CN107513298B - Improve the application of the photocatalyst product and photocatalyst product of adhesive force - Google Patents
Improve the application of the photocatalyst product and photocatalyst product of adhesive force Download PDFInfo
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- CN107513298B CN107513298B CN201710727238.8A CN201710727238A CN107513298B CN 107513298 B CN107513298 B CN 107513298B CN 201710727238 A CN201710727238 A CN 201710727238A CN 107513298 B CN107513298 B CN 107513298B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/007—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by irradiation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/704—Solvents not covered by groups B01D2257/702 - B01D2257/7027
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/45—Gas separation or purification devices adapted for specific applications
- B01D2259/4508—Gas separation or purification devices adapted for specific applications for cleaning air in buildings
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Abstract
The invention discloses a kind of applications of photocatalyst product and photocatalyst product for improving adhesive force.The photocatalyst product for improving adhesive force is made of following components: nano-titanium dioxide, butyl methacrylate, diacetyl tartaric acid monodiglyceride, isobutyl acrylate, Isobutyl methacrylate, sodium tripolyphosphate, styrene, stearoyl lactate, casein phosphopeptide, p-methyl benzenesulfonic acid, sulfonate surfactant, non-ionic antistatic agent and hardening agent；The hardening agent is one or both of xanthan gum and ovomucin.The photocatalyst product that the present invention improves adhesive force has the advantages that easy to use, and the photocatalyst product for improving adhesive force is applied to indoor article surface according to brushing dosage when in use.Simultaneously as the raising of adhesive force, the initial time that photo-catalyst film starts shedding off greatly extends, and slighter friction will not cause the destruction of film in use.
Description
Technical field
The invention belongs to Techniques for Indoor Air Purification field, more particularly to a kind of photocatalyst product for improving adhesive force,
And improve the photocatalyst product application in air treating indoors of adhesive force.
Background technique
Formaldehyde is widely considered to be indoor first killer by all circles, especially to infant, pregnant women, old man and chronic disease
The injury of patient is even more serious.Its main source has several aspects: all kinds of phenolic aldehyde as ornament materials such as skirting, ceilings
Resin glue wood-based plate, such as plywood, thin plank, fiberboard and particieboard etc.；Containing formaldehyde components and it is possible to outwardly distribute
Ornament materials, such as wall covering fabric, wallpaper paint and applies expects pipe；It is possible that the Interior Display and daily necessity of emitting formaldehyde,
Such as furniture, chemical fibre carpet and foamed plastics etc.；Certain materials of meeting emitting formaldehyde after burning, such as cigarette and some organic materials
Material；Some aromatic, mosquitocide liquid also contain formaldehyde components；Metope (coating) floor, furniture and some articles, pendulum decorations are in house
Anticorrosive mildewproof is all handled in advance with Antisepticize and mildew preventive, and most of preservative all has an impact to human body, and especially formaldehyde is to human body
Endanger most serious.
Photocatalyst is a kind of using Nano titanium dioxide as the total of the photosemiconductor material with photo-catalysis function of representative
Claim, toxic and harmful gas in the air that can effectively degrade；Various bacteria can effectively be killed；It is also equipped with deodorization, anti-pollution, purification simultaneously
The functions such as air.The main component of photocatalyst is titanium dioxide.Charge can be generated under sunlight or ultraviolet light irradiation,
With in air hydrone and oxygen molecule react, generate negative oxygen ion and hydroxyl free radical, these substances and have superpower
Oxidability can be such that ski dome substance is oxidized, and the cell wall of virus and bacteria can also be made to be destroyed, and reach removing
Indoor chemistry and the purpose of biological pollution.
Photocatalyst is covered into indoor article surface in the way of brushing, the area of brushing can be according to indoor pollution
Detection case determines that it is smaller to avoid patch type photocatalyst product surface area, the limited disadvantage of the reagentia played.This kind of medicine
Photo-catalytic nano particle is pasted onto body surface by the way of brushing by agent, forms thin film.But the heat of this layer film
Swollen contraction coefficients can not be identical with the coefficient of thermal expansion and contraction of furniture and wall surface, so extension of the film with the time
It can fall off, furthermore film can be also destroyed after object phase mutual friction in use, cause the failure of photocatalyst.
Summary of the invention
The object of the present invention is to provide a kind of photocatalyst product for improving adhesive force and the photocatalysts of the raising adhesive force
The application of product, problem to be solved are that existing photocatalyst product purification reaction acts on the limited and influence original beauty of article
The property seen.
The technical scheme to solve the above technical problems is that it is a kind of improve adhesive force photocatalyst product, by with
Lower component is constituted: nano-titanium dioxide, butyl methacrylate, diacetyl tartaric acid monodiglyceride, isobutyl acrylate, first
Base isobutyl acrylate, sodium tripolyphosphate, styrene, stearoyl lactate, casein phosphopeptide, p-methyl benzenesulfonic acid, sulfonate
Type surfactant, non-ionic antistatic agent and hardening agent；The hardening agent be one of xanthan gum and ovomucin or
Two kinds.
Preferably, the present invention improves the photocatalyst product of adhesive force as described above, consists of the following parts by weight:
35~45 parts of nano-titanium dioxide, 12~25 parts of butyl methacrylate, 20~30 parts of isobutyl acrylate, methacrylic acid are different
3~5 parts of butyl ester, 25~36 parts of styrene, 2~6 parts of p-methyl benzenesulfonic acid, 0.5~1.5 part of diacetyl tartaric acid monodiglyceride,
12~14 parts of sodium tripolyphosphate, 1.8~2.5 parts of stearoyl lactate, 16~22 parts of casein phosphopeptide, sulfonate type surface are living
20~28 parts of agent of property, 20~30 parts of non-ionic antistatic agent, 2~6 parts of xanthan gum and 15~30 parts of ovomucin.
Preferably, the present invention improves the photocatalyst product of adhesive force as described above, consists of the following parts by weight:
38 parts of nano-titanium dioxide, 18 parts of butyl methacrylate, 22 parts of isobutyl acrylate, 3.6 parts of Isobutyl methacrylate, benzene
28 parts of ethylene, 5 parts of p-methyl benzenesulfonic acid, 1.2 parts of diacetyl tartaric acid monodiglyceride, 12 parts of sodium tripolyphosphate, stearoyl lactylates
2 parts of sodium, 21 parts of casein phosphopeptide, 25 parts by weight of sulfonate surfactant, 28 parts by weight of non-ionic antistatic agent, Huang
3 parts and 25 parts of ovomucin of virgin rubber.
The present invention improves the photocatalyst product of adhesive force as described above, it is preferred that the nano-titanium dioxide is rutile titania
Type.
The present invention improves the photocatalyst product of adhesive force as described above, it is preferred that the sulfonate surfactant
Selected from one of following substance, two or more: alkylsulfonate, alkylbenzene sulfonate, alkylnaphthalene sulfonate, alpha-olefin sulphur
Hydrochlorate, alpha-sulfo monocarboxylate, the sulfoalkyl ester of fatty acid, sulphosuccinates, lignosulfonates, alkyl glycerylether sulphur
Hydrochlorate, alkyl diphenyl ether disulfonate.It is furthermore preferred that the alkylsulfonate is dodecyl sodium sulfate；The benzene sulfonamide
Hydrochlorate is neopelex.
The present invention improves the photocatalyst product of adhesive force as described above, it is preferred that non-ionic antistatic agent is selected from rouge
Ethylene oxide adduct, the ethylene oxide adduct of fatty alcohol, the ethylene oxide adduct of alkyl phenol, the ethoxylation rouge of fat acid
Fat amine, ethoxylated fatty amides, ethanol amine-glycidol ether.It is furthermore preferred that the ethoxylated fatty amine is selected from ethyoxyl
Change fatty alkyl primary amine, ethoxylated fat alkyl secondary amine, ethoxylation N- fatty alkyl -1,3- trimethylene diamines.
As above any one of the photocatalyst product for the improving adhesive force application in air treating indoors.Preferably, it wraps
The step of photocatalyst product for improving adhesive force is coated in matrix surface is included, and adheres to the raising coated in matrix surface
The step of photocatalyst product and pernicious gas of power contact.
The application method that the present invention improves the photocatalyst product of adhesive force will be improved using Spray painting tool or other tools
The photocatalyst product of adhesive force uniformly applies, the surface of film to indoor article, such as the surface of wall, the surface of furniture,
Surface, top surface of refrigerator of television set etc..Brushing dosage is that 1kg brushes 30m2~80m2。
The beneficial effects of the present invention are:
The present invention improve adhesive force photocatalyst product have the advantages that it is easy to use, when in use according to brushing dosage general
Improving the photocatalyst product of adhesive force is false to indoor article surface.Since the area of brushing can be according to indoor pollution
Detection case determine that it is smaller to avoid patch type photocatalyst product surface area, the limited disadvantage of the reagentia played.This
Outside, the photocatalyst product for improving adhesive force directly overlays article surface and the amalgamation of article is strong, and aesthetics is stronger.More
Importantly, due to the raising of adhesive force, the initial time that photo-catalyst film starts shedding off greatly extends, furthermore relatively light in use
Micro- friction will not cause the destruction of film.
Specific embodiment
The embodiment recorded herein is specific specific embodiment of the invention, for illustrating design of the invention,
Be it is explanatory and illustrative, should not be construed as the limitation to embodiment of the present invention and the scope of the invention.Except what is recorded herein
Outside embodiment, those skilled in the art can also based on the claim of this application book and specification disclosure of that using aobvious and
The other technical solutions being clear to, these technical solutions include using any obvious to making for the embodiment recorded herein
The technical solution of substitutions and modifications.
A kind of photocatalyst product of the raising adhesive force of specific embodiment of the present invention is made of following components: nano-silica
Change titanium, butyl methacrylate, diacetyl tartaric acid monodiglyceride, isobutyl acrylate, Isobutyl methacrylate, trimerization
Sodium phosphate, styrene, stearoyl lactate, casein phosphopeptide, p-methyl benzenesulfonic acid, sulfonate surfactant, nonionic
Type antistatic agent and hardening agent；The hardening agent is one or both of xanthan gum and ovomucin.
A kind of photocatalyst product of the raising adhesive force of specific embodiment of the present invention is made of following components: nano-silica
Change 35~45 parts of titanium, 12~25 parts of butyl methacrylate, 20~30 parts of isobutyl acrylate, Isobutyl methacrylate 3~5
Part, 25~36 parts of styrene, 2~6 parts of p-methyl benzenesulfonic acid, 0.5~1.5 part of diacetyl tartaric acid monodiglyceride, tripolyphosphate
12~14 parts of sodium, 1.8~2.5 parts of stearoyl lactate, 16~22 parts of casein phosphopeptide, sulfonate surfactant 20~
28 parts, 20~30 parts of non-ionic antistatic agent, 2~6 parts of xanthan gum and 15~30 parts of ovomucin.
In above two embodiment, it is preferred that the nano-titanium dioxide is anatase titanium dioxide.
Preferably, the sulfonate surfactant be selected from one of following substance, two or more: alkyl sulfonic acid
Salt, alkylbenzene sulfonate, alkylnaphthalene sulfonate, alpha-alkene sulfonate, alpha-sulfo monocarboxylate, fatty acid sulfoalkyl ester, amber
Amber acid ester sulfonates, lignosulfonates, alkyl glyceryl ether sulfonate, alkyl diphenyl ether disulfonate.It is furthermore preferred that the alkane
Base sulfonate is dodecyl sodium sulfate；The alkylbenzene sulfonate is neopelex.
Preferably, non-ionic antistatic agent is selected from the ethylene oxide adduct of fatty acid, the ethylene oxide of fatty alcohol adds
Close object, the ethylene oxide adduct of alkyl phenol, ethoxylated fatty amine, ethoxylated fatty amides, ethanol amine-glycidol
Ether.It is furthermore preferred that the ethoxylated fatty amine be selected from ethoxylated fat kiber alkyl amine, ethoxylated fat alkyl secondary amine,
Ethoxylation N- fatty alkyl -1,3- trimethylene diamines.
The raw materials used source of following embodiment is as follows:
Nano-titanium dioxide, Nanjing Tian Hang new material Co., Ltd, anatase titanium dioxide, model TTP-A10；Methacrylic acid fourth
Ester, Shanghai Mai Ruier chemical technology Co., Ltd, purity > 99.0wt%；Diacetyl tartaric acid monodiglyceride, Zhengzhou feudal dynasty
Chemical products Co., Ltd, purity 98wt%；Isobutyl acrylate, Shanghai Mai Ruier chemical technology Co., Ltd, purity
99wt%；Isobutyl methacrylate, Shanghai Mike's woods biochemical technology Co., Ltd, purity 99wt%；Sodium tripolyphosphate, western lattice
Ma aldrich (Shanghai) trade Co., Ltd, purity 98wt%；Styrene, Aladdin reagent, purity > 99.5wt%；It is stearic
Acyl lactylate, the emerging milky way Chemical Co., Ltd. in Hubei, purity 99wt%；Casein phosphopeptide, the macro letter health fine chemistry industry in Wuhan have
Limit company, purity 99wt%；P-methyl benzenesulfonic acid, Nanjing Datang chemical industry Co., Ltd, purity 99wt%；Sulfonate type surface
Activating agent (dodecyl sodium sulfate, neopelex, sodium lignin sulfonate, disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate) purchase
From Jiangsu Kai Yuan Science and Technology Ltd.；Non-ionic antistatic agent (polyoxyethylene dodecyl amine, polyoxyethylene cetyl base
Amine, polyoxyethylene (2) hydrogenated-tallow group amine, polyoxyethylene (10) hydrogenated-tallow group amine) it is limited purchased from Jiangyin City Ni Meida auxiliary agent
Company；The production of xanthan gum Mei Weihua biotechnology Group Plc is a kind of by the thin of Xanthomonas campestris fermentation generation
Extracellular acid heteroglycan.The polysaccharide producing high-molecular being made of D-Glucose, D-MANNOSE and D-Glucose aldehydic acid by 2:2:1
Close object；Ovomucin is the high molecular weight sulfuric ester glycoprotein that a kind of degree of glycosylation is more than 30%.
Embodiment 1
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 35 grams of nano-titanium dioxide, methyl
25 grams of butyl acrylate, 20 grams of isobutyl acrylate, 5 grams of Isobutyl methacrylate, 25 grams of styrene, 6 grams of p-methyl benzenesulfonic acid,
0.5 gram of diacetyl tartaric acid monodiglyceride, 14 grams of sodium tripolyphosphate, 1.8 grams of stearoyl lactate, casein phosphopeptide 22
Gram, 20 grams of dodecyl sodium sulfate, 30 grams of polyoxyethylene dodecyl amine, 2 grams of xanthan gum, 30 grams of ovomucin.
Preparation method: butyl methacrylate, the diacetyl tartaric acid monodiglyceride, third of the parts by weight will be met
The nanometer for meeting the weight fraction is added after mixing in olefin(e) acid isobutyl ester, Isobutyl methacrylate, styrene, p-methyl benzenesulfonic acid
Titanium dioxide, sodium tripolyphosphate, stearoyl lactate, casein phosphopeptide obtain the first mixture, and the first mixture, which is added to, to be stirred
It mixes in machine to be stirred 0.5-1 hours under the low speed of 60-80r/min, is put into ball mill and carries out ball milling, ball milling speed 60-80r/
min；It places into blender with the moderate-speed mixer mixing of 600-800r/min 10-20 minutes；The parts by weight will be met
Sulfonate surfactant, non-ionic antistatic agent, xanthan gum and ovomucin are added in the first mixture, are put into and are stirred
It mixes low speed 60-80r/min in machine to be stirred 2-5 hours, then moderate-speed mixer mixing 300-500r/min is stirred 10-20 points
Clock obtains the photocatalyst product for improving adhesive force.
Embodiment 2
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 45 grams of nano-titanium dioxide, methyl
12 grams of butyl acrylate, 30 grams of isobutyl acrylate, 3 grams of Isobutyl methacrylate, 36 grams of styrene, 2 grams of p-methyl benzenesulfonic acid,
1.5 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2.5 grams of stearoyl lactate, casein phosphopeptide 16
Gram, 28 grams of dodecyl sodium sulfate, 20 grams of polyoxyethylene dodecyl amine, 6 grams of xanthan gum, 20 grams of ovomucin.Preparation method
It is same as Example 1.
Embodiment 3
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 38 grams of nano-titanium dioxide, methyl
18 grams of butyl acrylate, 22 grams of isobutyl acrylate, 3.6 grams of Isobutyl methacrylate, 28 grams of styrene, p-methyl benzenesulfonic acid 5
Gram, 1.2 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2 grams of stearoyl lactate, casein phosphopeptide 21
Gram, 25 grams of dodecyl sodium sulfate, 28 grams of polyoxyethylene dodecyl amine, 3 grams of xanthan gum, 25 grams of ovomucin.Preparation method
It is same as Example 1.
Embodiment 4
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 35 grams of nano-titanium dioxide, methyl
25 grams of butyl acrylate, 20 grams of isobutyl acrylate, 5 grams of Isobutyl methacrylate, 25 grams of styrene, 6 grams of p-methyl benzenesulfonic acid,
0.5 gram of diacetyl tartaric acid monodiglyceride, 14 grams of sodium tripolyphosphate, 1.8 grams of stearoyl lactate, casein phosphopeptide 22
Gram, 20 grams of neopelex, 30 grams of polyoxyethylene cetyl base amine, 2 grams of xanthan gum, 30 grams of ovomucin.Preparation side
Method is same as Example 1.
Embodiment 5
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 45 grams of nano-titanium dioxide, methyl
12 grams of butyl acrylate, 30 grams of isobutyl acrylate, 3 grams of Isobutyl methacrylate, 36 grams of styrene, 2 grams of p-methyl benzenesulfonic acid,
1.5 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2.5 grams of stearoyl lactate, casein phosphopeptide 16
Gram, 28 grams of sodium lignin sulfonate, 20 grams of polyoxyethylene (2) hydrogenated-tallow group amine, 6 grams of xanthan gum, 20 grams of ovomucin.Preparation side
Method is same as Example 1.
Embodiment 6
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 38 grams of nano-titanium dioxide, methyl
18 grams of butyl acrylate, 22 grams of isobutyl acrylate, 3.6 grams of Isobutyl methacrylate, 28 grams of styrene, p-methyl benzenesulfonic acid 5
Gram, 1.2 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2 grams of stearoyl lactate, casein phosphopeptide 21
Gram, 25 grams of disodium 4-dodecyl-2,4 '-oxydibenzenesulfonate, 28 grams of polyoxyethylene (10) hydrogenated-tallow group amine, 3 grams of xanthan gum, ovomucin
25 grams.Preparation method is same as Example 1.
Embodiment 7
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 38 grams of nano-titanium dioxide, methyl
18 grams of butyl acrylate, 22 grams of isobutyl acrylate, 3.6 grams of Isobutyl methacrylate, 28 grams of styrene, p-methyl benzenesulfonic acid 5
Gram, 1.2 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2 grams of stearoyl lactate, casein phosphopeptide 21
Gram, 25 grams of dodecyl sodium sulfate, 28 grams of polyoxyethylene dodecyl amine, 2 grams of xanthan gum.Preparation method is same as Example 1,
But ovomucin is not added in the present embodiment.
Embodiment 8
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 38 grams of nano-titanium dioxide, methyl
18 grams of butyl acrylate, 22 grams of isobutyl acrylate, 3.6 grams of Isobutyl methacrylate, 28 grams of styrene, p-methyl benzenesulfonic acid 5
Gram, 1.2 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2 grams of stearoyl lactate, casein phosphopeptide 21
Gram, 25 grams of dodecyl sodium sulfate, 28 grams of polyoxyethylene dodecyl amine, 6 grams of xanthan gum.Preparation method is same as Example 1,
But ovomucin is not added in the present embodiment.
Embodiment 9
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 38 grams of nano-titanium dioxide, methyl
18 grams of butyl acrylate, 22 grams of isobutyl acrylate, 3.6 grams of Isobutyl methacrylate, 28 grams of styrene, p-methyl benzenesulfonic acid 5
Gram, 1.2 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2 grams of stearoyl lactate, casein phosphopeptide 21
Gram, 25 grams of dodecyl sodium sulfate, 28 grams of polyoxyethylene dodecyl amine, 3 grams of xanthan gum.Preparation method is same as Example 1,
But ovomucin is not added in the present embodiment.
Embodiment 10
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 38 grams of nano-titanium dioxide, methyl
18 grams of butyl acrylate, 22 grams of isobutyl acrylate, 3.6 grams of Isobutyl methacrylate, 28 grams of styrene, p-methyl benzenesulfonic acid 5
Gram, 1.2 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2 grams of stearoyl lactate, casein phosphopeptide 21
Gram, 25 grams of dodecyl sodium sulfate, 28 grams of polyoxyethylene dodecyl amine, 30 grams of ovomucin.Preparation method and 1 phase of embodiment
Together, but in the present embodiment xanthan gum is not added.
Embodiment 11
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 38 grams of nano-titanium dioxide, methyl
18 grams of butyl acrylate, 22 grams of isobutyl acrylate, 3.6 grams of Isobutyl methacrylate, 28 grams of styrene, p-methyl benzenesulfonic acid 5
Gram, 1.2 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2 grams of stearoyl lactate, casein phosphopeptide 21
Gram, 25 grams of dodecyl sodium sulfate, 28 grams of polyoxyethylene dodecyl amine, 20 grams of ovomucin.Preparation method and 1 phase of embodiment
Together, but in the present embodiment xanthan gum is not added.
Embodiment 12
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 38 grams of nano-titanium dioxide, methyl
18 grams of butyl acrylate, 22 grams of isobutyl acrylate, 3.6 grams of Isobutyl methacrylate, 28 grams of styrene, p-methyl benzenesulfonic acid 5
Gram, 1.2 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2 grams of stearoyl lactate, casein phosphopeptide 21
Gram, 25 grams of dodecyl sodium sulfate, 28 grams of polyoxyethylene dodecyl amine, 25 grams of ovomucin.Preparation method and 1 phase of embodiment
Together, but in the present embodiment xanthan gum is not added.
Embodiment 13
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 38 grams of nano-titanium dioxide, methyl
18 grams of butyl acrylate, 22 grams of isobutyl acrylate, 3.6 grams of Isobutyl methacrylate, 28 grams of styrene, p-methyl benzenesulfonic acid 5
Gram, 1.2 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2 grams of stearoyl lactate, casein phosphopeptide 21
Gram, 25 grams of dodecyl sodium sulfate, 28 grams of polyoxyethylene dodecyl amine.Preparation method is same as Example 1, but the present embodiment
In xanthan gum and ovomucin are not added.
Embodiment 14
The photocatalyst product of the raising adhesive force of the present embodiment is made of following components: 38 grams of nano-titanium dioxide, methyl
18 grams of butyl acrylate, 22 grams of isobutyl acrylate, 3.6 grams of Isobutyl methacrylate, 28 grams of styrene, p-methyl benzenesulfonic acid 5
Gram, 1.2 grams of diacetyl tartaric acid monodiglyceride, 12 grams of sodium tripolyphosphate, 2 grams of stearoyl lactate, casein phosphopeptide 21
Gram, 25 grams of dodecyl sodium sulfate, 28 grams of polyoxyethylene dodecyl amine, 20 grams of 204 resin (tackifier, tert-butyl phenolic aldehyde increase
Viscosity resin, 130-157 DEG C of softening point, the production of Shanxi chemical institute).Preparation method is same as Example 1.
Performance test and interpretation of result one
To above-described embodiment 1-13 obtain raising adhesive force photocatalyst product according to following standard method progressive
It can test, " function of purifying indoor air coating material purifying property " JC/T1074-2008.
The preparation of test piece: the photocatalyst product of the raising adhesive force of embodiment 1-15 preparation brushes 20m according to 1kg2
Dosage brushed respectively to the glass plate of 500mmX500mm；It is tested after being spontaneously dried 7 days in experimental enviroment.As a result such as
Shown in table 1-4.
1 product purifying property (formaldehyde) of table
| Pollutant (formaldehyde) | Purification efficiency | Standard requirements (I class product) | Standard requirements (II class product) |
| Embodiment 1 | 86 | >=75% | >=80% |
| Embodiment 2 | 78 | >=75% | >=80% |
| Embodiment 3 | 88 | >=75% | >=80% |
| Embodiment 4 | 72 | >=75% | >=80% |
| Embodiment 5 | 80 | >=75% | >=80% |
| Embodiment 6 | 76 | >=75% | >=80% |
| Embodiment 7 | 75 | >=75% | >=80% |
| Embodiment 8 | 75 | >=75% | >=80% |
| Embodiment 9 | 75 | >=75% | >=80% |
| Embodiment 10 | 72 | >=75% | >=80% |
| Embodiment 11 | 75 | >=75% | >=80% |
| Embodiment 12 | 72 | >=75% | >=80% |
| Embodiment 13 | 72 | >=75% | >=80% |
| Embodiment 14 | 68 | >=75% | >=80% |
In conjunction with table 1 product purifying property (formaldehyde) data it can be proved that prepared by the method improve adhesive force
Photocatalyst product has the ability of removal formaldehyde, and purifying property is greater than 72%.
2 product purifying property (toluene) of table
In conjunction with table 2 product purifying property (toluene) data it can be proved that prepared by the method improve adhesive force
Photocatalyst product has the ability of removal toluene, and purifying property is greater than 42%.
3 product clean-up effect persistence (formaldehyde) of table
| Pollutant (formaldehyde) | Purification efficiency | Standard requirements (I class product) | Standard requirements (II class product) |
| Embodiment 1 | 72 | >=60% | >=65% |
| Embodiment 2 | 66 | >=60% | >=65% |
| Embodiment 3 | 75 | >=60% | >=65% |
| Embodiment 4 | 58 | >=60% | >=65% |
| Embodiment 5 | 60 | >=60% | >=65% |
| Embodiment 6 | 64 | >=60% | >=65% |
| Embodiment 7 | 68 | >=60% | >=65% |
| Embodiment 8 | 68 | >=60% | >=65% |
| Embodiment 9 | 68 | >=60% | >=65% |
| Embodiment 10 | 59 | >=60% | >=65% |
| Embodiment 11 | 68 | >=60% | >=65% |
| Embodiment 12 | 59 | >=60% | >=65% |
| Embodiment 13 | 58 | >=60% | >=65% |
| Embodiment 14 | 52 | >=60% | >=65% |
It can prove that clean-up effect persistence is greater than 58% in conjunction with the data of 3 product clean-up effect persistence (formaldehyde) of table.
4 product clean-up effect persistence (toluene) of table
It can prove that clean-up effect persistence is greater than 35% in conjunction with the data of 4 product clean-up effect persistence (toluene) of table.
Performance test and interpretation of result two
To above-described embodiment 1-13 obtain raising adhesive force photocatalyst product according to following standard method progressive
It can test, " paint film adhesion measuring method " GB1720-1979.
5 photocatalyst adhesive force grade of table
| Photocatalyst | Adhesive force grade |
| Embodiment 1 | 2 |
| Embodiment 2 | 2 |
| Embodiment 3 | 1 |
| Embodiment 4 | 2 |
| Embodiment 5 | 2 |
| Embodiment 6 | 1 |
| Embodiment 7 | 3 |
| Embodiment 8 | 3 |
| Embodiment 9 | 3 |
| Embodiment 10 | 4 |
| Embodiment 11 | 3 |
| Embodiment 12 | 4 |
| Embodiment 13 | 6 |
| Embodiment 14 | 1 |
Inventor also attempts for other existing thickening substances to be added in the raw material of photocatalyst product, but adhesive force mentions
High effect is unobvious, and the addition of other existing thickening substances influences whether the purification removal energy of the harmful substances such as formaldehyde
Power, referring to 14 data of comparative example.
Each technical characteristic of above-mentioned disclosure is not limited to disclosed and other feature combination, and those skilled in the art are also
Can carry out other combinations between each technical characteristic according to the purpose of invention, be subject to realize the present invention purpose.
Claims (9)
1. a kind of photocatalyst product for improving adhesive force, it is characterised in that: consist of the following parts by weight: nanometer titanium dioxide
35~45 parts of titanium, 12~25 parts of butyl methacrylate, 20~30 parts of isobutyl acrylate, Isobutyl methacrylate 3~5
Part, 25~36 parts of styrene, 2~6 parts of p-methyl benzenesulfonic acid, 0.5~1.5 part of diacetyl tartaric acid monodiglyceride, tripolyphosphate
12~14 parts of sodium, 1.8~2.5 parts of stearoyl lactate, 16~22 parts of casein phosphopeptide, sulfonate surfactant 20~
28 parts, 20~30 parts of non-ionic antistatic agent, 2~6 parts of xanthan gum and 15~30 parts of ovomucin.
2. the photocatalyst product according to claim 1 for improving adhesive force, which is characterized in that by the component of following parts by weight
It constitutes: 38 parts of nano-titanium dioxide, 18 parts of butyl methacrylate, 22 parts of isobutyl acrylate, Isobutyl methacrylate 3.6
Part, 28 parts of styrene, 5 parts of p-methyl benzenesulfonic acid, 1 .2 parts of diacetyl tartaric acid monodiglyceride, 12 parts of sodium tripolyphosphate, tristearin
2 parts of acyl lactylate, 21 parts of casein phosphopeptide, 25 parts by weight of sulfonate surfactant, 28 weight of non-ionic antistatic agent
Amount part, 3 parts of xanthan gum and 25 parts of ovomucin.
3. the photocatalyst product according to claim 1 for improving adhesive force, which is characterized in that the nano-titanium dioxide is
Anatase titanium dioxide.
4. the photocatalyst product according to claim 3 for improving adhesive force, which is characterized in that the sulfonate type surface is living
Property agent be selected from one of following substance, two or more: alkylsulfonate, alkylbenzene sulfonate, alkylnaphthalene sulfonate, α-alkene
Sulfonated hydrocarbon, alpha-sulfo monocarboxylate, fatty acid sulfoalkyl ester, sulphosuccinates, lignosulfonates, alkyl glycerol
Ether sulfonate, alkyl diphenyl ether disulfonate.
5. the photocatalyst product according to claim 4 for improving adhesive force, which is characterized in that the alkylsulfonate is ten
Dialkyl sulfonates；The alkylbenzene sulfonate is neopelex.
6. the photocatalyst product according to claim 3 for improving adhesive force, which is characterized in that described non-ionic antistatic
Agent is selected from the ethylene oxide adduct of fatty acid, the ethylene oxide adduct of fatty alcohol, the ethylene oxide adduct of alkyl phenol, second
Oxygroup fatty amine, ethoxylated fatty amides, ethanol amine-glycidol ether.
7. the photocatalyst product according to claim 6 for improving adhesive force, which is characterized in that the ethoxylated fatty amine
Selected from ethoxylated fat kiber alkyl amine, ethoxylated fat alkyl secondary amine, ethoxylation N- fatty alkyl -1,3- trimethylene two
Amine.
8. the application in air treating indoors of any one of the claim 1-7 photocatalyst product for improving adhesive force.
9. the photocatalyst product according to claim 8 for the improving adhesive force application in air treating indoors, including will
The step of photocatalyst product of adhesive force is coated in matrix surface is improved, and makes the raising adhesive force coated in matrix surface
The step of photocatalyst product and pernicious gas contact.
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|---|---|---|---|---|
| CN1521223A (en) * | 2003-02-14 | 2004-08-18 | 王崇高 | Multifunctional green environmental protection type nanometer paint |
| CN1844270A (en) * | 2006-05-17 | 2006-10-11 | 河北科技大学 | Nano antibacterial powdered paint and its micro-suspension one-step preparation therefor |
| CN101486867A (en) * | 2009-02-12 | 2009-07-22 | 张文磊 | Photo-catalytic coating |
| CN101613559A (en) * | 2008-06-25 | 2009-12-30 | 云南格兰工业发展有限公司 | Hydrophilic nano zinc based composite coating |
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2017
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1521223A (en) * | 2003-02-14 | 2004-08-18 | 王崇高 | Multifunctional green environmental protection type nanometer paint |
| CN1844270A (en) * | 2006-05-17 | 2006-10-11 | 河北科技大学 | Nano antibacterial powdered paint and its micro-suspension one-step preparation therefor |
| CN101613559A (en) * | 2008-06-25 | 2009-12-30 | 云南格兰工业发展有限公司 | Hydrophilic nano zinc based composite coating |
| CN101486867A (en) * | 2009-02-12 | 2009-07-22 | 张文磊 | Photo-catalytic coating |
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