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CN107708296A - A kind of metal-based circuit board of high heat conduction and preparation method thereof - Google Patents

A kind of metal-based circuit board of high heat conduction and preparation method thereof Download PDF

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Publication number
CN107708296A
CN107708296A CN201710979512.0A CN201710979512A CN107708296A CN 107708296 A CN107708296 A CN 107708296A CN 201710979512 A CN201710979512 A CN 201710979512A CN 107708296 A CN107708296 A CN 107708296A
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CN
China
Prior art keywords
layer
metal
copper
circuit board
heat conduction
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Pending
Application number
CN201710979512.0A
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Chinese (zh)
Inventor
王红英
李志军
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Shenzhen Polytechnic
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Shenzhen Polytechnic
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Priority to CN201710979512.0A priority Critical patent/CN107708296A/en
Publication of CN107708296A publication Critical patent/CN107708296A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/05Insulated conductive substrates, e.g. insulated metal substrate
    • H05K1/053Insulated conductive substrates, e.g. insulated metal substrate the metal substrate being covered by an inorganic insulating layer
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/0201Thermal arrangements, e.g. for cooling, heating or preventing overheating
    • H05K1/0203Cooling of mounted components
    • H05K1/0209External configuration of printed circuit board adapted for heat dissipation, e.g. lay-out of conductors, coatings
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/44Manufacturing insulated metal core circuits or other insulated electrically conductive core circuits
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K2201/00Indexing scheme relating to printed circuits covered by H05K1/00
    • H05K2201/06Thermal details

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Insulated Metal Substrates For Printed Circuits (AREA)

Abstract

The invention discloses a kind of metal-based circuit board of high heat conduction and preparation method thereof.The metal-based circuit board includes metal substrate, nitridation aluminum insulation layer, conductive metal layer.Nitridation aluminum insulation layer is arranged on the upper surface of metal substrate.Conductive metal layer is arranged on the upper surface of nitridation aluminum insulation layer.The metal-based circuit board is used as insulating barrier using aluminium nitride film, can greatly improve the heat conductivility of circuit board, while the breakdown voltage that guarantee is higher, is greatly improved the service life and reliability of electronic component.

Description

A kind of metal-based circuit board of high heat conduction and preparation method thereof
Technical field
The present invention relates to printed-board technology field, more particularly to a kind of metal-based circuit board of high heat conduction and its making Method.
Background technology
With the rapid development of modern electronics industry, the volume of electronic product is less and less, and power density is increasing, dissipates Heat turns into the key factor for determining electronic product service life.Printed circuit board (PCB) (PCB) needed for electronic component surface mount Mechanically supported and electronic component is secured, while assume responsibility for the effect of heat dissipation channel.So PCB heat conductivility to close weight Will.
With the semiconductor power devices such as rectification and inverter circuit and the integrated miniaturization of module, and it is high-power LED generally use, current density also carry out bigger, cooling requirements also more and more higher.Traditional glass class printed circuit board (PCB), such as FR4 plates, can not meet the needs of radiating.Therefore, metal base printed circuit board is due to good heat dispersion acquisition Quick application, it is made up of the three-decker of uniqueness, i.e. circuit layer, insulating barrier and metal-based layer.Power component table Face is mounted on circuit layer, and caused heat is transmitted to metal-based layer by insulating barrier when device is run, then by Metal Substrate Layer transfers heat away from, so as to realize the radiating to device.
However, even if radiating preferable metal substrate at present, its insulating barrier main component is still epoxy resin, is simply added Ceramic powders have been added to increase its heat dispersion, its thermal conductivity factor is generally less than 2W/m.K, for the application environment of high power density For, be still radiating bottleneck.In addition, with the development of semiconductor devices, high pressure applications (several kilovolts) also come it is also more, Common aluminium base is pressure-resistant only several hectovolts, it is pressure-resistant in order to improve its, can only increase thickness of insulating layer, but so caused by directly Consequence is exactly pcb board heat conductivility is deteriorated.
The content of the invention
In view of the shortcomings of the prior art, the present invention proposes a kind of metal-based circuit board of high heat conduction and preparation method thereof, The metal-based circuit board, as insulating barrier, can greatly improve the heat conductivility of circuit board, while ensure higher using AlN films Breakdown voltage, overcome existing metal-base circuit plate insulating layer in terms of the radiating and insulation on contradiction.
To achieve these goals, technical solution of the present invention is as follows:
A kind of metal-based circuit board of high heat conduction, including metal substrate, nitridation aluminum insulation layer, conductive metal layer.Aluminium nitride Insulating barrier is arranged on the upper surface of metal substrate.Conductive metal layer is arranged on the upper surface of nitridation aluminum insulation layer.
Further, nitridation aluminum insulation layer is sprayed on the upper surface of conductive metal layer.Nitrogenize the thickness range of aluminum insulation layer For 0.2-3mm.
Further, conductive metal layer includes conductive layer, and the seed metal layer for electroplated conductive layer.Seed metal layer It is arranged on nitridation aluminum insulation layer.Conductive layer is arranged in seed metal layer.
Further, the bottom surface of metal substrate is provided with radiating fin or the flank of tooth.
Further, metal substrate is aluminium base or copper base.
Further, conductive metal layer is copper conductive layer or copper silver conductive layer.
Further, seed metal layer includes titanium layer, the first layers of copper;First layers of copper is arranged on titanium layer.Conductive layer includes Nickel dam, the second layers of copper;Nickel dam is arranged in the first layers of copper;Second layers of copper is arranged on nickel dam.
A kind of metal-base circuit board manufacturing method of high heat conduction, comprises the following steps:
Step 1:Metallic substrate surfaces are pre-processed;
Step 2:Using nanometer powder plasma spraying method, it is exhausted to spray aluminium nitride to pretreated metallic substrate surfaces Edge layer;
Step 3:Conductive metal layer is printed in aluminium nitride surface of insulating layer, is then sintered.
A kind of metal-base circuit board manufacturing method of high heat conduction, comprises the following steps:
Step 1:Metal substrate is subjected to surface clean, the blasting treatment of fine grain is then carried out, removes oxide-film and table Face pollutant;
Step 2:Using nanometer powder plasma spraying method, to the metallic substrate surfaces spraying aluminium nitride insulation after processing Layer;Then the aluminium nitride surface of insulating layer after spraying is carried out polishing processing using precision grinder;
Step 3:Titanium layer and first is formed on the aluminium nitride surface of insulating layer after polishing and cleaning with magnetron sputtering technique Layers of copper;With photolithographicallpatterned in the first layers of copper circuit forming surface pattern;Nickel dam is formed on the first layers of copper surface using electro-plating method With the second layers of copper;Photoresist and titanium layer and the first layers of copper are removed.
A kind of metal-base circuit board manufacturing method of high heat conduction, comprises the following steps:
Step 1:Metal substrate is subjected to surface clean, the blasting treatment of fine grain is then carried out, removes oxide-film and table Face pollutant;
Step 2:Using nanometer powder plasma spraying method, to the metallic substrate surfaces spraying aluminium nitride insulation after processing Layer;
Step 3:Layer of metal slurry is uniformly painted in aluminium nitride surface of insulating layer, is then sintered.
Beneficial effects of the present invention:
(1) metal-based circuit board can greatly improve the heat conductivility of circuit board using aluminium nitride film as insulating barrier, Ensure higher breakdown voltage simultaneously, be greatly improved the service life and reliability of electronic component.
(2) the metal-base circuit board manufacturing method can be realized directly on semi-conductor power module or LED radiator Circuit production, so as to save the circuit substrate among device and radiator, greatly improve under high power density application occasion Radiating effect.
Brief description of the drawings
Fig. 1 is first embodiment of the invention cross-sectional view.
Fig. 2 is second embodiment of the invention cross-sectional view.
Fig. 3 is third embodiment of the invention cross-sectional view.
Fig. 4 is fourth embodiment of the invention cross-sectional view.
Wherein, Fig. 1 to Fig. 4 reference is:Metal substrate 1, nitridation aluminum insulation layer 2, conductive metal layer 3;Titanium layer 31, First layers of copper 32, nickel dam 33, the second layers of copper 34.
Embodiment
With reference to the accompanying drawings and examples, the present invention is expanded on further.
Embodiment one:
As shown in figure 1, a kind of metal-based circuit board of high heat conduction, including metal substrate 1, it is arranged on the upper table of metal substrate 1 The nitridation aluminum insulation layer 2 in face, and it is arranged on the conductive metal layer 3 of nitridation aluminum insulation layer 2 upper surface.
Conductive metal layer 3 is formed by the circuit pattern being pre-designed.It is preferred that the thickness of nitridation aluminum insulation layer 2 is 0.2- 3mm。
It is preferred that metal substrate 1 is aluminium base or copper base.Metal substrate 1 or by other any high thermal conductivity coefficient low-resistances Anti- metal or the alloy powder of nonmetallic materials are made.
It is preferred that conductive metal layer 3 is copper conductive layer or copper silver conductive layer.
Aluminium nitride (AlN) is a kind of ceramic insulating material, and its dielectric strength is very high, can reach 20KV/mm;And its heat conduction Performance is also very good, and common AlN thermal conductivity factor can reach 20W/m.K, and the thermal conductivity factor of good AlN materials can reach More than 150W/m.K.
The processing method of the metal-based circuit board of the present embodiment is:
The first step, metallic substrate surfaces are pre-processed:Metal substrate 1 is subjected to surface clean, then carries out particulate The blasting treatment in footpath, removes oxide-film and surface contaminant;
Second step, using nanometer powder plasma spraying method, to 1 surface spraying of metal substrate, one layer of nitridation after processing Aluminum insulation layer 2;Then surface after spraying is carried out to polish processing using precision grinder;
3rd step, according to default circuit pattern, the surface of nitridation aluminum insulation layer 2 after polishing and cleaning is multiple with copper silver Condensation material prints one layer of conductive metal layer 3, then sinters, so as to form the Metal Substrate electricity of the high heat conduction with required circuit pattern Road plate.
Embodiment two:
As shown in Fig. 2 a kind of metal-based circuit board of high heat conduction, including metal substrate 1, it is arranged on the upper table of metal substrate 1 The nitridation aluminum insulation layer 2 in face, and it is arranged on the conductive metal layer 3 of nitridation aluminum insulation layer 2 upper surface.
Conductive metal layer 3 is formed by the circuit pattern being pre-designed.It is preferred that the thickness of nitridation aluminum insulation layer 2 is 0.2- 3mm。
Conductive metal layer 3 includes conductive layer, and the seed metal layer for electroplated conductive layer.Seed metal layer is arranged on nitrogen Change on aluminum insulation layer 2.Conductive layer is arranged in seed metal layer.
Seed metal layer includes titanium (Ti) layer 31, the first bronze medal (Cu) layer 32.First layers of copper 32 is arranged on titanium layer 31.
Conductive layer includes nickel (Ni) layer 33, the second bronze medal (Cu) layer 34.Nickel dam 33 is arranged in the first layers of copper 32;Second layers of copper 34 are arranged on nickel dam 33.
It is preferred that metal substrate 1 is aluminium base or copper base.Metal substrate 1 or by other any high thermal conductivity coefficient low-resistances Anti- metal or the alloy powder of nonmetallic materials are made.
It is preferred that conductive metal layer 3 is copper conductive layer or copper silver conductive layer.
The processing method of the metal-based circuit board of the present embodiment is:
The first step, metal substrate 1 is subjected to surface clean, then carry out fine grain blasting treatment, remove oxide-film and Surface contaminant;
Second step, using nanometer powder plasma spraying method, to 1 surface spraying of metal substrate, one layer of nitridation after processing Aluminum insulation layer 2;Then the surface of nitridation aluminum insulation layer 2 after spraying is carried out polishing processing using precision grinder;
3rd step, the surface of nitridation aluminum insulation layer 2 after polishing and cleaning, one layer of thin titanium is formed with magnetron sputtering technique Layer 31 and one layer thin of the first layers of copper 32, the layers of copper 32 of titanium layer 31 and first are used as the seed metal of next step plated conductive Layer;Then required circuit pattern is formed on the surface of the first layers of copper 32 with photolithographicallpatterned, has photoresist on the surface of the first layers of copper 32 Enter corresponding electroplate liquid in the case of mask, one layer of nickel dam 33 and one layer of second layers of copper 34 formed on surface using electro-plating method, Used as circuit conductive;Finally photoresist and the layers of copper 32 of titanium layer 31 and first are removed, there is required circuit pattern so as to be formed High heat conduction metal-based circuit board.
Embodiment three:
As shown in figure 3, a kind of metal-based circuit board of high heat conduction, including metal substrate 1, it is arranged on the upper table of metal substrate 1 The nitridation aluminum insulation layer 2 in face, and it is uniformly covered on the conductive metal layer 3 of nitridation aluminum insulation layer 2 upper surface.
Conductive metal layer 3 is formed by the circuit pattern being pre-designed.It is preferred that the thickness of nitridation aluminum insulation layer 2 is 0.2- 3mm。
It is preferred that metal substrate 1 is aluminium base or copper base.Metal substrate 1 or by other any high thermal conductivity coefficient low-resistances Anti- metal or the alloy powder of nonmetallic materials are made.
It is preferred that conductive metal layer 3 is copper conductive layer or copper silver conductive layer.
The processing method of the metal-based circuit board of the present embodiment is:
The first step, metal substrate 1 is subjected to surface clean, then carry out fine grain blasting treatment, remove oxide-film and Surface contaminant;
Second step, using nanometer powder plasma spraying method, to 1 surface spraying of metal substrate, one layer of nitridation after processing Aluminum insulation layer 2;
3rd step, layer of metal slurry is uniformly painted on nitridation aluminum insulation layer 2 surface, is then sintered, so as to form no electricity The high heat conduction metal-based circuit board of road figure.
Hereafter, corresponding circuitous pattern can be formed using caustic solution during use.
Example IV:
As shown in figure 4, a kind of metal-based circuit board of high heat conduction, including metal substrate 1, it is arranged on the upper table of metal substrate 1 The nitridation aluminum insulation layer 2 in face, and it is arranged on the conductive metal layer 3 of nitridation aluminum insulation layer 2 upper surface.The bottom surface of metal substrate 1 is set It is equipped with radiating fin or the flank of tooth.
Conductive metal layer 3 is formed by the circuit pattern being pre-designed.It is preferred that the thickness of nitridation aluminum insulation layer 2 is 0.2- 3mm。
It is preferred that metal substrate 1 is aluminium base or copper base.Metal substrate 1 or by other any high thermal conductivity coefficient low-resistances Anti- metal or the alloy powder of nonmetallic materials are made.
It is preferred that conductive metal layer 3 is copper conductive layer or copper silver conductive layer.
The processing method of the metal-based circuit board of the present embodiment is:
The first step, metal substrate 1 is subjected to surface clean, then carry out fine grain blasting treatment, remove oxide-film and Surface contaminant;
Second step, using nanometer powder plasma spraying method, to 1 surface spraying of metal substrate, one layer of nitridation after processing Aluminum insulation layer 2;
3rd step, conductive metal layer 3 is laid on nitridation aluminum insulation layer 2 surface, and conductive metal layer 3 is pressed into required circuit It is arranged into corresponding circuit;Pave 3 laggard stove of conductive metal layer to be sintered, led so as to form the height with required circuit pattern The Metal Substrate radiator of heat.
Above-described is only the preferred embodiment of the present invention, and the invention is not restricted to above example.It is appreciated that this The other improvement and change that art personnel directly export or associated without departing from the basic idea of the present invention It is considered as being included within protection scope of the present invention.

Claims (10)

  1. A kind of 1. metal-based circuit board of high heat conduction, it is characterised in that:
    Including metal substrate (1), nitridation aluminum insulation layer (2), conductive metal layer (3);
    The nitridation aluminum insulation layer (2) is arranged on the upper surface of metal substrate (1);
    The conductive metal layer (3) is arranged on the upper surface of nitridation aluminum insulation layer (2).
  2. 2. the metal-based circuit board of high heat conduction according to claim 1, it is characterised in that:
    The nitridation aluminum insulation layer (2) is sprayed on the upper surface of conductive metal layer (3);
    The thickness of the nitridation aluminum insulation layer (2) is 0.2-3mm.
  3. 3. the metal-based circuit board of high heat conduction according to claim 1, it is characterised in that:
    The conductive metal layer (3) includes conductive layer, and for electroplating the seed metal layer of the conductive layer;
    The seed metal layer is arranged on nitridation aluminum insulation layer (2);
    The conductive layer is arranged in the seed metal layer.
  4. 4. the metal-based circuit board of high heat conduction according to claim 1, it is characterised in that:
    The bottom surface of the metal substrate (1) is provided with radiating fin or the flank of tooth.
  5. 5. the metal-based circuit board of high heat conduction according to claim 1, it is characterised in that:
    The metal substrate (1) is aluminium base or copper base.
  6. 6. the metal-based circuit board of high heat conduction according to claim 1, it is characterised in that:
    The conductive metal layer (3) is copper conductive layer or copper silver conductive layer.
  7. 7. the metal-based circuit board of high heat conduction according to claim 3, it is characterised in that:
    The seed metal layer includes titanium layer (31), the first layers of copper (32);First layers of copper (32) is arranged on titanium layer (31);
    The conductive layer includes nickel dam (33), the second layers of copper (34);The nickel dam (33) is arranged in the first layers of copper (32);It is described Second layers of copper (34) is arranged on nickel dam (33).
  8. A kind of 8. metal-base circuit board manufacturing method of high heat conduction, it is characterised in that:
    Comprise the following steps:
    Step 1:Metal substrate (1) surface is pre-processed;
    Step 2:It is exhausted to pretreated metal substrate (1) surface spraying aluminium nitride using nanometer powder plasma spraying method Edge layer (2);
    Step 3:In nitridation aluminum insulation layer (2) surface printing conductive metal layer (3), then sinter.
  9. A kind of 9. metal-base circuit board manufacturing method of high heat conduction, it is characterised in that:
    Comprise the following steps:
    Step 1:Metal substrate (1) is subjected to surface clean, the blasting treatment of fine grain is then carried out, removes oxide-film and surface Pollutant;
    Step 2:Using nanometer powder plasma spraying method, insulated to metal substrate (1) surface spraying aluminium nitride after processing Layer (2);Then nitridation aluminum insulation layer (2) surface after spraying is carried out polishing processing using precision grinder;
    Step 3:Titanium layer (31) and are formed on nitridation aluminum insulation layer (2) surface after polishing and cleaning with magnetron sputtering technique One layers of copper (32);With photolithographicallpatterned in the first layers of copper (32) circuit forming surface pattern;Using electro-plating method in the first layers of copper (32) surface forms nickel dam (33) and the second layers of copper (34);Photoresist and titanium layer (31) and the first layers of copper (32) are removed.
  10. A kind of 10. metal-base circuit board manufacturing method of high heat conduction, it is characterised in that:
    Comprise the following steps:
    Step 1:Metal substrate (1) is subjected to surface clean, the blasting treatment of fine grain is then carried out, removes oxide-film and surface Pollutant;
    Step 2:Using nanometer powder plasma spraying method, insulated to metal substrate (1) surface spraying aluminium nitride after processing Layer (2);
    Step 3:Layer of metal slurry is uniformly painted on nitridation aluminum insulation layer (2) surface, is then sintered.
CN201710979512.0A 2017-10-19 2017-10-19 A kind of metal-based circuit board of high heat conduction and preparation method thereof Pending CN107708296A (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108901145A (en) * 2018-07-19 2018-11-27 惠州市鸿业新型材料有限公司 A kind of multilager base plate manufacturing method of surfaces nitrided insulating heat-conductive structure
TWI822346B (en) * 2022-09-20 2023-11-11 健策精密工業股份有限公司 Electronic device and method of manufacturing the same
US11924961B2 (en) 2022-03-11 2024-03-05 Unimicron Technology Corp. Circuit board and method of manufacturing the same

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108901145A (en) * 2018-07-19 2018-11-27 惠州市鸿业新型材料有限公司 A kind of multilager base plate manufacturing method of surfaces nitrided insulating heat-conductive structure
US11924961B2 (en) 2022-03-11 2024-03-05 Unimicron Technology Corp. Circuit board and method of manufacturing the same
TWI822346B (en) * 2022-09-20 2023-11-11 健策精密工業股份有限公司 Electronic device and method of manufacturing the same

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