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CN107735460B - 基于n-烷基葡糖胺的通用颜料分散体 - Google Patents

基于n-烷基葡糖胺的通用颜料分散体 Download PDF

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CN107735460B
CN107735460B CN201680031132.8A CN201680031132A CN107735460B CN 107735460 B CN107735460 B CN 107735460B CN 201680031132 A CN201680031132 A CN 201680031132A CN 107735460 B CN107735460 B CN 107735460B
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R·库普费尔
C·泽芬
J·鲁格
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Abstract

本发明涉及水性不含粘结剂的颜料分散体，其包含(A)至少一种有机和/或无机颜料，(B)一种或多种分散剂和/或表面活性剂，(C)至少一种式(I)的基础物质，其中，R1为表示H，C1‑C4‑烷基，CH2CH2OH或CH2CH(CH3)OH，(D)任选的一种或多种聚亚烷基二醇，(E)任选的另外的用于制备水性颜料分散体的常规添加剂，和(F)水。

Description

基于N-烷基葡糖胺的通用颜料分散体
本发明提供了基于水的不含粘结剂的颜料分散体及其用于使所有类型的水性和溶剂型油漆、乳胶漆和光泽油漆着色的用途。
在市场上和文献中，有许多已知的水性颜料分散体，也被称为颜料糊剂，其用于使水性乳胶漆和清漆着色。这些颜料分散体在五金商店、油漆厂和专业艺术商店中用作调色糊剂。出于该目的，借助于计量添加和调色体系，将水性颜料糊剂添加到水性油漆和清漆中。为了改进与基础油漆的相容性，通常将颜料分散体用碱调节至碱性pH。出于该目的，本领域技术人员充分了解使用碱例如NaOH或KOH或胺碱，例如链烷醇胺如2-氨基-2-甲基丙-1-醇(AMP-90/95，来自Angus)，且这连同在α位置中支化的仲链烷醇胺例如描述于US2012/0024193中。
European Coatings Journal在2009年第07卷第26至28页中也教导了包含作为中和剂的这种仲链烷醇胺和共分散剂的蓝色颜料糊剂产生较高的颜色强度，并且使用2-(仲丁基氨基)乙醇( N41,来自Arkema)的实例指出，这可以降低调整色光油漆的成本。
以这种方式也可能用于使油漆和清漆着色。出于此目的，市场上可获得特定的基于溶剂的糊剂。此外，越来越多使用通用颜料分散体，该通用颜料分散体适用于使所有类型的水性和溶剂型油漆、乳胶漆和光泽油漆着色。
WO2013/016270教导了不含VOC的仲和叔链烷醇胺，其用于含粘结剂的油漆中并导致光泽和湿磨损方面的改进。
在US2011/0146536中教导了另外的不含VOC的氨基醇的制备及其在含粘结剂的油漆中作为中和剂的用途。
WO2010/126657和US2010/0326320中教导了三羟基单胺或三羟基二胺在水性含粘结剂的油漆中的中和能力。同样地，就粘度、覆面力、变黄、光泽度、耐湿磨损性和粘合力方面描述所得油漆和涂料的性质。
EP 1676831教导了可用于水性含粘结剂的印刷油墨的N,N-二烷基葡糖胺。
US 2002/04066教导了包含烷基-、羟烷基-或芳基胺的水性不含分散剂的印刷油墨。
在实践中发现，这些通用颜料分散体在溶剂型油漆和清漆中仅具有不足的相容性，其表现在所使用的水性颜料分散体不显示其全色强度或覆面力，因此必须添加更多的颜料分散体以达到所需的色相。这种额外的消耗导致在油漆和清漆着色方面更高的成本。此外，所述的胺碱有助于增加VOC含量。
因此，本发明的目的是提供与水性涂料和与溶剂型涂料均相容的水性不含粘结剂的颜料分散体。此外，不应将含有VOC的成分添加到颜料分散体中。
已经发现，上述目的出人意料地通过使用N-烷基葡糖胺用于pH调节和作为共分散剂的水性不含粘结剂的颜料分散体来实现。
本发明提供了水性颜料分散体，其包含
(A)至少一种有机和/或无机颜料，
(B)一种或多种分散剂和/或表面活性剂，
(C)至少一种式(I)的化合物
其中，R1为H，C1-C4-烷基，CH2CH2OH或CH2CH(CH3)OH，
(D)任选的一种或多种聚亚烷基二醇，
(E)任选的常规用于制备水性颜料分散体的另外的添加剂，和
(F)水。
优选的颜料制剂包含以下量的组分：
(A)5重量％至80重量％，
(B)0.1重量％至30重量％，
(C)0.1重量％至10重量％，
(D)0重量％至10重量％，
(E)0重量％至30重量％，
(F)加和至(ad)100％，
在每种情况下基于颜料分散体的总重量。
在进一步优选形式中，本发明的颜料分散体具有>7的pH，在特别优选的形式中在8和10之间的pH。
在进一步优选形式中，本发明的颜料分散体具有<1％的VOC含量，根据DIN11890-2进行测定。
本发明的颜料分散体的组分(A)优选为细分的有机或无机白色或彩色颜料或这类的各种颜料的混合物。作为特别优选的有机颜料的示例性选择，本文应该提及单偶氮和双偶氮颜料，特别是颜色指数颜料颜料黄1，颜料黄3，颜料黄12，颜料黄13，颜料黄14，颜料黄16，颜料黄17，颜料黄73，颜料黄74，颜料黄81，颜料黄83，颜料黄87，颜料黄97，颜料黄111，颜料黄126，颜料黄127，颜料黄128，颜料黄155，颜料黄174，颜料黄176，颜料黄191，颜料黄213，颜料黄214，颜料红38，颜料红144，颜料红214，颜料红242，颜料红262，颜料红266，颜料红269，颜料红274，颜料橙13，颜料橙34或颜料棕41；β-萘酚和萘酚AS颜料，尤其是颜色指数颜料颜料红2，颜料红3，颜料红4，颜料红5，颜料红9，颜料红12，颜料红14，颜料红53:1，颜料红112，颜料红146，颜料红147，颜料红170，颜料红184，颜料红187，颜料红188，颜料红210，颜料红247，颜料红253，颜料红254，颜料红256，颜料橙5，颜料橙38或颜料棕1；色淀偶氮和金属络合物颜料，尤其是颜色指数颜料颜料红48:2，颜料红48:3，颜料红48:4，颜料红57:1，颜料红257，颜料橙68或颜料橙70；苯并咪唑啉颜料，尤其是颜色指数颜料颜料黄120，颜料黄151，颜料黄154，颜料黄175，颜料黄180，颜料黄181，颜料黄194，颜料红175，颜料红176，颜料红185，颜料红208，颜料紫32，颜料橙36，颜料橙62，颜料橙72或颜料棕25；异吲哚啉酮和异吲哚啉颜料，特别是颜色指数颜料颜料黄139或颜料黄173；酞菁颜料，特别是颜色指数颜料颜料蓝15，颜料蓝15:1，颜料蓝15:2，颜料蓝15:3，颜料蓝15:4，颜料蓝15:6，颜料蓝16，颜料绿7或颜料绿36；蒽嵌蒽醌，蒽醌，喹吖啶酮，二噁嗪，靛蒽醌，苝，紫环酮和硫靛蓝颜料，特别是颜色指数颜料颜料黄196，颜料红122，颜料红149，颜料红168，颜料红177，颜料红179，颜料红181，颜料红207，颜料红209，颜料红263，颜料蓝60，颜料紫19，颜料紫23或颜料橙43；三芳基碳鎓颜料，特别是颜色指数颜料颜料红169，颜料蓝56或颜料蓝61。
合适的无机颜料是例如炭黑颜料，例如气黑或炉黑；二氧化钛，硫化锌，氧化锌，氧化铁，磁铁矿，锰铁氧化物，铬氧化物，群青，镍锑钛氧化物或铬锑钛氧化物，锰钛金红石，钴氧化物，钴和铝的混合氧化物，金红石混合相颜料，稀土的硫化物，钴与镍和锌的尖晶石，基于铁和铬与铜、锌和锰的尖晶石，钒酸铋和体质颜料。更特别地，使用颜色指数颜料颜料黄184，颜料黄53，颜料黄42，颜料黄棕24，颜料红101，颜料蓝28，颜料蓝36，颜料绿50，颜料绿17，颜料黑7，颜料黑11，颜料黑33和颜料白6。优选地，还经常使用无机颜料的混合物。有机与无机颜料的混合物同样经常使用。
本发明的颜料分散体的合适组分(B)是常规聚合物和表面活性剂型分散剂或这些物质的混合物。典型地，这些是本领域技术人员已知的非离子、阴离子或两性界面活性物质。在众多已知化合物中，在下文引用代表性选择，但不限制本发明的适用性。
作为特别优选的聚合物分散剂的示例性选择，本文应提及甲醛与具有1至20个碳原子的取代和未取代的长链和短链烷基酚的缩合产物及其烷氧基化产物，酚醛清漆和衍生物；苯乙烯-苯酚缩合物，包括由取代酚和苯乙烯形成的缩合产物，及其烷氧基化产物。另外，这些缩合产物可以采用离子衍生物的形式，例如硫酸根，磺酸根，琥珀酸单酯，磷酸根，膦酸根或羧酸根及其盐。还应该提及部分或完全中和的丙烯酸酯树脂，改性的聚丙烯酸酯和丙烯酸和/或甲基丙烯酸和/或其酯和/或其酰胺的共聚物。用于相应共聚物的其它单体单元可为马来酸和/或其酯，酰胺和/或其酸酐和/或苯乙烯。聚合物分散剂通常具有1000至100000g/mol，优选2000至50000g/mol之间的Mn的平均摩尔质量，并且可采用无规或嵌段聚合物的形式。
作为特别优选的表面活性剂型分散剂的示例性选择，本文应提及直链和支链、饱和和不饱和的烷基磺酸盐，例如十二烷基磺酸盐，月桂基磺酸盐和十八烷基磺酸盐以及相应的烷基磷酸盐。另外，可能使用非支链或支链、直链或环状的C3-C20烷基或取代或未取代的芳基或直链脂肪醇、脂肪酸、脂肪胺或脂肪酰胺的烷氧基化产物。合适的氧化烯的实例是氧化乙烯，氧化丙烯，氧化丁烯或氧化苯乙烯。这些烷氧基化产物可另外地提供有离子头基，例如硫酸根，磺酸根，琥珀酸单酯，磷酸根，膦酸根或羧酸根及其盐。另外合适的是卵磷脂和磺基琥珀酸盐。
在组分(C)的上下文中的化合物(I)是多羟基胺
其中R1可为H，C1-C4-烷基，CH2CH2OH或CH2CH(CH3)OH。
优选地，R1为H，甲基或CH2CH2OH。
多羟基单元为己糖，优选差向异构体葡萄糖。
用于制备式(I)的烷基葡糖胺的方法对于本领域技术人员是已知的。对于R＝C1-C4-烷基的化合物，例如，其通过EP-A-1676831中所述的方法，通过在氢和过渡金属催化剂存在下用醛或酮对N-烷基多羟基胺进行还原性烷基化来进行。羟乙基-和羟丙基-N-甲基葡糖胺可以通过N-甲基葡糖胺与氧化乙烯或氧化丙烯在水溶液中反应来制备。式(I)的化合物可以以纯物质的形式或以水溶液的形式使用。由于叔胺如二甲基葡糖胺和羟乙基-和羟丙基-N-甲基葡糖胺不易于形成亚硝胺，因此这些对于本发明的分散体是优选的。
本发明的分散体的组分(D)聚亚烷基二醇是氧化烯的均聚物或共聚物。合适的氧化烯的实例是氧化乙烯，氧化丙烯，氧化丁烯或氧化苯乙烯。另外，可能使用从一元、二元、三元、四元或五元醇开始的聚亚烷基二醇或具有支链或星形结构的一、二、三、四或五官能胺。所使用的聚亚烷基二醇通常含有4至1000mol的氧化烯，优选4至200mol。
常规用于制备水性颜料分散体的另外的添加剂(组分(E))可为防腐剂/杀生物剂，消泡剂，脱气剂，填料，溶剂，光稳定剂，抗氧化剂或增稠剂，抗沉降剂和流变添加剂。另外的润湿剂可为例如基于聚硅氧烷醚的润湿剂。
用于制备本发明的水性颜料分散体(组分(F))的水优选以蒸馏水或软化水的形式使用。也可能使用饮用水(自来水)和/或天然来源的水。
本发明还进一步提供了用于制备本发明的颜料分散体的方法。出于此目的，将通常以粉末、薄片或粒状物形式的组分(A)以本身常规方式在水(F)和组分(B)和(C)以及任选的(D)和(E)的存在下进行分散。随后，任选可能地混入另外的水(F)中，从而将获得的水性颜料分散体调节到所需浓度。优选地，首先将液体组分(B)、(C)、(F)和任选的(D)混合并匀化，然后将粉末、粒状物或薄片形式的固体组分(A)和(D)搅拌至初始装入的混合物，其中将颜料和任选的填料转化成糊剂和将其初步分散体。根据所使用的颜料的颗粒硬度，任选地随后在冷却的同时借助研磨或分散单元进行细分散或细分布。出于此目的，可能使用搅拌器系统，溶解器(锯齿搅拌器)，转子-定子磨机，球磨机，搅拌球磨机如砂磨机和珠磨机，高速混合机，捏合设备，辊磨机或高性能珠磨机。使颜料的细分散或研磨进行到所需的粒度分布，并且可以在0至100℃的温度，适当地在10和70℃之间，优选20至60℃的温度进行。在细分散后，可以用水(F)进一步稀释颜料制剂。然而，本发明的颜料分散体的制备不限于该方法，因此也可以例如仅在研磨之后加入组分(C)。
本发明的颜料分散体适用于所有类型的大分子材料的颜料着色和着色。本发明的颜料分散体特别适用于颜料着色或制备水性和溶剂型无色和覆面乳胶漆和其它油漆，基于分散体的清漆，印刷油墨(例如纺织品印刷，柔版印刷，装饰印刷或凹版印刷油墨)，壁纸油墨；水性、水稀释性和溶剂型的无色和覆面清漆，木材着色剂，木材防腐体系，和例如由金属，木材，塑料，玻璃，陶瓷，混凝土，纺织材料，纸或橡胶制成的制品的表面涂层的清漆。
本发明的颜料分散体的特定性质是它们作为通用调色糊剂的用途。通用调色糊剂适合用于使水性油漆着色和用于使含溶剂的漆调色。如果将水性颜料制剂用于使含溶剂的漆着色，则颜料会凝聚并且凝聚的颜料在清漆中漂浮，且这在彩色颜料的情况下由颜色强度的损失或在白色颜料的情况下覆面能力的损失而显示出来。
实施例
颜料分散体的VOC含量是分散体中的在101.3kPa沸点低于250℃的各组分的总和。因此，为了配制不含VOC的颜料分散体，只应选择沸点高于250℃的那些成分。在使用市场上常规的胺(实施例1和2，表1)的情况下，取决于其使用浓度，这些对分散体的VOC含量贡献100％。式(I)的多羟基胺由于其高熔点和沸点而具有低VOC水平。
表1：中和剂的沸点
实施例 中和剂 沸点[℃]
1(C) 2-氨基-2-甲基丙-1-醇 165
2(C) 2-(仲丁基氨基)乙醇 186
3 式(I)的化合物，其中R＝H >>250(m.p.130℃)
4 式(I)的化合物，其中R＝CH<sub>3</sub> >>250(m.p.90℃)
颜料分散体的制备
将粉末、粒状物或滤饼形式的颜料与分散剂和其它添加剂一起在去离子水中转化为糊剂，然后均化，并用溶解器(例如来自VMA-Getzmann GmbH，AE3-M1型)或其它合适的装置，优选借助分散盘进行预分散。对于分散，首先将液体组分、包含组分(B)和(C)以及另外的组分(D)和(F)的分散剂浓缩物装入研磨容器中并混合。随后，添加粉状组分(A)和任选的(E)并用溶解器预分散。随后的细分散借助于珠磨机(例如来自VMA-Getzmann的AE3-M1)或者另一种合适的分散单元来进行，所述研磨用尺寸d＝1.3-1.7mm的混合氧化锆珠利用冷却进行。随后，将研磨体移除并且将颜料制剂分离。
实施例5(对比例)：
65.5份 C.I.颜料红101( Red 130，来自Lanxess，组分(A))，
10.0份阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
1.1份 氢氧化钠溶液(10％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.9份 水(组分(F))
实施例6(对比例)：
65.5份 C.I.颜料红101( Red 130，来自Lanxess，组分(A))，10.0份阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
0.3份 2-氨基-2-甲基丙-1-醇(95％水溶液，AMP-95，来自Angus，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.7份 水(组分(F))
实施例7(对比例):
65.5份 C.I.颜料红101( Red 130，来自Lanxess，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
0.4份 2-(仲丁基氨基)乙醇(( N41，来自Arkema)，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.6份 水(组分(F))
实施例8：
65.5份 C.I.颜料红101( Red 130，来自Lanxess，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN200，来自Clariant，组分(B))，
1.5份 式(I)的化合物，其中R＝H(30％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.5份 水(组分(F))
实施例9：
65.5份 C.I.颜料红101( Red 130，来自Lanxess，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
1.3份 式(I)的化合物，其中R＝CH3(50％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.7份 水(组分(F))
实施例10(对比例)：
65.5份 C.I.颜料黄184( Gelb L 1100，来自BASF，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
1.0份 氢氧化钠溶液(10％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.0份 水(组分(F))
实施例11(对比例):
65.5份 C.I.颜料黄184( Gelb L 1100，来自BASF，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
0.2份 2-氨基-2-甲基丙-1-醇(95％水溶液，AMP-95，来自Angus，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.8份 水(组分(F))
实施例12(对比例):
65.5份 C.I.颜料黄184( Gelb L 1100，来自BASF，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN200，来自Clariant，组分(B))，
0.2份 2-(仲丁基氨基)乙醇(( N41，来自Arkema)，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.8份 水(组分(F))
实施例13：
65.5份 C.I.颜料黄184( Gelb L 1100，来自BASF，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN200，来自Clariant，组分(B))，
1.4份 式(I)的化合物，其中R＝H(30％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.6份 水(组分(F))
实施例14：
65.5份 C.I.颜料黄184( Gelb L 1100，来自BASF，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物(Dispersogen 200，来自Clariant，组分(B))，
1.4份 式(I)的化合物，其中R＝CH3(50％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.6份 水(组分(F))
为了表征分散体，首先将它们在60℃老化7天；所有的糊剂在这个时期都是稳定的。此外，将颜料分散体的粘度在Haake VT 550流变仪中以1/60s的剪切速率和23℃的温度进行测定。结果列于表3中，且具有颜料典型的粘度。
为了测定基于各种基础涂料的颜料分散体的相容性，将2重量％的分散体搅拌到油漆和清漆AD(表2)中，并以200μm的涂层刮涂到对比卡上，并测定颜色强度。颜色强度结果列于表3中，并且对于本发明的式(I)的多羟基胺，对于红色(实施例8和9)和对于黄色(实施例13和14)都具有最高的颜色强度。包含2-(仲丁基氨基)乙醇的糊剂(对比例7和12)与溶剂型涂料不相容，并导致在使用中的絮凝，因此不适于比色测定。
表2：用于测试相容性的涂料
除非另有说明，份或百分比数字是重量份或重量百分数。
表3：实施例5-14的结果
对于白色颜料，在透明漆的情况下，颜色强度的测定是不合适的。在这里更适合的是测定覆面能力，作为颜料在油漆膜中的细分布的证据；完全不相容导致颜料包封，并且油漆膜显得透明(没有或几乎没有任何覆面能力)。出于此目的，接着用白色颜料制备颜料分散体(实施例11-15)，然后测定其覆面能力。出于此目的，将无色基础油漆与10重量％的钛分散体混合，并将400μm的油漆膜刮涂在黑色/白色对比卡上。干燥后，测定白色和黑色区域之间的对比度。
实施例15(对比例)：
65.5份 C.I.颜料白6(2160，来自Kronos，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
0.3份 2-氨基-2-甲基丙-1-醇(95％水溶液，AMP-95，来自Angus，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.7份 水(组分(F))
实施例16(对比例)：
65.5份 C.I.颜料白6(2160，来自Kronos，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN200，来自Clariant，组分(B))，
0.8份 2-(仲丁基氨基)乙醇(( N41，来自Arkema)，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
17.2份 水(组分(F))
实施例17：
65.5份 C.I.颜料白6(2160，来自Kronos，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
1.5份 式(I)的化合物，其中R＝H(30％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.5份 水(组分(F))
实施例18：
65.5份 C.I.颜料白6(2160，来自Kronos，组分(A))，
10.0份 阴离子型和非离子型分散剂的混合物( AN 200，来自Clariant，组分(B))，
1.3份 式(I)的化合物，其中R＝CH3(50％水溶液，组分(C))，
6.0份 分子量为300g/mol的甘油乙氧基化物(Polyglykol G 300，来自Clariant，组分(D))，
0.3份 消泡剂(Byk-018，来自Byk，组分(E))，
0.2份 防腐剂(Acticide MBS，来自Thor，组分(E))，
16.7份 水(组分(F))
覆面能力测定的结果列于表4中。包含式(I)的多羟基胺的颜料分散体通常适用于在水性和溶剂型涂料中产生覆面能力。
式(I)的多羟基胺适合用作水性颜料分散体的中和剂，而不会对VOC含量有贡献。该糊剂适用于均使水性和溶剂型油漆、清漆和涂料着色，因为式(I)的多羟基胺确保了高的颜色接受性，并起到溶剂型和水性体系之间的介质的作用。
表4：实施例15-18的结果

Claims (14)

1.水性不含粘结剂的颜料分散体，其包含
(A)至少一种有机和/或无机颜料，
(B)一种或多种分散剂和/或表面活性剂，
(C)至少一种式(I)的化合物
其中，R1表示H，C1-C4-烷基，CH2CH2OH或CH2CH(CH3)OH，和
(F)水。
2.根据权利要求1所述的水性不含粘结剂的颜料分散体，其中R1表示甲基或CH2CH2OH。
3.根据权利要求1所述的水性不含粘结剂的颜料分散体，其中R1表示甲基。
4.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其特征在于，所述无机颜料为金属氧化物颜料。
5.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其特征在于，所述颜料分散体的pH值大于7。
6.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其特征在于，所述颜料分散体的pH值在8和10之间。
7.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其包含5重量％至80重量％的组分(A)，基于所述颜料分散体的总重量计。
8.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其包含0.1重量％至30重量％的组分(B)，基于所述颜料分散体的总重量计。
9.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其包含0.1重量％至10重量％的组分(C)，基于所述颜料分散体的总重量计。
10.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其包含0.1重量％至10重量％的量的一种或多种聚亚烷基二醇作为组分(D)，基于所述颜料分散体的总重量计。
11.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其包含0重量％至30重量％的量的另外的用于制备水性颜料分散体的常规添加剂作为组分(E)，基于所述颜料分散体的总重量计。
12.根据权利要求1-3中任一项所述的水性不含粘结剂的颜料分散体，其中其VOC含量根据DIN11890-2测定为小于0.2％。
13.根据权利要求1-12中任一项所述的水性不含粘结剂的颜料分散体的用途，用于使水性、水稀释性和含溶剂的漆和油墨着色。
14.根据权利要求1-12中任一项所述的水性不含粘结剂的颜料分散体的用途，用于使水性、水稀释性和含溶剂的油漆着色。
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