that authorizes Novo.
Any known amylase all can be included in the composition of the present invention.
The lipase that is applicable to this paper comprises by those of Rhodopseudomonas group microorganisms, as GB1, and the Rhodopseudomonas stutzeri ATCC 19.154 that announces in 372,034.Also referring to the lipase in the clear Japanese patent application 53,20487 of Ri Tekai February 24 in 1978.This lipase derives from Amano Pharmaceutical Co..Other suitable commercially available lipase comprises Amano-CES, derives from the lipase of thickness look bacillus, as derives from the thickness chromobacterium mutation lipase NRRLB 3673 of Japanese Toyo Jozo Co. (Tagata); Derive from the thickness look bacillus lipase of U.S. Biochemical Corp. and Dutch Disoynth Co.; And the lipase that derives from the gladiolus pseudomonas.Derived from Humicola lanuginosa's
Enzyme, it can be commercially available from Novo, can be to be used for preferred lipase of the present invention referring to EP 341,947 also.
When composition of the present invention comprised compatible enzyme, said composition preferably also comprised effective enzyme stabilising system.Therefore, the aqueous liquid laundry detergent compositions that this paper comprises enzyme also can randomly comprise about by weight 0.001% to about 10%, preferred about 0.005% to about 8%, most preferably from about 0.01% to about 6% enzyme stabilising system.The enzyme stabilising system can be any and the compatible stabilising system of the used enzyme of the present invention.Above-mentioned system can be provided automatically by other preparation active substance, is perhaps added independently, adds as the producer by formulator or enzyme.The aforementioned stable system can for example comprise calcium ion, boric acid, propylene glycol, short chain carboxy acid, boric acid or their mixture, and according to the type and the physical form of detergent composition, is used to handle different stable problems.Be included in the aqueous liquid laundry detergent compositions of this paper if having the enzyme of cellulytic activity, then the enzyme stabilising system should also comprise cellulase inhibitor.
Washing assistant
Described composition also can comprise about by weight washing assistant of 0.1% to 80%.In one embodiment, composition of the present invention comprises about by weight 1% to about 20% builder component.Washing assistant is well known in the art, and can comprise for example phosphoric acid salt and multiple organic and inorganic non-phosphorus builder.
The water-soluble without phosphorus organic washing-assisting detergent that can be used for this paper comprises the ammonium salt of an alkali metal salt, ammonium salt and the replacement of various poly-acetate, carboxylic acid, poly carboxylic acid and poly-hydroxy sulfonic acid.The example of poly-acetate washing assistant and polycarboxylate washing assistant is the ammonium salt of sodium salt, sylvite, lithium salts, ammonium salt and the replacement of 1 tetraacethyl, nitrilotriacetic acid(NTA), oxygen di-succsinic acid, mellitic acid, poly carboxylic acid benzene and citric acid.Other polycarboxylate that is fit to that can be used for this paper is the carboxylate salt of polyacetal, it is described in the people's such as Crutchfield that announced on March 13rd, 1979 United States Patent (USP) 4,144,226 and the people's such as Crutchfield that announced on March 27th, 1979 United States Patent (USP) 4, in 246,495.The polycarboxylate washing assistant that can be used for this paper comprises the carboxylate salt lotion-aid combination of oxygen connection succsinic acid hydrogen salt and ether, it comprises the combination of tartrate monosuccinic acid salt and tartrate succsinic acid hydrogen salt, said composition is described in the people's such as Bush that announced on May 5th, 1987 the United States Patent (USP) 4,663,071.
The example of the without phosphorus inorganic builders that is fit to comprises silicate, silico-aluminate, borate and carbonate.
Aqueous liquid laundry detergent
Aqueous liquid detergent compositions of the present invention can make by any known method, comprises U.S. Patent number 6,274,540 and 6,306,817; The WIPO publication No. WO 01/16237 that announce March 8 calendar year 2001; With those disclosed method among the WO 01/16263 that announces March 8 calendar year 2001.
The laundry detergent composition of this paper is configured to aqueous liquid laundry detergent.Therefore, this paper detergent composition comprises by the weight of described liquid detergent composition about 3% to about aqueous liquid carriers of 98%, perhaps about 15% to about 95%, preferably water.Preferably, according to liquid laundry cleaning composition of the present invention the pH value of the washings that should provide for about 6 to about 10, more preferably from about 7 to about 9, so that by keep preferred cleaning and fabric nursing performance according to aqueous liquid detergent of the present invention.If desired, this cleaning compositions can comprise basifier, pH value control agent and/or buffer reagent.
The clothes washing auxiliary component
The laundry detergent of this paper also can comprise the clothes washing auxiliary component.The clothes washing auxiliary agent that is fit to is known in the art, and comprises soil release polymer, dye transfer inhibiting polymers, sequestrant, helping property polymkeric substance, sanitas, stablizer, structural agent, viscosity modifier, citric acid and comprise the delivery of particles of beneficial agent.
The delivery of particles that comprises beneficial agent that can be used for this paper comprises core material and at least in part around the wall material of described core material.As used herein, phrase " delivery of particles that comprises beneficial agent " comprises microcapsule, and it comprises perfume microcapsule (wherein core material comprises spices).As used herein, term " particle ", " delivery of particles that comprises beneficial agent ", " capsule " and " microcapsule " synonym.
Embodiment 1 to 4
The aqueous liquid detergent preparation that can prepare the following example by known traditional method of those of ordinary skills and equipment.
| Composition | 1 weight % | 2 weight % | 3 weight % | 4 weight % |
| Nonionogenic tenside | 4.0 | 4.0 | 7.0 | 4.0 |
| Anion surfactant | 7.0 | 3.0 | 8.0 | 3.0 |
| Citric acid | 2.0 | 3.0 | 2.5 | 3.0 |
| Lipid acid | 4.5 | 3.0 | 6.0 | 3.0 |
| PVPVI | 0.02 | 0.03 | 0.05 | 0.03 |
| The agent of helping property | 0.3 | 0.5 | ||
| Cationic hydroxyethyl cellulose ethanol | 0.18 | 0.15 | 0.25 | 0.15 |
| 0.85 | 1.00 | 1.2 | 1.00 | |
| Boric acid | 1.2 | 0.85 | 1.00 | 0.85 |
| DB110A | 0.0025 | 0.0025 | 0.0025 | 0.0025 |
| Sodium hydroxide | 3.0 | 3.0 | 3.5 | 3.0 |
| Spices and dyestuff | 0.6 | 0.5 | 0.7 | 0.5 |
| Opalizer | 0.100 | 0.040 | 0.040 | |
| Sanitas | 0.002 | 0.001 | 0.0018 | 0.001 |
| Perfume microcapsule | 1.3 | |||
| Water | Residual | Residual | Residual | Residual |
Though illustrated and described specific embodiments of the present invention, it will be apparent to one skilled in the art that and under the situation that does not deviate from essence of the present invention and scope, can make a plurality of other changes and modification.Therefore, claims all such changes and modification of being intended to be included in the scope of the present invention.
Claims (11)
1. aqueous liquid laundry detergent compositions that is used for clean textile, wherein said composition comprises:
A) by the weight 0.05% to 0.4% of described composition, preferred 0.1% to 0.3%, more preferably 0.15% to 0.2% cationic hydroxyethyl cellulose polymer, described polymkeric substance has 0.01 to 0.20, preferred 0.01 to 0.1, more preferably 0.01 to the cationic charge substitution value that is less than 0.1;
B) by the weight 5% to 30% of described composition, preferred 7% to 15% tensio-active agent, described tensio-active agent comprise at least a anion surfactant and at least a nonionogenic tenside; With
C) by the weight 2% to 15% of described composition, preferred 2.5% to 7% lipid acid.
2. aqueous liquid laundry detergent compositions as claimed in claim 1, wherein said cationic hydroxyethyl cellulose polymer has 200,000 to 800,000 molecular weight.
3. aqueous liquid laundry detergent compositions as claimed in claim 1 or 2, wherein said composition is substantially free of the enzyme with cellulytic activity, and preferably is substantially free of white dyes.
4. the described aqueous liquid laundry detergent compositions of each claim as described above, wherein said composition also comprises opalizer.
5. the described aqueous liquid laundry detergent compositions of each claim as described above, wherein said anion surfactant is selected from the alkylbenzene sulfonate of alkyl ethoxylate sulfate and straight chain, is preferably selected from the alkyl ethoxylate sulfate with 12 to 14 chain lengths and 1 to 8 ethoxylation degree.
6. the described aqueous liquid laundry detergent compositions of each claim as described above, wherein said composition also comprises suds suppressor and is substantially free of enzyme.
7. the described aqueous liquid laundry detergent compositions of each claim as described above, wherein said composition also comprises the clothes washing auxiliary component, and described clothes washing auxiliary component is selected from soil release polymer, dye transfer inhibiting polymers, sequestrant, helping property polymkeric substance, sanitas, stablizer, structural agent, viscosity modifier, the delivery of particles that comprises beneficial agent and citric acid.
8. aqueous liquid laundry detergent compositions as claimed in claim 1, wherein said composition also comprises 0.01 to 1% structural agent, and described structural agent is selected from hydrogenated castor oil.
9. the described aqueous liquid laundry detergent compositions of each claim as described above, wherein said composition also comprises the delivery of particles that contains beneficial agent, and the wherein said delivery of particles that comprises beneficial agent is preferably perfume microcapsule.
10. the described aqueous liquid laundry detergent compositions of each claim is used to hand-wash the purposes of high-count fabric as described above.
11., when wherein machine-washing machine is set at the washing high-count fabric as be used to the to machine-wash purposes of high-count fabric of each described aqueous liquid laundry detergent compositions in the claim 1 to 9.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US79164706P | 2006-04-13 | 2006-04-13 | |
| US60/791,647 | 2006-04-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101415809A true CN101415809A (en) | 2009-04-22 |
Family
ID=38458031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007800125838A Pending CN101415809A (en) | 2006-04-13 | 2007-04-05 | Liquid laundry detergents containing cationic hydroxyethyl cellulose polymer |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP2004785B1 (en) |
| JP (1) | JP2009532566A (en) |
| CN (1) | CN101415809A (en) |
| AR (1) | AR060456A1 (en) |
| AT (1) | ATE520764T1 (en) |
| BR (1) | BRPI0710140A2 (en) |
| CA (1) | CA2645374C (en) |
| MX (1) | MX2008013243A (en) |
| RU (1) | RU2421506C2 (en) |
| WO (1) | WO2007120547A1 (en) |
| ZA (1) | ZA200808541B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102959070A (en) * | 2010-06-24 | 2013-03-06 | 宝洁公司 | Soluble unit dose articles comprising a cationic polymer |
| CN111465733A (en) * | 2017-12-06 | 2020-07-28 | 花王株式会社 | Detergent |
| US11359166B2 (en) | 2017-12-06 | 2022-06-14 | Kao Corporation | Fabric treatment composition |
| US11401350B2 (en) | 2017-12-06 | 2022-08-02 | Kao Corporation | Polysaccharide derivative |
| CN115667482A (en) * | 2020-06-02 | 2023-01-31 | 陶氏环球技术有限责任公司 | Aqueous liquid laundry detergent formulations |
| US11655434B2 (en) | 2017-12-06 | 2023-05-23 | Kao Corporation | Composition |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0911752A2 (en) | 2008-05-28 | 2015-10-06 | Procter & Gamble | fabric softening detergents with good washing stability. |
| JP2011521083A (en) * | 2008-05-28 | 2011-07-21 | ザ プロクター アンド ギャンブル カンパニー | Fabric softening laundry detergent with good stability |
| US8383572B2 (en) * | 2008-09-19 | 2013-02-26 | The Procter & Gamble Company | Detergent composition containing suds boosting and suds stabilizing modified biopolymer |
| EP2302026A1 (en) * | 2009-09-15 | 2011-03-30 | The Procter & Gamble Company | Detergent composition comprising surfactant boosting polymers |
| US8357649B2 (en) | 2009-11-06 | 2013-01-22 | The Procter & Gamble Company | Delivery particle |
| ES2428231T5 (en) | 2010-06-24 | 2021-07-20 | Procter & Gamble | Stable non-aqueous liquid compositions comprising a cationic polymer in particulate form |
| PL2399980T3 (en) | 2010-06-24 | 2013-01-31 | Procter & Gamble | Stable compositions comprising cationic cellulose polymer and cellulase |
| EP2653537B1 (en) | 2010-12-17 | 2017-10-04 | Kanagawa University | Protective structure of substance to be protected, method of protecting substance to be protected, enzymatic reaction method, method of producing reaction product, method for adjusting the speed of enzymatic reaction, and enzyme material use kit |
| JP6817065B2 (en) * | 2014-02-25 | 2021-01-20 | エルジー ハウスホールド アンド ヘルスケア リミテッド | Fiber softener composition |
| EP2982738B2 (en) | 2014-08-07 | 2022-06-29 | The Procter & Gamble Company | Laundry detergent composition |
| HUE042641T2 (en) * | 2014-08-07 | 2019-07-29 | Procter & Gamble | Laundry detergent composition |
| AU2015346632B2 (en) | 2014-11-11 | 2019-07-04 | Rohm And Haas Company | Cationic carbohydrate polymers for fabric care |
| CN105779157A (en) * | 2014-12-24 | 2016-07-20 | 阎珊珊 | Preparation of lavender liquid laundry detergent |
| CN106821995B (en) * | 2017-02-22 | 2020-08-21 | 佛山市南海东方澳龙制药有限公司 | Triclabendazole preparation and preparation method and application thereof |
| US20180355294A1 (en) * | 2017-06-13 | 2018-12-13 | The Procter & Gamble Company | Consumer product |
| WO2018231750A1 (en) | 2017-06-13 | 2018-12-20 | The Procter & Gamble Company | Process for treating at least one garment |
| EP3415602A1 (en) * | 2017-06-13 | 2018-12-19 | The Procter & Gamble Company | Consumer product |
| EP3415603A1 (en) * | 2017-06-13 | 2018-12-19 | The Procter & Gamble Company | Consumer product |
| EP3441448A1 (en) * | 2017-08-11 | 2019-02-13 | The Procter & Gamble Company | Method of laundering fabrics |
| EP3441449A1 (en) * | 2017-08-11 | 2019-02-13 | The Procter & Gamble Company | Use of the combination of a cationic polysaccharide polymer and an anionic non-soap surfactant |
| JP2019099821A (en) * | 2017-12-06 | 2019-06-24 | 花王株式会社 | Liquid washing agent composition for textile product |
| US11662182B2 (en) | 2018-11-13 | 2023-05-30 | David Daniel Rankin, Sr. | Non-lethal defensive fluid composition and pressurized delivery system |
| US11320245B2 (en) | 2018-11-13 | 2022-05-03 | David Daniel Rankin, Sr. | Non-lethal defensive fluid composition and pressurized delivery system |
| US20200148965A1 (en) * | 2018-11-13 | 2020-05-14 | David Daniel Rankin, Sr. | Non-lethal defensive fluid composition and pressurized delivery system |
| US11499120B2 (en) * | 2020-01-30 | 2022-11-15 | Henkel Ag & Co. Kgaa | Three polymer blend to achieve fabric care in laundry |
| CA3230699A1 (en) * | 2020-03-26 | 2021-09-26 | David Daniel Rankin, Sr. | Non-lethal defensive fluid composition and pressurized delivery system |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2220099A (en) | 1934-01-10 | 1940-11-05 | Gen Aniline & Flim Corp | Sulphonic acids |
| US2477383A (en) | 1946-12-26 | 1949-07-26 | California Research Corp | Sulfonated detergent and its method of preparation |
| GB1234445A (en) | 1967-10-03 | 1971-06-03 | ||
| US3664961A (en) | 1970-03-31 | 1972-05-23 | Procter & Gamble | Enzyme detergent composition containing coagglomerated perborate bleaching agent |
| GB1372034A (en) | 1970-12-31 | 1974-10-30 | Unilever Ltd | Detergent compositions |
| US3919678A (en) | 1974-04-01 | 1975-11-11 | Telic Corp | Magnetic field generation apparatus |
| JPS5837833B2 (en) | 1976-08-11 | 1983-08-18 | 天野製薬株式会社 | Method for purifying microbial lipoprotein lipase |
| US4222905A (en) | 1978-06-26 | 1980-09-16 | The Procter & Gamble Company | Laundry detergent compositions having enhanced particulate soil removal performance |
| US4144226A (en) | 1977-08-22 | 1979-03-13 | Monsanto Company | Polymeric acetal carboxylates |
| US4246495A (en) | 1978-10-05 | 1981-01-20 | Jerome Pressman | Television monitor and control |
| US4239659A (en) | 1978-12-15 | 1980-12-16 | The Procter & Gamble Company | Detergent compositions containing nonionic and cationic surfactants, the cationic surfactant having a long alkyl chain of from about 20 to about 30 carbon atoms |
| US4663071A (en) | 1986-01-30 | 1987-05-05 | The Procter & Gamble Company | Ether carboxylate detergent builders and process for their preparation |
| GB8810954D0 (en) | 1988-05-09 | 1988-06-15 | Unilever Plc | Enzymatic detergent & bleaching composition |
| US4946624A (en) * | 1989-02-27 | 1990-08-07 | The Procter & Gamble Company | Microcapsules containing hydrophobic liquid core |
| US5234611A (en) * | 1991-08-28 | 1993-08-10 | The Procter & Gamble Company | Fabric softener, preferably liquid, with protected, dryer-activated, cyclodextrin/perfume complex |
| JPH05310542A (en) * | 1992-05-14 | 1993-11-22 | Kao Corp | Detergent composition |
| DK52393D0 (en) | 1993-05-05 | 1993-05-05 | Novo Nordisk As | |
| EP0668810B1 (en) | 1993-09-14 | 1999-12-01 | Regofix Ag | Clamping device for machine tools |
| AU736622B2 (en) | 1997-07-21 | 2001-08-02 | Procter & Gamble Company, The | Detergent compositions containing mixtures of crystallinity-disrupted surfactants |
| PH11998001775B1 (en) | 1997-07-21 | 2004-02-11 | Procter & Gamble | Improved alkyl aryl sulfonate surfactants |
| WO2001016263A2 (en) | 1999-08-27 | 2001-03-08 | The Procter & Gamble Company | Controlled availability of formulation components, compositions and laundry methods employing same |
| DE19941132A1 (en) | 1999-08-30 | 2001-03-01 | Basf Ag | Process for the continuous production of glutaraldehyde |
| GB9930433D0 (en) * | 1999-12-22 | 2000-02-16 | Unilever Plc | Use of fabric conditioning compositions for ironing benefits |
| ES2305492T3 (en) * | 2002-09-09 | 2008-11-01 | THE PROCTER & GAMBLE COMPANY | USE OF CATIONIC CELLS TO INCREASE THE RELEASE OF BENEFICIAL AGENTS FOR CARE OF FABRICS. |
| EP1462512B1 (en) * | 2003-03-24 | 2007-08-01 | The Procter & Gamble Company | Compositions comprising complexes of cyclodextrin and at least one laundry treatment active |
| US7226900B2 (en) * | 2003-06-16 | 2007-06-05 | The Proctor & Gamble Company | Liquid laundry detergent composition containing boron-compatible cationic deposition aids |
| EP1831341A1 (en) * | 2004-12-06 | 2007-09-12 | The Procter and Gamble Company | Fabric enhancing composition |
| GB0514147D0 (en) * | 2005-07-11 | 2005-08-17 | Unilever Plc | Laundry treatment compositions |
-
2007
- 2007-04-05 CA CA2645374A patent/CA2645374C/en not_active Expired - Fee Related
- 2007-04-05 MX MX2008013243A patent/MX2008013243A/en active IP Right Grant
- 2007-04-05 WO PCT/US2007/008376 patent/WO2007120547A1/en active Application Filing
- 2007-04-05 EP EP07754834A patent/EP2004785B1/en not_active Revoked
- 2007-04-05 AT AT07754834T patent/ATE520764T1/en not_active IP Right Cessation
- 2007-04-05 CN CNA2007800125838A patent/CN101415809A/en active Pending
- 2007-04-05 JP JP2009504274A patent/JP2009532566A/en active Pending
- 2007-04-05 RU RU2008138401/04A patent/RU2421506C2/en not_active IP Right Cessation
- 2007-04-05 BR BRPI0710140-6A patent/BRPI0710140A2/en not_active Application Discontinuation
- 2007-04-13 AR ARP070101589A patent/AR060456A1/en unknown
-
2008
- 2008-10-07 ZA ZA200808541A patent/ZA200808541B/en unknown
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102959070A (en) * | 2010-06-24 | 2013-03-06 | 宝洁公司 | Soluble unit dose articles comprising a cationic polymer |
| CN111465733A (en) * | 2017-12-06 | 2020-07-28 | 花王株式会社 | Detergent |
| US11359166B2 (en) | 2017-12-06 | 2022-06-14 | Kao Corporation | Fabric treatment composition |
| US11401350B2 (en) | 2017-12-06 | 2022-08-02 | Kao Corporation | Polysaccharide derivative |
| US11655434B2 (en) | 2017-12-06 | 2023-05-23 | Kao Corporation | Composition |
| US11655435B2 (en) | 2017-12-06 | 2023-05-23 | Kao Corporation | Hydroxy alkyl cellulose soil release agent with a cationic group and a C4—C12 hydrophobic group |
| CN111465733B (en) * | 2017-12-06 | 2023-06-06 | 花王株式会社 | Detergent |
| CN115667482A (en) * | 2020-06-02 | 2023-01-31 | 陶氏环球技术有限责任公司 | Aqueous liquid laundry detergent formulations |
Also Published As
| Publication number | Publication date |
|---|---|
| RU2421506C2 (en) | 2011-06-20 |
| CA2645374A1 (en) | 2007-10-25 |
| RU2008138401A (en) | 2010-05-20 |
| EP2004785B1 (en) | 2011-08-17 |
| ZA200808541B (en) | 2009-11-25 |
| EP2004785A1 (en) | 2008-12-24 |
| WO2007120547A1 (en) | 2007-10-25 |
| ATE520764T1 (en) | 2011-09-15 |
| CA2645374C (en) | 2011-11-29 |
| JP2009532566A (en) | 2009-09-10 |
| AR060456A1 (en) | 2008-06-18 |
| BRPI0710140A2 (en) | 2011-08-02 |
| MX2008013243A (en) | 2008-10-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101415809A (en) | Liquid laundry detergents containing cationic hydroxyethyl cellulose polymer | |
| US7576048B2 (en) | Liquid laundry detergents containing cationic hydroxyethyl cellulose polymer | |
| US10876072B2 (en) | Cleaning compositions containing a branched alkyl sulfate surfactant and a short-chain nonionic surfactant | |
| EP3298115B1 (en) | Method of making surfactant compositions and detergent compositions comprising alkoxylated glycerine as a solvent | |
| CN100591749C (en) | Fabric treatment compositions comprising oppositely charged polymers | |
| CN102257109B (en) | Laundry detergent composition | |
| CN100400634C (en) | Liquid laundry detergent composition containing boron-compatible cationic deposition aids | |
| US8293697B2 (en) | Structured fluid detergent compositions comprising dibenzylidene sorbitol acetal derivatives | |
| JP6640248B2 (en) | Detergent composition containing surfactant and propoxylated glycerin | |
| JP2020023709A (en) | Detergent composition containing surfactant and ethoxylated glycerin | |
| CA2575015A1 (en) | Softening laundry detergent | |
| CN102159693A (en) | Dual character biopolymer useful in cleaning products | |
| CN102959068A (en) | Stable compositions comprising cationic cellulose polymers and cellulase | |
| EP3655462B1 (en) | Functionalized siloxane polymers and compositions comprising same | |
| EP3322795A1 (en) | Cleaning compositions containing a cyclic amine and an encapsulated perfume | |
| US20180155658A1 (en) | Cleaning compositions including enzyme and bleach | |
| JP2002527575A (en) | Laundry detergent composition having cationically charged dye-retaining polymer | |
| CN1678723A (en) | Using cationic celluloses to enhance delivery of fabric care benefit agents | |
| CN102918142A (en) | Laundry detergent composition | |
| US20190119607A1 (en) | Laundry liquid composition | |
| EP3327106A1 (en) | Easy ironing/anti-wrinkle/less crease benefit by use of cationic polymers and its derivatives | |
| EP1392806B1 (en) | Method for softening fabrics | |
| WO2023072256A1 (en) | Fabric care composition comprising modified polysaccharides | |
| CA3234198A1 (en) | Methods for potentiating a biocide | |
| WO2007079849A1 (en) | Multiphase washing, rinsing or cleaning composition with vertical phase boundary |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20090422 |