MXPA98007515A - Champus for estilizar de alta esp - Google Patents

Abstract

The present invention relates to shampoo compositions for styling hair that provide improved cleaning, foaming and styling performance. These shampoo compositions comprise an alkylglyceryl ether sulphonate surfactant, a hair styling polymer comprising one or more selected hydrophobic monomer units, a non-polar volatile solvent and water. Methods for cleaning and styling the hair are also described herein. using the shampoo compositions to stylize the hair

Description

SHAMPOO FOR STYLING OF HIGH FOAM FIELD OF THE INVENTION The present invention relates to hair shampoo compositions that have improved cleaning, foaming and styling benefits. These shampoo compositions comprise an alkylglyceryl ether sulphonate surfactant, selected hair styling polymers and a non-polar volatile solvent to solubilize the styling polymer.

BACKGROUND OF THE INVENTION Various final results are desired in the washing, drying and styling of the hair. First and most obvious, one wants the hair to be completely cleansed. The most desirable thing is a process to take care of the hair that m.antenga the appearance and sensation of hair '. clean between hair washes. One also wants a process or product to take care of the hair that provides styling benefits of the hair, especially for the achievement and maintenance of hair style. Such retention is generally carried out in either of two ways: permanent chemical alteration or temporary alteration of hair style and shape. A permanent alteration - for example a permanent chemical alteration - implies the use of chemical agents to be reacted with the hair to achieve the desired effect. This permanent chemical alteration of the hair, however, is not an object of the present invention. The stylization benefit provided by the present invention is a temporary alteration. A temporary alteration is the only one that can be eliminated by water or by washing with shampoo. In other words, it is a non-permanent alteration. The temporary style alteration has generally been carried out by means of the application of a separate composition or compositions after the shampooing process to provide achievement and maintenance of the hair style. The materials used to provide these temporary styling benefits have generally been "resins or gums" that are usually applied in the form of mousses, gels, lotions, or sprays. This proposal presents various significant drawbacks for the user. 'A separate step is required following the shampooing to apply the styling composition. In addition, many of these styling agents are aesthetically unattractive, leaving the hair feeling sticky or stiff after application of the styling composition, thus frustrating the purpose of the cleaning process. In addition, many styling agents do not provide a long-lasting styling benefit or provide a stylization benefit that is altered too easily. While the shampoo compositions that are described in the prior art provide cleaning and conditioning benefits, they do not provide effective styling benefits. The benefits derived from stylization are highly desirable. . However, styling agents, such as styling polymers, can not be easily incorporated into conventional shampoos without suppressing the shampooing and cleansing ability of the shampoos, or the elemental deposition and performance of the styling polymer.

It has now been found that alkylglycerol sulfonate surfactants provide excellent cleaning and foaming performance when used in combination with selected styling polymers. It has also been found that when the selected styling polymers are dissolved in a non-polar volatile solvent, the styling polymer is easily dispersed in the shampoo composition and that the polymer is deposited on the hair during the cleaning and rinsing process. Previous developments in this area employed a styling polymer dissolved in a polar solvent, which was emulsified in a shampoo base (see U.S. Patent No. 5)., 120,532, for Wells et al., Issued June 9, 1993). However, polar solvents can inhibit the deposition of the styling polymer. These polar solvents tend to be too soluble in the shampoo base and may contain the styling polymer in the water phase of the shampoo and remain outside the hair in the rinse water during the rinse process. In addition, many of the commonly used polar solvents have strong unpleasant odors or can be hydrolytically unstable in an aqueous environment. A Non-polar solvent would be preferable in such cases, however, non-polar solvents tend to interfere with the cleaning and foaming ability of the shampoo base surfactant. Typical high foaming surfactants, such as alkyl sulfates, can foam in the presence of non-polar solvents, but have the disadvantage of reducing deposition in such a way that the stylization benefit is not achieved. Alkyl glyceryl ether sulfonates are also known to be good foaming surfactants (see U.S. Patent 2,979,465, to Parran et al., Issued April 11, 1961). However, it has now been found that the alkyl glyceryl ether sulfonate surfactants are capable of producing good cleaning and defoaming without interfering with the deposition of the selected hair styling polymers, dissolved in a non-polar volatile solvent. The present invention relates to hair shampoo compositions comprising an alkyl glyceryl ether sulphonate surfactant, selected styling hair polymers, a non-polar volatile solvent for dissolving the selected polymer and water. Washing with Shampoo with these products provides both hair cleansing and styling benefits from a particular product. These compositions also have good foaming ability. It has also been found that the styling shampoo compositions of the present invention provide product viscosities that maintain the stability of the product phase and a pleasing aesthetic appearance to the consumer. Therefore, it is an object of the present invention to provide hair shampoo compositions that provide both effective hair cleansing and good styling properties and further provide such compositions with good foaming performance. It is also an object of the present invention to provide hair shampoo compositions that provide good style retention benefits without leaving hair feeling stiff, sticky or careless and further providing such compositions that provide effective conditioning performance. It is still another object of the present invention to provide an improved method for cleaning and styling hair.

BRIEF DESCRIPTION OF THE INVENTION The present invention is directed to a shampoo composition, for styling hair, of high foaming comprising (a) from about 2% to about 2.5%, by weight, of an alkylglyceryl ether sulphonate surfactant; (b) from about 0.1% to about %, by weight, of hair styling polymers selected comprising hydrophobic monomer units selected from the group consisting of styrene; polystyrene macromonomer; alpha methylstyrene, t-butyl styrene; indene; norbornylene; β-pinene; α-pinene, 4-biphenyl acrylate, pentachlorophenyl acrylate; 3,5-dimethylarylamyl acrylate; 3,5- dimethyladamantyl methacrylate; 4- methoxycarbonylphenyl methacrylate; tri-ethylsilyl methacrylate; isobornyl acrylate, isobornyl methacrylate; and combinations thereof, '1 - "FK (c) from about 0.1% to about 10%, by weight, of a non-polar volatile solvent to solubilize the polymer to styling the hair, the non-polar volatile solvent having a boiling point of less than or equal to about 300 ° C and a solubility in water at 25 ° C of less than about 0.2% by weight; and (d) from about 50% to about 97.8% water; wherein the weight ratio of the polymer for styling the hair to the non-polar volatile solvent is from about 10:90 to about 70:30. The present invention is also directed to methods for cleaning and styling hair using the compositions of the present invention, which methods comprise the steps of (a) wetting the hair with water, (b) applying an effective amount of the composition of shampoo for hair, (c) shampooing the hair with the composition, (d) rinsing the hair composition and (e) drying and styling the hair. , '1 J * DETAILED DESCRIPTION OF THE INVENTION The shampoo compositions of the present invention comprise sulfonate surfactants from which Iglyceryl ether in combination with select styling polymers and non-polar volatile solvents to solubilize the selected polymers. The shampoo compositions and corresponding methods of the present invention may comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well as any of the ingredients, components, additional or optional limitations described at the moment . All percentages, parts and s-e ratios are based on the total weight of the shampoo compositions of the present invention, unless otherwise specified. All such weights as they pertain to the listed ingredients are based on the active level and, therefore, do not include carriers or by-products that may be included in commercially available materials. ^ ± w Alkylglyceryl ether sulphonate surfactant The compositions of the present invention comprise sulfonate surfactant alkylglyceryl ether (AGS surfactant) as a cleaning and foaming ingredient. These compositions comprise from about 2% to about 25%, more preferably from about 3% to about 20% and more preferably from about 4% to about 10% of the sulfonate surfactant. of alkylglyceryl ether. These AGS surfactants are derived from an alkyl glyceryl ether containing a sulfonate group or sulfonate salt. These compounds can generally be described as a glycerol alkylmonoether which also contains a sulfonate group. These AGS surfactants can generally be described in accordance with the following structures: ROCH2CHCH2SO3-X * I OH. HOCH ') CHCH S? 3-X + I, OR wherein R is a saturated or unsaturated linear chain, branched chain, or a cyclic alkyl group having from about 10 to about 18 carbon atoms, preferably from about 11 to about 16 carbon atoms and more preferably from about 12 to about 14 carbon atoms and X is a cation selected from the group consisting of ammonium; ammonium mono-alkyl sulfite; ammonium di-alkylsulfide; ammonium t substituted 1-alky1; ammonium tet ra-alkylsus tituido; alkali metal; alkali metal; and its mixtures. More preferably, the alkyl radicals, R in the above formulas, are saturated and linear chain d-e. The distribution of the alkyl chain lengths in the AGS surfactant has some effect on the character of the total shampoo product. A satisfactory distribution can be achieved in a commercially practicable way using fatty alcohols derived from coconut oil and tallow. An equivalent distribution of alkyl chain lengths can be achieved using other starting materials. In the preparation of coconut fatty alcohols used to provide the alkyl group of the AGS, the regular cut of coconut oil. The boiling cut can be retained with the regular cut of the coconut oils if desired. In the preparation of tallow fatty alcohols, a hydrogenation step is included to ensure that they are substantially saturated. Preferred AGS surfactants are those having an alkyl group whereby. at least about 50% of such alkyl groups are derived from alcohols having from about 10 to about 18 carbon atoms, which have mainly monoglyceryl radicals present, with less than about 30% diglyceryl radicals present. • The AGS surfactant exemplified hereinafter contains approximately 15% diglyceryl ether sulfonates and is preferred due to the easy manufacture of this material. The term "AGS" is proposed to include monoglyceryl, diglyceryl and traces of the glyceryl-major compounds. Small amounts, that is less than about 3% of the total, of triglyceryl ether sulfonates and tetraglyceryl ether sulfonates may be present. SAGs derived from glyceryl ethers having chain lengths are also included branched and linear, branched or mixed that emulate the linear chain lengths. The most preferred AGS surfactants for use in shampoo compositions in p-resen e are those that have a linear chain length of C12_14, and are crystalline in structure. The preferred cation, "X", in the AGS surfactants is sodium. An example of a commercially available AGS surfactant useful herein includes sodium cocoglyceryl ester sulfonate, as listed in CTFA International Cosmetic Ingredient Dictionay, fifth edition, 1993, page 660, which is incorporated by reference herein. its entirety The AGS surfactants can be prepared using a variety of conventional synthetic or other known methods. The AGS surfactants are preferably prepared by reacting the fatty alcohols with a slight excess of epichlorohydrin, and then sulfonating the resulting chloroglyceryl ethers by means of the Reaction of This requirement. Secondary reaction products, such as alkyldiglyceryl ether disulfonates, sp R0CH 3 -C H -CH3 - S0XX O CH3-CHOH-CH3-S03"X" they are formed in addition to the alkylmono-glyceryl ether sulfonate which is the primary product. Additional isomers of the diglyceryl compound are also formed and can be monosulfonated or disulfonated. For the purposes of this invention, sodium alkylglyceryl ether sulfonate should contain less than about 30% of the diglycerol ether product and preferably less than about 25%. The remainder is substantially monoglyceryl ether sulfonate. Generally, it is not desirable to reduce the content of alkyldiglyceryl ether to below about 5% for economic reasons. Suitable AGS surfactants are described, for example, in U.S. Patent No. 2,979,465 to Parran et al., Issued April 11, 1961; U.S. Patent No. 3,179,599 to Eaton et al., issued April 20, 1965; British Patent No. 848,224, published September 14, 1960; British Patent No. 791,415, published on March 5, 1958; U.S. Patent No. 5,322 / 643 d.e S'cha artz et al., issued June 21, 1994; and U.S. Patent No. 5,084,212, to Farris et al., issued January 28, 1992; whose descriptions are incorporated herein by reference.

Styling polymer for hair The shampoo compositions of the present invention comprise hydrophobic, water insoluble hair styling polymers comprising one or more selected hydrophobic monomers. The polymer concentrations vary from about 0.1% to about 10%, preferably from about 0.3% to about 7%, more preferably from about 0.5% to about 5%, by weight of the shampoo compositions. The hair styling polymers selected for use in the shampoo compositions of the present invention are water-insoluble, hydrophobic polymers. These selected polymers comprise one or more units of hydrophobic monomers selected from the styrene group; polystyrene macromonomer; alpha-methylstyrene; t-but i 1-is t irene; indene; norborni wood; β-pinene; a-pinene; 4-biphenyl acrylate; pentachlorophenyl acrylate; acrylate of 3, 5-dimet i ladamant i lo; methacrylate of 3, 5 -dimet i ladamant i lo; 4-methoxycarbonyl-1-phenyl methacrylate; trimethylsilyl methacrylate; isobornyl acrylate; isobornyl methacrylate; and combinations thereof. Preferred monomers are t-butyl-styrene. The selected hair styling polymers may be homopolymers, copolymers, terpolymers and other higher polymers comprising one or more of the selected hydrophobic monomer units described in. the present. The hair styling polymers selected may further comprise one or more monomer units different from the selected monomer units described herein. Such different monomer units may be hydrophobic or non-hydrophobic, provided that the resulting styling hair polymer comprises at least one or more of the selected monomer units described herein and the resulting polymer is insoluble. to water as defined hereafter. The examples -I *! of such different monomer units are well known in the art, the specific examples of which are described in U.S. Patents 5,120,531 to Wells et al., issued June 9, 1992; 5,120,532 to Wells et al., Issued June 9, 1992; 5,104,642 of Wells et al., Issued April 14, 1992; 4,272,511 of Papantoniou et al., Issued June 9, 1981; and 4,196,190 from Gehman et al., issued April 1, 1980, whose descriptions are incorporated into the pxe sat by reference. The term "hydrophobic monomer" means a monomer, which in polymerization with similar monomers, forms a water-insoluble homopolymer. The term polymer or homopolymer "insoluble to water" means a polymer having a solubility in water at 25 ° C of about 0.2% or less, calculated on a weight basis of the polymer plus water. The term "solubility" as used herein refers to the maximum concentration of polymer that can be dissolved in water to form a solution that is substantially clear to the naked eye.

The styling polymer for the caoelium preferably has a crystalline transition temperature (Tg) of at least about 20 ° C, preferably between about 0 ° C and about 80 ° C, and most preferably between about 20 ° C and approximately 60 ° C. The crystalline transition temperatures can be determined by differential scanning calorimetry. Hair styling polymers of shampoo compositions herein have an average molecular weight weight of at least about 10,000. The molecular weight will generally be less than about 5,000,000, although high molecular weights are not intended to be excluded. Preferably, the average molecular weight will be from about 30,000 to about 5,000,000, more preferably at least about 50,000, even more preferably at least about 75,000. The average molecular weight weight is preferably less than about 200,000, more preferably less than about 150, t000. The average weight, of molecular weight, for purposes thereof, can be measured by methods known in the art, suitable to determine the molecular weight of the sample - which is analyzed, for example the dimension of exclusion chromatography using pore sizes in the column of 103, 105 and 10 ° angstroms, or other equivalent methods. Styling hair polymers for use in shampoo compositions can be made by conventional or otherwise known polymerization techniques such as free radical polymerization. Styling polymers for the hair for use in shampoo compositions herein include t-butyl styrene / 2-ethylhexyl methacrylate copolymers having a weight / weight ratio of about 95 / monomers. 5, about 90/10, about 80/20, about 70/30, about 60/40 and about 50/50; t-butylstyrene / ethexhexyl acrylate copolymers which have a weight / weight ratio of monomers of about 95/5, about 90/10, about 80/20, about 70/30, about 60/40 and approximately 50/50; t-butylstyrene / ethylhexyl ethacrylate copolymers having a ratio of rae weight / weight of monomers of about 95/5, about 90/10, about 80/20, about 70/30, about 60/40 and about 50/50; and combinations thereof. Most preferred are the t-butyl ether / 2-ethylhexyl methacrylate copolymers.

Non Polar Volatile Solvent The shampoo compositions of the present invention comprise a non-polar volatile solvent for solubilizing the hair styling polymer described above. The solvent helps to disperse the styling hair polymer as fluid particles throughout the shampoo composition. The solvent concentrations should be sufficient to solubilize the styling polymer for the hair and disperse it as a separate fluid phase in the shampoo composition. Such concentrations vary from about 0.10% to about 10%, preferably from about 0.5% to about 8%, more preferably from about 1% to about 6%, by weight of the composition of -gp shampoo. At solvent concentrations below 0.1%, the hair styling polymer generally may not be sufficiently diluted, and at concentrations above 10%, the foaming and cleaning characteristics of the shampoo are impaired. The polymer at solvent ratios (weight ratio) of the shampoo compositions herein ranges from about 10:90 to about 70:30, preferably from about 30:70 to about 60:40. It is believed that the solvent also helps achieve the style that is given by styling the styling polymer for the hair deposited on the hair, thereby making it more flexible and adhesive during the styling and drying process of the hair. In addition, the solvent must have a low solubility in water. More preferred are hydrocarbons having a solubility in water of less than about 0.5% by weight, preferably less than 0.3% by weight, and most preferably less than 0.2% by weight. The polymer used for hair selected for use in shampoo compositions must, however, be soluble in the selected solvent, thus leaving the dispersion of the styling polymer for the hair and solvent combination as a dispersed fluid phase, separated in the shampoo composition. Additionally, the solvents should not interact with the styling agent of the polymer, such that it would substantially reduce the ability of the styling polymer for the hair to provide styling benefits for the hair under ordinary use situations. The selected solvent must also be volatile. In the deposition of the styling polymer for the hair and solvent combination on the hair, the solvent volatilizes leaving only the styling polymer on the hair, thus providing the benefits of maximum styling. To provide the necessary volatility, the solvent must have a boiling point of no more than about 300 ° C, more preferably from about 90 ° C to about 260 ° C, more preferably from about 100 ° C to about 200 ° C. (at approximately one atmosphere of pressure).

Jl 3Sg Volatile non-polar solvents suitable for use in the shampoo compositions herein are hydrocarbon solvents, ether solvents or combinations thereof. Hydrocarbon solvents, especially branched chain hydrocarbon solvents are more preferred. Suitable hydrocarbon solvents are saturated or unsaturated, linear or branched hydrocarbons having from about 8 to about 18 carbon atoms, preferably from about 10 to about 16 carbon atoms. Saturated hydrocarbons, such as branched hydrocarbons, are preferred. Suitable linear hydrocarbons include decane, dodecane, decene, tridecene and combinations thereof. Suitable branched hydrocarbons include isoparaffins, examples of which include isoparaffins commercially available from Exxon Chemical Company such as Isopar ™ H and -K (Cp-Cp isoparaffins), and Isopar ™ L (C11-C13 isoparaffins). Preferred branched hydrocarbons are isohexadecane, isododecane, 2,5-dimethdecanocane, isotetradecane and combinations thereof. Commercially available branched hydrocarbons include ? í • se Permethyl MP 99A and 101A (available from Preperse, Inc., South Plainfield, NJ, USA). Suitable ether solvents for use in the shampoo composition herein are the C5-C7 di-alkyl ethers and diethers, especially the C5-C5 di-alkyl ethers such as isoamyl ether, di-ethyl ester and di-hexyl ether.

Hair Styling Agents The combination of styling hair polymers and non-polar volatile solvents in the shampoo compositions of the present invention is also referred to herein as the styling agent. The hair styling agent of the shampoo compositions herein comprises a combination of a styling polymer for hydrophobic hair, insoluble to water (described above) and a volatile solvent no. polar, insoluble • to water (described above). The styling agent comprises a styling polymer for the hair with a volatile solvent of weight ratio from about 10:90 to about 70:30, 733P preference from about 20:80 to about 65:35, more preferably from about 30:70 to about 60:40. The styling polymer for the hair is combined with the non-polar volatile solvent in the weight ratios described previously. If the ratio is too low, the foaming performance of the shampoo composition is detrimental, and if the ratio is too high, the composition becomes too viscous and causes difficulty in. the dispersion of the styling polymer. Styling agents should have an average particle diameter in the final shampoo product from about 0.1 to about 100 microns, preferably from about 0.5 microns to about 25 microns. Such a particle size can be measured by known or otherwise conventional methods, for example optical microscopy. Preferred examples of styling agents include the following materials. It should be noted that the numbers in parentheses following the polymers indicate the relative weight ratios of the monomers.

-LS » Mixture A. Ratio p / p Polymer: indene / - 2-ethylhexyl methacrylate (90/10 w / w) 40 Solvent: isododecane 60 Mixture B. Polymer: isobornyl methacrylate / 2-ethylhexyl methacrylate (90/10 w / w) 50 Solvent: isododecane 50 Mixture C. Polymer: t-butystyrene / 2-ethylhexyl ethacrylate (50/50 p / p) 40 Solvent: isohexadecane 60 Mixture D. Polymer: t-butyl styrene / 2-ethylhexyl methacrylate (50/50 p / p) 30 Solvent: Isoparaffin Mixture of (Ci.-C-) 70 Mixture E. Polymer: indene / - 2-ethylhexyl methacrylate (60/40 p / p) 40 Solvent: Isoparaffin Mixture of XX-C- ^ 60 Sold as Isopar H by Exxon, which is a mixture of isoparaffins of Cu-C >; Sold as Isopar L by Exxon, which is a mixture of Cn-Cj isoparaffins; Water The shampoo compositions of the present invention may further comprise one or more optional components that are known for use in hair care compositions, with the proviso that such optional components are chemically and physically compatible with the essential components of the compositions. Shampoo compositions, or are not otherwise excessively detrimental to the aesthetic product or to the performance. 3" Additional Optional Surfactants The shampoo compositions of the present invention may further comprise a secondary surfactant. The concentrations of such optional secondary surfactants range from about 0% to about 30%, preferably from about 2% to about 15% and more preferably from about 4% to about 8% by weight of the shampoo compositions. Optional secondary surfactants suitable for use in shampoo compositions are those selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, zwitterionic surfactants, and mixtures thereof. Such surfactants are well known to those skilled in the art. Preferably, these optional secondary surfactants are detersive surfactants. By "detersive" it is meant that these surfactants provide a cleaning or detergent benefit. Non-limiting examples of secondary surfactants suitable for use in the compositions of the present invention are described in McCutcheon's, Dtergents and Emulsifiers, North American edition (1986), published by allured Publishing Corporation; McCutcheon's, Functio'nal Ma t e r i a 1 s, North American Edition (1992); U.S. Patent No. 5,151,210, to Steuri et al., Issued September 29, 1992; U.S. Patent No. 5,151,209, to McCall et al., Issued September 29, 1992; U.S. Patent No. 5,120,532, to Wells et al., Issued June 9, "1992; U.S. Patent No. 5,011,681, Ciotti et al., Issued April 30, 1991; United States Patent no. 4,788,006, by Bolich, Jr. et al., issued November 29, 1988; U.S. Patent No. 4,741,855, to Grote et al., Issued on May 3, 1988; U.S. Patent No. 4,704,272, to Oh et al., Issued November 3, 1987; U.S. Patent No. 4,557,853, to Collins, issued December 10, 1985; U.S. Patent No. 4,421,769, to Dixon et al., Issued December 20, 1983; and U.S. Patent No. 3,755,560, Dickert et al., issued August 28, 1973; each of these documents is ,Y.? ^ r it is incorporated herein by reference in its entirety. The following are non-limiting examples of useful surfactants herein. It must be recognized that care must be taken to determine the level of these surfactant materials used so as not to interfere with the deposition and performance characteristics of the styling polymer. Also, care must be taken to select the additional surfactant and its level, such that the softness properties of the compositions are not compromised. Among the anionic surfactants which are useful herein are those which can be defined in general as condensation products of long-chain alcohols, for example alcohols, of C8-30, with sugar or starch polymers, i.e., glycosides . These compounds can be represented by the formula (S) n-0-R, wherein S is a sugar portion such as glucose, fructose, mannose and galactose; n is an integer from about 1 to about 1000, and R is an alkyl group, of C8-30. Examples of alcohols, long chain from which the alkyl group can be derived, include decyl alcohol, cetyl alcohol, alcohol and .S * P e.stearyl, lauryl alcohol, myristyl alcohol, oleyl alcohol and the like. Preferred examples of these surfactants include those wherein S is a glucose portion, R is an alkyl group of C8-20, and n is an integer from about 1 to about 9. Commercial examples of these surfactants include decylpol iglucos gone (available as APG 325 CS from Henkel) and laur i lpol iglucós ido (available as APG 600CS and 625CS from Henkel). Other useful nonionic surfactants include the condensation products of alkylene oxides with fatty acids (ie, alkylene oxide of fatty acid esters). When these particular non-ionic surfactants are used, it is preferable to use them at low concentrations, preferably in combination with one or more of the other surfactants described herein. These materials have the general formula RCO (X) nOH, wherein R is an alkyl group of C10-30, X is -OCH2CH2- (ie, derived from ethylene glycol or oxide) or -OCH2CHCH3- (ie, derivative from propylene glycol or oxide), and n is an integer from about 1 to about 100. Other nonionic surfactants are the products of T3P condensation of alkylene oxide-s with 2 moles of fatty acids (i.e., alkylene oxide diethers of fatty acids). These materials have the general formula RCO (X) nOOCR, wherein R is an alkyl group of C10-30, X is -OCH2CH2- (ie, derived from ethylene glycol or oxide) or -OCH2CHCH3- (ie derivative -from propylene glycol or oxide), and n is an integer from about 1 to about 100. Other non-ionic surfactants are the condensation products of alkyl oxides with fatty alcohols (ie, alkyl oxide ethers of fatty alcohols) . These materials have the general formula R (X) nOR ', wherein R is an alkyl group of C10-30, X is -OCH2CH2- (ie, derived from ethylene glycol or oxide) or -OCH2CHCH3- (is said, derived from propylene glycol or oxide), and n is an integer from about 1 to about 100 and R 'is H or an alkyl group of C10-30. Still other nonionic surfactants are the condensation products of alkylene oxides with both fatty acids and fatty alcohols [i.e., wherein the polyalkylene oxide portion is esterified on one side with a fatty acid and etherified (i.e. of an ether link) on the other side with an alcohol ^ P fatty. These materials have the general formula RCO (X) nOR ', wherein R and R' are alkyl groups of CIO-30, X is -OCH2CH; (ie, derived from ethylene glycol or oxide) or -OCH2CHCH3- (derived from propylene glycol or oxide) and n is an integer from about 1 to about 100. Non-limiting examples of these nonionic surfactants derived from alkylene oxide include ceteth-1, ceteth-2, ceteth-6, ceteth-10, ceteth-12, c.eteareth-2, ceteareth-6, ceteareth-10, ceteareth-12, steareth-1, steareth-2, steareth-6, steareth-10 , steareth-12, PEG-2 stearate, PEG-4 stearate, PEG-6 stearate, PEG-10 stearate, PEG-12 stearate, PEG-20 glyceryl stearate, PEG-80 glyceryl sebacate , glyceryl stearate of 'PEG 1.0, glyceryl cocoate of PEG-30, cocoate of glyceryl of PEG-80, glyceryl sebacate of PEG-200, dilaurate of PEG-8, distearate of PEG-10 and their mixtures. Still other useful nonionic surfactants include polyhydroxy fatty acid amide surfactants corresponding to the structural formula: O Rl R2 N wherein: R "is H, C?-C, 2-hydroxyethyl, 2-hydroxypropyl, preferably C 1 -C 4 alkyl, more preferably methyl or ethyl, more preferably methyl; R 2 is alkyl or alkenyl of C5-C3 ?, preferably C7-C19 alkyl or alkenyl, more preferably C9-C17 alkyl or alkenyl, more preferably Cn-C5 alkyl or alkenyl and Z is a polyhydroxyhydrocarbyl portion having a chain linear hydrocarbyl with at least 3 hydroxyls directly attached to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof Z is preferably a sugar portion selected from the group consisting of glucose, fructose, maltose, lactose, galactose, mannose, xylose and mixtures thereof An especially preferred surfactant corresponding to the above structure is alkyl-N-methyl glucosidoamide (ie, wherein the R2CO- portion is derived from oil fatty acids of coconut.) The processes to produce r the compositions containing polyhydroxy fatty acid amides are described, for example, in the Specification of «= 1 -S * F Patent of G.B. 809,060, published February 18, 1959, by Thomas Hedley & Co. , Ltd .; U.S. Patent No. 2,965,576, to E.R. Wilson, issued December 20, 1960; U.S. Patent No. 2,703,798, for A.M. Schwartz, issued March 8, 1955; and U.S. Patent No. 1,985,424, to Píggott, issued December 25, 1934; which are incorporated herein by reference. A wide variety of anionic surfactants are useful herein. See, for example, the United States Patent 'No. 3,929,678, to Laughlin et al., Issued December 30, 1975, which is incorporated herein by reference in its entirety. Non-limiting examples of anionic surfactants include the alkyl isethionates and the alkyl and alkyl ether sulfates. The alkyl isethionates typically have the formula RCO-OCH2CH2S03M wherein R is alkyl or alkenyl from about 10 to about 30 carbon atoms and M is a water-soluble cation such as ammonium, sodium, potassium and triethanolamine. Np limiting examples of these isethionates include those alkyl isethionates selected from the group consisting of isethionate of 3B ammonium cocoyium, sodium cocoyl isethionate, sodium lauroyl isethionate, sodium e-stearoyl isethionate and mixtures thereof. The alkyl and alkyl ether sulfates typically have the respective formulas ROS03M and RO (C? H40) SO3, wherein R is alkyl or alkenyl from about • 10 to about 30 carbon atoms, x is from about 1 to about 10, and M is a water-soluble cation such as ammonium, sodium, potassium and triethanolamine. Examples of these materials are sodium lauryl sulfate and ammonium lauryl sulfate. Other class -. Suitable anionic surfactants are the water-soluble salts of the organic-sulfuric acid reaction products of the general formula: R? -S03-M wherein Ri is selected from the group consisting of a straight or branched chain saturated aliphatic hydrocarbon radical having from about 8 to about 24, preferably from about 10 to about 16 carbon atoms, and - and M is a cation. Still others "33C Anionic synthetic ionic reactants include the cyan designated as succinamates, olefin sulfonates having from about 12 to about 24 carbon atoms, and sulfonates from b-to lchi loxia Icano. Other anionic materials useful herein are soaps (i.e., alkali metal salts, eg, sodium or potassium salts) of fatty acids, typically having from about 8 to about 24 carbon atoms, preferably about 10 to about 20 carbon atoms. The fatty acids used to produce soaps can be obtained from natural sources such as, for example, glycerides derived from plant or animal (for example, palm oil, coconut oil, soybean oil, castor oil, tallow, lard, etc.) Fatty acids can be prepared synthetically. The soaps are described in more detail in U.S. Patent No. 4,557,853, cited above. Cationic surfactants can also be used in the present invention. Non-limiting examples of surfactants, cationics useful herein include cationic ammonium salts such as those having the formula: R2 - N - R3 X- R4 e'n wherein R is selected from an alkyl group having from about 12 to about 22 carbon atoms, or aromatic aryl or alkaryl groups having from about 12 to about 22 carbon atoms; R2, R3 and R4 are independently selected from hydrogen, an alkyl group having from about 1 to about 22 carbon atoms, aryl or alkaryl, aromatic groups having from about 12 to about 22 carbon atoms; and X is an anion selected from chloride, bromide, iodide, acetate, phosphate, nitrate, sulfate, methyl sulfate, ethyl sulfate, tosylate, lactate, citrate, glycolate and mixtures thereof. Additionally, the alkyl groups may also contain ether, or hydroxy, or amino group substituents (for example, alkyl groups may contain polyethylene glycol and portions of poly ipropi lengli.col). More preferably, Ri is an alkyl group having from about 12 to about 22 vn carbon atoms; R is selected from H or an alkyl group having from about 1 to about 22 carbon atoms; R3 and R4 are independently selected from H or an alkyl group having from about 1 to about 3 carbon atoms; and X is as- described in the previous paragraph. More preferably, Ri is an alkyl group having from about 12 to about 22 carbon atoms; R2, R3 and R4 are selected from H or an alkyl group having from about 1 to about 3 carbon atoms; and X is as' previously described. Other quaternary ammonium and amino surfactants include those in the form of ring structures formed by covalently bonding the radicals. Examples of such cationic surfactants include imidazolines, imidazoliniums and pyridiniums, e.tc. , wherein the surfactant has at least one radical containing nonionic hydrophilic surfactant as set forth above. Specific examples include 2-heptadecyl-4,5-dihydro-lH-imidazole-1-ethanol, chloride ,. of 4, 5-dihydro-l- (2-hydroxyethyl) -2-isoheptadecyl-l-phenylmethyl-imidazolium vile i ^ SF and 1- [2-oxo-2 - [[2 [(1 -oxooct adec i i) oxy] -ethyl-] pyridinium chloride. Alternatively, other useful cationic surfactants include amino-amides, wherein in the above structure Ri is alternatively R5CO- (CH:) n-, wherein R5 is an alkyl group having about 12 a. about 22 carbon atoms, and n is an integer from about 2 to about 6, more preferably from about 2 to about 4, and most preferably from about 2 to about 3. Non-limiting examples of these cationic emulsifiers include Chloride phosphate is tearamidopropy 1-PG-dimonium, etosulfate of tearamidopropy 1-ethyl ester, tearamidopropyldimethyl chloride (myristyl acetate) ammonium, tosylate of tearamidopropyldimethylchltearylammonium, stearamidopropyldimethylammonium chloride, stearamidopropyl dimethylammonium lactate and mixtures thereof . Non-limiting examples of cationic surfactants of the quaternary ammonium salt include those selected from the group consisting of cetylammonium chloride, cetylammonium bromide, laurylammonium chloride, laurylammonium bromide, stearylammonium chloride, stearylammonium bromide, .J » cetyl dimethyl ammonium chloride, cetyl dimethyl ammonium bromide, lauryldimethyl ammonium chloride, lauryl dimethyl ammonium oromide, stearyl dimethyl ammonium chloride, stearyltrimethylammonium bromide, Idime thi-ammonium, cetyltrimethylammonium chloride, cetyltrimethylammonium bromide, lauryltrimethylammonium chloride, lauryltrimethylammonium bromide, stearyltrimethylammonium chloride , stearyltrimethylammonium bromide, lauryldimethylammonium chloride, stearyl-dimethyl-il-t-ethyl-di-dimethyl-ammonium chloride, dicylammonium chloride, di-ethyl ammonium bromide, dilaurammonium chloride, dilaurammonium bromide, distearylammonium chloride, distearylammonium bromide, dicetylmethylammonium chloride, dicetylmethylammonium bromide, dilaurylmethylammonium chloride, dilaurylmethylammonium bromide, diesarinyl ammonium chloride, distearyldimethylammonium chloride, diesaromethyl ammonium bromide and mixtures Additional quaternary ammonium salts include those wherein the C 12 to C 22 alkyl carbon chain is derived from a tallow fatty acid or from a coconut fatty acid. The term "tallow" refers to an alkyl group derived from tallow fatty acids (usually hydrogenated tallow fatty acids), which generally have -SB mixtures of alkyl chains in the range of C16 to C18. The term "coco" refers to an alkyl group derived from a coconut fatty acid, which generally has mixtures of alkyl chains in the range of C12 to C14. Examples of quaternary ammonium salts derived from these tallow and coconut sources include ditallowdimethyl ammonium chloride, ditallow dimethyl ammonium sulfate, di (hydrogenated tallow) dimethyl ammonium chloride, di (hydrogenated tallow) dimethylammonium acetate, dipropylammonium phosphate, ditallow dimethyl ammonium nitrate, di (coconut alkyl) dimethylammonium chloride, bromide. di (coconut alkyl) dimethylammonium, tallow-ammonium chloride, coconut-ammonium chloride, teramide-propyl-PG-dimonium chloride phosphate, tearamidopropyl-ildonium ethosulfate, tearamido-propyl-dimethyl-chloride (myristyl acetate) ammonium chloride , isositol tetrasilicate propyl dimethyl ammonium stearamidopropyl dimethylammonium chloride, stearamidopropyl dimethylammonium lactate and mixtures thereof. Other cationic surfactants for use in the present invention are those which are useful for providing conditioning benefits, particularly hair conditioning properties and which are composed of quaternary ammonium or amino which have at least one N radical containing one or more nonionic hydrophilic portions selected from the portions of alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl and alkyl ester, and combinations thereof. The surfactant contains at least one hydrophilic portion within 4 (inclusive), preferably within 3 (inclusive), carbon atoms of the quaternary nitrogen or cationic amino-nitrogen. For purposes herein, this means that the carbon atom not in the hydrophilic portion to the cationic nitrogen must be within the set number of carbon atoms relative to the nitrogen. Additionally, carbon atoms that are part of a hydrophilic moiety, for example, carbon atoms in a hydrophilic polyoxyalkylene (eg, -CH2-CH2-0-), which are adjacent to the other hydrophilic moieties are not counted when they determine the number of hydrophilic portions within 4, or preferably 3 carbon atoms of the cationic nitrogen. In general, the alkyl portion of any hydrophilic portion is preferably a C 1 -C 3 alkyl. Radicals containing suitable hydrophilic surfactants include, for example, ethoxy, propoxy, polyoxyethylene, polyoxy- t '"! -s» propylene, ethylamido, propylamido, hydroxymethyl, hydroxyethyl, hydroxypropyl, methyl ester, ethyl ester, p-ro-pyl ester or mixtures thereof, as non-ionic hydrophilic portions. Specific examples of the preferred quaternary ammonium salts include polyoxyethylene (2) is tearlmethyl ammonium chloride, methylabis bisulfate (hydrogenated tallowamidoethyl) -2-hydroxyethylammonium chloride, polyoxypropylene (9) diethylchloride methylammonium, tripol ioxiet ileum phosphate (PEG = 10 total), stearylammonium chloride, bis (N-hydroxyethyl-2-oleyl-1-imide zolium) phosphate chloride (12), and isododecylbenzyl chloride 1 trie t anolamonium The salts of primary, secondary and tertiary fatty amines of cationic surfactants are also preferred. Alkyl groups of such amines preferably have from about 1 to about 30 carbon atoms and must contain at least one, preferably 2 to about 10, non-ionic hydrophilic portions selected from alkoxy, polyoxyalkylene, alkylamido , hydroxyalkyl and alkyl ester portions, and mixtures thereof. Secondary and tertiary amines are preferred, tertiary amines are particularly preferred. The examples Suitable amines specific include laurate of diet i laminoe t i Ipo 1 ioxie t i leño (5), coco-pol igl icer i i -4 hydrcxipropi Idihidroxie t ilamina and hydrochloride, of dihydroxyethylseboamine. The cationic conditioning agents for use herein may also include a plurality of quaternary ammonium portions or amino portions or a mixture thereof. Examples of amphoteric and zwitterionic surfactants that can be used in the compositions of the present invention are those which are generally described as derivatives of secondary and tertiary aliphatic amines, in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 22 carbon atoms (preferably Cs-C13) and one alone contains an anionic water solubilizing group, for example, carboxy, sulfonate, sulfate, phosphate or phosphonate. Examples are alkylimino acetates and imino dialkanoate and amino alkanoates of the formulas RN [CH2) mC02M] 2 and RNH (CH2) mC02M, wherein m is from 1 to 4, R is a C8-C22 alkyl or alkenyl and M is H, alkali metal, alkaline earth metal-ammonium or alkanolammonium. I also know * they include the imidazolinium and ammonium derivatives. Specific examples of suitable amphoteric surfactants include sodium 3-dodecyl-1-aminopropionate, sodium 3-dodecylaminopropansulte, N-alkyl taurines such as the one prepared by reacting dodecylamine with sodium isethionate according to the teaching of the US Patent. U.S. 2,658,072, which is incorporated herein by reference in its entirety; alkalic acid acids of. N-high such as those produced in accordance with the teaching of U.S. Patent 2,438,091, which is hereby incorporated by reference in its entirety; and the products sold under the trade name "Miranol" and described in U.S. Patent 2,528,378, which is hereby incorporated by reference in its entirety. Other examples of useful amphoteric surfactants include phosphates, such as coamidopropyl PG-dimonium chloride phosphate (commercially available as Monaquat PTC, from Mona Corp.). Also useful herein as amphoteric surfactants q. zwitterionics are the betaines. Examples of betaines include the high alkyl betaines, such as cocodimet and lcarboxy- ""F ethylbetaine, lauryldimethylcarboxymethylbetaine, lauryldimethylaliphecarboxyethylbetaine, cet il dimet i 1-carboxymethylbetaine, cetyl dimethylbetaine (available as Lonzaine 165P from Lonza Corp.), lauryl bis- (2-hydroxyethyl) carboxymethylbetaine, stearyl bis- (2-hydroxypropyl) carboxymet ilbetaine, oleyldimethyl-gamma-carboxypropylbetaine, lauryl-bis- (2-hydroxypropyl) -alpha-carboxyethylbetaine, cocodimet-iulul-propyl-betaine, tert-ryl-dimethylsulfopropylbetaine, lauryldimethyl-ilsulfoet-ilbetaine, lauryl-bis- (2-hydroxyethyl) -sulfopropylbetaine and amidobetaines and amidosulfobetaines (e? where the radical -RC0NH (CH2) 3 is attached to the nitrogen atom of betaine), oleylbetaine (available as Veltex OLB-50 amphoteric from Henkel), and cocamidopropylbetaine (available as Velvetex BK-35 and BA-35 of Henkel). Other useful amphoteric and zwitterionic surfactants include the sultaines- and hydroxysultaines such as cocamidopropylhydroxy-sultaine (available as Mirataine CBS from Rhone-Poulenc), and the sarcosinates of. alkanoyl corresponding to the formula RCON (CH3) CH2CH2C02M, wherein R is alkyl or alkenyl of about 10 to about 20 carbon atoms, and M is a water-soluble cation such as ammonium, sodium, potassium and tra 1 canolamine (for example, triethanolamine). The surfactants mentioned in the foregoing may optionally be used in combination with AGS in the hair care compositions of the present invention. Preferred surfactants for use in the present shampoo compositions include ammonium lauryl sulphide, laurth sulfate ammonium, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, lauryl sulfate monoethanolamine, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, laureth sulfate or diethanolamine, sodium monoglyceride lauric sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate, potassium laureth sulfate , sodium lauryl sarcosinate, sodium lauroyl sarcosinate, lauryl sarcosine, cocoyl sarcosine, ammonium cocoyl sulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate, potassium cocoyl sulfate, potassium lauryl sulfate, lauryl sulfate of triethanolamine, triethanolamine lauryl sulfate, monoethanolamine cocoylsulfate, mo-noethanolamine lauryl sulfate, tridecylbenzene sodium sulte, dodecylbenzene sodium te, cocoamidopropyl lbetaine, cocobetaine, laurylamido-propylbetaine, oleylbetaine, and cocoanfocarbo-glycinate. More preferred are ammonium laureth sulfate, cocoamidopropyl lbetaine and combinations thereof.

Conditioning Agent The shampoo compositions of the present invention may further comprise a hair conditioning agent. This is the agent that provides additional conditioning benefits for the hair such as ease of combing, feeling of softness of the hair and docility for the user. The resulting shampoo composition provides cleaning, styling and hair conditioning benefits in a single product. The cationic surfactants, as described above, can be used to give some conditioning benefits in the present compositions. Protein derivatives in similar form, such as hydrolyzed animal proteins, for example Crotein SPA (Croda) or Lexeine X250 (Inolex) or Polypeptide LSN (Stephan), are : J & They can be used to provide conditioning benefits. The hair conditioning agent of the present invention can be a non-volatile siloxane or a siloxane-containing material and is present at a level from about 0.01% to about 10% of the shampoo composition, preferably about 0.1%. to about 5%, more preferably from about 0.2% to about 3%. Siloxanes (see, for example, U.S. Patent 3,208,911, Oppliger, issued September 28, 1965) and siloxane-containing polymers have been taught to be used in hair conditioning compositions. US Pat. No. 4,601,902, issued to Fridd et al., Issued July 22, 1986, describes conditioning compositions or shampoo / conditioner for hair including a polydiorganosiloxane having substituted groups of quaternary ammonium bonded to the silicone, and a polydiorganosiloxane - having substituents deposited on silicone which are amino-substituted hydrocarbon groups. U.S. Patent 4,654,161, Kolmeier et al., Issued March 31 of 1987, describes a group of organopolyses that contain betaine substituents. When used in the hair care compositions are to provide good conditioning and compatibility with the anionic components, their antibacterial properties and low skin irritation. U.S. Patent 4,563,347, Starch, issued January 7, 1986, relates to compositions for conditioning hair that include siloxane components containing substituents to provide hair fixation. Japanese Published Application 56-129,300, L.ion Corporation, published on October 9, 1981, relates to shampoo conditioning compositions which include an organopolis and loxane-oxyalkylene copolymer together with an acrylic resin. U.S. Patent 4,479,893, Hirota et al., Issued October 10, 19.84. describe shampoo conditioning compositions containing phosphate ester surfactant and a silicon derivative (eg, polyether or alcohol modified siloxanes). Polyether-modified polysiloxanes are also described for use in shampoos in U.S. Patent 3,957,970, Korkis, issued on 18 May 1976. U.S. Patent 4,185,087, Moruno, issued January 22, 1980, describes quaternary nitrogen derivatives of tyalkyl amino-hydroxy organosilicon compounds that are to have superior hair conditioning properties. . Each of the documents mentioned in the foregoing in this paragraph are incorporated in the present by reference in their entirety. Siloxane-derived materials can also be used in compositions for styling hair. Japanese Published Application 56-092,811, Lion Corporation, published on December 27, 1979, discloses hair setting compositions comprising an amphoteric acrylic resin, an organopolysiloxane denatured with polyoxyalkylene and polyethylene glycol. U.S. Patent 4,744,978, Homan et al., Issued May 17, 198.8, discloses compositions for styling hair (such as hair sprays) that include the combination of a carboxy functional polydimethylsiloxane and an organic polymer cationic containing amine or ammonium groups. Styling compositions for hair including polydiorganosiloxanes and a polymer Cationic organic are taught in U.S. Patent 4,733,677, Gee et al., issued March 29, 1988 and U.S. Patent 4,724,851, Comwall et al., issued February 16, 1988. Finally, , European Patent Application 117,360, Cantrell et al., published September 5, 1984, describes compositions, which contain a siloxane polymer having at least one nitrogen-hydrogen bond,. a surfactant and a solubilized titanate, zirconate or germanate, which acts both as a conditioner and as an aid to styling the hair. Each of the documents mentioned in the foregoing in this paragraph are hereby incorporated by reference in their entirety. __ The non-volatile silicone fluids are useful as the component of the conditioning agent in the shampoo compositions of the present invention. Examples of such materials include polydimethylsiloxane gums, aminosilicones and phenylsilicones. More specifically, materials such as polyalkyl or polyaryl siloxanes with the following structure: 3 wherein R is alkyl or aryl, and x is an integer from about 7 to about 8,000 which can be used. Some groups are represented by blocking the ends of the silicone chains. The substituted alkyl or aryl groups in the siloxane chain (.R) or the ends of the siloxane chains (A) may have any structure since the resulting silicones remain fluid at room temperature, are hydrophobic, or are irritating, toxic or otherwise harm when applied to the hair, are compatible with the other components of the composition, are chemically stable under normal use and storage conditions and are capable of being deposited on the hair. Suitable groups A include methyl, methoxy, ethoxy, propoxy and aryloxy. The two R groups on the silicone atom may represent the same group or different groups. 'Preferably, the two R groups represent the same group. Suitable R groups include methyl, ethyl, propyl, phenyl, methynyl and phenylmethyl. The preferred silicones are polydime t i ls iloxane, pol idiet i ls iloxane and pol imet inylsiloxane. Polydimethylsiloxane is especially preferred. Suitable methods for preparing these silicone materials are described in U.S. Patents 2,826,551 and 3,964,500 and the references cited therein, each of which is incorporated herein in its entirety. The silicones useful in the present invention are also commercially available. Suitable examples include Viscasil, a registered trademark of the General Electric Company and silicones offered by Dow Corning, Corporation and by SWS Silicones, a division of Stauffer Chemical Company. Other useful silicone conditioning materials include materials of the formula: where x and y are integers that depend on molecular weight, the average molecular weight that is approximately between 5,000 and 10,000. This polymer is also known as "amodimethicone". Other cationic silicone polymer conditioning agents that can be used in the present compositions correspond to the formula: (R?) AG3-aSY (0SiG2) n (0SÍGb (R1) 2-b) m0SiG3-a (R?) A wherein G is selected from the group consisting of hydrogen, phenyl, OH, C? -C8 alkyl, and preferably methyl; a means 0 or an integer from 1 to 3 and preferably equals 0; b means 0 or 1 and preferably equals 1; the sum n + m is a number from 1 to 2,000 and preferably from 50 to 150, n being able to mean a number from 0 to 1,999 and preferably from 49 to 149 and m being able to mean an integer from 1 to 2,000 and preferably from 1 to 10; R1 is a monovalent radical of the formula CqH2qL in which q is an integer from 2 to 8 and L is selected from the groups -N (R2) CHt-CH2-N (R2) 2 -N (R2) 2 -N (R2) 3A " -N (R2) CH2-CH2-NR2H2A wherein R2 is selected from the group consisting of hydrogen, phenyl, benzyl, a saturated hydrocarbon radical, preferably an alkyl radical containing 1 to 20 carbon atoms and A means a halide ion. These compounds are described in more detail in European Patent Application EP 95,238, which is incorporated by reference in its entirety. An especially preferred polymer corresponding to this formula is the polymer known as "trimeth ils i lilamodimetone" of the formula: ^ Other cationic silicone polymeric conditioning agents that can be used in the present compositions correspond to the formula: wherein R3 means a monovalent hydrocarbon radical having from 1 to 18 carbon atoms-, and more especially an alkyl or alkenyl radical such as methyl; R4 means a hydrocarbon radical such as, preferably, an alkylene radical of Ci-Ciß or a radical of alkyleneoxy of C1-C18 and preferably of Ci-Cg; Q ~ is a halide ion, preferably chloride, r means a statistical average value of 2 to 20, preferably 2 to 8; s means a statistical average value of 20 to 200 and preferably 20 to 50. These compounds are described in greater detail in the United States Patent. 4,185,017, which is incorporated by reference in its whole. A polymer of this kind which is especially preferred is that sold by UNION CARBIDE under the name "UCAR SILICONE ALE 56". The compositions of the present invention can also comprise a water-soluble hair conditioning agent. Although these cationic hair conditioning agents are not necessary for the benefit of styling, they have been shown to assist in the deposition of the polymer to stylize the hair and the extent of styling benefit. Hair conditioning agent thereof will generally be present at levels from about 0.05% to about 5%, preferably from about 0.1% to about 4%, more preferably from about 0.2% to about 3%, by weight, of the shampoo composition. Water-soluble conditioning agents thereof may include organic cationic polymers, organic cationic surfactants and cationic silicone fluids. By "soluble in water", what is meant is a material that is soluble in water at a concentration of 0.1% e-n water (distilled or equivalent) at 25 ° C; Preferably, the water-soluble cationic conditioning agent will be soluble at a concentration of 0.5%, more preferably at a concentration of 1.0%. In general, the polymer will be considered soluble if it forms a substantially clear solution with the naked eye. The water soluble cationic polymers useful as the hair conditioning agent thereof are polymers which can provide conditioning benefits for hair and which are soluble in the shampoo composition. Any cationic polymers that can provide these benefits can be used. As used herein, the term "polymer" will include materials that are made either by the polymerization of a single type of monomer or are made by two (ie, copolymers) or more types of monomers. The cationic organic polymers thereof will generally have an average molecular weight that is at least about 5,000, typically at least about 10,000 and less than about 10 million. Preferably, the molecular weight is from about 100,000 to about 2 million. The cationic polymers will have cationic - nitrogen containing portions, such as cationic amino or quaternary ammonium portions or a mixture thereof.

Those skilled in the art will recognize that the charge density of the amino-containing polymers may vary depending on the pH and the isoelectric point of the amino groups. The polymer should be within the solubility limits prior to the intended use pH, which will generally be from about pH 3 to about pH 9, more generally from about pH 4 to about pH 8.. Any anionic counterions can be used for cationic polymers while the water solubility criteria are met. Suitable counterions include halides (for example, Cl, Br, I or F, preferably Cl, Br or I), sulfate and methyl sulfate. Others can also be used, since this list is not exclusive. The cationic portion containing nitrogen will generally be present as a substituent, in a fraction of the total monomer units of the cationic hair conditioning polymers. In this way, the cationic polymer can comprise copolymers, terpolymers, etc., of cationic units of amine or quaternary ammonium substituted monomer and other non-cationic units related thereto as units monomer spaders Such polymers are known in the art, and a variety can be found in the CTFA Csometic Ingredient Dictionary, 5th edition, edited by Wenninger and McEwen, (The Cosmetic, Toiletry, AHD Fragrance Association, Inc., Washington, D.C., 1993). Suitable cationic polymers include, for example, copolymers of vinyl monomers having cationic amine or quaternary ammonium functionalities with water-soluble spacer monomers such as acrylamide, methacrylamide, alkyl and dialkyl acrylamides, alkyl and dialkyl methacrylamides, alkyl acrylate, alkyl methacrylate, vinyl caprolactone and vinyl pyrrolidone. The substituted alkyl and dialkyl monomers preferably have C?-C7 alkyl groups, more preferably C?-TC3 alkyl groups. Other suitable spacing monomers include vinyl esters, vinyl alcohol (made by hydrolysis of polyvinyl acetate), maleic anhydride, propylene glycol and ethylene glycol. The cationic amines can be primary, secondary or tertiary amines, depending on the particular species and pH of the shampoo. In general, secondary and tertiary amines, especially tertiary amines are preferred. The amine substituted vinyl monomers can be polymerized in the amine form, and then optionally converted to ammonium by a quaternization reaction. The amines can also be quaternized in a similar manner subsequent to the formation of the polymer. For example, the tertiary amine functionalities can be quaternized by the reaction with a salt of the formula R'X, where R 'is a short chain alkyl, preferably a C1-C7 alkyl, more preferably an alkyl of C? -C3, and X is an anion that forms a water-soluble salt with the quaternized ammonium. The cationic ammonium and quaternary ammonium monomers include, for example, vinyl compounds substituted with dialkyl-minoalkyl acrylate, dialkylaminoalkyl methacrylate, monoalkylaminoalkyl acrylate, monoalkylaminoalkyl methacrylate, trialkyl methacryloxyalkyl ammonium salt, rialkylacryloxyalkyl ammonium salt, salts of diallyl quaternary ammonium and vinyl quaternary ammonium monomers having cationic nitrogen-containing rings such as pyridinium, imidazolium and quaternized pyrrolidone, for example alkylvinylimidazolium, alkyvinylpyridinium, alkylvinylpyrrolidone salts. The alkyl portions of these monomers are Cj.-C7 alkyls, preferably lower alkyls such as C1-C3 alkyls, more preferably Ci and C alkyls. • The cationic polymers thereof may comprise mixtures of monomer units derived from monomer substituted with quaternary ammonium and / or amine and / or compatible spacer monomers. Suitable cationic hair conditioning polymers include, for example, copolymers of l-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazolium salt (e.g. chloride salt) (industry-related by Cosmetic, Toiletry , and Fragrance Association, "CTFA", as Polyquat ernium-16), such as those commercially available from BASF Wyandotte Corp. (Parsippany, NJ, USA) under the trade name LUVIQUAT (for example, LUVIQUAT FC 370); copolymers of l-vinyl-2-pyrrolidone and dimethylaminoethyl methacrylate (related in industry by CTFA as Polyquaternium-11) such as those commercially available from Gaf Corporation (Wayne, NJ, USA) under the trade name GAFQUAT (for example, GAFQUAT 755N); cationic polymers containing diallyl quaternary ammonium, including, for example, homopolymers and copolymers of dimethyldiallylammonium chloride-acrylamide and dimethyldiallylammonium chloride, related in the industry (CTFA) such as Polyquaternium 6 and Polyquaternium 7, respectively; and acid salts of indole-alkyls of homo- and co-polymers of unsaturated carboxylic acids having from 3 to 5 carbon atoms, as described in U.S. Patent 4,009,256, incorporated herein by reference. reference. Other cationic polymers that can be used include polysaccharide polymers, such as cationic cellulose derivatives and cationic starch derivatives. Polymeric cationic polysaccharide materials suitable for use herein include those of the formula: R A-O (-R-N + -R3X) R; «* '- wherein: A is a residual group of anhydroglucose, such as an anhydroglucose residual of starch or cellulose, R is an alkylene, oxyalkylene, polyoxyalkylene hydroxyalkylene group, combinations thereof, Ri, R2 and 3 independently are alkyl, aryl, alkylaryl groups, arylalkyl, alkoxyalkyl or alkoxyaryl, each group contains up to about 18 carbon atoms, and the total number of carbon atoms for each cationic portion (ie, the sum of carbon atoms of R'i, R2 and R3) is preferably about 20 or less, and X is an anionic counterion, as previously described. Cellulose cationic is available from Amrchol Corp. (Edison, NJ, USA) in its Polymer JR® and LR® polymer series, as the hydroxyethylcellulose salts are reacted with trimethylammonium substituted epoxide, industry-related ( CTFA) as Polyquaternium 10. Another type of cationic cellulose - which includes the polymeric quaternary ammonium salts of hydroxyethylcellulose - is reacted with epoxide substituted with lauryl dimethyl ammonium, -related in industry (CTFA) as Polyquaternium 24. These materials are available from Amerchol Corp. (Edison, NJ. USA) under the trade name Polymer LM-200. Other cationic polymers that may be used include cationic guar gum derivatives, such as sodium chloride. hidroxipropi ltr imonio de guar (commercially available from Celanese Corp. in its Jaguar R series). Other materials include close ethers containing quaternary nitrogen (e.g., as described in U.S. Patent 3,962,418, incorporated by reference herein), and etherified close and starch copolymers (e.g., as described in US Pat. U.S. Patent 3,958,581, incorporated by reference herein). As discussed in the above, the cationic polymer thereof is soluble in water. This does not mean, however, that it must be soluble in. the shampoo composition. Preferably, however, the cationic polymer is either soluble in the shampoo composition or in a coacervate phase in the shampoo composition formed by the cationic polymer and anionic material. Coacervates of the cationic polymer can be formed with surfactants anionic or anionic polymers that can optionally be added to the compositions thereof (for example, sodium polystyrene sulfonate). Coacervate formation is dependent on a variety of criteria such as molecular weight, concentration and ratio of ionic materials interacting, ion concentration (including modification of ionic concentration, for example, by the addition of salts), charge density of the cationic and anionic species, pH and temperature. The coacervate systems and the effect of these parameters have been previously studied. See for example, J. Cas, et al., "Anionic and Cationic Compounds in Mixed Systems", Cosmetics & Toilertries, Vol. 106, April 1991, pp. 49-54, CJ 'van Os s, "Coacervat ion, Complex-Coacervat ion and Flocculat ion", J. Dispersion Science and Technology, Vol. 9 (5,6), 1988-89, pp. 561-573 and DJ Burgess, "Practical Analysis of Complex Coacervate Systems," J. Of Colloid and Interface Science, Vol. 140, No. 1, November 1990, pp. 227-238. It is believed that it is particularly advantageous for the cationic polymer to be present in the shampoo in a coacervate phase, or to form a coacervate phase of shampoo application or rinsing. for or from the hair. It is believed that coacervates are deposited more easily on the hair. In this way, it is generally preferred that the cationic polymer exists in the shampoo as a coacervate phase or forms a coacervate phase in dilution. If there is no longer a coacervate in the shampoo, the cationic polymer will preferably exist in a coacervate form in the shampoo in dilution with water for a ratio by weight of the water: shampoo composition of about 20: 1, more preferably a approximately 10: 1, still more than reference to approximately 8: 1. Techniques for the analysis of coacervate formation are known in the art. For example, microscopic analyzes of the shampoo compositions, at any chosen step of dilution, can be used to identify whether a phase of cancer has formed. Such a coacervate phase will be identifiable as an additional emulsified phase in the composition. The use of dyes can help distinguish the coacervate phase from other insoluble phases dispersed in the composition. Deconditioning ingredients such as oils and emollients can also be incorporated in the styling shampoo compositions of this invention.

Other Optional Components The shampoo compositions of the present invention may further comprise one or more other optional components known to be used in hair care compositions. The individual concentrations of such different optional components generally range from about 0.01% to about 10.0%, more typically from about 0.05%. at about 5.0% by weight of the shampoo composition. Examples of such different optional components include nacreous auxiliaries, such as coated mica, ethylene glycol distearate and PEG 3 distearate.; opacifiers such as Ti02; preservatives, such as benzyl alcohol, Glydant, Kathon, methylparaben, propylparaben and imidazolidinylurea; fatty alcohols such as cetearyl alcohol; sodium chloride; sodium sulfate; polyvinyl alcohol; ethyl alcohol; agents that adjust the pH, such as citric acid, sodium citrate, succinic acid, phosphoric acid, monosodium phosphate, disodium phosphate, sodium hydroxide and sodium carbonate; coloring agents, such as any of the dyes FD &C or D &C; perfumes; sequestering agents, such as disodium ethylenediamine t et ra-acetic acid; polymeric plasticizing agents, such as glycerin and propylene glycol; and thickeners and viscosity modifiers, such as a long chain fatty acid diethanolamide (e.g., lauric diethanolamide PEG), lauramide DEA, cocomonoet anol-amide, guar gum, xanthan gum, Crothix (Tet raes tearat or PEG-150 Pentaerythritol), methylcellulose, hydroxyethylcellulose, starches and starch derivatives. Salts such as sodium chloride can be used as necessary to adjust the viscosity. Other suitable thickening agents include long chain, nonionic alkylated cellulose ether thickening agents.

Manufacturing Method The styling shampoo compositions of the present invention can be made using conventional mixing and formulation techniques. For example, the styling polymer for Hair can first be dissolved in the non-polar volatile solvent. The remaining components are combined in a separation vessel and the polymer-solvent combination is added to those remaining components. The resulting shampoo composition should have a final viscosity from about 1500 to about 12,000 cps. The viscosity of the composition can be adjusted using sodium chloride as necessary.

Method of Use The shampoo compositions of the present invention can be used according to conventional shampooing methods or otherwise known to provide hair cleaning, styling and maintenance benefits. Such methods, when applied to the shampoo composition of the present invention, may comprise the following steps: (a) wetting the hair with water, (b) applying an effective amount of the shampoo composition of the present invention. to the hair, (c) washing the hair with the shampoo composition, (d) rinsing the shampoo composition from the hair, and (e) drying and styling the hair. As used herein, "effective amount" refers to an amount of the shampoo composition sufficient to provide the desired benefits of cleaning, styling and maintaining the hair considering the length and texture of the hair. After the '. hair is washed with the shampoo compositions of the present invention, the hair can be dried and stylized by conventional methods, for example combing, brushing, molding, curling, drying with heat, etc.

• EXAMPLES The compositions illustrated in Examples I-IX illustrate the specific embodiments of the shampoo compositions of the present invention, but are not intended to be limiting thereof. Other modifications can be assumed by the person skilled in the art without departing from the spirit and scope of the invention. These modalities Illustrated embodiments of the present invention provide excellent hair cleaning and styling performance. All the exemplified compositions are prepared by conventional formulation and mixing techniques. Component quantities are listed as percentages by weight and are excluded - secondary materials such as diluents, fillers, etc. The compositions listed therefore comprise the listed components and any of the secondary materials associated with such components.

Hair Styling Agents: A-E Mixtures The following table sets forth the specific modalities of the hair styling agents to be used in the shampoo compositions of the present invention. These styling agents (identified as Mixtures A-E) are incorporated into the shampoo compositions described in Examples I-IX set forth below. The following numbers in parentheses of each listed polymer are relative weight ratios of the monomers in which the polymer is listed. Each of the exemplified compositions provide excellent cleaning performance and hair styling.

Mixture A. Ratio p / p Polymer: indene / - 2-ethylhexyl methacrylate (90/10 w / w) 40 Solvent: isododecane 60 Mixture B. Polymer: isobornyl ratacrilate / 2-ethylhexyl methacrylate (90/10 w / w) 50 Solvent: isododecane 50 Mixture C. Polymer: t-butylstyrene / 2-ethylhexyl methacrylate (50/50 w / w) 40 Solvent: isohexadecane 60 Mixture D. Polymer: t-butylstyrene / 2-ethylhexyl methacrylate (50/50 p) / p) 30 Solvent: Isoparaffin mixture of (C11-C12) 1 70 Mixture E. Polymer: indene / - 2-ethylhexyl methacrylate (60/40 p / p). 40 Solvent: Isoparaffin Mixture of (Cu-Cu) 2 60 1 Sold as Isopar -H by Exxon, which is a mixture of Cu-C iso 2 isoparaffins. 2 Sold as Isopar L by Exxon, which is a mixture of Cu-C? 2 isoparaffins.

Mixes A to E (combinations of styling polymer for the hair and volatile non-polar solvent) are prepared by placing the appropriate non-polar volatile solvent in a suitable container, and then adding the appropriate styling polymer to the container. The mixture is then stirred while heating to approximately 71.11-82.22 ° C (160-180 ° F) until the polymer completely dissolves.

EXAMPLES I-V The compositions described in Examples I-V are specific embodiments of the shampoo compositions of the present invention.

Component% by Weight I II III rv v Ammonium Laureth Sulfate 2.00 2.00 8.00 2.00 2.00 Cocoa idopropylbetaine F 6.00 6.00 6.00. 6.00 6.00 Ammonium Lauryl Sulfate 0.00 2.00 0.00 0.00 0.00 Alkylglyceryl sulfonate - • 10.00 8.00 10.00 4.00 10.00 Mixture A 6.00 Mixture B 8.00 Mixture C 4.00 Mixture D 4.00 Mixture E 8.00 Monosodium Phosphate 0.1 0.1 0.1 0.1 0.1 Disodium Phosphate 0.2 0.2 0.2 0.2 0.2 Glycol distearate 2.00 2.00 2.00- 2.00 2.00 Cocomonoethanolamide 0.70 0.70 0.70 0.70 0.70 Fragrance 0.8 0.8 0.8 0.8 0.8 Pentaerythritol tetrastearate PEG-150 0.40 0.45 0.15 0.30 0.45 Cetyl Alcohol - 0.42 0.42 0.42 0.42 0.42 Esteartílico Alcohol 0.18 0.18 0.18 0.18 0.18 Polyquaternium 10 0.30 0.50 0.40 0.30 0.50 Dimethicone1 0.00 0.00 0.00 1.50 1.50 Hydantoin DMDM 0.37 0.37 0.37 0.37 0.37 Water CS 100 CS 100 CS 100 CS 100 CS 10C 1 This material is a 40/60 weight ratio blend of polydimethylsiloxane gum (GE SE 76, available from General Electric Company, Silicone Products Division, Waterford, NY, USA) and polydi-ethylsiloxane fluid (approximately 350 centistokes).

In a suitable container, glycol distearate, cocomonoethanolamide, pentaerythritol tetrastearate, PEG-150, cetyl alcohol, stearyl alcohol, monosodium phosphate and disodium phosphate are combined with all the AGS and half of each of the remaining surfactants [laureth -ammonium sulphide, cocoamidopropylbetaine F, (and ammonium lauryl sulfate when present)]. The mixture is then heated to about 71.11-82.22 ° C (160-180 ° F) and stirred until the solids melt. This mixture is cooled to room temperature. In another vessel, then • Polyquaternium-10, which is pre-dissolved in water, is added to the other ingredients cooled with mixing. The mixture of the appropriate polymer and the remaining ingredients are added with stirring. The resulting shampoo product is useful both for cleaning the hair and providing benefits to maintain the hair's style.

EXAMPLE VI The composition described in Example VI is a specific embodiment of the shampoo composition of the present invention. The composition is prepared by a similar method that described in Examples I-V.

Component% by Weight Alkylglycerol Sulphonate 14. .00 Mixture A 6.00 Monodisodium Phosphate 0. .1 Disodium Phosphate 0. .2 Glycol Distearate 2. .00 Cocomonoetanolamide 0.70 Fragrance 0. .8 Pentaerythritol Tetrastearate PEG-150 0.40 Alcohol Cetyl 0.42 Stearyl Alcohol •. 0.18 Polyquaternium 10 0.30 Hydantoin DMDM 0.37 Water CS EXAMPLES VII-IX The compositions described in the Examples V.II-IX are specific embodiments of the shampoo compositions of the present invention. The compositions are prepared by methods similar to those described in Examples I-V.

Component% by Weight VII VIII IX Ammonium Laureth Sulfate 2.00 2.00 2.00 Cocoamidopropylbetaine F 6.00 6.00 6.00 Ammonium Lauryl Sulfate 0.00 0.00 0.00 Alkylglycerol Sulphonate 10.00 10.00 10.00 Mixture A 9.00 3.0 1.50 Monosodium Phosphate 0.1 0.1 0.1 Disodium Phosphate 0.2 0.2 0.2 Glycol Distearate 2.00 2.00 2.00 Cocomonoethanolamide 0.70 0.70 0.70 Fragrance 0.8 0.8 0.8 Pentaerythritol tetrastearate PEG-150 0.50 0.15 Cetyl alcohol 0.42 0.42 0.42 Stearilic alcohol 0.18 0.18 0.18 Polyquaternium 10 0.50 0.30 0.30 Dimethicone1 0.00 0.00 0.00 Hydantoin DMDM 0.37 0.37 0.37 Water CS 100 CS 100 CS 100 1 This material is a 40/60 weight ratio blend of polydimethylsiloxane gum (GE SE 76, available from General Electric Company, Silicone Products Division, aterford, NY, USA) and polydimethylsiloxane fluid (about 350 centistokes).

Claims (23)

1. A shampoo composition for styling hair characterized in that it comprises: (a) from about 2% to about 25%, by weight, of an alkylglyceryl ether sulphonate surfactant; (b) from about 0.1% to about 10%, by weight, of a hydrophobic water-insoluble hair-styling polymer comprising hydrophobic monomer units selected from the groups consisting of styrene; p'oliestirene macromonomer; alpha methylstyrene, t-butyl styrene; indene; norbornylene; β-pinene; a-pinene, 4-biphenyl acrylate, pentachlorophenyl acrylate; 3, 5-dimethyladamantyl acrylate; 3, 5-dimethyl-adamantyl methacrylate; 4-methoxycarbonylphenyl methacrylate; trimethylsilyl methacrylate; i-bornyl acrylate, isobornyl methacrylate; and combinations thereof, (c) from about 0.1% to about 10%, by weight, of a non-polar volatile solvent to solubilize the polymer to styling the hair, the non-polar volatile solvent having a boiling point of no more of approximately 300 ° C and one solubility in water at 25 ° C of less than about 0.2% per pe; and (d) from about 50% to about 97.8% water; wherein the ratio by weight of the polymer for styling the hair to the volatile polar solvent is from about 10:90 to about 70:30.

2. The shampoo composition according to claim 1, characterized in that the weight ratio of the polymer for styling the hair to the non-polar volatile solvent is from about 30:70 to about 60:40.

3. The shampoo composition, according to claim 2, characterized in that the non-polar volatile solvent has a boiling point from about 100 ° C. at approximately 200 ° C.

4. The shampoo composition, according to claim 3, characterized in that the concentration of the non-polar volatile solvent is about 1% to about 6% by weight of the composition.

5. The shampoo composition according to claim 4, characterized in that the non-polar volatile solvent is selected from the group consisting of hydrocarbons, ethers and combinations thereof.

6. The shampoo composition, according to claim 5, characterized in that the non-polar volatile solvent is a straight or branched chain hydrocarbon having from about 8 to about 18 carbon atoms.

7. The shampoo composition according to claim 6, characterized in that the hydrocarbon is selected from the group consisting of isohexadecane, isododecane, 2,5-dimethdecanocane, isotetradecane and combinations.

8. The shampoo composition, according to claim 7, characterized in that the hydrocarbon is isododecane.

9. The shampoo composition, according to claim 1,. characterized in that the alkylglyceryl ether sulphonate surfactant comprises alkyl chains of which at least about 50% are derived from alcohols of about 10 to about 18 carbons, and contain less than about 30% diglycerol radicals.

10. The shampoo composition, according to claim 9, characterized in that the concentration of the polymer for styling the hair is from about 0.5% to about 5% by weight of the composition.

11. The shampoo composition according to claim 10, characterized in that the crystalline transition t-emperature of the polymer for styling the hair is from about 20 ° C to about 60 ° C.

12. The shampoo composition, according to claim 1, further characterized in that the composition comprises from about 2% to about 15% by weight of a surfactant secondary selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, zwitterionic surfactants and mixtures thereof.

13. The shampoo composition according to claim 12, characterized in that the secondary surfactant is selected from the group consisting of amphoteric surfactant, anionic surfactant and combinations thereof.

The shampoo composition, according to claim 1, characterized in that the hair styling polymer comprises t-butylstyrene monomer units.

15. The shampoo composition according to claim 1, characterized in that the hair styling polymer is selected from the group consisting of t-butyl styrene / 2-ethylhexyl methacrylate copolymer, styrene acrylate / ethylhexyl copolymer, t-butylstyrenes / ethylhexyl ethacrylate copolymer and combinations thereof.

16. A shampoo composition for styling hair characterized in that it comprises: (a) from about 2% to about 25%, by weight, of an alkylglyceryl ether sulphonate surfactant containing alkyl chains of which at least about 50% are derived from alcohols having from about 10 to about 18 carbons, and contains less than about 30% diglycerol radicals (b) from about 0.5% to about 5%, by weight, of a polymer to styling the hair, hydrophobic having a crystalline transition temperature from about 0 ° C to about 80 ° C, a solubility in water at 25 ° C of less than about 0.2% by weight and hydrophobic monomer units selected from the group consisting of styrene; polystyrene macromonomer , 'alpha methylstyrene; t-butylstyrene; indene; norbornylene; ß-pinene; a-pinene; 4-biphenyl acrylate; pentachlorophenyl acrylate; 3, 5-dimetyl acrylate iladamantyl; 3,5-dimethyladamantyl methacrylate; 4-methoxycarbonylphenyl methacrylate; trimethylsilyl methacrylate; bicycloheptadiene; 2, 3-dicarboxylmethyl-1, 6-hexadiene; isobornyl acrylate; isobornyl methacrylate; and combinations thereof. (c) from about 1% to about 6%, by weight, of a straight or branched chain hydrocarbon solvent having from about 8 to about 18 carbon atoms, and a boiling point of not more than about 300 ° C , to solubilize the polymer to stylize the hair; and (d) from about 50% to about 97.8% water; wherein the ratio by weight of the polymer for styling the hair to the non-polar volatile solvent is from about 30:70 to about 60:40.

17. The shampoo composition, according to claim 16, characterized in that the non-polar volatile solvent is a straight or branched chain hydrocarbon having from about 8 to about 18 carbon atoms.

18. The shampoo composition, according to claim 17, characterized in that the The hydrocarbon is selected from the group consisting of isohexadecane, isododecane, 2,5-dimethdecanocane, isotetradecane and combinations.

19. A method for cleaning and styling, the hair, which method characterized in that it comprises the steps of: (a) wetting the hair with water, (b) applying an effective amount of the shampoo compositions, in accordance with claim 1, to hair, (c) shampooing the hair with the shampoo composition, (d) rinsing the hair shampoo composition, and (e) drying and styling the hair.

20. A method for cleaning and styling the hair, which method characterized in that it comprises the steps of: (a) wetting the hair with water, (b) applying an effective amount of the shampoo compositions, according to claim 16, hair, (c) shampooing the hair with the shampoo composition, (d) rinsing the hair shampoo composition, and (e) drying and styling the hair.

21. The shampoo composition, according to claim 1, further characterized in that it comprises a conditioning agent.

22. The shampoo composition, according to claim 21, characterized in that the conditioning agent is a cationic polymer.

23. The shampoo composition, according to claim 22, characterized in that the cationic polymer is a cationic cellulose.