CN101007622A - Device for tail chlorine degassing and absorption for preparing hydrochloride gas and its preparation method - Google Patents
Device for tail chlorine degassing and absorption for preparing hydrochloride gas and its preparation method Download PDFInfo
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Abstract
The invention discloses a device and making method of hydrogen chloride gas, which comprises the following parts: one and two-grade descending diaphragm absorber, condensed alcaine groove, desorption tower and reboiler. The making method comprises the following steps: transmitting tail chlorine and hydrogen into combusting reactor through condensate separator and gas-liquid separator to produce hydrogen chloride gas; flowing the gas into gas-liquid separator; desorbing the gas; obtaining the product.
Description
Technical field the invention belongs to chlorine industry tail chlorine processing technology field, relates to device of a kind of tail chlorine degassing and absorption for preparing hydrochloride gas and preparation method thereof.
Background technology is present, and in chemical industry, the tail chlorine that caustic soda produces is the principal element that restriction caustic soda scale enlarges always.Prior art is utilized the directly synthetic hydrogenchloride of producing of tail chlorine and hydrogen, its product component instability, and also content is low.
Summary of the invention the purpose of this invention is to provide device of a kind of tail chlorine degassing and absorption for preparing hydrochloride gas and preparation method thereof, and the hydrogen chloride gas component of this device and preparation method thereof preparation is stable and purity is high.
For achieving the above object, the device of tail chlorine degassing and absorption for preparing hydrochloride gas of the present invention comprises synthetic furnace, I and II falling-film absorber, concentrated hydrochloric acid groove, desorption tower and reboiler; The bottom of said synthetic furnace is connected with tail chlorine surge tank with the hydrogen condenswater separator by pipeline respectively, the top of synthetic furnace is connected with the I and II falling-film absorber through gas-liquid separator by pipeline, and the bottom of secondary falling-film absorber is connected with blower fan through bubble-plate column by pipeline; The bottom of one-level falling-film absorber is connected with the concentrated hydrochloric acid groove by pipeline, and top is connected with the dilute hydrochloric acid groove through the hydrochloric acid pump by pipeline; The bottom of secondary falling-film absorber is connected with the dilute hydrochloric acid groove by pipeline; Said concentrated hydrochloric acid groove is connected with dilute hydrochloric acid one-level water cooler by pipeline through the hydrochloric acid pump, and the dilute hydrochloric acid groove is connected by the top of pipeline with the dilute hydrochloric acid secondary coolers, connects by pipeline in the bottom of dilute hydrochloric acid I and II water cooler; Said dilute hydrochloric acid one-level water cooler is connected with the upper and lower position of desorption tower respectively by two pipelines; The bottom of said desorption tower is connected with top with the reboiler bottom by pipeline respectively with the bottom, and the top of desorption tower is connected with hydrogen chloride cooler by pipeline, and the bottom of hydrogen chloride cooler is connected with gas-liquid separator by pipeline.
The bottom of said reboiler is connected with condensate drum by pipeline.
The top of said concentrated hydrochloric acid groove, dilute hydrochloric acid groove is connected with liquid packing by pipeline respectively.
Said synthetic furnace is provided with hydrogen gas fire arrester with the pipeline that the hydrogen condenswater separator is connected.
Details are as follows for the processing step of its preparation hydrogen chloride gas of the present invention:
1), from the tail chlorine of chemical plant liquid chlorine operation, its purity 〉=70%, hydrogeneous≤4%, through tail chlorine surge tank, pressure-controlling is at 0.12～0.14Mpa, its flow control of tail chlorine after the voltage stabilizing is at 0～650m
3/ h, with the hydrogen after voltage stabilizing from the chemical plant, its purity 〉=99%, flow control is at 0～700m
3/ h, send into the abundant combustion reactions of synthetic furnace by condenswater separator and hydrogen gas fire arrester and generate hydrogen chloride gas, hydrogen chloride gas comes out from synthetic furnace top, top hole pressure is controlled at 0.05～0.06MPa, temperature is controlled at 0～50 ℃ and gets final product, enter gas-liquid separator and carry out gas-liquid separation, the hydrogen chloride gas after the separation comes out to enter tail chlorine and takes off and inhale device and produce hydrogen chloride gas from the top;
2), from the hydrogen chloride gas that gas-liquid separator comes out, at first enter the one-level falling-film absorber and carry out thorough mixing from the dilute hydrochloric acid of dilute hydrochloric acid groove, said dilute hydrochloric acid enters from the top of one-level falling-film absorber, flow control is at 0～30m
3/ h, the storage tank liquid level is controlled at 20%～80% of its capacity, becomes the concentrated hydrochloric acid that contains the HCl31% weight ratio behind the absorbing hydrogen chloride gas, flows out from the bottom of one-level falling-film absorber to enter the concentrated hydrochloric acid groove; Unabsorbed hydrogen chloride gas enters the top of secondary falling-film absorber again after coming out in one-level falling-film absorber bottom, hydrogen chloride gas and other gas that absorbs does not fully enter the bubble-plate column bottom, dilute hydrochloric acid after the absorption enters the dilute hydrochloric acid groove from the bottom of secondary falling-film absorber, squeezes into the one-level falling-film absorber through the hydrochloric acid pump and recycles; The unabsorbed hydrogen chloride gas that comes out from the secondary falling-film absorber and other gas enter bubble-plate column and absorb with de-salted water, and the de-salted water pressure-controlling is at 0.35～0.5MPa, and flow control is at 0～3m
3/ h, the dilute hydrochloric acid after the absorption is sent into the secondary falling-film absorber;
3), the concentrated hydrochloric acid of concentrated hydrochloric acid groove is quantitatively delivered to dilute hydrochloric acid one-level water cooler through the hydrochloric acid pump and is preheating to about 78～82 ℃, concentrated hydrochloric acid after the preheating enters the top of desorption tower, spray through the liquid distributor in the desorption tower, the desorption tower bottom communicates with reboiler, the reboiler interlayer heats with low-pressure steam, keeps tower still temperature at 106～110 ℃;
4), autospasy is inhaled the hydrogen chloride gas that top of tower comes out, its temperature is 85～90 ℃, enter from the top of one-level hydrogen chloride cooler, be cooled with circulating water, the hydrogen chloride gas temperature is controlled at less than below 40 ℃, and then enter the cooling of secondary chlorination hydrogen cooler from the top, with 0 ℃ of brine refrigeration, the salt solution return water temperature should remain on below 10 ℃, the concentrated acid that the cooling back produces flows out from the bottom of hydrogen chloride cooler and enters the concentrated hydrochloric acid groove, the hydrogen chloride gas that the cooling back produces enters into the hydrogenchloride gas-liquid separator separates, liquid after the separation enters the concentrated hydrochloric acid groove from the bottom of gas-liquid separator, and qualified hydrogen chloride gas is delivered to polyvinyl chloride workshop conversion procedure synthesizing chloroethylene monomer.
Apparatus of the present invention are simple in structure, feasible process, the hydrogen chloride gas quality of preparation is good, the purity height, and evidence: HCL content is up to more than 99.3%, component instability when having avoided the direct synthesising hydrogen of tail chlorine, hydrogen, shortcoming that content is too low, and hydrogenchloride has all passed through dry fully, and water content is low, and its every index can reach polyvinyl chloride (PVC) and produce required requirement, be ideal vinyl chloride monomer raw materials for production, and significantly improved its transformation efficiency.
Appended drawings is a flow sheet equipment connection diagram of the present invention.
Embodiment with reference to the accompanying drawings, the device of tail chlorine degassing and absorption for preparing hydrochloride gas of the present invention comprises synthetic furnace 19, I and II falling-film absorber 1,2, concentrated hydrochloric acid groove 20, desorption tower 4 and reboiler 9; The bottom of synthetic furnace 19 is connected with tail chlorine surge tank 16 with condenswater separator 17 by pipeline respectively, the top of synthetic furnace 19 is connected with I and II falling-film absorber 1,2 through gas-liquid separator 13a by pipeline, and the bottom of secondary falling-film absorber 2 is connected with blower fan 18 through bubble-plate column 3 by pipeline; The bottom of one-level falling-film absorber 1 is connected with concentrated hydrochloric acid groove 20 by pipeline, and top is connected with dilute hydrochloric acid groove 12 through hydrochloric acid pump 11 by pipeline; The bottom of secondary falling-film absorber 2 is connected with dilute hydrochloric acid groove 12 by pipeline; Concentrated hydrochloric acid groove 20 is connected with dilute hydrochloric acid one-level water cooler 7 by pipeline through hydrochloric acid pump 10, and dilute hydrochloric acid groove 12 is connected by the top of pipeline with dilute hydrochloric acid secondary coolers 8, connects by pipeline in the bottom of dilute hydrochloric acid I and II water cooler 7,8; Dilute hydrochloric acid one-level water cooler 7 is connected with the upper and lower position of desorption tower 4 respectively by two pipelines; The bottom of desorption tower 4 is connected with top with reboiler 9 bottoms by pipeline respectively with the bottom, the top of desorption tower 4 is connected with hydrogen chloride cooler 5 by pipeline, the bottom of hydrogen chloride cooler 6 is connected with gas-liquid separator 13b by pipeline, and hydrogen chloride cooler 5 and hydrogen chloride cooler 6 are connected by pipeline; The bottom of reboiler 9 is connected with condensate drum 15 by pipeline; The top of concentrated hydrochloric acid groove 20, dilute hydrochloric acid groove 12 is connected with liquid packing 14 by pipeline respectively; Synthetic furnace 19 is provided with hydrogen gas fire arrester with the pipeline that condenswater separator 17 is connected.
With reference to the accompanying drawings, details are as follows for the processing step of its preparation hydrogen chloride gas of the present invention:
1), from the tail chlorine of chemical plant liquid chlorine operation, its purity 〉=70%, hydrogeneous≤4%, through tail chlorine surge tank 16, pressure-controlling is at 0.12～0.14Mpa, its flow control of tail chlorine after the voltage stabilizing is at 0～650m
3/ h, with the hydrogen after voltage stabilizing from the chemical plant, its purity 〉=99%, flow control is at 0～700m
3/ h, send into synthetic furnace 19 abundant combustion reactionss by condenswater separator 17 and hydrogen gas fire arrester and generate hydrogen chloride gas, hydrogen chloride gas comes out from synthetic furnace top, top hole pressure is controlled at 0.05～0.06MPa, temperature is controlled at 0～50 ℃ and gets final product, enter gas-liquid separator 13a and carry out gas-liquid separation, the hydrogen chloride gas after the separation comes out to enter tail chlorine and takes off and inhale device and produce hydrogen chloride gas from the top;
2), from the hydrogen chloride gas that gas-liquid separator 13a comes out, at first enter one-level falling-film absorber 1 and carry out thorough mixing with dilute hydrochloric acid from dilute hydrochloric acid groove 12, said dilute hydrochloric acid enters from the top of one-level falling-film absorber 1, flow control is at 0～30m
3/ h, the storage tank liquid level is controlled at 20%～80% of its capacity, becomes the concentrated hydrochloric acid that contains the HCl31% weight ratio behind the absorbing hydrogen chloride gas, flows out from the bottom of one-level falling-film absorber 1 to enter concentrated hydrochloric acid groove 20; Unabsorbed hydrogen chloride gas enters the top of secondary falling-film absorber 2 again after coming out in one-level falling-film absorber 1 bottom, hydrogen chloride gas and other gas that absorbs does not fully enter bubble-plate column 3 bottoms, dilute hydrochloric acid after the absorption enters dilute hydrochloric acid groove 12 from the bottom of secondary falling-film absorber 2, squeezes into one-level falling-film absorber 1 through hydrochloric acid pump 11 and recycles; The unabsorbed hydrogen chloride gas and other gas that come out from secondary falling-film absorber 2 enter the absorption of bubble-plate column 3 usefulness de-salted waters, and the de-salted water pressure-controlling is at 0.35～0.5MPa, and flow control is at 0～3m
3/ h, the dilute hydrochloric acid after the absorption is sent into the secondary falling-film absorber;
3), the concentrated hydrochloric acid of concentrated hydrochloric acid groove 20 is quantitatively delivered to dilute hydrochloric acid one-level water cooler 7 through hydrochloric acid pump 10 and is preheating to about 78～82 ℃, concentrated hydrochloric acid after the preheating enters the top of desorption tower 4, spray through the liquid distributor in the desorption tower 4, desorption tower 4 bottoms communicate with reboiler 9, reboiler 9 interlayers heat with low-pressure steam, flow by control steam, keep tower still temperature at 106～110 ℃, therefore the hydrochloric acid soln of reboiler 9 outlets is the gas-liquid mixtures that are the shape that seethes with excitement, this gas-liquid mixture is past the rising from desorption tower 4 bottoms, spray the concentrated hydrochloric acid solution that comes from top to bottom with desorption tower 4 inside and carry out heat exchange, through mass transfer, heat transfer makes in the concentrated hydrochloric acid hydrogen chloride gas be heated to take off and sucks out;
4), the hydrogen chloride gas that comes out from desorption tower 4 tops, its temperature is 85～90 ℃, earlier through the secondary chlorination hydrogen cooler, enter from the top of one-level hydrogen chloride cooler 5, be cooled with circulating water, the hydrogen chloride gas temperature is controlled at less than below 40 ℃, and then enter 6 coolings of secondary chlorination hydrogen cooler from the top, with 0 ℃ of brine refrigeration, the salt solution return water temperature should remain on below 10 ℃, the concentrated acid that the cooling back produces flows out from the bottom of hydrogen chloride cooler and enters concentrated hydrochloric acid groove 20, the hydrogen chloride gas that the cooling back produces enters into hydrogen chloride gas liquid/gas separator 13b to be separated, liquid after the separation enters concentrated hydrochloric acid groove 20 from the bottom of gas-liquid separator 13b, and qualified hydrogen chloride gas is delivered to polyvinyl chloride workshop conversion procedure synthesizing chloroethylene monomer.
The type selecting of equipment: the character characteristics under conditions such as differing temps, pressure and concentration according to HCl gas and hydrochloric acid, the contrive equipment of our company is mainly selected graphite, glass reinforced plastic and steel lining tetrafluoro equipment (seeing Table 1) for use.
Table 1: the type selecting of the appliance arrangement of tail chlorine degassing and absorption for preparing hydrochloride gas
| Sequence number | Device name | Specifications and models | Material | Unit | Quantity |
| 1 | The one-level falling-film absorber | YKX160m 2 | Graphite | Platform | 1 |
| 2 | The secondary falling-film absorber | YKX120m 2 | Graphite | Platform | 1 |
| 3 | Bubble-plate column | φ600×4000 | Graphite | Platform | 1 |
| 4 | Desorption tower | φ1200×12600 | Graphite | Platform | 1 |
| 5 | Hydrogenchloride one-level water cooler | YKB100m 2 | Graphite | Platform | 1 |
| 6 | The hydrogenchloride secondary coolers | YKB60m 2 | Graphite | Platform | 1 |
| 7 | Dilute hydrochloric acid one-level water cooler | YKB120m 2 | Graphite | Platform | 1 |
| 8 | The dilute hydrochloric acid secondary coolers | YKB80m 2 | Graphite | Platform | 1 |
| 9 | Reboiler | YKB140m 2 | Graphite | Platform | 1 |
| 10 | The hydrochloric acid pump | 50FS-25-28 | Tetrafluoro | |
2 |
| 11 | The hydrochloric acid pump | 50FS-20-30 | Tetrafluoro | |
2 |
| 12 | The dilute hydrochloric acid groove | φ2000×3000 | FRP | Platform | 1 |
| 13-a | Gas-liquid separator | φ800×2150 | FRP | Platform | 1 |
| 13-b | Gas-liquid separator | φ800×2150 | FRP | Platform | 1 |
| 14 | Liquid packing | Φ600×1100 | FRP | Platform | 1 |
| 15 | Condensate drum | Φ600×1600 | Carbon steel | Platform | 1 |
| 16 | The tail Chlorine Buffer Vessel | φ2000×4468 | Carbon steel | Platform | 1 |
| 17 | Condenswater separator | φ800×1000 | Carbon steel | Platform | 1 |
| 18 | Blower fan | HTF-250 | Pottery | Platform | 1 |
| 19 | Synthetic furnace | SSL-1200 | Graphite | Platform | 1 |
| 20 | The concentrated hydrochloric acid groove | φ2000×3000 | FRP | Platform | 1 |
(seeing Table 2,3,4,5,6) determined in our company's production technique index and operation:
Table 2: temperature
| Sequence number | Item | Title | Index |
| 1 | TI-302a-c | Synthetic furnace recirculated water return water temperature | 0℃≤45 |
| 2 | TI-303a-c | Synthetic furnace goes out the HCl temperature | 0℃≤50℃ |
| 3 | TI-304a-c | The hot return water temperature of synthetic furnace | 0℃≤100℃ |
| 4 | TI-361 | One-level falling liquid film return water temperature | 0℃≤45℃ |
| 5 | TI-362 | Secondary falling liquid film return water temperature | 0℃≤45℃ |
| 6 | TI-363 | Concentrated acid temperature after the preheating | 0℃≤80 |
| 7 | TI-364 | Desorption tower top temperature | 0℃≤90 |
| 8 | TI-365 | One-level cooling back HCL temperature | 0℃≤50℃ |
| 9 | TI-366 | Secondary cooling back HCL temperature | 0℃≤40 |
| 10 | TI-367 | Cooling back diluted acid temperature | 0℃≤45 |
| 11 | TRC-368 | Desorption tower still temperature temperature regulation | 106℃-110 |
| 12 | TI-369 | One-level HCL water cooler return water temperature | 0℃≤40 |
| 13 | TI-370 | Diluted acid water cooler return water temperature | 0℃≤40 |
| 14 | TI-371 | The chilled brine return water temperature | 0℃≤10℃ |
Table 3: pressure
| Sequence number | Item | Title | Index |
| 1 | PI-361 | The desorption tower top hole pressure | 0.05-0.06 |
| 2 | PI-363 | Decompression back vapor pressure | 0.35-0.5MPa |
| 3 | PRCA-365 | Tail chlorine surge tank pressure is regulated | 0.12-0.14MPa |
| 4 | PI-311 | The on-the-spot pressure of de-salted water | 0.35-0.5MPa |
| 5 | PI-303a-c | The synthetic furnace top hole pressure shows | 0.05-0.06MPa |
| 6 | PR-304 | Go outer tube HCl pressure survey | 0.05-0.06MPa |
Table 4: liquid level
| Sequence number | Item | Title | Index | |
| 1 | LI-362 | Concentrated hydrochloric acid storage tank liquid level | 30-2000cm | |
| 2 | LI-363 | Dilute hydrochloric acid storage tank liquid level | 30-2000cm | |
| 3 | LIC-365 | The desorption tower liquid level | 50-60％ | |
| 4 | LIC-366 | The condensate drum liquid level | 30-40％ | |
| 5 | LI-367 | Take off the on-the-spot liquid level of air-breathing liquid/gas separator | 0-10cm | |
| 6 | LI-602 | The on-the-spot liquid level of | Overflow | |
| 7 | LI-604 | 500m 3Acid jar on-the-spot liquid level | 1- | |
| 8 | LI-605 | 500m 3Acid jar liquid level | 20-80％ |
Table 5: flow
| Sequence number | Item | Title | Index |
| 1 | FRC-301a-c | Go into the stove hydrogen flowing quantity and show adjusting | 0-700m
3/ |
| 2 | FRC-302a-c | Go into the stove chlorine flowrate and show adjusting | 0-650m 3/h |
| 3 | FI-361 | Bubble-plate column discharge shows | 0-3m 3/h |
| 4 | FI-362 | Go into one-level falling liquid film diluted acid flow | 0-30m 3/h |
| 5 | FI-363 | Go into desorption tower concentrated acid flow | 0-30m 3/h |
Table 6: quality
| Sequence number | Title | Index |
| 1 | Tail chlorine purity | 〉=70% hydrogeneous≤4% |
| 2 | Hydrogen purity | 99％ |
| 3 | Dilute acid concentration | ≥20-24％(w/w) |
| 4 | Absorb acid concentration | 31.3-31.7％(w/w) |
| 5 | Hydrogeneous in the stove | ＜0.4％ |
Details are as follows in ordinary production operation of the present invention:
1, the flame of looking over one's shoulder changes, and regulates H
2With tail Cl
2Proportioning, making flame stabilization is Bluish white.
2, often note H
2With tail Cl
2Pressure, whether each technic index is normal.Synthetic furnace pressure when operation must not surpass 0.1MPa.
3, often note and regulate and absorb discharge, analyze the HCl gas purity, absorb acid concentration.Output and balance gas HCl according to acid decide the size that absorbs discharge.
4, carry out tours of inspection according to system of job responsibility.
5, carry out sampling analysis according to inspection plan, in time adjust operating mode.
6, often noticing that exoneration is inhaled glass valves slightly puts condensation acid, stops to collaborate or condensation acid is put unclean.
7, often patrol and examine the running condition of taking off desorption system.
Main innovate point of the present invention:
1, this covering device is compared the technique advanced person with domestic existing device of the same type, and single cover production capacity is large;
2, automatic instrument(s) is all adopted at all control points of tail villaumite acid desorption project, and automaticity is high;
3, the hydrogen chloride gas weight of tail villaumite acid desorption device generation is good. The hydrochloric acid desorption is adopted in the production of hydrogen chloride, the shortcoming that component is unstable, content is too low when having avoided tail chlorine, the direct synthesising hydrogen of hydrogen, and hydrogen chloride all passed through dryly fully, and water content is low. Its indices can reach PVC and produce required requirement, and HCL content not only produces qualified VCM up to more than 99.3%, has also significantly improved conversion ratio;
4, the maximum innovative point of this device is: use the tail chlorine synthesising hydrogen after former chlorine liquefies, desorption goes out hydrogen chloride again behind absorption by Hydrochloric Acid. In balance caustic soda tail chlorine, when the hydrogen chloride that provides high-quality transforms for PVC, greatly reduce the cost of PVC.
The condition that the present invention applies and prospect:
The condition of applying: at present domestic PVC produces most former chlorine production HCl gases that adopt, and former chlorine cost is higher. The price of chlorine shared proportion in the PVC cost is also larger. Adopt after the tail chlorine, the production cost of HCl gas per ton will reduce about 430 yuan, produce with respect to PVC, and it is remarkable to reduce cost. In chemical industry, the tail chlorine that caustic soda produces is the principal element of restriction caustic soda popularization always, but and the both tail chlorine of balance caustic soda of tail villaumite acid desorption device can reduce again the production cost of PVC greatly. Therefore, the popularization of tail villaumite acid desorption, significant for the development of caustic soda.
Industrialization prospect: in this process units, automaticity is higher, and labor intensity of operating staff is low, and needs personnel few, and remarkable in economical benefits forms large-scale industrialized production easily.
Claims (5)
1, a kind of device of tail chlorine degassing and absorption for preparing hydrochloride gas is characterized in that comprising synthetic furnace, I and II falling-film absorber, concentrated hydrochloric acid groove, desorption tower and reboiler; The bottom of said synthetic furnace is connected with tail chlorine surge tank with the hydrogen condenswater separator by pipeline respectively, the top of synthetic furnace is connected with the I and II falling-film absorber through gas-liquid separator by pipeline, and the bottom of secondary falling-film absorber is connected with blower fan through bubble-plate column by pipeline; The bottom of one-level falling-film absorber is connected with the concentrated hydrochloric acid groove by pipeline, and top is connected with the dilute hydrochloric acid groove through the hydrochloric acid pump by pipeline; The bottom of secondary falling-film absorber is connected with the dilute hydrochloric acid groove by pipeline; Said concentrated hydrochloric acid groove is connected with dilute hydrochloric acid one-level water cooler by pipeline through the hydrochloric acid pump, and the dilute hydrochloric acid groove is connected by the top of pipeline with the dilute hydrochloric acid secondary coolers, connects by pipeline in the bottom of dilute hydrochloric acid I and II water cooler; Said dilute hydrochloric acid one-level water cooler is connected with the upper and lower position of desorption tower respectively by two pipelines; The bottom of said desorption tower is connected with top with the reboiler bottom by pipeline respectively with the bottom, and the top of desorption tower is connected with hydrogen chloride cooler by pipeline, and the bottom of hydrogen chloride cooler is connected with gas-liquid separator by pipeline.
2, the device of tail chlorine degassing and absorption for preparing hydrochloride gas according to claim 1 is characterized in that the bottom of said reboiler is connected with condensate drum by pipeline.
3, the device of tail chlorine degassing and absorption for preparing hydrochloride gas according to claim 1 is characterized in that the top of said concentrated hydrochloric acid groove, dilute hydrochloric acid groove is connected with liquid packing by pipeline respectively.
4, the device of tail chlorine degassing and absorption for preparing hydrochloride gas according to claim 1 is characterized in that said synthetic furnace is provided with hydrogen gas fire arrester with the pipeline that the hydrogen condenswater separator is connected.
5, according to the method for preparing hydrogen chloride gas according to claim 1,2,3 or 4 described tail chlorine degassing and absorption for preparing hydrochloride gas devices, it is characterized in that being undertaken by following processing step:
1), from the tail chlorine of chemical plant liquid chlorine operation, its purity 〉=70%, hydrogeneous≤4%, through tail chlorine surge tank, pressure-controlling is at 0.12～0.14Mpa, its flow control of tail chlorine after the voltage stabilizing is at 0～650m
3/ h, with the hydrogen after voltage stabilizing from the chemical plant, its purity 〉=99%, flow control is at 0～700m
3/ h, send into the abundant combustion reactions of synthetic furnace by condenswater separator and hydrogen gas fire arrester and generate hydrogen chloride gas, hydrogen chloride gas comes out from synthetic furnace top, top hole pressure is controlled at 0.05～0.06MPa, temperature is controlled at 0～50 ℃ and gets final product, enter gas-liquid separator and carry out gas-liquid separation, the hydrogen chloride gas after the separation comes out to enter tail chlorine and takes off and inhale device and produce hydrogen chloride gas from the top;
2), from the hydrogen chloride gas that gas-liquid separator comes out, at first enter the one-level falling-film absorber and carry out thorough mixing from the dilute hydrochloric acid of dilute hydrochloric acid groove, said dilute hydrochloric acid enters from the top of one-level falling-film absorber, flow control is at 0～30m
3/ h, the storage tank liquid level is controlled at 20%～80% of its capacity, becomes the concentrated hydrochloric acid that contains the HCl31% weight ratio behind the absorbing hydrogen chloride gas, flows out from the bottom of one-level falling-film absorber to enter the concentrated hydrochloric acid groove; Unabsorbed hydrogen chloride gas enters the top of secondary falling-film absorber again after coming out in one-level falling-film absorber bottom, hydrogen chloride gas and other gas that absorbs does not fully enter the bubble-plate column bottom, dilute hydrochloric acid after the absorption enters the dilute hydrochloric acid groove from the bottom of secondary falling-film absorber, squeezes into the one-level falling-film absorber through the hydrochloric acid pump and recycles; The unabsorbed hydrogen chloride gas that comes out from the secondary falling-film absorber and other gas enter bubble-plate column and absorb with de-salted water, and the de-salted water pressure-controlling is at 0.35～0.5MPa, and flow control is at 0～3m
3/ h, the dilute hydrochloric acid after the absorption is sent into the secondary falling-film absorber;
3), the concentrated hydrochloric acid of concentrated hydrochloric acid groove is quantitatively delivered to dilute hydrochloric acid one-level water cooler through the hydrochloric acid pump and is preheating to about 78～82 ℃, concentrated hydrochloric acid after the preheating enters the top of desorption tower, spray through the liquid distributor in the desorption tower, the desorption tower bottom communicates with reboiler, the reboiler interlayer heats with low-pressure steam, keeps tower still temperature at 106～110 ℃;
4), autospasy is inhaled the hydrogen chloride gas that top of tower comes out, its temperature is 85～90 ℃, enter from the top of one-level hydrogen chloride cooler, be cooled with circulating water, the hydrogen chloride gas temperature is controlled at less than below 40 ℃, and then enter the cooling of secondary chlorination hydrogen cooler from the top, with 0 ℃ of brine refrigeration, the salt solution return water temperature should remain on below 10 ℃, the concentrated acid that the cooling back produces flows out from the bottom of hydrogen chloride cooler and enters the concentrated hydrochloric acid groove, the hydrogen chloride gas that the cooling back produces enters into the hydrogenchloride gas-liquid separator separates, liquid after the separation enters the concentrated hydrochloric acid groove from the bottom of gas-liquid separator, and qualified hydrogen chloride gas is delivered to polyvinyl chloride workshop conversion procedure synthesizing chloroethylene monomer.
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| CN102502497A (en) * | 2011-10-18 | 2012-06-20 | 山东聊城鲁西化工第四化肥有限公司 | Graded and continuous production device and technique of hydrochloric acid |
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| CN103663371B (en) * | 2013-11-21 | 2015-06-17 | 南通星球石墨设备有限公司 | Lower chamfer structure at bubble cap section of four-in-one graphite hydrochloric acid synthetic furnace |
| CN104310310A (en) * | 2014-11-14 | 2015-01-28 | 太原理工大学 | Device and method for catalytically dehydrogenating tail chlorine in chlor-alkali industry |
| CN106582271A (en) * | 2016-12-06 | 2017-04-26 | 太原理工大学 | Device and method for catalytic dehydrogenation and ferric chloride preparation of tail chlorine in chlor-alkali industry |
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| CN108325541A (en) * | 2018-03-26 | 2018-07-27 | 内蒙古鄂尔多斯电力冶金集团股份有限公司 | The activation system and method for calcium carbide process PVC production of resins catalyst |
| CN108325541B (en) * | 2018-03-26 | 2023-12-05 | 内蒙古鄂尔多斯电力冶金集团股份有限公司 | System and method for activating catalyst for calcium carbide PVC resin production |
| CN108314603A (en) * | 2018-03-29 | 2018-07-24 | 内蒙古鄂尔多斯电力冶金集团股份有限公司 | A kind of hydrochloric acid full stripping devices and methods therefor |
| CN112933880A (en) * | 2021-02-04 | 2021-06-11 | 济源市恒通高新材料有限公司 | Sulfur dioxide recovery process and device for terephthaloyl chloride production tail gas |
| CN114148991A (en) * | 2021-12-16 | 2022-03-08 | 安徽华塑股份有限公司 | Dehydrogenation method of hydrogen chloride raw material gas for acetylene method chloroethylene synthesis |
| CN114148991B (en) * | 2021-12-16 | 2024-01-16 | 安徽华塑股份有限公司 | Dehydrogenation method of hydrogen chloride raw material gas for synthesizing chloroethylene by acetylene method |
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