CN105967357B - A kind of water circulation system antisludging agent - Google Patents
A kind of water circulation system antisludging agent Download PDFInfo
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- CN105967357B CN105967357B CN201610353703.1A CN201610353703A CN105967357B CN 105967357 B CN105967357 B CN 105967357B CN 201610353703 A CN201610353703 A CN 201610353703A CN 105967357 B CN105967357 B CN 105967357B
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- circulation system
- water circulation
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- antisludging agent
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
- C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
- C02F5/12—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/22—Eliminating or preventing deposits, scale removal, scale prevention
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention discloses a kind of water circulation system antisludging agents, belong to field of combustion technology.Water circulation system antisludging agent provided by the invention can quickly remove the dirt in water circulation system, wherein most reach 23min fastly, it can be clean by the dirt removal in water circulation system, scale effect can be played for a long time simultaneously, longest can achieve 178 days scale inhibition effects, the utilization efficiency of water circulation system can be greatly improved, so that improving production efficiency reduces equipment operation maintenance cost.
Description
Technical field
The present invention relates to a kind of water circulation system antisludging agents, belong to field of combustion technology.
Background technique
Steam power plant is industrial water rich and influential family, and circulating cooling system water consumption accounts for about the 70%-80% of total water consumption, is utilized
Make-up water source of the recycled water as its circulating cooling system can greatly reduce the use of conventional source water, and realization is extensive water-saving,
Therefore circulating water cooling treatment work is carried out, the cost of electricity-generating of Thermal Power Enterprises can be greatly reduced.
Corrosion inhibiting and descaling agent is a kind of hydrologic cycle cooling system commonly water treatment agent, for alleviating recirculated water for circulation
The corrosion and scaling of the equipment such as water pump, pipeline, the condenser of cooling system, and then improve heat and power system operational efficiency, extend equipment
Service life, the economic benefit for improving Thermal Power Enterprises.Currently used corrosion inhibiting and descaling agent component is excessively single, hard when recycled water
When degree, basicity, chloride ion content are higher, difficulty reaches good anticorrosion-antiscaling effect, is unable to satisfy wanting for circulation operation
It asks.
Summary of the invention
The problem to be solved in the present invention is to provide a kind of water circulation system antisludging agents, count in mass ratio, by following components group
At: 25-30 parts of phytic acid, 10-15 parts of triethanolamine sodium sulfonate, 10-15 parts of oxalic acid, 3-6 parts of methanol, 3-8 parts of ascorbic acid, 3 times
In the water of aforementioned component gross mass.
In one embodiment of the invention, the water circulation system antisludging agent, is counted in mass ratio, by following components group
At: 25 parts of phytic acid, 10 parts of triethanolamine sodium sulfonate, 12 parts of oxalic acid, 5 parts of methanol, 3 parts of ascorbic acid.
In one embodiment of the invention, the water circulation system antisludging agent, is counted in mass ratio, by following components group
At: 30 parts of phytic acid, 12 parts of triethanolamine sodium sulfonate, 15 parts of oxalic acid, 6 parts of methanol, 8 parts of ascorbic acid.
In one embodiment of the invention, the water circulation system antisludging agent, is counted in mass ratio, by following components group
At: 27 parts of phytic acid, 15 parts of triethanolamine sodium sulfonate, 10 parts of oxalic acid, 3 parts of methanol, 6 parts of ascorbic acid.
The water circulation system includes boiler.
The present invention also provides a kind of methods for preparing the water circulation system antisludging agent, mainly comprise the steps that
(1) each component is weighed in proportion,
(2) using the water for being three times in component gross mass as solvent, 50 DEG C or so are heated to, sequentially adds phytic acid, triethanolamine
Sodium sulfonate, oxalic acid, methanol, ascorbic acid, stir evenly；
(3) cooled to room temperature stands 1-1.5h, obtains the water circulation system antisludging agent.
Water circulation system antisludging agent provided by the invention can quickly remove the dirt in water circulation system, wherein most reaching fastly
To 23min, so that it may the dirt removal in water circulation system is clean, while scale effect can be played for a long time, longest can
To reach 178 days scale inhibition effects, the utilization efficiency of water circulation system can be greatly improved, is set to improve production efficiency reduction
Received shipment seeks maintenance cost.
Specific embodiment
The preparation of 1 antisludging agent of embodiment
The water circulation system antisludging agent, is counted in mass ratio, composed of the following components: 25 parts of phytic acid, triethanolamine sulfonic acid
10 parts of sodium, 12 parts of oxalic acid, 5 parts of methanol, 3 parts of ascorbic acid.
(1) each component is weighed in proportion,
(2) using the water for being three times in component gross mass as solvent, 50 DEG C or so are heated to, sequentially adds phytic acid, triethanolamine
Sodium sulfonate, oxalic acid, methanol, ascorbic acid, stir evenly；
(3) cooled to room temperature stands 1h, obtains the water circulation system antisludging agent.
The preparation of 2 antisludging agent of embodiment
The water circulation system antisludging agent, is counted in mass ratio, composed of the following components: 30 parts of phytic acid, triethanolamine sulfonic acid
12 parts of sodium, 15 parts of oxalic acid, 6 parts of methanol, 8 parts of ascorbic acid.
(1) each component is weighed in proportion,
(2) using the water for being three times in component gross mass as solvent, 50 DEG C or so are heated to, sequentially adds phytic acid, triethanolamine
Sodium sulfonate, oxalic acid, methanol, ascorbic acid, stir evenly；
(3) cooled to room temperature stands 1.5h, obtains the water circulation system antisludging agent.
The preparation of 3 antisludging agent of embodiment
The water circulation system antisludging agent, is counted in mass ratio, composed of the following components: 27 parts of phytic acid, triethanolamine sulfonic acid
15 parts of sodium, 10 parts of oxalic acid, 3 parts of methanol, 6 parts of ascorbic acid.
(1) each component is weighed in proportion,
(2) using the water for being three times in component gross mass as solvent, 50 DEG C or so are heated to, sequentially adds phytic acid, triethanolamine
Sodium sulfonate, oxalic acid, methanol, ascorbic acid, stir evenly；
(3) cooled to room temperature stands 1h, obtains the water circulation system antisludging agent.
The preparation of antisludging agent of the reference examples 1 without phytic acid
The water circulation system antisludging agent, meter includes: 15 parts of triethanolamine sodium sulfonate in mass ratio, and 10 parts of oxalic acid, methanol 3
Part, 6 parts of ascorbic acid.
(1) each component is weighed in proportion,
(2) using the water for being three times in component gross mass as solvent, 50 DEG C or so are heated to, sequentially adds triethanolamine sulfonic acid
Sodium, oxalic acid, methanol, ascorbic acid, stir evenly；
(3) cooled to room temperature stands 1h, obtains the water circulation system antisludging agent.
The preparation of antisludging agent of the reference examples 2 without ascorbic acid
The water circulation system antisludging agent, meter includes: 27 parts of phytic acid in mass ratio, and 15 parts of triethanolamine sodium sulfonate, oxalic acid
10 parts, 3 parts of methanol, 6 parts of ascorbic acid.
(1) each component is weighed in proportion,
(2) using the water for being three times in component gross mass as solvent, 50 DEG C or so are heated to, sequentially adds phytic acid, triethanolamine
Sodium sulfonate, oxalic acid, methanol, ascorbic acid, stir evenly；
(3) cooled to room temperature stands 1h, obtains the water circulation system antisludging agent.
The preparation of 3 antisludging agent of reference examples
The water circulation system antisludging agent, meter includes: 27 parts of phytic acid in mass ratio, and 20 parts of triethanolamine sodium sulfonate, oxalic acid
10 parts, 10 parts of methanol, 6 parts of ascorbic acid.
(1) each component is weighed in proportion,
(2) using the water for being three times in component gross mass as solvent, 50 DEG C or so are heated to, sequentially adds phytic acid, triethanolamine
Sodium sulfonate, oxalic acid, methanol, ascorbic acid, stir evenly；
(3) cooled to room temperature stands 1h, obtains the water circulation system antisludging agent.
Water circulation system scale removal test, water cyclic system are carried out to the water circulation system antisludging agent that above embodiments are prepared
Fouling is 50 DEG C using temperature, carries out circulation scale removal, recycle stream after water circulation system antisludging agent is added in system with a thickness of 3-4mm
Fast 0.5m/s, test result is as shown in table 1 below,
Table 1
| The time required to scale removal (min) | The scale inhibition time (d) after scale removal | |
| Embodiment 1 | 28 | 178 |
| Embodiment 2 | 23 | 174 |
| Embodiment 3 | 26 | 169 |
| Reference examples 1 | 56 | 143 |
| Reference examples 2 | 61 | 122 |
| Reference examples 3 | 48 | 142 |
Although the present invention has been described by way of example and in terms of the preferred embodiments, it is not intended to limit the invention, any to be familiar with this skill
The people of art can do various change and modification, therefore protection model of the invention without departing from the spirit and scope of the present invention
Enclosing subject to the definition of the claims.
Claims (3)
1. a kind of water circulation system antisludging agent, which is characterized in that it counts in mass ratio, composed of the following components: 27 parts of phytic acid, three second
15 parts of hydramine sodium sulfonate, 10 parts of oxalic acid, 3 parts of methanol, 6 parts of ascorbic acid, the water of 3 times of aforementioned component gross masses.
2. a kind of water circulation system antisludging agent according to claim 1, which is characterized in that the water circulation system includes pot
Furnace.
3. a kind of method for preparing a kind of any water circulation system antisludging agent of claim 1-2, mainly includes following step
It is rapid:
(1) each component is weighed in proportion,
(2) using the water for being three times in component gross mass as solvent, 50 DEG C or so are heated to, sequentially adds phytic acid, triethanolamine sulfonic acid
Sodium, oxalic acid, methanol, ascorbic acid, stir evenly；
(3) cooled to room temperature stands 1-1.5h, obtains the water circulation system antisludging agent.
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| CN201610353703.1A CN105967357B (en) | 2016-05-25 | 2016-05-25 | A kind of water circulation system antisludging agent |
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| CN201610353703.1A CN105967357B (en) | 2016-05-25 | 2016-05-25 | A kind of water circulation system antisludging agent |
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| CN105967357B true CN105967357B (en) | 2019-01-29 |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4537684A (en) * | 1983-12-29 | 1985-08-27 | Union Oil Company Of California | Control of metal-containing scale deposition from high temperature brine |
| CN101580310A (en) * | 2009-06-22 | 2009-11-18 | 谢云漫 | Food grade electric kettle scale dissolver and preparation method thereof |
| CN101913713A (en) * | 2010-03-16 | 2010-12-15 | 上海立昌环境工程有限公司 | Sulfate scale cleaning agent |
| CN102131911A (en) * | 2008-09-07 | 2011-07-20 | 朗姆研究公司 | Cleaning solution formulations for substrates |
| CN103469222A (en) * | 2013-09-26 | 2013-12-25 | 宁夏启元国药有限公司 | Descaling agent for water scale of condensing equipment and descaling method |
| CN104058512A (en) * | 2014-06-27 | 2014-09-24 | 无锡市崇安区科技创业服务中心 | Quick boiler scale remover and preparing method thereof |
| CN104651075A (en) * | 2013-11-25 | 2015-05-27 | 刘现梅 | Printed circuit board aqueous cleaning compound |
| CN105585143A (en) * | 2015-12-22 | 2016-05-18 | 天津市尚拓环保科技有限公司 | Scale inhibitor for industrial water treatment and preparation method and application method thereof |
-
2016
- 2016-05-25 CN CN201610353703.1A patent/CN105967357B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4537684A (en) * | 1983-12-29 | 1985-08-27 | Union Oil Company Of California | Control of metal-containing scale deposition from high temperature brine |
| CN102131911A (en) * | 2008-09-07 | 2011-07-20 | 朗姆研究公司 | Cleaning solution formulations for substrates |
| CN101580310A (en) * | 2009-06-22 | 2009-11-18 | 谢云漫 | Food grade electric kettle scale dissolver and preparation method thereof |
| CN101913713A (en) * | 2010-03-16 | 2010-12-15 | 上海立昌环境工程有限公司 | Sulfate scale cleaning agent |
| CN103469222A (en) * | 2013-09-26 | 2013-12-25 | 宁夏启元国药有限公司 | Descaling agent for water scale of condensing equipment and descaling method |
| CN104651075A (en) * | 2013-11-25 | 2015-05-27 | 刘现梅 | Printed circuit board aqueous cleaning compound |
| CN104058512A (en) * | 2014-06-27 | 2014-09-24 | 无锡市崇安区科技创业服务中心 | Quick boiler scale remover and preparing method thereof |
| CN105585143A (en) * | 2015-12-22 | 2016-05-18 | 天津市尚拓环保科技有限公司 | Scale inhibitor for industrial water treatment and preparation method and application method thereof |
Non-Patent Citations (1)
| Title |
|---|
| "高效金属缓蚀添加剂入市";国内外化工简讯;《河南化工》;20010730(第7期);第45页 |
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