CN105778391A - Flame-retardant and antistatic material for shell of handheld Raman spectrometer - Google Patents
Flame-retardant and antistatic material for shell of handheld Raman spectrometer Download PDFInfo
- Publication number
- CN105778391A CN105778391A CN201610157078.3A CN201610157078A CN105778391A CN 105778391 A CN105778391 A CN 105778391A CN 201610157078 A CN201610157078 A CN 201610157078A CN 105778391 A CN105778391 A CN 105778391A
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- Prior art keywords
- retardant
- flame
- raman spectrometer
- antistatic
- handheld raman
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The invention relates to flame-retardant and antistatic material for the shell of a handheld Raman spectrometer, belongs to the technical field of spectrometer shell materials, and aims to solve the problems that the low-molecule phosphorus-nitrogen flame retardant and antistatic agent in the traditional flame-retardant and antistatic ABS materials are prone to hydrolysis and precipitation, and lasting flame-retardant and antistatic effects cannot achieve. A preparation method of the flame-retardant and antistatic material includes: evenly mixing ABS, flame-retardant and antistatic agent, toughening agent and antioxidant, using a double-screw extruder to perform melt mixing and extrusion pelletizing to obtain the flame-retardant and antistatic material. The flame-retardant and antistatic material is good in processing performance, lasting in flame-retardant and antistatic performances and capable of being used as the shell material of various handheld Raman spectrometers.
Description
Technical field
The present invention relates to a kind of handheld Raman spectrometer housing flame-retardant and anti-static material, belong to spectrogrph case material technical field.
Background technology
Acrylonitrile-butadiene-styrene copolymer (ABS), as one of engineering plastics five kinds important, possesses excellent physical and mechanical properties, good resistance to impact and dimensional stability, is used widely in handheld Raman spectrometer sheathing material.But ABS there is also certain problem, material itself is inflammable, be difficult to antistatic, becomes most problem demanding prompt solution in ensureing the application of handheld Raman spectrometer long-term stability.
Current flame-retardant and antistatic ABS material improves the fire resistance of ABS mainly through interpolation Halogen or phosphor nitrogen combustion inhibitor in the ABS course of processing, adds the mode of antistatic additive to improve ABS antistatic property simultaneously.Releasing more smog and enrichment possible in vivo when halogen containing flame-retardant is due to burning, application prospect causes anxiety, and more flame-proof ABS product turns to use halogen-free flame retardants.Halogen-free flame-proof antistatic ABS material reaches flame retardant effect mainly by the mode producing cigarette less phosphor nitrogen combustion inhibitor when adding burning, and its antistatic effect is generally realized by the mode of additional antistatic additive.But people find in the prolonged application of plastic, traditional phosphor nitrogen combustion inhibitor and antistatic additive mostly are little molecule, the i.e. relative molecular weight chemical substance lower than 1000, because molecular polarity and chemical bond, in prolonged application, facile hydrolysis, the problem easily precipitated out is there is with ABS matrix, thus bringing the loss of fire resistance and antistatic property, impact uses.
Summary of the invention
It is an object of the invention to fundamentally overcome the facile hydrolysis of low molecule phosphor nitrogen combustion inhibitor and antistatic additive existence in tradition flame-retardant and antistatic ABS material, easily precipitate out, be difficult to reach persistently fire-retardant and anlistatig problem, thus providing a kind of handheld Raman spectrometer housing flame-retardant and anti-static material.
The present invention is achieved by the following technical solutions.
A kind of handheld Raman spectrometer housing flame-retardant and anti-static material that the present invention relates to, the percentage by weight of its raw material is:
Described flame-retardant and anti-static agent is the one in poly-DADPS Phenylphosphine amide, poly-diaminodiphenyl ether Phenylphosphine amide, poly-MDA Phenylphosphine amide, and its structural formula is as follows.
Poly-DADPS Phenylphosphine amide
Poly-diaminodiphenyl ether Phenylphosphine amide R=-O-
Poly-MDA Phenylphosphine amide R=-CH2-
Wherein n is the integer between 2～2000.
Described toughener is the one in styrene-butadiene-styrene, ethylene-l-octane copolymer, ethylene propylene diene rubber.
Described antioxidant is the one in Hinered phenols primary antioxidant and phosphorous acid esters auxiliary antioxidant.
By diphenylphosphoryl dichloro respectively with diaminourea biphenol, diaminodiphenyl ether, MDA under nitrogen protection, in acetonitrile solution, 80 DEG C of stirring reaction 12h, reaction cools down after terminating, and filters, and dries preparation in described flame-retardant and anti-static agent.
Beneficial effect
A kind of handheld Raman spectrometer housing flame-retardant and anti-static material, has good processing characteristics, lasting fire resistance and antistatic property, it is possible to as all kinds of handheld Raman spectrometer case materials.
Detailed description of the invention
Below in conjunction with embodiment, present disclosure is described further.
Embodiment 1
By ABS65 kilogram, poly-DADPS Phenylphosphine amide 25 kilograms, styrene-butadiene-styrene 8 kilograms, antioxidant 1010 2 kilograms, use double screw extruder melting mixing, extruding pelletization after mix homogeneously, namely obtain handheld Raman spectrometer housing flame-retardant and anti-static material；Fire retardant is done with adopting tetrabromobisphenol A, add 2% stearyl trimethyl ammonium chloride to do the flame-retardant and antistatic ABS of antistatic treatment and compare, material contrast fire resistance and antistatic property, and by the fire resistance after the water resistance test of 70 DEG C of hot-water soak 168h and antistatic property, test concrete data in Table 1.Sample 1 is tetrabromobisphenol A flame-retardant and antistatic ABS, and sample 2 is APP and tetramethylolmethane anti-electrostatic fire retardant ABS, and sample 3 is poly-DADPS Phenylphosphine amide flame-retardant and antistatic ABS.
The table 1 handheld Raman spectrometer housing performance test table of flame-retardant and anti-static material
Embodiment 2
By ABS60 kilogram, poly-MDA Phenylphosphine amide 28 kilograms, ethylene-l-octane copolymer 10 kilograms, irgasfos 168 2 kilograms, use double screw extruder melting mixing, extruding pelletization after mix homogeneously, namely obtain handheld Raman spectrometer housing flame-retardant and anti-static material；The oxygen index (OI) of test flame-retardant and anti-static material is 27.3, and vertical combustion passes through UL-94V-0 level, and sheet resistance is 9.0 × 109, there is fire resistance and the antistatic property of excellence.
Embodiment 3
Weigh ABS70 kilogram, poly-diaminodiphenyl ether Phenylphosphine amide 22 kilograms, ethylene propylene diene rubber 7 kilograms, 1 kilogram of antioxidant, use double screw extruder melting mixing, extruding pelletization after mix homogeneously, namely obtain handheld Raman spectrometer housing flame-retardant and anti-static material；The oxygen index (OI) of test flame-retardant and anti-static material is 27.9, and vertical combustion passes through UL-94V-0 level, and sheet resistance is 3.8 × 109, there is fire resistance and the antistatic property of excellence.
Embodiment 4
Weigh ABS63 kilogram, poly-DADPS Phenylphosphine amide 25 kilograms, ethylene-l-octane copolymer 10 kilograms, 2 kilograms of antioxidant, use double screw extruder melting mixing, extruding pelletization after mix homogeneously, namely obtain handheld Raman spectrometer housing flame-retardant and anti-static material；The oxygen index (OI) of test flame-retardant and anti-static material is 26.7, and vertical combustion passes through UL-94V-0 level, and sheet resistance is 4.2 × 109, there is fire resistance and the antistatic property of excellence.
Embodiment 5
Weigh ABS60 kilogram, poly-diaminodiphenyl ether Phenylphosphine amide 27 kilograms, ethylene propylene diene rubber 10.5 kilograms, 2.5 kilograms of antioxidant, use double screw extruder melting mixing, extruding pelletization after mix homogeneously, namely obtain handheld Raman spectrometer housing flame-retardant and anti-static material；The oxygen index (OI) of test flame-retardant and anti-static material is 27.3, and vertical combustion passes through UL-94V-0 level, and sheet resistance is 6.0 × 109, there is fire resistance and the antistatic property of excellence.
Claims (6)
1. a handheld Raman spectrometer housing flame-retardant and anti-static material, it is characterised in that: the percentage by weight of raw material is:
2. a kind of handheld Raman spectrometer housing flame-retardant and anti-static material as claimed in claim 1, it is characterized in that: preparation method, for using double screw extruder melting mixing, extruding pelletization after ABS, flame-retardant and anti-static agent, toughener and antioxidant mix homogeneously, namely obtains handheld Raman spectrometer housing flame-retardant and anti-static material.
3. a kind of handheld Raman spectrometer housing flame-retardant and anti-static material as claimed in claim 1, it is characterised in that: described flame-retardant and anti-static agent is the one in poly-DADPS Phenylphosphine amide, poly-diaminodiphenyl ether Phenylphosphine amide, poly-MDA Phenylphosphine amide.
4. a kind of handheld Raman spectrometer housing flame-retardant and anti-static material as claimed in claim 1, it is characterised in that: described toughener is the one in styrene-butadiene-styrene, ethylene-l-octane copolymer, ethylene propylene diene rubber.
5. a kind of handheld Raman spectrometer housing flame-retardant and anti-static material as claimed in claim 1, it is characterised in that: described antioxidant is the one in Hinered phenols primary antioxidant and phosphorous acid esters auxiliary antioxidant.
6. a kind of handheld Raman spectrometer housing flame-retardant and anti-static material as described in claim 1 or 2 or 3; it is characterized in that: described flame-retardant and anti-static agent is by diphenylphosphoryl dichloro respectively with diaminourea biphenol, diaminodiphenyl ether, MDA under nitrogen protection; in acetonitrile solution; 80 DEG C of stirring reaction 12h; reaction cools down after terminating; filter, dry preparation.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2015109581762 | 2015-12-18 | ||
| CN201510958176 | 2015-12-18 |
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| Publication Number | Publication Date |
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| CN105778391A true CN105778391A (en) | 2016-07-20 |
| CN105778391B CN105778391B (en) | 2018-03-02 |
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| CN201610157078.3A Active CN105778391B (en) | 2015-12-18 | 2016-03-18 | A kind of handheld Raman spectrometer housing flame-retardant and anti-static material |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5811546A (en) * | 1981-07-13 | 1983-01-22 | Dainichi Seika Kogyo Kk | Coloring composition for synthetic resin |
| CN101709126A (en) * | 2009-12-01 | 2010-05-19 | 上海金发科技发展有限公司 | Flame-retardant and antistatic ABS modified resin |
| CN102352087A (en) * | 2011-08-31 | 2012-02-15 | 五行材料科技（江苏）有限公司 | Antistatic flame-retardant acrylonitrile butadiene styrene (ABS) rubber material and preparation method thereof |
| CN102796233A (en) * | 2012-07-18 | 2012-11-28 | 华南师范大学 | High molecular flame retarding and antistatic agent and synthetic method thereof |
| CN103289293A (en) * | 2013-06-20 | 2013-09-11 | 金发科技股份有限公司 | Transparent flame-retardant antistatic ABS material, and preparation method and application thereof |
| CN103788569A (en) * | 2014-03-04 | 2014-05-14 | 江南大学 | Inflaming-retarding and antistatic ABS modified material for safety helmet and preparing method thereof |
| CN103819866A (en) * | 2014-02-18 | 2014-05-28 | 金发科技股份有限公司 | High-performance permanently-antistatic flame-retardant ABS (acrylonitrile butadiene styrene) material and preparation method and application |
| CN104804366A (en) * | 2015-05-14 | 2015-07-29 | 宣海成 | ABS (Acrylonitrile Butadiene Styrene) modified resin with high hardness, flame retardance and antistatic property |
-
2016
- 2016-03-18 CN CN201610157078.3A patent/CN105778391B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5811546A (en) * | 1981-07-13 | 1983-01-22 | Dainichi Seika Kogyo Kk | Coloring composition for synthetic resin |
| CN101709126A (en) * | 2009-12-01 | 2010-05-19 | 上海金发科技发展有限公司 | Flame-retardant and antistatic ABS modified resin |
| CN102352087A (en) * | 2011-08-31 | 2012-02-15 | 五行材料科技（江苏）有限公司 | Antistatic flame-retardant acrylonitrile butadiene styrene (ABS) rubber material and preparation method thereof |
| CN102796233A (en) * | 2012-07-18 | 2012-11-28 | 华南师范大学 | High molecular flame retarding and antistatic agent and synthetic method thereof |
| CN103289293A (en) * | 2013-06-20 | 2013-09-11 | 金发科技股份有限公司 | Transparent flame-retardant antistatic ABS material, and preparation method and application thereof |
| CN103819866A (en) * | 2014-02-18 | 2014-05-28 | 金发科技股份有限公司 | High-performance permanently-antistatic flame-retardant ABS (acrylonitrile butadiene styrene) material and preparation method and application |
| CN103788569A (en) * | 2014-03-04 | 2014-05-14 | 江南大学 | Inflaming-retarding and antistatic ABS modified material for safety helmet and preparing method thereof |
| CN104804366A (en) * | 2015-05-14 | 2015-07-29 | 宣海成 | ABS (Acrylonitrile Butadiene Styrene) modified resin with high hardness, flame retardance and antistatic property |
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| CN105778391B (en) | 2018-03-02 |
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