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BR112015008680A2 - catalisador de amina para melhorar a estabilidade dos sistemas de poliuretano tendo agentes de expansão contendo halogênio - Google Patents

catalisador de amina para melhorar a estabilidade dos sistemas de poliuretano tendo agentes de expansão contendo halogênio

Info

Publication number
BR112015008680A2
BR112015008680A2 BR112015008680A BR112015008680A BR112015008680A2 BR 112015008680 A2 BR112015008680 A2 BR 112015008680A2 BR 112015008680 A BR112015008680 A BR 112015008680A BR 112015008680 A BR112015008680 A BR 112015008680A BR 112015008680 A2 BR112015008680 A2 BR 112015008680A2
Authority
BR
Brazil
Prior art keywords
catalyst
stability
amine catalyst
halogen containing
improving
Prior art date
Application number
BR112015008680A
Other languages
English (en)
Other versions
BR112015008680B1 (pt
Inventor
Louise Vincent Jean
Jesus Burdeniuc Juan
J Miller Timothy
Original Assignee
Air Prod & Chem
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Air Prod & Chem filed Critical Air Prod & Chem
Publication of BR112015008680A2 publication Critical patent/BR112015008680A2/pt
Publication of BR112015008680B1 publication Critical patent/BR112015008680B1/pt

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/09Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1825Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1833Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1858Catalysts containing secondary or tertiary amines or salts thereof having carbon-to-nitrogen double bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/18Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20Heterocyclic amines; Salts thereof
    • C08G18/2009Heterocyclic amines; Salts thereof containing one heterocyclic ring
    • C08G18/2027Heterocyclic amines; Salts thereof containing one heterocyclic ring having two nitrogen atoms in the ring
    • CCHEMISTRY; METALLURGY
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/22Catalysts containing metal compounds
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/16Catalysts
    • C08G18/22Catalysts containing metal compounds
    • C08G18/227Catalysts containing metal compounds of antimony, bismuth or arsenic
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    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/34Carboxylic acids; Esters thereof with monohydroxyl compounds
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/4009Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4027Mixtures of compounds of group C08G18/54 with other macromolecular compounds
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/50Polyethers having heteroatoms other than oxygen
    • C08G18/5021Polyethers having heteroatoms other than oxygen having nitrogen
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
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    • C08G18/546Oxyalkylated polycondensates of aldehydes
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    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/02Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by the reacting monomers or modifying agents during the preparation or modification of macromolecules
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    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
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    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
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    • C08J9/146Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
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    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
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    • C08G2110/00Foam properties
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    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/02Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/022Foams characterised by the foaming process characterised by mechanical pre- or post-treatments premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming
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    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/16Unsaturated hydrocarbons
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    • C08J2205/00Foams characterised by their properties
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    • C08J2205/052Closed cells, i.e. more than 50% of the pores are closed
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    • C08J2205/00Foams characterised by their properties
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    • C08J2207/00Foams characterised by their intended use
    • C08J2207/04Aerosol, e.g. polyurethane foam spray
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    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

resumo patente de invenção: "catalisador de amina para melhorar a estabilidade dos sistemas de poliuretano tendo agentes de expansão contendo halogênio". a presente invenção refere-se a composições de catalisador úteis na produção de espuma isolante de poliuretano ou de poli-isocianurato. as composições de catalisador dão estabilidade aumentada de uma mistura do catalisador, um agente de expansão contendo halogênio e um poliol. estas composições de catalisador compreendem pelo menos 10% de uma tetra-alquilguanidina e pelo menos 10% de um catalisador de amina terciária com um grupo reativo de isocianato. estes catalisadores melhorados podem ser usados com qualquer agente de expansão halogenado, e fornece benefícios de estabilidade substanciais com o uso de hidrofluoro-olefinas e hidrofluorocloro-olefinas. em uma modalidade exemplar, um processo inclui fornecer uma pré-mistura compreendendo um agente de expansão de hidro-halo-olefina, pelo menos um poliol, água, e um catalisador compreendendo 10-50% de tetrametilguanidina e 10-90% de um ou mais de um catalisador de amina contendo um grupo reativo de isocianato.
BR112015008680-2A 2012-10-24 2013-10-24 Composição de pré-mistura de poliol, método para fazer espuma, espuma, método para melhorar a estabilidade de uma pré-mistura de poliol e uso de tetra-alquilguanidina para melhorar a estabilidade de uma composição de pré-mistura de poliol BR112015008680B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261717690P 2012-10-24 2012-10-24
US61/717,690 2012-10-24
US13/951,958 US10023681B2 (en) 2012-10-24 2013-07-26 Delay action catalyst for improving the stability of polyurethane systems having halogen containing blowing agents
US13/951,958 2013-07-26
PCT/US2013/066541 WO2014066596A1 (en) 2012-10-24 2013-10-24 Amine catalyst for improving the stability of polyurethane systems having halogen containing blowing agents

Publications (2)

Publication Number Publication Date
BR112015008680A2 true BR112015008680A2 (pt) 2017-07-04
BR112015008680B1 BR112015008680B1 (pt) 2021-03-23

Family

ID=49484072

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015008680-2A BR112015008680B1 (pt) 2012-10-24 2013-10-24 Composição de pré-mistura de poliol, método para fazer espuma, espuma, método para melhorar a estabilidade de uma pré-mistura de poliol e uso de tetra-alquilguanidina para melhorar a estabilidade de uma composição de pré-mistura de poliol

Country Status (11)

Country Link
US (2) US10023681B2 (pt)
EP (3) EP2725047B1 (pt)
JP (3) JP5869546B2 (pt)
KR (1) KR101792793B1 (pt)
CN (3) CN103772634A (pt)
BR (1) BR112015008680B1 (pt)
CA (2) CA2830692C (pt)
ES (3) ES2846768T3 (pt)
MX (1) MX355844B (pt)
PL (2) PL2725047T3 (pt)
WO (1) WO2014066596A1 (pt)

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