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CN106232262B - Single crystal casting mold - Google Patents

Single crystal casting mold Download PDF

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Publication number
CN106232262B
CN106232262B CN201580021383.3A CN201580021383A CN106232262B CN 106232262 B CN106232262 B CN 106232262B CN 201580021383 A CN201580021383 A CN 201580021383A CN 106232262 B CN106232262 B CN 106232262B
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CN
China
Prior art keywords
mold
volume
mold cavity
model
crystal grain
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Active
Application number
CN201580021383.3A
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Chinese (zh)
Other versions
CN106232262A (en
Inventor
瑟奇·法格斯
多米尼克·科依兹
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Safran Aircraft Engines SAS
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Safran Aircraft Engines SAS
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Publication date
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Publication of CN106232262A publication Critical patent/CN106232262A/en
Application granted granted Critical
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns
    • B22C9/043Removing the consumable pattern
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C3/00Selection of compositions for coating the surfaces of moulds, cores, or patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C7/00Patterns; Manufacture thereof so far as not provided for in other classes
    • B22C7/02Lost patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/22Moulds for peculiarly-shaped castings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D18/00Pressure casting; Vacuum casting
    • B22D18/06Vacuum casting, i.e. making use of vacuum to fill the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D25/00Special casting characterised by the nature of the product
    • B22D25/02Special casting characterised by the nature of the product by its peculiarity of shape; of works of art
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • B22D27/045Directionally solidified castings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D29/00Removing castings from moulds, not restricted to casting processes covered by a single main group; Removing cores; Handling ingots
    • CCHEMISTRY; METALLURGY
    • C30CRYSTAL GROWTH
    • C30BSINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
    • C30B21/00Unidirectional solidification of eutectic materials
    • C30B21/02Unidirectional solidification of eutectic materials by normal casting or gradient freezing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01DNON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
    • F01D5/00Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
    • F01D5/12Blades

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)

Abstract

The present invention relates to single crystal casting field more particularly to a kind of molds (1) for single crystal casting, further relate to manufacture and use the mold.Particularly, mold (1) includes mold cavity (7), which includes the first volume (7a), the second volume (7b) and crystal grain conduit (4).Second volume (7b) is located in the first volume (7a) and communicates therewith, and including at least one horizontal protrusion relative to the first volume (7a).Crystal grain conduit (4) has the lower end (4a) connecting with the first volume (7a), and the upper end (4b) adjacent with the horizontal protrusion of the second volume (7b).Mold (1) further includes the partition member (11) being inserted between the second volume (7b) of mold cavity (7) and the upper end (4b) of crystal grain conduit (4).

Description

Single crystal casting mold
Background technique
The present invention relates to casting field, the more particularly, to model of lost pattern casting, further relate to manufacture shell mold method and The method cast using such as model.
In the following description, term " on ", "lower", "horizontal" and " vertical " are relative to just in the mold of casting metal Be generally oriented restriction.
So-called " dewaxing " casting or " losing mould " casting are widely known.They are complex-shaped particularly suitable for producing Metalwork.Therefore, lost pattern casting method is particularly used to manufacture turbine blade.
In lost pattern casting, the first step is usually the material for using fusion temperature relatively low, such as wax or resin manufacture mould Tool.Mold itself is covered with refractory material, to form mold, especially shell mold formula mold.Material model be emptied or from Here it is the name origin-of " losing mould " method for mould inside removing-later, molten metal is poured into mold, to fill The type chamber left after model is emptied or removes in mold.Once mold can be opened or be destroyed to metal cooled and solidified To regain the metalwork with mold shape.In the present context, term " metal " includes pure metal, and especially golden Belong to alloy.
It can be single cluster by multiple models couplings, wherein model passes through axis in order to manufacture multiple components simultaneously It links together, which forms the casting channel for molten metal in a mold.
In all kinds of molds that can be used in lost pattern casting, it is known that so-called " shell " mould is formed in the following manner: Model or model cluster are immersed in slurry, next dusted with fire sand to the model or cluster that are covered with slurry, from And shell is formed around model or cluster, then shell is toasted, to make its sintering integrally to reinforce shell. It is contemplated that continuous several times are impregnated and are dusted, to obtain the shell with adequate thickness before baking.Term " fire resisting For sand " in the present context for specifying any grain material, the granularity of the grain material is fine enough to production needed for satisfaction Tolerance, and the temperature of molten metal can be born in the solid state, while can also be merged, thus the shape when being toasted to shell At single piece.
In order to make Foundry Production component obtain particularly advantageous thermo-mechanical property, it is ensured that it is solidifying that metal receives orientation in a mold Admittedly being desirable.In the present context, term " directional solidification ", which is meant, converts with molten metal from liquid, is controlling Under, solid crystals are seeded in molten metal and grow in the molten metal.The purpose of directional solidification is to avoid crystalline substance in component The negative effect on boundary.Therefore, directional solidification can occur in column, or can be monocrystalline.Directional solidification in each column It is in same direction to orient all grain boundaries, therefore they cannot facilitate crack propagation.Monocrystalline directional solidification is to ensure that portion Part is as single crystalline solidification, to eliminate all grain boundaries.
To obtain monocrystalline directional solidification, mold provides " starting " type chamber usually in mold cavity, and it is logical to be somebody's turn to do " starting " type chamber It crosses selector channel to connect with mold cavity, for example, this is disclosed in French Patent (FRP) FR2734189.When metal in a mold While solidification, since start type chamber, mold is gradually cooled down, and is seeded in start type chamber so as to cause crystal.Selection is logical The effect in road is to give priority to single crystal grain first, the crystallization for the crystal grain for followed by enabling single crystal grain sow from start type chamber Advance towards mold cavity in forward position.
Clumsy shape in mold cavity, which may be constituted directional solidification, to be hindered.Therefore, greater level protrusion (spy is being presented Be not protrusion corresponding with the platform of turbine blade) mold cavity in, solidification front may stop at suddenly substantially hang down Histogram advances up, and may advance along projection direction.Suddenly change on this direction can be led in the place close to protrusion Defect is caused, unwanted crystal grain is particularly resulted in.
In order to avoid the problem, those skilled in the art utilize crystal grain conduit, and the effect of crystal grain conduit is for solidification front The backup path of horizontal protrusion in mold cavity is provided, and is realized in the case where not swerving.However, brilliant One of grain conduit is the disadvantage is that it makes mold more be difficult to knock out, and metal material solidification is formed by gold especially in crystal grain conduit Belong to branch next to need to remove from rough casting, therefore increases complicated and expensive finishing steps.
Summary of the invention
The present invention seeks to make up these defects, proposes a kind of single crystal casting mold, is used to form with larger lateral prominent The component risen, while also promoting being followed by subsequent processing for rough casting.
In at least one embodiment, which realizes that mold cavity includes: first by the mold with mold cavity Volume;Second volume, second volume are located in first volume and communicate therewith, and have relative to first volume At least one horizontal protrusion;And crystal grain conduit, the lower end of the crystal grain conduit are connect with first volume, upper end is adjacent to institute The horizontal protrusion of the second volume is stated, the mold further includes the second volume for being inserted in the mold cavity and the crystal grain Partition member between the upper end of conduit.
It is arranged by these, the cooling and solidification of metal material can be prominent towards level by die channel in mold cavity It rises and advances, the metal material in horizontal protrusion does not contact directly with the material in crystal grain conduit, therefore is easier to crystal grain conduit The metal branch of formation is separated from the remainder of rough casting.
For the constant advance for ensuring cooling forward position in mold cavity, the width of crystal grain conduit upper end can be with the second volume Horizontal protrusion is essentially equal.
Particularly, which can be used for manufacturing turbine blade, be applied to stationary guide blades and moving vane.For This, the first volume of mold cavity can correspond to turbine blade main body, and the second volume of mold cavity can correspond to whirlpool Turbine blade platform.In the present context, term " turbine " includes that energy shifts between fluid stream and at least one set of blade Any machine, such as compressor, pump, turbine or at least two combination in them.
In order to promote the directional solidification of molten metal material in mold cavity, mold can have below mold cavity Ejector half chamber, the start type chamber are connect by selector channel with mold cavity.
The invention further relates to a kind of methods for manufacturing single crystal casting mold, method includes the following steps: manufacture mould Type, the shape of the model copy mold cavity;The model described in refractory material is to form the mold cavity;And it empties The mold cavity.
It particularly, can be before coating step by the separation structure in order to be easier to merge partition member in a mold Part is inserted into model.Particularly, model can be made of fusion temperature lower than the material of the refractory material, such as wax or tree Rouge, and emptied from mold cavity using so-called " dewaxing " method with liquid.
Particularly, the coating step can execute in the following manner: model be immersed in slurry, with fire sand to mould Type dusts, to form shell around model, and is sintered to shell so that it is reinforced, to form shell mold.
The present invention also provides a kind of methods using mold, this method comprises: by liquid metal material vacuum pressing and casting to mould In tool type chamber;Metal material is caused to solidify with oriented approach from mold cavity bottom towards top;And mold is knocked out, including insertion Partition member between the second volume and crystal grain conduit upper end of mold cavity.In the present context, term " vacuum " should It is interpreted as the pressure more much lower than atmospheric pressure, especially less than 0.1 Pascal (Pa) to 0.01Pa.It is knocked out in mold Afterwards, the rough casting formed by metal material solidified in mold cavity can receive additional treatments, exist especially for separation The metal material branch solidified in crystal grain conduit.
Detailed description of the invention
It is following to the detailed description of the embodiment shown in non-limiting example by reading, it is well understood that this Invention, and advantages of the present invention will be also more clear.Description is with reference to the following drawings, in which:
Fig. 1 is the skeleton diagram of single crystal casting equipment comprising constitutes the mold of one embodiment of the present invention;
Fig. 2 is the perspective view for manufacturing the model of mold shown in Fig. 1;And
Fig. 3,4 and 5 shows cooling progress and solidification front in the casting method executed in equipment shown in Fig. 1.
Specific embodiment
Fig. 1 illustrates how that carry out gradual cooling to molten metal typically in casting method coagulates to obtain orientation Gu.
Mold 1 used in this method includes sprue cup 5 and pedestal 6.When mold 1 from heating chamber 3 extract out when, pedestal 6 with Bottom plate 2 directly contacts.Mold 1 also has mold cavity 7.Multiple mould types can also be arranged with trunking mode in equal dies Chamber.Mold cavity 7 is connect by feeding-passage 8 with sprue cup 5, and when toppling over molten metal, molten metal passes through feeding-passage 8.Mold cavity 7 is general also to be connect by baffle shape selector channel 9 with the smaller start type chamber 10 in pedestal 6 in bottom.Institute Show in embodiment, mold cavity 7 has a first volume 7a and the second volume 7b, the second volume 7b be located at the first volume 7a just on Side simultaneously communicates therewith, while substantially wider in a horizontal plane, to have at least one very aobvious relative to the first volume 7a The horizontal protrusion of work.More specifically, in the illustrated embodiment, mold 1 is for manufacturing turbine blade.Therefore, the first volume 7a corresponds to blade body, and the second volume 7b corresponds to bucket platform.
Mold cavity 7 also has crystal grain conduit 4, and the lower end 4a of crystal grain conduit 4 is directly connect with the first volume 7a, upper end 4b The horizontal protrusion of neighbouring second volume 7b.In said embodiment, upper end 4b is wider than the remainder of crystal grain conduit 4, thus The horizontal protrusion of neighbouring second volume 7b on the entire width L of the second volume 7b.Although adjacent, crystal grain conduit 4 it is upper End 4b and the second volume 7b is not connected to directly, because they are separated by rod partition member 11.
For example, partition member 11 can be made of ceramic materials.Although in the illustrated embodiment, its form is Cylindrical bar with circular cross section, but depend on the circumstances, it can be using other cross sections and other general shapes.Bar material Size and thermal conductivity can choose as in the adjacent water of the upper end 4b of crystal grain conduit 4 and the second volume 7b of mold cavity 7 Good thermo-contact is provided between flat protrusion.
Mold 1 can be manufactured by so-called " dewaxing " method or " losing mould " method.The first step of the method is formed such as Fig. 2 institute The model 12 shown.It is logical that model 12 is used to form mold cavity 7 and start type chamber 10, selector channel 9, sprue cup 5, and charging Road 8, they are hollow in mold 1.Model is obtained using low melting material, such as suitable wax or resin.When needing to give birth to When producing a large amount of components, especially these components can be produced by the way that wax or resin are injected permanent mold.For bolster model 12, It include by refractory material, such as support rod 20 made of ceramics, support rod 20 that it is corresponding with mold cavity 7 in model 12 Main body and its pedestal (not shown) connection corresponding with start type chamber 10.It, can be in order to which support rod 20 to be fixed on model 12 Using the natural adherency of 12 material of model, or utilize suitable adhesive.Also it can use identical mode for partition member 11 are merged into model 12, positioned at the volume of main body corresponding with the upper end 4b of crystal grain conduit 4 and and adjacent to mold cavity 7 Between the corresponding volume of horizontal protrusion of second volume 7b.
In this embodiment, in order to manufacture mold 1 using non-permanent model 12, model 12 is immersed in slurry, so It is dusted afterwards with fire sand to it.These dippings and step of dusting can be repeated several times, until forming shell, the shell around model 12 Body is formed by the sand for being impregnated with slurry of ideal thickness.
Next the model 12 of shell coating is heated to melt, and the low melting point material of model 12 is emptied from enclosure interior Material, while retaining support rod 20 and partition member 11.Next, shell is sintered in the baking procedure of higher temperature, To reinforce fire sand, mold 1 is consequently formed, support rod 20 and partition member 11 are integrally retained in mold 1.
Metal or metal alloy used in the casting method is poured into mold 1 in fusing by sprue cup 5, and is passed through Feeding-passage 8 fills start type chamber 10, selector channel 9 and mold cavity 7.Using metal alloy used in the method it In, particularly including monocrystalline nickel alloy, especially for example: the AM1 and AM3 of SNECMA company;And other alloys, such as C-M group 'sWithGeneral Electric's N6;The RR2000 and SRR99 of Rolls Royce;And the PWA1480 of Pratt&Whitney, 1484 and 1487.Table 1 is shown The component of these alloys.
Table 1: monocrystalline nickel alloy component by weight percentage
In casting, as shown in Figure 1, mold 1 is maintained in heating chamber 3.Hereafter, in order to cause molten metal gradually cold But, along major axis X, from will be supported in heating chamber 3, the mold 1 on cooling movable support member 2 is downward to be proposed.Since mold 1 is logical The pedestal 6 for crossing it is cooling by supporting element 2, and molten metal starts to solidify in start type chamber 10, and works as mold 1 from heating chamber It when being proposed gradually downward in 3, is set in mold 1 and spreads substantially vertically up, as shown in figure 3, solidification is with forward position 50 Occur.In the crystal grain for ensure initially to sow in start type chamber 10 by the choker that selector channel 9 and its baffle shapes are formed only There is one to can continue to extend to mold cavity 7.
As shown in figure 4, in the lower end 4a of crystal grain conduit 4,50 bifurcated of cooled and solidified forward position of metal continues in mold cavity Advance in 7 the first volume 7a, and advances in crystal grain conduit 4.Therefore, which substantially simultaneously approaches First volume 7a of mold cavity 7, the interface between the second volume 7b and the upper end 4b of crystal grain conduit 4.Therefore, because crystal grain is led Heat transfer between the horizontal protrusion of the second volume of the upper end 4b and mold cavity 7 of pipe 4, cooled and solidified forward position 50 can be second Substantially vertical direction of advance is maintained in volume 7b, as shown in figure 5, seemingly the upper end 4b of crystal grain conduit 4 is actually and mold Second volume communication of type chamber 7 is the same.In this way it is avoided that in the second volume 7b the direction of advance suddenly change, the suddenly change Unwanted crystal grain may be generated around the interface between the volume 7a and 7b of mold cavity 7.
Metal is cooling in mold 1 and after solidifying, and can knock out mold, next can be with to discharge metal parts Metal parts is modified by machining and/or surface treatment method.Pass through the upper end 4b and mold cavity of crystal grain conduit 4 Separation between 7 the second volume 7b, knocking out and handling the finishing of component for mold all become obviously to be more easier, because its It is enough to break the singular association between metal parts and metal branch corresponding with crystal grain conduit, so that they be separated.
Although with reference to particular implementation, invention has been described, however, it will be apparent that without departing from it is of the invention by In the case where general range defined by claim, different modifications and variations can be made.In addition, the different implementations being previously mentioned Each feature of mode can combine in Additional embodiments.Therefore, the description and the appended drawings are construed as illustrative, and It is not limiting.

Claims (9)

1. a kind of single crystal casting mold (1) comprising:
Mold cavity (7), the mold cavity include:
First volume (7a);
Second volume (7b), second volume are located on first volume (7a) and communicate therewith, and have relative to described At least one horizontal protrusion of first volume (7a);And
Crystal grain conduit (4), the lower end (4a) of the crystal grain conduit are connect with first volume (7a), upper end (4b) neighbouring described the The horizontal protrusion of two volumes (7b);
The mold (1) is characterized in that it includes the second volume (7b) for being inserted in the mold cavity (7) and the crystal grain Partition member (11) between the upper end (4b) of conduit (4).
2. mold (1) as described in claim 1, wherein the width and described second of the upper end (4b) of the crystal grain conduit (4) The horizontal protrusion of volume (7b) is equal.
3. mold (1) as described in claim 1, wherein the first volume (7a) of the mold cavity (7) corresponds to turbine The second volume (7b) of blade body, the mold cavity (7) corresponds to turbine blade platform.
4. mold (1) as described in claim 1, which has start type chamber (10) further below in the mold cavity (7), The start type chamber is connect by selector channel (9) with the mold cavity (7).
5. method of the one kind for manufacturing the single crystal casting mold (1) as described in one of Claims 1-4, this method includes following Step:
Modeling (12), the shape of the model at least copy mold type chamber (7);
The model described in refractory material (12) is at least to form the mold cavity (7);And
At least empty the mold cavity (7).
6. method as claimed in claim 5, wherein the partition member (11) is inserted into the model before coating step (12) in.
7. method as claimed in claim 5, wherein the model (12) is lower than the material of the refractory material by fusion temperature It is made, and is emptied from the mold cavity (7) with liquid.
8. method as claimed in claim 5, wherein the coating step executes in the following manner: the model (12) are soaked Enter in slurry, dusted with fire sand to the model, to form shell around the model (12), and to the shell Body is sintered so that it is reinforced.
9. the purposes of the single crystal casting mold (1) as described in any one of Claims 1-4, the purposes the following steps are included:
It will be in liquid metal material vacuum pressing and casting to mold cavity (7);
Solidify metal material from the bottom of the mold cavity (7) towards top with oriented approach;And
Knock out the mold (1), including be inserted in the mold cavity the second volume (7b) and the crystal grain conduit (4) it is upper Hold the partition member (11) between (4b).
CN201580021383.3A 2014-04-24 2015-04-17 Single crystal casting mold Active CN106232262B (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1453693A FR3020292B1 (en) 2014-04-24 2014-04-24 MOLD FOR MONOCRYSTALLINE FOUNDRY
FR1453693 2014-04-24
PCT/FR2015/051044 WO2015162362A1 (en) 2014-04-24 2015-04-17 Mould for monocrystalline casting

Publications (2)

Publication Number Publication Date
CN106232262A CN106232262A (en) 2016-12-14
CN106232262B true CN106232262B (en) 2019-03-05

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US (1) US9744587B2 (en)
EP (1) EP3134219B1 (en)
JP (1) JP6526053B2 (en)
CN (1) CN106232262B (en)
FR (1) FR3020292B1 (en)
RU (1) RU2686163C2 (en)
WO (1) WO2015162362A1 (en)

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CN110405146B (en) * 2019-08-30 2021-02-05 中国航发动力股份有限公司 Device and method for reinforcing die shell of crystal selector
CN113042713B (en) * 2021-02-26 2023-05-12 贵阳航发精密铸造有限公司 Seeding structure of large-size or multi-connected single-crystal guide blade and manufacturing device
CN115889687B (en) * 2022-11-09 2024-05-17 中国航发沈阳黎明航空发动机有限责任公司 Wax mould combination method for single crystal conjuncted guide vane air inlet edge seeding
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FR2734189A1 (en) * 1989-05-24 1996-11-22 Snecma Compact selector for single crystal growth used esp. for casting single crystal superalloy turbine vane
US4940073A (en) * 1989-07-19 1990-07-10 Pcc Airfoils, Inc. Mold for casting a single crystal metal article
US5404930A (en) * 1994-01-06 1995-04-11 Pcc Airfoils, Inc. Method and apparatus for casting an airfoil
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EP1894647A1 (en) * 2006-08-29 2008-03-05 Snecma Method of producing monocrystalline seeds simultaneously when casting monocrystalline parts
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