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CN106311183A - Filter material for sewage treatment and preparation method thereof - Google Patents

Filter material for sewage treatment and preparation method thereof Download PDF

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Publication number
CN106311183A
CN106311183A CN201610915752.XA CN201610915752A CN106311183A CN 106311183 A CN106311183 A CN 106311183A CN 201610915752 A CN201610915752 A CN 201610915752A CN 106311183 A CN106311183 A CN 106311183A
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Prior art keywords
parts
activated carbon
filtering material
sewage disposal
preparation
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Inventor
刘东东
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Zhengzhou Yuanran Biology Technology Co Ltd
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Zhengzhou Yuanran Biology Technology Co Ltd
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Priority to CN201610915752.XA priority Critical patent/CN106311183A/en
Publication of CN106311183A publication Critical patent/CN106311183A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/043Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/045Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing sulfur, e.g. sulfates, thiosulfates, gypsum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12Naturally occurring clays or bleaching earth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26Synthetic macromolecular compounds
    • B01J20/262Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon to carbon unsaturated bonds, e.g. obtained by polycondensation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Water Treatment By Sorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a filter material for sewage treatment and a preparation method thereof. The filter material for sewage treatment contains the following main raw materials in parts by weight: 7-11 parts of styrene sulfonic acid, 20-30 parts of silica gel, 8-20 parts of polyacrylamide, 5-8 parts of dimethyl malonate, 7-14 parts of azodicarbonamide, 10-18 parts of nano modified activated carbon, 10-15 parts of medical stone, 5-8 parts of straw fibers, 2-6 parts of alums, and 0.8-2.0 parts of calcium carbonate. The method for preparing the nano modified activated carbon comprises the following steps: performing hybrid modification on bamboo charcoal and titanium dioxide, adding polyepichlorohydrin and ethyl acetate, stirring, and drying, thereby obtaining the product. According to the invention, the physical and chemical indicators of sewage which is severely contaminated can reach the standard GB 18918-2002; the treatment process is simple, the dosage is small, the treatment effect is good, the performance is stable, the recovery degree of the contaminated sewage is high, the cost of treatment agents can be effectively reduced, and the filter material has excellent economic benefits and wide social benefits.

Description

A kind of filtering material for sewage disposal and preparation method thereof
Technical field
The present invention relates to a kind of Technology of Sewage field, a kind of filtering material for sewage disposal and preparation side thereof Method.
Background technology
The industrial development in last century, population increase.Cause the drastically deterioration of current environment.Enter 21 century, facing mankind Many crises, shortage of water resources is the biggest crisis of facing mankind.Water scarcity aggravates, and water pollution problems is day by day serious not Threaten the mankind disconnectedly.In order to solve this crisis, it is pure to obtain that various countries scientist finds effective method and approach one after another Water resource.Desalinization and sewage disposal recycling are two effective methods.The most existing many countries are light by sea water Change technology obtains pure drinking water and domestic water.Thus part solves water resources crisis.If but it is dirty not solve water Dye problem, along with water pollutes aggravation, has one day sea water also can be contaminated eventually.The mankind will not see the big of vastness more at that time Sea, existence is on the hazard, the memory the finest by becoming the mankind of swimming.So, it is crucial for solving water pollution problems, is to take stopgap measures it This.Find a kind of effective water technology and become the heat subject of current scientists study.For processing the side of waste water Method has a variety of, and main active charcoal facture, aeration, Anaerobic biotreatment method, embrane method, chemical oxidation treatment method and light are urged Change oxidizing treatment etc..But all there is certain difficulty, treatment effect when these persistent organic pollutants of actual treatment The most undesirable.Therefore, seek a kind of filtering material economic, effective with these pollutant of degrading, become various countries' environmental science work The research topic that author pays much attention to.
Summary of the invention
It is an object of the invention to provide a kind of filtering material for sewage disposal and preparation method thereof, above-mentioned to solve The problem proposed in background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of filtering material for sewage disposal, according to the primary raw material of weight portion be: styrene sulfonic acid 7-11 part, silicon Glue 20-30 part, polyacrylamide 8-20 part, dimethyl malenate 5-8 part, azodicarbonamide 7-14 part, nano modification activity Charcoal 10-18 part, Maifanitum 10-15 part, stalk fibre 5-8 part, Alumen 2-6 part, calcium carbonate 0.8-2.0 part;Described nano modification The preparation method of activated carbon, for carry out mixed and modified by bamboo charcoal, titanium dioxide, adds Hydrin and ethyl acetate subsequently, After stirring and drying and get final product.
As the further scheme of the present invention: the described filtering material for sewage disposal, the most former according to weight portion Material is: styrene sulfonic acid 8-10 part, silica gel 22-27 part, polyacrylamide 12-17 part, dimethyl malenate 5-8 part, azo two Methanamide 9-11 part, nano modification activated carbon 12-16 part, Maifanitum 10-15 part, stalk fibre 5-8 part, Alumen 2-6 part, carbonic acid Calcium 1.3-1.6 part;The preparation method of described nano modification activated carbon, for carry out mixed and modified by bamboo charcoal, titanium dioxide, adds subsequently Add Hydrin and ethyl acetate, after stirring and drying and get final product.
As the further scheme of the present invention: the described filtering material for sewage disposal, the most former according to weight portion Material is: styrene sulfonic acid 9 parts, 25 parts of silica gel, polyacrylamide 15 parts, dimethyl malenate 7 parts, azodicarbonamide 10 parts, Nano modification activated carbon 14 parts, Maifanitum 13 parts, stalk fibre 7 parts, 4 parts of Alumen, calcium carbonate 1.5 parts;Described nano modification is lived Property charcoal preparation method for bamboo charcoal, titanium dioxide are carried out mixed and modified, add Hydrin and ethyl acetate subsequently, stir After mixing drying and get final product.
The preparation method of a kind of filtering material for sewage disposal, concretely comprises the following steps:
(1) first, by styrene sulfonic acid, silica gel, polyacrylamide, dimethyl malenate, azodicarbonamide mixing, put Put in reactor, filter after heat treatment and prepare high molecular nanometer sphere;
(2) then, high molecular nanometer sphere is mixed with nano modification activated carbon, Maifanitum, stalk fibre, Alumen, calcium carbonate Closing uniformly, be then used by sonic oscillation and process, the power that sonic oscillation processes is 800W, and the time is 70 minutes, is placed in 4 DEG C of temperature Lower oven drying at low temperature pelletize, obtains the filtering material for sewage disposal.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention can make the physical and chemical index being stained significantly sewage reach GB18918-2002 standard;The letter of process technique Single, dosage is few, and treatment effect is good, stable performance, and contaminated sewage recovery extent is high, can significantly reduce inorganic agent Cost, there is good economic benefit and social benefit widely.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under not making creative work premise, all Belong to the scope of protection of the invention.
Embodiment 1
A kind of filtering material for sewage disposal, according to the primary raw material of weight portion be: styrene sulfonic acid 7 parts, silica gel 20 parts, polyacrylamide 8 parts, dimethyl malenate 5 parts, azodicarbonamide 7 parts, nano modification activated carbon 10 parts, Maifanitum 10 parts, stalk fibre 5 parts, 2 parts of Alumen, calcium carbonate 0.8 part;The preparation method of described nano modification activated carbon be by bamboo charcoal, two Titanium oxide carries out mixed and modified, adds Hydrin and ethyl acetate subsequently, after stirring and drying and get final product.
The preparation method of a kind of filtering material for sewage disposal, concretely comprises the following steps:
(1) first, by styrene sulfonic acid, silica gel, polyacrylamide, dimethyl malenate, azodicarbonamide mixing, put Put in reactor, filter after heat treatment and prepare high molecular nanometer sphere;
(2) then, high molecular nanometer sphere is mixed with nano modification activated carbon, Maifanitum, stalk fibre, Alumen, calcium carbonate Closing uniformly, be then used by sonic oscillation and process, the power that sonic oscillation processes is 800W, and the time is 70 minutes, is placed in 4 DEG C of temperature Lower oven drying at low temperature pelletize, obtains the filtering material for sewage disposal.
Embodiment 2
A kind of filtering material for sewage disposal, according to the primary raw material of weight portion be: styrene sulfonic acid 8 parts, silica gel 22 parts, polyacrylamide 12 parts, dimethyl malenate 5 parts, azodicarbonamide 9 parts, nano modification activated carbon 12 parts, Maifanitum 10 parts, stalk fibre 5 parts, 2 parts of Alumen, calcium carbonate 1.3 parts;The preparation method of described nano modification activated carbon be by bamboo charcoal, two Titanium oxide carries out mixed and modified, adds Hydrin and ethyl acetate subsequently, after stirring and drying and get final product.
The preparation method of a kind of filtering material for sewage disposal, concretely comprises the following steps:
(1) first, by styrene sulfonic acid, silica gel, polyacrylamide, dimethyl malenate, azodicarbonamide mixing, put Put in reactor, filter after heat treatment and prepare high molecular nanometer sphere;
(2) then, high molecular nanometer sphere is mixed with nano modification activated carbon, Maifanitum, stalk fibre, Alumen, calcium carbonate Closing uniformly, be then used by sonic oscillation and process, the power that sonic oscillation processes is 800W, and the time is 70 minutes, is placed in 4 DEG C of temperature Lower oven drying at low temperature pelletize, obtains the filtering material for sewage disposal.
Embodiment 3
A kind of filtering material for sewage disposal, according to the primary raw material of weight portion be: styrene sulfonic acid 9 parts, silica gel 25 parts, polyacrylamide 15 parts, dimethyl malenate 7 parts, azodicarbonamide 10 parts, nano modification activated carbon 14 parts, wheat meal 13 parts of stone, stalk fibre 7 parts, 4 parts of Alumen, calcium carbonate 1.5 parts;The preparation method of described nano modification activated carbon be by bamboo charcoal, Titanium dioxide carries out mixed and modified, adds Hydrin and ethyl acetate subsequently, after stirring and drying and get final product.
The preparation method of a kind of filtering material for sewage disposal, concretely comprises the following steps:
(1) first, by styrene sulfonic acid, silica gel, polyacrylamide, dimethyl malenate, azodicarbonamide mixing, put Put in reactor, filter after heat treatment and prepare high molecular nanometer sphere;
(2) then, high molecular nanometer sphere is mixed with nano modification activated carbon, Maifanitum, stalk fibre, Alumen, calcium carbonate Closing uniformly, be then used by sonic oscillation and process, the power that sonic oscillation processes is 800W, and the time is 70 minutes, is placed in 4 DEG C of temperature Lower oven drying at low temperature pelletize, obtains the filtering material for sewage disposal.
Embodiment 4
A kind of filtering material for sewage disposal, according to the primary raw material of weight portion be: styrene sulfonic acid 10 parts, silica gel 27 parts, polyacrylamide 17 parts, dimethyl malenate 8 parts, azodicarbonamide 11 parts, nano modification activated carbon 16 parts, wheat meal 15 parts of stone, stalk fibre 8 parts, 6 parts of Alumen, calcium carbonate 1.6 parts;The preparation method of described nano modification activated carbon be by bamboo charcoal, Titanium dioxide carries out mixed and modified, adds Hydrin and ethyl acetate subsequently, after stirring and drying and get final product.
The preparation method of a kind of filtering material for sewage disposal, concretely comprises the following steps:
(1) first, by styrene sulfonic acid, silica gel, polyacrylamide, dimethyl malenate, azodicarbonamide mixing, put Put in reactor, filter after heat treatment and prepare high molecular nanometer sphere;
(2) then, high molecular nanometer sphere is mixed with nano modification activated carbon, Maifanitum, stalk fibre, Alumen, calcium carbonate Closing uniformly, be then used by sonic oscillation and process, the power that sonic oscillation processes is 800W, and the time is 70 minutes, is placed in 4 DEG C of temperature Lower oven drying at low temperature pelletize, obtains the filtering material for sewage disposal.
Embodiment 5
A kind of filtering material for sewage disposal, according to the primary raw material of weight portion be: styrene sulfonic acid 11 parts, silica gel 30 parts, polyacrylamide 20 parts, dimethyl malenate 8 parts, azodicarbonamide 14 parts, nano modification activated carbon 18 parts, wheat meal 15 parts of stone, stalk fibre 8 parts, 6 parts of Alumen, calcium carbonate 2.0 parts;The preparation method of described nano modification activated carbon be by bamboo charcoal, Titanium dioxide carries out mixed and modified, adds Hydrin and ethyl acetate subsequently, after stirring and drying and get final product.
The preparation method of a kind of filtering material for sewage disposal, concretely comprises the following steps:
(1) first, by styrene sulfonic acid, silica gel, polyacrylamide, dimethyl malenate, azodicarbonamide mixing, put Put in reactor, filter after heat treatment and prepare high molecular nanometer sphere;
(2) then, high molecular nanometer sphere is mixed with nano modification activated carbon, Maifanitum, stalk fibre, Alumen, calcium carbonate Closing uniformly, be then used by sonic oscillation and process, the power that sonic oscillation processes is 800W, and the time is 70 minutes, is placed in 4 DEG C of temperature Lower oven drying at low temperature pelletize, obtains the filtering material for sewage disposal.
Comparative example 1
A kind of filtering material for sewage disposal, according to the primary raw material of weight portion be: styrene sulfonic acid 9 parts, silica gel 25 parts, polyacrylamide 15 parts, dimethyl malenate 7 parts, azodicarbonamide 10 parts, nano modification activated carbon 14 parts, wheat meal 13 parts of stone, stalk fibre 7 parts, 4 parts of Alumen, calcium carbonate 1.5 parts;The preparation method of described nano modification activated carbon be by bamboo charcoal, Titanium dioxide carries out mixed and modified, adds Hydrin and ethyl acetate subsequently, after stirring and drying and get final product.
The preparation method of a kind of filtering material for sewage disposal, concretely comprises the following steps:
(1) first, by styrene sulfonic acid, silica gel, polyacrylamide, dimethyl malenate, azodicarbonamide mixing, put Put in reactor, filter after heat treatment and prepare high molecular nanometer sphere;
(2) then, high molecular nanometer sphere is mixed with nano modification activated carbon, Maifanitum, stalk fibre, Alumen, calcium carbonate Close uniformly, obtain the filtering material for sewage disposal after drying.
Comparative example 2
A kind of filtering material for sewage disposal, according to the primary raw material of weight portion be: styrene sulfonic acid 9 parts, silica gel 25 parts, polyacrylamide 15 parts, nano modification activated carbon 14 parts, Maifanitum 13 parts, calcium carbonate 1.5 parts;Described nano modification is lived Property charcoal preparation method for bamboo charcoal, titanium dioxide are carried out mixed and modified, add Hydrin and ethyl acetate subsequently, stir After mixing drying and get final product.
The preparation method of a kind of filtering material for sewage disposal, concretely comprises the following steps:
(1) first, by styrene sulfonic acid, silica gel, polyacrylamide mixing, in placing response still, filter after heat treatment and prepare High molecular nanometer sphere;
(2) then, high molecular nanometer sphere is mixed homogeneously with nano modification activated carbon, Maifanitum, Alumen, calcium carbonate, connects Use sonic oscillation to process, the power that sonic oscillation processes is 800W, and the time is 70 minutes, and at a temperature of being placed in 4 DEG C, low temperature dries Dry pelletize, obtains the filtering material for sewage disposal.
Comparative example 3
A kind of filtering material for sewage disposal, according to the primary raw material of weight portion be: 25 parts of silica gel, malonic acid dimethyl Ester 7 parts, azodicarbonamide 10 parts, Maifanitum 13 parts, stalk fibre 7 parts, 4 parts of Alumen, calcium carbonate 1.5 parts;Described nanometer changes Property activated carbon preparation method for bamboo charcoal, titanium dioxide are carried out mixed and modified, add Hydrin and acetic acid second subsequently Ester, after stirring and drying and get final product.
The preparation method of a kind of filtering material for sewage disposal, concretely comprises the following steps:
(1) first, by silica gel, dimethyl malenate, azodicarbonamide mixing, in placing response still, mistake after heat treatment Filter prepares high molecular nanometer sphere;
(2) then, high molecular nanometer sphere is mixed with nano modification activated carbon, Maifanitum, stalk fibre, Alumen, calcium carbonate Closing uniformly, be then used by sonic oscillation and process, the power that sonic oscillation processes is 800W, and the time is 70 minutes, is placed in 4 DEG C of temperature Lower oven drying at low temperature pelletize, obtains the filtering material for sewage disposal.
The filtering material preparing embodiment of the present invention 1-5 and comparative example 1-3 detects, found that embodiment 2 is made The effect that standby filtering material produces is the most obvious, and the filtering material of embodiment 2 preparation is to common heavy metal ion in sewage Adsorption rate reaches 99%, and in sewage, the adsorption rate of common organic pollution reaches 92%.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of the spirit or essential attributes of the present invention, it is possible to realize the present invention in other specific forms.Therefore, no matter From the point of view of which point, all should regard embodiment as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all by fall in the implication of equivalency and scope of claim Change is included in the present invention.
Although moreover, it will be appreciated that this specification is been described by according to embodiment, but the most each embodiment only wraps Containing an independent technical scheme, this narrating mode of description is only that for clarity sake those skilled in the art should Description can also be formed those skilled in the art through appropriately combined as an entirety, the technical scheme in each embodiment May be appreciated other embodiments.

Claims (4)

1. the filtering material for sewage disposal, it is characterised in that according to the primary raw material of weight portion be: styrene sulfonic acid 7-11 part, silica gel 20-30 part, polyacrylamide 8-20 part, dimethyl malenate 5-8 part, azodicarbonamide 7-14 part, nanometer Modified activated carbon 10-18 part, Maifanitum 10-15 part, stalk fibre 5-8 part, Alumen 2-6 part, calcium carbonate 0.8-2.0 part;Described The preparation method of nano modification activated carbon for bamboo charcoal, titanium dioxide are carried out mixed and modified, subsequently add Hydrin and Ethyl acetate, after stirring and drying and get final product.
Filtering material for sewage disposal the most according to claim 1, it is characterised in that described for sewage disposal Filtering material, according to the primary raw material of weight portion be: styrene sulfonic acid 8-10 part, silica gel 22-27 part, polyacrylamide 12-17 Part, dimethyl malenate 5-8 part, azodicarbonamide 9-11 part, nano modification activated carbon 12-16 part, Maifanitum 10-15 part, Stalk fibre 5-8 part, Alumen 2-6 part, calcium carbonate 1.3-1.6 part;The preparation method of described nano modification activated carbon be by bamboo charcoal, Titanium dioxide carries out mixed and modified, adds Hydrin and ethyl acetate subsequently, after stirring and drying and get final product.
Filtering material for sewage disposal the most according to claim 1 and 2, it is characterised in that described at sewage Reason filtering material, according to the primary raw material of weight portion be: styrene sulfonic acid 9 parts, 25 parts of silica gel, polyacrylamide 15 parts, third Acid dimethyl 7 parts, azodicarbonamide 10 parts, nano modification activated carbon 14 parts, Maifanitum 13 parts, stalk fibre 7 parts, Alumen 4 parts, calcium carbonate 1.5 parts;The preparation method of described nano modification activated carbon for bamboo charcoal, titanium dioxide are carried out mixed and modified, with Rear interpolation Hydrin and ethyl acetate, after stirring and drying and get final product.
4. the preparation method of the filtering material for sewage disposal as described in claim 1-3 is arbitrary, it is characterised in that Concretely comprise the following steps:
(1) first, by styrene sulfonic acid, silica gel, polyacrylamide, dimethyl malenate, azodicarbonamide mixing, place anti- Answer in still, filter after heat treatment and prepare high molecular nanometer sphere;
(2) then, high molecular nanometer sphere is mixed all with nano modification activated carbon, Maifanitum, stalk fibre, Alumen, calcium carbonate Even, it is then used by sonic oscillation and processes, the power that sonic oscillation processes is 800W, and the time is 70 minutes, low at a temperature of being placed in 4 DEG C Temperature dries pelletize, obtains the filtering material for sewage disposal.
CN201610915752.XA 2016-10-20 2016-10-20 Filter material for sewage treatment and preparation method thereof Pending CN106311183A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111212567A (en) * 2017-08-01 2020-05-29 因思特艾克申有限公司 Removal of bacteria from drinking water by filtration

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000042535A (en) * 1998-07-24 2000-02-15 Sanyo Chem Ind Ltd Water treating agent and treatment of water
CN103506090A (en) * 2013-08-30 2014-01-15 蚌埠德美过滤技术有限公司 Modified active carbon water treatment absorbent and preparation method thereof
CN105001614A (en) * 2015-06-30 2015-10-28 苏州博利迈新材料科技有限公司 Heavy metal filtering nanometer membrane for waste water and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000042535A (en) * 1998-07-24 2000-02-15 Sanyo Chem Ind Ltd Water treating agent and treatment of water
CN103506090A (en) * 2013-08-30 2014-01-15 蚌埠德美过滤技术有限公司 Modified active carbon water treatment absorbent and preparation method thereof
CN105001614A (en) * 2015-06-30 2015-10-28 苏州博利迈新材料科技有限公司 Heavy metal filtering nanometer membrane for waste water and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
戈贤平主编: "《无公害淡水虾标准化生产》", 31 January 2006 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111212567A (en) * 2017-08-01 2020-05-29 因思特艾克申有限公司 Removal of bacteria from drinking water by filtration

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