CN109954579A - Two product ore-dressing technique of apatite ilmenite - Google Patents
Two product ore-dressing technique of apatite ilmenite Download PDFInfo
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- CN109954579A CN109954579A CN201910246340.5A CN201910246340A CN109954579A CN 109954579 A CN109954579 A CN 109954579A CN 201910246340 A CN201910246340 A CN 201910246340A CN 109954579 A CN109954579 A CN 109954579A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B7/00—Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
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Abstract
The invention belongs to technical field of beneficiation, provide a kind of two product ore-dressing technique of apatite ilmenite, including three sections of broken process, first segment ball milling and cyclone it is closed circuit, mix prefloat, second segment ball milling and second segment cyclone is closed circuit, low intensity magnetic separation, high intensity magnetic separation, de-magging rough floatation, de-magging cleaner flotation, titanium phosphorus separating flotation, the sub- technique of titanium ore dressing and phosphorus flotation.Technique of the invention passes through magnetic separation deferrization and flotation magnesium, improve the quality of obtained ilmenite concentrate, initial gross separation is carried out with Phosphate minerals to the titanium in mineral products by titanium phosphorus separating flotation, carry out the ore dressing processing of titanium and phosphorus respectively again, pass through present invention process process above-mentioned, the preferable ilmenite concentrate of quality can be obtained from apatite-ilmenite, while recycling phosphorus concentrate, improve the economic benefit of natural resource utilizing rate and dressing plant.
Description
Technical field
The invention belongs to technical field of beneficiation, more particularly to a kind of two product ore-dressing technique of apatite ilmenite.
Background technique
Titanium has the advantages of steel (intensity high) and aluminium (quality is light) concurrently simultaneously, pure titanium has good plasticity, it tough
Property more than 2 times of pure iron, heat-resisting and corrosion resistance is also fine.Since titanium there are these advantages, rare gold outstanding is promoted it as
Category, titanium and its alloy are first utilized in manufacture aircraft, rocket, guided missile, naval vessels etc., are widely used in chemical industry and petroleum again later
Department.
Ilmenite is main titaniferous ore, is the most important source of Titanium, TiO2Theoretical content 52.66%, iron
Content be generally between 20%-30%.The chemical component of ilmenite is related with formation condition.Currently, many mines are contained greatly
Apatite-ilmenite of amount.The ore in similar area mine generally contains TiO2Content is between 4%-8%, TiO2Content is higher,
The condition for having the ilmenite concentrate for obtaining high-quality.Its P2O5Content be generally 2% or more, P2O5Mainly in the form of apatite
In the presence of；Furthermore this kind of ore often ilmenite also with a certain amount of magnetic iron ore association, and also contain a small amount of martite, this
A little iron minerals are similar with the specific gravity of ilmenite and also similar to the affinity of water, so it easily in the gravity treatment of ilmenite and is floated
It chooses and is entered in ilmenite concentrate with ilmenite, cause ilmenite concentrate grade not high.Also containing a certain amount of in the gangue of this ore
It containing magnesium mica, if these magnesium are not deviate from, enters eventually into ilmenite concentrate, the credit rating of ilmenite concentrate can be reduced, reduce
Its price.Furthermore this kind of mineral phosphorus content is higher, if can recycle to phosphorus, not only conforms with the principle of resource high-efficiency recycling,
And the economic benefit for selecting factory will be further increased in the phosphorus concentrate obtained.
From the above, it is seen that green ore TiO2It is higher, P2O5Content it is also higher, content of MgO is also higher, and
Contain a certain amount of iron mineral, also to obtain good titanium fine powder, it is necessary to in ore iron and magnesium deviate from, to obtain
Synthetical recovery must also be subject to phosphorus by obtaining higher economic benefit.So we can effectively improve titanium essence it is necessary to develop one kind
TiO in powder2Content, apatite-ilmenite that iron content and content of MgO is effectively reduced select phosphorus to select titanium deferrization de-magging technique.
Summary of the invention
In order to solve the above-mentioned technical problems, the present invention provides a kind of two product ore-dressing techniques of apatite ilmenite, including
Three sections of broken process, first segment ball milling and cyclone are closed circuit, mix prefloat, second segment ball milling and second segment cyclone are closed circuit,
Low intensity magnetic separation, high intensity magnetic separation, de-magging rough floatation, de-magging cleaner flotation, titanium phosphorus separating flotation, the sub- technique of titanium ore dressing and phosphorus flotation；
Raw ore is after three sections of broken process, and to feed first segment ball milling closed circuit with cyclone for the crushed product that granularity is 0-12mm
In first segment ball milling, product feeds cyclone after first segment ball milling ore grinding, and the sand setting of cyclone returns to first segment ball milling and formed
It is closed circuit, the granularity P of cyclone80Mixing prefloat is fed for 60~70 μm of overflow product；
Mixing prefloat concentrate feed second segment ball milling and second segment cyclone it is closed circuit in second segment cyclone, second
The sand setting of section cyclone feeds second segment ball milling, product after second segment ball milling ore grinding return second segment cyclone formed it is closed circuit,
The P of second segment cyclone80Overflow for 30~40 μm feeds low intensity magnetic separation；
The concentrate of low intensity magnetic separation feeds high intensity magnetic separation, and the concentrate of high intensity magnetic separation feeds de-magging rough floatation, the underflow essence of de-magging rough floatation
Mine feeds de-magging cleaner flotation, and the underflow concentrate of de-magging cleaner flotation feeds titanium phosphorus separating flotation；
The concentrate of titanium phosphorus separating flotation feeds the sub- technique of titanium ore dressing, and the concentrate of the sub- technique of titanium ore dressing is ilmenite concentrate；
The tailing of titanium phosphorus separating flotation feeds phosphorus flotation, and the concentrate of phosphorus flotation is phosphorus concentrate；
It is floating to mix the tailing of prefloat, the tailing of low intensity magnetic separation, the tailing of high intensity magnetic separation, the tailing of de-magging rough floatation, de-magging essence
Tailing, the tailing of the sub- technique of titanium ore dressing and the tailing of phosphorus flotation of choosing collectively form technique tailing and throw tail.
Preferably, the mixing prefloat includes mixing pre- rough floatation, the pre- cleaner flotation of mixing and mixing three times to sweep flotation in advance,
Mixing prefloat is reverse flotation；The overflow product of cyclone feeds the pre- rough floatation of mixing, mix the underflow concentrate of pre- rough floatation to
Enter and mix pre- cleaner flotation, the foam tailing for mixing pre- rough floatation feeds to mix for the first time sweeps flotation in advance, and mixing is swept floating in advance for the first time
The foam tailing of choosing feeds second of mixing and sweeps flotation in advance, and the foam tailing that flotation is swept in second of mixing in advance feeds third time and mixes
Sweep flotation in advance, third time, which mixes, sweeps the underflow concentrate of flotation in advance and return to mix for the first time and sweep flotation in advance, and mixing is swept floating in advance for the first time
The underflow concentrate of choosing, the foam tailing return mixing for mixing the underflow concentrate for sweeping flotation in advance for second and mixing pre- cleaner flotation are pre- thick
Flotation；The concentrate for mixing pre- cleaner flotation is the concentrate for mixing prefloat, and it is to mix that third time, which mixes and sweeps the tailing of flotation in advance,
The tailing of prefloat.
Further, the ethylenediamine collecting agent and 18-22g per ton that 108-132g is added to mine in the pre- rough floatation of mixing
Foaming agent methyl isobutyl carbinol；In the pre- cleaner flotation of the mixing it is per ton to mine be added 72-88g ethylenediamine collecting agent and
The foaming agent methyl isobutyl carbinol of 13-16g；The second two per ton that 36-45g is added to mine in flotation is swept in the first time mixing in advance
The foaming agent methyl isobutyl carbinol of amine collecting agent and 9-11g.
Preferably, the sub- technique of titanium ore dressing includes three sections of shaking tables；The concentrate of titanium phosphorus separating flotation feeds first segment shaking table,
The chats of first segment table concentration feeds second segment table concentration, and the chats of second segment table concentration feeds third section shaking table weight
Choosing, the concentrate of three sections of table concentrations is the concentrate of the sub- technique of titanium ore dressing, and the tailing of three sections of table concentrations is the sub- work of titanium ore dressing
The tailing of skill.
Preferably, the phosphorus flotation includes that phosphorus rough floatation, phosphorus sweep flotation and twice phosphorus cleaner flotation, and phosphorus flotation is direct flotation；
The tailing of titanium phosphorus separating flotation feeds phosphorus rough floatation, and the froth concentrate of phosphorus rough floatation feeds first time phosphorus cleaner flotation, first time phosphorus
The concentrate of cleaner flotation feeds second of phosphorus cleaner flotation, and the underflow tailing of phosphorus rough floatation feeds phosphorus and sweeps flotation, second of phosphorus cleaner flotation
Underflow tailing return first time phosphorus cleaner flotation, the underflow tailing and phosphorus of first time phosphorus cleaner flotation sweep flotation froth concentrate return
Phosphorus rough floatation, the froth concentrate of second of phosphorus cleaner flotation are the concentrate of phosphorus flotation, and the tailing that phosphorus sweeps flotation is phosphorus flotation
Tailing.
Further, per ton in the phosphorus rough floatation that apatite collecting agent tall oil 135-165g, gangue suppression is added to mine
Preparation waterglass 72-88g and foaming agent methoxyl group polypropylene glycol 18-22g/t；It is per ton in first time phosphorus cleaner flotation to be caught to mine addition
It receives agent tall oil 81-99g, gangue inhibitor waterglass 45-55g and foaming agent methoxyl group polypropylene glycol 13-16g, phosphorus and sweeps flotation
In it is per ton give mine be added foaming agent methoxyl group polypropylene glycol 9-11g.
Preferably, the magnetic field strength of the low intensity magnetic separation is 1800-2200GS, and the magnetic field strength of high intensity magnetic separation is 7200-
8800GS。
Preferably, per ton in the de-magging rough floatation that PH regulator sulfuric acid 180-220g, ether amines collecting agent 55- is added to mine
66g and foaming agent 2# oil 13-16g；It is per ton in the de-magging cleaner flotation that ether amines collecting agent 27-33g is added to mine.
Preferably, per ton in the titanium phosphorus separating flotation that apatite collecting agent tall oil 135-165g, ferrotianium is added to mine
Mine mineral inhibitor starch 90-110g and foaming agent methoxyl group polypropylene glycol 18-22g.
Preferably, the valuable mineral main component of the raw ore is ilmenite and apatite, and the gangue mineral of raw ore is main
For pyroxene, mica, quartz, magnetic iron ore and martite；TiO2Content be 8.5%, P2O5Content be the 2.3%, product of iron
Position be the content of 13.5% and MgO be 3.5% raw ore after above-mentioned two product ore-dressing technique of apatite ilmenite processing, obtain
Obtain TiO2Content is 45.0%, P2O5Content be 0.05%, the content of Fe is 22.6%, the content of MgO is 0.45%, TiO2
The rate of recovery be 58.0%, P2O5The rate of recovery be 0.24%, the titanium that the Fe rate of recovery is 18.34% and the MgO rate of recovery is 1.41%
Concentrate, and obtain TiO2Content is 0.7%, P2O5Content be 38.0%, the content of Fe is 1.3%, the content of MgO is
0.4%, TiO2The rate of recovery be 0.29%, P2O5The rate of recovery be 58%, the Fe rate of recovery is 0.34% and the MgO rate of recovery is
0.4% phosphorus concentrate.
Technique of the invention improves the quality of obtained ilmenite concentrate, passes through titanium phosphorus by magnetic separation deferrization and flotation magnesium
Separating flotation carries out initial gross separation with Phosphate minerals to the titanium in mineral products, then carries out the ore dressing processing of titanium and phosphorus respectively, by aforementioned
Present invention process process, the preferable ilmenite concentrate of quality can be obtained from apatite-ilmenite, while recycling phosphorus concentrate, improve from
The economic benefit of right resource utilization and dressing plant.
Detailed description of the invention
Fig. 1 is two product ore-dressing technique embodiment flow diagram of apatite ilmenite；
Fig. 2 is the mixing prefloat flow diagram of two product ore-dressing technique embodiment of apatite ilmenite；
Fig. 3 is the sub- process flow diagram of titanium ore dressing of two product ore-dressing technique embodiment of apatite ilmenite；
Fig. 4 is the phosphorus flotation flowsheet schematic diagram of two product ore-dressing technique embodiment of apatite ilmenite.
Specific embodiment
In order to further illustrate the technical means and efficacy of the invention taken in order to solve the technical problem, below in conjunction with attached
Figure the invention will be described in further detail with specific embodiment, but not as the present invention claims protection scope limit.
The process of two product ore-dressing technique alternative embodiment of apatite ilmenite as shown in Figure 1, including three sections of breakers
Sequence S1001, first segment ball milling S1002 and cyclone S1003 are closed circuit, mix prefloat S1100, second segment ball milling S1005 and
Two sections of cyclone S1004 are closed circuit, low intensity magnetic separation S1006, high intensity magnetic separation S1007, de-magging rough floatation S1008, de-magging cleaner flotation S1009,
Titanium phosphorus separating flotation S1010, titanium ore dressing sub- technique S1200 and phosphorus flotation S1300；
Raw ore TiO2Content be 8.5%, P2O5Content be 2.3%, the grade of Fe is 13.5% and the content of MgO is
3.5%；Valuable mineral main component be ilmenite and apatite, gangue mineral be mainly pyroxene, mica, quartz, magnetic iron ore and
Martite, for raw ore after three sections of broken process S1001, granularity is that the crushed product of 0-12mm feeds first segment ball milling
First segment ball milling S1002 during S1002 and cyclone S1003 is closed circuit, product feeds cyclone after first segment ball milling S1002 ore grinding
The sand setting of S1003, cyclone S1003 return to first segment ball milling S1002 and form closed circuit, the granularity P of cyclone S100380For 60~
70 μm of overflow product feeds mixing prefloat S1100；
The concentrate of mixing prefloat S1100 feed second segment ball milling S1005 and second segment cyclone S1004 it is closed circuit in the
Two sections of cyclone S1004, the sand setting of second segment cyclone S1004 feed second segment ball milling S1005, second segment ball milling S1005 mill
Product after mine returns to second segment cyclone S1004 and forms closed circuit, the P of second segment cyclone S100480For 30~40 μm of overflow
Low intensity magnetic separation S1006 is fed, the magnetic field strength of low intensity magnetic separation S1006 is 2000GS；
The concentrate of low intensity magnetic separation S1006 feeds high intensity magnetic separation S1007, and the magnetic field strength of high intensity magnetic separation S1007 is 8000GS, high intensity magnetic separation
The concentrate yield of S1007 is 53.35%, TiO2Content is 14.42%, P2O5Content be 3.77%, the content of Fe is
12.2%, the content of MgO is 5.59%, TiO2The rate of recovery be 90.51%, P2O5The rate of recovery be 87.53%, the Fe rate of recovery
It is 85.22% for the 48.21% and MgO rate of recovery, the concentrate of high intensity magnetic separation S1007 feeds de-magging rough floatation S1008, de-magging rough floatation
It is 60g/t to mine and foaming agent 2# that PH regulator sulfuric acid 200g/t, which is added, to mine, ether amines collecting agent (flotigam3135) in S1008
For oily 15g/t to mine, the underflow concentrate of de-magging rough floatation S1008 feeds de-magging cleaner flotation S1009, adds in de-magging cleaner flotation S1009
Entering ether amines collecting agent (flotigam3135) is 30g/t to mine, the underflow concentrate yield of de-magging cleaner flotation S1009 is 43.02%,
TiO2Content is 17.36%, P2O5Content be 4.41%, the content of Fe is 14.57%, the content of MgO is 0.52%, TiO2
The rate of recovery be 87.85%, P2O5The rate of recovery be 82.5%, the Fe rate of recovery is 46.42% and the MgO rate of recovery is 6.4%, take off
The underflow concentrate of magnesium cleaner flotation S1009 feeds titanium phosphorus separating flotation S1010, and apatite is added in titanium phosphorus separating flotation S1010 and catches
Agent tall oil 150g/t is received to mine, ilmenite mineral inhibitor starch 100g/t to mine and foaming agent methoxyl group polypropylene glycol 20g/
t；
The concentrate yield of titanium phosphorus separating flotation S1010 is 36.71%, TiO2Content is 18.69%, P2O5Content be
0.61%, the content of Fe is 15.51%, the content of MgO is 0.48%, TiO2The rate of recovery be 80.7%, P2O5The rate of recovery be
7.7%, the Fe rate of recovery is 42.18% and the MgO rate of recovery is 5.77%；The concentrate of titanium phosphorus separating flotation S1010 feeds titanium ore dressing
The concentrate of sub- technique S1200, the sub- technique S1200 of titanium ore dressing are ilmenite concentrate, and the yield of ilmenite concentrate is 10.96%, TiO2Content is
45.0%, P2O5Content be 0.05%, the content of Fe is 22.6%, the content of MgO is 0.45%, TiO2The rate of recovery be
58.0%, P2O5The rate of recovery be 0.24%, the Fe rate of recovery is 18.34 and the MgO rate of recovery is 1.41%；
The tailing yield of titanium phosphorus separating flotation S1010 is 6.31%, TiO2Content is 9.63%, P2O5Content be
27.26%, the content of Fe is 9.08%, the content of MgO is 0.35%, TiO2The rate of recovery be 7.15%, P2O5The rate of recovery be
74.8%, the Fe rate of recovery is 4.24% and the MgO rate of recovery is 0.63%；The tailing of titanium phosphorus separating flotation S1010 feeds phosphorus flotation
The concentrate of S1300, phosphorus flotation S1300 are phosphorus concentrate, and the yield of phosphorus concentrate is 3.51%, TiO2Content is 0.7%, P2O5Contain
Amount is 38.0%, the content of Fe is 1.3%, the content of MgO is 0.4%, TiO2The rate of recovery be 0.29%, P2O5The rate of recovery
For 58%, the Fe rate of recovery be 0.34% and the MgO rate of recovery is 0.4%；
Mix the tailing of prefloat S1100, the tailing of low intensity magnetic separation S1006, the tailing of high intensity magnetic separation S1007, de-magging rough floatation
The tailing of S1008, the tailing of de-magging cleaner flotation S1009, the tailing of the sub- technique S1200 of titanium ore dressing and phosphorus flotation S1300 tailing
Technique tailing is collectively formed, the yield of technique tailing is 85.53%, TiO2Content is 4.15%, P2O5Content be 1.12%,
The content of Fe is 12.84%, the content of MgO is 4.02%, TiO2The rate of recovery be 41.71%, P2O5The rate of recovery be
41.76%, the Fe rate of recovery is 81.32% and the MgO rate of recovery is 98.19%, and technique tailing throws tail.
In the embodiment shown in fig. 1, using three sections of broken process, first segment ball milling and cyclone are closed circuit, it is pre- floating to mix
Choosing, second segment ball milling and second segment cyclone be closed circuit, low intensity magnetic separation, high intensity magnetic separation, de-magging rough floatation, de-magging cleaner flotation, titanium phosphorus separate
Flotation, titanium ore dressing sub- technique and phosphorus flotation process, by mix prefloat method, got rid of yield be 36.77% tail
While mine, TiO2Yield reached 93.2%, P2O5Yield reached 92.32%, in the yield for guaranteeing target minreal
Under the premise of got rid of a large amount of pyroxene, the gangue minerals such as quartz greatly reduce the treating capacity of subsequent job, reduce investment and
Operation cost reduces energy consumption.The particulate overflow high to the degree of dissociation of second segment ball milling ore grinding passes through first weak magnetic and removes magnetic magnet
Then mine and magnetic iron ore remove the martite of weak magnetic, magnetic concentrate Iron grade 12.2%, iron recovery by strong magnetic
48.21%, iron sulfur reduction effect highly significant is removed to mine relative to weak magnetic.It is removed by de-magging rough floatation and de-magging cleaner flotation and contains magnesium
Mica, the content of cleaner flotation concentrate MgO are that 0.52%, the MgO rate of recovery is 6.4%, magnesium removal effect highly significant.Using titanium phosphorus point
From flotation, apatite collecting agent tall oil 150g/t is added in flotation and is given to mine and ilmenite mineral inhibitor starch 100g/t
Mine effectively realizes the separation of titanium and phosphorus, is that subsequent titanium flotation and phosphorus flotation obtain qualified ilmenite concentrate and phosphorus concentrate and create
Advantageous condition, titanium phosphorus separating flotation, which also helps, further reduces equipment investment and energy consumption.Titanium phosphorus is separated later floating
Concentrate after choosing carries out the sub- process of titanium ore dressing, and obtaining yield is 10.96%, TiO2Content is 45.0%, P2O5Content
Content for 0.05%, Fe is 22.6%, the content of MgO is 0.45%, TiO2The rate of recovery be 58.0%, P2O5The rate of recovery
For the 0.24%, ilmenite concentrate that the Fe rate of recovery is 18.34 and the MgO rate of recovery is 1.41%.TiO2Grade and the rate of recovery it is all fine,
Content of magnesia is low, P2O5Content is low, and the index of ilmenite concentrate is very good, is high-quality ilmenite concentrate.To the tailing after titanium phosphorus separating flotation
Using the technique of phosphorus flotation, obtaining yield is 3.51%, TiO2Content is 0.7%, P2O5Content be that 38.0%, Fe contains
Amount is 1.3%, the content of MgO is 0.4%, TiO2The rate of recovery be 0.29%, P2O5The rate of recovery be 58%, the Fe rate of recovery is
The phosphorus concentrate that the 0.34% and MgO rate of recovery is 0.4%.P2O5Grade and the rate of recovery it is all fine, impurity content is lower, this part
The acquisition of phosphorus concentrate not only increases the comprehensive utilization ratio of resource, but also increases the economic benefit for selecting factory.
The mixing prefloat process of two product ore-dressing technique alternative embodiment of apatite ilmenite as shown in Figure 2, mixing
Prefloat S1100 includes mixing pre- rough floatation S1101, the pre- cleaner flotation S1102 of mixing and mixing three times to sweep flotation in advance, is mixed pre- floating
Selecting S1100 is reverse flotation；The overflow product of cyclone S1003 feeds the pre- rough floatation S1101 of mixing, mixes pre- rough floatation S1101
Be added 120g/t to mine ethylenediamine collecting agent and 20g/t to mine foaming agent methyl isobutyl carbinol；Mix pre- rough floatation
The underflow concentrate of S1101 feeds the pre- cleaner flotation S1102 of mixing, mixes pre- cleaner flotation S1102 addition 80g/t and catches to the ethylenediamine of mine
Agent and 15g/t are received to the foaming agent methyl isobutyl carbinol of mine, the concentrate yield for mixing pre- cleaner flotation S1102 is 63.23%,
TiO2Content is 12.53%, P2O5Content be 3.36%, the content of Fe is 19.07%, the content of MgO is 4.83%, TiO2
The rate of recovery be 93.20%, P2O5The rate of recovery be 92.32%, the Fe rate of recovery is 89.30% and the MgO rate of recovery is 87.20%；
The foam tailing for mixing pre- rough floatation S1101 feeds to mix for the first time sweeps flotation S1103 in advance, mixes sweep flotation in advance for the first time
S1103 be added 40g/t to mine ethylenediamine collecting agent and 10g/t to mine foaming agent methyl isobutyl carbinol, for the first time mix
The foam tailing for sweeping flotation S1103 in advance feeds second of mixing and sweeps flotation S1104 in advance, and second of mixing sweeps flotation S1104's in advance
Foam tailing feeds third time mixing and sweeps flotation S1105 in advance, and third time mixes the underflow concentrate return first for sweeping flotation S1105 in advance
Flotation S1103 is swept in secondary mixing in advance, is mixed the underflow concentrate for sweeping flotation S1103 in advance for the first time, is mixed for second and sweep flotation S1104 in advance
Underflow concentrate and mix the foam tailing of pre- cleaner flotation S1102 and return and mix pre- rough floatation S1101；Mix pre- cleaner flotation
The concentrate of S1102 is the concentrate for mixing prefloat S1100, and mixing sweep the tailing of flotation S1105 in advance for the third time is to mix in advance
The tailing of flotation S1100.
In the embodiment shown in Figure 2, mixing is swept in advance by the way of the concentrate of flotation returned using great-leap-forward, i.e., every grade sweep it is floating
The concentrate of choosing returns to top-ranking and sweeps flotation, and the ore pulp of every grade of this mode return increases the time that level-one sweeps flotation, has
The TiO that ensure that mixing prefloat concentrate of power2And P2O5High yield.
The sub- process flow of titanium ore dressing of two product ore-dressing technique alternative embodiment of apatite ilmenite as shown in Figure 3, institute
Stating the sub- technique S1200 of titanium ore dressing includes three sections of shaking tables；The concentrate of titanium phosphorus separating flotation S1010 feeds first segment shaking table S1201, the
The chats of one section of shaking table S1201 gravity treatment feeds second segment shaking table S1202 gravity treatment, and the chats of second segment shaking table S1202 gravity treatment is fed
Third section shaking table S1203 gravity treatment, the concentrate of three sections of table concentrations are ilmenite concentrate, and the tailing of three sections of table concentrations is titanium ore dressing
The tailing of technique S1200 is included into technique tailing and throws tail.
In the embodiment shown in fig. 3, table concentration is used in the sub- technique of titanium ore dressing, shaking table is adequately utilized to thin
The heavy metalliferous mineral of particle has the characteristics that preferable selectivity, and upgrading effect is obvious, obtains preferable ilmenite concentrate and refers to
Mark.
The phosphorus flotation flowsheet of two product ore-dressing technique alternative embodiment of apatite ilmenite as shown in Figure 4, the phosphorus are floating
Selecting S1300 includes that phosphorus rough floatation S1301, phosphorus sweep flotation S1302 and twice phosphorus cleaner flotation, and phosphorus flotation S1300 is direct flotation；Titanium phosphorus
The tailing of separating flotation S1010 feeds phosphorus rough floatation S1301, and apatite collecting agent tall oil 150g/ is added in phosphorus rough floatation S1301
T is to mine, gangue inhibitor waterglass 80g/t to mine and foaming agent methoxyl group polypropylene glycol 20g/t, the bubble of phosphorus rough floatation S1301
Foam concentrate feeds first time phosphorus cleaner flotation S1303, and collecting agent tall oil 90g/t is added to mine, arteries and veins in first time phosphorus cleaner flotation S1303
Stone inhibitor waterglass 50g/t is to mine and foaming agent methoxyl group polypropylene glycol 15g/t, the concentrate of first time phosphorus cleaner flotation S1303
Second of phosphorus cleaner flotation S1304 is fed, the underflow tailing of phosphorus rough floatation S1301 feeds phosphorus and sweeps flotation S1302, and phosphorus sweeps flotation
Foaming agent methoxyl group polypropylene glycol 10g/t is added in S1302, the underflow tailing of second of phosphorus cleaner flotation S1304 returns for the first time
It is thick that the froth concentrate that the underflow tailing and phosphorus of phosphorus cleaner flotation S1303, first time phosphorus cleaner flotation S1303 sweep flotation S1302 returns to phosphorus
The froth concentrate of flotation S1301, second of phosphorus cleaner flotation S1304 are the concentrate of phosphorus flotation S1300, i.e. phosphorus concentrate；Phosphorus sweeps flotation
The tailing of S1302 is the tailing of phosphorus flotation S1300, is included into technique tailing and throws tail.
Above-mentioned ' per ton to mine ' being previously mentioned refers to the ore weight for feeding this process, identical as '/t is to mine ' meaning.
Certainly, the present invention can also have other various embodiments, without deviating from the spirit and substance of the present invention, this
Field technical staff can make various corresponding changes and modifications according to the present invention, but these corresponding changes and modifications belong to
Scope of protection of the claims of the invention.
Claims (10)
1. a kind of two product ore-dressing technique of apatite ilmenite, including three sections of broken process, it is characterised in that: further include first segment
Ball milling and cyclone are closed circuit, mix prefloat, second segment ball milling and second segment cyclone are closed circuit, low intensity magnetic separation, high intensity magnetic separation, de-magging are thick
Flotation, de-magging cleaner flotation, titanium phosphorus separating flotation, the sub- technique of titanium ore dressing and phosphorus flotation；
Raw ore after three sections of broken process, granularity be 0-12mm crushed product feed first segment ball milling and cyclone it is closed circuit in
First segment ball milling, product feeds cyclone after first segment ball milling ore grinding, the sand setting of cyclone return first segment ball milling formed it is closed circuit,
The granularity P of cyclone80Mixing prefloat is fed for 60~70 μm of overflow product；
Mixing prefloat concentrate feed second segment ball milling and second segment cyclone it is closed circuit in second segment cyclone, second segment rotation
The sand setting of stream device feeds second segment ball milling, product after second segment ball milling ore grinding return second segment cyclone formed it is closed circuit, second
The P of section cyclone80Overflow for 30~40 μm feeds low intensity magnetic separation；
The concentrate of low intensity magnetic separation feeds high intensity magnetic separation, and the concentrate of high intensity magnetic separation feeds de-magging rough floatation, and the underflow concentrate of de-magging rough floatation is given
Enter de-magging cleaner flotation, the underflow concentrate of de-magging cleaner flotation feeds titanium phosphorus separating flotation；
The concentrate of titanium phosphorus separating flotation feeds the sub- technique of titanium ore dressing, and the concentrate of the sub- technique of titanium ore dressing is ilmenite concentrate；
The tailing of titanium phosphorus separating flotation feeds phosphorus flotation, and the concentrate of phosphorus flotation is phosphorus concentrate；
Mix the tailing of prefloat, the tailing of low intensity magnetic separation, the tailing of high intensity magnetic separation, the tailing of de-magging rough floatation, de-magging cleaner flotation
The tailing of tailing, the tailing of the sub- technique of titanium ore dressing and phosphorus flotation collectively forms technique tailing and throws tail.
2. two product ore-dressing technique of apatite ilmenite according to claim 1, it is characterised in that: the mixing prefloat
Flotation is swept in advance including mixing pre- rough floatation, the pre- cleaner flotation of mixing and mixing three times, and mixing prefloat is reverse flotation；Cyclone overflows
Miscarriage product feed the pre- rough floatation of mixing, and the underflow concentrate for mixing pre- rough floatation feeds the pre- cleaner flotation of mixing, mix pre- rough floatation
Foam tailing feeds to mix for the first time sweeps flotation in advance, and the foam tailing that flotation is swept in mixing in advance for the first time feeds second of mixing and sweeps in advance
Flotation, the foam tailing that flotation is swept in second of mixing in advance feed third time mixing and sweep flotation in advance, mix sweeps flotation in advance for the third time
Underflow concentrate return first time mixes sweeps flotation in advance, and the pre- underflow concentrate for sweeping flotation of mixing for the first time, second of mixing are swept floating in advance
The underflow concentrate of choosing and the foam tailing for mixing pre- cleaner flotation, which return, mixes pre- rough floatation；It is mixed for mixing the concentrate of pre- cleaner flotation
The concentrate of prefloat is closed, it is the tailing for mixing prefloat that third time, which mixes and sweeps the tailing of flotation in advance,.
3. two product ore-dressing technique of apatite ilmenite according to claim 1, it is characterised in that: the sub- work of titanium ore dressing
Skill includes three sections of shaking tables；The concentrate of titanium phosphorus separating flotation feeds first segment shaking table, and the chats of first segment table concentration feeds second
Section table concentration, the chats of second segment table concentration feed third section table concentration, and the concentrate of three sections of table concentrations is titanium choosing
The concentrate of the sub- technique of mine, the tailing of three sections of table concentrations are the tailing of the sub- technique of titanium ore dressing.
4. two product ore-dressing technique of apatite ilmenite according to claim 1, it is characterised in that: the phosphorus flotation includes
Phosphorus rough floatation, phosphorus sweep flotation and twice phosphorus cleaner flotation, and phosphorus flotation is direct flotation；The tailing of titanium phosphorus separating flotation feeds phosphorus and slightly floats
Choosing, the froth concentrate of phosphorus rough floatation feed first time phosphorus cleaner flotation, and it is floating that the concentrate of first time phosphorus cleaner flotation feeds second of phosphorus essence
Choosing, the underflow tailing of phosphorus rough floatation feed phosphorus and sweep flotation, and the underflow tailing of second of phosphorus cleaner flotation returns to first time phosphorus cleaner flotation,
The froth concentrate that the underflow tailing and phosphorus of first time phosphorus cleaner flotation sweep flotation returns to phosphorus rough floatation, the foam of second of phosphorus cleaner flotation
Concentrate is the concentrate of phosphorus flotation, phosphorus sweep flotation tailing be phosphorus flotation tailing.
5. two product ore-dressing technique of apatite ilmenite according to claim 1, it is characterised in that: the magnetic of the low intensity magnetic separation
Field intensity is 1800-2200GS, and the magnetic field strength of high intensity magnetic separation is 7200-8800GS.
6. two product ore-dressing technique of apatite ilmenite according to claim 2, it is characterised in that: the mixing is pre- thick floating
Choose the methyl isobutyl carbinol of the ethylenediamine and 18-22g per ton that 108-132g is added to mine；It is every in the pre- cleaner flotation of mixing
The ethylenediamine of 72-88g and the methyl isobutyl carbinol of 13-16g are added to mine for ton；The first time mixing is swept per ton in flotation in advance
The ethylenediamine of 36-45g and the methyl isobutyl carbinol of 9-11g are added to mine.
7. two product ore-dressing technique of apatite ilmenite according to claim 1, it is characterised in that: the de-magging rough floatation
In it is per ton give mine be added sulfuric acid 180-220g, ether amines 55-66g and 2# oil 13-16g；It is per ton in the de-magging cleaner flotation to add to mine
Enter ether amines 27-33g.
8. two product ore-dressing technique of apatite ilmenite according to claim 1, it is characterised in that: the titanium phosphorus separation is floating
It chooses per ton to mine addition tall oil 135-165g, starch 90-110g and methoxyl group polypropylene glycol 18-22g.
9. two product ore-dressing technique of apatite ilmenite according to claim 4, it is characterised in that: in the phosphorus rough floatation
It is per ton that tall oil 135-165g, waterglass 72-88g and methoxyl group polypropylene glycol 18-22g/t is added to mine；First time phosphorus essence is floating
Choose it is per ton tall oil 81-99g, waterglass 45-55g and methoxyl group polypropylene glycol 13-16g is added to mine, phosphorus is swept every in flotation
Methoxyl group polypropylene glycol 9-11g is added to mine in ton.
10. two product ore-dressing technique of apatite ilmenite described in one of -9 according to claim 1, it is characterised in that: the original
The valuable mineral main component of mine is ilmenite and apatite, and the gangue mineral of raw ore is mainly pyroxene, mica, quartz, magnet
Mine and martite；TiO2Content be 8.5%, P2O5Content be 2.3%, the grade of iron is 13.5% and the content of MgO
After the 3.5% raw ore processing of the two product ore-dressing technique of apatite ilmenite described in one of claim 1-9, TiO is obtained2
Content is 45.0%, P2O5Content be 0.05%, the content of Fe is 22.6%, the content of MgO is 0.45%, TiO2Recycling
Rate is 58.0%, P2O5The rate of recovery be 0.24%, the ilmenite concentrate that the Fe rate of recovery is 18.34% and the MgO rate of recovery is 1.41%,
And obtain TiO2Content is 0.7%, P2O5Content be 38.0%, the content of Fe is 1.3%, the content of MgO is 0.4%,
TiO2The rate of recovery be 0.29%, P2O5The rate of recovery be 58%, the phosphorus that the Fe rate of recovery is 0.34% and the MgO rate of recovery is 0.4%
Concentrate.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113117882A (en) * | 2019-12-30 | 2021-07-16 | 有研资源环境技术研究院(北京)有限公司 | Pre-flotation method for low-grade phosphorite in high sesquioxide |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101564707A (en) * | 2009-05-15 | 2009-10-28 | 四川安宁铁钛股份有限公司 | Vanadium titano-magnetite screen method |
| CN101575677A (en) * | 2003-08-01 | 2009-11-11 | 攀枝花金钛高科技有限责任公司 | Method for producing titanium-rich materials and steel products through titanium mine |
| US20100000913A1 (en) * | 2008-07-02 | 2010-01-07 | Georgia-Pacific Chemicals Llc | Collectors |
| CN104826741A (en) * | 2015-05-08 | 2015-08-12 | 中蓝连海设计研究院 | Flotation and backwater method aiming at collophanite double-back flotation process |
| CN108927293A (en) * | 2017-05-24 | 2018-12-04 | 中蓝连海设计研究院 | A kind of olive pyroxenite type ilmenite stepped-flotation separation method |
-
2019
- 2019-03-29 CN CN201910246340.5A patent/CN109954579B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575677A (en) * | 2003-08-01 | 2009-11-11 | 攀枝花金钛高科技有限责任公司 | Method for producing titanium-rich materials and steel products through titanium mine |
| US20100000913A1 (en) * | 2008-07-02 | 2010-01-07 | Georgia-Pacific Chemicals Llc | Collectors |
| CN101564707A (en) * | 2009-05-15 | 2009-10-28 | 四川安宁铁钛股份有限公司 | Vanadium titano-magnetite screen method |
| CN104826741A (en) * | 2015-05-08 | 2015-08-12 | 中蓝连海设计研究院 | Flotation and backwater method aiming at collophanite double-back flotation process |
| CN108927293A (en) * | 2017-05-24 | 2018-12-04 | 中蓝连海设计研究院 | A kind of olive pyroxenite type ilmenite stepped-flotation separation method |
Non-Patent Citations (2)
| Title |
|---|
| 王怀等: "某含磷钛低品位磁铁矿石的选矿试验研究", 《矿山机械》 * |
| 霍松洋等: "承德某铁尾矿回收磷、钛的试验研究", 《冶金冶炼与化工》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113117882A (en) * | 2019-12-30 | 2021-07-16 | 有研资源环境技术研究院(北京)有限公司 | Pre-flotation method for low-grade phosphorite in high sesquioxide |
| CN113117882B (en) * | 2019-12-30 | 2022-11-04 | 有研资源环境技术研究院(北京)有限公司 | Pre-flotation method for low-grade phosphorite in high sesquioxide |
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