CN104893458B - A kind of high deodorizing toilet cover coating of adhesive force - Google Patents
A kind of high deodorizing toilet cover coating of adhesive force Download PDFInfo
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- CN104893458B CN104893458B CN201510237729.5A CN201510237729A CN104893458B CN 104893458 B CN104893458 B CN 104893458B CN 201510237729 A CN201510237729 A CN 201510237729A CN 104893458 B CN104893458 B CN 104893458B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of high deodorizing toilet cover coating of adhesive force, its raw material includes by weight：25 30 parts of aqueous epoxy resins, 40 50 parts of water-based acrylic resin, 15 20 parts of water-compatible amino resin, modified 10 15 parts of medical stone powder, 8 12 parts of nano zeolite powder, 15 20 parts of nanomete talc powder, 8 12 parts of powdered whiting, 12 parts of organobentonite, 0.5 1.5 parts of polyether polyester azo polyether polyeste, 0.2 0.8 parts of fluorin modified crylic acid levelling agent, 0.2 0.5 parts of glyceryl tristearate, 24 parts of polyethylene glycol, 13 parts of hydroxymethyl cellulose, 0.5 2 parts of defoamer, 24 parts of preservative, 1 1.5 parts of rosin acid zirconates, 0.5 1.2 parts of linoleic acid zirconates.Ability of the present invention with excellent absorption stink substance, it is to avoid the secondary pollution of air, reduces transmission of disease probability, and adhesive force is good.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of high deodorizing toilet cover coating of adhesive force.
Background technology
Closestool during actual use the problem of having such：Foul smell diffuses, and under the impact of current, carries
The water smoke of excreta can floating away closestool, be suspended among air.To solve this technical problem, it is common practice to：The row of opening
Gas is fanned, make filth air it is fast some be discharged into outdoor.But this is still foul smell and the later mistake of the filthy floating away closestool of water smoke
Journey.In this process, the filthy water smoke in part can descend slowly and lightly everywhere, pollution toilet article, towel, bath towel, washbowl, bathtub etc., also have
The filthy water smoke in part can be sucked by human body, considerably increase transmission of disease chance.In order to offset foul smell, people can be in health
Between put a little volatile chemical flavouring agents, but this does not solve substantive issue, only can cause the secondary pollution of air.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of high deodorizing toilet cover coating of adhesive force,
Ability with excellent absorption stink substance, it is to avoid the secondary pollution of air, reduces transmission of disease probability, also with excellent
Adhesive force, weatherability, stability is high and pollution-free.
A kind of high deodorizing toilet cover coating of adhesive force proposed by the present invention, its raw material includes by weight：Water-base epoxy
25-30 parts of resin, 40-50 parts of water-based acrylic resin, 15-20 parts of water-compatible amino resin, modified 10-15 parts of medical stone powder is received
8-12 parts of zeolite powder of rice, 15-20 parts of nanomete talc powder, 8-12 parts of powdered whiting, 1-2 parts of organobentonite, polyether polyester changes
Property 0.5-1.5 parts of organosiloxane, 0.2-0.8 parts of fluorin modified crylic acid levelling agent, 0.2-0.5 parts of glyceryl tristearate, gather
2-4 parts of ethylene glycol, 1-3 parts of hydroxymethyl cellulose, 0.5-2 parts of defoamer, 2-4 parts of preservative, 1-1.5 parts of rosin acid zirconates is sub-
0.5-1.2 parts of oleic acid zirconates；
The preparation method of modified medical stone powder is as follows：Medical stone powder and water are fitted into autoclave and carry out hydro-thermal reaction
2-4h obtains material A；After material A is dried, add after being well mixed in sodium citrate solution, vibrate 55-65min, then enter
Row microwave heats 15-20min, and washing is dried to obtain modified medical stone powder.
Preferably, aqueous epoxy resins, water-based acrylic resin, the weight ratio of water-compatible amino resin are 26-28：45-48：
17-19。
Preferably, powdered whiting is 800-900 mesh.
Preferably, modified medical stone powder, nano zeolite powder, nanomete talc powder, organobentonite, polyether polyester are modified organic
Siloxanes, the weight ratio of fluorin modified crylic acid levelling agent are 13-14：10-11：16-17：1.5-1.8：0.8-1.2：0.4-0.6.
Preferably, the molecular weight of polyethylene glycol is 200-400.
Preferably, its raw material includes by weight：26-28 parts of aqueous epoxy resins, 45-48 parts of water-based acrylic resin,
17-19 parts of water-compatible amino resin, modified 13-14 parts of medical stone powder, 10-11 parts of nano zeolite powder, 16-17 parts of nanomete talc powder,
9-10 parts of powdered whiting, 1.5-1.8 parts of organobentonite, 0.8-1.2 parts of polyether polyester azo polyether polyeste, fluorine richness third
0.4-0.6 parts of olefin(e) acid levelling agent, 0.3-0.4 parts of glyceryl tristearate, 2.2-3.2 parts of polyethylene glycol, hydroxymethyl cellulose
1.7-2.2 parts, 1-1.2 parts of defoamer, 2.5-2.8 parts of preservative, 1.2-1.3 parts of rosin acid zirconates, linoleic acid zirconates 0.8-1
Part.
Preferably, the preparation method of modified medical stone powder is as follows：2-4 parts of medical stone powders and 6-10 parts of water are filled by weight
Enter to carry out hydro-thermal reaction 2-4h in autoclave and obtain material A, hydrothermal temperature is 290-320 DEG C；Material A is dried
Afterwards, after adding concentration to be well mixed in 0.1-0.2mol/L sodium citrate solution, 55-65min is vibrated, microwave is then carried out
15-20min is heated, microwave power is 450-500w, washing is dried to obtain modified medical stone powder, wherein material A and sodium citrate
The w/v (g/ml) of solution is 3-5:180-220.
Preferably, the preparation method of modified medical stone powder is as follows：By weight by 2.3-3.4 parts of medical stone powders and 7-8 parts
Water is fitted into progress hydro-thermal reaction 2.5-3.5h in autoclave and obtains material A, and hydrothermal temperature is 295-310 DEG C；By thing
Expect after A drying, after adding concentration to be well mixed in 0.12-0.16mol/L sodium citrate solution, vibrate 58-62min, connect
Carry out microwave heating 17-18min, microwave power is 470-480w, washing, is dried to obtain modified medical stone powder, wherein material A
W/v (g/ml) with sodium citrate solution is 3.8-4.5:190-210.
The preparation technology of the present invention is as follows：Aqueous epoxy resins, water-based acrylic resin, water-compatible amino resin are mixed equal
After even, add modified medical stone powder, nano zeolite powder, nanomete talc powder, powdered whiting, organobentonite, polyether polyester and change
Property organosiloxane, fluorin modified crylic acid levelling agent, glyceryl tristearate, polyethylene glycol, hydroxymethyl cellulose, defoamer,
Preservative, rosin acid zirconates, linoleic acid zirconates are uniformly mixing to obtain the high deodorizing toilet cover coating of adhesive force.
The present invention, as major ingredient, makes tool of the present invention using aqueous epoxy resins, water-based acrylic resin, water-compatible amino resin
There are excellent adhesive force, weatherability, stability is high, and set shrinkage factor is small, and hardness is high, and pliability is preferable and pollution-free；It is modified
Medical stone powder is carried out after hydro-thermal reaction using medical stone powder and water, after drying, is added in sodium citrate solution and is carried out microwave modification
Obtain, hydro-thermal reaction is modified to medical stone powder, get through the different micropore of script estrangement in medical stone powder, micropore is compared surface
Product and volume increase, and partial pore can be made to be expanded into mesopore under high pressure, cause average pore size to increase, add citric acid
Sodium solution carries out microwave modification, makes Na+It is replaceable go out medical stone powder in the larger cation of radius, further reduce medical stone powder
Steric hindrance, improve the pore volume of medical stone powder, interior diffusion rate is accelerated, exchange capacity increase, so as to improve its adsorptivity
Energy and ion-exchange performance；Sulphur based compound and compound nitrogen series that stink substance in lavatory represents for hydrogen sulfide and ammonia,
Modified medical stone powder, nano zeolite powder have loose structure in the present invention, make the sulphur based compound and nitrogen system chemical combination in air
Thing enters in loose structure, so as to reduce the content of sulphur based compound and compound nitrogen series in lavatory air, reduces stink；Together
When be modified medical stone powder, nano zeolite powder, nanomete talc powder, powdered whiting, organobentonite also as filler, rise skeleton,
Filling effect, paint thickness after increase solidification, improves coating wearability after solidification；And organobentonite and polyether polyester modification have
Organic siloxane, fluorin modified crylic acid levelling agent improve the anti-thixotropy of coating as levelling agent；Polyethylene glycol and three stearic acid are sweet
Grease cooperates, and substantially increases the effect of the antisolvent precipitation of coating；Rosin acid zirconates and the mating reaction of linoleic acid zirconates are significantly
Improve aerial curing rate of the invention.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of high deodorizing toilet cover coating of adhesive force proposed by the present invention, its raw material includes by weight：Water-base epoxy
25 parts of resin, 50 parts of water-based acrylic resin, 15 parts of water-compatible amino resin, modified 15 parts of medical stone powder, 8 parts of nano zeolite powder,
20 parts of nanomete talc powder, 800 12 parts of mesh powdered whitings, 1 part of organobentonite, 1.5 parts of polyether polyester azo polyether polyeste,
0.2 part of fluorin modified crylic acid levelling agent, 0.5 part of glyceryl tristearate, 2 parts of polyethylene glycol, 3 parts of hydroxymethyl cellulose, froth breaking
0.5 part of agent, 4 parts of preservative, 1 part of rosin acid zirconates, 1.2 parts of linoleic acid zirconates；
The preparation method of modified medical stone powder is as follows：4 parts of medical stone powders and 6 parts of water are loaded into autoclave by weight
Middle progress hydro-thermal reaction 4h obtains material A, and hydrothermal temperature is 290 DEG C；After material A is dried, addition concentration is 0.2mol/
After being well mixed in L sodium citrate solution, 55min is vibrated, microwave heating 20min is then carried out, microwave power is 450w, is washed
Wash, be dried to obtain modified medical stone powder, the wherein w/v (g/ml) of material A and sodium citrate solution is 1:36.
Embodiment 2
A kind of high deodorizing toilet cover coating of adhesive force proposed by the present invention, its raw material includes by weight：Water-base epoxy
28 parts of resin, 45 parts of water-based acrylic resin, 19 parts of water-compatible amino resin, modified 13 parts of medical stone powder, 11 parts of nano zeolite powder,
16 parts of nanomete talc powder, 850 10 parts of mesh powdered whitings, 1.5 parts of organobentonite, polyether polyester azo polyether polyeste 1.2
Part, 0.4 part of fluorin modified crylic acid levelling agent, 0.4 part of glyceryl tristearate, molecular weight is 200 3.2 parts of polyethylene glycol, hydroxyl
1.7 parts of methylcellulose, 1.2 parts of defoamer, 2.5 parts of preservative, 1.3 parts of rosin acid zirconates, 0.8 part of linoleic acid zirconates；
The preparation method of modified medical stone powder is as follows：2.3 parts of medical stone powders and 8 parts of water are loaded into reaction under high pressure by weight
Hydro-thermal reaction 2.5h is carried out in kettle and obtains material A, hydrothermal temperature is 310 DEG C；After material A is dried, adding concentration is
After being well mixed in 0.12mol/L sodium citrate solution, 62min is vibrated, microwave heating 17min, microwave power is then carried out
For 480w, washing is dried to obtain modified medical stone powder, the w/v (g/ml) of wherein material A and sodium citrate solution is
3.8:210。
Embodiment 3
A kind of high deodorizing toilet cover coating of adhesive force proposed by the present invention, its raw material includes by weight：Water-base epoxy
26 parts of resin, 48 parts of water-based acrylic resin, 17 parts of water-compatible amino resin, modified 14 parts of medical stone powder, 10 parts of nano zeolite powder,
17 parts of nanomete talc powder, 900 9 parts of mesh powdered whitings, 1.8 parts of organobentonite, polyether polyester azo polyether polyeste 0.8
Part, 0.6 part of fluorin modified crylic acid levelling agent, 0.3 part of glyceryl tristearate, molecular weight is 300 2.2 parts of polyethylene glycol, hydroxyl
2.2 parts of methylcellulose, 1 part of defoamer, 2.8 parts of preservative, 1.2 parts of rosin acid zirconates, 1 part of linoleic acid zirconates；
The preparation method of modified medical stone powder is as follows：2 parts of medical stone powders and 10 parts of water are loaded into reaction under high pressure by weight
Hydro-thermal reaction 2h is carried out in kettle and obtains material A, hydrothermal temperature is 320 DEG C；After material A is dried, adding concentration is
After being well mixed in 0.1mol/L sodium citrate solution, 65min is vibrated, microwave heating 15min is then carried out, microwave power is
500w, washing is dried to obtain modified medical stone powder, the wherein w/v (g/ml) of material A and sodium citrate solution is 3:
220。
Embodiment 4
A kind of high deodorizing toilet cover coating of adhesive force proposed by the present invention, its raw material includes by weight：Water-base epoxy
30 parts of resin, 40 parts of water-based acrylic resin, 20 parts of water-compatible amino resin, modified 10 parts of medical stone powder, 12 parts of nano zeolite powder,
15 parts of nanomete talc powder, 8 parts of powdered whiting, 2 parts of organobentonite, 0.5 part of polyether polyester azo polyether polyeste, fluorine richness
0.8 part of acrylic acid levelling agent, 0.2 part of glyceryl tristearate, molecular weight is 400 4 parts of polyethylene glycol, hydroxymethyl cellulose 1
Part, 2 parts of defoamer, 2 parts of preservative, 1.5 parts of rosin acid zirconates, 0.5 part of linoleic acid zirconates；
The preparation method of modified medical stone powder is as follows：3.4 parts of medical stone powders and 7 parts of water are loaded into reaction under high pressure by weight
Hydro-thermal reaction 3.5h is carried out in kettle and obtains material A, hydrothermal temperature is 295 DEG C；After material A is dried, adding concentration is
After being well mixed in 0.16mol/L sodium citrate solution, 58min is vibrated, microwave heating 18min, microwave power is then carried out
For 470w, washing is dried to obtain modified medical stone powder, the w/v (g/ml) of wherein material A and sodium citrate solution is
4.5:190。
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (8)
1. the high deodorizing toilet cover coating of a kind of adhesive force, it is characterised in that its raw material includes by weight：Aqueous epoxy resins
25-30 parts, 40-50 parts of water-based acrylic resin, 15-20 parts of water-compatible amino resin, modified 10-15 parts of medical stone powder, nanometer boiling
8-12 parts of stone flour, 15-20 parts of nanomete talc powder, 8-12 parts of powdered whiting, 1-2 parts of organobentonite, polyether polyester, which is modified, to be had
0.5-1.5 parts of organic siloxane, 0.2-0.8 parts of fluorin modified crylic acid levelling agent, 0.2-0.5 parts of glyceryl tristearate, poly- second two
2-4 parts of alcohol, 1-3 parts of hydroxymethyl cellulose, 0.5-2 parts of defoamer, 2-4 parts of preservative, 1-1.5 parts of rosin acid zirconates, linoleic acid
0.5-1.2 parts of zirconates；
The preparation method of modified medical stone powder is as follows：Medical stone powder and water are fitted into autoclave and carry out hydro-thermal reaction 2-4h
Obtain material A；After material A is dried, add after being well mixed in sodium citrate solution, vibrate 55-65min, then carry out micro-
Wave heating 15-20min, washing, is dried to obtain modified medical stone powder.
2. the high deodorizing toilet cover coating of adhesive force according to claim 1, it is characterised in that aqueous epoxy resins, aqueous
Acrylic resin, the weight ratio of water-compatible amino resin are 26-28：45-48：17-19.
3. the high deodorizing toilet cover coating of adhesive force according to claim 1 or claim 2, it is characterised in that powdered whiting is
800-900 mesh.
4. according to the high deodorizing toilet cover coating of any one of the claim 1-3 adhesive force, it is characterised in that modified medical stone
Powder, nano zeolite powder, nanomete talc powder, organobentonite, polyether polyester azo polyether polyeste, fluorin modified crylic acid levelling agent
Weight ratio be 13-14：10-11：16-17：1.5-1.8：0.8-1.2：0.4-0.6.
5. according to the high deodorizing toilet cover coating of any one of the claim 1-4 adhesive force, it is characterised in that polyethylene glycol
Molecular weight is 200-400.
6. according to the high deodorizing toilet cover coating of any one of the claim 1-4 adhesive force, it is characterised in that its raw material is by weight
Amount part includes：26-28 parts of aqueous epoxy resins, 45-48 parts of water-based acrylic resin, 17-19 parts of water-compatible amino resin, modified wheat
13-14 parts of meal stone flour, 10-11 parts of nano zeolite powder, 16-17 parts of nanomete talc powder, 9-10 parts of powdered whiting, organobentonite
1.5-1.8 parts, 0.8-1.2 parts of polyether polyester azo polyether polyeste, 0.4-0.6 parts of fluorin modified crylic acid levelling agent, three is stearic
0.3-0.4 parts of acid glyceride, 2.2-3.2 parts of polyethylene glycol, 1.7-2.2 parts of hydroxymethyl cellulose, 1-1.2 parts of defoamer, anti-corrosion
2.5-2.8 parts of agent, 1.2-1.3 parts of rosin acid zirconates, 0.8-1 parts of linoleic acid zirconates.
7. according to the high deodorizing toilet cover coating of any one of the claim 1-5 adhesive force, it is characterised in that modified medical stone
The preparation method of powder is as follows：2-4 parts of medical stone powders and 6-10 parts of water are fitted into progress hydro-thermal in autoclave by weight anti-
2-4h is answered to obtain material A, hydrothermal temperature is 290-320 DEG C；After material A is dried, addition concentration is 0.1-0.2mol/L
Sodium citrate solution in be well mixed after, vibrate 55-65min, then carry out microwave heating 15-20min, microwave power is
450-500w, washing is dried to obtain modified medical stone powder, the wherein w/v of material A and sodium citrate solution is 3-5g:
180-220ml。
8. according to the high deodorizing toilet cover coating of any one of the claim 1-6 adhesive force, it is characterised in that modified medical stone
The preparation method of powder is as follows：2.3-3.4 parts of medical stone powders and 7-8 parts of water are fitted into autoclave by weight and carry out hydro-thermal
Reaction 2.5-3.5h obtains material A, and hydrothermal temperature is 295-310 DEG C；After material A is dried, addition concentration is 0.12-
After being well mixed in 0.16mol/L sodium citrate solution, 58-62min is vibrated, microwave is then carried out and heats 17-18min, it is micro-
Wave power is 470-480w, washing, is dried to obtain the bulking value of modified medical stone powder, wherein material A and sodium citrate solution
Than for 3.8-4.5g:190-210ml.
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| CN107936797A (en) * | 2017-12-21 | 2018-04-20 | 安徽明豪实木家俱有限公司 | A kind of solid wood wardrobe surface environmental protection coating material |
| CN111995917A (en) * | 2020-09-03 | 2020-11-27 | 宋家豪 | Water-based high-adhesion water-resistant paint and preparation method thereof |
| CN114958132B (en) * | 2022-07-01 | 2023-03-31 | 漳州市和兴涂料有限公司 | Plastic coating for bathroom accessories and production process and application thereof |
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| CN104177975A (en) * | 2013-05-24 | 2014-12-03 | 青岛极致节能环保有限公司 | An environmental-friendly building external-wall coating material |
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| CN104449221A (en) * | 2014-11-24 | 2015-03-25 | 天长市开林化工有限公司 | High-adhesion flame-retardant corrosion-resistant paint |
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|---|---|---|---|---|
| CN102093791A (en) * | 2010-09-08 | 2011-06-15 | 成进学 | Formula process for nano negative ion compound functional coating |
| CN104177975A (en) * | 2013-05-24 | 2014-12-03 | 青岛极致节能环保有限公司 | An environmental-friendly building external-wall coating material |
| CN104212313A (en) * | 2014-09-19 | 2014-12-17 | 江苏海晟涂料有限公司 | Quick-drying friction-resisting high-temperature-resistant primer and preparation method thereof |
| CN104449221A (en) * | 2014-11-24 | 2015-03-25 | 天长市开林化工有限公司 | High-adhesion flame-retardant corrosion-resistant paint |
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