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CN107236213A - 一种阻燃pvc壁纸用复合材料及其制备方法 - Google Patents

一种阻燃pvc壁纸用复合材料及其制备方法 Download PDF

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CN107236213A
CN107236213A CN201710469802.0A CN201710469802A CN107236213A CN 107236213 A CN107236213 A CN 107236213A CN 201710469802 A CN201710469802 A CN 201710469802A CN 107236213 A CN107236213 A CN 107236213A
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王海燕
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Dongguan Jia Xin New Mstar Technology Ltd
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Abstract

本发明公开了一种阻燃PVC壁纸用复合材料,以重量份计,包括以下组分:PVC树脂100份;纳米结晶纤维素10‑17份,壳聚糖9‑14份,聚磷酸铵20‑35份,水滑石5‑9份,椰油基葡糖苷2‑5份,偶联剂3‑7份,增塑剂50‑60份,稳定剂1‑2份,发泡剂1‑2份。该阻燃PVC壁纸用复合材料具有良好的阻燃效果,而且该材料具有良好的柔韧性以及稳定性,使用寿命较长。

Description

一种阻燃PVC壁纸用复合材料及其制备方法
技术领域
本发明涉及壁纸材料领域,特别是涉及一种阻燃PVC壁纸用复合材料及其制备方法。
背景技术
壁纸是一种传统的墙面装饰材料,具有色彩多样、图案丰富、安全环保,施工方便、价格适宜等优点。近年来为了适应不同的空间场所,不同的兴趣爱好以及不同的价格层次,有多种类型的壁纸可供选择。根据壁纸的材料,可以分为:高分子材料类壁纸、纯纸类壁纸、无纺布类壁纸、织物类壁纸、硅藻土类壁纸、天然材料类壁纸、和纸类壁纸、云母片类壁纸、金银箔类壁纸以及墙布类壁纸。近年来随着科技的发展,出现了一些新型功能性壁纸,比如:电脑特效壁纸,吸湿壁纸,杀虫壁纸,高温壁纸,防霉壁纸,保温隔热壁纸,暖气壁纸,报火警壁纸以及消毒杀菌壁纸。
在众多种类的壁纸中,目前高分子材料类壁纸中的PVC塑料壁纸是生产量最多,市场最好的一种壁纸。PVC壁纸具有价格低廉,花色品种多,透气性好,适用面广,隔音效果佳,并且耐擦洗等优点,在各种场所广泛使用,极大的美化了人们的居住环境。但是,未经阻燃处理的PVC壁纸氧指数仅为21左右,属于易燃材料,存在潜在火灾风险。目前常用的阻燃方式多是采用无机阻燃剂,易结晶析出,从而导致纸张吸潮而发生相互粘连,对壁纸的储存带来较多问题。
中国专利CN201610005451.3公开了一种壁纸PVC层,按质量份数计,其原料由以下组分组成:塑化剂:250份;降粘剂:70~80份;PVC450树脂粉:350~400份;高温发泡剂:4~6份;低温发泡剂:6~10份;增白剂:80~120份;钛白粉:40~60份;重钙:200~220份;轻钙:40~60份;稳定剂:6~10份。该发明采用高温发泡剂和低温发泡剂相结合的配方,实现二次发泡,第一次在涂PVC皮料时,低温发泡剂起效,增加了纸张的柔韧性和印刷平整度,第二次在压纹时使用,高温使得高温发泡增加PVC厚度,提高压纹的清晰度,使得二者兼具,既满足纸张较好的柔韧性和印刷平整度,又有较好的压纹清晰度。但是该壁纸的阻燃性能仍需改进。
发明内容
本发明的目的是提供一种阻燃PVC壁纸用复合材料及其制备方法,该阻燃PVC壁纸用复合材料具有良好的阻燃效果,而且该材料具有良好的柔韧性以及稳定性,使用寿命较长。
为实现上述目的,本发明采用以下技术方案:
一种阻燃PVC壁纸用复合材料,以重量份计,包括以下组分:
PVC树脂100份;纳米结晶纤维素10-17份,壳聚糖9-14份,聚磷酸铵20-35份,水滑石5-9份,椰油基葡糖苷2-5份,偶联剂3-7份,增塑剂50-60份,稳定剂1-2份,发泡剂1-2份。
优选的,所述偶联剂为铝酸酯偶联剂和硅烷偶联剂的混合物。
优选的,所述增塑剂为DOTP与氯化芳烃油质量比为3:5的混合物。
优选的,所述稳定剂为柠檬酸稀土。
优选的,所述发泡剂为AC发泡剂。
一种阻燃PVC壁纸用复合材料的制备方法,包括以下步骤:
(1)将水滑石放入研磨机中,研磨20-30min,之后向其中滴加椰油基葡糖苷的水溶液,滴加完成后,继续研磨30-45min,取出烘干,制得改性水滑石粉末;
(2)将PVC树脂和增塑剂混合均匀,之后加入纳米结晶纤维素,壳聚糖和聚磷酸铵,在40-60℃条件下搅拌混合均匀,之后依次加入偶联剂,改性水滑石粉末,稳定剂和发泡剂继续搅拌均匀,制得阻燃PVC壁纸用复合材料。
本发明具有以下有益效果,
纳米结晶纤维素颗粒直径下,比表面积大,具有特有的光学性能和机械性能。纳米结晶纤维素表面存在大量的羟基,易与聚磷酸铵结合,从而使得聚磷酸铵可以在PVC复合材料中可以较为稳定的均匀分布,形成阻燃层。
水滑石为层状镁铝复合氧化物,其受热时结构水合层板羟基以及层间离子以水和CO2的形式脱出,从而起到阻燃作用。同时水滑石有助于提高PVC材料的稳定性,可以有效的延长本发明制得的阻燃PVC壁纸用复合材料的使用寿命。
具体实施方式
为了更好的理解本发明,下面通过实施例对本发明进一步说明,实施例只用于解释本发明,不会对本发明构成任何的限定。
实施例1
一种阻燃PVC壁纸用复合材料,以重量份计,包括以下组分:
PVC树脂100份;纳米结晶纤维素10份,壳聚糖9份,聚磷酸铵20份,水滑石5份,椰油基葡糖苷2份,偶联剂3份,增塑剂50份,稳定剂1份,发泡剂1份。
其中,偶联剂为铝酸酯偶联剂和硅烷偶联剂的混合物;增塑剂为DOTP与氯化芳烃油质量比为3:5的混合物;稳定剂为柠檬酸稀土;发泡剂为AC发泡剂。
该阻燃PVC壁纸用复合材料的制备方法,包括以下步骤:
(1)将水滑石放入研磨机中,研磨20min,之后向其中滴加椰油基葡糖苷的水溶液,滴加完成后,继续研磨30min,取出烘干,制得改性水滑石粉末;
(2)将PVC树脂和增塑剂混合均匀,之后加入纳米结晶纤维素,壳聚糖和聚磷酸铵,在40℃条件下搅拌混合均匀,之后依次加入偶联剂,改性水滑石粉末,稳定剂和发泡剂继续搅拌均匀,制得阻燃PVC壁纸用复合材料。
使用制得的阻燃PVC壁纸用复合材料以无纺布为基纸制备壁纸,测得其极限氧指数为36.2%,并且该壁纸长时间使用后仍能保持良好的性状。
实施例2
一种阻燃PVC壁纸用复合材料,以重量份计,包括以下组分:
PVC树脂100份;纳米结晶纤维素17份,壳聚糖14份,聚磷酸铵35份,水滑石9份,椰油基葡糖苷5份,偶联剂7份,增塑剂60份,稳定剂2份,发泡剂2份。
其中,偶联剂为铝酸酯偶联剂和硅烷偶联剂的混合物;增塑剂为DOTP与氯化芳烃油质量比为3:5的混合物;稳定剂为柠檬酸稀土;发泡剂为AC发泡剂。
该阻燃PVC壁纸用复合材料的制备方法,包括以下步骤:
(1)将水滑石放入研磨机中,研磨30min,之后向其中滴加椰油基葡糖苷的水溶液,滴加完成后,继续研磨45min,取出烘干,制得改性水滑石粉末;
(2)将PVC树脂和增塑剂混合均匀,之后加入纳米结晶纤维素,壳聚糖和聚磷酸铵,在60℃条件下搅拌混合均匀,之后依次加入偶联剂,改性水滑石粉末,稳定剂和发泡剂继续搅拌均匀,制得阻燃PVC壁纸用复合材料。
使用制得的阻燃PVC壁纸用复合材料以无纺布为基纸制备壁纸,测得其极限氧指数为38.5%,并且该壁纸长时间使用后仍能保持良好的性状。
实施例3
一种阻燃PVC壁纸用复合材料,以重量份计,包括以下组分:
PVC树脂100份;纳米结晶纤维素10份,壳聚糖14份,聚磷酸铵20份,水滑石9份,椰油基葡糖苷2份,偶联剂7份,增塑剂50份,稳定剂2份,发泡剂1份。
其中,偶联剂为铝酸酯偶联剂和硅烷偶联剂的混合物;增塑剂为DOTP与氯化芳烃油质量比为3:5的混合物;稳定剂为柠檬酸稀土;发泡剂为AC发泡剂。
该阻燃PVC壁纸用复合材料的制备方法,包括以下步骤:
(1)将水滑石放入研磨机中,研磨20min,之后向其中滴加椰油基葡糖苷的水溶液,滴加完成后,继续研磨45min,取出烘干,制得改性水滑石粉末;
(2)将PVC树脂和增塑剂混合均匀,之后加入纳米结晶纤维素,壳聚糖和聚磷酸铵,在40℃条件下搅拌混合均匀,之后依次加入偶联剂,改性水滑石粉末,稳定剂和发泡剂继续搅拌均匀,制得阻燃PVC壁纸用复合材料。
使用制得的阻燃PVC壁纸用复合材料以无纺布为基纸制备壁纸,测得其极限氧指数为45.6%,并且该壁纸长时间使用后仍能保持良好的性状。
实施例4
一种阻燃PVC壁纸用复合材料,以重量份计,包括以下组分:
PVC树脂100份;纳米结晶纤维素17份,壳聚糖9份,聚磷酸铵35份,水滑石5份,椰油基葡糖苷5份,偶联剂3份,增塑剂60份,稳定剂1份,发泡剂2份。
其中,偶联剂为铝酸酯偶联剂和硅烷偶联剂的混合物;增塑剂为DOTP与氯化芳烃油质量比为3:5的混合物;稳定剂为柠檬酸稀土;发泡剂为AC发泡剂。
该阻燃PVC壁纸用复合材料的制备方法,包括以下步骤:
(1)将水滑石放入研磨机中,研磨30min,之后向其中滴加椰油基葡糖苷的水溶液,滴加完成后,继续研磨30min,取出烘干,制得改性水滑石粉末;
(2)将PVC树脂和增塑剂混合均匀,之后加入纳米结晶纤维素,壳聚糖和聚磷酸铵,在60℃条件下搅拌混合均匀,之后依次加入偶联剂,改性水滑石粉末,稳定剂和发泡剂继续搅拌均匀,制得阻燃PVC壁纸用复合材料。
使用制得的阻燃PVC壁纸用复合材料以无纺布为基纸制备壁纸,测得其极限氧指数为40.3%,并且该壁纸长时间使用后仍能保持良好的性状。
实施例5
一种阻燃PVC壁纸用复合材料,以重量份计,包括以下组分:
PVC树脂100份;纳米结晶纤维素12份,壳聚糖11份,聚磷酸铵25份,水滑石7份,椰油基葡糖苷3份,偶联剂5份,增塑剂55份,稳定剂1份,发泡剂2份。
其中,偶联剂为铝酸酯偶联剂和硅烷偶联剂的混合物;增塑剂为DOTP与氯化芳烃油质量比为3:5的混合物;稳定剂为柠檬酸稀土;发泡剂为AC发泡剂。
该阻燃PVC壁纸用复合材料的制备方法,包括以下步骤:
(1)将水滑石放入研磨机中,研磨25min,之后向其中滴加椰油基葡糖苷的水溶液,滴加完成后,继续研磨45min,取出烘干,制得改性水滑石粉末;
(2)将PVC树脂和增塑剂混合均匀,之后加入纳米结晶纤维素,壳聚糖和聚磷酸铵,在50℃条件下搅拌混合均匀,之后依次加入偶联剂,改性水滑石粉末,稳定剂和发泡剂继续搅拌均匀,制得阻燃PVC壁纸用复合材料。
使用制得的阻燃PVC壁纸用复合材料以无纺布为基纸制备壁纸,测得其极限氧指数为44.1%,并且该壁纸长时间使用后仍能保持良好的性状。

Claims (6)

1.一种阻燃PVC壁纸用复合材料,其特征在于:以重量份计,包括以下组分:
PVC树脂100份;纳米结晶纤维素10-17份,壳聚糖9-14份,聚磷酸铵20-35份,水滑石5-9份,椰油基葡糖苷2-5份,偶联剂3-7份,增塑剂50-60份,稳定剂1-2份,发泡剂1-2份。
2.根据权利要求1所述的阻燃PVC壁纸用复合材料,其特征在于:所述偶联剂为铝酸酯偶联剂和硅烷偶联剂的混合物。
3.根据权利要求1所述的阻燃PVC壁纸用复合材料,其特征在于:所述增塑剂为DOTP与氯化芳烃油质量比为3:5的混合物。
4.根据权利要求1所述的阻燃PVC壁纸用复合材料,其特征在于:所述稳定剂为柠檬酸稀土。
5.根据权利要求1所述的阻燃PVC壁纸用复合材料,其特征在于:所述发泡剂为AC发泡剂。
6.一种阻燃PVC壁纸用复合材料的制备方法,其特征在于,包括以下步骤:
(1)将水滑石放入研磨机中,研磨20-30min,之后向其中滴加椰油基葡糖苷的水溶液,滴加完成后,继续研磨30-45min,取出烘干,制得改性水滑石粉末;
(2)将PVC树脂和增塑剂混合均匀,之后加入纳米结晶纤维素,壳聚糖和聚磷酸铵,在40-60℃条件下搅拌混合均匀,之后依次加入偶联剂,改性水滑石粉末,稳定剂和发泡剂继续搅拌均匀,制得阻燃PVC壁纸用复合材料。
CN201710469802.0A 2017-06-20 2017-06-20 一种阻燃pvc壁纸用复合材料及其制备方法 Withdrawn CN107236213A (zh)

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CN114411422A (zh) * 2022-03-02 2022-04-29 杭州萧山正达纺织有限公司 一种耐高温阻燃复合面料及其制备方法
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